KR100409023B1 - Cosmetic composition for oil cake - Google Patents

Cosmetic composition for oil cake Download PDF

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Publication number
KR100409023B1
KR100409023B1 KR10-2001-0043668A KR20010043668A KR100409023B1 KR 100409023 B1 KR100409023 B1 KR 100409023B1 KR 20010043668 A KR20010043668 A KR 20010043668A KR 100409023 B1 KR100409023 B1 KR 100409023B1
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oil
weight
parts
cosmetic composition
powder
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KR10-2001-0043668A
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Korean (ko)
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KR20030008766A (en
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김상준
김형진
유영창
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주식회사 엘지생활건강
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/891Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/895Polysiloxanes containing silicon bound to unsaturated aliphatic groups, e.g. vinyl dimethicone
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02Preparations containing skin colorants, e.g. pigments

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Cosmetics (AREA)

Abstract

본 발명은 오일케익용 화장료 조성물에 관한 것으로서, 본 발명에 따른 오일케익용 화장료 조성물은 분체 45 내지 60중량부, 오일 40 내지 55중량부 및 소르비탄 모노스테아레이트, 소르비탄 세스퀴올레이트 및 이들의 혼합물로 이루어진 군으로부터 선택된 계면활성제 0.5 내지 5중량부를 포함하되, 상기 분체는 디메치콘/비닐디메치콘 크로스폴리머 0.5 내지 5중량부를 함유하고, 상기 오일은 휘발성 실리콘 오일 5 내지 40중량부를 함유하는 것을 특징으로 한다. 본 발명의 화장료 조성물은 고온 유동성이 우수할 뿐만 아니라, 화장 후 휘발성 실리콘 오일이 휘발되어 번들거림이 적고 화장 지속성 및 사용감이 매우 양호하다.The present invention relates to a cosmetic composition for oil cakes, the cosmetic composition for oil cakes according to the invention powder 45 to 60 parts by weight, oil 40 to 55 parts by weight and sorbitan monostearate, sorbitan sesquioleate and their 0.5 to 5 parts by weight of a surfactant selected from the group consisting of mixtures, wherein the powder contains 0.5 to 5 parts by weight of dimethicone / vinyldimethicone crosspolymer, and the oil contains 5 to 40 parts by weight of volatile silicone oil. It is done. The cosmetic composition of the present invention is not only excellent in high temperature fluidity, but also volatile silicone oil is volatilized after make-up, so there is little bleeding, and makeup sustainability and feeling are very good.

Description

오일케익용 화장료 조성물{Cosmetic composition for oil cake}Cosmetic composition for oil cake {Cosmetic composition for oil cake}

본 발명은 오일케익용 화장료 조성물에 관한 것으로서, 보다 상세하게는 고온 유동성이 우수할 뿐만 아니라 번들거림이 적고 화장 지속성 및 사용감이 양호한 오일케익용 화장료 조성물에 관한 것이다.The present invention relates to a cosmetic composition for oil cakes, and more particularly, to a cosmetic composition for oil cakes, which has excellent high temperature fluidity, less bleeding, and good makeup persistence and usability.

오일케익은 크게 오일부와 분체부로 구성되는데, 통상적으로 오일부에 분체부를 분산시킨 후 유용성을 부여하기 위하여 가열한 다음, 접시에 몰딩하여 고형화 시키는 방법으로 제조된다. 이렇게 제형한 오일케익은 분체 화장료에 비하여 피부 부착성, 피부 결점에 대한 커버력이 양호하며, 발수능력이 우수한 화장막을 형성한다는 장점이 있어 널리 사용되고 있다. 그러나, 오일케익은 제조시 필요한 고온 유동성을 확보하기 위하여 오일부의 함량을 40중량부 이상으로 유지시켜야 하는데, 이러한 높은 오일 함량으로 인하여 화장시 번들거림 현상이 발생하며, 얼굴에서 분비되는 피지에 의해 화장막이 쉽게 흐트러지는 단점이 있다.The oil cake is largely composed of an oil part and a powder part, and is usually prepared by dispersing the powder part in an oil part, heating it to provide usability, and then molding the plate and solidifying the plate. The oil cake formulated in this way has a good skin adhesiveness, a good coverage for skin defects, and a cosmetic film having excellent water repellency compared to powder cosmetics. However, in order to secure the high temperature fluidity required during manufacturing, the oil cake must maintain the content of the oil portion of 40 parts by weight or more.Because of the high oil content, the lubrication phenomenon occurs during makeup, and the makeup film is formed by sebum secreted from the face. It has the disadvantage of easily distracting.

