KR100320412B1 - Fire retardant composition and its manufacturing method - Google Patents
Fire retardant composition and its manufacturing method Download PDFInfo
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- KR100320412B1 KR100320412B1 KR1019990054038A KR19990054038A KR100320412B1 KR 100320412 B1 KR100320412 B1 KR 100320412B1 KR 1019990054038 A KR1019990054038 A KR 1019990054038A KR 19990054038 A KR19990054038 A KR 19990054038A KR 100320412 B1 KR100320412 B1 KR 100320412B1
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- ammonium
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- 239000000203 mixture Substances 0.000 title claims abstract description 23
- 239000003063 flame retardant Substances 0.000 title claims abstract description 20
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000000843 powder Substances 0.000 claims abstract description 11
- GRLPQNLYRHEGIJ-UHFFFAOYSA-J potassium aluminium sulfate Chemical compound [Al+3].[K+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRLPQNLYRHEGIJ-UHFFFAOYSA-J 0.000 claims abstract description 10
- 239000012153 distilled water Substances 0.000 claims abstract description 9
- RAGLTCMTCZHYEJ-UHFFFAOYSA-K azanium;chromium(3+);disulfate Chemical compound [NH4+].[Cr+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RAGLTCMTCZHYEJ-UHFFFAOYSA-K 0.000 claims abstract description 7
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims abstract description 7
- 229960001763 zinc sulfate Drugs 0.000 claims abstract description 7
- 229910000368 zinc sulfate Inorganic materials 0.000 claims abstract description 7
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000000227 grinding Methods 0.000 claims abstract description 3
- 239000002304 perfume Substances 0.000 claims abstract 2
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 235000011126 aluminium potassium sulphate Nutrition 0.000 claims description 4
- 239000004033 plastic Substances 0.000 claims description 4
- 229920003023 plastic Polymers 0.000 claims description 4
- 229940050271 potassium alum Drugs 0.000 claims description 4
- 229940103272 aluminum potassium sulfate Drugs 0.000 claims description 3
- XGGLLRJQCZROSE-UHFFFAOYSA-K ammonium iron(iii) sulfate Chemical compound [NH4+].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O XGGLLRJQCZROSE-UHFFFAOYSA-K 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 229920003002 synthetic resin Polymers 0.000 claims description 3
- 239000000057 synthetic resin Substances 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 238000005485 electric heating Methods 0.000 claims 1
- 239000007791 liquid phase Substances 0.000 claims 1
- 239000007788 liquid Substances 0.000 abstract description 7
- 239000003205 fragrance Substances 0.000 abstract description 6
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract description 4
- ZLXPLDLEBORRPT-UHFFFAOYSA-M [NH4+].[Fe+].[O-]S([O-])(=O)=O Chemical compound [NH4+].[Fe+].[O-]S([O-])(=O)=O ZLXPLDLEBORRPT-UHFFFAOYSA-M 0.000 abstract description 4
- OIDPCXKPHYRNKH-UHFFFAOYSA-J chrome alum Chemical compound [K]OS(=O)(=O)O[Cr]1OS(=O)(=O)O1 OIDPCXKPHYRNKH-UHFFFAOYSA-J 0.000 abstract description 4
- 239000011651 chromium Substances 0.000 abstract description 4
- 239000004254 Ammonium phosphate Substances 0.000 abstract description 3
- 229940037003 alum Drugs 0.000 abstract description 3
- 229910000148 ammonium phosphate Inorganic materials 0.000 abstract description 3
- 235000019289 ammonium phosphates Nutrition 0.000 abstract description 3
- 229910052804 chromium Inorganic materials 0.000 abstract description 3
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 abstract description 3
- 238000001125 extrusion Methods 0.000 abstract description 3
- 238000001746 injection moulding Methods 0.000 abstract description 3
- 238000002156 mixing Methods 0.000 abstract 2
- 238000002844 melting Methods 0.000 abstract 1
- 230000008018 melting Effects 0.000 abstract 1
