KR100457722B1 - Flooring material with germanium-containing minerals - Google Patents
Flooring material with germanium-containing minerals Download PDFInfo
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- KR100457722B1 KR100457722B1 KR10-1998-0021573A KR19980021573A KR100457722B1 KR 100457722 B1 KR100457722 B1 KR 100457722B1 KR 19980021573 A KR19980021573 A KR 19980021573A KR 100457722 B1 KR100457722 B1 KR 100457722B1
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- germanium
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- 238000009408 flooring Methods 0.000 title claims abstract description 37
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 title claims abstract description 29
- 229910052732 germanium Inorganic materials 0.000 title claims abstract description 28
- 229910052500 inorganic mineral Inorganic materials 0.000 title claims abstract description 23
- 239000011707 mineral Substances 0.000 title claims abstract description 23
- 239000000463 material Substances 0.000 title claims description 19
- 239000002245 particle Substances 0.000 claims description 2
- 231100000419 toxicity Toxicity 0.000 abstract description 6
- 230000001988 toxicity Effects 0.000 abstract description 6
- 239000000126 substance Substances 0.000 abstract description 5
- 229910052760 oxygen Inorganic materials 0.000 abstract description 4
- 206010019233 Headaches Diseases 0.000 abstract description 3
- 208000013738 Sleep Initiation and Maintenance disease Diseases 0.000 abstract description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 3
- 239000004568 cement Substances 0.000 abstract description 3
- 208000002173 dizziness Diseases 0.000 abstract description 3
- 238000001035 drying Methods 0.000 abstract description 3
- 230000003203 everyday effect Effects 0.000 abstract description 3
- 206010016256 fatigue Diseases 0.000 abstract description 3
- 231100000869 headache Toxicity 0.000 abstract description 3
- 206010022437 insomnia Diseases 0.000 abstract description 3
- 239000001301 oxygen Substances 0.000 abstract description 3
- 208000024891 symptom Diseases 0.000 abstract description 3
- 239000003053 toxin Substances 0.000 abstract description 3
- 231100000765 toxin Toxicity 0.000 abstract description 3
- 230000000845 anti-microbial effect Effects 0.000 abstract description 2
- 230000003472 neutralizing effect Effects 0.000 abstract 1
- 235000019645 odor Nutrition 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 60
- 239000008279 sol Substances 0.000 description 10
- 238000000034 method Methods 0.000 description 7
- 238000005187 foaming Methods 0.000 description 6
- 239000004745 nonwoven fabric Substances 0.000 description 6
- 239000004014 plasticizer Substances 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000003381 stabilizer Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 238000007639 printing Methods 0.000 description 4
- 238000003672 processing method Methods 0.000 description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 3
- 239000012790 adhesive layer Substances 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 239000003365 glass fiber Substances 0.000 description 3
- 238000007646 gravure printing Methods 0.000 description 3
- 239000001023 inorganic pigment Substances 0.000 description 3
- 238000010030 laminating Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000012860 organic pigment Substances 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 239000011265 semifinished product Substances 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- 239000004604 Blowing Agent Substances 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 230000035882 stress Effects 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 108700012359 toxins Proteins 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 206010063493 Premature ageing Diseases 0.000 description 1
- 208000032038 Premature aging Diseases 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000002981 blocking agent Substances 0.000 description 1
- 230000017531 blood circulation Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 210000004698 lymphocyte Anatomy 0.000 description 1
- 239000008204 material by function Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000010022 rotary screen printing Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/10—Metal compounds
- C08K3/11—Compounds containing metals of Groups 4 to 10 or of Groups 14 to 16 of the Periodic Table
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/022—Non-woven fabric
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
- B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/02—Composition of the impregnated, bonded or embedded layer
- B32B2260/021—Fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/04—Impregnation, embedding, or binder material
- B32B2260/046—Synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2471/00—Floor coverings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/005—Additives being defined by their particle size in general
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Floor Finish (AREA)
- Laminated Bodies (AREA)
Abstract
본 발명은 다층구조로 이루어진 바닥재의 적어도 한층에 게르마늄(Ge) 함유 광물질을 적용하므로써, 시멘트의 잔여독성을 좀더 중화하거나 순화시키며, 화학 바닥재의 잔여독성을 감소시키고 열효율을 높여 주며, 주거공간내의 습도를 조절하여 건조를 예방하고, 항균성이 있어서 곰팡이 발생을 예방하고, 주거공간 주변의 냄새를 현격히 제거하여 주며, 주거공간내 산소의 산화층 독소를 중화하거나 순화시켜 생명체로의 흡수가 용이하도록 조절하여 주고, 또한 마이크로파 등 많은 전위(氣)가 유발되어 주거공간내에 전위를 풍부하게 조절하여 일상생활에서 느껴왔던 스트레스, 피로감, 두통, 현기증, 불면증 등의 증상을 완화시키는 효과가 있는 바닥재에 관한 것이다.The present invention by applying germanium (Ge) -containing minerals to at least one layer of the flooring having a multi-layer structure, to neutralize or purify the residual toxicity of the cement more, to reduce the residual toxicity of the chemical flooring and increase the thermal efficiency, humidity in the living space To prevent drying, to prevent mold due to antimicrobial properties, to significantly remove odors around the living space, and to make it easy to absorb into life by neutralizing or purifying the oxidized layer toxin of oxygen in the living space. In addition, a lot of potentials such as microwaves are induced to abundantly regulate the potential in the living space to relieve the symptoms such as stress, fatigue, headache, dizziness, insomnia that have been felt in everyday life.
