KR100355149B1 - Soil stabiling materials with seed - Google Patents

Soil stabiling materials with seed Download PDF

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Publication number
KR100355149B1
KR100355149B1 KR1019990027649A KR19990027649A KR100355149B1 KR 100355149 B1 KR100355149 B1 KR 100355149B1 KR 1019990027649 A KR1019990027649 A KR 1019990027649A KR 19990027649 A KR19990027649 A KR 19990027649A KR 100355149 B1 KR100355149 B1 KR 100355149B1
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weight
soil
residues
sludge
residue
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KR1019990027649A
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KR19990073402A (en
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변관정
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변일도
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F11/00Other organic fertilisers
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F3/00Fertilisers from human or animal excrements, e.g. manure
    • C05F3/04Fertilisers from human or animal excrements, e.g. manure from human faecal masses
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K17/00Soil-conditioning materials or soil-stabilising materials
    • C09K17/40Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
    • C09K17/48Organic compounds mixed with inorganic active ingredients, e.g. polymerisation catalysts
    • C09K17/50Organic compounds mixed with inorganic active ingredients, e.g. polymerisation catalysts the organic compound being of natural origin, e.g. cellulose derivatives

Abstract

PURPOSE: Provided is soil for vegetation which has low cohesion and excellent physical property, is used as fertile bed soil, increases frictional force and consistency and shows fertilizing effect. CONSTITUTION: A composition of soil for vegetation is characterized by mixing 20 wt.% of paper sludge, 5 wt.% of activated carbon, 5 wt.% of peat and 20 wt.% of sewage sludge; mixing the mixture thereof with 10 wt.% of soil, 5 wt.% of mineral, 5 wt.% of plant residue, 5 wt.% of animal residue and 5 wt.% of plant processed residue; and adding 5 wt.% of human excrement, and 15 wt.% of waste residue thereto, and mixing them.

Description

식생토{SOIL STABILING MATERIALS WITH SEED}Vegetation soil {SOIL STABILING MATERIALS WITH SEED}

본 발명은 절토지, 암반경사지, 사력지 및 표토가 빈약한 불모의 척박지로 자연식생이 곤란한 지역에 대하여 식물생육에 적합한 식생토와 그 제조방법에 관한 것이다.The present invention relates to a vegetation soil suitable for plant growth in a region where natural vegetation is difficult as a barren barren land with poor cuts, rock slopes, historic sites and topsoil.

일반적으로 무토양 암석지의 경사면 암반녹화공법으로는 경질의 절취사면을 교란하고 물리성을 개량해서 식생의 생육기반을 만드는 객토공법, 객토층이나 흙주머니를 사면에 설치한 테두리로 유지시키는 식목공법, 암반에 소단을 설치하여 L자나 U자의 구조물을 앙카(Anchor)등으로 경사면에 고정시켜 식재용 객토를 하는 테라스 혹은 소단식재공법, 마대에 토사를 채워서 경사진 암반면에 고정 쌓기를 하는 흙망태 쌓기 공법, 경사면 암반에 인공적으로 포켓(Pocket)을 만들어 객토한 후 식재하는 혈공식재공법, 니암이나 풍화암 등 경질의 절취면에 대하여 높은 수압으로 갈라진 가는 금(Crack)모양의 홈(Slit)을 판 후 그 위에 종자 뿜어 붙이기를 하는 워터슈트(Water Chute)파기공법, 암반에 차폐식재로서 목본류나 덩굴성 식물을 도입하는 덩굴식물 녹화공법 등이 꾸준히 개발되어 사용되고 있다.In general, sloped rock reclamation method of soilless rocky land is a landscaping method that disturbs hard cut slopes and improves physical properties to create a vegetation growth base, and a tree planting method that keeps the soil layer or soil bag on the slope. Install a bench on the rock and fix the L-shaped or U-shaped structure to the slope with anchors, etc. Construction method, blood formation method that artificially makes pockets on sloped rock and planted them, and cuts crack-shaped slits that are cracked with high water pressure on hard cutting surfaces such as niam or weathered rock. Water chute digging method of spraying seeds on it, and vine planting method of introducing woody or vine plants as a shielding material to rock This has been used steadily developed.

