KR100431424B1 - Method for cleaning and refreshing fabrics - Google Patents

Abstract

The present invention relates to a method for processing a textile product comprising the following steps: The textile product is placed in a container having one or more walls defining an opening and an empty space therein. Then, the temperature and the relative humidity of the air in the empty space inside the container are raised to the predetermined first temperature and the predetermined first relative humidity for a predetermined first period of time. Finally, at the end of the first period one or more of the temperature and relative humidity of the air in the empty space inside the vessel is changed to the predetermined second temperature and the predetermined second relative humidity for the predetermined second period.

Description

Method for cleaning and refreshing fabrics

Certain delicate fabrics are not suitable for conventional home immersion laundering. Household washing machines, which provide excellent laundering results for most fabrics used in today's society, can shrink or damage silk, linen, wool and other delicate fabrics under certain conditions. Consumers typically "dry clean" their delicate textile items. Unfortunately, dry cleaning typically involves a process of dipping the fabric in a variety of hydrocarbon and halocarbon solvents that require special handling, and the process is not suitable for home use because the solvent must be regenerated. Thus, dry cleaning is traditionally limited to commercial facilities, making it less convenient and more expensive than domestic laundry.

Attempts have been made to provide in-home dry cleaning systems that combine fabric washing and refreshing in home immersion laundering methods with the fabric protection benefits of dry cleaning. One such home system for washing and refreshing garments includes base sheets and plastic bags containing various liquid or gelling detergents. The garment is placed in a bag with the sheet and then tumbling in a conventional clothes dryer. In a typical commercial embodiment, multiple disposable flat sheets and single purpose plastic bags containing cleaning / refreshing agents are provided in a package.

Unfortunately, these prior methods often include only one step with respect to temperature and relative humidity. That is, the tumble dryer is set only for a specific temperature and time. Humidity in the bag is a function of the moisture and temperature setting added to the bag. However, once time and temperature are selected, a one-step process is set up. In addition, when using a conventional tumble dryer, consumers are often limited to temperature conditions preset by the manufacturer, which are intended for drying clothes rather than washing and refreshing clothes. Often these manufacturer's conditions are partially optimized for one or more of dewrinkling, deodorization and, optionally, perfume deposition.

In addition, these home methods are designed for use in devices such as conventional clothes dryers. Such devices are not always readily available, often uneconomical, and in many areas no clothes dryer is needed at all. For example, many warm tropical people typically do not have clothes dryers because they can dry their clothes all year round by hanging their clothes in the sun. In areas in the world where people do not typically have a clothes dryer, products requiring heating devices such as clothes dryers are of little or no value.

Steamer cabinets have also been used in the art to treat textile products with large amounts of steam. Unfortunately, such high temperature, high relative humidity methods can negatively impact textile products. In addition to the harsh effects on the fabric, a drying step is often needed, which even adds a further deformation to the fabric. The drying step also requires additional time and energy and often results in unnecessary shrinkage. And finally, steamer cabinets are typically wasteful in terms of steam because steam is only water.

Accordingly, there is a need to develop cleaning and refreshing compositions for use in providing household, non-immersive laundry and refreshing methods and acceptable cleaning properties without requiring a tumble dryer.

Unexpectedly, the present invention has also revealed a method of washing, wrinkling and refreshing only dry-cleanable fabrics by controlling the temperature and relative humidity in the container during home non-immersion laundering and refreshing processes. The present invention provides such a method for washing and refreshing fabrics.

Summary of the Invention

In one aspect of the invention, a step of (a) placing a textile product in a container having an opening and at least one wall defining an empty space therein, wherein the temperature and relative humidity of the air in the empty space inside the container is determined by a predetermined first (B) raising the temperature and the predetermined first relative humidity for a predetermined first period of time and at least one of the temperature and relative humidity of the air in the empty space inside the vessel at the end of the first period of time to the predetermined second temperature and Provided is a method of treating one or more textile products comprising the step (c) of changing for a second predetermined period of time to a predetermined second relative humidity.

In a preferred embodiment of the present invention, the fabric is contacted with the aqueous composition before being placed in the container according to step (a) as defined below.

In another preferred embodiment of the present invention, steam is used to raise the temperature and relative humidity of the air in the void inside the vessel, more preferably leaving the vent always open. In another aspect of the invention, the vapor introduced into the void inside the vessel comprises water and fragrances.