Description
본 발명은 바닥재에 게르마늄(Ge) 함유 광물질을 적용하여 시멘트의 잔여독성을 좀더 중화하거나 순화시켜서 화학 바닥재의 잔여독성을 감소시키고 열효율을 높여 주며, 주거공간내의 습도를 조절하여 건조를 예방하고, 항균성이 있어서 곰팡이 발생을 예방하고, 주거공간 주변의 냄새를 현격히 제거하여 주며, 주거공간내 산소의 산화층 독소를 중화하거나 순화시켜 생명체로의 흡수가 용이하도록 조절하여 주고, 또한 마이크로파 등 많은 전위(氣)가 유발되어 주거공간내에 전위를 풍부하게 조절하여 일상생활에서 느껴왔던 스트레스, 피로감, 두통, 현기증, 불면증 등의 증상을 완화시키는 효과가 있는 바닥재에 관한 것이다.The present invention by applying germanium (Ge) -containing minerals to the flooring material to further neutralize or purify the residual toxicity of the cement to reduce the residual toxicity of the chemical flooring and increase the thermal efficiency, to prevent drying by controlling the humidity in the living space, antibacterial This prevents the occurrence of mold, significantly removes the odor around the living space, neutralizes or purifies the oxidized layer of toxins in the living space, and makes it easy to absorb into living organisms. It is induced to abundantly regulate the dislocation in the living space relates to the flooring which has the effect of alleviating the symptoms such as stress, fatigue, headache, dizziness, insomnia that have been felt in everyday life.
현대인은 일반적으로 매우 연약한 반건강체로 살아갈 수 밖에 없는게 현실이고, 병에 걸리면 합병증으로 악화되기가 쉽고 피부의 조기노화현상이 심화되고 있는 이러한 때에 현대 의학은 많은 부분에 있어서 한계를 나타내고 있다.In general, modern people have to live as a very weak semi-healthy body, and in case of illness, complications are easily exacerbated and premature aging of the skin is intensifying.
따라서 이를 위해서 근본적인 '대체 의학 라인' 으로 '인체 외부조직' 을 통해 신체내부를 도와줌으로써 연약해진 현대인 체질에 과하지도 부족하지도 않으면서 인체에 도움이 될 수 있는 천연복합 기능성인 물질들을 여러 제품에 이용하는 경향이 증대되고 있다. 게르마늄도 그러한 천연복합 기능성 물질의 하나로서, 지금까지 게르마늄을 함유한 광물질을 바닥재에 적용한 예는 없다.Therefore, to achieve this, the basic 'alternative medicine line' is used to help the body through 'external human tissue', which uses natural complex functional substances in various products that can be helpful to the human body without being excessive or lacking in the fragile modern body. The trend is increasing. Germanium is one of such natural complex functional materials, and until now, there have been no examples of applying germanium-containing minerals to flooring materials.
따라서 본 발명의 목적은 다양한 효능을 지닌 게르마늄을 함유한 광물질을 바닥재에 적용함으로써 인체에 유익한 여러 효과를 갖는 바닥재를 제공하는 것이다.Accordingly, an object of the present invention is to provide a flooring material having various effects beneficial to the human body by applying a germanium-containing mineral having various effects to the flooring material.
