KR100445111B1 - Manufacturing method of emitting infra ray powder and picture color and crepas including the same - Google Patents

Manufacturing method of emitting infra ray powder and picture color and crepas including the same Download PDF

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KR100445111B1
KR100445111B1 KR10-2001-0059445A KR20010059445A KR100445111B1 KR 100445111 B1 KR100445111 B1 KR 100445111B1 KR 20010059445 A KR20010059445 A KR 20010059445A KR 100445111 B1 KR100445111 B1 KR 100445111B1
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weight
powder
oxide
granular powder
raw material
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KR10-2001-0059445A
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KR20030026170A (en
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최재인
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반석제로파 주식회사
최재인
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D13/00—Pencil-leads; Crayon compositions; Chalk compositions
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L29/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
    • C08L29/02—Homopolymers or copolymers of unsaturated alcohols
    • C08L29/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2206—Oxides; Hydroxides of metals of calcium, strontium or barium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2217—Oxides; Hydroxides of metals of magnesium
    • C08K2003/222—Magnesia, i.e. magnesium oxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2265—Oxides; Hydroxides of metals of iron

Abstract

본 발명은 원적외선을 방사하는 과립형 분체 및 그를 포함하는 회화용 물감 및 크레파스를 제조하는 방법에 관한 것으로, 과립형 분체는 산화규소(SiO2) 62~69 중량%, 산화철(FeO3) 6~10 중량%, 산화마그네슘(MgO) 3~5 중량%, 산화포타슘(KO) 5~6 중량%, 산화나트륨(NaO) 1~2 중량%, 산화칼슘(CaO) 1~3 중량%, 기타 광물질 18~20 중량%로 구성된 분말 원료에 상기 분말 원료에 대하여 물 30~50 중량%, 분산제 0.2~0.6 중량%, 폴리비닐알콜 0.5~1.0 중량%, 산화비소0.005~0.004(Bi2O3) 중량% 및 윤활제 0.1~0.4 중량%를 혼합하여 균일하게 혼련시키는 단계와, 상기 혼련된 원료를 볼밀을 사용하여 2~4 시간 동안 습식 분쇄하여 1~3㎛ 의 입도를 갖는 분체를 형성하는 단계와, 상기 분쇄된 분체를 분무 건조기의 입구 온도를 550~600℃로 유지하고 출구 온도를 100~150℃로 유지하여 상기 과립형 분체 내의 수분 함유량이 상기 과립형 분체에 대하여 0.1~0.4 중량%가 되게 분무 건조하여 과립형 분체를 형성하는 단계로 구성된다.The present invention relates to a granular powder that emits far-infrared rays, and a method for producing a paint for painting and crayons containing the same, wherein the granular powder is 62 to 69 wt% of silicon oxide (SiO 2 ) and 6 to 6 iron oxide (FeO 3 ). 10 wt%, magnesium oxide (MgO) 3-5 wt%, potassium oxide (KO) 5-6 wt%, sodium oxide (NaO) 1-2 wt%, calcium oxide (CaO) 1-3 wt%, other minerals 30 to 50 wt% of water, 0.2 to 0.6 wt% of dispersant, 0.5 to 1.0 wt% of polyvinyl alcohol, 0.005 to 0.004 (Bi 2 O 3 ) weight Mixing and uniformly mixing 0.1% to 0.4% by weight of lubricant and%, wet grinding the kneaded raw material using a ball mill for 2 to 4 hours to form a powder having a particle size of 1 to 3 μm, The pulverized powder was maintained at the inlet temperature of the spray dryer at 550-600 ° C. and the outlet temperature at 100-150 ° C. to provide the granular powder. It consists of the step of forming a granular powder by spray-drying so that the moisture content in it becomes 0.1-0.4 weight% with respect to the said granular powder.

