KR100477118B1 - A layer film sheet of intercepting light for personal computer printing - Google Patents

A layer film sheet of intercepting light for personal computer printing Download PDF

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Publication number
KR100477118B1
KR100477118B1 KR10-2002-0028443A KR20020028443A KR100477118B1 KR 100477118 B1 KR100477118 B1 KR 100477118B1 KR 20020028443 A KR20020028443 A KR 20020028443A KR 100477118 B1 KR100477118 B1 KR 100477118B1
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layer
light
shielding
laminated
film sheet
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KR10-2002-0028443A
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Korean (ko)
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KR20030090851A (en
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김양평
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주식회사지엠피
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/502Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52Macromolecular coatings

Abstract

퍼스날 컴퓨터 실사프린트용 차광적층필름시트에 있어서 금속진공증착층으로 하는 차광층을 합성수지재의 차광층으로 적층 구성하므로서 종래 합성수지재와 금속증착층의 이질성으로 발생하는 문제점을 해소하므로서 내굽힘성의 향상은 물론 제품전체의 품질을 크게 향상시킨 피씨실사프린트용 차광적층필름시트에 관한 것임.   In the light-shielding laminated film sheet for personal computer real-life printing, the light-shielding layer serving as the metal vacuum deposition layer is laminated with the light-shielding layer of synthetic resin, thereby eliminating the problems caused by the heterogeneity of the conventional synthetic resin material and the metal-deposited layer, as well as improving bending resistance. The present invention relates to a light-shielding laminated film sheet for PC yarn prints, which greatly improves the quality of the whole product.

Description

피씨 실사프린트용 차광적층필름시트{A LAYER FILM SHEET OF INTERCEPTING LIGHT FOR PERSONAL COMPUTER PRINTING}    Shading film sheet for PC real-life printing {A LAYER FILM SHEET OF INTERCEPTING LIGHT FOR PERSONAL COMPUTER PRINTING}

본 발명은 퍼스널 컴퓨터(PERSONAL COMPUTER)실사프린트용 차광적층필름에 관한 것으로 구체적으로는 실사프린트된 적층필름시트를 광고용, 선전용으로 사용할 때 특히 배면 방향에서 빛의 투과에 의한 산란현상으로 화상이 분명하게 보이지 않거나 어지럽게 보이는 것을 방지하기 위하여 실사프린트용 적층필름층에 차광층을 적층시킨 피씨 실사프린트용 차광적층필름에 관한 것이다.    BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a light-shielding laminated film for personal computer photorealistic printing. Specifically, when the photorealistic printed laminated film sheet is used for advertisement or promotional purposes, the image is clearly seen due to scattering phenomenon due to light transmission in the back direction. The present invention relates to a light-shielding laminated film for PC real-life printing in which a light shielding layer is laminated on the live-printing laminated film layer in order to prevent it from being seen or dizzy.

종래 퍼스널 컴퓨터 실사프린트용 적층시트로서 차광성을 갖는 적층필름시트는 폴리에스텔필름에 알루미늄진공증착, 티-다이(T-die)를 이용한 익스투루젼라미네이숀(extrusion lamination)방법, 그라비아 인쇄방법 등의 수단을 이용 백색잉크메디아층, 프라이머층, 합성수지필름층, 알루미늄진공증착층, 백색접착제층, 합성수지필름층의 순서로 적층시킨 PC 실사프린트용 차광적층필름시트라 할 수 있다.    As a laminated sheet for a conventional personal computer photo print, a laminated film sheet having light shielding properties is made of aluminum vacuum deposition on a polyester film, an extrusion lamination method using a T-die, and a gravure printing method. A light shielding laminated film sheet for PC real-world printing, which is laminated in the order of a white ink media layer, a primer layer, a synthetic resin film layer, an aluminum vacuum deposition layer, a white adhesive layer, and a synthetic resin film layer, may be used.