식생토란 점착성을 가진 녹생토의 일종으로 녹화토를 이용한 녹화공법은 지금까지 암절개지에 국한되었고, 일반 경사법면이나 경토한 법면, 리핑한 법면 같은 비암절개지에는 통상 격자 블럭을 축조하여 기반을 조성한 후 종자를 뿌리거나 잔디를 심어 식물이 자랄 수 있는 환경을 조성해주는 녹화공법이 주로 행해져 왔다.Vegetation soil is a kind of green soil with sticky soil. The greening method using green soil has been limited to dark incisions until now. In general, non-rock incisions such as inclined surface, hard soil, and ripped surface are usually constructed with grid blocks to form seeds. The greening method has been mainly used to create an environment where plants can grow by spraying or planting grass.

국내특허공보 공고번호 제96-1828호는 인공토양의 일종으로서, 자연토양 생활오니 및 제지오니 등을 사용하여 비료성분으로 환원하는 배지의 역할을 한 인공 토양 조성물을 개량한 것으로서, 이와 유사한 종래의 기술은 국내특허출원 출원인 에멘산업녹화주식회사 특허출원번호 제85-8720호(녹생토조성물) 및 제89-13774호(녹생토 조성물)이 있으며, 국내특허출원번호 제88-10388호(법면녹화용 식생메트의 제조방법)이 있고 일본공개특허공보 공개번호 제61-38023호는 함수성 및 보수성을 개량한 법면 녹화공법, 발아성, 점착성, 보수성, 양생성 및 작업성에 중점을 두고 개발된 일본공개특허공보 공개번호 3-180618호 및 3-180619호가 공개되어 있으며, 국내특허출원 출원번호 제85-8720호는 '화산석분말, 피트, 연탄재, 밭 흙, 슬러리케이크, 갈탄, 계분, 미생물제, 수용성 규산, 마그네슘'을 원료로 하고 있고, 국내특허출원 출원번호 제89-13774호는 '피트, 연탄재, 오니케이크 및 펄프슬러지'를 원료로 하고 있어 보비력을 강화하는데는 상당의 성과가 있으나 시공 후 가 물질사이의 접착력이 약하여 절개지의 경사가 심한 경우에는 시공하기 어렵고 또 한파가 심할 시에는 균열이 생겨 수분의 증발이 더욱 심해지는 경향이 있으며, 장기간의 가뭄이 계속될 시에는 비교적 얇게 시공된 부분에 수분이 빨리 증발되어 건조한 상태가 되므로 시공당시의 수분에 의하여 발아된 씨앗이 고사해 버리는 문제점이 있었다.Korean Patent Publication No. 96-1828 is a kind of artificial soil, which is an improvement of an artificial soil composition that serves as a medium for reducing fertilizer components using natural soil sludge and paper sludge. The technology includes the patent application No. 85-8720 (green soil composition) and 89-13774 (green soil composition) of the Emen Industrial Greenery Co., Ltd., which is a domestic patent application applicant, and the Korean patent application No. 88-10388 (vegetable plant for legal greening). Japanese Laid-Open Patent Publication No. 61-38023 is a Japanese green patent publication with a focus on the greening method, germination, adhesiveness, water retention, curing and workability, which improved the functionality and water retention Publication Nos. 3-180618 and 3-180619 are disclosed, and Korean Patent Application No. 85-8720 discloses' volcanic powder, pits, briquettes, field soil, slurry cake, lignite, powder, microbial agent, and water-soluble. 'Silicate and Magnesium' as a raw material, and domestic patent application No. 89-13774 is made of 'pit, briquettes, on-cake and pulp sludge' as raw materials. Due to the weak adhesion between materials, it is difficult to construct when the incision is severely inclined, and when the cold is severe, cracks tend to occur and the evaporation of water tends to be more severe, and in case of prolonged drought, it is relatively thin. Moisture evaporates quickly and becomes a dry state, so there is a problem that the seeds germinated by moisture at the time of construction will die.