In another preferred aspect of the present invention, the method comprises the steps of: (a) introducing a textile product into a container having an opening and at least one wall defining an empty space therein; introducing ozone into the empty space therein for a predetermined first period of time; (b) and changing at least one of the temperature and relative humidity of the air in the empty space inside the container at the end of the first period to a predetermined second temperature and a predetermined second humidity for a predetermined second period of time (c) Provided is a method of treating a textile product comprising a. Ozone can also be generated as an ozone source, such as an ultraviolet lamp or a high voltage source, in an empty space inside the vessel. Preferably, the ozone level supplied inside the vessel is 0.5 to 200 ppm, preferably 0.5 to 50 ppm, more preferably 0.5 to 20 ppm. Levels below 0.5 ppm are undesirable because they do not provide sufficient bleaching performance and consequently do not provide sufficient performance of the benefits associated with the bleaching properties.

The present invention provides an advantage over the prior art by limiting the optimal process steps for washing and refreshing delicate textile products in home non-immersion laundry methods. The process of the invention can be carried out in a suitable container, for example a plastic bag, wardrobe, cabinet or tumble dryer.

Unlike many of the preceding processes, the process of the present invention comprises two or more separate steps, preferably three steps. Surprisingly, it has been found that the optimum conditions for deodorizing textile products differ from those best for wrinkle removal. In addition, the deposition of fragrances in textile products requires a third set of conditions for optimal performance. In the multi-step method of the present invention, temperature, relative humidity or both can be adjusted or controlled. Alternatively, one step of the present invention may include introducing ozone into the container to neutralize the chemical causing the odor on the washed and refreshed textile product.

The present invention further provides a method of conveying the active ingredient, for example a fragrance, to the fabric to be treated. At the same time, the method herein minimizes the amount of vapor carried so that the active material is not wasted. Finally, the method herein is designed to carry only enough steam to achieve the fabric treatment without the need for additional mechanical drying.

The present invention relates to a useful method of washing and refreshing fabrics by non-immersion washing methods. Temperature and relative humidity are controlled in the multistage process of the present invention.

The present invention provides a method for washing and refreshing textile products by household non-immersion methods. The process requires at least two steps, preferably three steps. The method can be carried out in any suitable apparatus in which the temperature and relative humidity can be controlled and controlled. In another aspect of the invention, one of the method steps involves the process of neutralizing a chemical causing an odor on a textile product which is introduced into the container and washed and refreshed.

The warm moist environment inside the vessel volatilizes the malodorous component in a "vapor distillation" method and wets the fabric and the contamination thereon. This wetting of the fabric can loosen the pre-wrinkle and no new wrinkles are formed because the textile product is hung in the container. The shrinkage of the fabric can be minimized by suitably selecting the amount of vapor and specifically the amount of water used in the process and, importantly, by properly venting the vessel in this way. In addition, if the container is not evacuated, if there is a volatilized malodorous material that has been removed from the fabric but not captured by the filter, it may undesirably re-deposit on the fabric.

Relative humidity is a concept well known to those skilled in the fabric protection arts. As used herein, "relative humidity" means the ratio of the actual amount of water vapor in the air to the maximum possible amount at the same temperature.

Temperature and relative humidity regulators are well known in the art as passive and active regulators. As used herein, an "active" regulator is a regulator that feeds feedback to the device to be adjusted after reading the dosage, and the device is adjusted based on the feedback received. As used herein, a "manual" regulator is a regulator that turns the device on or off, or opens or closes the device based on a predetermined setting, such as time. For example, a manual thermostat turns on the heating element or closes the exhaust vents to raise the temperature in a given environment, and after a period of time turns off the heating elements or opens the vents. In contrast, an active thermostat reads the temperature and, for example, if the temperature is too low, it raises the power to the heating element or closes the exhaust to raise the temperature.

Way

In order to properly wash and refresh textile products, various aspects of product appearance must be presented. Specifically, the textile product should be at least substantially free of odors and wrinkles after washing and refreshing operations. It is often desirable to flavor the product to provide a pleasant odor, which should not leave localized stains. The process of the present invention requires at least two steps designed with respect to deodorization, wrinkle removal and / or fragrance deposition on textile products. In addition, a manual spot removal method is provided for removing localized spots, but the spot removal method is performed outside of the apparatus. Conditions for each of these method steps are described in more detail below.

The process steps of the present invention may suitably be performed in any order, but first the deodorization step is discussed. Deodorization here is to be distinguished from masking or covering up the odor comprising the step of applying a fresh scent to the fabric. As used herein, deodorization involves the substantial removal or neutralization of malodor causing chemicals. In the case of eliminating or neutralizing odor causing ingredients, the textile product should have little or no residual odor. This step of the process can be carried out with ozone to neutralize the odor, or by high temperature and exhaust and / or by filter capturing to remove the odor causing components. The advantage of using ozone as a bleaching system is that these components provide not only a satisfactory overall color safety, odor reduction, stain removal, but also hygiene of the treated products, especially for cellulose fabrics.

