KR100463676B1 - A composition for retaining bordeaux mixture - Google Patents

A composition for retaining bordeaux mixture Download PDF

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KR100463676B1
KR100463676B1 KR10-2001-0086124A KR20010086124A KR100463676B1 KR 100463676 B1 KR100463676 B1 KR 100463676B1 KR 20010086124 A KR20010086124 A KR 20010086124A KR 100463676 B1 KR100463676 B1 KR 100463676B1
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composition
solution
lime
added
water
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KR20030055987A (en
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이태식
김호성
전종수
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인바이오믹스 주식회사
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/06—Aluminium; Calcium; Magnesium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/02—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N61/00—Biocides, pest repellants or attractants, or plant growth regulators containing substances of unknown or undetermined composition, e.g. substances characterised only by the mode of action

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
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Abstract

본 발명은 고상의 유화파라핀을 가열용해한후 스테아린산을 넣어 교반혼합하고 상기 혼합액에 가열된 물을 전체 사용량의 약 10%를 소량씩 가하면서 교반하여 탁한 백색으로 되면 다시 10%의 가열된 물을 가하면서 교반하여 상전환이 완료되면 나머지 물을 가해 교반하여 숙성시켜 석회보르도액 약효연장용 조성물의 부착율을 관찰조사한 결과, 유화파라핀에 스테아린산를 첨가하여 교반혼합후 가열된 물을 투입하여 교반 숙성시킴으로써 약해가 없고 약효지속기간도 증가된 석회보르도액 약효 연장용 조성물을 제조하는 뛰어난 효과가 있다.The present invention heat-dissolves the solid emulsion paraffin, and then stirred and mixed with stearic acid, and stirred with adding a small amount of the heated water to the mixed solution in a small amount of about 10% of the total amount of the solution added 10% heated water again When the phase conversion was completed by stirring, the remaining water was added to the mixture, followed by stirring to observe the adhesion rate of the composition for extending the lime bordea solution. As a result, stearic acid was added to the emulsified paraffin. There is an excellent effect of preparing a composition for extending lime bordeaux liquid drug efficacy and duration of increase.

Description

석회보르도액 약효연장용 조성물{A composition for retaining bordeaux mixture}Lime Bordeaux liquid pharmacologically effective composition {A composition for retaining bordeaux mixture}

본 발명은 석회보르도액 약효연장용 조성물에 관한 것이다. 더욱 상세하게는, 본 발명은 유화파라핀에 스테아린산를 첨가하여 교반혼합후 가열된 물을 투입하여 교반 숙성시켜 제조된 약해가 없고 약효지속기간도 증대된 석회보르도액 약효연장용 조성물에 관한 것이다.The present invention relates to a composition for extending the lime Bordeaux liquid drug. More specifically, the present invention relates to a lime bordo liquid drug-extension composition which is prepared by adding stearic acid to emulsified paraffin, stirred and mixed by stirring and mixing with heated water, and having an extended drug efficacy.

석회보르도액은 보호살균제로서 예방위주의 농약이므로 병원균에 작용하여 살균작용을 나타내기 위해서는 먼저 병원균의 세포벽을 투과하여야 한다. 그러나 병원균의 세포벽은 왁스(wax)와 단백질로 구성되어 있으므로 병원균의 세포내에 침투하여 작용점에 도달하려면 왁스와 잘 결합할 수 있는 친유성기와 단백질에 잘 결합할 수 있는 친수성기를 분자내에 동시에 가지고 있어야 한다.Lime Bordeaux liquid is a protective fungicide as a prophylactic pesticide, so it must first penetrate the cell wall of the pathogen in order to act on the pathogen. However, since the cell wall of the pathogen is composed of wax and protein, in order to penetrate into the cell of the pathogen and reach the point of action, the cell wall must have a lipophilic group that can bind to the wax and a hydrophilic group that can bind to the protein. .

석회보르도액의 효과는 제조후 시간이 경과함에 따라 살균력이 떨어지고 예방위주의 농약이므로 발병전에 살포하는 것을 원칙으로 하고 잠복기를 고려하여 병해의 증상이 발현되기 2-7일전에 살포하는 것이 좋고 살포후 유효기간은 기상조건에 따라서 상이하나 심한 강우가 없는 한 2주 정도 지속되며 특히 살포액은 강우전에 완전히 건조한 피막을 형성할 수 있어야 한다.The effect of lime Bordeaux solution is that sterilization power is decreased with time after manufacture, and it is a pesticide-oriented pesticide, so it should be sprayed before the onset of disease, and it should be sprayed 2-7 days before the onset of the disease considering the incubation period. The duration varies depending on weather conditions, but lasts about two weeks unless there is heavy rainfall, in particular the spray solution should be able to form a completely dry film before rainfall.

