KR100359384B1 - Coating chain and there coating method - Google Patents

Coating chain and there coating method Download PDF

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Publication number
KR100359384B1
KR100359384B1 KR1019990031762A KR19990031762A KR100359384B1 KR 100359384 B1 KR100359384 B1 KR 100359384B1 KR 1019990031762 A KR1019990031762 A KR 1019990031762A KR 19990031762 A KR19990031762 A KR 19990031762A KR 100359384 B1 KR100359384 B1 KR 100359384B1
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South Korea
Prior art keywords
chain
parts
weight
coating
pigment
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KR1019990031762A
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Korean (ko)
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KR19990083783A (en
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김원철
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화성계전(주)
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Priority to KR1019990031762A priority Critical patent/KR100359384B1/en
Publication of KR19990083783A publication Critical patent/KR19990083783A/en
Priority to AU46230/00A priority patent/AU4623000A/en
Priority to PCT/KR2000/000529 priority patent/WO2001007527A1/en
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Publication of KR100359384B1 publication Critical patent/KR100359384B1/en
Priority to US10/400,720 priority patent/US20030185994A1/en

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/04—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C09D127/06—Homopolymers or copolymers of vinyl chloride
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00—Processes for applying liquids or other fluent materials
    • B05D1/16—Flocking otherwise than by spraying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00—Processes for applying liquids or other fluent materials
    • B05D1/18—Processes for applying liquids or other fluent materials performed by dipping
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/02—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
    • B05D3/0218—Pretreatment, e.g. heating the substrate

Abstract

PURPOSE: Provided is a method for coating a chain comprising a plurality of rings with a fluorescent pigment or a common coloring pigment to produce a chain which is not eroded even when it is exposed to water for a long period of time and has an aesthetic appearance. CONSTITUTION: The method includes the steps of mixing 100 weight parts of polyvinylchloride, 0.5 to 2.0 weight parts of a plasticizer, 0.05 to 0.1 weight parts of a filler, 0.01 to 1.0 weight parts of a stabilizer and 0.05 to 3.0 weight parts of a pigment to form a coating solution; preheating a chain comprising a plurality of rings at about 150 to 350 deg.C for 1 to 2 minutes; dipping the preheated chain in the coating solution, followed by heating at 150 to 350 deg.C for 1 to 2 minutes and cooling the chain to the ambient temperature.

Description

체인 코팅방법.{COATING CHAIN AND THERE COATING METHOD}Chain coating method. {COATING CHAIN AND THERE COATING METHOD}

본 발명은 다수개의 링으로 구성된 체인에 관한 것으로서, 특히 체인의 표면에 형광안료 또는 일반 색상안료를 코팅 처리하는 방법에 관한 것이다.The present invention relates to a chain consisting of a plurality of rings, and more particularly to a method of coating a fluorescent pigment or a general color pigment on the surface of the chain.

통상적으로, 체인은 장공 타입의 링이 서로 연결되어 구성된 것이며, 이러한 체인은 현재 국/내외에서 다양한 용도로 활용되고 있는 실정이다. 한편 이러한 체인의 구성 및 용도는 이미 널리 공지된 기술이기 때문에 상세한 설명은 생략하기로 한다.In general, the chain is composed of a ring-type ring is connected to each other, the chain is currently being used for a variety of purposes in and outside the country. On the other hand, since the configuration and use of such a chain is already well known technology, a detailed description thereof will be omitted.

그러나, 이러한 체인은 그 자체가 물을 접하게 되면 쉽게 부식될 뿐만 아니라 촉감 자체가 차가우며, 또한 외관상 투박하여 사용자로 하여금 불쾌감을 야기시켰다. 또한 상기 체인은 각 사용처에서 완벽한 효과를 구현하지 못하고, 특히 가이드 레일, 등산로, 선박, 주차장 E/L 등에 사용된 체인은 안전성에 많은 문제점을 가지고 있다.However, these chains themselves are not only easily corroded when they come in contact with water, they are also cold to the touch, and they are also coarse in appearance, causing user discomfort. In addition, the chain does not implement a perfect effect in each use, especially the chain used for guide rails, hiking trails, ships, parking lot E / L has a lot of safety problems.

한편, 대한민국 공개실용신안공보 공개번호 제 98-59714 호에는 목걸이, 팔지를 구성하는 구슬의 일부분에 야광 또는 형광층을 형성시킨 장신구용 체인이 공개된 바가 있다.On the other hand, the Republic of Korea Utility Model Publication No. 98-59714 discloses a chain for ornaments formed by forming a luminous or fluorescent layer on a portion of the beads constituting the necklace, arm.

