KR100404793B1 - Stacking film for refill bag - Google Patents

Stacking film for refill bag Download PDF

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Publication number
KR100404793B1
KR100404793B1 KR10-2000-0061841A KR20000061841A KR100404793B1 KR 100404793 B1 KR100404793 B1 KR 100404793B1 KR 20000061841 A KR20000061841 A KR 20000061841A KR 100404793 B1 KR100404793 B1 KR 100404793B1
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South Korea
Prior art keywords
film
container
contents
silicone oil
laminated
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KR10-2000-0061841A
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Korean (ko)
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KR20020031616A (en
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장욱
김기섭
이인현
이용현
김경원
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주식회사 엘지생활건강
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/18Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/34Layered products comprising a layer of synthetic resin comprising polyamides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2318/00Mineral based
    • B32B2318/02Oil
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2323/00Polyalkenes
    • B32B2323/04Polyethylene
    • B32B2323/046LDPE, i.e. low density polyethylene

Abstract

본 발명은 실리콘 오일을 포함하는 비닐 수지의 필름과 1 내지 4 겹의 일반 적층용 필름을 적층시켜서 이루어진 적층 필름 및 이것으로 제조된 필름 용기에 관한 것으로, 필름 용기 내면과 내용물 간의 마찰력을 줄여 용기내 내용물의 인출을 용이하게 하고, 이에 따라 내용물의 용기내 잔량을 최소화할 수 있게 한다.The present invention relates to a laminated film formed by laminating a film of a vinyl resin containing a silicone oil and a film for general lamination of 1 to 4 layers, and a film container made therefrom, thereby reducing friction between the inner surface of the film container and the contents and It is possible to facilitate the withdrawal of the contents, thereby minimizing the remaining amount in the container of the contents.

Description

리필 포장재용 적층 필름{Stacking film for refill bag}Stacking film for refill bag

본 발명은 적층 필름 및 필름 용기에 관한 것이다. 보다 상세하게는, 본 발명은 실리콘 오일(silicon oil)을 포함하는 비닐 수지의 필름과 1 내지 4 겹의 일반 적층용 필름을 적층시켜서 이루어진 적층 필름 및 이것으로 제조된 필름 용기에 관한 것이다.The present invention relates to laminated films and film containers. In more detail, this invention relates to the laminated | multilayer film which laminated | stacked the film of the vinyl resin containing a silicone oil, and 1-4 layers of general lamination films, and the film container made from this.

필름 용기는 세제류 및 두발용 화장료 제품에서와 같이 매번 용기를 포함한 제품을 구입할 필요없이 이전에 쓰던 용기에 리필하여 쓸 수 있게 하기 위해서 제품을 최소한의 비용으로 간편하게 포장하는 데에 사용된다. 종래의 필름 용기는 폐기시 부피 축소 용이함과 저렴한 가격으로 현재 소비자들이 매우 선호하고 있으나 리필 제품을 소비자가 본 제품 용기에 재충진할 때 필름용기 내면과 내용물 간의 마찰력 발생에 의해 내용물이 나오는 속도가 늦고, 또한 내용물 잔량이 많이 남은 채로 버려야 하는 불편함이 있었다.Film containers are used to conveniently package products at minimal cost to enable refilling into previously used containers without the need to purchase products, including containers each time, such as in detergents and hair cosmetic products. Conventional film containers are now very favored by consumers because of easy volume reduction and low price when discarding, but when refilling the refilled product into this product container, the contents are released slowly due to the friction between the inner surface of the film container and the contents. In addition, there was an inconvenience of having to throw away the contents remaining much.

이러한 불편함을 해결하기 위해 국내외의 액체제품 제조사에서는 토출구를 본 제품 용기에 꽂아 쓸 수 있도록 마개를 단 필름 용기에 내용물을 담아 제품을 판매하는 경우도 있으나, 이는 취급상 다소 편리할 뿐 내용물의 잔량이 남는 것을방지할 수 없을 뿐더러 마개 부착 비용이 과다하게 발생되며 또한 마개 부착 설비를 수입해야 하기 때문에 외화 유출의 문제점도 수반하게 된다.In order to solve this inconvenience, domestic and foreign liquid product manufacturers sometimes sell the product in a film container with a cap so that the outlet can be inserted into the product container. This cannot be prevented, and the cost of the cap is excessively generated and the problem of foreign currency spillage is accompanied because the capping equipment has to be imported.

