JPH0995556A - Fire-resistant board composition - Google Patents

Fire-resistant board composition

Info

Publication number
JPH0995556A
JPH0995556A JP27503195A JP27503195A JPH0995556A JP H0995556 A JPH0995556 A JP H0995556A JP 27503195 A JP27503195 A JP 27503195A JP 27503195 A JP27503195 A JP 27503195A JP H0995556 A JPH0995556 A JP H0995556A
Authority
JP
Japan
Prior art keywords
fire
weight
waste
paper
mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP27503195A
Other languages
Japanese (ja)
Other versions
JP2736317B2 (en
Inventor
Jiro Fujimasu
次郎 藤増
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to JP27503195A priority Critical patent/JP2736317B2/en
Publication of JPH0995556A publication Critical patent/JPH0995556A/en
Application granted granted Critical
Publication of JP2736317B2 publication Critical patent/JP2736317B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/78Recycling of wood or furniture waste

Landscapes

  • Compositions Of Macromolecular Compounds (AREA)
  • Dry Formation Of Fiberboard And The Like (AREA)
  • Processing Of Solid Wastes (AREA)
  • Fireproofing Substances (AREA)

Abstract

PROBLEM TO BE SOLVED: To economically obtain a fire-resistant board compsn. excellent in fire resistance while contributing to solve environmental problems by adding a specific additive to a mixture of a paper or wood waste and a plastic waste. SOLUTION: A fire-resistant board compsn. in an amount of 100 pts.wt. is prepd. by adding 20-30 pts.wt. fire-resistant additive comprising a mixture of aluminum hydroxide, sodium silicate, and calcium or magnesium chloride in a ratio of 6:(1-3):(1-3) or a mixture of an alumina cement and a silica powder in a ratio of 1:(0.5-1.5) to 70-80 pts.wt. mixture comprising 35-40 pts.wt. (dry basis) paper and/or wood waste and 35-40 pts.wt. plastic waste. Even when the paper or wood waste contains a large amt. of water, it can be used as it is without being dried. A fire-resistant board is obtd. e.g. by crushing the wastes into the form of cotton wool, mixing the crushing product with the fire-resistant additive, and hot-pressing the resultant mixture.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、紙質または木質廃材と
プラスチック廃材とを利用した耐火性ボード組成物に関
する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a fire-resistant board composition using waste paper or wood and plastic waste.

【0002】[0002]

【発明の背景】本発明者は、今までに、古紙、製紙廃材
等の紙質廃材、または木材チップ、おがくず、かんな屑
等の木質廃材やプラスチック廃材を利用した人造木材等
の建材用組成物を数多く提案して来た。これらを大別す
ると、濡れた材料にはセメント系の固化剤を使用し、乾
いた材料には主としてメラミン樹脂等をバインダーとし
て使用したものであった。それらはそれなりに合理性が
あるとしても、得られる製品に甲乙の差があり、必ずし
も満足できる結果を得ていたとは言い難い。
BACKGROUND OF THE INVENTION The inventor of the present invention has hitherto provided a composition for building materials such as waste paper, waste paper materials such as paper waste materials, or wood waste materials such as wood chips, sawdust, and planks and plastic waste materials, and artificial wood materials. I have proposed a lot. When these are roughly classified, a cement-based solidifying agent is used for a wet material, and a melamine resin or the like is mainly used as a binder for a dry material. Even if they are reasonable in their own way, it is hard to say that they have always obtained satisfactory results due to differences in products obtained.

【0003】[0003]

【発明の目的】本発明の目的は、大量に廃棄される紙質
廃材や木質廃材と、同じく大量に廃棄されるプラスチッ
ク廃材とを併用して、しかも耐火性を有するボード組成
物を提供することにある。
OBJECT OF THE INVENTION It is an object of the present invention to provide a board composition having a fire resistance in combination with a large amount of waste paper and wood waste and a large amount of waste plastic waste. is there.

【0004】更に、本発明の目的は、例えば生古紙ヘド
ロのような大量に水を含有する廃棄物を、乾燥すること
なく、そのまま使用することができるボード組成物を提
供することにある。
Further, it is an object of the present invention to provide a board composition which can be used as it is, without drying a waste material containing a large amount of water, such as raw waste paper sludge.