Description

원적외선을 방사하는 과립형 분체 및 그를 포함하는 회화용 물감 및 크레파스의 제조방법{Manufacturing method of emitting infra ray powder and picture color and crepas including the same}Manufacturing method of emitting infra ray powder and picture color and crepas including the same}

수세기 동안 회화는 작가와 소유자들이 특정 소수의 문화를 형성하면서 보수적 가치관의 틀을 벗어나지 못한채 역사속에 안주하여 왔다. 수세기가 지난 현대에 와서야 다양한 장르가 등장하였고 행위, 설치 비디오 예술적 표현 등으로 한계를 의식하면서 새 장르에 도전하고 있다. 그러나 이 또한 공유 평등의 예술이 될 수는 없다. 복잡 다양한 테크놀러지 시대를 거쳐 인류는 자유가 아닌 자유를 선택하였고 문명의 이기 속에서 자연이 아닌 자연을 선택하고 말았다. 이제는 더 이상 잘못된 사고의 틀에 머무를 수 없다. 사실 회화는 단순한 감상의 대상이나 특정 소수의 과시적 도구로 평가되어서는 안된다. 작가 또한 미술 그 자체를 소득 개념으로만 악용하지 말아야 한다. 작가는 자기 만족의 일신 주의에서 벗어나 제작한 그림이 소유자에게 회화적 가치외에 또 하나의 욕구 충족을 줄 수 있는 방법이 있다면 서슴치 말고 제공해야 하며 소유자 역시 단순한 회화적 감상과 투자 개념에서 시대적 순수 가치 개념으로 전환을 시도할 때 라고 생각한다. 원적외선 회화 물감으로 그린 바이오 원적외선 회화는 바로 이러한 고정관념을 제거하고 디지탈 시대의 시류를 명쾌히 해명하여 줄 것이다.For centuries, painting has settled down in history without leaving the framework of conservative values as artists and owners formed a certain minority of cultures. Only a few centuries later, various genres have emerged and the new genre is being challenged with awareness of limitations through acts, installation video and artistic expressions. But this too cannot be the art of shared equality. Through the age of complex technologies, humanity has chosen freedom, not freedom, and nature, not nature, in the face of civilization. You can no longer stay in the wrong frame of thinking. In fact, painting should not be regarded as a simple object of appreciation or as a small number of display tools. The artist should not abuse art itself as an income concept. The artist must provide the paintings that are produced out of the monotheism of self-satisfaction in order to provide the owner with another desire besides pictorial value. I think it's time to try switching. Bio far-infrared paintings painted with far-infrared paintings will remove this stereotype and clarify the current time of the digital era.

본 발명은 원적외선을 방사하는 과립형 분체 및 그를 포함하는 회화용 물감 및 크레파스의 제조방법에 관한 것으로, 더욱 상세하게는 기존의 회화용 물감 또는 크레파스에 원적외선을 방사하는 과립형 분체를 비율에 따라 배합하여 그림을 그렸을 때 완성된 회화에서 원적외선이 방출하도록 한 것이다.The present invention relates to a granular powder that emits far-infrared rays, and to a method of manufacturing paints and crayons containing the same, and more particularly, to a granule powder that emits far-infrared rays into existing paints or crayons according to a ratio. When the picture is drawn, far infrared rays are emitted from the completed painting.

종래의 유화 물감은 안료(60~70%)와 건성유(린씨드 오일 25~30%)에 천연수지(다마르 5~10%)와 보조제 를첨가하여 생산한다. 일반적으로 토성 계열의 안료인 번트시엔나, 엄버 등은 기름의 흡유량이 크고 울트라 마린, 망간 블루, 유기 안료 등은 흡유량이 적은 편이다. 유화 물감은 다른 물감에 비해 미디엄(바인더)의 양이 적게 사용된다. 미디엄을 만들기 위하여 천연수지(다마르)를 녹인 후 건성유(린씨드 오일)를 섞고 보조 첨가제를 넣은 단계, 안료(60~70%)와 바인더(25~30%)를 유리판에 붓고 고루 섞는 단계, 안료와 미디엄(고착제)를 균일하게 혼합하고 미세하게 분쇄 연마하는 단계를 거쳐 만든 유화용 물감을 튜브나 병 속에 보관한다.Conventional emulsions are produced by adding natural resins (5-10%) and supplements to pigments (60-70%) and dry oils (25-30% rinseed oil). In general, Saturn-based pigments such as burnt cienna and umber have a large oil absorption amount, and ultramarine, manganese blue, and organic pigments have a low oil absorption amount. Emulsion paints use less medium (binder) than other paints. Dissolving natural resin (damar) to make medium, mixing dry oil (rinseed oil) and adding auxiliary additives, pouring pigment (60 ~ 70%) and binder (25 ~ 30%) onto glass plate and mixing them evenly, The pigment and medium (fixing agent) are uniformly mixed and finely ground and polished to store the oil paints made in a tube or bottle.