The deodorization step is described herein as the first step for convenience. It is understood that the deodorization and wrinkle removal steps may be performed in any order. If a perfume deposition step is used, it must be carried out after the deodorizing step, so that the perfume is not removed from the fabric immediately after it is added to the fabric.

Thus, when deodorization is the first step, the first temperature should be at least about 45 ° C., preferably at least about 60 ° C., most preferably at least about 70 ° C., and the first relative humidity should be at least about 20%. At this relatively high temperature, the odor causing chemical is removed from the fabric and then preferably removed from the vessel through the vent. Even more preferably, the vent includes a filter to prevent odor emanations from entering the environment outside the vessel. When the first temperature and the first relative humidity are reached, the process time, ie the first time, can be from about 2 minutes to about 20 minutes, preferably from about 5 minutes to about 15 minutes, even more preferably from about 8 minutes to about 12 minutes. have.

The deodorization step described above can be reinforced or even replaced by the process of treating the textile product with ozone incorporated, preferably at room temperature. The use of ozone to neutralize odor causing chemicals and to sanitize garments such as medical gowns is well known in the art. Specifically, reference is made to published patent applications DE 24 33 909 and FR 2059 841, both of which are incorporated herein by reference. For the methods described herein, ozone can be introduced into the vessel from a suitable source such as an ultraviolet lamp. One or more ozone sources may be used, which may be located at any convenient location or adjacent to the outside of the vessel. The ozone source should be sized according to the volume of the container taking into account the surface area of the textile product being washed and refreshed. Those skilled in the art will be aware of what type and size of device should be used for a given container.

The second step of the present invention relates to the removal of wrinkles that require relatively high temperatures and relative humidity. Good air circulation is beneficial for the wrinkle removal step but is not essential. For the second step, that is, the wrinkle removal step, the second temperature should exceed "T" defined by the following equation (1).

In Equation 1 above,

RH ₂ is the second relative humidity (%).

RH ₂ is at least 50%, preferably at least 75%, more preferably at least about 85%, even more preferably at least about 90%. Preferably, the second temperature is less than about 90 ° C, more preferably less than about 80 ° C, most preferably less than about 70 ° C. When the second temperature and the second relative humidity are reached, the process time, ie the second time, can be from about 2 minutes to about 20 minutes, preferably from about 5 minutes to about 15 minutes, even more preferably from about 8 minutes to about 12 minutes. have.

Finally, there is a third step, preferably comprising the slow cooling of the interior empty space. As the temperature drops, the amount of steam that can hold in the air decreases, and as the air saturates, the steam begins to condense. Naturally, the vapor condenses on the textile product inside the bag and as this product dries, active ingredients such as perfumes are left behind. As briefly discussed above, the process steps of the present invention are designed to transport the active material without saturation to the extent that it is necessary to further dry the fabric without undue consumption. Preferably, during the third step of the process, the temperature in the interior empty space drops to a third temperature, the third temperature is less than about 45 ° C., preferably less than about 40 ° C., more preferably about 35 ° C. Is less than. This third step may last for a third period of time, which may be from about 2 minutes to about 20 minutes, preferably from about 3 minutes to about 10 minutes, even more preferably from about 3 minutes to about 5 minutes.

As discussed in more detail below, the vapor inside the vessel is preferably a cleaning and refreshment composition. The cleaning refreshment composition may be added directly to the container, through the sheet / substrate, in the cartridge or by other means known to those skilled in the art. Preferably, the cleaning and refreshing composition is in a cartridge introduced into the empty space inside the container or the cleaning and refreshing composition is discharged from the cartridge into the empty space inside the container.

Device

The method of the invention can be carried out in any suitable apparatus. Such devices require a container that substantially wraps the fabric product to be washed and refreshed. By "substantially wrapping" is meant that while the textile product is wrapped in a container, the container may comprise one or more vents, and preferably comprises. The container should have an opening that accesses the textile product, and preferably there is a bar, hook or other device to hang the textile product. Garments that hang on the processing device may also be weighted or stretched to improve wrinkle reduction. Hanging weights and stretching devices are well known to those skilled in the art. Preferably, the garment to be treated is mechanically stretched after it is placed in a container and before starting the process. This stretching or so-called stretching of the garment assists in the relaxation of the wrinkles during the process. Preferred stretching systems include heavy clamps as well as lightweight compact or retractable stretching systems, which include stretching devices such as springs. The latter system has the advantage that it is possible to adjust the stretching force and the required direction as needed, while at the same time not adding additional weight to the laundry and refreshing device. Preferably such a system is installed at its base inside the container. One example of such a system is a rollerblind commonly used as a sunfilter in automobiles and commercially available from Halfords. This system is a roller blind that can be stretched or shrunk by a roll-up spring mechanism. In order to apply this system to the stretch of the garment it is necessary to make minor modifications to this system. One preferred adaptation includes attaching a housing of such a system to the base of the device and providing one or more clamps on the other side such that clamping and thus stretching or stretching of the garment within the device is obtained. The elongation of the spring can also be adjusted to the desired elongation for a given garment. The size of the clamp can be varied so that one or more clamps are attached to this system. Yet another variant includes having only one clamp to operate in conjunction with or partially together with a blind stretching system located opposite the housing of the system.