이러한 선출원 공개고안은 체인을 구성하고 있는 구슬에 홈을 형성한 후 여기에 야광액을 충전하여 구성된 것이며, 이는 통상의 체인, 상세하게는 장공 타입의 링으로 구성된 체인에는 적용할 수 없는 기술이다. 즉, 통상의 체인 링에는 홈을 형성할 수 없을 뿐만 아니라 설사 홈을 형성한다 해도 전술한 문제점을 해소할 수 없는 단점이 예상된다.Such a prior application disclosure is formed by forming a groove in a bead constituting the chain and filling it with a luminous liquid, which is not applicable to a general chain, in particular, a chain composed of a ring-type ring. That is, not only the grooves can be formed in the ordinary chain ring, but the above-described problems cannot be solved even if the grooves are formed.

따라서, 상기한 바와 같은 문제점을 해결하기 위한 본 발명의 목적은 형광안료 또는 일반 색상안료로 조성된 코팅액을 체인의 표면에 코팅하는 방법을 제공함에 있다.Therefore, an object of the present invention for solving the above problems is to provide a method for coating the surface of the chain with a coating liquid composed of a fluorescent pigment or a general color pigment.

본 발명의 다른 목적은 다수개의 링으로 구성된 체인의 촉감을 향상시키고, 야간에 식별 가능하도록 체인을 코팅하는 방법을 제공함에 있다.Another object of the present invention is to provide a method of improving the feel of a chain composed of a plurality of rings and coating the chain to be distinguishable at night.

상기한 목적을 달성하기 위한 제1 견제에 따른 본 발명은, 통상의 체인을 약 150~350℃에서 1~2분 동안 예열한 다음, 이를 소정의 조성물로 혼합된 코팅액으로 디핑처리한 후, 상기 코팅 처리된 체인을 150~350℃에서 1~2분 동안 열처리한 다음, 이를 대기 온도까지 냉각 처리하여 코팅하는 방법을 구현하였다.The present invention according to the first check for achieving the above object, after preheating the conventional chain for about 1 to 2 minutes at about 150 ~ 350 ℃, and then dipping it with a coating liquid mixed with a predetermined composition, the The coated chain was heat-treated at 150 to 350 ° C. for 1 to 2 minutes, and then cooled to ambient temperature to implement a coating method.

보다 바람직하기로는, 폴리염화비닐 100 중량부와 0.5~2 중량부의 가소제, 0.05~0.1 중량부의 충진제 및 0.01~1.0 중량부의 안정제, 그리고 0.05~3.0 중량부의 안료를 혼합하여 조성된 코팅액을 구현하였다.More preferably, the coating solution is prepared by mixing 100 parts by weight of polyvinyl chloride, 0.5 to 2 parts by weight of a plasticizer, 0.05 to 0.1 parts by weight of a filler, 0.01 to 1.0 parts by weight of a stabilizer, and 0.05 to 3.0 parts by weight of a pigment.

이하 본 발명에 따른 바람직한 실시 예를 상세히 설명한다. 그리고, 하기의 설명에서는 본 발명의 체인 코팅방법을 이해하는데 필요한 부분만이 설명되며, 그 이외 부분의 설명은 본 발명의 요지를 흐트리지 않도록 생략될 것이라는 것을 유의하여야 한다.Hereinafter, preferred embodiments of the present invention will be described in detail. In the following description, only parts necessary for understanding the chain coating method of the present invention will be described, and it should be noted that the description of other parts will be omitted so as not to obscure the subject matter of the present invention.

우선, 본 발명은 쇠로 제작된 통상의 체인, 즉 장공 타입으로 형성된 다수개의 링들이 서로 연결되어 구성된 체인의 표면을 코팅 처리하는 것이다. 상세하게는 전술한 체인을 예열기에 투입한 후 약 150~350℃에서 1~2분 동안 예열시킨 다음, 이를 본 발명의 주요 구성요소인 코팅액으로 디핑 처리한다.First, the present invention is to coat the surface of a conventional chain made of steel, that is, a chain composed of a plurality of rings formed in a long hole type connected to each other. Specifically, the chain is introduced into the preheater and then preheated at about 150 to 350 ° C. for 1 to 2 minutes, which is then dipped into the coating liquid, which is the main component of the present invention.

