KR100451410B1 - Artificial marble based glass being prepared and cut easily and manufacturing process - Google Patents
Artificial marble based glass being prepared and cut easily and manufacturing process Download PDFInfo
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- KR100451410B1 KR100451410B1 KR10-2001-0067310A KR20010067310A KR100451410B1 KR 100451410 B1 KR100451410 B1 KR 100451410B1 KR 20010067310 A KR20010067310 A KR 20010067310A KR 100451410 B1 KR100451410 B1 KR 100451410B1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10165—Functional features of the laminated safety glass or glazing
- B32B17/10247—Laminated safety glass or glazing containing decorations or patterns for aesthetic reasons
- B32B17/10256—Laminated safety glass or glazing containing decorations or patterns for aesthetic reasons created by printing techniques
- B32B17/10275—Laminated safety glass or glazing containing decorations or patterns for aesthetic reasons created by printing techniques on interlayer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
- B32B17/10678—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer comprising UV absorbers or stabilizers, e.g. antioxidants
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
- B32B17/10733—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing epoxy
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
- B32B17/10743—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing acrylate (co)polymers or salts thereof
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
- B32B17/1077—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing polyurethane
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10807—Making laminated safety glass or glazing; Apparatus therefor
- B32B17/1088—Making laminated safety glass or glazing; Apparatus therefor by superposing a plurality of layered products
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
- C03C17/32—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with synthetic or natural resins
- C03C17/326—Epoxy resins
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/3405—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of organic materials
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Biochemistry (AREA)
- Laminated Bodies (AREA)
Abstract
합성수지를 유기용제에 용해시킨 것에 안료, 결합제, 윤활제 및 건조제등을 첨가한 것으로 구성된 각종 색상의 인쇄 잉크를 접착력 보강제인 프라이머가 도포된 유리면에 다색으로 인쇄하여 다색 무늬가 형성된 유리 인조대리석을 제조하는 방법에 있어서,The printing inks of various colors consisting of pigments, binders, lubricants and desiccants added to the synthetic resins in organic solvents are printed in multiple colors on glass surfaces coated with primers, which are adhesive enhancers, to produce glass artificial marbles with multicolor patterns. In the method,
상기 인쇄잉크로서 통상의 폴리우레탄수지(P.U)와 에폭시 수지(EPOXY)의 혼합물에 접착보강제로 실리카, 규사등 무기재료(세라믹스) 대신에 합성수지인 아크릴 레이트 올리고머를 상기 P.U및 에폭시와 함께 동일양 또는 유사한 양을 첨가함과 동시에 거기에 자외선 흡수제(UV Coater)도 함께 첨가하여 잉크를 제조하고 잉크와 유리면의 접착력 보강제인 프라이머로는 통상의 불소수지와 같은 합성수지에 무기재료 대신 G.P(다목적)실란, 카플링제(Silane coupling agent)를 프라이머 전체양에 대하여 약 30∼50wt%를 첨가하여 기존의 방법대로 유리면에 프라이머 코팅층 및 인쇄층을 형성한 후 자외선(UV) 램프(고압수은 lamp)가 설치된 U.V건조기내에서 80∼100℃로 건조시켜 유리로된 각종 무늬를 갖는 인조 대리석을 얻는 것이다.As the printing ink, an acrylate oligomer, which is a synthetic resin, is used together with the PU and epoxy in place of an inorganic material (ceramic) such as silica and silica as an adjuvant to a mixture of a conventional polyurethane resin (PU) and an epoxy resin (EPOXY). A similar amount is added and UV coater is added to the ink to prepare the ink, and the primer, which is an adhesion enhancer between the ink and the glass surface, is a GP (multipurpose) silane instead of an inorganic material to a synthetic resin such as fluorine resin. UV-dryer equipped with UV lamp (high pressure mercury lamp) after adding coupling agent (Silane coupling agent) about 30 to 50wt% based on the total amount of the primer to form a primer coating layer and a printing layer on the glass surface according to the conventional method It is made to dry at 80-100 degreeC in the inside, and the artificial marble which has various patterns of glass is obtained.
