KR101159265B1 - Perfume composition made of Cheju nature Citrus and Cosmetic composition using the same - Google Patents

Abstract

The present invention relates to a Jeju natural citrus flavor composition and a cosmetic composition using the same, more specifically, citrus flavor composition containing D-limonene as an active ingredient containing natural citrus essential oil extracted from Jeju citrus in Korea as a main ingredient and cosmetics using the same It relates to a composition.

The natural citrus flavor composition of the present invention is characterized by containing cyclosiloxane and citrus essential oils extracted from the citrus and dissolved in the cyclosiloxane.

According to the present invention, the essential oil extracted and separated from the tangerine of Jeju has an excellent effect in relieving the mind and body calm and calm, anxiety and depression can be usefully used as a fragrance, deodorant, cosmetics and the like. In addition, the present invention has a rapid diffusion and high sustainability because the citrus essential oil is dissolved in the cyclo siloxane and present in the form of silicon-flavored particles.

Citrus fruits, essential oils, essential oils, cyclosiloxanes, aromas, fragrances, cosmetics

Description

Perfume composition made of Cheju nature Citrus and Cosmetic composition using the same}

The present invention relates to a Jeju natural citrus flavor composition and a cosmetic composition using the same, more specifically, citrus flavor composition containing D-limonene as an active ingredient containing natural citrus essential oil extracted from Jeju citrus in Korea as a main ingredient and cosmetics using the same It relates to a composition.

Citrus is a fruit orchard belonging to the dicotyledonous herb and the citrus subfamily, and means a variety of citrus, gold persimmon, and citrus among the citrus subfamily.

Orchards grow only the types of tangerines according to the citrus fruits, and all of the types of tangerines are evergreen shrubs or small arbors. It is unknown in Korea when citrus fruits began to be cultivated, but the cultivated varieties of citrus fruits mainly consisted of the cold-bearing tangerine, which was introduced in Japan in 1911.

Citrus from Jeju has good taste and aroma and contains various vitamins, especially vitamins A and C. In addition, it contains a lot of physiologically active ingredients such as pectin, various essential oils and hesperidin, and is one of the most widely used fruits for Koreans. Coming.

Recently, the production of citrus fruits in Korea is increasing rapidly, and the production of citrus processed products such as canned food, juice, and nectar is showing rapid growth. As the consumption of citrus fruits grows, the amount of citrus fruits used is increasing.

During citrus processing, a large amount of citrus peel is discarded. When processing citrus fruits for canning or juus and nectar production, peel all the citrus fruits and use only citrus pulp. If the citrus peel is disposed of as it is, it can be a cause of environmental pollution. If it can be recycled, it can not only solve the pollution problem but also actively utilize waste resources that contain a lot of active ingredients in Korea, which lacks natural resources. When peeling citrus fruit is a great thing.

Currently, the use of citrus peel in the country is hardly made. Some are dried and used as drugs or as part of their feed. However, in the foreign countries, as well as extracting essential oil (essential oil) from the citrus peel, it is used as an animal feed, pectin and hesperidin extract material.

Citrus essential oils are aromatic substances contained in citrus peels and pulp, and only a very small amount can be obtained during extraction, and research is being conducted to obtain such citrus essential oil components more efficiently.

Korean Patent Publication No. 10-0663981 discloses a cosmetic composition containing and extracting an essential oil component having antibacterial activity from citrus fruits against major causative bacteria causing skin diseases such as acne. Korean Patent Publication No. 10-0553330 discloses a cosmetic composition containing and extracting an essential oil component having antimicrobial activity against major causative agents causing skin diseases such as athlete's foot from citrus fruits.

However, as mentioned above, citrus essential oils have been actively researched for antimicrobial effects and utilization as additives for foods and medicines, but research as a fragrance composition is insignificant.