따라서, 내용물의 잔량이 남는 것을 방지하면서 비용이 과다하게 발생되지 않는 포장용 필름 및 필름 용기의 개발 필요성이 대두되었다.Therefore, there is a need to develop a packaging film and a film container that do not cause excessive costs while preventing the remaining amount of the content.

본 발명의 목적은 필름 용기 내면과 내용물 간의 마찰력을 줄여 용기내 내용물의 인출을 용이하게 하고, 이에 따라 내용물의 용기내 잔량을 최소화할 수 있게 하는 적층 필름 및 이것으로 제조된 필름 용기를 제공하는 데 있다.SUMMARY OF THE INVENTION An object of the present invention is to provide a laminated film and a film container made from the same, which can reduce the frictional force between the inner surface of the film container and the contents to facilitate the withdrawal of the contents in the container, thereby minimizing the remaining amount of the contents in the container. have.

본 발명에 따른 적층 필름은 0.3 내지 3 중량%의 실리콘 오일을 포함하는 비닐 수지의 필름과 일반 적층용 필름을 적층시켜서 이루어지는 것을 특징으로 한다.The laminated film according to the present invention is characterized by laminating a film of a vinyl resin containing 0.3 to 3% by weight of silicone oil and a film for general lamination.

본 발명에 따른 필름 용기는 상기의 적층 필름으로 성형되는 것을 특징으로 한다.The film container according to the present invention is characterized in that it is molded into the laminated film.

이하 본 발명의 구체적인 실시예를 참조하여 상세히 설명한다.Hereinafter, with reference to specific embodiments of the present invention will be described in detail.

본 발명에 따른 적층 필름은 실리콘 오일을 포함하는 비닐 수지의 필름과 일반 적층용 필름을 적층시켜서 이루어진다.The laminated | multilayer film which concerns on this invention is made by laminating | stacking the film of vinyl resin containing a silicone oil, and the film for general lamination.

상기에서 비닐 수지에는 선형저밀도 폴리에틸렌(linear low density polyethylene) 또는 저밀도 폴리에틸렌(low density polyethylene)이 포함된다. 이때 선형저밀도 폴리에틸렌 수지 또는 저밀도 폴리에틸렌 수지를 단독 또는 혼합한 상태에서 실리콘 오일을 혼합하고 기타 첨가제를 첨가하여 마스터배치를 제조한 후 사용할 수도 있고, 선형저밀도 폴리에틸렌 수지 또는 저밀도 폴리에틸렌 수지 및 기타 첨가제를 첨가하여 제조한 기존의 마스터배치에 실리콘 오일을 혼련시켜 사용할 수도 있다.The vinyl resin includes linear low density polyethylene or low density polyethylene. In this case, the linear low density polyethylene resin or the low density polyethylene resin alone or in a mixed state in which the silicone oil is mixed and other additives may be used to prepare a master batch, or linear low density polyethylene resin or low density polyethylene resin and other additives It is also possible to knead silicone oil to the existing masterbatch manufactured.

본 발명에서는 적층 필름의 실리콘 오일 함량을 0.3 내지 3 중량%로 하였다.이때 실리콘 오일 함량을 0.3 중량% 이하로 사용할 경우에는 필름면의 마찰력 감소 효과가 기대한 만큼 나타나지 않으며, 실리콘 오일을 3 중량% 이상 사용한 경우에는 실리콘 오일 함량 증가에 따른 뚜렷한 마찰력 감소 효과 향상이 나타나지 않으면서 내층 필름에 외층 필름을 적층할 때 적층 강도가 저하되는 문제점이 발생되었다.In the present invention, the silicone oil content of the laminated film is 0.3 to 3% by weight. When the silicone oil content is used at 0.3% by weight or less, the frictional force reducing effect of the film surface does not appear as expected, and the silicone oil is 3% by weight. In the case of the above-mentioned use, the lamination strength was lowered when the outer layer film was laminated on the inner layer film without a significant improvement in the frictional force reduction effect due to the increase in the silicone oil content.