Description
본 발명은 투명 유리에 각종 색상의 칼라인쇄를 하여 유리로된 인조대리석을 제조하는 방법 및 그 방법에 의해 제조된 유리로된 인조대리석에 관한 것으로서, 특히 절단 가공이 용이하고 별도로 인쇄층의 보호층이나 파편 보호층이 불필요한 유리 인조대리석에 관한 것이다.The present invention relates to a method for producing artificial marble made of glass by color printing of various colors on transparent glass, and to an artificial marble made of glass prepared by the method. The present invention relates to a glass artificial marble which does not require a debris protective layer.
종래의 유리로된 인조대리석은 불소수지와 같은 합성수지에 실리카, 규사등 무기재료(세라믹)로된 보강충전제와 자외선 흡수제를 첨가하여된 프라이머를 투명 유리 밑면에 도포하고 불소수지와 같은 합성수지에 각종 색상의 안료와 실리카, 산화납, 산화붕소, 알카리 금속 산화물등 무기재료와 윤활제등을 첨가한 것으로 구성되는 인쇄 잉크를 상기 프라이머 층위에 인쇄하여 프라이머와 인쇄 잉크에 혼합된 무기재료에 의해 인쇄층과 유리와의 접착력을 보강하여 왔으나 이 경우에는 무기재료(세라믹)를 첨가하였기 때문에 그것들이 완전히 용융되어 유리에 접착하게 하려는 400℃내지 900℃까지의 고열로 가열하여야 인쇄층이 유리면에 완전 융착되어 박리되지 않게되는데 이와같이 고열로 유리면과 인쇄층을 가열한 후 경화하게 되면 유리의 물성, 즉 경도가 변하여 절단이 어려워지므로 가공상 많은 문제점이 있었다. 또한 상기 프라이머층과 인쇄층 위에 표면 보호를 위하여 자외선 흡수제를 인쇄층 위에 도포하고 다시 그 위에 파편 보호를 위한 파편 보호층을 도포하는 등 많은 공정과 재료가 필요하였었다.Conventional glass artificial marble is made of synthetic resin such as fluorine resin, and a primer made by adding a reinforcing filler made of inorganic material (ceramic) such as silica and silica sand and an ultraviolet absorber is applied to the bottom of the transparent glass, and various colors are applied to the synthetic resin such as fluorine resin. A printing ink consisting of a pigment, an inorganic material such as silica, lead oxide, boron oxide, and an alkali metal oxide and a lubricant, is printed on the primer layer, and the printing layer and glass are made of an inorganic material mixed with the primer and the printing ink. In this case, since the inorganic material (ceramic) was added, the printing layer must be heated to a high temperature of 400 ° C to 900 ° C to melt completely and adhere to the glass. In this way, if the glass surface and the printing layer are heated and cured at a high temperature, the properties of the glass, Changed the hardness becomes difficult to cut the number of issues were processed. In addition, many processes and materials were required, such as applying a UV absorber on the printed layer to protect the surface on the primer layer and the printed layer, and then applying a fragment protective layer on the fragment to protect the fragment.
본 발명은 상기한 바와같은 종래의 유리로된 인조대리석 제조의 결점을 개선하여 재료가 적게들고 공정이 간편하면서 대리석의 절단 가공이 용이한 유리로된 인조대리석의 제조방법을 제공코져하는 것으로서 이를 실예를 들어 상세히 설명하면 다음과 같다.The present invention improves the drawbacks of conventional marble artificial marble as described above to provide a method of manufacturing artificial marble made of glass that is low in material, easy to process, and easy to cut marble. It will be described in detail as follows.
도 1 은 본 발명에 따라 제조되는 유리 인조대리석의 단면도.* 도면 중 주요부분에 대한 부호의 설명 *1 is a cross-sectional view of the glass artificial marble prepared according to the present invention.
