KR100263216B1 - Concentrated, stable fablic softener composition - Google Patents

Abstract

Fabric softener activity with main solvents, especially monool and diol main solvents having a ClogP of from about 0.15 to about 0.64, preferably from about 0.25 to about 0.62, more preferably from about 0.40 to 0.60, having ester bonds in the hydrophobic long chain chain It is disclosed to have the ability to prepare transparent aqueous fabric softener compositions containing a relatively high concentration of a sieve. The fabric softener activator is unsaturated or has a medium length chain (˜C _12-14 ) and the main solvent is used in an amount up to about 40%. Other solvents may also be present. Some of the main solvents are novel compounds and / or novel mixtures. Premixes of fabric softeners, main solvents and any other solvents are useful in complete formulations by eliminating / limiting the need for heating.

Description

Concentrated, Stable Fabric Softener Composition {CONCENTRATED, STABLE FABLIC SOFTENER COMPOSITION}

The present invention relates to compositions for softening, preferably translucent, or more preferably transparent, aqueous, concentrated, liquid softening useful for softening clothing. In particular, the present invention relates to a fabric softening composition for use in a rinse cycle of a fabric laundry operation, in order to provide good fabric-flexible / electrostatic-controlling advantages, wherein the composition is particularly at or below normal temperatures, ie normal room temperature. At temperatures up to 25 ° C., for example, having good water-dispersibility, and for example stain reduction of fabrics, and good re-wetting, and / or improved storage and viscosity stability.

The art describes problems related to the processing and preparation of clear, concentrated fabric conditioning formulations. For example, European Patent Application No. 404,471 (Machin et al., Published December 27, 1990) discloses an isotropic liquid casting composition containing at least 20% by weight of a softener and at least 5% by weight of a short chain organic acid. have.

Fabric softening compositions containing high content of solvents are known in the art. However, softener aggregates can form and deposit on clothing, which can reduce staining and softening performance. In addition, the composition may be increased in concentration and / or precipitated at low temperatures, that is, at a temperature of about 40 ° F. (about 4 ° C.) to about 65 ° F. (about 18 ° C.). The composition can also lead to an increase in cost to the consumer due to the high solvent content associated with the production of concentrated transparent products.

The present invention provides a concentrated, aqueous liquid textile treatment composition having a relatively low solvent content (ie, preferably up to about 40% by weight of the composition), wherein the composition is normal under extended storage conditions. With improved stability at temperatures, ie room temperature and below normal (ie, transparent or translucent and do not precipitate, gel, increase concentration or solidify). It is characterized by having an organic solvent in a limited molar ratio range relative to the fabric softener. The composition also provides good soft water dissipation and good cold water dispersibility, with good flexibility, antistatic properties and fabric re-wetting, in addition to the reduction of dispersant residues formed and good freeze-thaw recovery.

It is an object of the present invention to provide one or more of the following: reduced contamination on fabrics, good dispersibility in rinse water, phase safety at low temperatures and / or preferably acceptable viscosity and viscosity stability at low temperatures, and / or recovery from freezing. It is to provide an aqueous, concentrated, translucent, or preferably transparent, rinse-added liquid fabric casting composition that provides advantages.

Summary of the Invention

The composition herein comprises the following A to E:

A. About 2 to about 80%, preferably about 13 to about 75%, more preferably about 17% of the biodegradable fabric softener active agent selected from the group consisting of 1 to 3, based on the weight of the composition: To about 70%, and even more preferably about 19 to about 65%:

1. Softeners having Formula 1 below:

Wherein each R substituent is H or a short chain C _1-6 , preferably C _1-3 alkyl or hydroxyalkyl group, for example methyl (most preferred), ethyl, propyl, hydroxyethyl and the like, benzyl Or mixtures thereof; Each m is 2 or 3; Each n is from 1 to about 4, preferably 2; Each Y is -O- (O) C-,-(R) N- (O) C-, -C (O) -N (R)-or -C (O) -O-, preferably -O- (O) C-; Each of the sum of the carbon in the R ¹ - plus 1 (subsequent, R ¹ and YR ^1, 'YR ¹ (Y is -O- (O) C- or (R) N- (O) -C- one time) Sum 'is used alternately to represent a hydrophobic chain, generally R ¹ chain length is even for fatty alcohols and amines and odd for fatty acids.) Is C _6-22 , preferably C _14-20 And the sum of only one YR ¹ is about 12 or less, and the sum of the other YR ¹ is about 16 or more, and each R ¹ is a long chain C _6-22 (or C _5-21 ) hydrocarbyl, or substituted Hydrocarbyl substituents, preferably C _10-20 (or C _9-19 ) alkyl or alkenyl (unsaturated alkyl groups including polyunsaturated alkyl, sometimes also referred to as 'alkylene'), most preferably C _12- R ¹ is a straight group when ₁₈ (or C _11-17 ) alkyl or alkylene and the sum of the carbons is C _16-18 and the iodine value of the parent fatty acid of the R ¹ group (hereinafter referred to as IV) Is Preferably from about 20 to about 140, more preferably from about 50 to about 130, and most preferably from about 70 to about 115 (herein, the iodine value of the 'parent' fatty acid, or 'corresponding' fatty acid, Means an unsaturated group of an R ¹ group having the same content as that of an unsaturated group present in a fatty acid containing the same R ¹ group; Counter ions of X ^- is a softener-compatible anion, preferably, chloride, bromide, methyl sulfate, ethyl sulfate, sulfate and nitrate anions, and more preferably a chlorine anion;

2. Softeners having Formula 2

Wherein each Y, R, R ¹ and X ^(-) is as defined above (such compounds include the formula [CH ₃ ] ₃ N ⁽⁺⁾ [CH ₂ CH (CH ₂ O (O) CR ¹ ) O (O) CR ¹ ] Cl ^(-) (wherein C (O) R ¹ is derived from unsaturated, for example oleic acid, fatty acids, preferably each R is a methyl or ethyl group, preferably Each R ¹ is in the range of C _15-19 , wherein certain branching and substitution may occur in the alkyl chain); and

3. mixtures thereof;

[In one preferred biodegradable quaternary ammonium fabric softening compound, C (O) R ¹ is derived from unsaturated fatty acids such as oleic acid, and / or fatty acids and / or partially hydrogenated fatty acids, and also from vegetable oils and And / or derived from partially hydrogenated vegetable oils such as canola oil, safflower oil, peanut oil, sunflower oil, soybean oil, corn oil, tall oil, rice bran oil, and other preferred biodegradable quaternary ammonium fabric softening compounds,- (O) CR ¹ is saturated (preferably less than 10 iodine, more preferably about 5 or less), C _8-14 , preferably C _12-14 hydrocarbyl, or for example in coconut palm oil Derived substituted hydrocarbyl substituent] [Hereinafter, the biodegradable fabric softener activator containing an ester bond is called 'DEQA', which is a diester, triester quantum wool. Containing, and monoester compounds 3 a long chain hydrophobic group naejineun 1, preferably containing two or more. The corresponding amide softener activator and mixed ester-amide softener activator may also contain 1 to 3, preferably 2, long chain hydrophobic groups. Preferred fabric softener actives have the properties that can be prepared by conventional mixing methods at ambient temperature, in the presence of at least about 15% solvent C, as described below.];

B. 2,2,4-trimethyl-1,3-pentanediol having a ClogP of about 0.15 to about 0.64, preferably about 0.25 to about 0.62, and more preferably about 0.40 to about 0.60; Ethoxylate, diethoxylate or triethoxylate of said 2,2,4-trimethyl-1,3-pentanediol; And / or an insufficient amount of a solvent selected from the group consisting of 2-ethyl-1,3-hexanediol, and / or mixtures thereof, and when used alone provide a transparent product, preferably Is insufficient to provide a stable product, more preferably a detectable change in the physical properties of the composition, and in particular insufficient to provide a complete glass thereof, preferably selected from the group consisting of I to XI About 40% or less, preferably about 10 to about 35%, more preferably about 12 to about 25%, and even more preferably about 14 to about 20% of the main solvent (by weight of the composition):

I. Monools comprising:

a. n-propanol and / or

b. 2-butanol or 2-methyl-2-propanol;

