KR100339746B1 - Method of making a compound metal covered with aluminum - Google Patents

Method of making a compound metal covered with aluminum Download PDF

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Publication number
KR100339746B1
KR100339746B1 KR1019990057925A KR19990057925A KR100339746B1 KR 100339746 B1 KR100339746 B1 KR 100339746B1 KR 1019990057925 A KR1019990057925 A KR 1019990057925A KR 19990057925 A KR19990057925 A KR 19990057925A KR 100339746 B1 KR100339746 B1 KR 100339746B1
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plate
aluminum
temperature
base material
brass
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KR1019990057925A
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Korean (ko)
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KR20010056184A (en
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김진영
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김진영
(주)호진
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K20/00Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating
    • B23K20/04Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating by means of a rolling mill
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K20/00Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating
    • B23K20/24Preliminary treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K2103/00Materials to be soldered, welded or cut
    • B23K2103/18Dissimilar materials
    • B23K2103/20Ferrous alloys and aluminium or alloys thereof

Abstract

동판, 황동판, 철판을 모재로 하고 알루미늄 스텐판을 크레드재로 하여 만드는 본 발명의 성형 가공용 합금판재의 크레드 제조방법은 먼저, 동판, 황동판, 철판 표면을 니켈 또는 크롬 산화방지 처리하고, 알루미늄 표면을 브러싱 또는 샌딩처리한다. 다음에, 300∼400℃의 온도로 가열하고 30∼40의 압력으로 압연한 후에, 300∼400℃의 온도로 재가열함으로써, 열전도율이 높고 내부식성이 향상된 합금판재를 제조할 수 있다.The method of manufacturing a cradle of an alloy sheet for forming processing of the present invention, in which a copper plate, a brass plate, an iron plate is used as a base material, and an aluminum stainless plate is used as a crad material, first of all, a surface of the copper plate, brass plate, and iron plate is subjected to nickel or chromium oxidation treatment, and the aluminum surface is treated. Brush or sand it. Next, an alloy plate member having high thermal conductivity and improved corrosion resistance can be produced by heating to a temperature of 300 to 400 ° C., rolling to a pressure of 30 to 40 ° C, and then reheating to a temperature of 300 to 400 ° C.

Description

성형 가공용 합금판재의 크레드 제조방법{METHOD OF MAKING A COMPOUND METAL COVERED WITH ALUMINUM}CRAD MANUFACTURING METHOD OF ALUMINUM PLATE MATERIAL FOR MOLDING PROCESS

본 발명은 성형 가공용 합금판재의 크레드 제조방법에 관한 것으로, 더욱 상세하게는, 동판, 황동판, 철판 표면을 니켈 또는 크롬 산화방지 처리하고, 알루미늄 표면을 브러싱 또는 샌딩처리한다. 다음에, 300∼400℃의 온도로 가열하고 30∼40의 압력으로 압연한 후에, 300∼400℃의 온도로 재가열하여 제조하는 방식의 성형 가공용 합금판재의 크레드 제조방법에 관한 것이다.BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for producing a cradle of an alloy plate material for molding, and more particularly, to nickel or chromium oxidation treatment of copper, brass, and iron plates, and to brushing or sanding of aluminum surfaces. Next, the present invention relates to a method for producing a cradle of an alloy plate material for forming processing by heating at a temperature of 300 to 400 ° C, rolling at a pressure of 30 to 40 ° C, and then reheating to a temperature of 300 to 400 ° C.

동판이나 황동판은 내부식성이 강하기 때문에 산업용 재료로 널리 이용된다. 특히, 전기 밥솥으로 사용할 경우에는 내부식성 뿐만 아니라 열전도율이 뛰어나야만 전기 소모가 적고 보다 짧은 시간 내에 밥을 지을 수 있다. 이를 만족하기 위해서는 이들 판재에 크레드로서 알루미늄을 압착하는 방법을 이용한다.Copper and brass plates are widely used as industrial materials because of their high corrosion resistance. In particular, when used as an electric cooker, not only corrosion resistance but also excellent thermal conductivity can consume less electricity and cook rice in a shorter time. In order to satisfy this, the method of crimping aluminum as a clad on these board | plate materials is used.