The container preferably has only one wall shaped like an eggshell. It has been found that the vapor, subsequently the active ingredient, preferentially condenses at the corners and along the sharp edges of the more conventional rectangular shaped cabinet. This is not to say that the method of the present invention cannot be performed in a conventional rectangular cabinet, but the method of the present invention can be performed. However, fewer sharp edges and corners in the cabinet are more efficient. Thus, cabinets, wardrobes and garment bags are all suitable for use in the present invention. In addition, although a typical tumble dryer may be a suitable container, such devices are typically not equipped with a humidity controller or lack the ability to program a multi-step process for both temperature and humidity. Thus, with some further programming and regulators, a general tumble dryer can be used in the method of the present invention.

In addition to at least one wall defining an empty space therein, the vessel of the invention is preferably an exhaust and / or filter, a heating element capable of heating the liquid to produce steam and carrying out drying to heat the air, A moisture supply and an air circulation device such as a fan. More preferably, the vessel further comprises an active thermostat capable of varying and maintaining the air temperature in the void within the vessel, a passive humidity regulator and / or coolant capable of varying and maintaining the relative humidity of the air in the void within the vessel. And a humidity sink such as: Even more preferably, the air circulation device is a fan and the fan inlet is present in an empty space inside the vessel to allow at least some of the air to be recycled within the empty space of the vessel. Preferably, for the optimum deodorization, it is preferred that the air speed around the garment of 0.05 to 10m / s, more preferably from 0.1 to 5m.s ^-1, most preferably from 0.5 to 2m.s ^-1. In addition, a filter is provided in or adjacent to the outside of the container.

Water and active substances, ie, "cleaning and refreshing compositions", can be added to the container in any suitable manner. The composition may be introduced into the bag, may be introduced into a reservoir for feeding to the heating element / humidifier, the composition may be infused using a canister, or the absorbent substrate saturated with the composition may be placed in the bag. . Suitable substrates and compositions for use in the methods of the present invention are described in more detail below. Those skilled in the art will recognize other methods of adding the active material to the container, which methods are within the scope of the present invention.

Cleaning / Refreshment Composition

The cleaning / refreshment composition preferably comprises water and a member selected from the group consisting of surfactants, perfumes, preservatives, bleaches, auxiliary cleaners, shrinkage reducing agents, organic solvents and mixtures thereof. Preferred organic solvents are glycol ethers, in particular methoxy propoxy propanol, ethoxy propoxy propanol, propoxy propoxy propanol, butoxy propoxy propanol, butoxy propanol, ethanol, isopropanol and mixtures thereof. Fabric shrink reduction compositions suitable for use in the present invention are selected from the group consisting of all isomers of ethylene glycol, propanediol, butanediol, pentanediol, hexanediol and mixtures thereof. More preferably, the fabric shrink reduction composition is selected from the group consisting of niopentyl glycol, polyethylene glycol, 1,2-propanediol, 1,3-butanediol, 1-octanol and mixtures thereof. The surfactant is preferably a nonionic surfactant such as ethoxylated alcohol or ethoxylated alkyl phenol and is present at about 2% or less based on the weight of the cleaning / refreshment composition. Typical fabric cleaning / refreshment compositions herein may comprise at least about 80%, preferably at least about 90%, more preferably at least about 95% water.

The following examples set forth specific ranges for the individual components of a preferred cleaning / refreshment composition for use herein. A more detailed description of the individual components of the cleaning / refreshment composition, i.e., organic solvents, surfactants, flavorings, preservatives, bleaches and auxiliary cleaning agents, is described in US Pat. No. 5,789,368 to You et al., Dated August 4, 1998. You can find it. The entire disclosure of patent documents, such as Yu, is incorporated herein by reference. In addition, cleaning / refreshment compositions are described in co-pending US patent application Ser. No. 08 / 789,171 filed Jan. 24, 1997 in Tririn et al. The entire disclosure of the application of Trin et al. Is incorporated herein by reference. In addition, the shrinkage reducing compositions for use in the present invention are concurrently entitled “Cleaning Compositions to Reduce Fabric Shrinkage”, filed by Strang and Cylosi on August 24, 1998. Pending U.S. Provisional Application 60 / 097,596. The entire description of the Strand and cyclocy applications are incorporated herein by reference.