따라서 피막형성을 위해서는 살포된 농약의 식물체 표면 부착성을 좋게 해 주어야 하고 살포된 농약의 증기압을 낮게 유지시켜 주어야 하며 환경조건 특히 비 또는 이슬 등에 의하여 부착된 약제가 씻겨 내려가는 것을 방지하여야 한다.Therefore, in order to form the film, the surface adhesion of the sprayed pesticides should be improved, the vapor pressure of the sprayed pesticides should be kept low, and the attached drugs should be prevented from being washed away by environmental conditions, especially rain or dew.

또한 비와 이슬 등에 의하여 석회가 유실될 경우 약해의 원인이 되기도 한다.In addition, the loss of lime due to rain and dew can cause weakness.

본 발명자들은 상기와 같은 점을 감안하여 고상의 유화파라핀을 가열용해한후 스테아린산을 넣어 교반혼합하고 상기 혼합액에 가열된 물을 전체 사용량의 약 10%를 소량씩 가하면서 교반하여 탁한 백색으로 되면 다시 10%의 가열된 물을 가하면서 교반하여 상전환이 완료되면 나머지 물을 가해 교반하여 숙성시켜 석회보르도액 약효연장용 조성물의 부착율을 관찰조사함으로써 본 발명을 완성하였다.In view of the above, the present inventors heat-dissolve the solid emulsified paraffin, and then stir mixed with a stearic acid and stir while adding about 10% of the total amount of the heated water to the mixed solution by adding a small amount. When the phase inversion is completed by adding% of heated water, the remaining water is added and stirred to complete the present invention by observing the adhesion rate of the lime bordea liquid drug extension composition.

따라서, 본 발명의 목적은 유화파라핀에 스테아린산를 첨가하여 교반혼합후 가열된 물을 투입하여 교반 숙성시켜 제조된 약해가 없고 약효지속기간도 증대된 석회보르도액 약효연장용 조성물을 제공함에 있다.Accordingly, an object of the present invention is to provide a composition for extending the lime bordo liquid medicinal effect, which is prepared by adding stearic acid to the emulsified paraffin and then stirring and mixing by adding heated water after stirring and mixing.

본 발명의 상기 목적은 고상의 유화파라핀을 가열용해한후 스테아린산을 넣어 교반혼합하고 상기 혼합액에 가열된 물을 전체 사용량의 약 10%를 소량씩 가하면서 교반하여 탁한 백색으로 되면 다시 10%의 가열된 물을 가하면서 교반하여 상전환이 완료되면 나머지 물을 가해 교반하여 숙성시켜 석회보르도액 약효연장용 조성물의 부착율을 관찰조사함으로써 달성하였다.The above object of the present invention is to dissolve the solid emulsion emulsion paraffin, and then mixed with a mixture of stearic acid and stirred while adding about 10% of the total amount of the heated water to the mixed solution by a small amount to become cloudy white again 10% heated When the phase inversion was completed by stirring with water, the remaining water was added and stirred to achieve aging by observing the adhesion rate of the lime bordo liquid medicinal extension composition.

이하 본 발명의 구성을 설명한다.Hereinafter, the configuration of the present invention.

본 발명은 유화파라핀 24㎏에 스테아린산 4㎏을 첨가하여 교반혼합후 가열된 물을 투입하여 교반 숙성시켜 석회보르도액 약효연장용 조성물 I를 제조하는 단계; 유화파라핀 36㎏에 스테아린산 6㎏을 첨가하여 교반혼합후 가열된 물을 투입하여 교반 숙성시켜 석회보르도액 약효연장용 조성물 II를 제조하는 단계; 상기 단계에서 얻은 약효연장용 조성물들을 석회보르도액과 혼용하여 처리한 후 시간경과에 따른 약효성분의 부착률를 관찰하는 단계로 구성된다.The present invention comprises the steps of preparing a lime Bordeaux liquid medicinal composition I by adding 4 kg of stearic acid to the emulsion paraffin 24kg, stirred and mixed by stirring and mixing the heated water; Adding 6 kg of stearic acid to 36 kg of emulsified paraffin, stirring and mixing, adding heated water, and then stirring and ripening to prepare a composition for lime bordo liquid drug extension II; After medicating the composition for extending the drug obtained in the above step mixed with lime Bordeaux solution and consists of the step of observing the adhesion rate of the active ingredient over time.

