KR100411685B1 - The Active Soluble Cleaning Composite of Natural State Using Soybean Fatty acids And The Making Method Thereof - Google Patents

The Active Soluble Cleaning Composite of Natural State Using Soybean Fatty acids And The Making Method Thereof Download PDF

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KR100411685B1
KR100411685B1 KR10-2002-0064793A KR20020064793A KR100411685B1 KR 100411685 B1 KR100411685 B1 KR 100411685B1 KR 20020064793 A KR20020064793 A KR 20020064793A KR 100411685 B1 KR100411685 B1 KR 100411685B1
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weight
parts
fatty acid
lecithin
soybean fatty
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KR20030035929A (en
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최광화
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(주)그린앤크린
최광화
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/40—Products in which the composition is not well defined
    • C11D7/44—Vegetable products
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/26—Organic compounds containing oxygen
    • C11D7/261—Alcohols; Phenols
    • C11D7/262—Alcohols; Phenols fatty or with at least 8 carbon atoms in the alkyl or alkenyl chain
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/26—Organic compounds containing oxygen
    • C11D7/265—Carboxylic acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/32—Organic compounds containing nitrogen
    • C11D7/3263—Amides or imides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/36—Organic compounds containing phosphorus

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Abstract

본 발명은 대두지방산과 레시틴을 이용한 활성 수용성 천연세제 조성물 및 그 제조방법에 관한 것으로, 대두지방산이나 미강지방산 등 천연식물성지방산, 레시틴 및 알칸올 아미드에 대하여 고급 알콜, 다가 알콜 등 유기용매를 혼합하여 고속으로 교반한 후, 다시 특수 활성분 및 기타 첨가제로 검화공법을 적용하여 브라운 운동을 할 수 있는 크기의 미세한 세제분자를 형성하여, 이를 수분과 PH조절을 통해 중성상태나 알카리상태로 제조하는 것을 특징으로 한다. 상기 세제 조성물에 따른 세제분자 또는 그 미셀은 물 속에서 브라운 운동에 의해 스스로 강력한 침투력과 세척력 및 유지분해력을 발휘하며 이에 따라 공해유발없는 청정성을 구현할 수 있다.The present invention relates to an active water-soluble natural detergent composition using soybean fatty acid and lecithin, and a method for preparing the same. An organic solvent such as a higher alcohol or a polyhydric alcohol is mixed with natural vegetable fatty acids such as soybean fatty acid or rice bran fatty acid, lecithin and alkanol amide. After stirring at high speed, it is applied to the saponification method with special active ingredients and other additives to form fine detergent molecules that can brown movement, and to prepare them in neutral or alkaline state by controlling moisture and PH. It features. Detergent molecules or micelles according to the detergent composition exerts its own strong penetration and cleaning power and oil-degrading power by the Brownian movement in water, thereby realizing cleanliness without pollution.

본 발명에 따른 활성 수용성 천연세제는 대두지방산 14 ~ 22 중량부, 레시틴 2 ~ 4 중량부, 알칸올아미드 6 ~ 14 중량부, 이소옥틸페녹시 폴리옥시에톡시 에탄올 15 중량부, 증류수 42 중량부, p-tert-옥시페녹시 폴리에톡시 에탄올 10 중량부 및 에틸렌 디아민 테트라아세트산 3 중량부로 구성된다.Active water-soluble natural detergent according to the present invention 14 to 22 parts by weight of soybean fatty acid, 2 to 4 parts by weight of lecithin, 6 to 14 parts by weight of alkanolamide, 15 parts by weight of isooctylphenoxy polyoxyethoxy ethanol, 42 parts by weight of distilled water 10 parts by weight of p-tert-oxyphenoxy polyethoxy ethanol and 3 parts by weight of ethylene diamine tetraacetic acid.

Description

대두지방산과 레시틴을 이용한 활성 수용성 천연세제 조성물 및 그 제조방법{The Active Soluble Cleaning Composite of Natural State Using Soybean Fatty acids And The Making Method Thereof}Active Soluble Cleaning Composite of Natural State Using Soybean Fatty acids And The Making Method Thereof}

본 발명은 순 식물성 대두지방산과 레시틴을 이용한 활성 수용성 천연세제 조성물 및 그 제조방법에 관한 것이다.The present invention relates to an active water-soluble natural detergent composition using pure vegetable soybean fatty acid and lecithin, and a method of preparing the same.