The fragrance is a fragrance that gives the interior atmosphere a feeling of clarity and freshness, and is used to achieve a refreshing feeling for a person. Therefore, fragrance is required to be gentle, refreshing and refreshing, and sometimes even to the stability and calming effect of a person's mind and body. However, the production of fragrances of general fragrances are mostly made up of trace amounts of natural fragrances and synthetic fragrances. When using fragrances, the use of fragrances may be confused depending on the strength of the fragrances, and the use of fragrances may be avoided due to pain in the head.

The present invention was created to improve the above problems, using natural citrus essential oil extracted from Jeju citrus without using any synthetic fragrance to increase the ratio of natural fragrance and relieve mental and physical stability and calm, anxiety and depression It is an object to provide a natural citrus fragrance composition and a cosmetic composition using the same having excellent effects and no side effects.

Another object of the present invention is to provide a natural citrus flavor composition having a rapid diffusion and high sustainability of citrus aromas generated from citrus essential oil and a cosmetic composition using the same.

The natural citrus fragrance composition of the present invention for achieving the above object is characterized in that it contains cyclosiloxane and citrus essential oil extracted from the citrus and dissolved in the cyclosiloxane.

The cyclosiloxane is octa methyl cyclo tetra siloxane, the natural citrus flavor composition is characterized in that 60 to 80% by weight of the octa methyl cyclo tetra siloxane, 20 to 40% by weight of the citrus essential oil.

It further comprises at least one herbal oil extracted from frankincense, eucalyptus, juniper, lavender, sandalwood, neroli, ylang-ylang, rosemary and geranium.

And the cosmetic composition of the present invention for achieving the above object is characterized in that it contains the natural citrus flavor composition.

The cosmetic composition is characterized in that the formulation of any one selected from skin, lotion, cream, essence, shampoo, detergent, soap, pack.

As described above, according to the present invention, the essential oil extracted and separated from the tangerine of Jeju has an excellent effect in relieving mental and physical stability and calmness, anxiety and depression, and thus may be usefully used as a fragrance, deodorant, cosmetic, and the like.

In addition, the present invention has a rapid diffusion and high sustainability because the citrus essential oil is dissolved in the cyclo siloxane and present in the form of silicon-flavored particles.

Hereinafter, a natural citrus flavor composition and a cosmetic composition using the same according to an embodiment of the present invention will be described in detail.

The natural citrus fragrance composition of the present invention contains cyclosiloxane and citrus essential oils extracted from the citrus and dissolved in the cyclosiloxane.

Cyclosiloxanes have cyclic siloxane bonds (Si-O). As cyclosiloxane, cyclo tetra siloxane, cyclo penta siloxane, cyclo hexa siloxane can be used. The cyclosiloxane acts as a volatile carrier or carrier of citrus flavors produced from citrus essential oils. Citrus essential oils are dissolved in cyclo siloxane and present in the form of silicone-flavored particles so that the fragrance composition of the present invention has fast diffusion and high sustainability.

As the cyclosiloxane, octa methyl cyclo tetra siloxane in which eight methyl groups are bonded to silicon is preferably used. Octa methyl cyclotetrasiloxane can be represented by the formula:

The octa methyl cyclotetrasiloxane has a low viscosity and is not reactive, and thus is particularly contained in the cosmetic composition to improve diffusion, flowability, and smoothness.

Natural citrus flavor composition of the present invention is composed of 60 to 80% by weight of cyclosiloxane, 20 to 40% by weight of citrus essential oil. If the cyclosiloxane content is less than 60% by weight, the diffusion and persistence of the natural citrus flavor is reduced, the fragrance is reduced, and if the content exceeds 80% by weight, the effect of the natural citrus flavor may be lowered.

Citrus essential oil is extracted from the domestic Jeju citrus. Jeju citrus in the present invention is Hagyul, Ilhyangha, Pyungyul, Bujiwha, Dangyuja, Jigak, Joadeung, Dongjunggyul, persimmon Varieties such as Tangerine (Gamwhagyul), Potato (Gamja), Sadugam, Seminole, Chunggyun, Byunggyul, Geumgamja and Cheonyahagyul are available. .