본 발명에서 사용하는 베타사이드 엘엑스(Betacide LX)는 방부제이며 당업계에서 일반적으로 사용하는 다른 종류의 방부제로 대체사용이 가능하다.Betaside LX (Betacide LX) used in the present invention is a preservative and can be replaced by other types of preservatives generally used in the art.

이하 본 발명의 구체적인 방법을 실시예를 들어 단계별로 설명하고자 하지만 본 발명의 권리범위는 이들 실시예에만 한정되는 것은 아니다.Hereinafter, the specific method of the present invention will be described step by step with reference to Examples, but the scope of the present invention is not limited only to these Examples.

실시예 1 : 유화파라핀 24%를 포함하는 석회보르도액 약효연장용 조성물(I) 제조Example 1 Preparation of Lime Bordeaux Liquid Drug-Extending Composition (I) Containing Emulsion Paraffin 24%

가열장치 및 보온장치가 부착된 용해조에 고체상의 유화파라핀 24㎏을 넣고 95℃로 30분동안 서서히 가열 용해한 후 상기 용해된 파라핀 용액에 천연물질로 된 스테아린산(유화제) 4㎏과 베타사이드 엘엑스(Betacide LX) 0.1㎏을 넣고 10분동안 교반 용해시켰다. 상기의 완전히 용해된 용액에 전체 사용하는 물의 10%에 해당하는 양만큼의 95℃의 가열된 물을 소량씩 가하면서 10분동안 교반하였다. 이 때 용액의 온도가 85℃이하가 되면 입자가 형성되므로 주의하여야 했다. 상기와 같이 용액을 90℃ 이상으로 계속 유지하면서 교반하게 되면 점도가 강해지면서 탁한 백색의 물질이 형성되었다. 이 때 전체 사용하는 물의 10%에 해당하는 양만큼의 95℃의 물을 다시 서서히 첨가하면서 교반을 10분동안 계속하였다. 상 전환이 완료되면 95℃의 가열된 나머지 80%의 물을 소량씩 가하면서 교반하였다. 물 투입이 끝난후 20분간 계속 교반하면서 숙성시켰다. 상기 상전환은 일차적으로 색의 변화를 보고 알 수 있고 이차적으로는 점성의 변화를 보고 알 수 있었다. 상전환이 되기 전에서는 혼합용액이 반투명상태로 있다가 상전환이 되면서 점성이 증가되고 갑자기 유백색으로 변화되었다. 상전환이 완료된 이후로는 물을 첨가해도 형태변화가 전혀 없었다.24 kg of solid emulsified paraffin was added to a dissolution tank equipped with a heating device and a thermostat, and slowly dissolved by heating at 95 ° C. for 30 minutes. Then, 4 kg of stearic acid (emulsifier) made of natural substances and betaside LX were dissolved in the dissolved paraffin solution. 0.1 kg of Betacide LX) was added thereto and stirred for 10 minutes. The fully dissolved solution was stirred for 10 minutes while adding a small amount of heated water at 95 ° C. in an amount corresponding to 10% of the total water used. At this time, when the temperature of the solution is less than 85 ℃ was formed because the particles were careful. As described above, the solution was stirred while maintaining the solution at 90 ° C. or higher. As a result, a viscous white material was formed. At this time, stirring was continued for 10 minutes while slowly adding water at 95 ° C. in an amount corresponding to 10% of the total water used. Upon completion of phase inversion, the remaining 80% of heated water at 95 ° C. was added in small portions. After the addition of water, the aging was continued while stirring for 20 minutes. The phase inversion can be seen primarily by seeing a change in color and secondly by a change in viscosity. Before the phase inversion, the mixed solution remained translucent, and as the phase shifted, the viscosity increased and suddenly turned milky. After the phase change was completed, there was no morphological change even if water was added.