【0005】[0005]

【発明の構成、作用】本発明は、乾燥重量で紙質及び/
又は木質廃材35〜40重量部及びプラスチック廃材3
5〜40重量部の混合物に、水酸化アルミニウム
(a)、珪酸ソーダ(b)及び塩化カルシウムもしくは
塩化マグネシウム(c)をa:b:cの重量比が6:1
〜3:1〜3となるように混合した耐火用添加剤20〜
30重量部を、全体が100重量部となるように添加し
たことを特徴とする耐火性ボード組成物を提供する。
According to the present invention, the paper quality and / or the dry weight are
Or wood waste material 35-40 parts by weight and plastic waste material 3
Aluminum hydroxide (a), sodium silicate (b) and calcium chloride or magnesium chloride (c) are added to a mixture of 5 to 40 parts by weight in a weight ratio of a: b: c of 6: 1.
~ 3: 1 to 3 mixed fireproof additive 20 ~
A refractory board composition is provided in which 30 parts by weight is added so that the total amount is 100 parts by weight.

【0006】更に、本発明は、乾燥重量で紙質及び/又
は木質廃材35〜40重量部及びプラスチック廃材35
〜40重量部の混合物に、アルミナセメント(a′)及
びシリカ粉末(b′)をa′:b′の重量比が1:0.
5〜1.5になるように混合した耐火用添加剤20〜3
0重量部を、全体が100重量部となるように添加した
ことを特徴とする耐火性ボード組成物を提供する。
Further, the present invention provides 35-40 parts by weight of paper and / or wood waste and dry plastic waste 35 by dry weight.
Alumina cement (a ') and silica powder (b') in a mixture of -40 parts by weight with a weight ratio of a ': b' of 1: 0.
Refractory additives 20 to 3 mixed to be 5 to 1.5
There is provided a refractory board composition, wherein 0 part by weight is added so that the total amount is 100 parts by weight.

【0007】本発明の組成物を製造する場合、古紙、製
紙廃材等の紙質廃材や木材チップ、おがくず、かんなく
ず等の本質廃材は、乾燥状態でも使用できるが、大量に
水を含んでいる場合でも、乾燥することなく、そのまま
使用することができる。たとえば、製紙工場から排出さ
れる生古紙ヘドロの含水率は約70%であるが、組成物
の製造工程で水分の殆どが蒸発してしまう。従って、コ
ストアップのもとになる乾燥工程を殊更に必要としな
い。
In the case of producing the composition of the present invention, paper waste materials such as waste paper and papermaking waste materials and essential waste materials such as wood chips, sawdust, and citrus can be used even in a dry state, but when a large amount of water is contained. However, it can be used as it is without drying. For example, the water content of raw waste paper sludge discharged from a paper mill is about 70%, but most of the water content evaporates in the manufacturing process of the composition. Therefore, there is no need for a further drying step which causes a cost increase.

【0008】プラスチック廃材としては、大量に廃棄さ
れるものとして塩化ビニルシートやペットボトル等があ
るが、これらは粉砕して使用される。プラスチック廃材
の粉砕物は、組成物の製造過程でホットプレス内で溶融
し、紙質又は木質廃材のバインダーとして作用する。プ
ラスチック廃材は紙質または木質廃材とほぼ同量使用す
るのが適当である。組成物の製造過程で高温処理を必要
としないので、プラスチック廃材から有毒ガスが発生す
ることもない。プラスチック廃材としてウレタンフォー
ムの廃材も使用することができるが、このものは塩化ビ
ニルが溶融流動する190℃付近では溶融しないので、
バインダーとしてではなく、紙質又は木質廃材と同様
に、一種の骨材として扱うべきである。
[0008] As plastic waste materials, there are vinyl chloride sheets, PET bottles, etc., which are discarded in large quantities, and these are crushed and used. The crushed material of the plastic waste material is melted in the hot press during the production process of the composition and acts as a binder for the waste material of paper or wood. It is appropriate to use the same amount of plastic waste material as paper or wood waste material. Since no high temperature treatment is required in the manufacturing process of the composition, no toxic gas is generated from the plastic waste material. Urethane foam waste can also be used as plastic waste, but this does not melt near 190 ° C when vinyl chloride melts and flows,
It should be treated as a kind of aggregate like paper or wood waste, not as a binder.