 Citrus essential oil can be extracted from the citrus peel according to a conventional essential oil extraction method, the essential oil extraction method can be easily implemented by those skilled in the art. For example, the oil refining process includes steam distillation, in which oil is discharged at a temperature lower than the actual boiling point, an expression for pressing to obtain essential oils, an adsorption method for absorption by a nonvolatile solvent such as fat, Solvent extraction using volatile solvents (e.g. hexane, ethyl alcohol, benzene, etc.) to extract fragrance components; extraction by collecting wounds and leaching sap from plant stems or rhizomes And supercritical extration (CO2 extraction), but are not limited thereto.

As an example of the pressing method, the citrus peel of the citrus peel is opened by pressing the yellow epidermis of the citrus peel while pushing it with a myriad of fine grooves. Essence flows out of the drum is absorbed into the groove of the drum, and the oil absorbed into the groove of the drum is collected and centrifuged to separate the essential oil. In addition, the citrus peel is pulverized to a predetermined size as a solvent extraction method, and then injected into the extraction reactor. The extraction solvent is then injected in a predetermined amount against the citrus peel. Usable extraction solvent may be a single solvent or a mixed solvent thereof selected from the group consisting of water, a lower alcohol having 1 to 5 carbon atoms, and an organic solvent. Preferably, the lower alcohol may be methanol, ethanol or isopropanol, and as the organic solvent, hexane, ethyl acetate or acetone, which are low polar solvents, may be used. At this time, the content of the extraction solvent may be appropriately adjusted according to the solvent used, and in the case of using water and lower alcohol, 1 to 20 times by volume, preferably 3 to 10 times by weight relative to the weight of the dry pulverized plant. In the case of the organic solvent, it is used in 0.5 to 2 times, preferably 0.6 to 1 times.

The extracted citrus essential oils comprise 70-90% by weight of D-limonene as the main component. D-limonene, which is extracted from citrus fruits, is known to have anti-cancer activity and calms the excitability of the central nervous system. In addition, hesperidin, naringin, narizine, narylcin are contained as flavonoids, and carotenoids, pectin and the like are contained.

The citrus essential oils may be used in natural medical treatment methods for preventing and treating diseases by various physiological actions. Essential oils extracted from citrus fruits play a central role and function in the plant's biochemical structure, acting like hormones present between cells, and regulating physiological functions and transmitting information. In other words, plants can protect themselves from pests and diseases, and adapt to the environment by coping with stress situations about hatching and breeding. Absorption of these essential oils into the human body causes various reactions. Citrus essential oil, which has a calming and calming effect on mind and body, uses natural fragrances properly, thus enhancing the user's fragrance achievement, converting the user's mood to natural fragrances, and acting as a natural fragrance to relieve anxiety and depression. Natural fragrances are natural fragrances that give a long-lasting effect and give a feeling of freshness and freshness to people who feel refusal to use general fragrances. It is expected to have an excellent effect on the stability and sedation of mind and body such as blood circulation.

Therefore, the citrus flavor composition of the present invention can relieve mental and physical stability and calm, anxiety and depression when used as a fragrance. When used as a fragrance, the citrus fragrance composition may be used as it is or may be used by further including a conventional fragrance component. Such fragrances can be used in a form that is sprayed into the air in a spray container. In particular, the citrus flavor composition of the present invention can be used as a deodorant, of course.

The citrus flavor composition of the present invention may further comprise a cyclosiloxane and herbal oil in addition to citrus essential oil. In this case, the composition is 60 to 80% by weight of cyclosiloxane, 10 to 20% by weight of citrus essential oil, and 10 to 20% by weight of herb oil.

Herbal oils include frankincense, eucalyptus, juniper, lavender, sandalwood, neroli, ylang-ylang, rosemary, geranium, lavender, chemomile, peppermint, spearmint, applemint, limeblossom, sage, lemongrass, lemon verbena, rosehip, Oils extracted and separated from herbs such as cinnamon, jacques, sweet fennel, ginger, saffron, echinacea, jasmine, caraway, hibiscus and marigold can be used.