실시예 2 : 유화파라핀 36%를 포함하는 석회보르도액 약효연장용 조성물(II) 제조Example 2 Preparation of Lime Bordeaux Liquid Efficacy Extension (II) Containing 36% Emulsified Paraffin

가열장치 및 보온장치가 부착된 용해조에 고체상의 유화파라핀 36㎏을 넣고 95℃로 30분동안 서서히 가열 용해한 후 상기 용해된 파라핀 용액에 천연물질로 된 스테아린산(유화제) 6㎏과 베타사이드 엘엑스(Betacide LX) 0.1㎏을 넣고 10분동안 교반 용해시켰다. 상기의 완전히 용해된 용액에 전체 사용하는 물의 10%에 해당하는 양만큼의 95℃의 가열된 물을 소량씩 가하면서 10분동안 교반하였다. 이 때 용액의 온도가 85℃이하가 되면 입자가 형성되므로 주의하여야 했다. 상기와 같이 용액을 90℃ 이상으로 계속 유지하면서 교반하게되면 점도가 강해지면서 탁한 백색의 물질이 형성되었다. 이 때 전체 사용하는 물의 10%에 해당하는 양만큼의 95℃의 물을 다시 서서히 첨가하면서 교반을 10분 동안 계속하였다. 상 전환이 완료되면 95℃의 가열된 나머지 80%의 물을 소량씩 가하면서 교반하였다. 물 투입이 끝난후 약 20분간 계속 교반하면서 숙성시켰다.36 kg of solid emulsion paraffin was added to a dissolution tank equipped with a heating device and a heating device, and slowly dissolved by heating at 95 ° C. for 30 minutes. Then, 6 kg of stearic acid (emulsifier) and betaside LX (natural emulsion) were dissolved in the dissolved paraffin solution. 0.1 kg of Betacide LX) was added thereto and stirred for 10 minutes. The fully dissolved solution was stirred for 10 minutes while adding a small amount of heated water at 95 ° C. in an amount corresponding to 10% of the total water used. At this time, when the temperature of the solution is less than 85 ℃ was formed because the particles were careful. As described above, when the solution was kept at 90 ° C. or higher while stirring, the viscosity became strong and a cloudy white material was formed. At this time, stirring was continued for 10 minutes while slowly adding water at 95 ° C. in an amount corresponding to 10% of the total water used. Upon completion of phase inversion, the remaining 80% of heated water at 95 ° C. was added in small portions. After the addition of water, the aging was continued while stirring for about 20 minutes.

상기 실시예 1 및 2에서 제조한 석회보르도액 약효연장용 조성물의 조성비를 표 1에 나타내었다.Table 1 shows the composition ratios of the lime bordeaux liquid medicinal extension for the compositions prepared in Examples 1 and 2.

성분ingredient 조성물 I 성분비(%)Composition I component ratio (%) 조성물 II 성분비(%)Composition II Component Ratio (%) 비 고Remarks 유화파라핀Emulsified paraffin 2424 3636 유화제Emulsifier 44 66 Betacide LXBetacide LX 0.10.1 0.10.1 물water 71.971.9 57.957.9 총계sum 100100 100100

상기 실시예 1 및 2에서 제조한 석회보르도액 약효연장용 조성물들은 하기 표 2와 같은 비율로 물에 희석하여 사용하여야 한다. 만일 상기 약효연장용 조성물을 석회보르도액과 함께 혼용할 경우에는 석회보르도액을 먼저 만든 후 상기 석회보르도액에 약효연장용 조성물을 혼합시킨다. 약효연장용 조성물은 먼저 약효연장용 조성물 1ℓ를 물 20ℓ에 희석시킨후 나머지 물을 보충하는 방법으로 사용한다.Lime Bordeaux liquid drug extension compositions prepared in Examples 1 and 2 should be used diluted in water in the ratio as shown in Table 2. If the drug extension composition is mixed with the lime bordeaux solution, the lime bordeaux solution is first prepared, and then the composition for extending the drug effect is added to the lime bordeaux solution. The pharmacotherapeutic composition is first used to dilute 1L of the pharmacotherapeutic composition in 20L of water and then replenish the remaining water.

구분division 조성물 IComposition I 조성물 IIComposition II 비 고Remarks 조성물 투입량Composition input amount 1ℓ1ℓ 1ℓ1ℓ 물 투입량Water input 500ℓ500ℓ 700ℓ700ℓ

실험예 1 : 약효연장용 조성물들의 부착율 조사Experimental Example 1: Investigation of adhesion rate of the composition for drug extension

상기 실시예에서 제조한 약효연장용 조성물 I 및 II의 시간경과에 따른 부착율변화를 조사하였다. 조사 결과를 하기 표3에 나타내었다.The change in adhesion rate with time lapse of the compositions for drug efficacy extension I and II prepared in the above Examples was investigated. The investigation results are shown in Table 3 below.