이러한 단점을 개선하기 위하여 미국 특허 제5,645,903호에는 수중유(Oil in Water) 유화형 고형 화장료 조성물을, 미국 특허 제5,362,482호에는 유중수(Water in Oil) 유화형 고형 화장료 조성물을 개시하고 있고, 미국 특허 제5,266,321호에는 실리콘 겔을 이용하여 높은 오일 함유량을 유지시키면서도 번들거림이나 들뜸 현상을 개선하는 방법이 개시되어 있다. 그러나, 이러한 조성물들은 몰딩시 고온 유동성을 확보하기 위하여 30중량부 이하로 분체부의 함량을 낮춰야 한다. 따라서, 분체부에 의한 색상 부여 및 결점 은폐 등의 충분한 화장 효과를 발휘하지 못하는 단점이 있다.In order to remedy this disadvantage, US Patent No. 5,645,903 discloses an oil in water emulsion type solid cosmetic composition, US Patent No. 5,362,482 discloses a Water in Oil emulsion type solid cosmetic composition, and Patent No. 5,266,321 discloses a method for improving bleeding or lifting while maintaining a high oil content using a silicone gel. However, these compositions should be lowered to 30 parts by weight or less in order to ensure high temperature fluidity during molding. Therefore, there is a disadvantage in that it does not exhibit sufficient cosmetic effects such as color impartment and defect concealment by the powder part.

따라서, 본 발명이 이루고자 하는 기술적 과제는 상기 문제점을 해결하여 고온 유동성이 우수하면서도 충분한 함량의 분체를 함유하므로써 화장 효과가 양호하며 번들거림이 적고 화장 지속성 및 사용감이 매우 양호한 오일케익용 화장료 조성물을 제공하는데 있다.Accordingly, the technical problem to be achieved by the present invention is to provide a cosmetic composition for oil cake having a good makeup effect, less bleeding and very good makeup persistence and usability by solving the above problems by containing powder of sufficient high temperature fluidity and sufficient content. have.

상기와 같은 목적을 달성하기 위해, 본 발명은 분체 45 내지 60중량부, 오일 40 내지 55중량부 및 소르비탄 모노스테아레이트, 소르비탄 세스퀴올레이트 및 이들의 혼합물로 이루어진 군으로부터 선택된 계면활성제 0.5 내지 5중량부를 포함하되, 상기 분체는 디메치콘/비닐디메치콘 크로스폴리머 0.5 내지 5중량부를 함유하고, 상기 오일은 휘발성 실리콘 오일 5 내지 40중량부를 함유하는 것을 특징으로 하는 오일케익용 화장료 조성물을 제공한다.In order to achieve the above object, the present invention is 45 to 60 parts by weight of powder, 40 to 55 parts by weight of oil and sorbitan monostearate, sorbitan sesquioleate and a mixture selected from the group consisting of 0.5 to 0.5 5 parts by weight, wherein the powder contains 0.5 to 5 parts by weight of dimethicone / vinyl dimethicone crosspolymer, and the oil provides 5 to 40 parts by weight of a volatile silicone oil. .

본 발명에 따른 화장료 조성물에 있어서, 휘발성 실리콘 오일로는 휘발성이 높은 옥타메틸사이클로테트라실록산이나 데카메틸사이클로펜타실록산을 단독으로 또는 이들을 혼합하여 사용하는 것이 바람직하다.In the cosmetic composition according to the present invention, as the volatile silicone oil, it is preferable to use volatile octamethylcyclotetrasiloxane or decamethylcyclopentasiloxane, alone or in combination thereof.

이하, 본 발명을 상세히 설명한다.Hereinafter, the present invention will be described in detail.