Pretreatment Composition

In one embodiment of the present invention, the cleaning / refreshment composition may be used to pretreat the fabric before placing it in the container defined in step (a) of the present invention. In addition, the pretreatment of the fabric has been found to be very advantageous for the removal of creamy or pasty deodorant stains adhered to clay, such as horse mud, as well as to local parts of textile products, such as the armpits of the fabric. . It has also been found that this pretreatment step is advantageous for improving the deodorization and wrinkle removal performance of the device on the treated fabric. Thus, a method of treating a fabric is provided, wherein the fabric is contacted with a cleaning / refreshing composition as defined herein before placing the fabric in the container defined in step (a). Preferably, the fabric is commercially available, such as aluminum aerosol cans coated with polyethylene or with a hand spray bottle (VEL) commercially available under the headings No. 792458 for 500 ml and Part No. 772657 for 500 ml. Contact is achieved by spraying with an aerosol spray (Boxal part of the Algroup Wheaton). A suitable valve for the can is an aluminum cup spray valve from Seaquist. Preferably, the cans are filled with nitrogen at an initial filling pressure of 10 bar with a propellant, while the pretreatment composition is filled up to 60% of the total volume of the cans. Typical descriptions of such spray dispensers can be found in WO 96/04940, page 21, line 21 to page 22, line 27. Optionally, for cleaning / refreshment compositions, for further improved deodorizing performance, cyclodextrins, in particular β-cyclodextrins such as β-hydroxypropyl cyclodextrins or β-methylated cyclodextrins, can be used while improved wrinkle removal For this purpose, lubricants such as D5 cyclomethicone from Dow Corning or ester quaternary ammonium compounds such as di (tallowyloxyethyl) dimethyl ammonium can be used. Typical levels of such cyclodextrins are at least 0.01% by weight, preferably 0.1 to 5% by weight.

materials

In one embodiment of the present invention, the cleaning / refreshment composition can be releasably absorbed into an absorbent substrate (hereinafter referred to as "substrate"). The substrate releasably contains the composition. “Releasably containing” means herein that the composition is effectively released from the substrate into the contaminated fabric as part of the cleaning and fabric refreshment process. This release is mainly caused by volatilization of the composition due to heat from additional heat sources.

The substrate may be in any desired form, for example in the form of powder, flakes, shreds, or the like. However, it is highly desirable that the substrate is in the form of a complete pad or "sheet" that substantially maintains its structural integrity throughout the process. The substrates and sheets of the present invention are sometimes referred to in the literature as "carriers" or "absorbent carrier sheets" and it is understood that all of these names refer to liquid absorbent materials that can be used to conveniently transport liquids. Such descriptions are described in detail in US Pat. No. 5,789,368 to Yu et al. The production of such sheets does not form any part of the present invention and is already described in the literature. For example, U.S. Patent No. 5,009,747 to Viazmensky et al., April 23, 1991, and US Patents issued to Biazmensky et al., March 8, 1994, incorporated herein by reference. See 5,292,581.

The substrate is intended to contain an amount of the cleaning / refreshment composition sufficient to be effective for the intended purpose. The capacity of the substrate for such a composition varies depending on the intended use. The size of the substrate should not be so large that the user cannot handle it. Typically, the dimensions of the substrate are sufficient to provide a macroscopic surface area (both sides of the substrate) in the range of about 360 cm 2 or more, preferably in the range of about 360 to about 3000 cm 2. For example, generally rectangular substrates may have dimensions of about 10 to about 35 cm (X-direction) and about 18 to about 45 cm (Y-direction).

In one preferred embodiment of the present invention, the substrate is a dark material, such as a black fabric, or is coated with a dark material. It is well known that dark materials absorb light better than bright materials. Thus, dark substrates tend to absorb more heat and further volatilize the cleaning and refreshing composition, for example when solar radiation is used as an additional heat source.

As discussed, the substrate may optionally be coated with a fibrous, preferably heat resistant, most preferably hydrophobic coversheet, as described in detail in U.S. Patent No. 5,789,368 to Yu et al., Herein incorporated by reference as above. have. In addition, co-pending U.S. Provisional Application No. 60 / 077,556, filed March 11, 1998, in the name of Wise et al., Describes certain improvements to the coversheet of the present invention. Without departing from the intention and scope of the present invention, cover sheets described in Yu et al. Can be used in appropriate combination with improvements described in Wise's literature, as desired by the manufacturer.