한편, 상기의 코팅액은 수지를 주성분으로 하고 여기에 가소제, 충진제, 안정제 및 형광안료 또는 일반 색상안료로 조성된 것이다. 즉, 상기 코팅액은 폴리염화비닐 100 중량부와 가소제 0.5~2 중량부, 충진제 0.05~0.1 중량부, 안정제 0.01~1.0 중량부 및 형광안료 또는 일반 색상안료 0.05~3.0 중량부를 서로 혼합하여 제조된 것이다.On the other hand, the coating solution is a resin as a main component and is composed of a plasticizer, a filler, a stabilizer and a fluorescent pigment or a general color pigment. That is, the coating solution is prepared by mixing 100 parts by weight of polyvinyl chloride, 0.5 to 2 parts by weight of plasticizer, 0.05 to 0.1 parts by weight of filler, 0.01 to 1.0 parts by weight of stabilizer, and 0.05 to 3.0 parts by weight of fluorescent pigment or general color pigment. .

여기서 상기 가소제로는 3가지 물질 중에서 어느 하나를 선택하여 사용되며, 이는 D-2 헥실 프탈레이트(D-2 HEXYL PHTHALATE: 이하 "DOP"라 함), D-부틸 프탈레이트(D-BUTYL PHTHALATE: 이하 "DBP"라 함) 및 D-이소 프탈레이트(D-ISO PHTHALATE: 이하 "DOA"라 함)이다.Wherein the plasticizer is used to select any one of the three materials, which is D-2 hexyl phthalate (D-2 HEXYL PHTHALATE: "DOP"), D-butyl phthalate (D-BUTYL PHTHALATE: " DBP ”) and D-iso phthalate (D-ISO PHTHALATE: hereinafter referred to as“ DOA ”).

한편 상기 충진제로는 탄산칼슘 등이 사용되며, 상기 안정제는 주로 분말형태의 바륨 스트레이트 또는 카륨 아연에 액상 BC 103을 섞어 사용된다.Meanwhile, calcium carbonate and the like are used as the filler, and the stabilizer is mainly used by mixing liquid BC 103 in barium straight or carium zinc in powder form.

그리고 상기 안료로는 형광안료 또는 일반 색상안료가 사용된다. 이때 상기 형광안료는 노란색 또는 오렌지색 혹은 밝은 녹색을 띄게 되며, 또한 AV Partile size: 5N, Light Fastness: 3, Heat stability: 110~230F, Oil Absorption: 30~35% 및 Moisture content: 3.5%의 물리적 특성을 가진다. 또한 전술한 일반 색상안료는 통상의 색상을 띄게 된다.As the pigment, a fluorescent pigment or a general color pigment is used. In this case, the fluorescent pigment is yellow, orange, or light green, and also has AV Partile size: 5N, Light Fastness: 3, Heat stability: 110 to 230F, Oil Absorption: 30 to 35%, and Moisture content: 3.5% Has In addition, the above-mentioned general color pigments will have a normal color.

이하, 본 발명의 바람직한 실시 예에 의거 상세히 설명하겠는 바, 상기 본 발명이 실시 예에 의해 한정되는 것은 아니다.Hereinafter, the present invention will be described in detail based on the preferred embodiment of the present invention, but the present invention is not limited to the embodiment.

[실시예 1]Example 1

폴리염화비닐 100 중량부와 1.0 중량부의 DOP, 0.08 중량부의 탄산칼슘 및 0.07 중량부의 바륨 스트레이트, 그리고 1.0 중량부의 형광안료, 바람직하게는 전술한 물리적 특성을 가지는 형광안료 1.0 중량부를 서로 혼합시켜 코팅액을 제조한다.100 parts by weight of polyvinyl chloride, 1.0 parts by weight of DOP, 0.08 parts by weight of calcium carbonate and 0.07 parts by weight of barium straight, and 1.0 parts by weight of fluorescent pigments, preferably 1.0 parts by weight of fluorescent pigments having the above-described physical properties, were mixed with each other. Manufacture.

다음, 쇠로 제작된 체인을 200℃에서 약 1분 동안 예열시킨 후, 이를 전술한 코팅액으로 디핑처리한 다음, 약 250℃의 온도에서 1분 30초 동안 열처리한 후, 곧바로 송풍로 안으로 투입시켜 대기 온도까지 냉각시켜 야광 코팅층이 형성된 체인을 만든다.Next, the steel chain was preheated at 200 ° C. for about 1 minute, then dipped with the coating solution described above, and then heat treated at a temperature of about 250 ° C. for 1 minute 30 seconds. Cool to temperature to form a chain with a luminous coating layer.

