KR100190816B1 - Package container material for high viscosity liquid products - Google Patents

Package container material for high viscosity liquid products Download PDF

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KR100190816B1
KR100190816B1 KR1019960032160A KR19960032160A KR100190816B1 KR 100190816 B1 KR100190816 B1 KR 100190816B1 KR 1019960032160 A KR1019960032160 A KR 1019960032160A KR 19960032160 A KR19960032160 A KR 19960032160A KR 100190816 B1 KR100190816 B1 KR 100190816B1
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container
silicone oil
high viscosity
viscosity liquid
container material
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KR19980013608A (en
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장욱
이재덕
김기섭
이인현
김민기
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성재갑
주식회사엘지화학
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances

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  • Polymers & Plastics (AREA)
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Abstract

본 발명은 실리콘 오일과 폴리에틸렌 또는 폴리프로필렌수지를 컴파운드한 재료를 사용하여 용기를 성형함으로써 용기 내면의 마찰력을 줄여 고점도 내용물을 사용할 때 내용물의 유동성을 향상시킨 고점도 액체제품 포장용기 재료에 관한 것이다.The present invention relates to a high-viscosity liquid product packaging container material which improves the fluidity of contents when high viscosity contents are used by reducing the friction of the inner surface of the container by molding the container using a material compounded with silicone oil and polyethylene or polypropylene resin.

Description

고점도 액체제품 포장용기 재료High viscosity liquid product packaging material

본 발명은 고점도 액체제품 포장 용기 재료에 관한 것이다. 좀 더 구체적으로 본 발명은 실리콘 오일과 폴리에틸렌 또는 폴리프로필렌수지를 컴파운드한 재료를 사용하여 용기를 성형함으로써 용기 내면의 마찰력을 줄여 고점도 내용물을 사용할 때 내용물의 유동성을 향상시킨 고점도 액체제품 용기 재료에 관한 것이다. 본발명에서 고점도 액체제품이란 점도가 2PS(poise)이상인 액체 세제류, 두발용 화장품, 기초화장품, 액상 조미료 등을 포함한다.The present invention relates to a high viscosity liquid product packaging container material. More specifically, the present invention relates to a high-viscosity liquid product container material which improves the fluidity of contents when using high viscosity contents by reducing friction of the inner surface of the container by molding the container using a material compounded with silicone oil and polyethylene or polypropylene resin. will be. High-viscosity liquid products in the present invention include liquid detergents having a viscosity of 2 PS (poise) or more, hair cosmetics, basic cosmetics, liquid seasonings and the like.

통상 두발용 화장품 등 고점도 액체제품은 내용물이 고점도로, 소비자가 내용물을 절반 이상 사용한후 잔량 사용을 위해 용기를 뒤집어 짤 때 내용물과 용기변면과의 마찰력 발생에 의해 내용물이 나오는 속도가 늦고, 또한 내용물이 소량 잔존할 경우 상기 마찰력에 의해 잔량 사용이 불가능하여 소비자들이 내용물 잔존 제품을 버려야 하거나, 내용물이 소량 남은 용기에 물을 혼합하여 흔들어 사용해야 하는 불편함이 있다.In general, high viscosity liquid products such as hair cosmetics have high viscosity, and when the consumer squeezes the container for the remaining amount after using more than half of the contents, the speed of the contents coming out is slowed due to friction between the contents and the sides of the container. If the remaining amount is small, the remaining amount cannot be used by the frictional force, and consumers have to throw away the remaining product, or there is inconvenience of mixing and shaking water in a container with a small amount of content.

이러한 불편함을 해결하기 위해 국내외 고점도 액체 제품을 제조하는 회사에서는 거꾸로 세울 수 있는 용기에 내용물을 충진한 제품을 제조하여 판매하는 경우도 있으나, 이 경우 용기 마개가 편편하고 넓어야하는 디자인상의 제약이 있으며-타원형, 원형, 꼭지 모양의 마개 사용이 불가함-또한 유통시 취급 부주의로 마개가 열릴 경우 내용물 누액 발생의 우려가 있다.In order to solve this inconvenience, companies that manufacture high-viscosity liquid products at home and abroad may produce and sell products filled with contents in upside down containers, but in this case, there are design restrictions that the container closure should be flat and wide. -It is impossible to use elliptical, round, and faucet caps.-Also, if the cap is opened due to careless handling during distribution, there is a risk of leakage of contents.