또한 종래의 교육용 크레파스는 파라핀과 왁스를 용기에 넣고 가열하여 녹이는 단계, 이때에 파라핀유를 첨가한다. 파라핀과 왁스가 완전히 녹으면 탄산칼슘 분말을 천천히 넣고 원하는 안료를 넣은 다음 고루 섞이도록 저어준다. 그리고 마련된 틀에 넣어 냉각 시킨 다음 틀에서 꺼낸다. 회화의 작가는 한 편의 작품을 완성하기 위하여 오랜 시간을 캔버스를 최단 거리에서 응시해야 하므로 쉽게 눈의 피로를 호소하게 된다. 뿐만 아니라 회화 작업을 할때 주위의 유해 물질 즉 애폭신애폰 기타 화공약품 등의 유독성 가스로 인해 쉽게 육체적 피로를 초래하게 된다.In addition, the conventional educational crayons are paraffin and wax in a container and heated to dissolve, at this time paraffin oil is added. Once the paraffin and wax are completely dissolved, slowly add the calcium carbonate powder, add the desired pigment and stir to mix evenly. Cool it in the prepared mold and take it out of the mold. The artist of the painting has to stare at the canvas for the longest time in order to complete a piece of art, so it easily complains of eye strain. In addition, when painting, toxic gases such as toxic chemicals such as epoxy and other chemicals can easily cause physical fatigue.

작가가 심혈을 기울여 제작한 작품이 주위 환경의 조건에 다라 쉽게 변색 또는 퇴색하는 경향이 있다.The works produced by the artist with great care tend to discolor or fade easily depending on the conditions of the surrounding environment.

본 발명은 이와 같은 종래의 문제점을 해결하기 위한 것으로 인체에 유익한 생육광선인 원적외선이 방사되는 회화용 물감 및 크레파스의 제조방법을 제공하는데 있다.The present invention is to provide a method for producing a paint for painting and crayons that far-infrared radiation, which is a growth light beam beneficial to the human body to solve such a conventional problem.

상기한 본 발명의 목적은 산화규소(SiO2) 62~69 중량%, 산화철(FeO3) 6~10 중량%, 산화마그네슘(MgO) 3~5 중량%, 산화포타슘(KO) 5~6 중량%, 산화나트륨(NaO) 1~2 중량%, 산화칼슘(CaO) 1~3 중량%, 기타 광물질 18~20 중량%로 구성된 분말 원료에 상기 분말 원료에 대하여 물 30~50 중량%, 분산제 0.2~0.6 중량%, 폴리비닐알콜 0.5~1.0 중량%, 산화비소0.005~0.004(Bi2O3) 중량% 및 윤활제 0.1~0.4 중량%를 혼합하여 균일하게 혼련시키는 단계와, 상기 혼련된 원료를 볼밀을 사용하여 2~4 시간 동안 습식 분쇄하여 1~3㎛ 의 입도를 갖는 분체를 형성하는 단계와, 상기 분쇄된 분체를 분무 건조기의 입구 온도를 550~600℃로 유지하고 출구 온도를 100~150℃로 유지하여 상기 과립형 분체 내의 수분 함유량이 상기 과립형 분체에 대하여 0.1~0.4 중량%가 되게 분무 건조하여 과립형 분체를 형성하는 단계와, 상기 과립형 분체를 유화용 안료 60~70 중량%에 대해 10~20 중량%를 혼합하여 고루 섞고 안료와 상기 과립형 분체가 혼합된 안료와 고착제를 균일하게 혼합하고 미세하게 분쇄 연마하는 단계를 포함하는 원적외선을 방사하는 회화용 물감의 제조방법에 의해 달성된다.The object of the present invention described above is 62 to 69% by weight of silicon oxide (SiO 2 ), 6 to 10% by weight of iron oxide (FeO 3 ), 3 to 5% by weight of magnesium oxide (MgO), 5 to 6% by weight of potassium oxide (KO) % To 30-50% by weight of water, dispersant 0.2%, based on the powder raw material, consisting of%, sodium oxide (NaO) 1-2%, calcium oxide (CaO) 1-3%, other minerals 18-20% by weight ~ 0.6% by weight, polyvinyl alcohol 0.5 ~ 1.0% by weight, arsenic oxide 0.005 ~ 0.004 (Bi 2 O 3 ) by weight of the mixing and mixing 0.1 to 0.4% by weight of the uniformly kneading, and the ball-mill Forming a powder having a particle size of 1 to 3 μm by wet grinding for 2 to 4 hours using the same, and maintaining the inlet temperature of the spray dryer at 550 to 600 ° C. and an outlet temperature of 100 to 150 It is maintained at ℃ and spray-drying so that the water content in the granular powder is 0.1 to 0.4% by weight relative to the granular powder to form granular powder And mixing 10 to 20 wt% of the granular powder with respect to 60 to 70 wt% of the pigment for emulsification, uniformly mixing the pigment and the fixing agent mixed with the pigment and the granular powder, and finely grinding and grinding It is achieved by a method for producing a paint for emitting far infrared rays comprising a.

