KR100358082B1 - Stain removal cleaner composition - Google Patents
Stain removal cleaner composition Download PDFInfo
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- KR100358082B1 KR100358082B1 KR1019940038781A KR19940038781A KR100358082B1 KR 100358082 B1 KR100358082 B1 KR 100358082B1 KR 1019940038781 A KR1019940038781 A KR 1019940038781A KR 19940038781 A KR19940038781 A KR 19940038781A KR 100358082 B1 KR100358082 B1 KR 100358082B1
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- detergent composition
- ether
- oxyethylene
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- 239000000203 mixture Substances 0.000 title claims abstract description 30
- 239000003599 detergent Substances 0.000 claims abstract description 22
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 16
- 238000004140 cleaning Methods 0.000 claims abstract description 13
- -1 oxyethylene oxypropylene alkyl ether Chemical class 0.000 claims abstract description 12
- 239000000443 aerosol Substances 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 8
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 claims abstract description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000007921 spray Substances 0.000 claims abstract description 7
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims abstract description 6
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 claims abstract description 6
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims abstract description 6
- 239000011976 maleic acid Substances 0.000 claims abstract description 6
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims abstract description 6
- 235000010288 sodium nitrite Nutrition 0.000 claims abstract description 4
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims abstract description 3
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims abstract description 3
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims abstract description 3
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000005642 Oleic acid Substances 0.000 claims abstract description 3
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 3
- 235000021314 Palmitic acid Nutrition 0.000 claims abstract description 3
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 3
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910021538 borax Inorganic materials 0.000 claims abstract description 3
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims abstract description 3
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 claims abstract description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 3
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims abstract description 3
- 235000021313 oleic acid Nutrition 0.000 claims abstract description 3
- 239000010452 phosphate Substances 0.000 claims abstract description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 3
- 239000004328 sodium tetraborate Substances 0.000 claims abstract description 3
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 3
- 239000008117 stearic acid Substances 0.000 claims abstract description 3
- 239000003795 chemical substances by application Substances 0.000 claims abstract 2
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 claims abstract 2
- 238000005260 corrosion Methods 0.000 claims description 13
- 230000007797 corrosion Effects 0.000 claims description 12
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 10
- 239000000194 fatty acid Substances 0.000 claims description 10
- 229930195729 fatty acid Natural products 0.000 claims description 10
- 150000004665 fatty acids Chemical class 0.000 claims description 10
- 239000003112 inhibitor Substances 0.000 claims description 9
- 239000004615 ingredient Substances 0.000 claims description 2
- 239000007788 liquid Substances 0.000 abstract description 4
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 abstract 1
- 239000001630 malic acid Substances 0.000 abstract 1
- 235000011090 malic acid Nutrition 0.000 abstract 1
- 238000005406 washing Methods 0.000 description 12
- 230000000694 effects Effects 0.000 description 6
- 239000003921 oil Substances 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 4
- 239000012141 concentrate Substances 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical class OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 238000011109 contamination Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000000428 dust Substances 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 235000021472 generally recognized as safe Nutrition 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- 241000207199 Citrus Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 210000003746 feather Anatomy 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 235000013310 margarine Nutrition 0.000 description 1
- 239000003264 margarine Substances 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 235000004252 protein component Nutrition 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 229950011008 tetrachloroethylene Drugs 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
- C11D3/187—Hydrocarbons aromatic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0043—For use with aerosol devices
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0073—Anticorrosion compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
-
- C11D2111/12—
Abstract
Description
본 발명은 부분 세척용 세제조성물에 관한 것으로서, 더욱 상세하게는 천연식물성 용제인 디리모넨, 유화제, 고급지방산 및 부식방지제가 특정비율로 혼합구성된 화합물을 알콜계 또는 물을 용매로 하여 녹이고 이것을 용도에 따라 에어로졸스프레이 또는 농축액 형태로 만든 와이셔츠, 블라우스, 교복 등의 깃, 소매 부분의 세척에 유용한 부분 세척용 세제조성물에 관한 것이다.The present invention relates to a detergent composition for partial washing, and more particularly, a compound in which a natural vegetable solvent, dirimonene, an emulsifier, a higher fatty acid, and a corrosion inhibitor is mixed at a specific ratio, is dissolved in an alcoholic or water solvent and used for this purpose. Accordingly, the present invention relates to a detergent composition for partial cleaning, which is useful for cleaning collars and sleeves of shirts, blouses, school uniforms and the like in the form of aerosol sprays or concentrates.