액체제품은 그 특성상 유통중 단 1개의 제품에서 누액이 발생되더라도, 1포장단위(Box) 전체 제품을 오염시키며, 특히 창고 적재시 상단 박스보관 제품에서 누액 발생시 그 하단 박스 제품까지 오염을 발생시킬 우려가 있다.Due to its characteristics, liquid products contaminate the entire product even if only one product is leaked during distribution.In particular, liquid products may cause contamination from the upper box storage products to the lower box products when leakage occurs. There is.

또한 소매점 등 매장 진열시 누액이 발생되면 진열대 전체를 오염시킬 수 있고 그 제품 근처의 다른 제품에도 영향을 미칠 수 있다.In addition, leaks during store displays, such as retail stores, can contaminate the entire shelf and affect other products near the product.

이에 본 발명자들은 이러한 문제점을 해결하고자 지속적으로 연구해온 결과 실리콘 오일과 폴리에틸렌 또는 폴리프로필렌수지를 컴파운드한 재료를 사용하여 용기를 성형하면 용기면의 마찰력이 감소되어 액체제품 내용물의 유동성을 향상시킴으로 내용물이 소량 잔존시에도 사용성이 크게 향상됨을 밝혀내고 본 발명을 완성하게 되었다.Therefore, the present inventors have continuously studied to solve this problem, and as a result of molding the container using a compound of silicone oil and polyethylene or polypropylene resin, the frictional force of the container surface is reduced to improve the flowability of the liquid product contents. It has been found that the usability is greatly improved even in the presence of a small amount, thereby completing the present invention.

본 발명은 플라스틱 포장용기에 있어서, 고밀도 폴리에틸렌이나 저밀도 폴리에틸렌 또는 폴리프로필렌수지에 실리콘 오일을 0.3 내지 3 중량% 용융혼련하여 성형한 액체포장 용기 재료에 관한 것이다.The present invention relates to a liquid packaging container material formed by melt-kneading 0.3 to 3% by weight of silicone oil in a high density polyethylene, a low density polyethylene or a polypropylene resin in a plastic packaging container.

본 발명에 따르면 폴리에틸렌 또는 폴리프로필렌수지에 실리콘 오일을 0.3 내지 3 중량% 혼합하여 컴파운드된 재료를 사용할 수도 있고, 실리콘 오일과 상기 수지를 혼합하여 마스타 배치(Master Batch)제조 후 이 마스타 배치를 수지와 혼합하여 사용할 수도 있다.According to the present invention, a compound compounded by mixing 0.3 to 3% by weight of silicone oil in polyethylene or polypropylene resin may be used, and after mixing the silicone oil and the resin to prepare a master batch, the master batch may be mixed with a resin. It can also be mixed and used.

이때 용기중 실리콘 오일 함량을 0.3 중량% 이하로 사용할 경우에는 용기면의 마찰력 감소효과가 기대한 만큼 나타나지 않으며, 실리콘 오일을 3 중량%이상 사용할 경우에는 시릴콘 함량 증가에 비례한 용기면의 또렷한 마찰력 감소 효과가 나타나지 않으며, 또한 용기에 스크린 인쇄시 잉크의 점착력이 저하된느 문제점이 발생할 수 있다.In this case, when the silicone oil content in the container is used at 0.3% by weight or less, the frictional force reduction effect of the container surface does not appear as expected, and when the silicone oil is used in an amount of 3% by weight or more, the friction surface of the container is proportional to the increase in the content of cyrylcone There is no reduction effect, and may also cause a problem that the adhesion of the ink is lowered when screen printing on the container.

본 발명에 따른 액체제품 용기재료를 제조할 때 바람직하게 이용할 수 있는 방법으로는 중공성형법 또는 인젝션 블로우법을 들 수 있다.The method which can be preferably used when preparing the liquid product container material according to the present invention includes a blow molding method or an injection blow method.

본 발명에 따른 재료의 쉬트(Sheet)는 폴리에틸렌만으로 제조된 쉬트에 비해 마찰력이 현저하게 감소된 것으로 나타났으며(표 1참조), 본 발명에 따라 제조된 용기 또한 고점도 액체제품 사용시 내용물의 유동성이 월등히 향상된 것으로 나타났다(표 2참조).The sheet of the material according to the present invention was found to have a significantly reduced friction compared to the sheet made of polyethylene only (see Table 1), and the container prepared according to the present invention also has a fluidity of the contents when using a high viscosity liquid product. Significantly improved (see Table 2).

이하 본 발명을 하기 실시예에 의해 더욱 구체적으로 설명한다.Hereinafter, the present invention will be described in more detail with reference to the following examples.