일예로서, 이러한 성형용 알루미늄 합금판재의 제조방법으로는, 1994. 12. 28. 출원되어 1998. 8. 6. 등록된 대한민국 특허 제158723호가 있다. 이것은 자동차 차체시트 등의 판재에 사용되는 성형용 알루미늄 합금판재의 제조방법에 관한 것으로서, 그 구성을 보면, Si 0.3 내지 1.7중량%, Cu 0.01 내지 1.2중량%, MnO 0.01 내지 1.1중량%, MgO 0.4 내지 1.4중량%, Fe 1.0중량%이하를 포함하고, 그 나머지의 Al과 불가피한 불순물로 형성되는 알루미늄 합금판재를 연속소둔 및 냉각방식에 의해여 450℃ 이상의 온도에서 3초 이상 가열하는 요체화 처리를 수행하는 단계와, 100℃/min 이상의 냉각속도로 60 내지 250℃의 온도까지 상기 알루미늄 판재를 냉각시키는 단계와, 상기 60 내지 250℃의 온도를 유지하면서 상기 알루미늄 합금판재를 코일형상으로 감는 단계 및 상기 60 내지 250℃의 온도에서 1분 내지 10시간의 예비시효를 수행하는단계로 이루어진 것을 특징으로 하고 있다.As an example, the manufacturing method of such an aluminum alloy sheet for forming, there is Republic of Korea Patent No. 158723, filed December 28, 1994 and registered on August 6, 1998. This relates to a method for producing an aluminum alloy sheet for molding to be used for sheet materials such as automobile body sheets, and the composition thereof includes Si 0.3 to 1.7 wt%, Cu 0.01 to 1.2 wt%, MnO 0.01 to 1.1 wt%, and MgO 0.4 The aluminum alloy plate material, which comprises from 1.4% by weight to 1.0% by weight of Fe and is formed of the remaining Al and inevitable impurities, is subjected to a subjective treatment of heating at a temperature of 450 ° C. or higher for 3 seconds or more by a continuous annealing and cooling method. Performing the steps of: cooling the aluminum plate to a temperature of 60 to 250 ° C. at a cooling rate of 100 ° C./min or more, winding the aluminum alloy plate into a coil shape while maintaining the temperature of 60 to 250 ° C .; It is characterized in that the step consisting of preliminary aging of 1 minute to 10 hours at a temperature of 60 to 250 ℃.

이러한 종래의 성형용 알루미늄 합금판재의 제조방법은 자동차용 차체로서의 충분한 강도 및 성형성을 갖고 있으나, 이를 전기 밥솥과 같은 재질로 활용할 수 없는 단점이 있다. 또한, 상기 특허에 개시되어 있는 합금판재는 알루미늄을 주성분으로 하고 있으며, 그 밖에 미량원소로서 Si, Cu, MnO, MgO, Fe을 포함한 성분비를 특정하고 있는 것으로서, 알루미늄을황동이나 철판과 같은 모재의 크레드로서 제조하는 방법에 관해서는 언급되어 있지 않다.The conventional method of manufacturing a molding aluminum alloy sheet material has a sufficient strength and formability as a vehicle body, but there is a disadvantage that cannot be used as a material such as an electric cooker. In addition, the alloy sheet material disclosed in the patent has aluminum as its main component, and specifies a component ratio including Si, Cu, MnO, MgO and Fe as trace elements. There is no mention of the method of preparation as a crad.

이와 같은 문제점을 해결하기 위한 본 발명의 목적은 동판, 황동판, 철판과 같은 모재의 표면을 니켈 또는 크롬 산화 방지처리하고, 알루미늄 표면을 브러싱 또는 샌딩처리한 다음에, 300∼400℃의 온도로 가열하여 30∼40의 압력으로 압연한 후, 300∼400℃의 온도로 재가열함으로써, 열전도율이 높고 강도가 우수한 성형 가공용 합금판재의 크레드 제조방법를 제공하는데 있다.An object of the present invention for solving this problem is to prevent the nickel or chromium oxidation treatment of the surface of the base material such as copper plate, brass plate, iron plate, brushing or sanding the aluminum surface, and then heated to a temperature of 300 ~ 400 ℃ By rolling at a pressure of 30 to 40 and then reheating at a temperature of 300 to 400 ° C, it is possible to provide a method for producing a cradle of an alloy plate material for forming processing having high thermal conductivity and excellent strength.