본 발명에 따른 적층 필름은 상기 일반 적층용 필름이 나일론 필름임을 특징으로 한다. 나일론 필름은 내마모성이 있고 인쇄가 잘 되며 적은 비용으로 대량생산이 가능한 장점이 있다.Laminated film according to the invention is characterized in that the general laminated film is a nylon film. Nylon film has the advantage of being abrasion resistant, printing well and mass production at low cost.

본 발명에 따른 적층 필름의 제조시 바람직하게 이용할 수 있는 방법으로는 인플레이션(inflation) 공법으로 내층 필름을 제조한 후 드라이 라미네이션(dry lamination) 또는 티다이 익스트루션 라미네이션(T-die extrusion lamination) 공법으로 외층 필름을 적층하는 방법을 들 수 있다.A method that can be preferably used in the manufacture of the laminated film according to the present invention is to produce an inner film by the inflation method (dry lamination) or T-die extrusion lamination (T-die extrusion lamination) method The method of laminating | stacking an outer layer film is mentioned.

본 발명에 따른 필름 용기는 상기의 적층 필름으로 제조된 것을 특징으로 한다.The film container according to the invention is characterized in that it is made of the laminated film.

이렇게 하여 제조된 필름 용기는 주방용 세제, 두발용 화장품, 섬유유연제등에 사용될 수 있다.Thus prepared film container can be used in kitchen detergents, hair cosmetics, fabric softeners and the like.

이하에서 본 발명의 바람직한 실시예 및 비교예들이 기술되어질 것이다.Hereinafter, preferred embodiments and comparative examples of the present invention will be described.

이하의 실시예들은 본 발명을 예증하기 위한 것으로서 본 발명의 범위를 국한시키는 것으로 이해되어져서는 안될 것이다.The following examples are intended to illustrate the invention and should not be understood as limiting the scope of the invention.

실시예 1Example 1

선형 저밀도 폴리에틸렌에 실리콘 오일을 0.1 중량% 용융 혼련시켜 150㎛ 두께의 필름을 제조하였다.A 150 μm thick film was prepared by melt kneading 0.1 wt% silicone oil in linear low density polyethylene.

실시예 2Example 2

선형 저밀도 폴리에틸렌에 실리콘 오일을 0.3 중량% 용융 혼련시켜 150㎛ 두께의 필름을 제조하였다.A 150 μm thick film was prepared by melt kneading 0.3 wt% silicone oil in linear low density polyethylene.

실시예 3Example 3

선형 저밀도 폴리에틸렌에 실리콘 오일을 1 중량% 용융 혼련시켜 150㎛ 두께의 필름을 제조하였다.A 150 μm thick film was prepared by melt kneading 1 wt% silicone oil in linear low density polyethylene.

실시예 4Example 4

선형 저밀도 폴리에틸렌에 실리콘 오일을 3 중량% 용융 혼련시켜 150㎛ 두께의 필름을 제조하였다.A 150 μm thick film was prepared by melt kneading 3 wt% silicone oil on linear low density polyethylene.

실시예 5Example 5

선형 저밀도 폴리에틸렌에 실리콘 오일을 4 중량% 용융 혼련시켜 150㎛ 두께의 필름을 제조하였다.A 150 μm thick film was prepared by melt kneading 4 wt% silicone oil on linear low density polyethylene.

실시예 6Example 6

실시예 2의 필름에 15㎛ 두께의 나일론(nylon) 필름을 적층한 후 가로 140mm 높이 260mm의 스탠딩 파우치(standing pouch)형의 필름 용기를 제조하였다.A 15 μm thick nylon film was laminated on the film of Example 2, and then a standing pouch type film container having a width of 140 mm and a height of 260 mm was prepared.

실시예 7Example 7

실시예 3의 필름에 15㎛ 두께의 나일론 필름을 적층한 후 가로 140mm 높이 260mm의 스탠딩 파우치형의 필름 용기를 제조하였다.After laminating a 15 μm thick nylon film on the film of Example 3, a film container of standing pouch type having a width of 140 mm and a height of 260 mm was prepared.

비교예 1Comparative Example 1

선형 저밀도 폴리에틸렌만을 사용하여 150㎛ 두께의 필름을 제조하였다.A 150 μm thick film was made using only linear low density polyethylene.

비교예 2Comparative Example 2

비교예 1의 필름을 사용하여 실시예 6과 같은 방법으로 필름 용기를 제조하였다.Using the film of Comparative Example 1 was prepared a film container in the same manner as in Example 6.