Preferably citrus essential oils and well-branded frankincense, eucalyptus, juniper, lavender, sandalwood, neroli, ylang-ylang, rosemary, using any one extracted from geranium. Of course, two or more may be mixed. Herb oil can be extracted using the same method as the extraction method of citrus essential oil described above.

In addition to the citrus flavor composition of the present invention may be added fruit flavor or the like according to the taste of the consumer or the needs of the manufacturer.

And the cosmetic composition of the present invention is conventionally known in the natural citrus flavor composition, such as stabilizers, solubilizers, vitamins, pigments and flavors, surfactants, organic and inorganic pigments, organic powders, antioxidants, pH adjusters, alcohols, etc. It may be made of any one of the formulation further selected from skin, lotion, cream, essence, shampoo, detergent, soap, pack including the ingredient. In addition, in each formulation, other components other than the above components can be arbitrarily selected and blended according to the formulation or purpose of use of other cosmetics. Natural citrus flavor composition may be contained in 0.1 to 90% by weight of the cosmetic composition.

Specifically, when the formulation of the cosmetic composition of the present invention is a lotion, cream or pack, as known components, animal fibers, plant fibers, waxes, paraffins, starches, tragacanth, cellulose derivatives, polyethylene glycol, silicone, bentonite, silica, Talc or zinc oxide may be used.

When the formulation of the cosmetic composition of the present invention is a solution or emulsion, a solvent, solvating agent or emulsifying agent is used, such as water, ethanol, isopropanol, ethyl carbonate, ethyl acetate, benzyl alcohol, benzyl benzoate, propylene glycol, 1, 3-butylglycol oil, glycerol aliphatic ester, polyethyleneglycol or sorbitan non-dispersion ester and the like can be used.

Water, liquid diluents such as ethanol or propylene glycol, suspending agents such as ethoxylated isostearyl alcohol, polyoxyethylene sorbitol ester and polyoxyethylene sorbitan ester when the formulation of the cosmetic composition of the present invention is a suspension, microcrystalline Cellulose, aluminum metahydroxy, bentonite, agar or tragacanth and the like can be used.

Aliphatic alcohol sulfate, aliphatic alcohol ether sulfate, sulfosuccinic acid monoester, isethionate, imidazolinium derivative, methyltaurate, sarcosinate, fatty acid amide ether sulfate when the formulation of the cosmetic composition of the present invention is a surfactant-containing cleansing , Alkylamidobetaines, aliphatic alcohols, fatty acid glycerides, fatty acid diethanolamides, vegetable oils or ethoxylated glycerol fatty acid esters and the like can be used.

In addition to the cosmetic composition of the present invention may be prepared in any formulation commonly prepared in the art, may be appropriately selected depending on the intended use.

Hereinafter, preferred examples of citrus flavor compositions are provided for the purpose of understanding the present invention, but the following examples are merely to illustrate the present invention, and the scope of the present invention is not limited to the following examples.

(Example)

Citrus essential oils were prepared by mixing citrus essential oil and octa methyl cyclotetrasiloxane (XIAMETER DMX-0244, Dow Coming Co., Ltd.) extracted by the conventional steam distillation method described below, and then stirring the mixture for 1 hour.

Prepare a steam distillation apparatus consisting of two round flasks prepared in order to apply heat from the bottom and connected with a U-shaped glass tube in the middle. Put and boil at a temperature of 100 ℃. In another round flask, 80 ml of diethyl ether was added and the temperature was maintained at 40 ° C. After about 40 to 50 minutes had elapsed in this state, the citrus essential oil as a fragrance component was collected in a U-shaped glass tube in the middle of the steam distillation apparatus. The essential oil components were filtered through filter paper and the water was completely removed using a vacuum condenser to obtain citrus essential oil.

The composition of the citrus flavor composition is shown in Table 1 below.