이와 같은 차광적층필름시트는 알루미늄 진공증착층이 있어 빛의 차단성이 극히 우수하나 알루미늄 진공증착층은 금속 박막이므로 내굽힘성이 약하여 장기간 사용에 따른 재질의 피로가 오면 내면의 증착막에 파열이 발생하므로서 미세한 간극 사이로 빛이 투과하는 현상이 발생하고 또 폴리에스텔필름에 진공증착된 알루미늄 진공증착박막은 상호 열팽창계수의 차이가 크므로 수시로 변화하는 온도차이에 따라 팽창과 수축의 반복으로 양면간에 엄청난 전단력이 발생하므로서 결국에는 면과 면의 탈리현상이 일어나 이와 같은 틈으로 수분, 개스, 산소 등이 침투하여 금속 증착층을 산화 부식하게 되므로서 프린트된 화상이 희미하게 나타나고 얼룩이 생성되며 본래의 목적인 차광기능도 떨어지게 된다.    Such a light-shielding laminated film sheet has an aluminum vacuum deposition layer, which is extremely excellent in blocking light. However, since the aluminum vacuum deposition layer is a metal thin film, the bending resistance is weak due to weak bending resistance. Therefore, the phenomenon of light transmission between minute gaps occurs, and the aluminum vacuum deposition thin film vacuum-deposited on the polyester film has a large difference in mutual thermal expansion coefficient. Therefore, the shearing force between the two sides is greatly increased by repeated expansion and contraction according to the temperature difference that changes frequently. As a result, desorption of cotton and cotton occurs, water, gas, oxygen, etc. penetrate into the gaps, and the metal deposition layer is oxidized and corroded, resulting in faint printed images and stains. Will also fall.

본 발명은 종래 금속진공증착층을 차광층으로 적층시킨 피씨 실사프린트용 차광적층필름시트의 문제점을 해결하여 보다 우수한 차광적층필름을 제공함에 목적이 있으며 구체적으로는 차광층을 연접 적층되는 적층층과 유사한 재질로 구성하므로서 층간에 접착력을 높이고 이질성을 갖는 재질(층)간에 발생하는 문제점의 해결 즉 적층필름의 내굽힘성의 향상, 열팽창계수의 차이로 발생하는 층간의 박리현상방지등으로 우수한 차광기능의 보장은 물론 인쇄된 화상을 변질없이 장기간 보존할 수 있게 적층층을 조화있게 구성하므로서 내구성의 향상과 함께 차광성이 우수한 피씨 실사프린트용 차광 적층필름시트를 제공함에 목적이 있다.    The present invention has been made in view of solving the problems of the conventional film-printed light-shielding laminated film sheet laminated with a metal vacuum deposition layer as a light-shielding layer, and specifically, to provide a superior light-shielding laminated film, and specifically, a laminated layer in which a light-shielding layer is successively laminated. It is composed of similar materials to improve adhesion between layers and solve problems that occur between different materials (layers), that is, to improve the bending resistance of laminated films and to prevent peeling between layers due to the difference in thermal expansion coefficient. It is an object of the present invention to provide a light-shielding laminated film sheet for PC real-life printing with excellent light-shielding property by improving the durability and harmonizing the laminated layer so that the printed image can be stored for a long time without being deteriorated.

본 발명은 피씨 실사프린트용 차광적층필름시트에 관한 것으로 더욱 구체적으로는 종래 금속증착층을 차광층으로 적층시킨 피씨 실사프린트용 차광적층필름의 이질성의 재질적층에 따라 발생하는 문제점을 우수한 차광성을 가지면서 적층시트를 구성하는 타재질과의 유사한 합성수지 재질의 차광층으로 적층구성시킨 피씨 실사프린트용 차광적층필름시트로 이를 구체적으로 설명하면 베이스층인 백색폴리에치렌 박막층위에 잉크메디아층이 형성되어 있고 백색폴리에치렌박막층 아래면은 코로나 방전처리된 폴리에스텔면과 접착적층 되어있으며 폴리에스텔필름 타면 역시 코로나 방전처리되어있고 이면에 흑색 PE박막층이 접착적층되고 그 아래에 이형층(점착제층) 그리고 이형지의 순서로 적층된 피씨실사프린트용 차광적층필름시트의 구성이라 할 수 있다.    The present invention relates to a light-shielding laminated film sheet for PC real-life printing, and more particularly, to provide excellent light-shielding properties due to the heterogeneous material stacking of the light-shielding laminated film for real-life PC-printing, which is laminated with a conventional metal deposition layer as a light-shielding layer. It is a light-shielding laminated film sheet for PC real-life printing, which is composed of a light-shielding layer made of a synthetic resin material similar to the other materials constituting the laminated sheet. Specifically, an ink media layer is formed on the white polyethylene thin film layer as a base layer. The bottom side of the white poly ethylene thin film layer is adhesively laminated with the corona discharge treated polyester surface, and the other side of the polyester film is also corona discharge treated, and the black PE thin film layer is adhesively laminated on the back side, and the release layer (adhesive layer) is underneath. The composition of light-shielding laminated film sheets for PC yarn prints laminated in the order of release paper can do.