1 : 유리면 2 : 프라이머층3 : 잉크층DESCRIPTION OF SYMBOLS 1 Glass surface 2 Primer layer 3: Ink layer
도 1에 도시된 바와 같이 본 발명의 유리 인조대리석은 투명유리(1)은 일면에 합성수지에 다목적 실란 카플링제를 첨가한 프라이머층(2)과 폴리우레탄수지, 에폭시수지 및 아크릴 레이트 올리고머 혼합물에 자외선 흡수제를 첨가한 잉크층(3)이 차례로 도포 적층된 구성이다.이하 본 발명 인조대리석의 구성을 위한 제조방법은 다음과 같다.합성수지를 유기용제에 용해시킨 것에 안료, 결합제, 윤활제 및 건조제등을 첨가한 것으로 구성된 각종 색상의 인쇄 링크를 접착력 보강제인 프라이머가 도포된 유리면에 다색으로 인쇄하여 다색 무늬가 형성된 유리 인조대리석을 제조하는 방법에 있어서,상기 인쇄잉크로서 통상의 폴리우레탄수지(P.U)와 에폭시 수지(EPOXY)의 혼합물에 접착보강제로 실리카, 규사등 무기재료(세라믹스) 대신에 합성수지인 아크릴 레이트 올리고머를 상기 P.U및 에폭시와 함께 동일양 또는 유사한 양을 첨가함과 동시에 거기에 자외선 흡수제(UV Coater)도 함께 첨가하여 잉크를 제조하고 잉크와 유리면의 접착력 보강제인 프라이머로는 통상의 불소수지와 같은 합성수지에 무기재료 대신 G.P(다목적)실란, 카플링제(Silane coupling agent)를 프라이머 전체양에 대하여 약 30∼50wt%를 첨가한 것을 프라이머로하여 기존의 방법대로 유리면(1)에 프라이머층(2)및 인쇄층(3)을 형성한후 자외선(UV) 램프(고압수은 lamp)가 설치된 U.V건조기내에서 80∼100℃로 건조시켜 유리도된 각종 무늬를 갖도록 한 것이다.As shown in Figure 1, the glass artificial marble of the present invention is a transparent glass (1) UV light on the primer layer (2) and the polyurethane resin, epoxy resin and acrylate oligomer mixture in which the multi-purpose silane coupling agent is added to the synthetic resin on one surface The ink layer 3 to which the absorbent is added is laminated in order. The manufacturing method for the composition of the artificial marble of the present invention is as follows. A pigment, a binder, a lubricant, a drying agent, and the like are prepared by dissolving a synthetic resin in an organic solvent. A method of manufacturing a glass artificial marble having a multi-colored pattern by printing a printing link of various colors on the glass surface coated with a primer, which is an adhesive reinforcement agent, in a multi-colored pattern, wherein the printing ink has a conventional polyurethane resin (PU) and Acrylic resin, synthetic resin, instead of inorganic materials (ceramic) such as silica and silica sand as an adjuvant to epoxy mixture (EPOXY) The oligomer is added with the PU or epoxy in the same amount or similar amount, and the UV coater is also added thereto to prepare the ink. In the same synthetic resin, GP (multi-purpose) silane and coupling agent (Silane coupling agent) was added to the total amount of about 30 to 50wt% based on the primer as a primer, the primer layer (2) ) And the printed layer 3 is dried in an UV dryer equipped with an ultraviolet (UV) lamp (high pressure mercury lamp) at 80 to 100 ° C. to have various patterns of glass.
따라서 상기와 같은 제조방법으로는 구성된 본 발명의 유리 인조대리석은 프라이머나 인쇄잉크에 실리카, 규사등 세라믹 물질, 즉 무기재료를 보강제 충전제로 사용하지 않고도 접착력이 우수한 아크릴 레이트 올리고머를 기존의 폴리우레탄과 에폭시수지와 함께 혼합하여 잉크를 제조하므로서 80∼100℃의 저온 가열에 의해서도 경화가 되어 경화시간이 단축되는 장점이 있고 또한 무기재료의 첨가에 의한 접착력보다 더 인쇄층의 접착력이 우수하거나 유사하면서 인쇄층의 경화후 완성된 인조대리석을 절단시에는 인쇄층과 프라이머 층에 무기질이 포함되지 않고 저온 경화에 의해서 유리의 경도에 변화가 없었기 때문에 절단이 용이한 장점이 있었다.Therefore, the glass artificial marble of the present invention, which is composed of the above-described manufacturing method, has excellent adhesion to acrylate oligomers without using a ceramic material such as silica, silica sand, or an inorganic material as a filler in a primer or printing ink. By mixing with epoxy resin to prepare ink, it is cured by low temperature heating at 80 ~ 100 ℃ and the curing time is shortened.It also has better or similar adhesion of printing layer than adhesive force by adding inorganic material. When the finished artificial marble was cut after curing of the layer, there was an advantage in that the cutting was easy because the printing layer and the primer layer did not contain inorganic material and the hardness of the glass did not change due to low temperature curing.