본 발명에 따른 바닥재는 다층구조에 있어서 적어도 하나의 층에 게르마늄 함유 광물질이 첨가된 것을 특징으로 한다.Flooring according to the invention is characterized in that the germanium-containing mineral is added to at least one layer in a multi-layer structure.
본 발명에서 사용되는 광물질 중에 있는 게르마늄은 원자번호가 32번인 원자량 72.59의 원소로서 격자구조로 되려는 특성이 있으며, 이 게르마늄의 전자적 특성은 비어있는 포지틴 호울(positine hole)을 형성하고 32개 전자중 4개는 외부를 도는데 외부 4개의 전자는 오염된 공기나 이물질 등 다른 전자를 유도하여 자기전위로 바뀌어(중화) 다시 방출되는데, 이러한 기능에 의해 인체내부에서 중금속, 수은 등과 결합하여 배설되므로써 이들을 제거할 수 있다.Germanium in the mineral used in the present invention has an element number of atomic number 72.59 having an atomic number of 32.59 and has a property to become a lattice structure, and the electronic property of germanium forms an empty positine hole and among 32 electrons Four of them circulate outside, and the other four electrons induce other electrons such as polluted air or foreign substances, which are converted into magnetic potentials (neutralized) and released again. These functions remove them by being combined with heavy metals and mercury in the human body. Can be.
또한 게르마늄은 산소대체작용, 면역기관의 임파구 작용, 활성화 유도 작용을 지니고 있고, 전위(氣)의 불균형을 정상균형으로 조절하여 주며, 혈행을 용이하게 하여 점차적으로 체질개선을 유도하게 하는 등의 역할을 한다.In addition, germanium has the role of oxygen replacement, lymphocyte function of immune organs, activation induction, regulates dislocation imbalance to normal balance, facilitates blood circulation, and gradually leads to constitutional improvement. Do it.
그러므로 천연 게르마늄 함유 광물질을 혼합하여 제조한 본 발명의 바닥재는 게르마늄의 성질에 기인한 '다원소다공성' 의 전자적 특성과 '항장성-전위성' 의 '천연 복합 기능성' 을 지니고, 주거공간 환경을 생명체에 적합하도록 조절하기 위하여 인체 외부조직을 통해 인체 '내부' 를 도와주는 '음' '양' 의 자연요법 역할을 하며, 인체의 본래대로 돌아가려는 작용기능이 무리하지 않고 원활하게 이루어지게 하는 여건을 조성할 수 있다.Therefore, the flooring material of the present invention prepared by mixing natural germanium-containing minerals has the electronic properties of 'poly-element porosity' and 'natural complex functionality' of 'hangability-potential' due to the properties of germanium, It acts as a natural remedy of 'Yin' and 'Yang' to help the human body 'inside' through external tissues to adjust to be suitable for life. Can be formulated.
본 발명의 바닥재에 적용되는 게르마늄 함유 광물질은 원적외선 방사율이 저온인 40℃에서 0.46% 이상, 100℃에서 0.87% 이상이 되고, 입자의 크기는 바닥재를 구성하는 성분과 혼용성이 잘 나타나도록 적용 가능한 크기인 100~325메쉬(mesh)이며, 순수 게르마늄이 50~400ppm 범위에서 첨가된 것을 사용한다. 이러한 게르마늄 함유 광물질은 SiO2, Al2O3, Fe2O3, CaO, MgO, Na 2O, K2O, TiO2 등의 성분으로 구성되어 있으며, (주)한국 프리벤션의 N-GEO-3210 등을 사용할 수 있다. 바닥재 각층에 적용시 5~20중량부를 첨가하는데 5중량부 미만을 첨가할 경우에는 게르마늄 발생효과가 미비하고, 20중량부 이상 적용시에는 다른 성분과의 혼용성이 잘 나타나지 않는다.The germanium-containing minerals applied to the flooring material of the present invention are at least 0.46% at 40 ° C and 0.87% at 100 ° C having a far-infrared emissivity, and the size of the particles is applicable to show compatibility with the components constituting the flooring. Size 100 ~ 325 mesh (mesh), pure germanium is used that is added in the range of 50 ~ 400ppm. Such germanium-containing minerals are composed of SiO 2 , Al 2 O 3 , Fe 2 O 3 , CaO, MgO, Na 2 O, K 2 O, TiO 2, etc. -3210 can be used. When it is applied to each layer of flooring, 5 to 20 parts by weight is added, but less than 5 parts by weight of germanium generating effect is insufficient, when applied to more than 20 parts by weight is not well mixed with other components.