종래의 깃, 소매 부분의 세척용 세제는 미국특허 제4,842,762호에서 개시된 바와 같이 주로 LAB(직쇄알킬벤젠계), ABS(알킬벤젠술폰산염), AOS(알파올레핀술폰산염)과 같은 광물성 유화제와 지방산 알콜인 식물성 유화제를 주재로 한 스틱형이 주종이었다.Conventional detergents for cleaning feathers and sleeves include fatty emulsifiers and fatty acids such as LAB (straight alkylbenzene based), ABS (alkylbenzenesulfonate), AOS (alphaolefinsulfonate), as disclosed in US Pat. No. 4,842,762. A stick type mainly based on the vegetable emulsifier which is alcohol was dominant.
이들 세제의 경우 와이셔츠 깃 또는 소매에 부착된 먼지나 매연, 피부 분비물과 같은 유지성분, 피부각질과 같은 단백질 성분들을 어느 정도까지는 세탁할 수 있으나 완전하게는 세탁할 수 없다. 또한, 스틱형의 경우 사용상의 불편함이 있다.These detergents can, to some extent, wash, but not completely wash, dust, fumes, oily components such as skin secretions, and protein components such as skin exfoliates on shirt collars or sleeves. In addition, in the case of a stick type, there is inconvenience in use.
본 발명에 있어 용제로 사용되는 디리모넨은 천연 감귤류(citrus)껍질의 추출액으로서 브라질, 호주, 미국 및 유럽 등의 오렌지 껍질로부터 증류추출함으로써얻어지는 부산물이다.Dilimonene, which is used as a solvent in the present invention, is a by-product obtained by distillation from orange peels of Brazil, Australia, USA and Europe as an extract of natural citrus peel.
이 디리모넨은 화학구조상으로 터페노이드계로서 10개의 탄소수를 가진 친유성 구조적 특성 때문에 오일 또는 유지성분 오염제거 능력 즉, 디그리싱율(degreasing rate)에 있어 종래의 석유용제인 퍼클로로에틸렌 보다 상대적으로 높다.This dilimonene is relatively higher than the conventional petroleum solvent perchlorethylene in its ability to decontaminate oil or oil components, that is, its degreasing rate, due to its lipophilic structural properties of 10 carbon atoms as terpenoids. .
또한, 디리모넨은 액체로서 155 ℃ 이상의 높은 끓는점을 갖기 때문에 화학적으로 안정성이 있을 뿐 아니라 FDA(미국 식품의약국)에 등재된 자료에 의하면 GRAS(generally recognized as safe)로써 세제로 응용함에 있어서도 문제가 되지 않는다고 한다.In addition, since dilimonene has a high boiling point above 155 ° C as a liquid, it is not only chemically stable but also has problems in application as a detergent as GRAS (generally recognized as safe) according to data registered with the FDA. It is not said.
이와 같은 디리모넨을 실제로 사용한 예로는 미국특허 제4,511,488호와 제4,620,937호 및 영국특허 제1,603,047호 등이 있는 바, 이들 특허에서는 디리모넨을 공업용 세제 조성물에 사용하고 있다. 여기에서는 디리모넨을 공업용 오일등에 의해 오염된 부위를 세정하기 위해 사용되는 크리너에 적용하고 있을 뿐 물세탁에 의한 부분 세정제로서 의류나 고급 직물류에 적용한 예는 없다.Examples of actually using such dilimonene include U.S. Patent Nos. 4,511,488 and 4,620,937, and U.S. Patent No. 1,603,047. In these patents, dilimonene is used in an industrial detergent composition. Herein, dilimonene is applied to cleaners used to clean areas contaminated with industrial oils, and there is no example of applying to clothing or high-quality textiles as a partial cleaning agent by water washing.