Spot cleaning composition

The user of the method of the invention can be provided with a variety of spot cleaning compositions for use in any preliminary spotting process of the invention. Such compositions are used to remove topical stains from the fabric to be treated, either before or after the laundry and refreshing processes defined herein. The spot cleaning composition must be miscible with the fabric to be treated. That is, no significant amount of dye should be removed from the fabric during the spot treatment, and the spot cleaning composition should leave no visible stain on the fabric. Thus, in a preferred embodiment of the present invention, there is provided a spot cleaning composition that is substantially free of materials that leave visible residue on the treated fabric. This essentially means that the preferred composition is formulated to contain as high as possible the highest levels of volatiles, preferably water, typically about 95%, preferably about 97.7%, and about 0.1 to about 0.7% surfactant. do. Preferred spot cleaning compositions also contain a cleaning solvent such as butoxypropoxy propanol (BPP) at low but effective levels, typically from about 1 to about 4%, preferably about 2%.

Preferred spot washing methods and compositions are described in US Pat. No. 5,789,368 to Yu et al., Which is incorporated herein by reference. In addition, spot washing methods and compositions are described in US Pat. No. 5,630,847, issued to Roetker on May 20, 1997. The entire description of the Lötker patent literature is incorporated herein by reference.

Treatment member

In one embodiment, the treatment member is provided to assist in removing localized stains from the fabric. In a preferred embodiment of the invention, the spot cleaning composition is provided in a dispenser, such as a bottle, with the dispensing tip having an end tip that can act as a treatment member. In addition, the treatment member may comprise an absorbent base material, which may be, for example, a natural or synthetic sponge, an absorbent cellulosic sheet or pad, or the like. Multiple protrusions may be present in contact with or extending out of this base material. Specific examples of processing members can be found in U.S. Pat.No. 5,789,368 to Yu et al., Incorporated herein by reference as such.

Absorbent Stain Receptive Products

Absorbent stain receiving products, sometimes referred to herein as stain receptors, may optionally be used in any preliminary spotting operation herein. Such stain receptors can be any absorbent material that absorbs liquid compositions that can be used for preliminary spotting operations. Disposable paper towels, cloth towels such as towels under the trade name BOUNTY ^™ , clean rags and the like can be used. However, in a preferred form, the stain receptor is designed to "wick" or "draw" the liquid composition away from the contaminated area. One preferred type of stain receptor consists of a nonwoven pad, such as a heat bonded air laid fabric ("TBAL"). Another highly preferred type of stain receptor for use herein includes polymeric foams comprising polymerized water-in-oil emulsions, sometimes referred to as "poly-HIPE". The preparation of polymeric foams is described very extensively in the patent literature, for example, DesMarais, Stone, Thompson as of November 9, 1993, all of which are incorporated herein by reference. , U.S. Pat.No. 5,260,345 to Young, Lavon and Dyer, U.S. Pat. See US Pat. No. 5,650,222 to Mares et al. Conventional conditions for forming the polymeric foams of the present invention are described by T. Mar. 13, 1998, the disclosure of which is incorporated herein by reference. a. Co-pending US patent application Ser. No. 09 / 042,418, entitled "Absorbent Material for Dispensing Aqueous Liquids," filed by Des Mares et al. Further description of the conditions for forming polymeric foams for use in the present invention is described in T. Mar. 13, 1998, the contents of which are incorporated herein by reference. a. Co-pending US Provisional Patent Application No. 60 / 077,955, entitled “Abrasion Resistant Polymeric Foam and Stain Receptor Made therefrom,” filed by Des Mares et al.

The various stain receptors described herein, and described in the literature cited herein, preferably comprise a liquid impermeable backsheet. The backsheet can be made of a thin layer of, for example, polypropylene, polyethylene, or the like. The backsheet protects the surface on which the receptor rests against the spot cleaning composition. For example, spot washing is typically performed on a hard surface, such as a table top. The stain receptor is placed on the table and the fabric to be treated is placed on the stain receptor. The spot cleaning composition is applied to the contaminated area of the fabric and then drawn to the stain receptor. However, in the absence of the back sheet, the spot cleaning composition may leak on the table top, causing damage to it.

The following examples further illustrate the present invention but are not intended to limit it.

Example I

Hang a pair of XL men's jackets that are exposed to cigarette smoke and corrugated using standardized methods. The jacket is then hung inside a plastic bag with two coplanar flat ends (top and bottom) that are cylindrical in side wall and inclined slightly outward near the center. Just to illustrate, you can think of the bag as a cut eggshell with the top and bottom cut off. The container has a door for internal access and the door is sealed with a zipper. A small slit near the base of the bag acts as the vent and the vent is always open during this process.

Inside the bag there are fans, heating elements, thermocouples and reservoirs in fluid communication with the heating elements. About 100-125 ml of a composition comprising about 99% water and 1% fragrance is added to a reservoir and the door is closed.