[실시예 2]Example 2

폴리염화비닐 100 중량부와 1.5 중량부의 DBP, 0.1 중량부의 탄산칼슘 및 0.05 중량부의 카륨 아연, 그리고 3.0 중량부의 일반 색상안료, 바람직하게는 노란색의 안료를 서로 혼합시켜 코팅액을 제조한다.A coating solution is prepared by mixing 100 parts by weight of polyvinyl chloride, 1.5 parts by weight of DBP, 0.1 parts by weight of calcium carbonate and 0.05 parts of carium zinc, and 3.0 parts by weight of general color pigments, preferably yellow pigments.

다음, 쇠로 제작된 체인을 320℃에서 약 2분 동안 예열시킨 후, 이를 전술한 코팅액으로 디핑처리한 다음, 약 250℃의 온도에서 2분 동안 열처리한 후, 곧바로 송풍로 안으로 투입시켜 대기 온도까지 냉각시킨다. 그러면 노락색의 코팅층이 형성된 체인이 만들어지게 된다.Next, the steel chain was preheated at 320 ° C. for about 2 minutes, then dipped with the coating solution described above, then heat treated at a temperature of about 250 ° C. for 2 minutes, and then immediately introduced into an air furnace to an atmospheric temperature. Cool. Then, a chain having a yellow coating layer is formed.

[실시예 3]Example 3

폴리염화비닐 100 중량부와 2.0 중량부의 DOA, 0.1 중량부의 탄산칼슘 및 0.1 중량부의 카륨 아연, 그리고 1.5 중량부의 형광안료, 바람직하게는 전술한 물리적 특성을 가지는 형광안료 1.5 중량부를 서로 혼합시켜 코팅액을 제조한다.100 parts by weight of polyvinyl chloride, 2.0 parts by weight of DOA, 0.1 parts by weight of calcium carbonate and 0.1 parts by weight of carium zinc, and 1.5 parts by weight of fluorescent pigments, preferably 1.5 parts by weight of fluorescent pigments having the above-mentioned physical properties, were mixed with each other. Manufacture.

다음, 쇠로 제작된 체인을 320℃에서 약 2분 동안 예열시킨 후, 이를 전술한 코팅액으로 디핑처리한 다음, 약 250℃의 온도에서 2분 동안 열처리한 후, 곧바로 송풍로 안으로 투입시켜 대기 온도까지 냉각시켜 야광 코팅된 체인을 만든다.Next, the steel chain was preheated at 320 ° C. for about 2 minutes, then dipped with the coating solution described above, then heat treated at a temperature of about 250 ° C. for 2 minutes, and then immediately introduced into an air furnace to an atmospheric temperature. Cool to make a luminous coated chain.

[실시예 4]Example 4

폴리염화비닐 100 중량부와 2.0 중량부의 DOP, 0.1 중량부의 탄산칼슘 및 0.1 중량부의 카륨 아연, 그리고 3.0 중량부의 형광안료, 바람직하게는 전술한 물리적 특성을 가지는 형광안료 3.0 중량부를 서로 혼합시켜 코팅액을 제조한다.100 parts by weight of polyvinyl chloride, 2.0 parts by weight of DOP, 0.1 parts by weight of calcium carbonate and 0.1 parts by weight of zinc, and 3.0 parts by weight of fluorescent pigments, preferably 3.0 parts by weight of fluorescent pigments having the above-described physical properties, were mixed with each other. Manufacture.

다음, 쇠로 제작된 체인을 320℃에서 약 2분 동안 예열시킨 후, 이를 전술한 코팅액으로 디핑처리한 다음, 약 250℃의 온도에서 2분 동안 열처리한 후, 곧바로 송풍로 안으로 투입시켜 대기 온도까지 냉각시켜 야광 코팅된 체인을 만든다.Next, the steel chain was preheated at 320 ° C. for about 2 minutes, then dipped with the coating solution described above, then heat treated at a temperature of about 250 ° C. for 2 minutes, and then immediately introduced into an air furnace to an atmospheric temperature. Cool to make a luminous coated chain.

이상으로 살펴본 바와 같이, 본 발명은 체인의 표면을 코팅 처리함으로써 장기간 물에 노출시켜도 부식되지 않을 뿐만 아니라 미적 감각이 뛰어나며, 또한 체인 촉감이 부드러운 장점을 가지고 있다. 그리고 상기 체인은 꼬임 현상 및 소음이 없을 뿐만 아니라 전기 누전을 방지할 수 있고, 또한 미끄럼을 방지할 수 있는 이점이 있다.As described above, the present invention is not only corroded even after long-term exposure to water by coating the surface of the chain, but also has excellent aesthetics, and has a soft chain feel. In addition, the chain is free from twisting and noise, and also has an advantage of preventing electric leakage and preventing slipping.