구분division 경과일수Elapsed days 0일0 days 5일5 days 10일10 days 20일20 days 30일30 days 보르도액단용Bordeaux liquid 100100 9090 7070 2525 00 약효연장용 조성물 IEfficacy Extension I 100100 100100 100100 9595 8585 약효연장용 조성물 IIEfficacy Extension II 100100 100100 9090 9090 8080

상기 표3에서 알 수 있듯이 보르도액만 처리했을 때에는 처리후 10일이 경과되면 급속하게 약효성분이 경감되며 환경인자에 매우 민감하게 반응하였다. 그러나 보르도액에 약효연장용 조성물 I 및 II를 혼용하였을 때에는 환경인자 특히 강우에 내성이 강하였고 약효연장용 조성물 I를 사용하였을 때에는 약효성분이 약 30일간 지속되었다.As can be seen in Table 3, when only Bordeaux liquid was treated, the active ingredient was rapidly reduced after 10 days of treatment, and was very sensitive to environmental factors. However, when Bordeaux liquid was mixed with the composition for long-acting effects I and II, it was resistant to environmental factors, especially rainfall, and the active ingredient lasted for about 30 days.

이상, 상기 실시예 및 실험예를 통하여 설명한 바와 같이 본 발명의 석회보르도액 약효연장용 조성물은 석회보르도액의 부착성을 증가시켜 약효지속기간을 증가시키고 석회의 유실을 방지함으로써 약해가 없는 뛰어난 효과가 있어 식물체의 표면을 병해충 및 바람과 동결피해로부터 보호해주는 농자재로서의 산업상 매우 유용한 발명인 것이다.As described above, the composition for extending the lime bordea solution of the present invention as described through Examples and Experimental Examples has an excellent effect without weakening by increasing the adhesion of the lime bordea solution to increase the drug duration and prevent the loss of lime. It is an industrially useful invention as an agricultural material that protects the surface of plants from pests, wind and freezing damage.

Claims (2)

고상의 유화파라핀 24 중량%, 스테아린산 4 중량%, 물 71.9 중량% 및 방부제 0.1 중량%로 이루어짐을 특징으로 하는 석회보르도액의 약효연장용 조성물.A composition for extending the efficacy of lime bordeaux solution, characterized in that it consists of 24% by weight of the emulsified paraffin solid, 4% by weight stearic acid, 71.9% by weight water and 0.1% by weight preservative. 고상의 유화파라핀 36 중량%, 스테아린산 6 중량%, 물 57.9 중량% 및 방부제 0.1 중량%로 이루어짐을 특징으로 하는 석회보르도액의 약효연장용 조성물.A composition for extending the medicinal effect of lime Bordeaux liquid, comprising 36% by weight of emulsified paraffin in solid phase, 6% by weight of stearic acid, 57.9% by weight of water, and 0.1% by weight of preservative.
KR10-2001-0086124A 2001-12-27 2001-12-27 A composition for retaining bordeaux mixture KR100463676B1 (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5543023A (en) * 1978-09-22 1980-03-26 Kiyoshi Saotome Prevention of damage of bordeaux mixture to citrus fruit
JPS55124709A (en) * 1979-03-19 1980-09-26 Saburo Yui Agricultural germicide
JPH02279611A (en) * 1989-04-20 1990-11-15 Nippon Oil & Fats Co Ltd Preparation of bordeaux mixture
JPH0873307A (en) * 1994-09-07 1996-03-19 Aritsune Kogyo Kk Production of bordeaux mixture and device therefor
JP2000026223A (en) * 1998-07-09 2000-01-25 Inoue Sekkai Kogyo Kk Bordeaux mixture and agricultural germicide
KR20010100073A (en) * 2001-09-05 2001-11-14 양두석 Composite fertilizer comprising Bordeaux mixture, boron and molybdenum and manufacturing method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5543023A (en) * 1978-09-22 1980-03-26 Kiyoshi Saotome Prevention of damage of bordeaux mixture to citrus fruit
JPS55124709A (en) * 1979-03-19 1980-09-26 Saburo Yui Agricultural germicide
JPH02279611A (en) * 1989-04-20 1990-11-15 Nippon Oil & Fats Co Ltd Preparation of bordeaux mixture
JPH0873307A (en) * 1994-09-07 1996-03-19 Aritsune Kogyo Kk Production of bordeaux mixture and device therefor
JP2000026223A (en) * 1998-07-09 2000-01-25 Inoue Sekkai Kogyo Kk Bordeaux mixture and agricultural germicide
KR20010100073A (en) * 2001-09-05 2001-11-14 양두석 Composite fertilizer comprising Bordeaux mixture, boron and molybdenum and manufacturing method thereof

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