II. Hexane diol isomers comprising:

2,3-butanediol, 2,3-dimethyl-; 1,2-butanediol, 2,3-dimethyl-; 1,2-butanediol, 3,3-dimethyl-; 2,3-pentanediol, 2-methyl-; 2,3-pentanediol, 3-methyl-; 2,3-pentanediol. 4-methyl-; 2,3-hexanediol; 3,4-hexanediol; 1,2-butanediol, 2-ethyl-; 1,2-pentanediol, 2-methyl-; 1,2-pentanediol, 3-methyl-; 1,2-pentanediol, 4-methyl-; And / or 1,2-hexanediol;

III. Heptane diol isomers comprising:

1,3-propanediol, 2-butyl-; 1,3-propanediol, 2,2-diethyl-; 1,3-propanediol, 2- (l-methylpropyl)-; 1,3-propanediol, 2- (2-methylpropyl)-; 1,3-propanediol, 2-methyl-2-propyl-; 1,2-butanediol, 2,3,3-trimethyl-; 1,4-butanediol, 2-ethyl-2-methyl-; 1,4-butanediol, 2-ethyl-3-methyl-; 1,4-butanediol, 2-propyl-; 1,4-butanediol, 2-isopropyl-; 1,5-pentanediol, 2,2-dimethyl-; 1,5-pentanediol, 2,3-dimethyl-; 1,5-pentanediol, 2,4-dimethyl-; 1,5-pentanediol, 3,3-dimethyl-; 2,3-pentanediol, 2,3-dimethyl-; 2,3-pentanediol, 2,4-dimethyl-; 2,3-pentanediol, 3,4-dimethyl-; 2,3-pentanediol, 4,4-dimethyl-; 3,4-pentanediol, 2,3-dimethyl-; 1,5-pentanediol, 2-ethyl-; 1,6-hexanediol, 2-methyl-; 1,6-hexanediol, 3-methyl-; 2,3-hexanediol, 2-methyl-; 2,3-hexanediol, 3-methyl-; 2,3-hexanediol, 4-methyl-; 2,3-hexanediol, 5-methyl-; 3,4-hexanediol, 2-methyl-; 3,4-hexanediol, 3-methyl-; 1,3-heptanediol; 1,4-heptanediol; 1,5-heptanediol; And / or 1,6-heptanediol;

Ⅳ. Octane diol isomers comprising:

1,3-propanediol, 2- (2-methylbutyl)-; 1,3-propanediol, 2- (1,1-dimethylpropyl)-; 1,3-propanediol, 2- (1,2-dimethylpropyl)-; 1,3-propanediol, 2- (l-ethylpropyl)-; 1,3-propanediol, 2- (l-methylbutyl)-; 1,3-propanediol, 2- (2,2-dimethylpropyl)-; 1,3-propanediol, 2- (3-methylbutyl)-; 1,3-propanediol, 2-butyl-2-methyl-; 1,3-propanediol, 2-ethyl-2-isopropyl-; 1,3-propanediol, 2-ethyl-2-propyl-; 1,3-propanediol, 2-methyl-2- (1-methylpropyl)-; 1,3-propanediol, 2-methyl-2- (2-methylpropyl)-; 1,3-propanediol, 2-t-butyl-2-methyl-; 1,3-butanediol, 2,2-diethyl-; 1,3-butanediol, 2- (1-methylpropyl)-; 1,3-butanediol, 2-butyl-; 1,3-butanediol, 2-ethyl-2,3-dimethyl-; 1,3-butanediol, 2- (1,1-dimethylethyl)-; 1,3-butanediol, 2- (2-methylpropyl)-; 1,3-butanediol, 2-methyl-2isopropyl-; 1,3-butanediol, 2-methyl-2-propyl-; 1,3-butanediol, 3-methyl-2-isopropyl-; 1,3-butanediol, 3-methyl-2-propyl-; 1,4-butanediol, 2,2-diethyl-; 1,4-butanediol, 2-methyl-2-propyl-; 1,4-butanediol, 2- (1-methylpropyl)-; 1,4-butanediol, 2-ethyl-2,3-dimethyl-; 1,4-butanediol, 2-ethyl-3,3-dimethyl-; 1,4-butanediol, 2- (1,1-dimethylethyl)-; 1,4-butanediol, 2- (2-methylpropyl)-; 1,4-butanediol, 2-methyl-3-propyl-; 1,4-butanediol, 3-methyl-2-isopropyl-; 1,3-pentanediol, 2,2,3-trimethyl-; 1,3-pentanediol, 2,2,4-trimethyl-; 1,3-pentanediol, 2,3,4-trimethyl-; 1,3-pentanediol, 2,4,4-trimethyl-; 1,3-pentanediol, 3,4,4-trimethyl-; 1,4-pentanediol, 2,2,3-trimethyl-; 1,4-pentanediol, 2,2,4-trimethyl-; 1,4-pentanediol, 2,3,3-trimethyl-; 1,4-pentanediol, 2,3,4-trimethyl-; 1,4-pentanediol, 3,3,4-trimethyl-; 1,5-pentanediol, 2,2,3-trimethyl-; 1,5-pentanediol, 2,2,4-trimethyl-; 1,5-pentanediol, 2,3,3-trimethyl-; 1,5-pentanediol, 2,3,4-trimethyl-; 2,4-pentanediol, 2,3,3-trimethyl-; 2,4-pentanediol, 2,3,4-trimethyl-; 1,3-pentanediol, 2-ethyl-2-methyl-; 1,3-pentanediol, 2-ethyl-3-methyl-; 1,3-pentanediol, 2-ethyl-4-methyl-; 1,3-pentanediol, 3-ethyl-2-methyl-; 1,4-pentanediol, 2-ethyl-2-methyl-; 1,4-pentanediol, 2-ethyl-3-methyl-; 1,4-pentanediol, 2-ethyl-4-methyl-; 1,4-pentanediol, 3-ethyl-2-methyl-; 1,4-pentanediol, 3-ethyl-3-methyl-; 1,5-pentanediol, 2-ethyl-2-methyl-; 1,5-pentanediol, 2-ethyl-3-methyl-; 1,5-pentanediol, 2-ethyl-4-methyl-; 1,5-pentanediol, 3-ethyl-3-methyl-; 2,4-pentanediol, 3-ethyl-2-methyl-; 1,3-pentanediol, 2-isopropyl-; 1,3-pentanediol, 2-propyl-; 1,4-pentanediol, 2-isopropyl-; 1,4-pentanediol, 2-propyl-; 1,4-pentanediol, 3-isopropyl-; 1,5-pentanediol, 2-isopropyl-; 2,4-pentanediol, 3-propyl-; 1,3-hexanediol, 2,2-dimethyl-; 1,3-hexanediol, 2,3-dimethyl-; 1,3-hexanediol, 2,4-dimethyl-; 1,3-hexanediol, 2,5-dimethyl-; 1,3-hexanediol, 3,4-dimethyl-; 1,3-hexanediol, 3,5-dimethyl-; 1,3-hexanediol, 4,5-dimethyl-; 1,4-hexanediol, 2,2-dimethyl-; 1,4-hexanediol, 2,3-dimethyl-; 1,4-hexanediol, 2,4-dimethyl-; 1,4-hexanediol, 2,4-dimethyl-; 1,4-hexanediol, 3,3-dimethyl-; 1,4-hexanediol, 3,4-dimethyl-; 1,4-hexanediol, 3,5-dimethyl-; 1,3-hexanediol, 4,4-dimethyl-; 1,4-hexanediol, 4,5-dimethyl-; 1,4-hexanediol, 5,5-dimethyl-; 1,5-hexanediol, 2,2-dimethyl-; 1,5-hexanediol, 2,3-dimethyl-; 1,5-hexanediol, 2,4-dimethyl-; 1,5-hexanediol, 2,5-dimethyl-; 1,5-hexanediol, 3,3-dimethyl-; 1,5-hexanediol, 3,4-dimethyl-; 1,5-hexanediol, 3,5-dimethyl-; 1,5-hexanediol, 4,5-dimethyl-; 1,6-hexanediol, 2,2-dimethyl-; 1,6-hexanediol, 2,3-dimethyl-; 1,6-hexanediol, 2,4-dimethyl-; 1,6-hexanediol, 2,5-dimethyl-; 1,6-hexanediol, 3,3-dimethyl-; 1,6-hexanediol, 3,4-dimethyl-; 2,4-hexanediol, 2,3-dimethyl-; 2,4-hexanediol, 2,4-dimethyl-; 2,4-hexanediol, 2,5-dimethyl-; 2,4-hexanediol, 3,3-dimethyl-; 2,4-hexanediol, 3,4-dimethyl-; 2,4-hexanediol, 3,5-dimethyl-; 2,4-hexanediol, 4,5-dimethyl-; 2,4-hexanediol, 5,5-dimethyl-; 2,5-hexanediol, 2,3-dimethyl-; 2,5-hexanediol, 2,4-dimethyl-; 2,5-hexanediol, 2,5-dimethyl-; 2,5-hexanediol, 3,3-dimethyl-; 2,5-hexanediol, 3,4-dimethyl-; 2,6-hexanediol, 3,3-dimethyl-; 1,3-hexanediol, 2-ethyl-; 1,3-hexanediol, 4-ethyl-; 1,4-hexanediol, 2-ethyl-; 1,4-hexanediol, 4-ethyl-; 1,5-hexanediol, 2-ethyl-; 2,4-hexanediol, 3-ethyl-; 2,4-hexanediol, 4-ethyl-; 2,5-hexanediol, 3-ethyl-; 1,3-heptanediol, 2-methyl-; 1,3-heptanediol, 3-methyl-; 1,3-heptanediol, 4-methyl-; 1,3-heptanediol, 5-methyl-; 1,3-heptanediol, 6-methyl-; 1,4-heptanediol, 2-methyl-; 1,4-heptanediol, 3-methyl-; 1,4-heptanediol, 4-methyl-; 1,4-heptanediol, 5-methyl-; 1,4-heptanediol, 6-methyl-; 1,5-heptanediol, 2-methyl-; 1,5-heptanediol, 3-methyl-; 1,5-heptanediol, 4-methyl-; 1,5-heptanediol, 5-methyl-; 1,5-heptanediol, 6-methyl-; 1,6-heptanediol, 2-methyl-; 1,6-heptanediol, 3-methyl-; 1,6-heptanediol, 4-methyl-; 1,6-heptanediol, 5-methyl-; 1,6-heptanediol, 6-methyl-; 2,4-heptanediol, 2-methyl-; 2,4-heptanediol, 3-methyl-; 2,4-heptanediol, 4-methyl-; 2,4-heptanediol, 5-methyl-; 2,4-heptanediol, 6-methyl-; 2,5-heptanediol, 2-methyl-; 2,5-heptanediol, 3-methyl-; 2,5-heptanediol, 4-methyl-; 2,5-heptanediol, 5-methyl-; 2,5-heptanediol, 6-methyl-; 2,6-heptanediol, 2-methyl-; 2,6-heptanediol, 3-methyl-; 2,6-heptanediol, 4-methyl-; 3,4-heptanediol, 3-methyl-; 3,5-heptanediol, 2-methyl-; 3,5-heptanediol, 3-methyl-; 3,5-heptanediol, 4-methyl-; 2,4-octanediol; 2,5-octanediol; 2,6-octanediol; 2,7-octanediol; 3,5-octanediol; And / or 3,6-octanediol;