이와 같은 차광 적층필름시트의 구성을 좀더 구체적으로 파악하기 위해 이의 제조방법을 알아보면 먼저 코로나 방전처리된 폴리에스텔필름(PET film)일측면에 수용성의 이민계 프라이머(GMP200 : C.A.S.NO 7732-18-5)용액을 로울러 전이방법으로 코팅하여 열풍건조시킨 다음 그 위에 티-다이(T-die)를 이용 백색 PE용융박막층을 압출 도포하여 백색 PE박막층을 형성시키며 같은 방법으로 코로나 방전처리된 폴리에스텔필름 타면에도 프라이머(GMP200)용액을 로울러전이 방법으로 코팅하여 열풍건조시킨 다음 그 위에 티-다이(T-die)를 이용 흑색 PE용융박막층을 압출 도포하여 흑색 PE박막층을 형성시킨 다음 백색 PE박막층위에는 비닐계, 아크릴계, 우레탄계에서 선택되는 프라이머 접착제를 도포 건조한 후 잉크메디아층을 콤마코타로 코팅층을 형성시키고 흑색 PE박막층에는 점착제의 코팅층인 이형층을 형성시킨 후 그 위에 이형지로 첨착시키므로서 완전제품을 얻을 수 있다.    In order to understand the composition of the light-shielding laminated film sheet in more detail, first, a method of preparing the light-shielding laminated film sheet has a water-soluble imine-based primer (GMP200: CASNO 7732-18-) on one side of a corona discharge-treated polyester film. 5) The solution is coated by roller transfer method and hot-air-dried, and then the white PE molten thin film layer is extruded using T-die to form a white PE thin film layer. On the other side, the primer (GMP200) solution was coated by roller transfer method and hot-air dried. Then, the black PE molten thin film layer was extruded using T-die to form a black PE thin film layer, and then the vinyl on the white PE thin film layer. After applying and drying the primer adhesive selected from acrylic, urethane, and urethane, an ink media layer is formed with a comma coat, and a black PE thin film is formed. There was formed a coating layer of the release layer of the pressure-sensitive adhesive it is possible to obtain a full standing product because impregnated with a release paper thereon.

이상의 방법으로 얻어진 적층필름시트의 구조는 도 1에서와 같이 표면층이 잉크메디아층(1), 다음층이 프라이머(접착제)층(2), 백색 PE박막층(3), 프라이머(접착제)층(4), 폴리에스텔필름층(5), 프라이머(접착제)층(6), 흑색 PE박막층(7), 이형층(점착제층)(8), 이형지(9)의 순서로 적층된 피씨 실사프린트용 차광적층필름시트라 할 수 있다.    In the structure of the laminated film sheet obtained by the above method, as shown in Fig. 1, the surface layer is an ink media layer (1), the next layer is a primer (adhesive) layer (2), a white PE thin film layer (3), and a primer (adhesive) layer (4). ), Polyester film layer (5), primer (adhesive) layer (6), black PE thin film layer (7), release layer (adhesive layer) (8), release paper (9) laminated in order of light shielding It can be called a laminated film sheet.