- 239000000835 fiber Substances 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 239000013078 crystal Substances 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- 150000008064 anhydrides Chemical class 0.000 description 2
- KXHIGEBWWSRJHG-UHFFFAOYSA-L calcium chromium(3+) sulfate Chemical compound [Ca+2].S(=O)(=O)([O-])[O-].[Cr+3] KXHIGEBWWSRJHG-UHFFFAOYSA-L 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 229920000092 linear low density polyethylene Polymers 0.000 description 2
- 239000004707 linear low-density polyethylene Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 1
- WKNIDMJWLWUOMZ-UHFFFAOYSA-N [K].[Cr] Chemical compound [K].[Cr] WKNIDMJWLWUOMZ-UHFFFAOYSA-N 0.000 description 1
- YSYYSJGUQSWQDD-UHFFFAOYSA-J [O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.N.N.[Cr+3].[Cr+3] Chemical compound [O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.N.N.[Cr+3].[Cr+3] YSYYSJGUQSWQDD-UHFFFAOYSA-J 0.000 description 1
- QQHSIRTYSFLSRM-UHFFFAOYSA-N alumanylidynechromium Chemical compound [Al].[Cr] QQHSIRTYSFLSRM-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- UMEAURNTRYCPNR-UHFFFAOYSA-N azane;iron(2+) Chemical compound N.[Fe+2] UMEAURNTRYCPNR-UHFFFAOYSA-N 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- IMBKASBLAKCLEM-UHFFFAOYSA-L ferrous ammonium sulfate (anhydrous) Chemical compound [NH4+].[NH4+].[Fe+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O IMBKASBLAKCLEM-UHFFFAOYSA-L 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/02—Inorganic materials
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
본 발명은 방화난연제(防火難燃劑)의 조성물 및 그의 제조방법에 관한 것으로서, 액상 및 분말의 방화난연제를 만드는데 그 목적이 있다.BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a composition of a fire retardant (및 火 방법) and a method for producing the same, and its object is to make a liquid and powder fire retardant.
크롬칼리명반(明礬), 황산암모늄철(Ⅲ).12수화물(水和物), 황산암모늄크롬(Ⅲ), 황산칼륨알루미늄, 황산칼륨크롬(Ⅲ), 황산아연, 제1인산암모늄,에탄올, 향료등을 증류수 1Ｌ 중에 용해도에 따라서 용해하여 액상화한 것에 그 특징이 있는 액상과 , 에탄올과 향료를 제외한 성분을 분말화 한 것에 그 특징이 있는 분말의 방화난연제, 또는 분말화 한 것을 합성수지(플라스틱)에 첨가하여 혼합 용융하여 사출성형, 압출성형, 필라멘트화 한것에 그 특징이 있는 방화 난연제의 조성물 및 그의 제조 방법.Chromium alum, iron ammonium sulfate (III) .12 hydrate, ammonium chromium sulfate (III), potassium aluminum sulfate, potassium chromium sulfate (III), zinc sulfate, ammonium phosphate, ethanol, Perfume etc. were dissolved and liquefied in 1 L of distilled water according to the solubility, and the liquid, characterized by powdering components other than ethanol and fragrance, was a fire retardant of powder, or powdered. A fire-retardant flame retardant composition characterized by injection molding, extrusion molding, and filamentation by mixing, melting, and mixing the same, and a method for producing the same.
Description
본 발명은 방화난연제(防火難燃劑)의 조성물 및 그의 제조방법에 관한 것으로서, 액상 및 분말의 방화난연제의 조성물을 만드는데 그 목적이 있다. 더욱 상세하게는 크롬칼리명반(明礬)(chromic potassium alum), 황산암모늄철(Ⅲ).12수화물(水和物)(ammonium iron(Ⅲ)sulfate 12-water), 황산암모늄크롬(Ⅲ)(ammonium chromium(Ⅲ)sulfate), 황산칼륨알루미늄(alumium potassium sulfate),황산칼륨크롬(Ⅲ)(chromi(Ⅲ)potassium sulfate), 황산아연(Zn SO47H2O), 제1인산암모늄(NH4H2PO4), 에탄올(알코올). 향(향료) 등을 성분별 물에 용해도에 따라서 비율별로 액상화하고, 분쇄하여 분말화(POWDER) 한것에 그 특징이 있는 방화난연제(防火難燃劑) 의 조성물 및 그의 제조방법.BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a composition of a fire retardant (및 火 제조) and a method for producing the same, and has an object of making a composition of liquid and powder fire retardant. More specifically, chromic potassium alum, ammonium iron (III). 12 hydrate (ammonium iron (III) sulfate 12-water), ammonium chromium (III) sulfate (ammonium) chromium (III) sulfate, aluminum potassium sulfate, chromium (III) potassium sulfate, zinc sulfate (Zn SO 4 7H 2 O), ammonium monophosphate (NH 4 H2PO) 4 ), ethanol (alcohol). A fire-retardant flame retardant composition, and a method for producing the same, which are characterized by liquefying fragrances (fragrances) and the like in proportion to solubility in water according to their components, and pulverizing and powdering them.