V nonan diol isomers comprising:

2,4-pentanediol, 2,3,3,4-tetramethyl-; 2,4-pentanediol, 3-t-butyl-; 2,4-hexanediol, 2,5,5-trimethyl-; 2,4-hexanediol, 3,3,4-trimethyl-; 2,4-hexanediol, 3,3,5-trimethyl-; 2,4-hexanediol, 3,5,5-trimethyl-; 2,4-hexanediol, 4,5,5-trimethyl-; 2,5-hexanediol, 3,3,4-trimethyl-; And / or 2,5-hexanediol, 3,3,5-trimethyl-;

Ⅵ. Glyceryl ether and / or di (hydroxyalkyl) ethers comprising:

1,2-propanediol, 3- (n-pentyloxy)-; 1,2-propanediol, 3- (2-pentyloxy)-; 1,2-propanediol, 3- (3-pentyloxy)-; 1,2-propanediol, 3- (2-methyl-1 -butyloxy)-; 1,2-propanediol, 3- (iso-amyloxy)-; 1,2-propanediol, 3- (3-methyl-2-butyloxy)-; 1,2-propanediol, 3- (cyclohexyloxy)-; 1,2-propanediol, 3- (1-cyclohex-1-enyloxy)-; 1,3-propanediol, 2- (pentyloxy)-; 1,3-propanediol, 2- (2-pentyloxy)-; 1,3-propanediol, 2- (3-pentyloxy)-; 1,3-propanediol, 2- (2-methyl-1 -butyloxy)-; 1,3-propanediol, 2- (iso-amyloxy)-; 1,3-propanediol, 2- (3-methyl-2-butyloxy)-; 1,3-propanediol, 2- (cyclohexyloxy)-; 1,3-propanediol, 2- (1-cyclohex-1-enyloxy)-; 1,2-propanediol, 3- (butyloxy)-, triethoxylated; 1,2-propanediol, 3- (butyloxy)-, tetraethoxylated; 1,2-propanediol, 3- (butyloxy)-, pentaethoxylated; 1,2-propanediol, 3- (butyloxy)-, hexaethoxylated; 1,2-propanediol, 3- (butyloxy)-, heptaethoxylation; 1,2-propanediol, 3- (butyloxy)-, octaethoxylation; 1,2-propanediol, 3- (butyloxy)-, nonaethoxylation; 1,2-propanediol, 3- (butyloxy)-, monopropoxylation; 1,2-propanediol, 3- (butyloxy)-, dibutyleneoxylation; 1,2-propanediol, 3- (butyloxy)-, tributyleneoxylation; 1,2-propanediol, 3-phenyloxy-; 1,2-propanediol, 3-benzyloxy-; 1,2-propanediol, 3- (2-phenolethyloxy)-; 1,2-propanediol, 3- (1-phenyl-2-propanyloxy)-; 1,3-propanediol, 2-phenyloxy-; 1,3-propanediol, 2- (m-cresyloxy)-; 1,3-propanediol, 2- (p-cresyloxy)-; 1,3-propanediol, -benzyloxy-; 1,3-propanediol, 2- (2-phenylethyloxy)-; 1,3-propanediol, 2- (1-phenylethyloxy)-; Bis (2-hydroxybutyl) ether, and / or bis (2-hydroxycyclopentyl) ether;

Iii. Saturated and unsaturated aliphatic cyclic diols and derivatives thereof comprising:

(a) saturated diols and derivatives thereof comprising:

1-isopropyl-1,2-cyclobutanediol; 3-ethyl-4-methyl-1,2-cyclobutanediol; 3-propyl-1,2-cyclobutanediol; 3-isopropyl-1,2-cyclobutanediol; 1-ethyl-1,2-cyclopentanediol; 1,2-dimethyl-1,2-cyclopentanediol; 1,4-dimethyl-1,2-cyclopentanediol; 2,4,5-trimethyl-1,3-cyclopentanediol; 3,3-dimethyl-1,2-cyclopentanediol; 3,4-dimethyl-1,2-cyclopentanediol; 3,5-dimethyl-1,2-cyclopentanediol; 3-ethyl-1,2-cyclopentanediol; 4,4-dimethyl-1,2-cyclopentanediol; 4-ethyl-1,2-cyclopentanediol; 1,1-bis (hydroxymethyl) cyclohexane; 1,2-bis (hydroxymethyl) cyclohexane; 1,2-dimethyl-1,3-cyclohexanediol; 1,3-bis (hydroxymethyl) cyclohexane; 1,3-dimethyl-1,3-cyclohexanediol; 1,6-dimethyl-1,3-cyclohexanediol; 1-hydroxycyclohexaneethanol; 1-hydroxy-cyclohexanemethanol; 1-ethyl-1,3-cyclohexanediol; 1-methyl-1,2-cyclohexanediol; 2,2-dimethyl-1,3-cyclohexanediol; 2,3-dimethyl-1,4-cyclohexanediol; 2,4-dimethyl-1,3-cyclohexanediol; 2,5-dimethyl-1,3-cyclohexanediol; 2,6-dimethyl-1,4-cyclohexanediol; 2-ethyl-1,3-cyclohexanediol; 2-hydroxycyclohexaneethanol; 2-hydroxyethyl-1-cyclohexanol; 2-hydroxymethylcyclohexanol; 3-hydroxyethyl-1-cyclohexanol; 3-hydroxycyclohexaneethanol; 3-hydroxymethylcyclohexanol; 3-methyl-1,2-cyclohexanediol; 4,4-dimethyl-1,3-cyclohexanediol; 4,5-dimethyl-1,3-cyclohexanediol; 4,6-dimethyl-1,3-cyclohexanediol; 4-ethyl-1,3-cyclohexanediol; 4-hydroxyethyl-1-cyclohexanol; 4-hydroxymethylcyclohexanol; 4-methyl-1,2-cyclohexanediol; 5,5-dimethyl-1,3-cyclohexanediol; 5-ethyl-1,3-cyclohexanediol; 1,2-cycloheptanediol; 2-methyl-1,3-cycloheptanediol; 2-methyl-1,4-cycloheptanediol; 4-methyl-1,3-cycloheptanediol; 5-methyl-1,3-cycloheptanediol; 5-methyl-1,4-cycloheptanediol; 6-methyl-1,4-cycloheptanediol; 1,3-cyclooctanediol; 1,4-cyclooctanediol; 1,5-cyclooctanediol; 1,2-cyclohexanediol, diethoxylation; 1,2-cyclohexanediol, triethoxylation; 1,2-cyclohexanediol, tetraethoxylation; 1,2-cyclohexanediol, pentaethoxylation; 1,2-cyclohexanediol, hexaethoxylation; 1,2-cyclohexanediol, heptaethoxylation; 1,2-cyclohexanediol, octaethoxylation; 1,2-cyclohexanediol, nonaethoxylation; 1,2-cyclohexanediol, monopropoxylation; 1,2-cyclohexanediol, monobutyleneoxylation; 1,2-cyclohexanediol, dibutyleneoxylation; And / or 1,2-cyclohexanediol, tributyleneoxylation; And

(b) unsaturated aliphatic cyclic diols comprising:

1,2-cyclobutanediol, 1-ethenyl-2-ethyl-; 3-cyclobutene-1,2-diol, 1,2,3,4-tetramethyl-; 3-cyclobutene-1,2-diol, 3,4-diethyl-; 3-cyclobutene-1,2-diol, 3- (1,1-dimethylethyl)-; 3-cyclobutene-1,2-diol, 3-butyl-; 1,2-cyclopentanediol, 1,2-dimethyl-4-methylene-; 1,2-cyclopentanediol, 1-ethyl-3-methylene-; 1,2-cyclopentanediol, 4- (1-propenyl); 3-cyclopentene-1,2-diol, 1-ethyl-3-methyl-; 1,2-cyclohexanediol, 1-ethenyl-; 1,2-cyclohexanediol, 1-methyl-3-methylene-; 1,2-cyclohexanediol, 1-methyl-4-methylene-; 1,2-cyclohexanediol, 3-ethenyl-; 1,2-cyclohexanediol, 4-ethenyl-; 3-cyclohexene-1,2-diol, 2,6-dimethyl-; 3-cyclohexene-1,2-diol, 6,6-dimethyl-; 4-cyclohexene-1,2-diol, 3,6-dimethyl-; 4-cyclohexene-1,2-diol, 4,5-dimethyl-; 3-cyclooctene-1,2-diol; 4-cyclooctene-1,2-diol; And / or 5-cyclooctene-1,2-diol;

Iii. _Alkoxylated derivatives of C _3-8 diols, including 'EO' in the following meaning polyethoxylated, i.e.,-(CH ₂ CH ₂ O) _n H; Me-E _n is methyl-cap polyethoxylated — (CH ₂ CH ₂ O) _n CH ₃ ; '2 (Me-E _n )' means the required 2 Me-E _n groups; 'PO' means polypropoxylated,-(CH (CH ₃ ) CH ₂ O) _n H; 'BO' means polybutyleneoxy group, (CH (CH ₂ CH ₃ ) CH ₂ 0) _n H; And 'n-BO' means poly (n-butyleneoxy) or poly (tetramethylene) oxy group-(CH ₂ CH ₂ CH ₂ CH ₂ O) _n H. The term '(C _x )' here means the number of carbon atoms in the alkoxylated base material:

1. 1,2-propanediol (C3) 2 (Me-E _1-4 ); 1,2-propanediol (C3) P0 ₄ ; 1,2-propanediol, 2-methyl- (C4) (Me-E _4-10 ); 1,2-propanediol, 2-methyl- (C4) 2 (Me-E ₁ ); 1,2-propanediol, 2-methyl- (C4) PO ₃ ; 1,2-propanediol, 2-methyl- (C4) BO ₁ ; 1,3-propanediol (C3) 2 (Me-E _6-8 ); 1,3-propanediol (C3) P0 _5-6 ; 1,3-propanediol, 2,2-diethyl- (C7) _El-7 ; 1,3-propanediol, 2,2-diethyl- (C7) PO ₁ ; 1,3-propanediol, 2,2-diethyl- (C7) n-BO _1-2 ; 1,3-propanediol, 2,2-dimethyl- (C5) 2 (Me E _l-2 ); 1,3-propanediol, 2,2-dimethyl- (C5) PO _3-4 ; 1,3-propanediol, 2- (1-methylpropyl)-(C7) _El-7 ; 1,3-propanediol, 2- (1-methylpropyl)-(C7) PO ₁ ; 1,3-propanediol, 2- (1-methylpropyl)-(C7) n-BO _1-2 ; 1,3-propanediol, 2- (2-methylpropyl)-(C7) _El-7 ; 1,3-propanediol, 2- (2-methylpropyl)-(C7) PO ₁ ; 1,3-propanediol, 2- (2-methylpropyl)-(C7) n-BO _1-2 ; 1,3-propanediol, 2-ethyl- (C5) (Me E _6-10 ); 1,3-propanediol, 2-ethyl- (C5) 2 (Me _El ); 1,3-propanediol, 2-ethyl- (C5) P0 ₃ ; 1,3-propanediol, 2-ethyl-2-methyl- (C6) (Me _El-6 ); 1,3-propanediol, 2-ethyl-2-methyl- (C6) P0 ₂ ; 1,3-propanediol, 2-ethyl-2-methyl- (C6) BO ₁ ; 1,3-propanediol, 2-isopropyl- (C6) (Me _El-6 ); 1,3-propanediol, 2-isopropyl- (C6) PO ₂ ; 1,3-propanediol, 2-isopropyl- (C6) BO ₁ ; 1,3-propanediol, 2-methyl- (C4) 2 (Me E _2-5 ); 1,3-propanediol, 2-methyl- (C4) P0 _4-5 ; 1,3-propanediol, 2-methyl- (C4) B0 ₂ ; 1,3-propanediol, 2-methyl-2-isopropyl- (C7) E _2-9 ; 1,3-propanediol, 2-methyl-2-isopropyl- (C7) PO ₁ ; 1,3-propanediol, 2-methyl-2-isopropyl- (C7) n-BO _1-3 ; 1,3-propanediol, 2-methyl-2-propyl- (C7) _El-7 ; 1,3-propanediol, 2-methyl-2-propyl- (C7) PO ₁ ; 1,3-propanediol, 2-methyl-2-propyl (C7) n-BO _1-2 ; 1,3-propanediol, 2-propyl- (C6) (Me E _1-4 ); 1,3-propanediol, 2-propyl- (C6) PO ₂ ; 1,3-propanediol, 2-propyl- (C6) BO ₁ ;