상술한 목적을 달성하기 위한 본 발명의 성형 가공용 합금판재의 크레드 제조방법은 동판, 황동판, 철판으로 이루어진 그룹으로부터 선택된 모재의 표면을 니켈 또는 크롬 산화방지 처리하는 단계(a)와, 알루미늄 표면을 브러싱 또는 샌딩 처리하는 단계(b)와, 상기 모재에 브러싱 또는 샌딩 처리된 알루미늄을 맞붙인 상태에서 300∼400℃의 온도로 가열하는 단계(c)와, 상기 모재와 알루미늄을 30∼40㎏/㎠의 압력으로 압연하여 압착시키는 단계(d)와, 상기 압착후에 300∼400℃의 온도로 재가열하는 단계(e)를 포함하는 것을 특징으로 한다.In order to achieve the above object, a method of manufacturing a cradle of an alloy plate for molding according to the present invention comprises the steps of (a) nickel or chromium oxidation treatment on a surface of a base material selected from the group consisting of a copper plate, a brass plate, and an iron plate, and brushing an aluminum surface. Or (b) performing a sanding process, heating (c) to a temperature of 300 to 400 ° C. in a state where the brushed or sanded aluminum is bonded to the base material, and the base material and aluminum are 30 to 40 kg / cm 2. Rolling and pressing at a pressure of (d), and after the pressing step of reheating to a temperature of 300 ~ 400 ℃ characterized in that it comprises a (e).

이하, 본 발명의 바람직한 실시예에 대해서 상세하게 설명하기로 한다.Hereinafter, preferred embodiments of the present invention will be described in detail.

본 발명의 바람직한 실시예에서는 성형 가공용 합금판재의 크레드 제조방법으로서, 동판이나 황동판 같은 모재를 표면 처리하고, 크레드재로서 알루미늄을 브러싱이나 샌딩 처리한 다음에, 이들 부재를 열간 압연하여 견고하게 압착시키는 방안을 예시하였다. 본 발명에 따라 제조되는 합금판재는 2중으로 하거나 알루미늄을 교대로 개재시켜 3중 또는 그 이상의 다중층 구조로 하는 것도 가능하다.In a preferred embodiment of the present invention, as a method for producing a cradle of an alloy plate material for forming, surface treatment of a base material such as a copper plate or a brass plate, and brushing or sanding aluminum as a crad material, followed by hot rolling of these members to be firmly pressed. The scheme is illustrated. The alloy sheet produced in accordance with the present invention may be doubled or alternately interposed aluminum to have a triple or more multilayer structure.

이러한 열간 압연공정에 의한 합금판재의 크레드 제조방법은 전체적으로, 동판, 황동판, 철판으로 이루어진 그룹으로부터 선택된 모재의 표면을 니켈 또는 크롬 산화방지 처리하는 단계(a)와, 알루미늄 표면을 브러싱 또는 샌딩 처리하는 단계(b)와, 상기 모재에 브러싱 또는 샌딩 처리된 알루미늄을 맞붙인 상태에서 300∼400℃의 온도로 가열하는 단계(c)와, 상기 모재와 알루미늄을 30∼40㎏/㎠의 압력으로 압연하여 압착시키는 단계(d)와, 상기 압착후에 300∼400℃의 온도로 재가열하는 단계(e)를 거쳐 만들어진다.The method of manufacturing a cradle of an alloy plate material by such a hot rolling process includes the steps of (a) treating the surface of a base material selected from the group consisting of a copper plate, a brass plate, and an iron plate with nickel or chromium oxidation, and brushing or sanding the aluminum surface. Step (b), the step (c) of heating to a temperature of 300 ~ 400 ℃ in the state in which the brushed or sanded aluminum bonded to the base material, and rolling the base material and aluminum at a pressure of 30 ~ 40kg / ㎠ By pressing step (d) and after the pressing step (e) of reheating to a temperature of 300 ~ 400 ℃.

여기에서, 모재로는 다양한 재질을 이용할 수 있으나, 내부식성 및 성형성이 우수한 동판을 비롯하여 황동판이나 철이 많이 함유되어 있는 철판을 사용하였다. 또한, 이들 모재의 표면은 니켈이나 크롬을 도금하여 산화를 방지한다. 이와 같이,산화 처리를 마친 모재의 표면은 열을 가하거나 물이나 기타 이물질과 접촉되어도 산화되지 않게 되어 내부식성이 향상된다.Here, a variety of materials may be used as the base material, but a brass plate or an iron plate containing a lot of iron is used, including a copper plate having excellent corrosion resistance and formability. In addition, the surface of these base materials is plated with nickel or chromium to prevent oxidation. As such, the surface of the base material which has been oxidized is not oxidized even when heated or in contact with water or other foreign substances, thereby improving corrosion resistance.

