KR880001144B1 - Colloid detergent composition and method for preparation thereof - Google Patents

Abstract

The colloid detergent composition is prepared by stirring a mixture of compounds (I) and (II) 15-40 wr.%, compound (III) 5-15 wt.%, organic solvent 15-60 wt.%, organic amine 3-10 wt.%, activator 5-10 wt.%, perfume, pigment and addition material. In formulas, R is myristil, palmitil, stearil, oleil or linoleil group; R' is caprylic, caproil or lauril group; R" is lanolin, stearil or caproil group.

Description

Colloidal cleaner composition and preparation method thereof

The present invention relates to a colloid cleaner. In particular, the present invention is to prepare a composition of the colloidal detergent of the higher fatty acids, higher alcohols, organic amines, special active ingredients, other additives and the like dispersed in a colloidal state in which a part of the constituent molecules in the organic solvent is cut and prepared at room temperature The purpose is to produce a manufacturing method that can be.

The colloidal detergent of the present invention has a strong penetrating power to easily remove dirt on the surface of various organic materials including skin, and also to wash not only the surface of inorganic metal, but also the pores of the inorganic material in the case of a porous material, and peeling dirt. It is unique in that it has the advantage of being completely cleaned even with a slight physical force (water spray level). The detergent is also a completely non-polluting agent, nonionic and low foaming. Another object of the present invention is to provide a method for producing a simple and economical composition.

Although many kinds are known as conventional detergent compositions, Igepon A is represented by cosmetic soaps, laundry soaps, and synthetic surfactants, to which various additives are added to the salts which have been salted after heat-reacting fat and oil and sodium hydroxide. Igepon; A Sulfonated fatty acid ester), Gardinol (sulfated fatty alcohol) and allyl-aryl sulfate, but soaps cannot be used in hard water, while synthetic surfactants cause pollution problems. However, the technical problem to be solved also has many more disadvantages. Accordingly, an object of the present invention is to provide a new type of detergent composition and a method for preparing the same, which are generally selected only for the advantages of both soap and synthetic surfactant, and the characteristics of the method are that the molecules are cut (dissolved by high-speed stirring). To create a colloidal state. In addition, the manufacturing method is an energy-saving manufacturing method in which a heating step and a cooling step are omitted, and all stirring, molecular cutting, mixing, and neutralization reactions are all economical manufacturing methods at room temperature.

Developing the technical gist of the present invention, (1) the partial portion utilizes the compatibility of the cleaved higher fatty acid and the higher alcohol with a certain ratio and imparts synergism of the respective cleaning powers, and (2) After dissolving it in alcohol as a solvent at room temperature, (3) improving the lipophilic properties by making a certain ratio of higher fatty acids into amidated salts with organic amines, and (4) special active ingredients and other necessary additives. The present invention relates to a colloidal detergent composition in which an alkyl group molecule is cleaved by strong stirring, and a method for producing the same.

In addition, all the stirring, mixing, and reaction is carried out at room temperature, there is no need for a process such as heating and cooling, which is an important feature of the manufacturing method.

The present invention is dissolved 15 to 40 parts by weight of fatty acids represented by the following general formula (I) and (II) in a conventional organic solvent, that is, ethyl alcohol, isopropyl alcohol, butyl alcohol, butyl cellosolve or mixtures thereof In a vessel equipped with a high speed stirrer, the mixture was stirred for 5 minutes to 15 minutes, mixed with 5-15 W of higher alcohol represented by the following general formula (III), and then stirred for 10 to 30 minutes to form an emulsion solution. Neutralize by adding 3 to 10 parts by weight of organic amine, and 5 to 10 parts by weight of active ingredient are added, and flavoring, coloring, and other additives are added as necessary to provide a colloidal detergent composition in which some molecules are cut.

Wherein R is a myristyl group, palmityl group, stearyl group, oleyl group or linoleyl group, R 'is caprylic group, caproyl group, or lauryl group, and R "is a lanolin group, a stearyl group Or a caproyl group, in particular agitation is carried out at room temperature, which typically omits the heating and cooling process to provide an industrially advantageous production method.

Organic amines that may be used in the composition include asymmetric dimethyl ethyldiamine, aurylamine, n-hexamethyleneamine, ethanolamine, diethanolamine, triethanolamine, dimethylpropylenediamine and dimethyl pentamethylenediamine, alone or in mixtures thereof. Can be used.

Special active ingredients are added at the end of the agitation, examples of which are coconut acid diethanolamide or octylphenoxyethanol, which are added and cooled. If desired, small amounts of paints, adjuvants, fragrances, milk whites, preservatives, thickeners, modifiers, thickeners, buffers and the like may be added.

The detergent of the present invention may be used as such, but may also be used as a diluent in some cases. Detergent of the present invention can be adjusted in the range of 6 to 8 by the addition of citric acid or organic amine when pH adjustment is required. The detergent is tested after washing the cleanser (eg, skin), the gloss, the sensation (surface feel of the surface), the residual components, etc. Very good.