또한 본 발명은 산화규소(SiO2) 62~69 중량%, 산화철(FeO3) 6~10 중량%, 산화마그네슘(MgO) 3~5 중량%, 산화포타슘(KO) 5~6 중량%, 산화나트륨(NaO) 1~2 중량%, 산화칼슘(CaO) 1~3 중량%, 기타 광물질 18~20 중량%로 구성된 분말 원료에 상기 분말 원료에 대하여 물 30~50 중량%, 분산제 0.2~0.6 중량%, 폴리비닐알콜 0.5~1.0 중량%, 산화비소0.005~0.004(Bi2O3) 중량% 및 윤활제 0.1~0.4 중량%를 혼합하여 균일하게 혼련시키는 단계와, 상기 혼련된 원료를 볼밀을 사용하여 2~4 시간 동안 습식 분쇄하여 1~3㎛ 의 입도를 갖는 분체를 형성하는 단계와, 상기 분쇄된 분체를 분무 건조기의 입구 온도를 550~600℃로 유지하고 출구 온도를 100~150℃로 유지하여 상기 과립형 분체 내의 수분 함유량이 상기 과립형 분체에 대하여 0.1~0.4 중량%가 되게 분무 건조하여 과립형 분체를 형성하는 단계와, 상기 과립형 분체를 크레파스용 안료 60~70 중량%에 대해 10~20 중량%를 혼합하여 고루 섞고 크레파스 1본 제작당 기준으로 파라핀 10g, 왁스 10g을 용기에 넣고 가열하여 파라핀과 왁스를 녹이고 파라핀유 6ml와 탄산칼슘분말 5g 을 넣은 다음 과립형 분체가 혼합된 안료를 넣고 고루 섞는 단계와, 그 후 고루 섞인 것이 확인되면 불을 끄고 완전히 용해된 원료를 틀에 부어 고정시키고 냉각시키는 단계를 포함하는 원적외선을 방사하는 크레파스의 제조방법에 의해 달성된다.In addition, the present invention is 62 to 69% by weight of silicon oxide (SiO 2 ), 6 to 10% by weight of iron oxide (FeO 3 ), 3 to 5% by weight of magnesium oxide (MgO), 5 to 6% by weight of potassium oxide (KO), oxide 30 to 50% by weight of water and 0.2 to 0.6% of dispersant in a powder raw material consisting of 1 to 2% by weight of sodium (NaO), 1 to 3% by weight of calcium oxide (CaO) and 18 to 20% by weight of other minerals. %, 0.5 to 1.0% by weight of polyvinyl alcohol, 0.005 to 0.004% by weight of arsenic oxide (Bi 2 O 3 ) and 0.1 to 0.4% by weight of the lubricant is uniformly kneaded and the kneaded raw material using a ball mill Forming a powder having a particle size of 1 to 3 μm by wet grinding for 2 to 4 hours, maintaining the inlet temperature of the spray dryer at 550 to 600 ° C. and the outlet temperature at 100 to 150 ° C. By spray drying the water content in the granular powder to be 0.1 to 0.4% by weight relative to the granular powder to form granular powder; The granular powder is mixed evenly by mixing 10 to 20% by weight with respect to 60 to 70% by weight of the pigment for crayons, and 10 g of paraffin and 10 g of wax are added to a container and dissolved in paraffin and wax by heating 6 ml of paraffin oil. And 5 g of calcium carbonate powder, and then adding the pigment mixed with granular powder, and then mixing the mixture, and then, if it is confirmed that the mixture is evenly mixed, turn off the fire and pour the completely dissolved raw material into the mold to fix and cool it. It is achieved by a method for producing spinning crayons.