다음에, 크레드로서 사용하는 알루미늄의 경우에는 모재와의 접착력을 증대시키기 위한 방안으로 브러시를 이용하여 표면을 브러싱 처리하거나 샌드 페이퍼를 이용하여 샌딩 처리한다. 표면 처리된 알루미늄을 니켈 또는 크롬 도금된 모재와 밀착시킨 상태에서 300∼400℃의 온도로 가열시킨다.Next, in the case of aluminum to be used as a crad, the surface is brushed using a brush or sanded using sand paper in order to increase the adhesive force with the base material. The surface-treated aluminum is heated to a temperature of 300 to 400 ° C. in close contact with the nickel or chromium plated base material.

300∼400℃의 온도에서 소정시간 가열하여 어느 정도 용융된 상태에서, 적절한 가압롤러를 이용하여 용융된 2개의 금속을압연하여 부착시킨다. 이때, 소재의 이송속도는 모재에 크레드가 압착되기에 충분한 속도로 이송시키면 된다.After heating for a predetermined time at a temperature of 300 to 400 ° C. and in a molten state to some extent, two molten metals are rolled and attached using an appropriate pressure roller. At this time, the feed rate of the material may be transferred at a speed sufficient to press the crad to the base material.

모재에 알루미늄 크레드가 압착되고 나면, 다시 300∼400℃의 온도로 재가열하여 2금속 간의 결합력이 보다 증대되도록 한다. 소정시간 동안 가열한 후에, 접착된 소재는 적절한 속도(가령, 100℃/min 이상)로 자연냉각함으로써 충분한 강도및 경도를 유지할 수 있도록 한다.After the aluminum clad is pressed to the base material, it is reheated again at a temperature of 300 to 400 ° C. to increase the bonding strength between the two metals. After heating for a predetermined time, the bonded material is allowed to naturally cool at an appropriate rate (eg, 100 ° C./min or more) to maintain sufficient strength and hardness.

실시예 1Example 1

실시예 1에서는 모재로서 동판을 이용하였으며, 크레드재로는 알루미늄 스텐판을 이용하였다. 먼저, 동판에 니켈도금하여 산화방지 처리한 다음, 알루미늄 표면은 브러시를 이용하여 브러싱 처리하여 접촉면을 깨끗이 하였다. 다음에, 니켈 도금된 동판에 브러싱 처리된 알루미늄을 접촉시킨 상태에서 약 350℃의 온도까지 가열한 후에, 통상의 가압롤러를 이용하여이들 금속을 약 35㎏/㎠의 압력으로 압연하여 견고하게 부착되도록 하였다. 다음에, 압착된 소재를 약 350℃의 온도가 되도록 재가열하였다. 이와 같이 제조된 동판-알루미늄 합금판재는 열전도성이 우수하고 내부식성 및 강도가 뛰어남을 실험을 통해서 확인할 수 있었다.In Example 1, a copper plate was used as a base material, and an aluminum stenter plate was used as a crad material. First, nickel plating on the copper plate was performed to prevent oxidation, and then the aluminum surface was brushed using a brush to clean the contact surface. Next, after heating to a temperature of about 350 ° C. while brushed aluminum is brought into contact with the nickel plated copper plate, the metals are rolled at a pressure of about 35 kg / cm 2 using a conventional pressure roller to be firmly attached. It was made. Next, the compressed material was reheated to a temperature of about 350 ° C. The copper-aluminum alloy plate material thus prepared was confirmed through experiments of excellent thermal conductivity, excellent corrosion resistance and strength.

실시예 2Example 2

실시예 2에서는 모재로서 황동판을 이용하였으며, 크레드재로는 실시예 1과 마찬가지로 알루미늄 스텐판을 이용하였다.먼저, 황동판에 크롬도금하여 산화방지 처리한 다음, 알루미늄 표면은 샌드 페이퍼를 이용하여 샌딩 처리하여 접촉면을 깨끗이 하였다. 다음에, 크롬 도금된 황동판에 샌딩 처리된 알루미늄을 접촉시킨 상태에서 약 400℃의 온도까지 가열 한후에, 통상의 가압롤러를 이용하여 이들 금속을 약 40㎏/㎠의 압력으로 압연하여 견고하게 부착되도록 하였다. 다음에,압착된 소재를 약 380℃의 온도가 되도록 재가열하였다. 이와 같이 제조된 황동판-알루미늄 합금판재 역시, 열전도성 및내부식성과 강도가 우수함을 실험을 통해서 확인할 수 있었다.In Example 2, a brass plate was used as a base material, and an aluminum stainless plate was used as a crad material as in Example 1. First, the brass plate was oxidized by chrome plating, and then the aluminum surface was sanded using sand paper. To clean the contact surface. Then, after heating to a temperature of about 400 ℃ in contact with the sanded aluminum chrome plated brass plate, using a conventional pressure roller to roll these metals at a pressure of about 40kg / ㎠ to firmly adhere It was. Next, the compressed material was reheated to a temperature of about 380 ° C. The brass plate-aluminum alloy plate material thus prepared was also confirmed through experiments of excellent thermal conductivity, corrosion resistance and strength.