본 발명의 목적은 크롬칼리명반,황산암모늄철(Ⅲ)12수화물, 황산암모늄크롬(Ⅲ), 황산칼륨알루미늄, 황산칼륨크롬(Ⅲ), 황산아연, 제인산암모늄,에탄올(알코올), 향료 등을 증류수에 성분별로 용해도에 따라서 비율별로 용해하여 액상화하고 불에 타기쉬운 섬유,카펫트,쇼파등에 스프레이 분사하여 건조하면 화재시에 불에타지도 않고 단시간내에 스스로 불이 끄지게 하려는 목적의 방화난연제이며, 또한 성분별로 분쇄하여 분말화 하여 화섬(화학섬유), 플라스틱, 등의 원료에 혼합하여 용융 사출성형,압출성형,섬유필라멘트로 만들어 사용시 화재시에 불에 타지 않는 것에 그 특징을 갖는다.The object of the present invention is chromium aluminium, iron ammonium sulfate (III) 12 hydrate, chromium ammonium sulfate (III), potassium aluminum sulfate, potassium chromium sulfate (III), zinc sulfate, ammonium phosphate, ethanol (alcohol), fragrance, etc. It is a fire retardant for the purpose of dissolving liquid in distilled water according to its solubility according to its solubility and liquefying and spraying it on fire-resistant fiber, carpet, sofa, etc. In addition, it is pulverized by component, powdered, mixed with raw materials such as chemical fibers, plastics, and the like, to make melt injection molding, extrusion molding, and fiber filament.
본 발명은 방화난연제(防火難燃劑)의 조성물 및 그의 제조방법에 관한 것으로서, 액상 및 분말의 두종류를 만들기 위한 것이다. 종래에는 화재시에 불을 끄기 위한 분말을 분사하는 방법으로서 주성분이 제1인산암모늄으로서 복합적으로 만들어져 화재 발생시에만 분사하는 방법의 분말로서 연한 핑크 빛의 색깔로서 분사시 분말이 분산되어 분진이 발생하는 문제점이 있고 청소시에 곤난한 문제점이 있다.BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a composition of a fire retardant (, 火 방법) and a method for producing the same, for making two types of liquid and powder. Conventionally, as a method of injecting powder to extinguish fire in case of fire, the main component is made of complex ammonium phosphate and sprayed only in case of fire. It is light pink color and powder is dispersed when spraying. There is a problem and a difficult problem when cleaning.
본 발명은 액상의 경우 투명하고,무취이며, 화분사, 코팅하여 화재가 발생 하였을 때에 불에 붙지 않는 특징의 조성물로서 그 특징이 있다. 또한 분말의 방화난연제의 경우는 분말화 한 조성물을 화섬(화학섬유), 플라스틱의 원료에 혼합 용융하여 화재 발생시 불이 붙지 않는 것이 목적이며, 조성성분 또한 크롬칼리명반, 황산암모늄철(Ⅲ)12수화물,황산암모늄크롬(Ⅲ),황산칼륨알루미늄,황산칼늄크롬(Ⅲ), 황산아연, 제1인산암모늄, 에탄올, 향료등의 조성물을 사용하였다.The present invention is characterized as a composition of a transparent, odorless, pollen yarn, coating does not adhere to the fire when a fire occurs in the case of a liquid. In the case of powder fire retardant, the purpose is to mix and melt the powdered composition with raw material of chemical fiber and plastic so that it does not catch fire in case of fire.The composition is also chromium alum, iron ammonium sulfate (III) 12 Compositions such as hydrate, ammonium chromium (III) sulfate, potassium aluminum sulfate, calcium chromium sulfate (III), zinc sulfate, ammonium monophosphate, ethanol, and fragrance were used.