여기에서 잉크메디아층은 미세실리카 입자를 주성분으로 하는 통상의 잉크메디아 조성물로 구성되며, 접착제(VMTA)층은 비닐계, 아크릴계, 폴리우레탄계의 프라이머 단독이거나 이들의 혼합 접착제이고 백색 PE박막층 또는 흑색 PE박막층과 폴리에스텔필름을 접합시키는 접착제는 수성의 이민계 프라이머 접착제이다.    Here, the ink media layer is composed of a conventional ink media composition mainly composed of microsilica particles, and the adhesive (VMTA) layer is a vinyl, acrylic or polyurethane primer alone or a mixed adhesive thereof, and a white PE thin layer or black PE. The adhesive for bonding the thin film layer and the polyester film is an aqueous imine-based primer adhesive.

또 백색 PE박막층은 저밀도폴리에치렌에 탄산칼슘, 이산화티탄, 백색안료를 첨가한 마스터벳치를 티-다이에서 용융압출시켜 형성시킨 박막층이고, 흑색 PE박막층 역시 저밀도폴리에치렌에 카본을 첨가시킨 마스터 벳치를 티-다이에서 용융 압출시켜 형성시킨 박막층이다.    In addition, the white PE thin film layer is a thin film layer formed by melt-extrusion of a low density polyethylene styrene with calcium carbonate, titanium dioxide and a white pigment in a tee-die, and the black PE thin film layer is also a master in which carbon is added to the low density poly ethylene. It is a thin film layer formed by melt-extruding a bezel from a tee-die.

그리고 구체적인 규격을 일예를들어 설명하면 잉크메디아층의 두께가 약 30미크론, 백색 PE박막층의 두께가 40미크론, 흑색 PE박막층의 두께가 30미크론, 폴리에스텔필름이 50미크론이며 양면이 코로나 방전처리된 필름이다. The specific specification will be described as an example. The ink media layer is about 30 microns thick, the white PE thin layer is 40 microns thick, the black PE thin layer is 30 microns thick, the polyester film is 50 microns thick, and both sides are corona discharged. It is a film.

그 밖에 잉크메디아층과 백색 PE박막층, 백색 PE박막층과 폴리에스텔필름(PET film), 폴리에스텔필름과 흑색 PE박막층 사이의 접착제층과 흑색 PE박막층과 이형지 사이의 점착제층의 두께는 접착제 코팅시 용매의 사용량 즉, 용액의 점도에 따라 약간의 차이는 있으나 수미크론에 불과할 정도로 엷게 코팅된다. In addition, the thickness of the adhesive layer between the ink media layer, the white PE thin film layer, the white PE thin film layer and the polyester film, the adhesive layer between the polyester film and the black PE thin film layer, and the black PE thin film layer and the release paper is the solvent during the coating of the adhesive. There is a slight difference depending on the amount of use, that is, the viscosity of the solution, but the coating is light enough to be only a few microns.

위와 같은 방법으로 구성된 실사프린트용 적층필름시트의 특징은 빛 차단성이 우수한 카본블랙이 첨가되므로서 흑색 PE박막층의 차광성 또한 우수하며 차광적층시트를 구성하는 각각의 적층층 다시 말하면 폴리에스텔필름층, 흑색 또는 백색의 PE박막층, 합성수지프라이머로 구성되는 접착제층 등이 종래 차광층으로 이질성의 금속 증착층과는 달리 상호 유사한 물성을 갖고 있을 뿐만 아니라 열팽창계수의 차이에 의하여 발생하는 전단력을 줄일 수 있으므로 층간에 큰 전단력이 발생하지 않아 층간의 박리현상을 방지내지는 줄일 수 있고 또한 차광층의 내굽힘성을 크게 향상시킬 수 있어 결국 전체적인 품질향상과 수명을 크게 연장시킬 수 있는 피씨 실사프린트용 차광적층필름시트라할 수 있다.   The feature of the laminated film sheet for the actual printing configured in the above manner is that carbon black having excellent light blocking property is added, and the light blocking property of the black PE thin film layer is also excellent, and each laminated layer constituting the light-shielding laminated sheet, that is, the polyester film layer , Black or white PE thin film layer, adhesive layer composed of synthetic resin primer, etc., unlike conventional metal deposition layer as a light shielding layer, not only have similar physical properties but also reduce the shear force caused by the difference in coefficient of thermal expansion Light shearing lamination film for PC due diligence printing, which can prevent the peeling phenomenon between layers because it does not generate large shear force between layers, and can greatly improve the bending resistance of light shielding layer. Citra.