따라서, 본 발명자들은 상기와 같은 종래 제품의 결함을 극복하고자 노력한 결과, 천연 오렌지 껍질액인 디리모넨과 유화제를 주성분으로 하고 여기에 고급지방산과 특정 조성의 부식방지제를 특정비율로 혼합한 세제조성물을 알콜 또는 물을 용매로 녹이고 이를 편리하게 사용할 수 있도록 에어로졸 스프레이 또는 농축액 형태로 한 본 발명의 부분 세척용 세제조성물을 개발하게 되었다.Therefore, the present inventors have tried to overcome the defects of the conventional products as described above, as a main component of a dimerene and an emulsifier, a natural orange peel liquid, a high-fat fatty acid and a specific composition of a detergent composition mixed with a corrosion inhibitor of a specific composition Partial cleaning detergent compositions of the present invention have been developed in the form of aerosol sprays or concentrates in order to dissolve alcohol or water in a solvent and to use it conveniently.
이와 같이 본 발명은 디리모넨을 주성분으로 함으로써 세척성이 탁월할 뿐만 아니라 사용상 편리한 부분 세척용 세제조성물을 제공하는데 그 목적이 있다.As such, the present invention has an object of providing a detergent composition for partial washing that is excellent in washability and is convenient for use by using dilimonene as a main component.
본 발명은 부분 세척용 세제조성물에 있어서, 디리모넨과 유화제를 주성분으로 함유하되 디리모넨이 10 ∼ 60 중량%, 유화제가 20 ∼ 55 중량% 함유된 것을 그 특징으로 한다.The present invention is characterized in that the detergent composition for partial washing contains dilimonene and an emulsifier as main components, but contains dirimonene 10 to 60% by weight and emulsifier 20 to 55% by weight.
또한, 본 발명은 상기의 세제조성물 중에 고급지방산 0.1 ∼ 1.5 중랑%, 부식방지제 0.001 ∼ 0.10 중량% 및 알콜 또는 물 10 ∼ 50 중량%가 함유되어 있는 것을 그 특징으로 한다.In addition, the present invention is characterized in that the detergent composition contains 0.1 to 1.5 weight percent of higher fatty acids, 0.001 to 0.10 weight percent of corrosion inhibitor, and 10 to 50 weight percent of alcohol or water.
이와 같은 본 발명을 더욱 상세히 설명하면 다음과 같다.Referring to the present invention in more detail as follows.
본 발명은 천연 오렌지 껍질액인 디리모넨과 유화제를 주성분으로 함으로써 세척성이 탁월하고 사용상 편리한 에어로졸 스프레이 또는 농축액 형태의 부분 세척용 세제조성물에 관한 것으로서 특히, 디리모넨을 사용함에 있어서는 그 사용량을 전체 세제조성에 대해 10 ∼ 60 중량%로 하여 유화제 20 ∼ 55 중량%와 함께 사용하고 이와 더불어서 고급지방산(특히, 말릭산) 0.1 ∼ 1.5 중량% 및 알콜 또는 물 10 ∼ 50 중량%를 함께 조성하여 사용하면 더욱 효과적인 세정효과를 얻을 수가 있다.The present invention relates to a detergent composition for partial washing in the form of an aerosol spray or a concentrated liquid which is excellent in washability by using dirimonene, which is a natural orange peel solution, and an emulsifier. When used in combination with 20 to 55% by weight of emulsifier and 0.1 to 1.5% by weight of higher fatty acids (particularly maleic acid) and 10 to 50% by weight of alcohol or water, Effective cleaning effect can be obtained.
본 발명에서 디리모넨의 함량이 10 중량% 미만이면 기름성분에 대한 세정효과를 발휘하기 어렵고, 60 중량％를 초과하면 유화제와 배합이 맞지 않아 세정력이 떨어진다.In the present invention, if the content of dilimonene is less than 10% by weight, it is difficult to exert a cleaning effect on the oil component, and when the content of dilimonene exceeds 60% by weight, it is incompatible with the emulsifier and the cleaning power is lowered.