본 발명의 오일케익용 화장료 조성물은 오일 40 내지 55중량부를 함유하는데, 이 가운데 5 내지 50중량부는 휘발성 실리콘 오일이다. 오일의 함량은 일반적인 오일케익과 유사한 범위이므로 몰딩시 충분한 유동성을 부여되며, 휘발성 실리콘 오일이 화장시 휘발되므로써 화장 후 번들거림이 적고 화장 지속성이 양호하게 된다. 휘발성 실리콘 오일의 함량이 5중량부 미만이면 휘발성 오일의 함량이 지나치게 적어 번들거림 개선 등의 효과가 나타나지 않으며, 40중량부를 초과하면 피부가 당기는 문제점이 있다. 오일로는 페이스트상 오일, 액상 오일, 고체상 오일(왁스) 등이 사용될 수 있는데, 통상적으로 탄화수소계, 고급 지방산, 고급 지방산 에스테르, 고급 알코올, 실리콘계 오일, 식물성 오일 등이 사용된다. 또한, 휘발성 실리콘 오일로는 환상실리콘형이 사용되는데, 특히, 휘발성이 높은 옥타메틸사이클로테트라실록산이나 데카메틸사이클로펜타실록산을 단독으로 또는 이들을 혼합하여 사용할 수 있다.The cosmetic composition for oil cake of the present invention contains 40 to 55 parts by weight of oil, of which 5 to 50 parts by weight is volatile silicone oil. Since the oil content is in a range similar to that of a general oil cake, sufficient fluidity is imparted during molding, and since volatile silicone oil is volatilized during makeup, there is little bleeding after makeup and makeup sustainability is good. If the content of the volatile silicone oil is less than 5 parts by weight, the content of the volatile oil is too small, there is no effect such as lubrication improvement, if the content exceeds 40 parts by weight there is a problem in pulling the skin. As the oil, a paste oil, a liquid oil, a solid oil (wax) and the like may be used. Typically, hydrocarbon-based, higher fatty acids, higher fatty acid esters, higher alcohols, silicone oils, vegetable oils, and the like are used. In addition, a cyclic silicone type is used as the volatile silicone oil. In particular, volatile octamethylcyclotetrasiloxane or decamethylcyclopentasiloxane may be used alone or in combination thereof.

본 발명의 오일케익용 화장료 조성물에 함유되는 휘발성 실리콘 오일은 일반적인 탄화수소계, 에스테르계 오일 등에 비하여 고온 유동성이 떨어지므로, 이를 제형화하기 위해서 적절한 계면활성제를 사용하였다. 즉, 계면활성제는 그 종류에 따라 고온 유동성과 색소 분산성이 크게 차이가 나는데, 소르비탄 모노스테아레이트나 소르비탄 세스퀴올레이트는 폴리옥시에틸렌 메틸폴리실록산, 폴리소르베이트60, 폴리소르베이트20 등의 계면활성제와는 달리 고온 유동성과 색소 분산성이 우수하므로, 본 발명에 따른 화장료 조성물에 0.5 내지 5중량부를 첨가하면 충분한 고온 유동성과 색소분산성을 부여할 수 있다.Since the volatile silicone oil contained in the cosmetic composition for oil cake of the present invention has a high temperature fluidity inferior to general hydrocarbon-based and ester-based oils, an appropriate surfactant was used to formulate it. In other words, the surfactants differ greatly in high temperature fluidity and pigment dispersibility according to their type, and sorbitan monostearate and sorbitan sesquioleate are polyoxyethylene methyl polysiloxane, polysorbate 60, polysorbate 20, and the like. Unlike the surfactant, since it is excellent in high temperature fluidity and pigment dispersibility, by adding 0.5 to 5 parts by weight of the cosmetic composition according to the present invention, sufficient high temperature fluidity and pigment dispersibility can be imparted.

또한, 본 발명에 따른 오일케익용 화장료 조성물은 충분한 화장효과를 나타낼 수 있도록 분체 45 내지 60중량부를 함유한다. 분체로는 탈크, 마이카, 카올린, 탄산칼슘 등의 체질안료, 산화티탄, 산화아연과 같은 백색안료, 황산화철, 적산화철, 흑산화철, 군청 등의 착색안료, 운모티탄, 산화철 처리 운모티탄 등의 진주광택안료, 부드러운 사용감과 피지 조절 등을 목적으로 하는 폴리메틸메타크릴레이트 분체, 나일론 가루, 셀룰로오스, 녹말, 실크, 실리카 등의 원료가 사용될 수 있다. 다만, 오일에 함유된 휘발성 실리콘이 화장시 피부에서 빠르게 휘발되므로써 오일부의 함량이 감소하여 퍼짐성과 사용감이 저하되는 문제점이 있으므로, 분체 중에 디메치콘/비닐디메치콘 크로스폴리머 0.5 내지 5중량부를 첨가하여 이러한 문제점을 해결하였다. 즉, 디메치콘/비닐디메치콘 크로스폴리머는 탄성이 우수하여 분체에 첨가시 피부와의 마찰을 줄이고 부드러운 사용감을 부여하여 준다.In addition, the cosmetic composition for oil cake according to the present invention contains 45 to 60 parts by weight of powder to exhibit a sufficient cosmetic effect. Powders include sieving pigments such as talc, mica, kaolin and calcium carbonate, white pigments such as titanium oxide and zinc oxide, colored pigments such as iron sulfate, iron oxide, black iron oxide and ultramarine, mica titanium and iron oxide treated mica titanium. Raw materials such as pearlescent pigment, polymethyl methacrylate powder, nylon powder, cellulose, starch, silk, silica, etc. for the purpose of soft feeling and sebum control can be used. However, since the volatile silicone contained in the oil is rapidly volatilized from the skin during makeup, there is a problem in that the content of the oil portion decreases and the spreadability and the feeling of use decrease, so that 0.5 to 5 parts by weight of dimethicone / vinyl dimethicone crosspolymer is added to the powder. I solved the problem. That is, the dimethicone / vinyl dimethicone crosspolymer is excellent in elasticity, thereby reducing friction with the skin and giving a soft feeling when added to the powder.