【0009】本発明の組成物において、耐火用添加剤と
して、水酸化アルミニウム(a)、珪酸ソーダ(b)及
び塩化カルシウムもしくは塩化マグネシウム(c)の混
合物、またはアルミナセメント(a′)及びシリカ粉末
(b′)の混合物が使用される。前者として、本発明者
が開発した「フジボーカ」と称する混合物を使用するこ
とができる。このものは、水酸化アルミニウム、珪酸ソ
ーダ及び塩化カルシウム(もしくは塩化マグネシウム)
をほぼ6:2:2の重量割合で混合した微粉末である。
また後者として、同じく本発明者が開発した「トーマス
セラミックス」と称する混合物を使用することができ
る。このものは、アルミナセメント及びシリカ粉末をほ
ぼ1:1の重量割合で混合した微粉末である。このトー
マスセラミックスに生古紙ヘドロのような含水率の高い
材料を混合すると、アルミナセメントの水和作用によっ
て硬化が生ずると同時に、自由水分も減少する。
In the composition of the present invention, as a refractory additive, a mixture of aluminum hydroxide (a), sodium silicate (b) and calcium chloride or magnesium chloride (c), or alumina cement (a ') and silica powder. A mixture of (b ') is used. As the former, it is possible to use a mixture developed by the present inventor and referred to as "Fujivocaa". This is aluminum hydroxide, sodium silicate and calcium chloride (or magnesium chloride)
Is a fine powder in which the weight ratio of about 6: 2: 2 is mixed.
Also, as the latter, a mixture called "Thomas ceramics" also developed by the present inventor can be used. This is a fine powder in which alumina cement and silica powder are mixed in a weight ratio of about 1: 1. When a material having a high water content such as raw waste paper sludge is mixed with this Thomas ceramics, hardening occurs due to the hydration of alumina cement, and at the same time, free water also decreases.

【0010】本発明の耐火性ボードの製造方法の一例を
述べると次のとおりである。
An example of the method for manufacturing the refractory board of the present invention is as follows.

【0011】先づ、原料の製紙ヘドロ(含水率70%程
度のもの、またはこれを乾燥したもの)または木質廃材
(古い木造家屋の残材や一年生の植物の茎等)を破砕機
で粗挽きした後、多くの針状の刃を持ったかんなを回転
させて、綿のように細かく繊維状にほぐし、粉砕機で粉
砕分離する。
First, raw papermaking sludge (water content of about 70%, or dried one) or wood waste (residual material of old wooden house or annual plant stem) is roughly ground with a crusher. After that, the planer with many needle-shaped blades is rotated to loosen it into fine fibers like cotton, and then crushed and separated by a crusher.

【0012】他方、プラスチック廃材(例えば農家で使
用したビニルシート廃棄物、ペットボトル等)を同様に
破砕機・粉砕機によりできるだけ綿状に粉砕する。
On the other hand, plastic waste materials (for example, vinyl sheet waste used in farmers, PET bottles, etc.) are similarly crushed into a cotton shape by a crusher / crusher.

【0013】このように綿状にした紙質もしくは木質廃
材(A)、プラスチック廃材(B)及び耐火用添加剤
(C)(例えばフジボーカ)を、所要の配合比で、混合
開繊機によって、必要ならば、予熱しながら、混合撹拌
した後、ホットプレスに投入する。ホットプレスの温度
は、プラスチックが溶融流動するが、分解しない温度
(例えば150〜190℃)に保つ。必要に応じて簡単
なガス清浄装置を設置してもよい。
The cotton-like or wood waste material (A), the plastic waste material (B) and the fire-resistant additive (C) (for example, Fuji Voca) thus prepared in the required mixing ratio by a mixing opening machine, if necessary. For example, while preheating, after mixing and stirring, put into a hot press. The hot press temperature is maintained at a temperature (for example, 150 to 190 ° C.) at which the plastic melts and flows but does not decompose. A simple gas cleaning device may be installed if necessary.

【0014】ホットプレス中で紙質又は木質廃材(原料
A)に含まれている水分は蒸発する。プラスチック(原
料B)は融解して流動状態になり、均一に混合されてい
る原料(A)及び耐火用添加剤(C)の粒子の表面を覆
い、三者一体となる準備が完了する。ここで、プレスに
よって、40〜50kg/cm2程度の圧力をかけ、成
形して、次いで冷却・仕上げ工程を経る。仕上げの際に
切り落された破片は、再び原料(A)の流れの針状かん
なに投入されて、綿状に粉砕され原料の一部となる。従
って製造工場から廃棄物は発生しない。
The water contained in the waste paper or wood (raw material A) in the hot press is evaporated. The plastic (raw material B) melts into a fluid state, covers the surfaces of the particles of the raw material (A) and the refractory additive (C) that are uniformly mixed, and the preparation for the three-part integral is completed. Here, a pressure of about 40 to 50 kg / cm 2 is applied by a press to mold, and then a cooling / finishing step is performed. The fragments cut off at the time of finishing are again charged into the needle-shaped planer of the flow of the raw material (A) and pulverized into a cotton-like shape to become a part of the raw material. Therefore, no waste is generated from the manufacturing plant.