또한 일본공개특허번호 공개번호 제61-38023호는 '칼슘계 광물인 토바모라이트를 주분으로 하고 특정직경의 경량기포 콘크리트와 퇴비와의 혼합물에 식물종자, 섬유, 화학비료, 접착제 등'으로 구성하여 함수성과 보수성을 높이기는 하였으나 암반절개지에서는 토양양분의 부족으로 녹화용 식물 선택의 폭이 좁아지는 문제가 있으며, 일본공개특허공보 공개번호 제3-180618호 및 제3-180619호는 '전분 등을 제거한 감자박, 대두박과 보리짚 추비로 된 비료 조성물을 카복실메틸에테르염을 첨가하여 발아성, 점착성, 보수성 및 작업성을 양호하게 개량하여 법면 녹화용으로 사용하였으나 식물성 재료를 주원료로 하고 있어 법면의 장기적인 녹화에는 불리한 점이 많았다.In addition, Japanese Laid-Open Patent Publication No. 61-38023 is composed of 'tobamorite, a calcium-based mineral, mainly composed of plant seeds, fibers, chemical fertilizers, adhesives, etc. in a mixture of lightweight foam concrete and compost with a specific diameter'. However, in rock cutouts, there is a problem that the selection of plants for greening is narrowed due to the lack of soil nutrients, and Japanese Laid-Open Patent Publication Nos. 3-180618 and 3-180619 refer to 'starch, etc.' The fertilizer composition consisting of potato foil, soybean meal and barley straw was removed, and carboxyl methyl ether salt was added to improve germination, adhesiveness, water retention and workability. There were many disadvantages to long-term greening.

국내특허공보 공고번호 제96-1830호는 토목공사의 도로나 부지정지공사 등 절토구간의 경사면 무토양암석지에 일정두께로 피복하여 녹화시키는데 사용하는 인조토양인 음식물발효퇴비에 경량골재, 연탄재, 톱밥, 마사토 혹은 밭 흙, 시멘트, 소석회, 분산재를 첨가 혼합하여 무토양 암석지에 후충기재 뿜어 붙이기 공법에 사용되는 녹생토 조성물의 제조방법에 관한 것이며,Korean Patent Publication No. 96-1830 is a light weight aggregate, briquette, sawdust for food fermentation compost, which is an artificial soil used for covering and planting a certain thickness on slope-free soil rocks of cut sections such as roads and site stop works of civil engineering works. And a method for producing a green soil composition used in the process of spraying the insecticide material on the soil-free rock by adding, mixing, or encapsulating the soil, masato or field soil, cement, lime, and dispersant.

국내특허공보 공고번호 제96-3573호에는 토탄, 오니케이크, 펄프슬러지, 톱밥, 마사토, 지렁이분, 점질균 미생물로 조성된 점녹토조성물이 공개되어 있고,Korean Patent Publication No. 96-3573 discloses a clay nocturnal composition composed of peat, onicake, pulp sludge, sawdust, masato, earthworm powder, and viscous microorganisms,

국내특허공보 공고번호 제96-11616호는 연탄재, 제지부산물, 부숙톱밥, 토탄, 마사토, 보습제메텔 및 유기물로 조성된 부식토조성물에 관한 것임을 알수 있으나,Korean Patent Publication No. 96-11616 discloses a corrosive earth composition composed of briquettes, paper by-products, cooked sawdust, peat, masato, moisturizers, and organics.

시공 후 건조기후로 인한 수분증발로 인하여 비교적 얇게 시공된 부분에는발아된 씨앗의 고사현상과 응집제등 사용으로 인하여 건조 후에는 '콘크리트화'되는 고결 현상으로 종자발아가 불량이거나 추후 비산되어 온 잡초종자의 발아와, 착근을 못하는 현상과, 녹화토 전량에 초목류 종자를 혼합하여 사용하므로 표층 0.5~1Cm이하의 종자는 전량 낭비되고 있고, 이들 종자가 부패시 표층토 내의 발아가능 종자의 발아에도 악영향을 미치는 등의 문제점이 있었다.Due to the evaporation of moisture after drying, the relatively thin parts of the construction may be 'concrete' after drying due to the deadness of the germinated seeds and the use of flocculants, etc. Seed germination, unreachability, and the use of green vegetation seeds in the total amount of greening soil are mixed, so all seeds below 0.5 ~ 1Cm are wasted, and these seeds adversely affect the germination of gerable seeds in surface soil when decaying. There was a problem.