이하, 본 발명을 구체적으로 설명하기 위해 실시예를 들어 상세하게 설명하기로 한다. 그러나, 본 발명에 따른 실시예들은 여러 가지 다른 형태로 변형될 수 있으며, 본 발명의 범위가 아래에서 상술하는 실시예들에 한정되는 것으로 해석되어져서는 안된다. 본 발명의 실시예들은 당업계에서 평균적인 지식을 가진 자에게 본 발명을 보다 완전하게 설명하기 위해서 제공되어지는 것이다.Hereinafter, the present invention will be described in detail with reference to Examples. However, embodiments according to the present invention can be modified in many different forms, the scope of the present invention should not be construed as limited to the embodiments described below. Embodiments of the present invention are provided to more completely explain the present invention to those skilled in the art.

실시예 1Example 1

하기 표 1에 기재된 조성에 따라 분체부를 분쇄기에서 2회 분쇄하여 75~80℃로 가열한 오일부에 첨가하였다. 이어서, 이 혼합물을 디스퍼형 믹서를 이용하여1200rpm으로 2분간 교반하고, 75~80℃로 가열, 탈포한 후 접시에 몰딩하여 오일케익을 제조하였다.According to the composition shown in Table 1, the powder portion was pulverized twice in a pulverizer and added to the oil portion heated to 75 ~ 80 ℃. Subsequently, the mixture was stirred for 2 minutes at 1200 rpm using a disper mixer, heated to 75-80 ° C., degassed, and molded into a dish to prepare an oil cake.

비교예 1 내지 3Comparative Examples 1 to 3

하기 표 1에 기재된 성분과 함량을 참조하여, 상기 실시예 1과 동일한 방식으로 제조하였다.It was prepared in the same manner as in Example 1 with reference to the components and contents shown in Table 1 below.

원료명(중량부)Raw material name (weight part) 실시예Example 비교예Comparative example 1One 1One 22 33 세레신 왁스Ceresin wax 33 33 33 33 이소스테아릴 이소스테아레이트Isostearyl isostearate 15.115.1 40.140.1 14.114.1 15.115.1 소르비탄세스퀴올레이트Sorbitan sesquioleate 1One 1One -- 1One 파라옥시안식향산부틸Butyl paraoxybenzoate 0.20.2 0.20.2 0.20.2 0.20.2 폴리옥시에틸렌 메틸폴리실록산Polyoxyethylene methylpolysiloxane -- -- 22 -- 데카메틸사이클로펜타실록산Decamethylcyclopentasiloxane 2525 -- 2525 2525 스쿠알란Squalane 55 55 55 55 향료Spices 0.20.2 0.20.2 0.20.2 0.20.2 디메치콘/비닐디메치콘 크로스폴리머Dimethicone / Vinyl Dimethicone Crosspolymer 33 33 33 -- 마이카Mica 1515 1515 1515 1515 탄산칼슘Calcium carbonate 22 22 22 22 산화철 색소Iron oxide pigment 5.55.5 5.55.5 5.55.5 5.55.5 산화티탄Titanium oxide 2525 2525 2525 2525 나일론 가루Nylon powder -- -- -- 33

* 디메치콘/비닐디메치콘 크로스폴리머:다우 코닝사(DC 9506).Dimethicone / vinyldimethicone crosspolymer: Dow Corning (DC 9506).