따라서 , 본 발명은 증류수 1Ｌ에 각 성분별로 물에 용해도에 따라서 불휘발분의 함량 비율별로 용해하는 기술적 어려움과 화재 발생시에 각성분별 특징에 따라서 불이 붙지 않게 되는 임계점을 찾아 용해 하여야 하고 화학 반응에 의하여 증류수의 색깔이 유색화(有色化) 되는 것을 없이 하기 위한 것과, 상온에서의 용해도와 온도를 상승시켜 화학 반응에 의한 변화가 없이 빨리 이상적으로 용해 되는 임계점을 찾는 것이 기술적인 어려움이 있어 실시예에 따라서 그 문제점을 해결 하였다.Therefore, the present invention has to find and dissolve the technical difficulties in dissolving the content of non-volatile content according to the solubility in water for each component in 1L of distilled water and the critical point which does not catch fire according to the characteristics of each component at the time of fire. In order to prevent the color of distilled water from being colored, and to find the critical point that is ideally dissolved quickly without changing by chemical reaction by increasing the solubility and temperature at room temperature, there is a technical difficulty. Therefore, the problem was solved.
본 발명의 바람직한 일실시예에 따른 아래의 각 성분의 조성비율은 다음과 같다. 먼저 각성분의 특징을 보다 상세하게 설명하면 다음과 같다.Composition ratios of the following components according to a preferred embodiment of the present invention are as follows. First, the characteristics of each component will be described in detail as follows.
(1).크롬칼리명반(明礬)(chromic potassium alum)의 화학식은 KCr(SO4)212H2O로서 암자색(暗紫色)의 8면체결정( 8面體結晶)으로서 수용액은 차가울때는 암자색, 열을주면 섭씨 80℃에서 녹색(綠色)이 되고 증발하면 녹색 무정형(無晶形)의 괴(塊)가 된다. 오래 방치하면 냉각(冷却)되면서 청자색(靑紫色)으로 변한다. 물에 녹으며,알콜에는 불용(不溶)이다. (2). 황산암모늄철(Ⅲ).12수화물(水和物)(ammonium iron(Ⅲ)sulfate)12-water)의 화학식은 (NH4)Fe(SO4)2.12H2O)로서 담자색 정팔면체결정(淡紫色 正8面體結晶) 섭씨 25℃에서 100gr의 물에 124.4gr 용해되고 에탄올에 불용(不溶).(3). 황산암모늄크롬(Ⅲ)(ammonium chromium(Ⅲ)sulfate)의 화학식은 (NH4)Cr(SO4)2로서 무수화물은 녹색육방정계(綠色6方晶係)결정이며, 물 100gr에 대한 용해도는 섭씨 25℃에서 12.2gr, 40℃에서 32.8gr 녹는다. 에탄올에는 불용이며, 수용액은 청자색에서 녹색이된다.(4).황산칼륨알루미늄(aluminum potassium sulfate)이며 화학식은 KAL(SO4)2또는 (K2SO4. Al2(SO4)3. 24H2O 이고 무수화물(無水和物)은 물 100gr 에 3.1gr(0℃), 10.1gr(30℃) 용해되고 알코올에는 불용, 200℃이상에서 SO3를 잃고서 분해된다 12수화물은 (12水和物)은 무색정팔면체(無色正8面體).(5). 황산칼륨크롬(Ⅲ)(chromium(Ⅲ) potassium sulfate)로 화학식은 KCr(SO4)2이며 노색정팔면체결정(綠色正8面體結晶) 크롬명반 또는 크롬칼륨명반이라 부른다 물 100gr에 대한 용해도는 25℃에서 24.39gr, 열을 가하면 50gr, 에탄올에는 불용이다. 수용액은 청자색에서 50 - 70 ℃에서 녹색이 된다. (6). 황산아연(ZnSO47H2O), (7).제1인산암모늄(NH4H2PO4).(8).에탄올(알코올).(9).향료. 의 조성물로서 실시예를 들어서 설명하면......