또한, 본 발명에서는 유화제로서 옥시에틸렌옥시프로필렌알킬에테르, 옥시에틸렌옥시프로필렌알킬벤젠에테르, 옥시에틸렌라우릴에테르 및 옥시에틸렌알킬벤젠에테르 중에서 선택된 두 가지 이상의 화합물 20 ∼ 50 중량%를 사용하는데, 이러한 유화제는 서로 기능의 일부를 대신할 수는 있으나 완전하지는 못하며 혼용할 경우에만 큰 효과를 얻을 수 있다.In the present invention, 20 to 50% by weight of two or more compounds selected from oxyethylene oxypropylene alkyl ether, oxyethylene oxypropylene alkyl benzene ether, oxyethylene lauryl ether and oxyethylene alkyl benzene ether are used. Can replace some of the functions of each other, but they are not complete and can only have great effects when used together.
여기서 유화제 함량이 20 중량％ 미만이면 세정력이 떨어지고, 55 중량%를 초과하면 유화안정성의 균형이 깨져 장기 보존에 어려움이 있다.If the emulsifier content is less than 20% by weight, the cleaning power is lowered. If the emulsifier content is more than 55% by weight, the balance of emulsification stability is broken, and thus long-term storage is difficult.
그리고 본 발명에 있어서 고급지방산으로는 올레인산, 스테아린산, 팔미트산, 말릭산 및 말레인산 중에서 선택된 하나 또는 두 가지 이상의 혼합물을 0.1 ∼ 1.5 중량% 사용하는데, 그 함량이 0.1 중량% 미만이거나 1.5 중량% 초과시에는 제품의 알카리가 증가하여 세탁시 점유의 손상을 가져올 수 있다.In the present invention, as the higher fatty acid, 0.1 to 1.5% by weight of one or two or more mixtures selected from oleic acid, stearic acid, palmitic acid, maleic acid and maleic acid is used, when the content is less than 0.1% by weight or more than 1.5% by weight. This increases the alkali of the product, which can cause damage to the occupancy during washing.
또한, 본 발명의 세제조성물을 에어로졸 형태로 만들 경우 주석(Tin) 캔의 부식 방지를 목적으로 통상적으로 알려져 있는 여러 부식방지제 중에서도 아질산소다, 보락스, 포스포네이트, 포스페이트, 아민, 벤조에이트, 몰리브데이트, 나이트 라이트를 선택 사용하는데 그 특징이 있다. 특히, 부식방지제는 아질산소다를 필수성분으로 함유하면서 상기에서 예시한 성분들 중에서 선택된 1종 또는 2종 이상이 혼합된 조성으로 사용하였을 때 에어로졸 용기에 적합한 특성 즉, 주석(Tin) 방식성 효과 및 침전안정성 효과를 극대화할 수 있다. 이러한 부식방지제는 0.001 ∼ 0.10 중량％ 첨가하는데, 그 사용량이 0.001 중량％ 미만이면 방식처리가 불충분한 문제가 있고, 0.10 중량％를 초과하면 침전이 생기는 문제가 발생한다.In addition, when making the detergent composition of the present invention in the form of an aerosol, sodium nitrite, borax, phosphonate, phosphate, amine, benzoate, mol among various corrosion inhibitors commonly known for the purpose of preventing corrosion of tin cans. There is a characteristic of using rib date and night light. In particular, the corrosion inhibitor contains sodium nitrite as an essential ingredient and when one or two or more selected from the above exemplified components are used in a mixed composition, it is suitable for aerosol containers, that is, a tin anticorrosive effect and Sedimentation stability effect can be maximized. Although the corrosion inhibitor is added in an amount of 0.001 to 0.10% by weight, if the amount of the corrosion inhibitor is less than 0.001% by weight, there is a problem in that the anticorrosive treatment is insufficient. If the amount is more than 0.10% by weight, precipitation occurs.
한편, 본 발명에서는 상기 디리모넨, 고급지방산, 유화제 등 이외에 용제로 에탄올, 메탄올, 물 등을 첨가한다.On the other hand, in the present invention, ethanol, methanol, water and the like are added to the solvent in addition to the dilimonene, higher fatty acids, emulsifiers and the like.