Ingredient Example 1 Example 2 Example 3 Example 4 Example 5 Octamethylcyclotetrasiloxane 50 wt% 60% by weight 70 wt% 80 wt% 90 wt% Citrus essential oil 50 wt% 40 wt% 30 wt% 20 wt% 10 wt%

The sensory appreciation of the taste preference and physical and mental stability and soothing effect for the citrus flavor composition prepared according to the composition ratio of Table 1 was carried out. The evaluation method was conducted by selecting 10 men and women each who thought they were sensitive to fragrance to confirm whether the fragrance is excellent. The sensory evaluation was performed by spraying the citrus fragrance composition of Example 1 in a panel room of 3m in length, 3m in height, and 2m in height, and after 24 hours, the evaluators stayed in the panel room for 10 minutes to perform sensory evaluation. In the same manner as described above, sensory evaluation was also performed on Examples 2 to 5, respectively.

There are 8 sensory evaluation items: "Very active, active, refreshing, warm, pleasant, pleasant, calm, calm, happy, full, happy and full." , "I feel excited", and the points for each evaluation item, the average value for each 10 men and women after the evaluation is shown in the flavor taste diagram of Table 2 below.

division Example 1 Example 2 Example 3 Example 4 Example 5 south 0.4 0.6 One 0.8 0.4 female 0.3 0.7 One 0.7 0.5 Sum 0.7 1.3 2 1.5 0.9

(Evaluation criteria: Very good -2, Good -1.5, Normal -1, Less than -1)

Referring to the results of Table 2, in the case of Example 2, the taste preference is more than normal, in the case of Example 3, the taste preference is very good, and in the case of Example 4 it was found that the smell preference. In the case of Example 1, 0.7 points and Example 5 were 0.9 points, which was lower than those of Examples 2 to 4.

Table 3 below shows the results of mental and physical stability and sedation effects.

division Example 1 Example 2 Example 3 Example 4 Example 5 south 0.3 0.5 One 0.7 0.4 female 0.3 0.7 0.9 0.7 0.4 points 0.6 1.2 1.9 1.4 0.8

(Evaluation criteria: Very good -2, Good -1.5, Normal -1, Less than -1)

Looking at the results of Table 3, in Example 2, the physical and mental stability and sedation effect is more than normal, in the case of Example 3, mental and physical stability and sedative effect is good or more and in Example 4 the physical and mental stability and sedation effect is more than normal appear. In addition, in Example 1, it was 0.6 point, and in Example 5, it was 0.8 point, and it was shown that physical and mental stability and calming effect were lowered as compared with Examples 2 to 4.

From the above results, it was confirmed that the citrus flavor composition of the present invention is effective in relieving mental and physical stability and calm, anxiety and depression. In particular, the present invention was found to have the best effect when it is composed of 60 to 80% by weight of cyclosiloxane, 20 to 40% by weight of citrus essential oil. And the cosmetic composition containing the citrus fragrance composition is also expected to be effective in relieving mental and physical stability and calm, anxiety and depression when used.

In addition, the citrus flavor composition of the present invention was found to have a high fragrance lasting even after 24 hours.

In the above, the present invention has been described with reference to one embodiment, which is merely exemplary, and it will be understood by those skilled in the art that various modifications and equivalent embodiments are possible.

Accordingly, the true scope of protection of the present invention should be determined only by the appended claims.

Claims (5)

delete Containing cyclosiloxane and citrus essential oils extracted from the citrus and dissolved in the cyclosiloxane, The cyclosiloxane is octa methyl cyclotetrasiloxane, 60 to 80% by weight of the octa methyl cyclotetrasiloxane, 20 to 40% by weight of the citrus essential oil, characterized in that the fragrance composition for spraying with natural citrus flavor. The fragrance composition for spraying with natural citrus fragrance according to claim 2, further comprising at least one herbal oil extracted from frankincense, eucalyptus, juniper, lavender, sandalwood, neroli, ylang-ylang, rosemary and geranium. . delete delete