【0015】ボード製造工程の一例を図1に示す。An example of the board manufacturing process is shown in FIG.

【0016】[0016]

【実施例】次に実施例により本発明を更に詳しく説明す
る。
EXAMPLES The present invention will be described in more detail by way of examples.

【0017】実施例1〜5及び比較例1〜4 表1に示す割合の各種の原料を用い、前述の製造方法に
従ってボードを製造した。
Examples 1 to 5 and Comparative Examples 1 to 4 Using various raw materials in the proportions shown in Table 1, boards were manufactured according to the above manufacturing method.

【0018】表1中、フジボーガSSは、水酸化アルミ
ニウム、珪酸ソーダ粉末及び塩化マグネシウムの6:
2:2の混合物であり、トーマスセラミックスは、アル
ミナセメントとシリカ粉末の1:1の混合物であり、ト
ーマスバルーン100は、無機質の軽量骨材で頁岩を膨
張させたものである。また生古紙ヘドロは製紙工場から
排出される廃棄物で、含水率は約70%である。
In Table 1, Fujiboga SS is a mixture of aluminum hydroxide, sodium silicate powder and magnesium chloride:
It is a 2: 2 mixture, Thomas ceramics is a 1: 1 mixture of alumina cement and silica powder, and Thomas balloon 100 is a shale expansion made from a lightweight inorganic aggregate. Raw waste paper sludge is a waste product discharged from a paper mill and has a water content of about 70%.

【0019】製造した実施例1、3及び比較例1〜4の
ボードについて、単位体積重量、曲げ強さ、一軸圧縮強
さ及び難燃等級を測定した。結果を表1に示す。なお、
難燃等級は、JIS A 1321の建築物の内装材料及
び工法の難燃性試験方法に従って測定した。
With respect to the manufactured boards of Examples 1 and 3 and Comparative Examples 1 to 4, the unit volume weight, bending strength, uniaxial compressive strength and flame retardancy were measured. The results are shown in Table 1. In addition,
The flame-retardant grade was measured according to the flame-retardant test method of JIS A 1321 building interior materials and construction methods.

【0020】実施例1及び3のボードは、難燃性等級が
1級であり、また強度も十分に高い。比較例1及び2は
紙質又は木質廃材の一部をトーマスバルーンに置き換え
たものであり、難燃性は1級であるが、強度が若干劣っ
ている。比較例3及び4は耐火用添加剤を使用しないも
のであり、難燃性及び強度は共に劣っている。
The boards of Examples 1 and 3 have a flame retardancy rating of grade 1 and have sufficiently high strength. In Comparative Examples 1 and 2, a part of the waste paper or wood was replaced with Thomas balloon, and the flame retardancy was grade 1, but the strength was slightly inferior. Comparative Examples 3 and 4 do not use a refractory additive and are inferior in flame retardancy and strength.

【0021】[0021]

【発明の結果】本発明は、大量に廃棄される紙質もしく
は木質廃材及びプラスチック廃材を有効に利用するもの
であるから、環境問題の解決に寄与すると共に、非常に
経済的であり、しかも難燃性1級という耐火性に優れた
ボードを得ることができる。
INDUSTRIAL APPLICABILITY Since the present invention effectively utilizes a large amount of waste paper or wood waste materials and plastic waste materials, it contributes to solving environmental problems and is very economical and flame retardant. It is possible to obtain a board having excellent fire resistance, which is grade 1 of the properties.

【0022】[0022]

【表1】 [Table 1]

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明に従う耐火性ボードの製造工程の一例を
示すフローチャートである。
FIG. 1 is a flowchart showing an example of a manufacturing process of a refractory board according to the present invention.