2. 1,2-butanediol (C4) (Me E _2-8 ); 1,2-butanediol (C4) P0 _2-3 ; 1,2-butanediol (C4) BO ₁ ; 1,2-butanediol, 2,3-dimethyl- (C6) _El-6 ; 1,2-butanediol, 2,3-dimethyl- (C6) n-BO _1-2 ; 1,2-butanediol, 2-ethyl- (C6) _El-3 ; 1,2-butanediol, 2-ethyl (C6) n-BO ₁ ; 1,2-butanediol, 2-methyl- (C5) (Me E _l-2 ); 1,2-butanediol, 2-methyl- (C5) PO ₁ ; 1,2-butanediol, 3,3-dimethyl- (C6) _El-6 , 1,2-butanediol, 3,3-dimethyl- (C6) n-BO _1-2 ; 1,2-butanediol, 3-methyl- (C5) (Me _El-1 ); 1,2-butanediol, 3-methyl- (C5) PO ₁ ; 1,3-butanediol (C4) 2 (Me E _3-6 ); 1,3-butanediol (C4) P0 ₅ ; 1,3-butanediol (C4) B0 ₂ ; 1,3-butanediol, 2,2,3-trimethyl- (C7) (Me E _l-3 ); 1,3-butanediol, 2,2,3-trimethyl- (C7) PO _1-2 ; 1,3-butanediol, 2,2-dimethyl- (C6) (Me E _3-8 ); 1,3-butanediol, 2,2-dimethyl- (C6) PO ₃ ; 1,3-butanediol, 2,3-dimethyl- (C6) (Me E _3-8 ); 1,3-butanediol, 2,3-dimethyl- (C6) PO ₃ ; 1,3-butanediol, 2-ethyl- (C6) (Me _El-6 ); 1,3-butanediol, 2-ethyl- (C6) P0 _2-3 ; 1,3-butanediol, 2-ethyl- (C6) BO ₁ ; 1,3-butanediol, 2-ethyl-2-methyl- (C7) (Me _El ); 1,3-butanediol, 2-ethyl-2-methyl- (C7) PO ₁ ; 1,3-butanediol, 2-ethyl-2-methyl- (C7) n-BO _2-4 ; 1,3-butanediol, 2-ethyl-3-methyl- (C7) (Me _El ); 1,3-butanediol, 2-ethyl-3-methyl- (C7) PO ₁ ; 1,3-butanediol, 2-ethyl-3-methyl- (C7) n-BO _2-4 ; 1,3-butanediol, 2-isopropyl- (C7) (Me _El ); 1,3-butanediol, 2-isopropyl- (C7) PO ₁ ; 1,3-butanediol, 2-isopropyl- (C7) n-BO _2-4 ; 1,3-butanediol, 2-methyl- (C5) 2 (Me E _l-3 ); 1,3-butanediol, 2-methyl- (C5) P0 ₄ ; 1,3-butanediol, 2-propyl- (C7) E _2-9 ; 1,3-butanediol, 2-propyl- (C7) PO ₁ ; 1,3-butanediol, 2-propyl- (C7) n-BO _1-3 ; 1,3-butanediol, 3-methyl- (C5) 2 (Me El _l-3 ); 1,3-butanediol, 3-methyl- (C5) P0 ₄ ; 1,4-butanediol (C4) 2 (Me E _2-4 ); 1,4-butanediol (C4) P0 _4-5 ; 1,4-butanediol (C4) B0 ₂ ; 1,4-butanediol, 2,2,3-trimethyl- (C7) E _2-9 ; 1,4-butanediol, 2,2,3-trimethyl- (C7) PO ₁ ; 1,4-butanediol, 2,2,3-trimethyl- (C7) n-BO _1-3 ; 1,4-butanediol, 2,2-dimethyl- (C6) (Me _El-6 ); 1,4-butanediol, 2,2-dimethyl- (C6) PO ₂ ; 1,4-butanediol, 2,2-dimethyl- (C6) BO ₁ ; 1,4-butanediol, 2,3-dimethyl- (C6) (Me _El-6 ); 1,4-butanediol, 2,3-dimethyl- (C6) PO ₂ ; 1,4-butanediol, 2,3-dimethyl- (C6) BO ₁ ; 1,4-butanediol, 2-ethyl- (C6) (Me E _1-4 ); 1,4-butanediol, 2-ethyl- (C6) P0 ₂ ; 1,4-butanediol, 2-ethyl- (C6) BO ₁ ; 1,4-butanediol, 2-ethyl-2-methyl- (C7) _El-7 ; 1,4-butanediol, 2-ethyl-2-methyl- (C7) PO ₁ ; 1,4-butanediol, 2-ethyl-2-methyl- (C7) n-BO _1-2 ; 1,4-butanediol, 2-ethyl-3-methyl- (C7) _El-7 ; 1,4-butanediol, 2-ethyl-3-methyl- (C7) PO ₁ ; 1,4-butanediol, 2-ethyl-3-methyl- (C7) n-BO _1-2 ; 1,4-butanediol, 2-isopropyl- (C7) _El-7 ; 1,4-butanediol, 2-isopropyl- (C7) PO ₁ ; 1,4-butanediol, 2-isopropyl- (C7) n-BO _1-2 ; 1,4-butanediol, 2-methyl- (C5) (Me E _6-10 ); 1,4-butanediol, 2-methyl- (C5) 2 (Me _El ); 1,4-butanediol, 2-methyl- (C5) PO ₃ ; 1,4-butanediol, 2-methyl- (C5) BO ₁ ; 1,4-butanediol, 2-propyl- (C7) _El-5 ; 1,4-butanediol, 2-propyl- (C7) n-BO _1-2 ; 1,4-butanediol, 3-ethyl-l-methyl- (C7) E _2-9 ; 1,4-butanediol, 3-ethyl-l-methyl- (C7) PO ₁ ; 1,4-butanediol, 3-ethyl-l-methyl- (C7) n-BO _1-3 ; 2,3-butanediol (C4) (Me E _6-10 ); 2,3-butanediol (C4) 2 (Me _El ); 2,3-butanediol (C4) PO _3-4 ; 2,3-butanediol (C4) BO ₁ ; 2,3-butanediol, 2,3-dimethyl- (C6) E _3-9 ; 2,3-butanediol, 2,3-dimethyl- (C6) PO ₁ ; 2,3-butanediol, 2,3-dimethyl- (C6) n-BO _1-3 ; 2,3-butanediol, 2-methyl- (C5) (Me _El-5 ); 2,3-butanediol, 2-methyl- (C5) PO ₂ ; 2,3-butanediol, 2-methyl- (C5) BO ₁ ;