또한 본 발명에서는 프라이머층에 보강 충전제로 무기재료를 첨가하지 않고도 실란 카플링제에 의해 유리와 인쇄층의 접착력을 향상시켜 저온에서도 인쇄층의 접착이 용이하게 하였음은 물론이고 그로 인하여 유리가 경도나 강도의 변화가 없으므로 완성 제품의 절단도 용이하게 하는 특징이 있으며,In addition, in the present invention, the adhesion between the glass and the printing layer is improved by the silane coupling agent without adding an inorganic material as a reinforcing filler to the primer layer, so that the adhesion of the printing layer is easy even at low temperatures, and thus the glass has hardness or strength. There is no change in the characteristics, so it is easy to cut the finished product.
또 인쇄층 자체에 자외선 흡수제(U.V)를 첨가 혼합하였기 때문에 종래의 인쇄후 그 인쇄층에 U.V를 도포하고 다시 그 위에 파편 보호층을 형성할 필요가 없이 인쇄층 자체가 표면 보호가 되므로 공정의 단축과 재료의 절감등으로 인하여 제조 원가가 현저하게 절감됨은 물론이고 단시간에 일정규격 제품을 양산 할 수 있는 특징도 있는 것이다.In addition, since the UV absorber (UV) is added to and mixed with the printed layer itself, the printing layer itself is a surface protection without the need to apply UV to the printed layer after printing and to form a debris protective layer thereon. Due to the reduction of materials and materials, not only the manufacturing cost is significantly reduced, but also there is a characteristic that it can mass-produce a certain standard product in a short time.
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| KR20170039418A (en) | 2015-10-01 | 2017-04-11 | (주)제이원산업 | Manufacture Method for Concrete Board Using Waste Glass Chip And Concrete Board By Theof |
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| KR20040042355A (en) * | 2002-11-14 | 2004-05-20 | 제일모직주식회사 | Marble Chips with High Contamination Resistance and Artificial Marble Using the Same |
| KR101827064B1 (en) | 2015-12-14 | 2018-03-22 | 현대자동차주식회사 | Shatter-proof glass coating composition, architectural tempered shatter-proof glass using it and method for manufacturing architectural tempered shatter-proof glass |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR960001422A (en) * | 1994-06-30 | 1996-01-25 | 김태구 | Component Function Management System of Exhaust System |
| JPH09255902A (en) * | 1996-03-22 | 1997-09-30 | Asahi Glass Co Ltd | Primer composition for bonding substrate to sealant |
| KR0152263B1 (en) * | 1989-12-28 | 1998-10-15 | 가와무라 시게꾸니 | Active energy ray-curable composition and applicable method |
| JP2001089744A (en) * | 1999-09-22 | 2001-04-03 | Asahi Glass Co Ltd | Method of applying sealing material improved in light- resistant adhesion |
| KR20010033678A (en) * | 1997-12-29 | 2001-04-25 | 데코 페턴트 인코포레이티드 | Method and compositions for decorating vitreous articles with radiation curable inks having improved adhesion and durability |
-
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR0152263B1 (en) * | 1989-12-28 | 1998-10-15 | 가와무라 시게꾸니 | Active energy ray-curable composition and applicable method |
| KR960001422A (en) * | 1994-06-30 | 1996-01-25 | 김태구 | Component Function Management System of Exhaust System |
| JPH09255902A (en) * | 1996-03-22 | 1997-09-30 | Asahi Glass Co Ltd | Primer composition for bonding substrate to sealant |
| KR20010033678A (en) * | 1997-12-29 | 2001-04-25 | 데코 페턴트 인코포레이티드 | Method and compositions for decorating vitreous articles with radiation curable inks having improved adhesion and durability |
| JP2001089744A (en) * | 1999-09-22 | 2001-04-03 | Asahi Glass Co Ltd | Method of applying sealing material improved in light- resistant adhesion |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20170039418A (en) | 2015-10-01 | 2017-04-11 | (주)제이원산업 | Manufacture Method for Concrete Board Using Waste Glass Chip And Concrete Board By Theof |
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