본 발명에 따른 바닥재는 일반적인 바닥재의 제조공정과 동일한 공정으로 생산할 수 있는데, 이를 일반적인 가정용 바닥재를 일예로 본 발명에 첨부된 도면을 참조하여 상세하게 설명하면 다음과 같다.Flooring according to the present invention can be produced in the same process as the manufacturing process of the general flooring, it will be described in detail with reference to the drawings attached to the present invention as an example of a general household flooring as follows.
본 발명에 따른 바닥재의 일예는 도 1에 도시된 바와 같이 기재층(1), 인쇄 무늬가 부여된 발포 또는 비발포 상부층(2), 투명스킨층(3), 하부발포층(4) 및 UV 층(5)으로 이루어지며, 상기 각층 제조시 또는 인쇄무늬 부여시에 원료에 게르마늄 함유 광물질을 첨가할 수 있다.One example of the flooring according to the invention is a base layer (1), a foamed or non-foamed upper layer (2), a transparent skin layer (3), a lower foaming layer (4) and UV as shown in FIG. It is composed of a layer (5), it is possible to add a germanium-containing mineral to the raw material during the manufacturing of each layer or applying a printed pattern.
이하에서는 도 1의 바닥재에 있어, 예를 들어 인쇄무늬 부분과 하부발포층에 게르마늄 함유 광물질이 첨가된 바닥재의 제조공정에 대해 설명한다.Hereinafter, in the flooring material of FIG. 1, the manufacturing process of the flooring material to which germanium containing mineral material was added to the printed pattern part and the lower foaming layer is demonstrated, for example.
상기 기재층(1)은 내열성 및 치수 안정성이 우수한 부직포와 유리섬유 매트(glass non woven fiber;GF)에 PVC 졸을 함침시켜 제조한다.The base layer 1 is prepared by impregnating a PVC sol in a nonwoven fabric and a glass non woven fiber (GF) having excellent heat resistance and dimensional stability.
상기 기재층(1) 위에 발포 또는 비발포 상부층(2)을 적층하는데, 적층방법은 나이프코타를 이용하여 코팅한 후 140~170℃의 겔링드럼이나 오븐을 이용하여 겔링시켜 반제품을 만든다.Laminating the foamed or non-foamed upper layer (2) on the base layer (1), the lamination method is coated using a knife coat and then gelled using a gelling drum or oven at 140 ~ 170 ℃ to make a semi-finished product.
상기 상부층(2)은 PVC 페이스트 수지 100중량부, 가소제 40~70중량부, 안정제 1~3중량부, 선택적으로 발포제 1~5중량부, 충진제 10~50중량부, 아연계 촉진제 1~5중량부를 정량투입하여 고속 임펠러가 있는 믹서기에서 10~40분간 혼합하며 내부 온도를 40℃ 이하가 되게 유지하는 졸(sol)가공방법을 이용하여 얻을 수 있다.The upper layer 2 is 100 parts by weight of PVC paste resin, 40 to 70 parts by weight of plasticizer, 1 to 3 parts by weight of stabilizer, optionally 1 to 5 parts by weight of blowing agent, 10 to 50 parts by weight of filler, 1 to 5 parts by weight of zinc-based accelerator It can be obtained by using a sol processing method in which the part is quantitatively mixed and mixed in a mixer with a high speed impeller for 10 to 40 minutes and the internal temperature is kept below 40 ° C.