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 FI 技術表示箇所 C08L 101/00 LSY B09B 3/00 301Z ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 6 Identification code Office reference number FI technical display location C08L 101/00 LSY B09B 3/00 301Z

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 乾燥重量で紙質及び/又は木質廃材35
〜40重量部及びプラスチック廃材35〜40重量部の
混合物に、水酸化アルミニウム(a)、珪酸ソーダ
(b)及び塩化カルシウムもしくは塩化マグネシウム
(c)をa:b:cの重量比が6:1〜3:1〜3とな
るように混合した耐火用添加剤20〜30重量部を、全
体が100重量部となるように添加したことを特徴とす
る耐火性ボード組成物。
1. A dry weight of paper and / or wood waste material 35
To 40 parts by weight and 35 to 40 parts by weight of plastic waste material, aluminum hydroxide (a), sodium silicate (b) and calcium chloride or magnesium chloride (c) in a weight ratio of a: b: c of 6: 1. A fire-resistant board composition comprising 20 to 30 parts by weight of a refractory additive mixed so as to be 3 to 1 to 3 so as to be 100 parts by weight as a whole.
【請求項2】 乾燥重量で紙質及び/又は木質廃材35
〜40重量部及びプラスチック廃材35〜40重量部の
混合物に、アルミナセメント(a′)及びシリカ扮末
(b′)をa′:b′の重量比が1:0.5〜1.5にな
るように混合した耐火用添加剤20〜30重量部を、全
体が100重量部となるように添加したことを特徴とす
る耐火性ボード組成物。
2. Paper and / or wood waste material 35 by dry weight
To 40 parts by weight and 35 to 40 parts by weight of plastic waste material, alumina cement (a ') and silica powder (b') in a weight ratio of a ': b' of 1: 0.5 to 1.5. A refractory board composition comprising 20 to 30 parts by weight of a refractory additive mixed so that the total amount thereof is 100 parts by weight.
JP27503195A 1995-09-29 1995-09-29 Fire resistant board composition Expired - Fee Related JP2736317B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP27503195A JP2736317B2 (en) 1995-09-29 1995-09-29 Fire resistant board composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP27503195A JP2736317B2 (en) 1995-09-29 1995-09-29 Fire resistant board composition

Publications (2)

Publication Number Publication Date
JPH0995556A true JPH0995556A (en) 1997-04-08
JP2736317B2 JP2736317B2 (en) 1998-04-02

Family

ID=17549915

Family Applications (1)

Application Number Title Priority Date Filing Date
JP27503195A Expired - Fee Related JP2736317B2 (en) 1995-09-29 1995-09-29 Fire resistant board composition

Country Status (1)

Country Link
JP (1) JP2736317B2 (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100320412B1 (en) * 1999-11-25 2002-01-12 최낙명, 홍석범 Fire retardant composition and its manufacturing method
JP2002137213A (en) * 2000-11-06 2002-05-14 Okamura Corp Method for recycling top board
US6500373B1 (en) 1998-02-23 2002-12-31 Masao Konishi Manufacturing method of fused molded product mainly composed of various plastics
JP2005343045A (en) * 2004-06-03 2005-12-15 Joto Techno Co Ltd Molding
JP2007507579A (en) * 2003-09-29 2007-03-29 チェー,ジュン−ハン Non-combustible composition, architectural non-combustible molded article using the same, and method for producing the same
JP2013022954A (en) * 2011-07-21 2013-02-04 Hideo Yugawa Method of producing fiberboard having improved water resistance, fire resistance and physical strength
RU2688718C1 (en) * 2018-09-27 2019-05-22 Федеральное государственное бюджетное образовательное учреждение высшего образования "Саратовский государственный технический университет имени Гагарина Ю.А." (СГТУ имени Гагарина Ю.А.) Mixture for producing composite construction materials containing components of municipal wastes

Cited By (8)

* Cited by examiner, † Cited by third party
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US6500373B1 (en) 1998-02-23 2002-12-31 Masao Konishi Manufacturing method of fused molded product mainly composed of various plastics
KR100320412B1 (en) * 1999-11-25 2002-01-12 최낙명, 홍석범 Fire retardant composition and its manufacturing method
JP2002137213A (en) * 2000-11-06 2002-05-14 Okamura Corp Method for recycling top board
JP4519305B2 (en) * 2000-11-06 2010-08-04 株式会社岡村製作所 How to recycle the top board
JP2007507579A (en) * 2003-09-29 2007-03-29 チェー,ジュン−ハン Non-combustible composition, architectural non-combustible molded article using the same, and method for producing the same
JP2005343045A (en) * 2004-06-03 2005-12-15 Joto Techno Co Ltd Molding
JP2013022954A (en) * 2011-07-21 2013-02-04 Hideo Yugawa Method of producing fiberboard having improved water resistance, fire resistance and physical strength
RU2688718C1 (en) * 2018-09-27 2019-05-22 Федеральное государственное бюджетное образовательное учреждение высшего образования "Саратовский государственный технический университет имени Гагарина Ю.А." (СГТУ имени Гагарина Ю.А.) Mixture for producing composite construction materials containing components of municipal wastes

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