따라서 본 발명의 원적외선 회화 물감 및 원적외선 교육용 크레파스로 그림을 그리는 작가는 원적외선 회화 물감 및 원적외선 교육용 크레파스에서 발산되는 원적외선의 효과로 안하여 종래의 회화 물감과 크레파스로 그림을 그릴때와는 달리 쉽게 눈의 피로를 느끼지 않을 뿐아니라 완성된 회화의 변색이나 탈색을 막을 수 있고 원적외선 회화 물감으로 그린 회회를 실내에 걸어 두었을 때 원적외선 회화에서 발산하는 원적외선의 영향으로 실내 공기를 정화시켜 쾌적한 생활 공간을 제공하게 되며 특히 병원 병실에 걸어 두면 환자들의 쾌유에 도움이 될 수 있는 효과를 기대하게 된다.Therefore, the artist who draws with far-infrared paints and crayons for far-infrared education of the present invention is not as easy as when drawing with conventional paints and crayons without the effect of far-infrared rays emitted from far-infrared paints and crayons for far-infrared education. Not only does it feel tired, but it also prevents discoloration and discoloration of the finished painting, and when the ashes painted with far-infrared paints are placed indoors, the indoor air is purified by the far-infrared rays emitted by far-infrared paintings to provide a comfortable living space. In particular, if you walk in the hospital room is expected to be beneficial to patients' comfort.

[실시예1]Example 1

산화규소(SiO2) 65중량%, 산화철(Fe2O3) 8중량%, 산화마그네슘(MgO) 4중량%, 산화포타슘(KO) 5중량%, 산화나트륨(NaO) 1중량%, 산화칼슘(CaO) 2중량%, 기타 광물질 15중량%로 이루어진 분말(raw powder)에 상기 분말 원료에 대하여 물 40중량%를 첨가하고 가소제로 폴리비닐알콜 0.75중량% 및 산화비소(Bi2O3) 0.001중량%를 첨가한 후 윤활제로 아연산 0.2 중량%를 첨가하여 균일하게 혼련시킨다.65% by weight of silicon oxide (SiO 2 ), 8% by weight of iron oxide (Fe 2 O 3 ), 4% by weight of magnesium oxide (MgO), 5% by weight of potassium oxide (KO), 1% by weight of sodium oxide (NaO), calcium oxide 40% by weight of water is added to the powder raw material to a raw powder composed of 2% by weight (CaO) and 15% by weight of other minerals, and 0.75% by weight of polyvinyl alcohol and 0.002% of arsenic oxide (Bi 2 O 3 ) as a plasticizer. After adding the weight%, 0.2 weight% of zinc acid is added as a lubricant to knead uniformly.

상기 혼련된 원료를 볼밀(ball mill)을 사용하여 2~4시간 바람직하게는 3시간동안 습식 분쇄한 후분무 건조 (spray dry)시켜 1∼3㎛ 정도의 입도를 가지는 과립형 분체를 제조하였다. 이때 과립형 분체를 제조하는 동안 분무 건조기의 입구 온도를 550~600℃, 바람직하게는 580℃가 되도록 유지하며 분무 건조기의 출구 온도를 100~150℃, 바람직하게는 120℃가 되도록 유지하여 분체 내의 수분 함유량이 0.2~0.3 중량% 이 되도록 한다. 그 결과 1.05~1.13g/㎤의 밀도를 갖는 과립형 분체가 제조된다. 이렇게 제조된 분체를 상기 발명의 구성항에서 명기된 방법으로 유화용 물감 또는 크레파스에 넣고 이렇게 넣은 유화용 물감과 또는 크레파스로 그린 회화에서 발산하는 원적외선의 방사율과 방사에너지 FT-IR 스팩트로 메타로 흑체와 비교하여 측정한 결과 다음 도표와 같았다.The kneaded raw material was wet milled using a ball mill for 2 to 4 hours, preferably 3 hours, and then spray dried to prepare granular powder having a particle size of about 1 to 3 μm. At this time, while preparing the granular powder, the inlet temperature of the spray dryer is maintained at 550 ~ 600 ℃, preferably 580 ℃ and the outlet temperature of the spray dryer is maintained at 100 ~ 150 ℃, preferably 120 ℃ in the powder The water content is 0.2 to 0.3% by weight. As a result, granular powder having a density of 1.05 to 1.13 g / cm 3 is produced. The powder thus prepared was put in an oil paint or crayon by the method specified in the constituent section of the present invention, and the emissivity of the far-infrared radiation emitted from the painting drawn with crayon or the radiant energy FT-IR spectra was meta black. The result of the measurement is as follows.