이와 같이 기재층(1)에 상부층(2)을 적층하여 얻어진 반제품 위에 다양한 무늬와 색상의 인쇄를 하게 되는데, 인쇄방법은 그라비아 인쇄 방법과 로타리 스크린을 이용한 졸 코팅(sol coating) 방법을 적용할 수 있다. 그라비아 인쇄법은 잉크를 사용하는데 유성잉크와 수성 잉크 둘다 적용이 가능하며, 유성잉크는 PVC계 공중합체 10~40중량부, 유기용제 30~70중량부, 미분산된 유기 또는 무기계 안료 1~20중량부를 투입하여 고속믹서로 혼합하여 적용할 수 있으며, 수성 잉크는 우레탄 아크릴계 수지 20~50중량부, 수분 10~30중량부, 유기 또는 무기계 안료 1~20중량부를 투입하여 적용하게 된다. 그 외의 인쇄방법으로는 로타리 스크린 인쇄기를 이용하여 PVC 졸 100중량부에 유기 또는 무기계 안료 1~10중량부, 게르마늄 함유 광물질 10~20중량부를 고속믹서로 혼합하여 적용할 수도 있다.In this way, various patterns and colors are printed on the semi-finished product obtained by laminating the upper layer 2 on the base layer 1, and the printing method may be a gravure printing method and a sol coating method using a rotary screen. have. The gravure printing method uses ink, and both oil-based ink and water-based ink can be applied, and oil-based ink has 10 to 40 parts by weight of PVC copolymer, 30 to 70 parts by weight of organic solvent, and 1 to 20 undispersed organic or inorganic pigments. It can be applied by mixing in a high speed mixer by adding a weight part, the aqueous ink is applied by adding 20 to 50 parts by weight of urethane acrylic resin, 10 to 30 parts by weight of water, 1 to 20 parts by weight of organic or inorganic pigments. Other printing methods may be applied by mixing a high speed mixer with 1 to 10 parts by weight of organic or inorganic pigments and 10 to 20 parts by weight of germanium-containing minerals in 100 parts by weight of a PVC sol using a rotary screen printing machine.
상기 과정에 의해 인쇄가 완료되면 그 인쇄된 상면에 투명스킨층(3)을 적층하게 되는데, 투명스킨층은 PVC페이스트 수지 100중량부, 가소제 40~70중량부, 안정제 1~3중량부, 자외선 차단제 0.1~1중량부를 고속 임펠러가 있는 믹서기에서 10~40분간 혼합하며 내부온도를 40℃ 이하로 유지하는 졸 가공법을 사용한다.When the printing is completed by the above process, the transparent skin layer 3 is laminated on the printed upper surface. The transparent skin layer is 100 parts by weight of PVC paste resin, 40 to 70 parts by weight of plasticizer, 1 to 3 parts by weight of stabilizer, and ultraviolet ray. 0.1-1 parts by weight of the blocking agent is mixed in a mixer with a high speed impeller for 10-40 minutes and a sol processing method is used to keep the internal temperature below 40 ° C.
투명스킨층(3)이 적층된 후에 기재층 이면에 하부발포층(4)을 적층하는데, 이 하부발포층은 PVC 페이스트 수지 100중량부, 가소제 40~70중량부, 안정제 1~3중량부, 발포제 1~5중량부, 충진제 10~60중량부, 아연계 촉진제 1~3중량부와 천연 게르마늄 함유 광물질 5~20중량부를 정량투입하여 고속 임펠러가 있는 믹서기에서 10~40분간 혼합하여 나이프코타를 이용하여 코팅한 후 오븐과 겔링드럼을 이용하여 겔링하여 형성한다.After the transparent skin layer 3 is laminated, the lower foaming layer 4 is laminated on the back side of the base layer, which is 100 parts by weight of PVC paste resin, 40 to 70 parts by weight of plasticizer, 1 to 3 parts by weight of stabilizer, 1 to 5 parts by weight of blowing agent, 10 to 60 parts by weight of filler, 1 to 3 parts by weight of zinc-based accelerator and 5 to 20 parts by weight of natural germanium-containing minerals are metered in, and mixed in a mixer with a high speed impeller for 10 to 40 minutes After coating by using a gel formed by using an oven and a gelling drum.
그런 다음 내마모성과 내오염성이 우수한 UV 도료를 표면에 도포한 후 경화 겔링시켜 표면처리하여 최종제품을 얻는다.Then, a UV paint having excellent abrasion resistance and fouling resistance is applied to the surface, and then cured and gelled to obtain a final product.