3. 1,2-pentanediol (C5) E _3-10 ; 1,2-pentanediol, (C5) PO ₁ ; 1,2-pentanediol, (C5) n-BO _2-3 ; 1,2-pentanediol, 2-methyl (C6) E _1-3 ; 1,2-pentanediol, 2-methyl (C6) n-BO ₁ ; 1,2-pentanediol, 2-methyl (C6) BO ₁ ; 1,2-pentanediol, 3-methyl (C6) _El-3 ; 1,2-pentanediol, 3-methyl (C6) n-BO ₁ ; 1,2-pentanediol, 4-methyl (C6) _El-1 ; 1,2-pentanediol, 4-methyl (C6) n-BO ₁ ; 1,3-pentanediol (C5) 2 (Me-E _1-2 ); 1,3-pentanediol (C5) P0 _3-4 ; 1,3-pentanediol, 2,2-dimethyl- (C7) (Me-E _l ); 1,3-pentanediol, 2,2-dimethyl- (C7) PO ₁ ; 1,3-pentanediol, 2,2-dimethyl- (C7) n-BO _2-4 ; 1,3-pentanediol, 2,3-dimethyl- (C7) (Me-E _l ); 1,3-pentanediol, 2,3-dimethyl- (C7) PO ₁ ; 1,3-pentanediol, 2,3-dimethyl- (C7) n-BO _2-4 ; 1,3-pentanediol, 2,4-dimethyl (C7) (Me-E _l ); 1,3-pentanediol, 2,4-dimethyl- (C7) PO ₁ ; 1,3-pentanediol, 2,4-dimethyl- (C7) n-BO _2-4 ; 1,3-pentanediol, 2-ethyl- (C7) E _2-9 ; 1,3-pentanediol, 2-ethyl- (C7) PO ₁ ; 1,3-pentanediol, 2-ethyl- (C7) n-BO _1-3 ; 1,3-pentanediol, 2-methyl- (C6) 2 (Me-E _1-6 ); 1,3-pentanediol, 2-methyl- (C6) P0 _2-3 ; 1,3-pentanediol, 2-methyl- (C6) BO ₁ ; 1,3-pentanediol, 3,4-dimethyl- (C7) (Me-E _l ); 1,3-pentanediol, 3,4-dimethyl- (C7) PO ₁ ; 1,3-pentanediol, 3,4-dimethyl- (C7) n-BO _2-4 , 1,3-pentanediol, 3-methyl- (C6) 2 (Me-E _1-6 ); 1,3-pentanediol, 3-methyl- (C6) P0 _2-3 ; 1,3-pentanediol, 3-methyl- (C6) BO ₁ ; 1,3-pentanediol, 4,4-dimethyl- (C7) (Me-E _l ); 1,3-pentanediol, 4,4-dimethyl- (C7) PO ₁ ; 1,3-pentanediol, 4,4-dimethyl- (C7) n-BO _2-4 ; 1,3-pentanediol, 4-methyl- (C6) 2 (Me-E _1-6 ); 1,3-pentanediol, 4-methyl- (C6) P0 _2-3 ; 1,3-pentanediol, 4-methyl- (C6) BO ₁ ; 1,4-pentanediol, (C5) 2 (Me-E _1-2 ); 1,4-pentanediol (C5) PO _3-4 ; 1,4-pentanediol, 2,2-dimethyl- (C7) (Me-E _l ), 1,4-pentanediol, 2,2-dimethyl- (C7) PO ₁ ; 1,4-pentanediol, 2,2-dimethyl- (C7) n-BO _2-4 ; 1,4-pentanediol, 2,3-dimethyl- (C7) (Me-E _l ); 1,4-pentanediol, 2,3-dimethyl- (C7) PO ₁ ; 1,4-pentanediol, 2,3-dimethyl- (C7) n-BO _2-4 ; 1,4-pentanediol, 2,4-dimethyl- (C7) (Me-E _l ); 1,4-pentanediol, 2,4-dimethyl- (C7) PO ₁ ; 1,4-pentanediol, 2,4-dimethyl- (C7) n-BO _2-4 ; 1,4-pentanediol, 2-methyl- (C6) (Me-E _1-6 ); 1,4-pentanediol, 2-methyl- (C6) P0 _2-3 ; 1,4-pentanediol, 2-methyl- (C6) BO ₁ ; 1,4-pentanediol, 3,3-dimethyl- (C7) (Me-E _l ); 1,4-pentanediol, 3,3-dimethyl- (C7) PO ₁ ; 1,4-pentanediol, 3,3-dimethyl- (C7) n-BO _2-4 ; 1,4-pentanediol, 3,4-dimethyl- (C7) (Me-E _l ); 1,4-pentanediol, 3,4-dimethyl- (C7) PO ₁ ; 1,4-pentanediol, 3,4-dimethyl- (C7) n-BO _2-4 ; 1,4-pentanediol, 3-methyl- (C6) 2 (Me-E _1-6 ); 1,4-pentanediol, 3-methyl- (C6) P0 _2-3 ; 1,4-pentanediol, 3-methyl- (C6) BO ₁ ; 1,4-pentanediol, 4-methyl- (C6) 2 (Me-E _1-6 ); 1,4-pentanediol, 4-methyl- (C6) P0 _2-3 ; 1,4-pentanediol, 4-methyl- (C6) BO ₁ ; 1,5-pentanediol, (C5) (Me-E _4-110 ); 1,5-pentanediol (C5) 2 (Me-E ₁ ); 1,5-pentanediol (C5) P0 ₃ ; 1,5-pentanediol, 2,2-dimethyl- (C7) _El-7 ; 1,5-pentanediol, 2,2-dimethyl- (C7) PO ₁ ; 1,5-pentanediol, 2,2-dimethyl- (C7) n-BO _1-2 ; 1,5-pentanediol, 2,3-dimethyl- (C7) _El-7 ; 1,5-pentanediol, 2,3-dimethyl- (C7) PO ₁ ; 1,5-pentanediol, 2,3-dimethyl- (C7) n-BO _1-2 ; 1,5-pentanediol, 2,4-dimethyl- (C7) _El-7 ; 1,5-pentanediol, 2,4-dimethyl- (C7) PO ₁ ; 1,5-pentanediol, 2,4-dimethyl- (C7) n-BO _1-2 ; 1,5-pentanediol, 2-ethyl- (C7) _El-5 ; 1,5-pentanediol, 2-ethyl- (C7) n-BO _1-2 ; 1,5-pentanediol, 2-methyl- (C6) (Me-E _1-4 ); 1,5-pentanediol, 2-methyl- (C6) PO ₂ ; 1,5-pentanediol, 3,3-dimethyl- (C7) _El-7 ; 1,5-pentanediol, 3,3-dimethyl- (C7) PO ₁ ; 1,5-pentanediol, 3,3-dimethyl- (C7) nBO _1-2 ; 1,5-pentanediol, 3-methyl- (C6) (Me-E _1-4 ); 1,5-pentanediol, 3-methyl (C6) P0 ₂ ; 2,3-pentanediol, (C5) (Me-E _1-3 ); 2,3-pentanediol, (C5) PO ₂ ; 2,3-pentanediol, 2-methyl- (C6) _El-7 ; 2,3-pentanediol, 2-methyl- (C6) PO ₁ ; 2,3-pentanediol, 2-methyl- (C6) n-BO _1-2 ; 2,3-pentanediol, 3-methyl- (C6) _El-7 ; 2,3-pentanediol, 3-methyl- (C6) PO ₁ ; 2,3-pentanediol, 3-methyl- (C6) n-BO _1-2 ; 2,3-pentanediol, 4-methyl- (C6) _El-7 ; 2,3-pentanediol, 4-methyl- (C6) PO ₁ ; 2,3-pentanediol, 4-methyl- (C6) n-BO _1-2 ; 2,4-pentanediol, (C5) 2 (Me-E _1-4 ); 2,4-pentanediol (C5) P0 ₄ ; 2,4-pentanediol, 2,3-dimethyl- (C7) (Me-E _l-4 ); 2,4-pentanediol, 2,3-dimethyl- (C7) PO ₂ ; 2,4-pentanediol, 2,4-dimethyl- (C7) (Me-E _1-4 ); 2,4-pentanediol, 2,4-dimethyl- (C7) PO ₂ ; 2,4-pentanediol, 2-methyl- (C7) (Me E _5-10 ); 2,4-pentanediol, 2-methyl- (C7) PO ₃ ; 2,4-pentanediol, 3,3-dimethyl- (C7) (Me-E _1-4 ); 2,4-pentanediol, 3,3-dimethyl- (C7) PO ₂ ; 2,4-pentanediol, 3-methyl- (C6) (Me-E _5-10 ); 2,4-pentanediol, 3-methyl- (C6) PO ₃ ;