[실시예2]Example 2

상기 실시예 1의 방법으로 만들어진 유화용 물감과 크래파스로 그린 회화의 열화상 온도 측정(D.I.T.I)을 한 결과 바이오 에너지(Bio Energy)가 측정되었으며 종래의 유화용 물감과 크레파스로 그린 회화는 바이오 에너지가 측정되지 않았다.Bioenergy was measured as a result of thermal image temperature measurement (DITI) of an oil painting paint made with the method of Example 1 and crayons, and a painting made with conventional oil paints and crayons was bioenergy. Not measured.

※ 유첨: 열화상 온도 측정결과 도면※ Attachment: Thermal image temperature measurement result drawing

[실시예3]Example 3

상기 실시예 1의 방법으로 만들어진 유화용 물감으로 그린 그림과 종래의 유화용 물감으로 그린 그림을 같은 조건에서 (여름 6,7,8,9월) 4개월간 비닐 하우스에서 직사광선을 쪼인 결과 두 작품 중 종래 유화용 물감으로 그린 작품은 30%이상 색채가 변색 또는 탈색되었고 원적외선 방사 물질이 함유된 유화용 물감으로 그린 그림은 변색 또는 탈색 그리고 전혀 균열이나 손상이 없었으며 종래의 유화용 물감으로 그린 작품은 심한 균열과 손상이 육안으로 뚜렷이 확인되었다.The paintings drawn with the oil paints made by the method of Example 1 and the paintings made with conventional oil paints were subjected to direct sunlight in a plastic house for 4 months under the same conditions (Summer, July, August, September). Previously, paintings made with oil paints have been discolored or discolored by more than 30%, and paintings made with oil paints containing far-infrared radiation have no discoloration or discoloration and no cracks or damage. Severe cracks and damages were clearly visible.

[실시예4]Example 4

초등학생 50명과 유치원생 50명에게 상기 실시예 1의 방법으로 만들어진 크레파스와 종래의 크레파스로 2회에 걸쳐 한 작품을 약 60분 정도로 완성하도록 한 후 눈의 피로감을 질문하였더니 다음과 같은 통계가 나왔다.50 elementary school students and 50 kindergarten students were asked to complete a work about twice as much as about 60 minutes with crayons made by the method of Example 1 and conventional crayons, and the following statistics appeared.

Claims (3)