상기와 같은 본 발명의 에이로졸 스프레이 또는 농축액 형태의 세제조성물은 상기와 같이 디리모넨을 주성분으로 함으로써 인체에 전혀 무해하고 환경오염 방지효과가 있으며, 여기에 고급지방산, 유화제, 부식방지제 등을 특정비율로 조정함으로써 세척력이 뛰어나고 견, 모, 마, 큐프라 등으로 만들어진 옷감의 수축이나 염색 탈리 등의 형태 변화없이 와이셔츠, 블라우스, 교복 등의 깃, 소매의 오염을 깨끗이 제거하는 부분 세척 전문세정제로서 유용하게 사용될 수 있다.Detergent composition in the form of aerosol spray or concentrate of the present invention as described above is a harmless to the human body by the main ingredient of dilimonene as described above and has an environmental pollution prevention effect, high-grade fatty acids, emulsifiers, corrosion inhibitors, etc. By adjusting the ratio, it is excellent in washing power and it is a part cleaning professional cleaner that removes contamination of collars and sleeves of shirts, blouses, school uniforms, etc. without changing the shape such as shrinkage or dyeing of fabric made of silk, wool, hemp, cupra, etc. It can be usefully used as.
이하, 본 발명을 실시예에 의거 상세히 설명하겠는 바, 본 발명이 실시예에 의해 한정되는 것은 아니다.Hereinafter, the present invention will be described in detail with reference to Examples, but the present invention is not limited by Examples.
실시예 1 ∼ 4, 비교예 1 ∼ 3Examples 1-4, Comparative Examples 1-3
다음 표 1의 배합비율에 따라 수성 성분부와 유성 성분부를 각각 혼합하고 55 ∼ 60 ℃, 500 ∼ 3,000 rpm 조건하에서 15 ∼ 30분 동안 유화균질 교반기(AGIHOMO MIXER)로 충분히 배합하여 세제조성물을 제조하였다.Next, the aqueous component and the oil component were mixed according to the mixing ratios of Table 1, and the detergent composition was prepared by sufficiently blending with an emulsion homogenizer (AGIHOMO MIXER) for 15 to 30 minutes at 55 to 60 ° C. and 500 to 3,000 rpm. .
그리고 LPG 충진제를 사용하여 용이하게 분사할 수 있도록 에어로졸 충진을 하였다. 다음 실시예 및 비교예가 특정한 충진제와 에어로졸 타입의 종류에 한정되는 것은 아니다.And aerosol filling was to be easily sprayed using LPG filler. The following examples and comparative examples are not limited to specific types of fillers and aerosol types.
실험예 1Experimental Example 1
상기 실시예 및 비교예에서 제조된 조성물을 시료로 하여 다음과 같은 조건에서 세척력 시험을 실시하였으며, 그 결과는 다음 표 2에 나타낸 바와 같다.Using the compositions prepared in Examples and Comparative Examples as a sample was carried out a washing force test under the following conditions, the results are shown in Table 2 below.
가. 시험편 : 아래 부서에서 1명씩 흰 와이셔츠를 3 일간 착용함.end. Test piece: One white shirt is worn for three days by the following departments.
현장(글리세린반, 공무반) : 현장에서 발생되는 먼지나 기름 등의 오염.Site (glycerine class, public service group): Pollution such as dust or oil generated at the site.
사무실(관리부, 연구개발실) : 관리부의 경우 와이셔츠가 노후되었고 연구실의 경우 찌든 때가 묻어 있음.Office (management department, R & D office): In the management department, the shirt is old and the laboratory is stuck.
기타(창고반, 운전기사) : 가벼운 때와 얼룩이 묻어 있음.Others (warehouse, driver): Light and stained.
나. 조성물 처리방법I. Composition treatment method
오염 부분의 2 cm 높이에서 최대한 빈틈없이 분사함.Spray as tightly as possible at 2 cm height of dirt.
다. 세척과 평가방법All. Cleaning and evaluation method
운전기사, 창고반, 공무반, 글리세린반 : 농축수퍼타이[(주)럭키제품] 1 g/ℓ (표준 사용량)을 30 ℃에서 용해 후 세탁기에 세척하고 자연건조 후 육안 판정함.Driver, Warehouse, Public Service, Glycerin: Concentrate Super Tie (Lucky Co., Ltd.) 1 g / ℓ (standard usage) is dissolved at 30 ℃, washed in a washing machine and visually determined after natural drying.