실험예 1: 필름의 마찰력 비교Experimental Example 1: Comparison of frictional force of the film

본 발명에 따른 필름 용기의 마찰력은 하기의 방법에 의해 측정되었다.The frictional force of the film container according to the present invention was measured by the following method.

조성별 마찰력 비교를 위해 실시예 1, 2, 3, 4, 5 및 비교예 1의 필름을 마찰 시험기를 이용하여 마찰값을 측정하였으며 또한 관능 평가로 필름의 매끄러움 정도를 평가하였다.In order to compare the frictional force by composition, the friction values of the films of Examples 1, 2, 3, 4, 5 and Comparative Example 1 were measured using a friction tester, and the degree of smoothness of the films was evaluated by sensory evaluation.

이때 마찰값은 수치가 낮은수록, 관능 평가는 매끄러울수록 필름의 마찰력은 낮은 것으로 해석된다.At this time, the lower the friction value, the smoother the sensory evaluation, the lower the friction force of the film is interpreted.

구분division 마찰력(단위:MU)Friction force (unit: MU) 관능 평가Sensory evaluation 실시예 1Example 1 0.580.58 보통usually 실시예 2Example 2 0.280.28 매끄러움lubricity 실시예 3Example 3 0.200.20 매우 매끄러움Very smooth 실시예 4Example 4 0.100.10 매우 매끄러움Very smooth 실시예 5Example 5 0.090.09 매우 매끄러움Very smooth 비교예 1Comparative Example 1 0.650.65 보통usually

상기 표 1에 나타난 바와 같이, 실리콘 오일이 0.3 중량% 이상 사용된 실시예 2, 3, 4, 5의 필름이 폴리에틸렌 만을 사용한 비교예 1의 필름에 비해 마찰력이 월등히 낮은 것으로 확인되었다.As shown in Table 1, it was confirmed that the film of Examples 2, 3, 4, 5 in which the silicone oil was used in more than 0.3% by weight is significantly lower than the film of Comparative Example 1 using only polyethylene.

실험예 2: 필름 용기로부터의 내용물 인출성 비교Experimental Example 2: Comparison of the content withdrawal from the film container

실시예 6, 7 및 비교예 2의 필름 용기에 점도 50 PS의 두발용 화장품 내용물을 600g 충진하고 밀봉한 후 개봉구가 25 mm 길이가 되게 필름 용기 좌측 상단을 자른 후 거꾸로 매달아 15초간 경과 후 흘러나온 내용물의 양을 측정하여 인출량을 나타내었으며 인출량이 많을수록 인출성이 우수한 것으로 평가하였다.After filling 600 g of the cosmetic contents for hair with a viscosity of 50 PS into the film containers of Examples 6, 7 and Comparative Example 2 and sealing them, cut the upper left side of the film container so that the opening was 25 mm long, hang it upside down, and then flow for 15 seconds. Withdrawal amount was measured by measuring the amount of the contents. The higher the withdrawal amount was, the better the withdrawal property was.

또한 내용물 잔량은 관능 평가로 측정하였으며 평가 방법은 상기 내용물이 600g 충진된 상기 실시예 6, 7 및 비교예 2의 필름 용기 제품을 10명의 여성에게 나누어주고 본 제품 용기에 재충진토록 한 다음, 필름 용기에 남은 잔량 무게를 측정하여 평균치를 구하였으며, 내용물 잔량이 적을수록 필름 용기로부터의 내용물의 인출성이 우수한 것으로 평가하였다.In addition, the remaining amount of the contents was measured by the sensory evaluation, and the evaluation method is to divide the film container products of Examples 6, 7 and Comparative Example 2 filled with 600g of the contents to 10 women and refill the product container, and then the film The residual value remaining in the container was measured to obtain an average value, and the smaller the remaining content was, the more excellent the drawability of the content from the film container was evaluated.

구분division 인출량Withdrawal amount 내용물 잔량Content amount 실시예 6Example 6 200g200 g 29g29 g 실시예 7Example 7 220g220 g 26g26 g 비교예 2Comparative Example 2 140g140 g 4242

상기 표 2에 나타난 바와 같이, 필름 용기로부터의 점성이 있는 내용물의 인출성은 실시예 6, 7의 필름 용기가 비교예 2의 필름 용기 보다 월등히 우수한 것을 확인하였다.As shown in the said Table 2, withdrawal property of the viscous content from the film container confirmed that the film container of Examples 6 and 7 was much better than the film container of the comparative example 2.