Theoretical identification of the excellent cleaning action of the colloidal detergent according to the present invention is difficult, but in general,

1. The difference between the C ₁₀ -C ₁₄ ratio and the C ₁₄ -C ₂₀ detergency in higher fatty acids is complementary and they are dispersed in a suspended state in which the alkyl group is cleaved by strong stirring in the solvent,

2. The synergy of washing force due to the specific ratio of the mixing ratio of higher fatty acids and higher alcohols as a whole (3: 1 to 2: 1) and the penetration force due to the cleavage of molecules of a certain ratio are improved.

3. The lipophilic property of the salt or amide bond which is made by making the carboxyl group of higher fatty acid react with organic amine at normal temperature improves,

4. It is considered to be due to the combined action of organic solvents and other active ingredients.

On the other hand, the colloidal detergent of the present invention can be used in various ways, but the typical method is a creamy or concentrated liquid on the surface with dirt and wiped off after spraying water (water spray), the cleaning is simply finished, the action at this time When the silver detergent comes into contact with water, the dilution effect starts the molecules of the concentrated detergent, and the molecules of the detergent penetrate into the molecules and into the air of the detergent. Its exfoliation effect is exceptional, so it can be cleaned even with a slight physical force. In some cases, it can be completely cleaned even by spraying degree. In addition, it can provide inexpensive detergent because industrial raw materials are inexpensive. There is also an advantage.

The following is not intended to limit the spirit and spirit of the present invention, but examples for detailed implementation of the present invention.

Example 1

20 parts by weight of stearic acid, 5 parts by weight of oleic acid, 5 parts by weight of caprylic acid were added to a vessel equipped with a high speed stirrer, and 32 parts by weight of isoproyl alcohol and 10 parts by weight of ethyl alcohol were stirred for 10 minutes at room temperature to give a uniform suspension. Make 10 parts by weight of stearyl alcohol was added thereto, and the mixture was stirred at high speed for about 20 minutes to give a coloida state. After adding 8 parts by weight of coconut acid diethanol amide as a special active ingredient, 10 parts by weight of asymmetric dimethyl ethylene diamine is added to the resulting colloidal solution and stirred for 10 minutes to form a creamy detergent.

The cream prepared above was confirmed to have a strong cleaning action when used on the hair, skin, clothing. In addition, when applied to a metal surface, it became a pure white glossy metal surface (like a surface polished with an abrasive).

Example 2

In the same manner as in Example 1, 10 parts by weight of stearic acid, 15 parts by weight of palmitic acid, 20 parts by weight of isopropyl alcohol, 30 parts by weight of ethyl alcohol, 10 parts by weight of lauryl alcohol, 10 parts by weight of ethylene diamine, coconut A mucus-like detergent is prepared by using 5 parts by weight of the acid diethanolamide as a composition.

This mucus detergent is rubbed onto the surface of organic matter (eg, wooden furniture, etc.), and then washed with water to obtain a clean, glossy surface. In addition, washing with water after applying grease on the skin (eg grease) will completely remove and clean the grease (eg black grease) that has penetrated the skin.

Claims (6)

15 to 40 parts by weight of the higher fatty acids represented by the following general formulas (I) and (II), 5 to 15 parts by weight of the higher alcohols represented by the following general formula (III), 15 to 60 parts by weight of the organic solvent, 3 to organic amines A colloidal detergent composition comprising cutting a portion of a molecule by agitating a mixture of 10 parts by weight, 5 to 10 parts by weight of an active ingredient, an appropriate amount of aroma, an appropriate amount of a dye, and an appropriate amount of other additives.

Wherein R is myristyl group, palmityl group, stearyl group, oleyl group or linoleyl group, R 'is caprylic group, carpoyl group or lauryl group, and R "is lanolin group, stearyl group Or a caproyl group. The colloidal detergent composition of claim 1, wherein the higher fatty acid is one or more fatty acids selected from tolu fatty acid myristic acid, palmitic acid, stearic acid, oleic acid, and linoleic acid. The colloidal detergent composition according to claim 1, wherein the higher alcohol is lanolin alcohol, stearyl alcohol, caproyl alcohol, or a mixture thereof. The detergent composition according to claim 1, wherein the active composition is coconut acid diethanolamide or octylphenoxy ethanol. 15 to 40 parts by weight of the higher fatty acids represented by the following general formulas (I) and (II) are added to 15 to 60 parts by weight of an organic solvent, and stirred at high speed for 5 to 15 minutes to form a suspension, which is represented by the following general formula (III) 5 to 15 parts by weight of higher alcohol was added to make an emulsion solution by high-speed stirring at room temperature for 10 to 30 minutes, and then 3 to 10 parts by weight of organic amine and 5 to 10 parts by weight of active ingredient were added. A method for producing a colloidal detergent in which some molecules are cleaved, wherein another additive is added. The method for preparing a colloidal detergent according to claim 5, wherein all the stirring, mixing, and reaction steps are performed at room temperature.