이밖에도, 본 발명에 따른 합금판재의 크레드 제조방법에 의해서, 상술한 동판-알루미늄이나 황동판-알루미늄 이외에도철판-알루미늄과 같은 2중 구조가 가능하며, 경우에 따라서는 동판-알루미늄-황동판-알루미늄-스텐판과 같은 5중구조나 동판-알루미늄-황동판-알루미늄-철판-알루미늄-스텐판과 같은 7중 구조와 같이 3∼7중 구조를 갖는 다중층 구조로도 제조할 수 있다.In addition, by the method of manufacturing a cradle of an alloy sheet according to the present invention, in addition to the above-described copper plate-aluminum or brass plate-aluminum, a double structure such as iron plate-aluminum is possible, and in some cases, copper plate-aluminum-brass plate-aluminum-sten It can also be produced in a multi-layer structure having three to seven structures, such as a five-layer structure such as a plate or a seven-layer structure such as copper plate-aluminum-brass plate-aluminum-iron plate-aluminum-sten plate.

이상으로 설명한 본 발명에 의하면, 동판, 황동판, 철판을 모재로 하고 알루미늄 스텐판을 크레드재로 하여 제조하게 되며, 그 제조방법을 보면, 먼저, 동판, 황동판, 철판 표면을 니켈 또는 크롬 산화방지 처리하고, 알루미늄 표면을 브러싱또는 샌딩처리하고, 다음에, 300∼400℃의 온도로 가열하고 30∼40의 압력으로 압연한 후에, 300∼400℃의 온도로 재가열하여 만들기 때문에, 열전도율이 높고 내부식성이 향상되어 수명이 연장되는 이점이 있다.According to the present invention described above, the copper plate, the brass plate, the iron plate as a base material, and the aluminum stainless plate as a crad material to manufacture, looking at the manufacturing method, first, the surface of the copper plate, brass plate, iron plate nickel or chromium oxidation treatment The surface of the aluminum is brushed or sanded, and then heated to a temperature of 300 to 400 ° C., rolled to a pressure of 30 to 40, and then reheated to a temperature of 300 to 400 ° C., thereby providing high thermal conductivity and corrosion resistance. This has the advantage that the life is extended.

Claims (1)

동판, 황동판, 철판으로 이루어진 그룹으로부터 선택된 모재의 표면을 니켈 또는 크롬을 도금하여 산화방지 처리하는 단계(a)와,(A) plating an surface of a base material selected from the group consisting of a copper plate, a brass plate, and an iron plate to prevent oxidation by plating nickel or chromium; 알루미늄 표면을 브러싱 또는 샌딩 처리하는 단계(b)와,(B) brushing or sanding the aluminum surface, 상기 모재에 브러싱 또는 샌딩 처리된 알루미늄을 맞붙인 상태에서 300∼400℃의 온도로 가열하는 단계(c)와,(C) heating to a temperature of 300 to 400 ° C. in a state in which the brushed or sanded aluminum is bonded to the base material; 상기 모재와 알루미늄을 30∼40㎏/㎠의 압력으로 압연하여 압착시키는 단계(d)와,(D) compressing the base material and aluminum by rolling at a pressure of 30 to 40 kg / cm 2; 상기 압착후에 300∼400℃의 온도로 상기 압착된 모재와 알루미늄을 재가열하는 단계(e)를 포함하는 것을 특징으로 하는 성형 가공용 합금판재의 크레드제조방법.And (e) reheating the crimped base material and aluminum at a temperature of 300 to 400 ° C. after the crimping.
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KR101960784B1 (en) * 2017-05-30 2019-03-21 엘티정밀(주) Manufacturing method for battery cooling devcie of vehicle

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JPH08309561A (en) * 1995-05-18 1996-11-26 Kobe Steel Ltd Manufacture of clad plate excellent in formability
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KR101780735B1 (en) * 2015-12-11 2017-09-21 희성정밀 주식회사 Cooling plate producing method for battery stack of electric vehicle and cooling plate by the same
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