본 발명의 바닥재는 도 2와 같이 도 1의 바닥재의 하부발포층(4) 밑에 이지층(6)을 적층할 수도 있으며, 이때 이지층(6)은 PVC페이스트 수지 100중량부, 가소제 40~70중량부, 안정제 1~5중량부, 충진제 10~50중량부를 투입하여 고속 임펠러가 있는 믹서기 내에서 10~40분간 혼합하는 졸 가공방법이나 카렌다에서 압연가공하는 방법으로 적층가능하다.In the flooring of the present invention, as shown in FIG. 2, the easy layer 6 may be laminated under the lower foaming layer 4 of the flooring material of FIG. 1, wherein the easy layer 6 is 100 parts by weight of PVC paste resin and plasticizer 40 to 70. It can be laminated by a sol processing method for mixing 10 to 40 minutes in a blender with a high speed impeller by adding 1 part by weight, 1 to 5 parts by weight of a stabilizer and 10 to 50 parts by weight of a filler, or rolling in a calendar.
또한 본 발명은 도 3과 같이 부직포와 글라스파이버가 합판된 기재층(1')과 상부층(2), 투명스킨층(3) 및 UV층(5)으로 이루어질 수 있다.In addition, the present invention may be made of a base layer (1 ') and the upper layer (2), the transparent skin layer (3) and the UV layer (5) laminated nonwoven fabric and glass fiber as shown in FIG.
도 3의 바닥재는 부직포 형태로 이루어진 유리섬유 매트(C)를 페이스트졸(paste sol)로 함침후 겔링드럼이나 오븐으로 반겔링(semi-gelling)하고 나서, 그위에 상부층(2)을 형성한다. 이때 상부층(2)은 PVC페이스트 수지 100중량부, 가소제 40~70중량부, 안정제 1~3중량부, 충진제 10~50중량부, 아연계 촉진제 1~5중량부를 정량 투입하여 고속 임펠러가 있는 믹서기 내에서 10~40분간 혼합하여 졸 가공 방법을 이용하여 형성한다. 이렇게 제조된 반제품의 표면에 그라비아 인쇄로 무늬면을 형성한 후, 접착졸을 이용하여 바닥재의 최하단에 사용되는 폴리에스테르 부직포와 150~180℃ 온도조건의 겔링드럼으로 합판하고 나서, 상부층(2) 위에 나이프 코우터(knife coater)에 의해서 투명스킨층(3)을 코팅하고 오븐에서 200~230℃의 온도조건으로 겔링시킨 다음, 내마모성과 내오염성이 우수한 UV도료로 코팅후 경화시켜 표면처리함으로써 완제품을 제작한다.The flooring of FIG. 3 is impregnated with a non-woven fiberglass mat (C) with a paste sol, and then semi-gelling with a gelling drum or an oven to form an upper layer 2 thereon. At this time, the upper layer 2 is 100 parts by weight of PVC paste resin, 40 to 70 parts by weight of plasticizer, 1 to 3 parts by weight of stabilizer, 10 to 50 parts by weight of filler, 1 to 5 parts by weight of zinc-based accelerator, and a mixer having a high speed impeller It mixes in 10 to 40 minutes and forms using a sol processing method. After forming a patterned surface by gravure printing on the surface of the semi-finished product thus prepared, and then laminating it with a polyester nonwoven fabric used at the bottom of the floor using an adhesive sol and a gelling drum at a temperature of 150 to 180 ° C, the upper layer (2) Finished product by coating transparent skin layer (3) by knife coater on top and gelling in oven at 200 ~ 230 ℃ temperature, then coating with UV paint with excellent abrasion resistance and stain resistance To produce.
도 3의 바닥재에서 게르마늄 함유 광물질은 예를 들어 접착층, 상부층 및 투명스킨층 중의 한층 이상에 첨가할 수 있고, 도 1과 도 2의 설명에서와 같이 고속 임펠러가 있는 믹서기에서 원료성분들을 혼합할 때 천연 게르마늄 함유 광물질 5~20중량부를 함께 혼합하여 적용한다. 단, 투명스킨층에 혼합할 때에는 투명성에 영향을 주지 않을 정도인 5~12중량부를 적용하는 것이 바람직하다.The germanium-containing minerals in the flooring of FIG. 3 can be added to at least one of the adhesive layer, the top layer and the transparent skin layer, for example, when mixing the raw ingredients in a blender with a high speed impeller as described in FIGS. 1 and 2. 5 to 20 parts by weight of natural germanium-containing minerals are mixed and applied. However, when mixing in a transparent skin layer, it is preferable to apply 5-12 weight part which does not affect transparency.
또한 본 발명의 바닥재는 도 4에서와 같은 구조일 수도 있다.In addition, the flooring of the present invention may have a structure as shown in FIG.