산화규소(SiO2) 62~69 중량%, 산화철(FeO3) 6~10 중량%, 산화마그네슘(MgO) 3~5 중량%, 산화포타슘(KO) 5~6 중량%, 산화나트륨(NaO) 1~2 중량%, 산화칼슘(CaO) 1~3 중량%, 기타 광물질 18~20 중량%로 구성된 분말 원료에 상기 분말 원료에 대하여 물 30~50 중량%, 분산제 0.2~0.6 중량%, 폴리비닐알콜 0.5~1.0 중량%, 산화비소0.005~0.004(Bi2O3) 중량% 및 윤활제 0.1~0.4 중량%를 혼합하여 균일하게 혼련시키는 단계와;62 to 69% by weight of silicon oxide (SiO 2 ), 6 to 10% by weight of iron oxide (FeO 3 ), 3 to 5% by weight of magnesium oxide (MgO), 5 to 6% by weight of potassium oxide (KO), sodium oxide (NaO) 30 to 50% by weight of water, 0.2 to 0.6% by weight of dispersant, polyvinyl in a powder raw material consisting of 1 to 2% by weight, 1 to 3% by weight of calcium oxide (CaO), 18 to 20% by weight of other minerals Mixing 0.5 to 1.0 weight percent of alcohol, 0.005 to 0.004 weight percent (Bi 2 O 3 ), and 0.1 to 0.4 weight percent of a lubricant to uniformly knead the mixture; 상기 혼련된 원료를 볼밀을 사용하여 2~4 시간 동안 습식 분쇄하여 1~3㎛ 의 입도를 갖는 분체를 형성하는 단계와;Wet grinding the kneaded raw material using a ball mill for 2 to 4 hours to form powder having a particle size of 1 to 3 μm; 상기 분쇄된 분체를 분무 건조기의 입구 온도를 550~600℃로 유지하고 출구 온도를 100~150℃로 유지하여 상기 과립형 분체 내의 수분 함유량이 상기 과립형 분체에 대하여 0.1~0.4 중량%가 되게 분무 건조하여 과립형 분체를 형성하는 단계를 포함하는 원적외선을 방사하는 과립형 분체의 제조방법.The pulverized powder is sprayed to maintain the inlet temperature of the spray dryer at 550-600 ° C. and the outlet temperature at 100-150 ° C. such that the water content in the granular powder is 0.1-0.4 wt% based on the granular powder. Method of producing a granular powder that emits far-infrared rays comprising the step of drying to form granular powder. 산화규소(SiO2) 62~69 중량%, 산화철(FeO3) 6~10 중량%, 산화마그네슘(MgO) 3~5 중량%, 산화포타슘(KO) 5~6 중량%, 산화나트륨(NaO) 1~2 중량%, 산화칼슘(CaO) 1~3 중량%, 기타 광물질 18~20 중량%로 구성된 분말 원료에 상기 분말 원료에 대하여 물 30~50 중량%, 분산제 0.2~0.6 중량%, 폴리비닐알콜 0.5~1.0 중량%, 산화비소0.005~0.004(Bi2O3) 중량% 및 윤활제 0.1~0.4 중량%를 혼합하여 균일하게 혼련시키는 단계와;62 to 69% by weight of silicon oxide (SiO 2 ), 6 to 10% by weight of iron oxide (FeO 3 ), 3 to 5% by weight of magnesium oxide (MgO), 5 to 6% by weight of potassium oxide (KO), sodium oxide (NaO) 30 to 50% by weight of water, 0.2 to 0.6% by weight of dispersant, polyvinyl in a powder raw material consisting of 1 to 2% by weight, 1 to 3% by weight of calcium oxide (CaO), 18 to 20% by weight of other minerals Mixing 0.5 to 1.0 weight percent of alcohol, 0.005 to 0.004 weight percent (Bi 2 O 3 ), and 0.1 to 0.4 weight percent of a lubricant to uniformly knead the mixture; 상기 혼련된 원료를 볼밀을 사용하여 2~4 시간 동안 습식 분쇄하여 1~3㎛ 의 입도를 갖는 분체를 형성하는 단계와;Wet grinding the kneaded raw material using a ball mill for 2 to 4 hours to form powder having a particle size of 1 to 3 μm; 상기 분쇄된 분체를 분무 건조기의 입구 온도를 550~600℃로 유지하고 출구 온도를 100~150℃로 유지하여 상기 과립형 분체 내의 수분 함유량이 상기 과립형 분체에 대하여 0.1~0.4 중량%가 되게 분무 건조하여 과립형 분체를 형성하는 단계와;The pulverized powder is sprayed to maintain the inlet temperature of the spray dryer at 550-600 ° C. and the outlet temperature at 100-150 ° C. such that the water content in the granular powder is 0.1-0.4 wt% based on the granular powder. Drying to form granular powder; 상기 과립형 분체를 유화용 안료 60~70 중량%에 대해 10~20 중량%를 혼합하여 고루 섞고 안료와 상기 과립형 분체가 혼합된 안료와 고착제를 균일하게 혼합하고 미세하게 분쇄 연마하는 단계를 포함하는 원적외선을 방사하는 회화용 물감의 제조방법.Mixing 10 to 20% by weight of the granular powder with respect to 60 to 70% by weight of an emulsified pigment, and uniformly mixing and finely grinding and grinding the pigment and the binder mixed with the pigment and the granular powder. Method for producing a paint for radiating far infrared rays. 