4. 1,3-hexanediol (C6) (Me-E _1-5 ); 1,3-hexanediol (C6) P0 ₂ ; 1,3-hexanediol (C6) BO ₁ ; 1,3-hexanediol, 2-methyl- (C7) E _2-9 ; 1,3-hexanediol, 2-methyl- (C7) PO ₁ ; 1,3-hexanediol, 2-methyl- (C7) n-BO _1-3 ; 1,3-hexanediol, 2-methyl- (C7) BO ₁ ; 1,3-hexanediol, 3-methyl- (C7) E _2-9 ; 1,3-hexanediol, 3-methyl (C7) PO ₁ ; 1,3-hexanediol, 3-methyl- (C7) n-BO _1-3 ; 1,3-hexanediol, 4-methyl- (C7) E _2-9 ; 1,3-hexanediol, 4-methyl- (C7) PO ₁ ; 1,3-hexanediol, 4-methyl- (C7) n-BO _1-3 ; 1,3-hexanediol, 5-methyl- (C7) E _2-9 ; 1,3-hexanediol, 5-methyl- (C7) PO ₁ ; 1,3-hexanediol, 5-methyl- (C7) n-BO _1-3 ; 1,4-hexanediol (C6) (Me-E _1-5 ); 1,4-hexanediol (C6) P0 ₂ ; 1,4-hexanediol (C6) BO ₁ ; 1,4-hexanediol, 2-methyl- (C7) E _2-9 ; 1,4-hexanediol, 2-methyl- (C7) PO ₁ ; 1,4-hexanediol, 2-methyl- (C7) n-BO _1-3 ; 1,4-hexanediol, 3-methyl- (C7) E _2-9 ; 1,4-hexanediol, 3-methyl- (C7) PO ₁ ; 1,4-hexanediol, 3-methyl- (C7) n-BO _1-3 ; 1,4-hexanediol, 4-methyl- (C7) E _2-9 ; 1,4-hexanediol, 4-methyl- (C7) PO ₁ ; 1,4-hexanediol, 4-methyl- (C7) n-BO _1-3 ; 1,4-hexanediol, 5-methyl- (C7) E _2-9 ; 1,4-hexanediol, 5-methyl- (C7) PO ₁ ; 1,4-hexanediol, 5-methyl- (C7) n-BO _1-3 ; 1,5-hexanediol (C6) (Me-E _1-5 ); 1,5-hexanediol (C6) P0 ₂ ; 1,5-hexanediol (C6) BO ₁ ; 1,5-hexanediol, 2-methyl- (C7) E _2-9 ; 1,5-hexanediol, 2-methyl- (C7) PO ₁ ; 1,5-hexanediol, 2-methyl- (C7) n-BO _1-3 ; 1,5-hexanediol, 3-methyl- (C7) E _2-9 ; 1,5-hexanediol, 3-methyl- (C7) PO ₁ ; 1,5-hexanediol, 3-methyl- (C7) n-BO _1-3 ; 1,5-hexanediol, 4-methyl- (C7) E _2-9 ; 1,5-hexanediol, 4-methyl- (C7) PO ₁ ; 1,5-hexanediol, 4-methyl- (C7) n-BO _1-3 ; 1,5-hexanediol, 5-methyl- (C7) E _2-9 ; 1,5-hexanediol, 5-methyl- (C7) PO ₁ ; 1,5-hexanediol, 5-methyl- (C7) n-BO _1-3 ; 1,6-hexanediol (C6) (Me-E _1-2 ); 1,6-hexanediol (C6) PO _1-2 ; 1,6-hexanediol (C6) n-BO ₄ ; 1,6-hexanediol, 2-methyl- (C7) _El-5 ; 1,6-hexanediol, 2-methyl- (C7) n-BO _1-2 ; 1,6-hexanediol, 3-methyl- (C7) _El-5 ; 1,6-hexanediol, 3-methyl- (C7) n-BO _1-2 ; 2,3-hexanediol (C6) _El-5 ; 2,3-hexanediol (C6) n-BO ₁ ; 2,3-hexanediol (C6) BO ₁ ; 2,4-hexanediol (C6) (Me-E _3-8 ); 2,4-hexanediol (C6) PO ₃ ; 2,4-hexanediol, 2-methyl- (C7) (Me-E _1-2 ); 2,4-hexanediol, 2-methyl- (C7) PO _1-2 ; 2,4-hexanediol, 3-methyl- (C7) (Me-E _1-2 ); 2,4-hexanediol 3-methyl- (C7) PO _1-2 ; 2,4-hexanediol, 4-methyl- (C7) (Me-E _1-2 ); 2,4-hexanediol 4-methyl- (C7) PO _1-2 ; 2,4-hexanediol, 5-methyl- (C7) (Me-E _1-2 ); 2,4-hexanediol 5-methyl- (C7) PO _1-2 ; 2,5-hexanediol (C6) (Me-E _3-8 ); 2,5-hexanediol (C6) P0 ₃ ; 2,5-hexanediol, 2-methyl- (C7) (Me-E _1-2 ); 2,5-hexanediol, 2-methyl- (C7) PO _1-2 ; 2,5-hexanediol, 3-methyl- (C7) (Me-E _1-2 ); 2,5-hexanediol, 3-methyl- (C7) PO _1-2 ; 3,4-hexanediol (C6) EO _1-5 ; 3,4-hexanediol (C6) n-BO ₁ ; 3,4-hexanediol (C6) BO ₁ ;

5. 1,3-heptanediol (C7) _El-7 ; 1,3-heptanediol (C7) PO ₁ ; 1,3-heptanediol (C7) n-BO _1-2 ; 1,4-heptanediol (C7) _El-7 ; 1,4-heptanediol (C7) PO ₁ ; 1,4-heptanediol (C7) n-BO _1-2 ; 1,5-heptanediol (C7) _El-7 ; 1,5-heptanediol (C7) PO ₁ ; 1,5-heptanediol (C7) n-BO _1-2 ; 1,6-heptanediol (C7) _El-7 ; 1,6-heptanediol (C7) PO ₁ ; 1,6-heptanediol (C7) n-BO _1-2 ; 1,7-heptanediol (C7) El _-1 ; 1,7-heptanediol (C7) n-BO ₁ ; 2,4-heptanediol (C7) E _3-10 ; 2,4-heptanediol (C7) (Me-E ₁ ); 2,4-heptanediol (C7) PO ₁ ; 2,4-heptanediol (C7) n-BO ₃ ; 2,5-heptanediol (C7) E _3-10 ; 2,5-heptanediol (C7) (Me-E _l ); 2,5-heptanediol (C7) PO ₁ ; 2,5-heptanediol (C7) n-B0 ₃ ; 2,6-heptanediol (C7) E _3-10 ; 2,6-heptanediol (C7) (Me-E _l ); 2,6-heptanediol (C7) PO ₁ ; 2,6-heptanediol (C7) n-BO ₃ ; 3,5-heptanediol (C7) E _3-10 ; 3,5-heptanediol (C7) (Me-E _l ); 3,5-heptanediol (C7) PO ₁ ; 3,5-heptanediol (C7) n-BO ₃ ;