관리실, 연구실 : 세제없이 그대로 세탁기에 세척하고 자연건조 후 육안 판정함.Management room, laboratory: Wash in the washing machine without detergent and visually determine after drying.
실험예 2Experimental Example 2
상기 실시예 및 비교예에서 제조된 조성물을 시료로 하여 인공 오염포에 대한 오염별 세척력을 시험 평가하였으며, 그 결과는 다음 표 3에 나타낸 바와 같다.Using the compositions prepared in Examples and Comparative Examples as a sample to test the contamination by cleaning for artificial contaminated cloth, the results are shown in Table 3 below.
가. 시험편 : 면 원단의 크기를 10cm x 10cm로 하고, 각각의 원단에 오염으로서 적색 수성잉크, 밀크 커피, 유리창 먼지, 적색 루즈, 구두약, 카본 블랙, 마아가린을 풀바르듯 균일하게 문질러 준비하였다.end. Test piece: The size of the cotton fabric was 10 cm x 10 cm, and each of the fabrics was prepared by rubbing uniformly with red water ink, milk coffee, glass dust, red rouge, bitumen, carbon black, and margarine as contamination.
나. 조성물 처리방법 : 오염 부분의 2 cm 높이에서 최대한 붙여서 빈틈없이분사함.I. Composition treatment method: Spread as tightly as possible at 2 cm height of contaminated part.
다. 세척과 평가방법 : 농축수퍼타이 1 g/ℓ (표준 사용량)을 30 ℃에서 용해 후 세탁기에 세척하고 자연 건조 후 육안 판정.All. Method of washing and evaluation: Dissolve 1 g / l of concentrated water supernatant (standard usage) at 30 ℃, wash it in washing machine and visually judge after natural drying.
실험예 3Experimental Example 3
상기 실시예 및 비교예에시 제조된 세제조성물 시료를 주석(Tin)캔에 넣고 부식을 시험평가하였으며, 그 결과는 다음 표 4에 나타낸 바와 같다.The detergent composition samples prepared in Examples and Comparative Examples were placed in a tin can and tested for corrosion. The results are shown in Table 4 below.
가, 시험평가방법(A) Test Evaluation Method
조성물 시료를 넣은 주석(Tin)캔을 50 ℃의 오븐에 넣고 1주일, 2주일, 1개월, 3개월, 6개월 후 개봉하여 육안으로 부식을 평가하였다.Tin cans containing the composition samples were placed in an oven at 50 ° C., and opened after 1 week, 2 weeks, 1 month, 3 months, and 6 months, and the corrosion was visually evaluated.
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| KR100383539B1 (en) * | 2000-08-17 | 2003-05-12 | 이경일 | Manufacturing Method For Detergent Containing Orange D-limonene |
| KR100356983B1 (en) * | 2000-10-16 | 2002-10-18 | 윤경주 | Mild composition of cleaning material for clothing |
| KR102247764B1 (en) * | 2020-12-31 | 2021-05-03 | 백귀찬 | Liquid typed extinguishing composition for fire extinguisher for kitchen |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0224400A (en) * | 1988-07-13 | 1990-01-26 | Heihachi Hirose | Stain remover |
| KR910003152A (en) * | 1989-07-12 | 1991-02-27 | 이승동 | Anticorrosive |
| JPH03212499A (en) * | 1990-01-18 | 1991-09-18 | Nippon Alpha Metals Kk | Detergent composition for liquid crystal part |
| WO1994016051A1 (en) * | 1993-01-15 | 1994-07-21 | Silk & Clean International Ab | Method and means for cleaning |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0224400A (en) * | 1988-07-13 | 1990-01-26 | Heihachi Hirose | Stain remover |
| KR910003152A (en) * | 1989-07-12 | 1991-02-27 | 이승동 | Anticorrosive |
| JPH03212499A (en) * | 1990-01-18 | 1991-09-18 | Nippon Alpha Metals Kk | Detergent composition for liquid crystal part |
| WO1994016051A1 (en) * | 1993-01-15 | 1994-07-21 | Silk & Clean International Ab | Method and means for cleaning |
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