본 발명은 상기와 같은 문제점을 해결하고자 식물 생육에 적합한 식재층을 인공적으로 조성하여 속성녹화를 이루게 하고, 조경수, 정원수의 잔디재배에 특히 적당하며, 주위의 기존군락과 조화 있는 초목을 선별하여 자연적 생태계를 조성하는 인공토양으로서, 영구적으로 토양을 보전함과 동시에 국토녹화 및 경관을 수려하게 할 수 있는 식생토와 그 제조방법을 제공하는데 그 목적이 있다.In order to solve the problems described above, the present invention artificially forms a planting layer suitable for plant growth, thereby achieving attribute greening, and is particularly suitable for lawn cultivation of landscaping water and garden water, and selects vegetation in harmony with surrounding existing communities. As an artificial soil for creating an ecosystem, it aims to provide a vegetated soil and its manufacturing method that can preserve soil permanently and make national greenery and landscape beautiful.

상기한 바와 같은 목적을 달성하기 위하여, 본원 발명은 조경수, 정원수 및 잔디재배에 적당하며 씨앗을 섞어서 투입하며, 거름으로도 활용할 수 있는 제지슬러지, 활성탄, 토탄, 오니류, 인분뇨전사, 식물성 잔재물, 동물성 잔재물, 수산가공 잔재물, 광물성, 흙, 폐기물 등으로 조성된 식생토와 그 제조방법에 관한 것이다.In order to achieve the object as described above, the present invention is suitable for landscaping water, garden water and grass cultivation, mixed with seeds, paper sludge, activated carbon, peat, sludge, manure transcript, plant residues, animal that can be utilized as manure The present invention relates to a vegetation soil composed of residues, fishery residues, minerals, soil, waste, etc. and a method of manufacturing the same.

활성탄은 야자나무껍질 및 숯 등을 사용하여 제조하며, 오니류는 축산폐수, 상하수 및 기타 폐수를 처리한 오니를 사용할 수 있으며, 식물성 잔재물로 표현한 것은 농작물잔사, 톱밥, 왕겨, 수피, 목분 등을 말하며, 동물성 잔재물은 우지, 선지, 육분 및 골분 등이고, 수산가공 잔재물은 어분 및 어패류 등이며, 광물성은 석회석, 인광석, 진주석, 질석, 비석 등이고, 흙은 마사토, 황토, 점토 등이다.Activated charcoal is produced using palm bark and charcoal, and sludge can use live sludge, water and sewage, and other sludge treated sludge. Residues represented as vegetable residues refer to crop residue, sawdust, rice husk, bark, wood flour, etc. Animal residues are tallow, seonji, meat and bone meal, fishery residues are fishmeal and fish and shellfish, minerals are limestone, phosphate, pearlite, vermiculite, zeolite and the like, and soil is masato, ocher, clay and the like.

소각 잔재물은 연소재, 분진 및 석탄재 등을 표현한 것임을 알 수 있다.Incineration residues can be seen that represent the combustion, dust and coal ash.

상기 녹화토 시공시에는 씨앗을 섞어서 함께 콤푸레샤로 분사시켜 시공하는 것이다.본 발명에서 사용하는 폐기물잔재물은 통상 제지슬러지를 소각시킨 연소재이거나 화력발전소에서 발생한 재를 말하며, 폐기물분진은 연료를 사용한 보일러 및 굴뚝 청소시에 발생한 미세한 분진을 말하며,식물잔재물은 농작물 잔사, 톱밥, 왕겨등을 말하며, 식물성 가공잔재물은 각종 과일 등의 통조림 제조과정에서 발생하는 즉 식품가공시 생성되는 불량품이나 찌꺼기 등을 사용하는 것이다.When the green earth is installed, the seeds are mixed and sprayed together with a compressor. The waste residue used in the present invention generally refers to a combustor incinerated paper sludge or ash generated from a thermal power plant, and waste dust is a boiler using fuel. And fine dust generated during chimney cleaning, plant residue refers to crop residues, sawdust, rice husks, etc., and vegetable processed residues are used in the process of manufacturing canned food such as various fruits, that is, defective products or residues generated during food processing. It is.