산화규소(SiO2) 62~69 중량%, 산화철(FeO3) 6~10 중량%, 산화마그네슘(MgO) 3~5 중량%, 산화포타슘(KO) 5~6 중량%, 산화나트륨(NaO) 1~2 중량%, 산화칼슘(CaO) 1~3 중량%, 기타 광물질 18~20 중량%로 구성된 분말 원료에 상기 분말 원료에 대하여 물 30~50 중량%, 분산제 0.2~0.6 중량%, 폴리비닐알콜 0.5~1.0 중량%, 산화비소0.005~0.004(Bi2O3) 중량% 및 윤활제 0.1~0.4 중량%를 혼합하여 균일하게 혼련시키는 단계와;62 to 69% by weight of silicon oxide (SiO 2 ), 6 to 10% by weight of iron oxide (FeO 3 ), 3 to 5% by weight of magnesium oxide (MgO), 5 to 6% by weight of potassium oxide (KO), sodium oxide (NaO) 30 to 50% by weight of water, 0.2 to 0.6% by weight of dispersant, polyvinyl in a powder raw material consisting of 1 to 2% by weight, 1 to 3% by weight of calcium oxide (CaO), 18 to 20% by weight of other minerals Mixing 0.5 to 1.0 weight percent of alcohol, 0.005 to 0.004 weight percent (Bi 2 O 3 ), and 0.1 to 0.4 weight percent of a lubricant to uniformly knead the mixture; 상기 혼련된 원료를 볼밀을 사용하여 2~4 시간 동안 습식 분쇄하여 1~3㎛ 의 입도를 갖는 분체를 형성하는 단계와;Wet grinding the kneaded raw material using a ball mill for 2 to 4 hours to form powder having a particle size of 1 to 3 μm; 상기 분쇄된 분체를 분무 건조기의 입구 온도를 550~600℃로 유지하고 출구 온도를 100~150℃로 유지하여 상기 과립형 분체 내의 수분 함유량이 상기 과립형 분체에 대하여 0.1~0.4 중량%가 되게 분무 건조하여 과립형 분체를 형성하는 단계와;The pulverized powder is sprayed to maintain the inlet temperature of the spray dryer at 550-600 ° C. and the outlet temperature at 100-150 ° C. such that the water content in the granular powder is 0.1-0.4 wt% based on the granular powder. Drying to form granular powder; 상기 과립형 분체를 크레파스용 안료 60~70 중량%에 대해 10~20 중량%를 혼합하여 고루 섞고 크레파스 1본 제작당 기준으로 파라핀 10g, 왁스 10g을 용기에 넣고 가열하여 파라핀과 왁스를 녹이고 파라핀유 6ml와 탄산칼슘분말 5g 을 넣은 다음 과립형 분체가 혼합된 안료를 넣고 고루 섞는 단계와;The granular powder is mixed evenly by mixing 10 to 20% by weight with respect to 60 to 70% by weight of the pigment for crayons, and paraffin and wax are dissolved by heating 10 g of paraffin and 10 g of wax on the basis of one crepas. 6 ml and 5 g of calcium carbonate powder were added, and then the pigment mixed with granular powder was added and mixed with each other; 그 후 고루 섞인 것이 확인되면 불을 끄고 완전히 용해된 원료를 틀에 부어 고정시키고 냉각시키는 단계를 포함하는 원적외선을 방사하는 크레파스의 제조방법.Then, if it is confirmed that evenly mixed, the method of manufacturing crayons that emit far infrared rays comprising the step of turning off the fire, and then pour the completely dissolved raw material into the mold to fix and cool.
KR10-2001-0059445A 2001-09-25 2001-09-25 Manufacturing method of emitting infra ray powder and picture color and crepas including the same KR100445111B1 (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR950026844A (en) * 1994-03-10 1995-10-16 전창호 Manufacturing method of far infrared emitter powder
KR980001899A (en) * 1996-06-15 1998-03-30 한희갑 Far Infrared Radiation Material and Manufacturing Method Thereof
KR19980040084A (en) * 1996-11-29 1998-08-17 윤경중 Dye Containing Far Infrared Radiation
KR100384536B1 (en) * 1999-10-11 2003-05-22 김완겸 A printing ink containing body stimulating object for health-aid

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR950026844A (en) * 1994-03-10 1995-10-16 전창호 Manufacturing method of far infrared emitter powder
KR980001899A (en) * 1996-06-15 1998-03-30 한희갑 Far Infrared Radiation Material and Manufacturing Method Thereof
KR19980040084A (en) * 1996-11-29 1998-08-17 윤경중 Dye Containing Far Infrared Radiation
KR100384536B1 (en) * 1999-10-11 2003-05-22 김완겸 A printing ink containing body stimulating object for health-aid

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