(1) .The chemical formula of chromic potassium alum is KCr (SO 4 ) 2 12H 2 O, which is an octahedral crystal of 8 purple, which is dark purple and heat when the solution is cold. If you give it, it becomes green at 80 ℃, and if it evaporates, it becomes green amorphous mass. If left for a long time, it cools and turns blue-purple. Soluble in water, insoluble in alcohol. (2). The chemical formula of ammonium iron (III) sulfate 12-water is (NH 4 ) Fe (SO 4 ) 2 .12H 2 O) as a pale purple octahedral crystal. It is soluble in 124.4gr of 100gr of water at 25 ° C and insoluble in ethanol. (3). The chemical formula of ammonium chromium (III) sulfate is (NH 4 ) Cr (SO 4 ) 2, where the anhydride is a green hexagonal crystal and its solubility in water is 100gr. Melt 12.2gr at 25 ° C and 32.8gr at 40 ° C. Insoluble in ethanol, aqueous solution turns from blue purple to green. (4) Aluminum potassium sulfate and the chemical formula is KAL (SO 4 ) 2 or (K 2 SO 4 .Al 2 (SO 4 ) 3 .24H 2 O and anhydride is dissolved in 100gr of water, 3.1gr (0 ℃), 10.1gr (30 ℃), insoluble in alcohol, and decomposed by losing SO 3 above 200 ℃.和 物) is a colorless octahedron. (5) It is chromium (III) potassium sulfate, and its chemical formula is KCr (SO 4 ) 2, and it is a colorless octahedral crystal. It is called chromium alum or chromium potassium alum. Solubility in 100gr of water is 24.39gr at 25 ° C, 50gr when heated, and insoluble in ethanol. Zinc sulfate (ZnSO 4 7H 2 O), (7). Monobasic ammonium phosphate (NH 4 H 2 PO 4 ). (8). Ethanol (alcohol). (9) Flavor. .....
실시예 1Example 1
(1). 크롬칼리명반 --- 5중량 %(One). Chrome Cali Alum --- 5% by weight
(2). 황산암모늄철(Ⅲ).12수화물 --- 5중량 %(2). Ferrous ammonium sulfate (III) .12 hydrate --- 5% by weight
(3). 황산암모늄크롬(Ⅲ) --- 3중량 %(3). Ammonium Chromium Sulfate (III) --- 3% by weight
(4). 황산칼륨알루미늄 --- 15중량 %(4). Potassium Sulfate Aluminum --- 15 wt%
(5). 황산칼늄크롬(Ⅲ) --- 7중량 %(5). Calcium Chromium Sulfate (III)-7 wt%
(6). 황산아연 --- 10중량 %(6). Zinc Sulfate --- 10 wt%
(7). 제1인산암모늄 --- 5중량 %(7). Ammonium monophosphate --- 5% by weight
(8). 에탄올 --- 10중량 %(8). Ethanol--10 wt%
(9). 향료 --- 5중량 %(9). Fragrances --- 5% by weight
(10). 증류수 --- 35중량 %(10). Distilled Water --- 35% by weight
위의 조성물을 교반 회전기에서 섭씨 30 - 40 ℃의 온도로 교반 공정중에 위의 조성물 순서되로 첨가 하면서 교반하여 액상화 한다.The above composition is liquefied by stirring while adding the above compositions in order during the stirring process at a temperature of 30-40 ° C. in a stirring rotor.
위의 (1) - (7)의 성분을 분쇄하여 분말화 한다.The components of (1) to (7) above are ground and powdered.
분말화 한 것을 증류수 1Ｌ에 첨가 하여 섭씨 30 - 40 ℃의 온도로 고정 후 교반하여 용해하여 액상화 하여 완성한다.The powdered product is added to 1 L of distilled water, fixed at a temperature of 30-40 ° C, stirred, dissolved, and finished.