이하 실시 예를 통하여 상세히 설명하기로 한다.It will be described in detail through the following examples.

실시예 1Example 1

제지슬러지 20중량%, 활성탄5중량%, 토탄5중량% 및 오니류 20중량%를 혼합 교반한 다음에,20% by weight of paper sludge, 5% by weight of activated carbon, 5% by weight of peat and 20% by weight of sludge are mixed and stirred,

흙 10중량%에 광물성물질 5중량%, 식물성 잔재물 5중량%와 동물성 잔재물 5중량% 및 식물성가공 잔재물 5중량%를 섞은 후에 인분뇨잔사 5중량%, 및 폐기물 잔재물15중량%으로 혼합시킨 다음에 상기 혼합 교반한 화합물과 함께 이차 혼합 교반하여 식생토를 제조하는 것이다.5% by weight of minerals, 5% by weight of vegetable residues, 5% by weight of animal residues and 5% by weight of vegetable processed residues are mixed with 10% by weight of soil, 5% by weight of manure residues, and 15% by weight of waste residues. Secondary mixing and stirring together with the mixed and stirred compound to produce vegetation soil.

실시예 2Example 2

제지슬러지 20중량%, 활성탄5중량%, 토탄5중량% 및 상, 하수오니류 20중량%를 혼합 교반한 다음에,20% by weight of papermaking sludge, 5% by weight of activated carbon, 5% by weight of peat, and 20% by weight of phase and sewage sludge were mixed and stirred.

황토 또는 마사토 10중량%에 석회석 5중량%, 톱밥 또는 왕겨 5중량%와 우지, 선지 및 육분 5중량% 및 어분 또는 어패류 5중량%를 섞은 후에 인분뇨잔사 5중량%, 및 석탄재 또는 연소재 15중량%으로 혼합시킨 다음에 상기 혼합 교반한 화합물과 함께 이차 혼합 교반하여 식생토를 제조하는 것이다.10% by weight of ocher or masato, 5% by weight of limestone, 5% by weight of sawdust or chaff, 5% by weight of Uji, sesame and meat meal and 5% by weight of fishmeal or shellfish, 5% by weight of manure residue, and 15% of coal or burning ash The mixture is mixed with%, followed by secondary mixing and stirring with the mixed and stirred compound to prepare vegetated soil.

실시예 3Example 3

제지슬러지 20중량%, 활성탄5중량%, 토탄5중량% 및 폐수처리오니 20중량%를 혼합 교반한 다음에,20% by weight of paper sludge, 5% by weight of activated carbon, 5% by weight of peat and 20% by weight of wastewater treatment sludge were mixed and stirred,

점토 10중량%에 진주석 또는 인광석 5중량%, 톱밥 또는 왕겨 5중량%와 육분 또는 골분 5중량% 및 어패류 5중량%를 섞은 후에 인분뇨잔사 5중량%, 및 폐기물분진 15중량%으로 혼합시킨 다음에 상기 혼합 교반한 화합물과 함께 이차 혼합 교반하여 식생토를 제조하는 것이다.Mix 10% by weight of clay, 5% by weight of pearl or phosphate, 5% by weight of sawdust or chaff, 5% by weight of meat or bone meal, and 5% by weight of fish and shellfish, and then 5% by weight of manure residue and 15% by weight of waste dust. Secondary mixing and stirring together with the mixed and stirred compound to produce vegetation soil.

표 1. 상기 실시예에 의해 제조된 식생토 시험결과Table 1. Vegetation soil test results prepared by the above example