일반적으로, 대부분의 합성세제는 프로필렌 사합체의 폴리프로필렌 벤젠 술포네이트 유형의 경성화합물에 의한 것으로서 환경오염은 물론이고 인체에도 심각한 폐해를 유발하고 있어 그 사용이 규제되고 있는 실정이다.In general, most synthetic detergents are caused by a polypropylene benzene sulfonate-type hard compound of propylene tetramer, which causes serious harm to humans as well as environmental pollution, and its use is regulated.

따라서, 리니어 벤젠 술포네이트 유형의 연성합성세제가 대안으로 제시되기도 하였으나, 수중분해도의 우수성에도 불구하고 수질에 치명적인 오염물의 배출이 문제되었다. 또한, 첨가제를 요하는 황산염, 술폰산염 세제는 서브미크논 탄산칼슘이나 니트릴로 트리아세트산, 헥사메틸렌 디아민 테트라아세트산, 디에틸렌 트리아민 펜타아세트산을 유출시켰다. 이에 따라 이들을 대체할 친환경적 성질의 천연세제가 절실히 요구되고 있는 실정이다.Therefore, although a flexible synthetic detergent of the linear benzene sulfonate type has been proposed as an alternative, the emission of fatal contaminants in water quality has been a problem in spite of the superiority in the degree of decomposition in water. Moreover, the sulfate and sulfonate detergent which require an additive outflowed triacetic acid, hexamethylene diamine tetraacetic acid, and diethylene triamine pentaacetic acid by submicron calcium carbonate and nitrile. Accordingly, there is an urgent need for environmentally friendly natural detergents to replace them.

특히, 기존의 합성세제는 일반적으로 탄화수소계의 지방분자로 구성된 유친화성(油親和性)구조와 황산염으로 구성된 수친화성(水親和性)구조의 양친화성(兩親和性) 분자구조를 가지고 있으며, 이러한 분자구조의 특성 및 이 특성에 따라 커질 수밖에 없는 분자의 질량 때문에, 기존의 합성세제분자 또는 그 미셀은 물 속에서 스스로 운동력을 발생하는 브라운 운동을 활발히 진행하지 못하였다.In particular, conventional synthetic detergents generally have an affinity molecular structure composed of hydrocarbon-based fatty molecules and an affinity structure composed of sulfates and a water-compatible structure composed of sulfates. Due to the characteristics of the molecular structure and the mass of the molecules that can only be enlarged according to these characteristics, the existing synthetic detergent molecules or micelles could not actively proceed with the Brownian movement that generates kinetic power in water.

일반적으로 합성세제에 의한 세척작용은 세제분자의 유친화성 구조가 오물에 접촉하여 달라붙거나, 오물에 침투한 후 오물과 함께 세척대상물로부터 떨어져 나가는 방식으로 진행된다.In general, the washing action by the synthetic detergent proceeds in such a way that the affinity structure of the detergent molecule adheres to the dirt and sticks to it, or penetrates the dirt and then moves away from the washing object together with the dirt.

따라서, 합성세제분자가 세척대상물에 붙어있는 오물과 접촉하고 침투할 확률을 높이기 위해서는 공해의 주범인 거품이 많이 나야 하고, 또한 휘젓기, 비비기, 두드리기 등 외부의 물리적인 힘을 통하여 세제분자와 오물과의 접촉도 활발히 할 필요가 있다. 나아가 오물에 침투한 세제분자를 오물과 함께 세척대상물로부터 떼어내고, 분산시키고, 또 물 속에 확산시키는 세척력을 발생시키기 위해서는 또다시 휘젓기, 비비기, 두드리기 등 외부의 물리적인 힘을 필요로 한다.Therefore, in order to increase the probability that synthetic detergent molecules come into contact with and penetrate the dirt attached to the object to be washed, a lot of bubbles, which are the main culprit of pollution, must be produced, and the detergent molecules, dirt and It is also necessary to actively contact. Furthermore, in order to generate the cleaning force to remove, disperse, and diffuse the detergent molecules infiltrated with the dirt from the object to be washed with the dirt, external physical forces such as stirring, rubbing, and tapping are required again.