액상화 하여 스프레이 분사시 휘발이 용이 하도록 에탄올을 10중량 % 첨가하고, 향료를 첨가 하여 교반후 최종 완성하여 액상화 한다.10% by weight of ethanol is added to facilitate volatilization during spraying by liquefaction, and after the stirring is completed, the solution is finally completed and liquefied.
위의 조성물 (1)-(7)의 성분을 분쇄하여 분말화 하여 이 분말 30중량%에 합성수지(플라스틱)70중량% 혼합,용융하여 칩으로 만들어 사출성형,압출성형, 섬유 필라멘트로 가공하여 각 용도별로 사용할수 있다 특히 전선의 피막용 또는 건축자재용 으로 사용하는 PVC, PP, PE, PS, 스티로폴 단열제에 화재 발생시 근원적으로 불이 붙지 않게 하기 위한 것과 , 전선의 합선시에 전기로 인한 화재 발생시에 불이 붙지 않게 하기위한 용도에 그 특징이 있는 방화난연제 분말.The components of the above compositions (1)-(7) are pulverized and powdered, mixed with 30% by weight of this resin and 70% by weight of synthetic resin (plastic), melted into chips and processed into injection molding, extrusion molding and fiber filament. It is possible to use by application, especially for PVC, PP, PE, PS, Styropol insulation used for wire coating or building materials. A fire retardant powder characterized by its use to prevent fire from occurring during occurrence.
위의 조성물 액상을 종이와 섬유에 스프레이후 상온에서 건조후 불을 붙여 보았다. 불이 전혀 붙지 않고서 타지도 않았지만 기존의 종이와 섬유에다 불을 붙혀 보니 곧바로 불이 붙으면서 타올랐다.After spraying the composition liquid on paper and fibers, and dried at room temperature, the fire was applied. The fire didn't burn at all, but when it was fired on the existing paper and fiber, it burned as soon as the fire started.
합성수지 LLDPE 와 연질 PVC 에 본 발명의 분말을 30 중량 % 첨가하고 용융하여 칩으로 만든다음 불에 붙혀 보니 불이 붙지 않았다.기존의 LLDPE 와 PVC는 불에 붙혀 보니 녹으면서 불이 붙으며 냄새가 발생하였다.30% by weight of the powder of the present invention was added to the synthetic resin LLDPE and soft PVC, melted into chips, and then caught on fire. The existing LLDPE and PVC did not catch on fire. It was.
Claims (4)
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4479912A (en) * | 1981-10-20 | 1984-10-30 | Bernadine A. Eggan | Fiber board composition |
| JPH03177366A (en) * | 1989-12-05 | 1991-08-01 | Ngk Insulators Ltd | Raw material for cementless monolithic refractory and production of cementless monolithic refractory using the same raw material |
| US5480587A (en) * | 1988-12-21 | 1996-01-02 | Aluminum Company Of America | Materials for use as fire retardant additives |
| JPH0995556A (en) * | 1995-09-29 | 1997-04-08 | Jiro Fujimasu | Fire-resistant board composition |
| US5660763A (en) * | 1995-03-10 | 1997-08-26 | Thermic Labs, Inc. | Fire fighting composition and products containing same |
| KR0133634B1 (en) * | 1994-07-08 | 1998-04-21 | 김철갑 | Cellulose component containing retard agent |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4479912A (en) * | 1981-10-20 | 1984-10-30 | Bernadine A. Eggan | Fiber board composition |
| US5480587A (en) * | 1988-12-21 | 1996-01-02 | Aluminum Company Of America | Materials for use as fire retardant additives |
| JPH03177366A (en) * | 1989-12-05 | 1991-08-01 | Ngk Insulators Ltd | Raw material for cementless monolithic refractory and production of cementless monolithic refractory using the same raw material |
| KR0133634B1 (en) * | 1994-07-08 | 1998-04-21 | 김철갑 | Cellulose component containing retard agent |
| US5660763A (en) * | 1995-03-10 | 1997-08-26 | Thermic Labs, Inc. | Fire fighting composition and products containing same |
| JPH0995556A (en) * | 1995-09-29 | 1997-04-08 | Jiro Fujimasu | Fire-resistant board composition |
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