도 4의 바닥재는 부직포 형태로 이루어진 유리섬유 매트(C)와 부직포(A)를 접착졸로 접착합판하여 기재층(1')을 형성한 후에 다양한 형상 및 색상을 갖는 칩을 일정하게 산포할 수 있는 설비를 이용하여 기재층(1')의 상면에 배열한 후 200~230℃의 열을 줄 수 있는 오븐을 통과시켜 칩을 겔링시키고, 투명스킨층(3)을 그 상면에 코팅하여 오븐으로 겔링한 후, 내마모성과 내오염성이 우수한 UV도료로 표면처리하여 제작된다.The flooring of Figure 4 is a non-woven fabric of a glass fiber mat (C) and a non-woven fabric (A) by bonding an adhesive sol to form a base layer (1 ') can be uniformly scattered chips having various shapes and colors After arranging on the upper surface of the base layer 1 'by using a facility, the chip is gelled by passing through an oven capable of heating at 200 to 230 ° C, and the transparent skin layer 3 is coated on the upper surface and gelled by an oven. After that, it is manufactured by surface treatment with UV paint having excellent abrasion resistance and stain resistance.
도 4의 바닥재에서 게르마늄 함유 광물질은 접착층, 상부층 중의 한층 이상에 5~20중량부를 첨가할 수 있고, 또한 칩층 또는 투명스킨층에는 5~12중량부를 첨가할 수 있다.In the flooring material of FIG. 4, the germanium-containing mineral material may be added in an amount of 5 to 20 parts by weight to at least one of the adhesive layer and the upper layer, and 5 to 12 parts by weight to the chip layer or the transparent skin layer.
본 발명의 바닥재는 다층구조로 된 바닥재의 적어도 한층에 게르마늄(Ge) 함유 광물질을 적용하므로써 시멘트의 잔여독성을 중화하거나 순화시키고, 화학 바닥재의 잔여독성을 감소시키고 열효율을 높여 주며, 주거공간내의 습도를 조절하여 건조를 예방하고, 항균성이 있어서 곰팡이 발생을 예방하고, 주거공간 주변의 냄새를 현격히 제거하여 주며, 주거공간내의 산소의 산화층 독소를 중화하거나 순화시켜 생명체에 흡수가 용이하도록 조절하여 주고, 또한 마이크로파 등 많은 전위(氣)가 유발되어 주거공간내에 전위를 풍부하게 조절하여 일상생활에서 느껴왔던 스트레스, 피로감, 두통, 현기증, 불면증 등의 증상이 완화되는 효과를 갖는다.The flooring of the present invention neutralizes or purifies the residual toxicity of cement by applying germanium (Ge) -containing minerals to at least one layer of the flooring having a multi-layered structure, reduces the residual toxicity of the chemical flooring, increases thermal efficiency, and humidity in a residential space. To prevent drying, to prevent mold due to antimicrobial properties, to significantly remove the odor around the living space, to neutralize or purify the oxidized layer toxins of oxygen in the living space, and to make it easy to absorb into life, In addition, many potentials such as microwaves are induced to abundantly regulate the potential in the living space, thereby relieving symptoms such as stress, fatigue, headache, dizziness, and insomnia that have been felt in everyday life.
도 1 내지 도 4는 본 발명이 적용되는 예시적인 바닥재들의 단면도를 나타내는 것으로서,1 to 4 show cross-sectional views of exemplary floorings to which the present invention is applied.
도 1은 게르마늄 함유 광물질이 첨가된 상부층과 하부발포층을 갖는 바닥재의 단면도이고,1 is a cross-sectional view of a flooring material having an upper layer and a lower foaming layer to which germanium containing minerals are added,
도 2는 게르마늄 함유 광물질이 첨가된 상부층과 하부발포층을 갖고, 부가적으로 이지층을 갖는 바닥재의 단면도이며,2 is a cross-sectional view of a flooring material having an upper layer and a lower foaming layer to which germanium containing minerals are added, and additionally having an easy layer;
도 3은 게르마늄 함유 광물질이 첨가된 기재층과 부가적으로 인쇄층을 갖는 바닥재의 단면도이고,3 is a cross-sectional view of a flooring material having a substrate layer to which germanium containing minerals are added and additionally a printing layer,
도 4는 게르마늄 함유 광물질이 첨가된 기재층과 부가적으로 칩층을 갖는 바닥재의 단면도이다.4 is a cross-sectional view of a flooring material having a substrate layer to which germanium containing minerals are added and an additional chip layer.