이하, 실시예 1 및 비교예 1 내지 3에 따라 제조한 오일케익에 대하여 여성 20명을 대상으로 실시예 1과 비교예 1 내지 3을 얼굴 양쪽 부위에 사용하게 한 후, 다음 평가 기준에 따라 제품의 표면상태, 사용감, 화장 지속성, 번들거림 및 커버력을 평가한 값을 평균하여 그 결과를 표 2에 나타냈다.Hereinafter, the oil cakes prepared according to Example 1 and Comparative Examples 1 to 3 were subjected to Example 1 and Comparative Examples 1 to 3 on both sides of the face of 20 women, and then the product was evaluated according to the following evaluation criteria. Table 2 shows the results obtained by averaging the surface condition, usability, makeup sustainability, glossiness, and coverage.

<평가 기준><Evaluation Criteria>

매우 나쁨 : 1Very bad: 1

나 쁨 : 2Poor: 2

보 통 : 3Normal: 3

우 수 : 4Right hand: 4

매우 우수 : 5Very good: 5

항목Item 실시예 1Example 1 비교예 1Comparative Example 1 비교예 2Comparative Example 2 비교예 3Comparative Example 3 제품의 표면상태Surface condition of the product 4.04.0 4.14.1 1.51.5 3.83.8 사용감Feeling 3.73.7 3.53.5 3.33.3 2.52.5 화장 지속성Makeup persistence 3.83.8 2.42.4 3.93.9 3.73.7 번들거림Bundle 3.93.9 2.22.2 3.43.4 3.63.6 커버력Coverage 3.83.8 2.82.8 3.73.7 3.63.6

상기 표 2에 나타난 바와 같이, 본 발명에 따른 휘발성 실리콘 오일과 계면 활성제, 분체를 함유한 실시예 1은 제품의 표면상태, 사용감, 화장 지속성, 번들거림 및 커버력이 모두 양호함을 알 수 있다.As shown in Table 2, Example 1 containing the volatile silicone oil, the surfactant, and the powder according to the present invention can be seen that the surface condition, usability, makeup persistence, shine and coverage of the product are all good.

한편, 비교예 1은 휘발성 실리콘 오일을 함유하지 않아 번들거림이 많고 화장지속성이 떨어지며, 비교예 2 및 비교예 3은 각각 본 발명에 따른 계면활성제 또는 분체를 함유하지 않아 고온 유동성이 저하되여 제품의 외관이 불량하거나 사용감이 부드럽지 못하다.On the other hand, Comparative Example 1 does not contain a volatile silicone oil, so there is a lot of shine and cosmetic persistence, Comparative Example 2 and Comparative Example 3 does not contain a surfactant or powder according to the present invention, respectively, the high temperature fluidity is lowered, the appearance of the product This is poor or not comfortable to use.

이상과 같이, 본 발명에 따른 오일케익용 화장료 조성물은 고온 유동성이 우수할 뿐만 아니라, 화장 후 휘발성 실리콘 오일이 휘발되어 번들거림이 적고 화장 지속성 및 사용감이 매우 양호하다.As described above, the cosmetic composition for oil cake according to the present invention is not only excellent in high temperature fluidity, but also volatile silicone oil is volatilized after make-up, less bleeding, and make-up durability and feeling is very good.

Claims (2)

오일케익용 화장료 조성물에 있어서, 분체 45 내지 60중량부, 오일 40 내지 55중량부 및 소르비탄 모노스테아레이트, 소르비탄 세스퀴올레이트 및 이들의 혼합물로 이루어진 군으로부터 선택된 계면활성제 0.5 내지 5중량부를 포함하되, 상기 분체는 디메치콘/비닐디메치콘 크로스폴리머 0.5 내지 5중량부를 함유하고, 상기 오일은 휘발성 실리콘 오일 5 내지 40중량부를 함유하는 것을 특징으로 하는 오일케익용 화장료 조성물.In the cosmetic composition for oil cake, 45 to 60 parts by weight of powder, 40 to 55 parts by weight of oil and 0.5 to 5 parts by weight of surfactant selected from the group consisting of sorbitan monostearate, sorbitan sesquioleate and mixtures thereof However, the powder contains 0.5 to 5 parts by weight of dimethicone / vinyldimethicone crosspolymer, and the oil contains 5 to 40 parts by weight of volatile silicone oil. 제1항에 있어서, 상기 휘발성 실리콘 오일은 옥타메틸사이클로테트라실록산, 데카메틸사이클로펜타실록산 및 이들의 혼합물로 이루어진 군으로부터 선택된 어느 하나인 것을 특징으로 하는 오일케익용 화장료 조성물.The cosmetic composition of claim 1, wherein the volatile silicone oil is any one selected from the group consisting of octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, and mixtures thereof.
KR10-2001-0043668A 2001-07-20 2001-07-20 Cosmetic composition for oil cake KR100409023B1 (en)

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