시료명검사항목Sample Name Inspection Items 실시 예 1Example 1 실시 예 2Example 2 실시 예 3Example 3 비 고Remarks 납(㎎/ℓ)Lead (mg / l) 0.0470.047 0.0430.043 0.0260.026 3 이하3 or less 구리(㎎/ℓ)Copper (mg / l) 0.0370.037 0.0290.029 0.0250.025 3 이하3 or less 카드뮴(㎎/ℓ)Cadmium (mg / l) 불검출Not detected 불검출Not detected 불검출Not detected 0.3 이하0.3 or less 6가크롬(㎎/ℓ)Hexavalent chromium (mg / l) 0.0550.055 0.0460.046 0.0380.038 1.5 이하1.5 or less 수은(㎎/ℓ)Mercury (mg / l) 불검출Not detected 불검출Not detected 불검출Not detected 0.005 이하0.005 or less 비소(㎎/ℓ)Arsenic (mg / l) 0.0180.018 0.0350.035 0.0330.033 1.5 이하1.5 or less 시안(㎎/ℓ)Cyan (mg / ℓ) 불검출Not detected 0.0070.007 0.0050.005 1 이하1 or less 테트라클로로에틸렌(㎎/ℓ)Tetrachloroethylene (mg / L) 불검출Not detected 불검출Not detected 불검출Not detected 0.1 이하0.1 or less 트리클로로에틸렌(㎎/ℓ)Trichloroethylene (mg / l) 불검출Not detected 불검출Not detected 불검출Not detected 0.3 이하0.3 or less 유기인(㎎/ℓ)Organophosphorus (mg / l) 불검출Not detected 불검출Not detected 불검출Not detected 1 이하1 or less

상기 시험결과는 충청남도 보건환경연구원에서 시험한 결과입니다.The test results above were tested by Chungcheongnam-do Institute of Health and Environment.

상기한 바와 같이 본 발명은, 응집력이 낮고 물리성이 좋으면서 비옥한 종자전용 상토로 사용 할 수 있으며, 토양간의 마찰력과 견지력을 증강시키며, 분사시 또는 시공시 흘러내림이 방지되고, 조경용 거름으로 활용할 수 있는 효과가 있는 것이다.As described above, the present invention can be used as a top soil for fertile seeds with low cohesive force and good physical properties, enhances friction and holding force between soils, prevents shedding during spraying or construction, and landscaping manure. It can be used as an effect.

Claims (2)

식생토의 제조방법에 있어서, 제지슬러지 20중량%, 활성탄5중량%, 토탄5중량% 및 오니류 20중량%를 혼합 교반한 다음에, 흙 10중량%에 광물성물질 5중량%, 식물성 잔재물 5중량%와 동물성 잔재물 5중량% 및 식물성가공 잔재물 5중량%를 섞은 후에 인분뇨잔사 5중량%, 및 폐기물 잔재물15중량%으로 혼합시킨 다음에 상기 혼합 교반한 화합물과 함께 이차 혼합 교반하여 조성물을 제조함을 특징으로 하는 식생토의 제조방법.In the method for preparing vegetated soil, 20% by weight of papermaking sludge, 5% by weight of activated carbon, 5% by weight of peat and 20% by weight of sludge are mixed and stirred, and then 10% by weight of soil 5% by weight of minerals and 5% by weight of vegetable residues. After mixing 5% by weight of animal residues and 5% by weight of vegetable processing residues, 5% by weight of manure residues, and 15% by weight of waste residues are mixed, followed by secondary mixing and stirring with the mixed and stirred compound to prepare a composition. Method for producing vegetation soil to be. 식생토에 있어서, 제지슬러지 20중량%, 활성탄5중량%, 토탄5중량% 및 오니류 20중량%,흙 10중량%, 광물성물질 5중량%, 식물성 잔재물 5중량%와 동물성 잔재물 5중량% 및 식물성가공 잔재물 5중량%, 인분뇨잔사 5중량%, 및 폐기물 잔재물15중량%로 조성됨을 특징으로 하는 식생토.20% by weight of paper sludge, 5% by weight of activated carbon, 5% by weight of peat and 20% by weight of sludge, 10% by weight of soil, 5% by weight of minerals, 5% by weight of vegetable residues and 5% by weight of animal residues 5% by weight of processed residues, 5% by weight of manure residues, and 15% by weight of waste residues.
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KR20020077740A (en) * 2001-04-02 2002-10-14 반채연 Agricultural soil (crop soil) production method
KR20040001288A (en) * 2002-06-27 2004-01-07 (주)이앤엠코리아 A way to manufacture vegetation nutrition soil by using a algae
KR100883733B1 (en) * 2007-12-31 2009-02-13 김승환 Sludge block
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KR102201367B1 (en) 2020-07-20 2021-01-11 (주)테라생태환경 vegetation soil for slope and manufacturing method thereof

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