****도면의 주요부분에 대한 부호의 설명******** Description of the symbols for the main parts of the drawings ****
1, 1 '. 기재층 2. 상부층 3. 투명스킨층1, 1 '. Base layer 2. Upper layer 3. Transparent skin layer
4. 하부발포층 5. UV층 6. 이지층4. Lower foam layer 5. UV layer 6. Easy layer
7. 인쇄무늬 8. 칩층 A. 부직포7. Printed pattern 8. Chip layer A. Nonwoven fabric
B. 접착층 C. 유리섬유매트B. Adhesive layer C. Glass fiber mat
Claims (1)
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KR10-1998-0021573A KR100457722B1 (en) | 1998-06-10 | 1998-06-10 | Flooring material with germanium-containing minerals |
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KR10-1998-0021573A KR100457722B1 (en) | 1998-06-10 | 1998-06-10 | Flooring material with germanium-containing minerals |
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KR20000001353A KR20000001353A (en) | 2000-01-15 |
KR100457722B1 true KR100457722B1 (en) | 2005-02-23 |
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KR10-1998-0021573A KR100457722B1 (en) | 1998-06-10 | 1998-06-10 | Flooring material with germanium-containing minerals |
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KR20000072510A (en) * | 2000-09-07 | 2000-12-05 | 성재갑 | Multilayer-Flooring Containing Silver or Gold Flaked Powder and the Method for the Manufacturing thereof |
KR102097842B1 (en) * | 2015-03-04 | 2020-04-06 | (주)엘지하우시스 | Odor reduction type fabric flooring and manufacturing method thereof |
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KR930009280A (en) * | 1991-10-31 | 1993-05-22 | 경상현 | TU Pointer Adjustment Jitter Reduction Circuit in Synchronous Multiple Devices |
KR940005641A (en) * | 1992-06-27 | 1994-03-22 | 벡커, 바인 | Metallocenes containing aryl-substituted indenyl derivatives as ligands, methods for their preparation and their use as catalysts |
KR950023649A (en) * | 1994-01-20 | 1995-08-18 | 박노훈 | Synthetic resin sheet containing far-infrared radiation ceramics and copper sheet attached to the sheet |
KR950025146U (en) * | 1994-02-24 | 1995-09-15 | 박창윤 | Heat-resistant and deodorant wallpaper |
KR960004302U (en) * | 1994-07-18 | 1996-02-14 | Synthetic Resin Sheet | |
KR960003949A (en) * | 1994-07-04 | 1996-02-23 | 성재갑 | Vinyl flooring with antibacterial effect |
KR19990064369A (en) * | 1998-05-12 | 1999-08-05 | 이종학 | Geomagnetic compensation composition and flooring containing the same |
KR19990037561U (en) * | 1998-03-09 | 1999-10-15 | 성재갑 | Germanium-based flooring and wallpaper |
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1998
- 1998-06-10 KR KR10-1998-0021573A patent/KR100457722B1/en not_active IP Right Cessation
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
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KR930009280A (en) * | 1991-10-31 | 1993-05-22 | 경상현 | TU Pointer Adjustment Jitter Reduction Circuit in Synchronous Multiple Devices |
KR940005641A (en) * | 1992-06-27 | 1994-03-22 | 벡커, 바인 | Metallocenes containing aryl-substituted indenyl derivatives as ligands, methods for their preparation and their use as catalysts |
KR950023649A (en) * | 1994-01-20 | 1995-08-18 | 박노훈 | Synthetic resin sheet containing far-infrared radiation ceramics and copper sheet attached to the sheet |
KR950025146U (en) * | 1994-02-24 | 1995-09-15 | 박창윤 | Heat-resistant and deodorant wallpaper |
KR960003949A (en) * | 1994-07-04 | 1996-02-23 | 성재갑 | Vinyl flooring with antibacterial effect |
KR960004302U (en) * | 1994-07-18 | 1996-02-14 | Synthetic Resin Sheet | |
KR19990037561U (en) * | 1998-03-09 | 1999-10-15 | 성재갑 | Germanium-based flooring and wallpaper |
KR19990064369A (en) * | 1998-05-12 | 1999-08-05 | 이종학 | Geomagnetic compensation composition and flooring containing the same |
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