따라서, 기존의 합성세제는 세탁기의 회전력이나, 인력으로 행해지는 비비기, 문지르기, 두드리기 등 외부의 물리적인 힘이 있어야만 세척력이 발생하게 되고, 이에 따라 기존의 합성세제로 인하여 발생하는 거품 및 합성세제에 사용되는 각종 화합물은 환경 및 인체에 악영향을 미치는 문제점이 있었다.Therefore, the existing synthetic detergents are required to have external physical forces, such as rubbing, rubbing, tapping, etc., which are performed by the rotational force of the washing machine or by manpower, and thus the washing force is generated. Accordingly, foam and synthetic detergent generated by the conventional synthetic detergents are generated. Various compounds used in the problem had a bad effect on the environment and the human body.

본 발명은 상기와 같은 문제점을 해결하기 위하여 안출된 것으로서, 본 발명의 목적은 피부를 비롯해서 각종 유·무기물질 표면의 오염을 용이하게 제거하며,침투, 보습, 유화, 분산, 세정, 분해 등의 복합적인 기능을 포함하는 세제 및 그 제조방법을 제공하는 것이다.The present invention has been made to solve the above problems, the object of the present invention is to easily remove the contamination of the surface of various organic and inorganic substances, including the skin, such as penetration, moisturizing, emulsification, dispersion, cleaning, decomposition It is to provide a detergent and a method of manufacturing the same containing a complex function.

상기와 같은 본 발명의 목적은, 천연 대두지방산이나 미강지방산 등 천연식물성지방산, 레시틴 및 알칸올 아미드에 고급 알콜이나 다가 알콜 등 유기용매를 혼합하여 고속으로 교반한 후, 여기에 다시 특수 활성분 및 기타 첨가제로 검화공법에 적용하여 브라운 운동을 할 수 있는 크기의 미세한 세제분자를 형성하여, 이를 수분과 PH조절을 통해 중성상태나 알카리상태로 제조함으로써 달성된다.The object of the present invention as described above, the natural vegetable fatty acid such as natural soybean fatty acid and rice bran fatty acid, lecithin and alkanol amide mixed with an organic solvent such as higher alcohol or polyhydric alcohol and stirred at a high speed, and then added to the special active ingredient and It is achieved by forming a fine detergent molecule of a size capable of brown movement by applying to the saponification method with other additives, and manufacturing it in a neutral state or an alkaline state through controlling moisture and PH.

일반적으로, 식물성 지방에 레시틴(Lecithin)을 혼합하여 교반하면, 식물성지방 분자는 그 구조의 일부가 절단되어 수용화(水溶化)된다. 예를 들어, 식물성 지방과 계란 노른자를 혼합하여 교반하면, 식물성지방 분자는 계란의 노른자 속에 들어있는 레시틴에 의해 그 분자구조의 일부가 절단되어 마요네즈와 같은 식품이 된다. 이 때 식물성지방 대신 식물성지방산을 이용하는 경우에도 상기와 마찬가지로 분자구조의 절단이 용이해 진다.In general, when lecithin is mixed with vegetable fat and stirred, part of its structure is cleaved and solubilized. For example, when a mixture of vegetable fat and egg yolk is mixed and stirred, the vegetable fat molecule is cleaved by lecithin contained in the egg yolk to form a food such as mayonnaise. In this case, in the case of using vegetable fatty acid instead of vegetable fat, the molecular structure is easily cut as described above.

본 발명은 이러한 현상을 이용하여 안출된 것으로서, 본 발명에 의한 세제분자는 탄화수소계의 유친화성 분자구조를 가지고 있지만, 그 분자 또는 그 분자의 미셀은 물 속에서 활발한 브라운 운동을 함에 따라 외부의 물리적인 힘이 없이도 물 속에서 급속히 확산되며 불규칙 자유운동을 하게 된다. 따라서, 본 세제 조성물은 스스로의 운동력에 의해 세척대상물에 붙어있는 오물에 직접 접촉, 침투 및 충돌하고, 그 운동에너지나 충돌에너지에 의해 오물을 떼어 내거나 오물과 함께 떨어지게 되므로써 세척력을 발생하게 된다.The present invention has been devised using such a phenomenon, and the detergent molecule according to the present invention has a hydrocarbon-based affinity molecular structure, but the molecule or micelle of the molecule undergoes active Brownian movement in water, thereby causing external physical activity. Without the force of force, it rapidly diffuses in the water and causes irregular free movement. Therefore, the present detergent composition directly contacts, penetrates and collides with the dirt attached to the object to be cleaned by its own kinetic force, and generates cleaning power by removing the dirt or falling with the dirt by its kinetic energy or collision energy.