그러나 이들 실시예는 본 발명을 구체적으로 설명하기 위한 것일뿐 어떤 형태로든 본 발명의 기술적 범위가 이들 실시예로 한정되는 것은 아니다.However, these examples are only for illustrating the present invention in detail, and the technical scope of the present invention in any form is not limited to these examples.

(실시예 1)(Example 1)

저밀도 폴리에틸렌에 실리콘 오일을 8중량% 용융 혼련하여 펠렛(Pellet)상의 마스타 배치를 제조하였다.A master batch of pellets was prepared by melt kneading 8% by weight of silicone oil in low density polyethylene.

(실시예 2)(Example 2)

고밀도 폴리에틸렌에 실시예 1의 마스타 배치를 2 중량% 혼합하여 핫프레스(hot press)방법으로 두께 1mm의 쉬트를 제조하였다(전체쉬트에 대한 실리콘 오일의 함량: 0.16중량%)2 wt% of the master batch of Example 1 was mixed with high density polyethylene to prepare a sheet having a thickness of 1 mm by a hot press method (content of silicone oil relative to the total sheet: 0.16 wt%).

(실시예 3)(Example 3)

고밀도 폴리에틸렌에 실시예 1의 마스타 배치를 10 중량% 혼합하여 실시예 2와 동일한 쉬트를 제조하였다(전체쉬트에 대한 실리콘오일의 함량: 0.8중량%)The same sheet as in Example 2 was prepared by mixing 10 wt% of the master batch of Example 1 in high density polyethylene (content of silicon oil relative to the whole sheet: 0.8 wt%).

(실시예 4)(Example 4)

고밀도 폴리에틸렌에 실시예 1의 마스타 배치를 30중량% 혼합하여 실시예 2와 동일한 쉬트를 제조하였다(전체쉬트에 대한 실리콘오일의 함량: 2.4 중량%)The same sheet as in Example 2 was prepared by mixing 30 wt% of the master batch of Example 1 in high-density polyethylene (content of silicone oil in the total sheet: 2.4 wt%).

(실시예 5)(Example 5)

고밀도 폴리에틸렌에 실시예 1의 마스타 배치를 40중량% 혼합하여 실시예 2와 동일한 쉬트를 제조하였다(전체쉬트에 대한 실리콘오일의 함량: 3.2 중량%)The same sheet as in Example 2 was prepared by mixing 40 wt% of the master batch of Example 1 in high density polyethylene (content of silicone oil relative to the whole sheet: 3.2 wt%).

(실시예 6)(Example 6)

고밀도 폴리에틸렌에 실시예 1의 마스타 배치를 2 중량% 혼합하여 중공 성형법으로 용량 250㎖의 용기를 성형하였다(전체용기에 대한 실리콘오일의 함량: 0.16 중량%)The master batch of Example 1 was mixed with 2% by weight of high density polyethylene to form a container having a capacity of 250 ml by the blow molding method (content of silicone oil in the total container: 0.16% by weight).

(실시예 7)(Example 7)

고밀도 폴리에틸렌에 실시예 1의 마스타 배치를 5 중량% 혼합하여 실시예 6과 동일한 용기를 성형하였다(전체용기에 대한 실리콘오일의 함량: 0.4 중량%)The same container as in Example 6 was formed by mixing 5% by weight of the master batch of Example 1 in high density polyethylene (content of silicone oil: 0.4% by weight of the total container).

(실시예 8)(Example 8)

고밀도 폴리에틸렌에 실시예 1의 마스타 배치를 10 중량% 혼합하여 실시예 6과 동일한 용기를 성형하였다(전체용기에 대한 실리콘오일의 함량: 0,8중량%)The same container as in Example 6 was formed by mixing 10% by weight of the master batch of Example 1 in high density polyethylene (content of silicone oil in the total container: 0,8% by weight).

(비교예 1)(Comparative Example 1)

고밀도 폴리에틸렌만 사용하여 실시예2와 동일한 쉬트를 제조하였다.The same sheet as in Example 2 was prepared using only high density polyethylene.

(비교예 2)(Comparative Example 2)

고밀도 폴릴에틸렌에 저밀도 폴리에틸렌을 30 중량% 혼합하여 실시예 2와 동일한 쉬트를 제조하였다.The same sheet as in Example 2 was prepared by mixing 30% by weight of low density polyethylene with high density polyethylene.

(비교예 3)(Comparative Example 3)

고밀도 폴리에틸렌만 사용하여 실시예 6와 동일한 쉬트를 제조하였다.The same sheet as in Example 6 was prepared using only high density polyethylene.