The external "on / off" switch is turned on to initiate the fabric refreshment process. The switch is connected to a programmable microprocessor that regulates the multistage process. First, the temperature is raised to about 70 ° C. at a relative humidity of about 50%. This is accomplished by running the fan and heating element with little or no contact with the cleaning and refreshment composition. This first step lasts for 10-15 minutes. In the second step, the temperature is reduced to about 50 ° C. and the relative humidity is raised above about 95%. This is accomplished through the introduction of evaporated cleaning and refreshing compositions. The fan continues to run during the second stage, which lasts for about 7-9 minutes.

Finally, the fan that started the heating element is turned off and the interior of the bag is naturally cooled to about 45 ° C. in about 10 minutes. The fan turns off automatically and the indicator light indicates that the process is complete. When the jackets are moved, they are substantially free of wrinkles, deodorized and ready to wear.

Example II

Hang a pair of XL men's jackets on hangers that are exposed to cigarette smoke and wrinkled using standardized methods. Subsequently, the most creased portion is pretreated with a commercially available demineralized water pocket spray under serial number Vel. No. 772457 (Vel) and slightly moistened without immersing the corrugated area. These jackets are then hung inside a plastic bag with two coplanar flat ends (top and bottom) with a sidewall cylindrical and inclined slightly outwards near the center. Just to illustrate, you can think of the bag as a cut eggshell with the top and bottom cut off. The container has a door for internal access and the door is sealed with a zipper. An exhaust vent is provided near the base of the bag, but the exhaust vent remains closed when ozone is present in the bag.

Inside the bag is a receptacle for accommodating a cartridge containing a fan, an ultraviolet lamp, a heating element, a thermocouple and a cleaning and refreshing composition. The receptacle is in fluid connection with the heating element. The cleaning and refreshing composition comprises about 100 to 125 ml of a composition comprising approximately 99% water and 1% perfume. Connect the cartridge to the receptacle and close the door.

The external "on / off" switch is turned on to initiate the fabric refreshment process. The switch is connected to a programmable microprocessor that regulates the multistage process. First, the ultraviolet lamp is turned on to generate ozone. Leave the lamp on for about 10 minutes. The fan is optionally run during this first step. In the second step, the temperature is raised to about 50 ° C. and the relative humidity is raised above about 50%. This is accomplished through the introduction of evaporated cleaning and refreshing compositions. The fan continues to operate for the second stage, which lasts for about 7-12 minutes.

Finally, the heating element is turned off while the fan is running and the interior of the bag is naturally cooled to about 45 ° C. in about 10 minutes. The fan turns off automatically and the indicator light indicates that the process is complete. When the jackets are moved, they are substantially free of wrinkles, deodorized and ready to wear.

Example III

Cleaning and Refreshing Compositions

The cleaning and refreshing compositions of the present invention may comprise only water and fragrances, but may also include additional textile treatment components. For example, a fabric cleaning / refreshment composition according to the present invention for use in the methods described herein is prepared as follows.

ingredient weight% Sheet Cartridge Emulsifier (TWEEN 20) ^* 0.5 0 Spices 0.5 0.5 KATHON 0.0003 0 Sodium benzoate 0.1 0 water Remaining amount Remaining amount ^* Polyoxyethylene (20) sorbitan monolaurate commercially available from ICI Surfactants

In addition, preferred compositions for use in the method of the present invention are as follows.

ingredient weight% Range (% by weight) water 99.0 95.1 to 99.9 Spices 0.5 0.05 to 1.5 Surfactant ^* 0.5 0.05 to 2.0 Ethanol or isopropanol 0 Random amount to 4% Solvent (e.g. BPP) 0 Random amount to 4% Hydrogen peroxide 0 Random amount to 4% ^* pH range is about 6 to about 8.

Example IV

Spot cleaning composition

Preferably, with a dispenser as defined above and TBAL or poly-HIPE foam stain receptor, a spot cleaning composition for use in the present invention is prepared as follows:

ingredient Anionic Composition (%) Hydrogen peroxide 1.000 Amino tris (methylene phosphonic acid) ^* 0.0400 Butoxypropoxypropanol (BPP) 2.000 NH ₄ Coconut E ₁ S 0.285 Dodecyldimethylamine oxide 0.031 Magnesium chloride 0.018 Magnesium sulfate 0.019 Hydrotropes, fragrances, and other trace substances 0.101 Carton preservative 0.0003 Water (deionized or distilled) 96.5 Target pH 6.0 ^* Stabilizer for Hydrogen Peroxide

Preferably, in order to minimize the potential for dye damage as described above, the H ₂ O ₂ -containing preliminary spotting composition may contain anionic or nonionic surfactant in an amount less than the amount of H ₂ O ₂ (from the composition By weight). Preferably, the weight ratio range of surfactant: H ₂ O ₂ is about 1:10 to about 1: 1.5, most preferably about 1: 4 to about 1: 3.