본 발명의 그 밖의 목적, 특정한 장점 및 신규한 특징들은 첨부한 도면들과 연관되어지는 이하의 발명의 상세한 설명과 바람직한 실시예로부터 더욱 분명해질 것이다.Other objects, specific advantages, and novel features of the present invention will become more apparent from the following detailed description of the invention and the preferred embodiments in connection with the accompanying drawings.

이하 본 발명에 따른 대두지방산과 레시틴을 이용한 활성 수용성 천연세제 조성물 및 그 제조방법의 구성에 대하여 설명하기로 한다.Hereinafter will be described the composition of an active water-soluble natural detergent composition using the soybean fatty acid and lecithin and a method for preparing the same.

상기 수용성 천연세제 조성물은 대두지방산 14 ~ 22 중량부, 레시틴 2 ~ 4 중량부, 알칸올아미드 6 ~ 14 중량부, 이소옥틸페녹시 폴리옥시에톡시 에탄올 15 중량부, 증류수 42 중량부, p-tert-옥시페녹시 폴리에톡시 에탄올 10 중량부 및 에틸렌 디아민 테트라아세트산 3 중량부로 구성된다.The water-soluble natural detergent composition is 14 to 22 parts by weight of soybean fatty acid, 2 to 4 parts by weight of lecithin, 6 to 14 parts by weight of alkanolamide, 15 parts by weight of isooctylphenoxy polyoxyethoxy ethanol, 42 parts by weight of distilled water, p- 10 parts by weight of tert-oxyphenoxy polyethoxy ethanol and 3 parts by weight of ethylene diamine tetraacetic acid.

상기 대두지방산이 22 중량부를 초과하여 배합되면 점도가 너무 높아져 스프레이 작용 등이 약해지며, 14 중량부 미만으로 배합되면 세척대상물의 생분해력이 약해진다. 마찬가지로, 상기 알칸올아미드도 14 중량부를 초과하여 배합되면 점도가 너무 높아져 스프레이 작용 등이 약해지며, 6 중량부 미만으로 배합되면 세척대상물의 생분해력이 약해진다.When the soybean fatty acid is blended in excess of 22 parts by weight, the viscosity becomes too high to weaken the spraying action, etc., and when formulated to less than 14 parts by weight, the biodegradability of the object to be cleaned is weakened. Similarly, when the alkanolamide is blended in excess of 14 parts by weight, the viscosity becomes too high to weaken the spraying action, etc., and when it is blended in less than 6 parts by weight, the biodegradability of the object to be cleaned is weakened.

본 발명에서는 천연계에서 추출한 순 식물성의 고급지방산을 이용하는데, 바람직하게는 대두지방산이 제안될 것이나 미강지방산 등 기타 식물성지방산이 그 대체품으로 제시될 수 있음도 물론이다.In the present invention, a pure vegetable high fatty acid extracted from natural origin is used. Preferably, soybean fatty acid will be proposed, but other vegetable fatty acids such as rice bran fatty acid can be presented as a substitute.

본 발명에 따른 천연세제는 이하에서 설명되는 바람직한 실시예를 통해 보다 명확하게 재현될 수 있을 것이다.Natural detergents according to the present invention will be more clearly reproduced through the preferred embodiments described below.