이와 같은 차광적층필름시트는 프린팅하므로서 일반 선전 광고물로 널리 사용할 수 있음은 물론 유리진열장 외측면의 선전광고 인쇄물, 투명유리창문 및 유리문 등에 부착되는 선전광고인쇄물 등 화상배면에서 빛이 조사되는 장소에 적절한 피씨 실사프린트용 차광적층필름시트라할 수 있다. Such a shading laminated film sheet can be widely used as a general propaganda advertisement by printing, as well as propaganda advertisement prints on the outside of glass showcases, propaganda advertisement prints attached to transparent glass windows and glass doors, etc. Suitable light-shielding laminated film sheet for PC realistic print can be used.

도 1은 본 발명에 의한 차광적층필름시트의 측단면도    1 is a side cross-sectional view of a light-shielding laminated film sheet according to the present invention.

Claims (1)

백색 PE박막층(3), 프라이머(접착제)층(4), 폴리에스텔필름층(5), 프라이머(접착제)층(6), 흑색 PE박막층(7), 이형층(점착제층)(8), 이형지(9)의 순서로 적층된 베이스층의 백색 PE박막층(3) 표면에 프라이머(접착제)층(2), 그 위에 잉크메디아층(1)이 형성된 피씨 실사프린트용 차광 적층필름시트.   White PE thin film layer 3, primer (adhesive) layer 4, polyester film layer 5, primer (adhesive) layer 6, black PE thin film layer 7, release layer (adhesive layer) 8, A light-shielding laminated film sheet for PC real-life printing, in which a primer (adhesive) layer (2) and an ink media layer (1) are formed on the surface of the white PE thin film layer (3) of the base layer laminated in the order of the release paper (9).
KR10-2002-0028443A 2002-05-22 2002-05-22 A layer film sheet of intercepting light for personal computer printing KR100477118B1 (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20150014765A (en) * 2013-07-30 2015-02-09 동우 화인켐 주식회사 A frontal light-shielding layer of a display device and a display device having the frontal light-shielding layer

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62156994A (en) * 1985-12-28 1987-07-11 Canon Inc Medium and method for thermal transfer recording
US5319475A (en) * 1990-05-22 1994-06-07 De La Rue Holographics Limited Tamper resisting holographic security seal
US5472757A (en) * 1992-12-25 1995-12-05 Mitsubishi Paper Mills Limited Ink jet recording sheet
JPH0976647A (en) * 1995-09-12 1997-03-25 Oji Yuka Synthetic Paper Co Ltd Thermal transfer recording image receiving sheet
US6177187B1 (en) * 1996-07-13 2001-01-23 Sinhl Gmbh Recording material for inkjet printing
KR20030033441A (en) * 2001-10-23 2003-05-01 주식회사지엠피 A layer film sheet of intercepting light for personal computer printing

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62156994A (en) * 1985-12-28 1987-07-11 Canon Inc Medium and method for thermal transfer recording
US5319475A (en) * 1990-05-22 1994-06-07 De La Rue Holographics Limited Tamper resisting holographic security seal
US5472757A (en) * 1992-12-25 1995-12-05 Mitsubishi Paper Mills Limited Ink jet recording sheet
JPH0976647A (en) * 1995-09-12 1997-03-25 Oji Yuka Synthetic Paper Co Ltd Thermal transfer recording image receiving sheet
US6177187B1 (en) * 1996-07-13 2001-01-23 Sinhl Gmbh Recording material for inkjet printing
KR20030033441A (en) * 2001-10-23 2003-05-01 주식회사지엠피 A layer film sheet of intercepting light for personal computer printing

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20150014765A (en) * 2013-07-30 2015-02-09 동우 화인켐 주식회사 A frontal light-shielding layer of a display device and a display device having the frontal light-shielding layer
KR102028486B1 (en) * 2013-07-30 2019-10-04 동우 화인켐 주식회사 A frontal light-shielding layer of a display device and a display device having the frontal light-shielding layer

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