특히, 가이드 레일, 등산로, 선박, 주차장 E/L 등에 사용시 종래의 체인보다 안정된 상태에서 사용할 수 있는 이점이 있다. 그리고, 체인의 표면을 야광 코팅처리 함으로써 야간에 식별이 가능하여 사고의 위험으로부터 예방할 수 있으며, 또한 실내장식 및 각종 인테리어 등으로 사용할 수 있는 상승된 효과가 있다.In particular, when used in guide rails, hiking trails, ships, parking lot E / L, there is an advantage that can be used in a stable state than the conventional chain. And, by luminous coating the surface of the chain can be identified at night to prevent from the risk of accidents, there is also an increased effect that can be used for interior decoration and various interiors.

Claims (8)

다수개의 링으로 연결된 체인을 코팅하는 방법에 있어서,In the method of coating a chain connected by a plurality of rings, 폴리염화비닐 100 중량부와 0.5~2.0 중량부의 가소제, 0.05~0.1 중량부의 충진제 및 0.01~1.0 중량부의 안정제, 그리고 0.05~3.0 중량부의 안료를 혼합하여 코팅액을 제조하는 과정과;Preparing a coating liquid by mixing 100 parts by weight of polyvinyl chloride, 0.5 to 2.0 parts by weight of a plasticizer, 0.05 to 0.1 parts by weight of a filler, 0.01 to 1.0 parts by weight of a stabilizer, and 0.05 to 3.0 parts by weight of a pigment; 상기 체인을 약 150~350℃에서 1~2분 동안 예열한 다음, 이를 상기 코팅액으로 디핑처리한 후, 상기 코팅 처리된 체인을 150~350℃에서 1~2분 동안 열처리한 다음, 이를 대기 온도까지 냉각 처리하는 과정으로 이루어짐을 특징으로 하는 체인 코팅방법.The chain is preheated at about 150 to 350 ° C. for 1 to 2 minutes, then dipped into the coating solution, and the coated chain is heat treated at 150 to 350 ° C. for 1 to 2 minutes, and then at ambient temperature. Chain coating method characterized in that the cooling process is made to. 삭제delete 제1항에 있어서, 상기 가소제는 D-2 헥실 프탈레이트, D-부틸 프탈레이트, D-이소 프탈레이트 중에서 선택된 어느 하나임을 특징으로 하는 체인 코팅방법.The method of claim 1, wherein the plasticizer is a chain coating method, characterized in that any one selected from D-2 hexyl phthalate, D- butyl phthalate, D-iso phthalate. 제1항에 있어서, 상기 충진제는 탄산칼슘 임을 특징으로 하는 체인 코팅방법.The method of claim 1, wherein the filler is calcium carbonate. 제1항에 있어서, 상기 안정제는 바륨 스트레이트 또는 카륨 아연에 액상 BC 103을 섞어 제조된 것임을 특징으로 하는 체인 코팅방법.The method of claim 1, wherein the stabilizer is a chain coating method, characterized in that prepared by mixing liquid BC 103 in barium straight or carium zinc. 제1항에 있어서, 상기 안료는 형광안료 또는 일반 색상안료 임을 특징으로 하는 체인 코팅방법.The chain coating method of claim 1, wherein the pigment is a fluorescent pigment or a general color pigment. 삭제delete 삭제delete
KR1019990031762A 1999-07-28 1999-07-28 Coating chain and there coating method KR100359384B1 (en)

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PCT/KR2000/000529 WO2001007527A1 (en) 1999-07-28 2000-05-25 Coated chain and method for coating chain
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KR20030018198A (en) * 2001-08-27 2003-03-06 화성계전(주) Safety cap and coating method for noctilucence coating
KR20030048777A (en) * 2001-12-13 2003-06-25 황세주 Tongs and tongs' manufacture method of clothes hanger

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DE3933903A1 (en) * 1989-10-11 1991-04-18 Basf Ag FLUORESCENT PIGMENTS
JPH0411661A (en) * 1990-02-09 1992-01-16 Showa Electric Wire & Cable Co Ltd Fluorescent thermoplastic resin composition
BR9304587A (en) * 1993-11-29 1995-07-18 Pereira Paulo Celso Fi Cerello System used to bathe in chain and padlock
DE19623495A1 (en) * 1996-06-12 1997-12-18 Ema Elektro Maschinen Schultze Process for coating a workpiece

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