본 발명에 따른 활성 수용성 천연세제 조성물은, 대두지방산 14 ~ 22 중량부, 레시틴 2 ~ 4 중량부, 알칸올아미드 6 ~ 14 중량부, 이소옥틸페녹시 폴리옥시에톡시 에탄올 15중량부 및 p-tert-옥시페녹시 폴리에톡시 에탄올 10중량부에 보조 첨가제로서 에틸렌 디아민 테트라아세트산 3중량부를 첨가하고 증류수 42중량부를 첨가하여 각 공정에 따라 고속으로 교반하는 단계; 이 혼합물에 대하여 검화공법을 적용하여 브라운 운동을 할 수 있는 크기의 미세한 세제분자를 형성하는 단계; 및 상기 세제분자에 대하여 수분의 조절과 PH의 조절을 통해 중성상태나 알카리상태로 만드는 단계;를 통하여 제조된다.The active water-soluble natural detergent composition according to the present invention is 14 to 22 parts by weight of soybean fatty acid, 2 to 4 parts by weight of lecithin, 6 to 14 parts by weight of alkanolamide, 15 parts by weight of isooctylphenoxy polyoxyethoxy ethanol and p- adding 3 parts by weight of ethylene diamine tetraacetic acid as an auxiliary additive to 10 parts by weight of tert-oxyphenoxy polyethoxy ethanol, and adding 42 parts by weight of distilled water to stir at high speed according to each process; Applying a saponification method to the mixture to form fine detergent molecules of a size capable of Brownian motion; It is prepared through the step of making a neutral or alkaline state through the control of water and the pH of the detergent molecule.

본 발명에 의한 천연세제 조성물에 따른 세제분자 또는 그 미셀은 물속에서 브라운 운동에 의해 급속히 확산되어 불규칙 자유운동을 하기 때문에 스스로의 강력한 침투력 및 운동력에 의해 세척대상물에 붙어있는 오물에 직접 접촉, 침투 및 충돌을 하게 된다. 이에 따라 그 운동에너지나 충돌에너지에 의해 상기 세제분자는 오물을 떼어 내거나 오물과 함께 떨어지게 되므로써 세척력을 지니게 된다. 이러한 천연세제 조성물은 경·연수는 물론 염수에서도 세척력과 분해력의 항상성을 도모할 수 있으며, 황산염, 인산염, 질산염, 니트닐로트리아세트산 등의 유해물질을 함유치 않으므로 친 환경적인 기능을 수행한다.Detergent molecules or micelles according to the natural detergent composition according to the present invention is rapidly diffused by the Brownian movement in water and irregular free movement, so that they directly contact, infiltrate, and penetrate the dirt attached to the object to be cleaned by their strong penetration and kinetic power. There is a conflict. As a result, the detergent molecules are separated by the kinetic energy or the collision energy, or fall together with the dirt, thereby having a cleaning power. Such a natural detergent composition can promote the homeostasis of cleaning power and degradability in brine, soft water as well as salt water, and does not contain harmful substances such as sulphate, phosphate, nitrate, and nitrotriacetic acid.

표 1에서는 국가공인 시험기관인 한국생활용품시험연구원에서 본 발명에 따른 활성 수용성 천연세제 조성물에 대한 생분해 시험을 한(시험방법 KS M2714-92) 결과를 나타내었다. 표 1에 나타난 바와 같이, 상기 천연세제 조성물의 생분해도는 99%로 나타났으며, 이러한 값은 종래의 합성세제로서는 얻을 수 없는 수치이다.Table 1 shows the results of the biodegradation test (test method KS M2714-92) for the active water-soluble natural detergent composition according to the present invention at the Korea Household Products Testing Institute, a nationally recognized test institute. As shown in Table 1, the biodegradability of the natural detergent composition was found to be 99%, which is a value that cannot be obtained with a conventional synthetic detergent.

시료명Sample name 천연세제 조성물(본 발명에 따른 실시예)Natural detergent composition (Example according to the present invention) 생분해도Biodegradability 99%99% 시험방법Test Methods KS M 2714-92KS M 2714-92

상기 언급안 바와 같은 본 발명에 따른 대두지방산과 레시틴을 이용한 활성 수용성 천연세제 조성물에 의하면, 일반적인 합성세제의 경우처럼 세제분자와 오물과의 접촉확률을 높이기 위하여 거품을 낼 필요도 없고, 일반 합성세제에 첨가제로 사용하는 각종 화합물도 사용할 필요가 없기 때문에, 인체나 환경에 해로운 오염물질이 전혀 없는 친환경적인 특징이 있다.According to the active water-soluble natural detergent composition using soybean fatty acid and lecithin according to the present invention as described above, it is not necessary to bubble to increase the probability of contact between detergent molecules and dirt as in general synthetic detergents, and general synthetic detergents. Since there is no need to use various compounds used as additives to the additives, there is an environmentally friendly feature that there are no pollutants harmful to humans or the environment.