(실험예 1 : 마찰력 비교)(Experimental example 1: comparison of frictional force)

본 발명에 따른 용기재료의 마찰력은 하기의 방법에 의해 측정되었다.The frictional force of the container material according to the present invention was measured by the following method.

재질 조성별 마찰력 비교를 위해 실시예 2, 3, 4 및 5 및 비교예 1 및 2의 쉬트를 마찰 시험기를 이용하여 마찰값을 측정하였으며, 또한 관능평가로 쉬트의 매끄럼움 정도를 평가하였다.In order to compare the frictional force by material composition, the friction values of the sheets of Examples 2, 3, 4, and 5 and Comparative Examples 1 and 2 were measured using a friction tester, and the degree of smoothness of the sheets was evaluated by sensory evaluation.

이때 마찰값은 수치가 낮을수록, 관능평가는 매끄러울수록 쉬트의 마찰력은 낮은 것으로 해석한다.The lower the friction value, the smoother the sensory evaluation, the lower the frictional force of the sheet.

[표 1 : 마찰력 비교]Table 1: Friction Force Comparison

상기 표 1의 결과로부터 실리콘오일을 함유한 실시예 3, 4 및 5의 쉬트는 실리콘오일을 함유하지 않은 비교예 1 및 2의 쉬트에 비해 마찰력이 월등히 낮은 것을 확인할 수 있다.From the results of Table 1, the sheets of Examples 3, 4, and 5 containing silicon oil may be found to have significantly lower friction than the sheets of Comparative Examples 1 and 2 containing no silicone oil.

(실험예 2 : 내용물 소량 잔존시 유동성 비교)(Experimental Example 2: Comparison of Fluidity when Small Contents Remain)

실시예 6, 7, 8 및 비교예 3의 용기에 점도 50PS의 두발용 화장품 내용물을 40g 충진하고 용기를 180˚각도로 거꾸로 매달아 10초간 경과후 흘러내린 내용물의 양을 측정하였으며, 유출된 내용물 양이 많을수록 유동성이 우수한 것으로 평가하였다.The container of Examples 6, 7, 8 and Comparative Example 3 was filled with 40g of the hair cosmetic content with a viscosity of 50 PS, and the container was suspended upside down at 180 ° angle to measure the amount of the content which flowed down after 10 seconds. The more, the more excellent the fluidity was evaluated.

[표 2.유동성 비교][Table 2. Liquidity Comparison]

상기 표 2의 결과로부터 고점도 액체 제품의 유동성은 실시예 7및 8의 용기가 비교예 3의 용기보다 월등히 우수하다는 것을 확인할 수 있다.From the results in Table 2, it can be seen that the fluidity of the high viscosity liquid product is much better than that of the containers of Examples 7 and 8.

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Claims (4)

플라스틱 포장 용기에 있어서, 폴리에틸렌 또는 폴리프로필렌 수지에 실리콘 오일 0.3 내지 3 중량% 를 용융혼련시켜 성형한 고점도 액체제품 포장용기 재료.A plastic packaging container comprising: a high viscosity liquid product packaging container material formed by melt-kneading 0.3 to 3% by weight of silicone oil in polyethylene or polypropylene resin. 제 1항에 있어서, 실리콘 오일이 마스타배치 또는 컴파운드 방법으로 용기에 첨가된 것인 포장용기 재료.The packaging container material of claim 1, wherein the silicone oil is added to the container by a masterbatch or compound method. 제 1항에 있어서, 중공성형 또는 인젝션 불로우 방법으로 제조한 포장용기 재료.The packaging material of claim 1, wherein the packaging material is produced by blow molding or injection blow. 제 1항에 있어서, 고점도 액체제품이 주방용 세제, 두발용 화장품, 기초 화장품 또는 액상 조미료인 포장용기 재료.The packaging container material of claim 1, wherein the high viscosity liquid product is a kitchen detergent, a hair cosmetic, a basic cosmetic, or a liquid seasoning.
KR1019960032160A 1996-08-01 1996-08-01 Package container material for high viscosity liquid products KR100190816B1 (en)

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KR1019960032160A KR100190816B1 (en) 1996-08-01 1996-08-01 Package container material for high viscosity liquid products

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KR1019960032160A KR100190816B1 (en) 1996-08-01 1996-08-01 Package container material for high viscosity liquid products

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KR19980013608A KR19980013608A (en) 1998-05-15
KR100190816B1 true KR100190816B1 (en) 1999-06-01

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