Claims (36)

(A) placing the textile product in a container having at least one wall defining an opening and an empty space therein; (B) raising the temperature and relative humidity of the air in the empty space inside the container to the predetermined first temperature and the predetermined first relative humidity for a predetermined first period of time; And (C) changing at least one of the temperature or relative humidity of the air in the empty space inside the container at the end of the first period to the predetermined second temperature and the predetermined second relative humidity for a predetermined second period of time; , Method of processing textile products. The method of claim 1 wherein the fabric is contacted with the pretreatment composition prior to being placed in the container of step (a). The method of claim 1 wherein the contact is by spraying. The method of claim 1 wherein steam is used to raise the temperature and relative humidity of the air in the void inside the vessel. The method of claim 1, further comprising lowering the temperature in the interior empty space to a third temperature of less than about 45 ° C. 3. The container of claim 1 wherein the container is Heating element (a), Moisture supply (b), Vent and / or filter (c) and Further comprising an air circulation device (d). 7. The method of claim 6, wherein the vessel further comprises an active thermostat capable of varying and maintaining the air temperature in the void inside the vessel. The method of claim 6, wherein the vessel further comprises a manual humidity regulator capable of varying and maintaining the relative humidity of the air in the void inside the vessel. The method of claim 6, wherein the exhaust port is always open. The method of claim 4 wherein the vapor introduced into the void inside the vessel comprises water and fragrances. 7. The method of claim 6 wherein the air circulation device is a fan and the fan inlet is in an empty space inside the container such that at least a portion of the air in the empty space of the container is recycled. The method of claim 1, wherein the first temperature is at least about 45 ° C. and the first relative humidity is at least about 20%. The method of claim 1 wherein the second temperature exceeds T as defined by Equation 1: Equation 1 In Equation 1 above, RH ₂ is the second relative humidity (%). The method of claim 13, wherein RH ₂ is at least 50%. The method of claim 13, wherein the second temperature is less than about 90 ° C. 15. (A) placing the textile product in a container having at least one wall defining an opening and an empty space therein; (B) introducing ozone into the empty space therein for a first predetermined period; And (C) changing at least one of the temperature or relative humidity of the air in the empty space inside the container at the end of the first period to a predetermined second temperature and a predetermined second humidity for a predetermined second period of time, How to treat textile products. The method of claim 16, wherein the first temperature is at least about 45 ° C. 18. 18. The method of claim 16 or 17, wherein ozone is generated by an ozone source in the void inside the vessel. 19. The method of claim 18, wherein the ozone source is an ultraviolet lamp or a high voltage source. The method of claim 18, wherein the ozone provides the treated fabric with an advantage selected from malodor reduction or removal, stain removal, sanitisation, and combinations thereof. The method of claim 16 wherein steam is used to change the temperature and relative humidity of the air in the void inside the vessel. The method of claim 16, further comprising a cooling step after the second period of time, wherein the temperature in the internal void space is lowered below 45 ° C. 18. The container of claim 16 wherein the container is Heating element (a), Moisture supply (b), Vent and / or filter (c) and Further comprising an air circulation device (d). 24. The method of claim 23, wherein the vessel further comprises an active temperature controller capable of varying and maintaining the air temperature within the void inside the vessel. The method of claim 23, wherein the vessel further comprises a manual humidity controller capable of varying and maintaining the relative humidity of the air in the void inside the vessel. The method of claim 23, wherein the exhaust port is always in a closed state. 22. The method of claim 21 wherein the vapor introduced into the void inside the vessel comprises water and fragrances. The method of claim 23 wherein the air circulation device is a fan and the fan inlet is in an empty space inside the container such that at least a portion of the air in the empty space of the container is recycled. 29. The method of claim 28, wherein the air circulation device provides an air velocity around the garment at 0.05-10 ^m · s ⁻¹ . The method of claim 16, wherein the second temperature exceeds T as defined by Equation 1 below: Equation 1 T = 60- (0.17 * RH ₂ ) In Equation 1 above, RH ₂ is the second relative humidity (%). The method of claim 30, wherein RH ₂ is at least 50%. The method of claim 16, wherein the second temperature is less than about 90 ° C. 18. The method of claim 1 or 16, wherein the cartridge containing the cleaning and refreshing composition is introduced into an empty space inside the container, and the cleaning and refreshment composition is discharged from the cartridge into the empty space inside the container. The method of claim 16, wherein the container further comprises a filter. 35. The method of claim 34, wherein the filter is very close to the pan. The method of claim 1 or 16, wherein the garment is stretched or stretched before initiation of the circulation.