또한, 본 발명에 따른 활성 수용성 천연세제 조성물은 수용성으로 물 속에서 세제분자의 브라운운동에 의해 세척력이 발생되여 세척과 헹굼이 동시에 일어나기 때문에, 세탁기, 식기세척기 등에 사용할 경우 세척시간이 단축되어, 결과적으로 전기소모량, 물 소비량의 감소는 물론 노동시간의 감축으로 자원절약까지 기대할 수 있는 효과가 있다.In addition, since the active water-soluble natural detergent composition according to the present invention is water-soluble, the washing force is generated by the Brownian movement of the detergent molecules in water, so that washing and rinsing occur at the same time, so that the washing time is shortened when used in a washing machine or a dishwasher. As a result, the electricity consumption and water consumption can be reduced, as well as the reduction of working hours.

비록 본 발명이 상기 언급된 바람직한 실시예와 관련하여 설명되어졌지만, 발명의 요지와 범위로부터 벗어남이 없이 용도에 따라 다양한 변형을 하는 것이 가능하다. 따라서 첨부된 특허청구범위는 본 발명의 요지에 속하는 이러한 수정이나 변형을 포함한다.Although the present invention has been described in connection with the above-mentioned preferred embodiments, it is possible to make various modifications depending on the use without departing from the spirit and scope of the invention. Accordingly, the appended claims include such modifications and variations as fall within the spirit of the invention.

Claims (2)

대두지방산 14 ~ 22 중량부, 레시틴 2 ~ 4 중량부, 알칸올아미드 6 ~ 14 중량부, 이소옥틸페녹시 폴리옥시에톡시 에탄올 15 중량부, 증류수 42 중량부, p-tert-옥시페녹시 폴리에톡시 에탄올 10 중량부 및 에틸렌 디아민 테트라아세트산 3 중량부로 구성되는 것을 특징으로 하는 대두지방산과 레시틴을 이용한 활성 수용성 천연세제 조성물.14 to 22 parts by weight of soybean fatty acid, 2 to 4 parts by weight of lecithin, 6 to 14 parts by weight of alkanolamide, 15 parts by weight of isooctylphenoxy polyoxyethoxy ethanol, 42 parts by weight of distilled water, p-tert-oxyphenoxy poly An active water-soluble natural detergent composition using soybean fatty acid and lecithin, comprising 10 parts by weight of ethoxy ethanol and 3 parts by weight of ethylene diamine tetraacetic acid. 대두지방산 14 ~ 22 중량부, 레시틴 2 ~ 4 중량부, 알칸올아미드 6 ~ 14 중량부, 이소옥틸페녹시 폴리옥시에톡시 에탄올 15 중량부, 증류수 42 중량부, p-tert-옥시페녹시 폴리에톡시 에탄올 10 중량부 및 에틸렌 디아민 테트라아세트산 3 중량부로 구성된 혼합물을 충분히 교반한 후, 이를 검화공법에 적용하여 브라운 운동을 할 수 있는 크기의 미세한 세제분자로 제조하는 것을 특징으로 하는 대두지방산과 레시틴을 이용한 활성 수용성 천연세제 조성물을 제조하는 방법.14 to 22 parts by weight of soybean fatty acid, 2 to 4 parts by weight of lecithin, 6 to 14 parts by weight of alkanolamide, 15 parts by weight of isooctylphenoxy polyoxyethoxy ethanol, 42 parts by weight of distilled water, p-tert-oxyphenoxy poly Soybean fatty acid and lecithin, characterized in that the mixture consisting of 10 parts by weight of ethoxy ethanol and 3 parts by weight of ethylene diamine tetraacetic acid is sufficiently stirred, and then applied to the saponification method to prepare fine detergent molecules having a size of Brown's motion. Method for producing an active water-soluble natural detergent composition using.
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