상기한 실시예들을 종합한 결과, 본 발명에 따른 적층 필름은 종래의 필름에 비해 마찰력이 현저히 감소된 것으로 나타났으며, 이러한 적층 필름으로 필름 용기를 제조할 때 필름 용기로부터의 내용물의 인출성이 월등히 향상되는 것으로 나타났다.As a result of the synthesis of the above-described embodiments, the laminated film according to the present invention was found to have a significantly reduced friction compared with the conventional film. Significantly improved.

따라서, 본 발명에 의하면 실리콘 오일을 포함하는 비닐 수지의 필름과 1 내지 4 겹의 일반 적층용 필름을 적층시켜서 이루어진 적층 필름 및 이것으로 제조된 필름 용기를 제공함으로써 필름 용기 내면과 내용물 간의 마찰력을 줄여 용기내 내용물의 인출을 용이하게 하고, 이에 따라 내용물의 용기내 잔량을 최소화할 수 있게 하는 효과가 있다.Accordingly, according to the present invention, a friction film between the inner surface of the film container and the contents is reduced by providing a laminated film formed by laminating a film of a vinyl resin containing silicone oil and a film for general lamination of 1 to 4 layers and a film container made therefrom. There is an effect to facilitate the withdrawal of the contents in the container, thereby minimizing the remaining amount in the container of the contents.

이상에서 본 발명은 기재된 구체예에 대해서만 상세히 설명되었지만 본 발명의 기술사상 범위 내에서 다양한 변형 및 수정이 가능함은 당업자에게 있어서 명백한 것이며, 이러한 변형 및 수정이 첨부된 특허청구범위에 속함은 당연한 것이다.Although the present invention has been described in detail only with respect to the described embodiments, it will be apparent to those skilled in the art that various modifications and variations are possible within the technical scope of the present invention, and such modifications and modifications are within the scope of the appended claims.

Claims (4)

0.3 내지 3 중량%의 실리콘 오일을 포함하는 선형저밀도 폴리에틸렌, 저밀도 폴리에틸렌 및 이들의 혼합물로 이루어진 군에서 선택된 비닐 수지의 필름과 나일론 필름을 적층시켜서 이루어지는 것을 특징으로 하는 리필 포장재용 적층 필름.A laminated film for a refill packaging material, comprising laminating a film of a vinyl resin and a nylon film selected from the group consisting of linear low density polyethylene, low density polyethylene, and mixtures thereof containing 0.3 to 3% by weight of silicone oil. 삭제delete 삭제delete 삭제delete
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100844270B1 (en) * 2002-08-16 2008-07-07 주식회사 엘지생활건강 Multi-layered film comprising polyethylene

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR920006092A (en) * 1990-09-13 1992-04-27 박중헌 T-Die for Nylion Film Lamination
KR960705675A (en) * 1993-12-01 1996-11-08 데니스 피.산티니 ORIENTED HDPE FILMS WITH SKIN LAYERS
KR970005972A (en) * 1995-07-03 1997-02-19 라르스 브로르젠 Gas bag for vehicle safety devices
KR970015014A (en) * 1995-09-06 1997-04-28 이종학 Manufacturing method of laminating film or sheet
JPH10329915A (en) * 1997-05-30 1998-12-15 Mitsuboshi Belting Ltd Fruit conveying belt

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR920006092A (en) * 1990-09-13 1992-04-27 박중헌 T-Die for Nylion Film Lamination
KR960705675A (en) * 1993-12-01 1996-11-08 데니스 피.산티니 ORIENTED HDPE FILMS WITH SKIN LAYERS
KR970005972A (en) * 1995-07-03 1997-02-19 라르스 브로르젠 Gas bag for vehicle safety devices
KR970015014A (en) * 1995-09-06 1997-04-28 이종학 Manufacturing method of laminating film or sheet
JPH10329915A (en) * 1997-05-30 1998-12-15 Mitsuboshi Belting Ltd Fruit conveying belt

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100844270B1 (en) * 2002-08-16 2008-07-07 주식회사 엘지생활건강 Multi-layered film comprising polyethylene

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