6. 1,3-butanediol, 3-methyl-2-isopropyl- (C8) PO ₁ ; 2,4-pentanediol, 2,3,3-trimethyl- (C8) PO ₁ ; 1,3-butanediol, 2,2-diethyl- (C8) E _2-5 ; 2,4-hexanediol, 2,3-dimethyl- (C8) E _2-5 ; 2,4-hexanediol, 2,4-dimethyl- (C8) E _2-5 ; 2,4-hexanediol, 2,5-dimethyl- (C8) E _2-5 ; 2,4-hexanediol, 3,3-dimethyl- (C8) E _2-5 ; 2,4-hexanediol, 3,4-dimethyl- (C8) E _2-5 ; 2,4-hexanediol, 3,5-dimethyl- (C8) E _2-5 ; 2,4-hexanediol, 4,5-dimethyl- (C8) E _2-5 ; 2,4-hexanediol, 5,5-dimethyl- (C8) E _2-5 ; 2,5-hexanediol, 2,3-dimethyl- (C8) E _2-5 ; 2,5-hexanediol, 2,4-dimethyl- (C8) E _2-5 ; 2,5-hexanediol, 2,5-dimethyl- (C8) E _2-5 ; 2,5-hexanediol, 3,3-dimethyl- (C8) E _2-5 ; 2,5-hexanediol, 3,4-dimethyl- (C8) E _2-5 ; 3,5-heptanediol, 3-methyl- (C8) E _2-5 ; 1,3-butanediol, 2,2-diethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 2,3-dimethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 2,4-dimethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 2,5-dimethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 3,3-dimethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 3,4-dimethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 3,5-dimethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 4,5-dimethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 5,5-dimethyl-, n-BO _1-2 ; 2,5-hexanediol, 2,3-dimethyl (C8) n-BO _1-2 ; 2,5-hexanediol, 2,4-dimethyl- (C8) n-BO _1-2 ; 2,5-hexanediol, 2,5-dimethyl- (C8) n-BO _1-2 ; 2,5-hexanediol, 3,3-dimethyl- (C8) n-BO _1-2 ; 2,5-hexanediol, 3,4-dimethyl- (C8) n-BO _1-2 ; 3,5-heptanediol, 3-methyl- (C8) n-BO _1-2 ; 1,3-propanediol, 2- (1,2-dimethylpropyl)-(C8) n-BO ₁ ; 1,3-butanediol, 2-ethyl-2,3-dimethyl- (C8) n-BO ₁ ; 1,3-butanediol, 2-methyl-2-isopropyl- (C8) n-BO ₁ ; 1,4-butanediol, 3-methyl-2-isopropyl- (C8) n-BO ₁ ; 1,3-pentanediol, 2,2,3-trimethyl (C8) n-BO ₁ ; 1,3-pentanediol, 2,2,4-trimethyl- (C8) n-BO ₁ ; 1,3-pentanediol, 2,4,4-trimethyl- (C8) n-BO ₁ ; 1,3-pentanediol, 3,4,4-trimethyl- (C8) n-BO ₁ ; 1,4-pentanediol, 2,2,3-trimethyl- (C8) n-BO ₁ ; 1,4-pentanediol, 2,2,4-trimethyl- (C8) n-BO ₁ ; 1,4-pentanediol, 2,3,3-trimethyl- (C8) n-BO ₁ ; 1,4-pentanediol, 2,3,4-trimethyl- (C8) n-BO ₁ ; 1,4-pentanediol, 3,3,4-trimethyl- (C8) n-BO ₁ ; 2,4-pentanediol, 2,3,4-trimethyl- (C8) n-BO ₁ ; 2,4-hexanediol, 4-ethyl- (C8) n-BO ₁ ; 2,4-heptanediol, 2-methyl- (C8) n-BO ₁ ; 2,4-heptanediol, 3-methyl- (C8) n-BO ₁ ; 2,4-heptanediol, 4-methyl- (C8) n-BO ₁ ; 2,4-heptanediol, 5-methyl- (C8) n-BO ₁ ; 2,4-heptanediol, 6-methyl- (C8) n-BO ₁ ; 2,5-heptanediol, 2-methyl- (C8) n-BO ₁ ; 2,5-heptanediol, 3-methyl- (C8) n-BO ₁ ; 2,5-heptanediol, 4-methyl- (C8) n-BO ₁ ; 2,5-heptanediol, 5-methyl- (C8) n-BO ₁ ; 2,5-heptanediol, 6-methyl- (C8) n-BO ₁ ; 2,6-heptanediol, 2-methyl- (C8) n-BO ₁ ; 2,6-heptanediol, 3-methyl- (C8) n-BO ₁ ; 2,6-heptanediol, 4-methyl- (C8) n-BO ₁ ; 3,5-heptanediol, 2-methyl- (C8) n-BO ₁ ; 1,3-propanediol, 2- (1,2-dimethylpropyl)-(C8) _El-3 ; 1,3-butanediol, 2-ethyl-2,3-dimethyl- (C8) _El-1 ; 1,3-butanediol, 2-methyl-2-isopropyl- (C8) _El-3 ; 1,4-butanediol, 3-methyl-2-isopropyl- (C8) _El-1 ; 1,3-pentanediol, 2,2,3-trimethyl- (C8) El _-1 ; 1,3-pentanediol, 2,2,4-trimethyl- (C8) _El-1 ; 1,3-pentanediol, 2,4,4-trimethyl- (C8) El _-1 ; 1,3-pentanediol, 3,4,4-trimethyl- (C8) El _-1 ; 1,4-pentanediol, 2,2,3-trimethyl- (C8) El _-1 ; 1,4-pentanediol, 2,2,4-trimethyl- (C8) _El-1 ; 1,4-pentanediol, 2,3,3-trimethyl- (C8) El _-1 ; 1,4-pentanediol, 2,3,4-trimethyl- (C8) _El-1 ; 1,4-pentanediol, 3,3,4-trimethyl (C8) E _1-3 ; 2,4-pentanediol, 2,3,4-trimethyl- (C8) E _1-3 ; 2,4-hexanediol, 4-ethyl- (C8) _El-1 ; 2,4-heptanediol, 2-methyl- (C8) _El-1 ; 2,4-heptanediol, 3-methyl- (C8) _El-1 ; 2,4-heptanediol, 4-methyl- (C8) _El-1 ; 2,4-heptanediol, 5-methyl- (C8) _El-1 ; 2,4-heptanediol, 6-methyl- (C8) _El-1 ; 2,5-heptanediol, 2-methyl- (C8) _El-1 ; 2,5-heptanediol, 3-methyl- (C8) _El-1 ; 2,5-heptanediol, 4-methyl- (C8) _El-1 ; 2,5-heptanediol, 5-methyl- (C8) _El-1 ; 2,5-heptanediol, 6-methyl- (C8) _El-1 ; 2,6-heptanediol, 2-methyl- (C8) _El-3 ; 2,6-heptanediol, 3-methyl- (C8) _El-1 ; 2,6-heptanediol, 4-methyl- (C8) _El-1 ; And / or 3,5-heptanediol, 2-methyl- (C8) _El-1 ; And

7. mixtures thereof;

Iii. Aromatic diols comprising:

1-phenyl-1,2-ethanediol; 1-phenyl-1,2-propanediol; 2-phenyl-1,2-propanediol; 3-phenyl-1,2-propanediol; 1- (3-methylphenyl) -1,3-propanediol; 1- (4-methylphenyl) -1,3-propanediol; 2-methyl-1-phenyl-1,3-propanediol; 1-phenyl-1,3-butanediol; 3-phenyl-1,3-butanediol; 1-phenyl-1,4-butanediol; 2-phenyl-1,4-butanediol; And / or 1-phenyl-2,3-butanediol; And

Iii. One or more CH ₂ groups are bonded, and for each bonded CH ₂ group, two hydrogen atoms are removed from adjacent carbon atoms in the molecule to form one carbon-carbon double bond, thereby maintaining a constant number of hydrogen atoms in the molecule A main solvent comprising the following homologs or analogs of the above structure:

1,3-propanediol, 2,2-di-2-propenyl-; 1,3-propanediol, 2- (1-pentenyl)-; 1,3 propanediol, 2- (2-methyl-2-propenyl) -2- (2-propenyl)-; 1,3-propanediol, 2- (3-methyl1-butenyl)-; 1,3-propanediol, 2- (4-pentenyl)-; 1,3-propanediol, 2-ethyl-2- (2-methyl-2-propenyl)-; 1,3-propanediol, 2-ethyl-2- (2-propenyl)-; 1,3-propanediol, 2-methyl-2- (3-methyl-3-butenyl)-; 1,3-butanediol, 2,2-diallyl-; 1,3-butanediol, 2- (1-ethyl-1-propenyl)-; 1,3-butanediol, 2- (2-butenyl) -2-methyl-; 1,3-butanediol, 2- (3-methyl-2-butenyl)-; 1,3-butanediol, 2-ethyl-2- (2-propenyl)-; 1,3-butanediol, 2-methyl-2- (1-methyl-2-propenyl)-; 1,4-butanediol, 2,3-bis (1-methylethylidene)-; 1,4-butanediol, 2- (3-methyl-2-butenyl) -3-methylene-; 2-butene-1,4-diol, 2- (1,1-dimethylpropyl)-; 2-butene-1,4-diol, 2- (1-methylpropyl)-; 2-butene-1,4-diol, 2-butyl-; 1,3-pentanediol, 2-ethenyl-3-ethyl-; 1,3-pentanediol, 2-ethenyl-4,4-dimethyl-; 1,4-pentanediol, 3-methyl-2- (2-propenyl)-; 1,5-pentanediol, 2- (1-propenyl)-; 1,5-pentanediol, 2- (2-propenyl)-; 1,5-pentanediol, 2-ethylidene-3-methyl-; 1,5-pentanediol, 2-propylidene-; 2,4-pentanediol, 3-ethylidene-2,4-dimethyl-; 4-pentene-1,3-diol, 2- (1,1-dimethylethyl)-; 4-pentene-1,3-diol, 2-ethyl-2,3-dimethyl-; 1,4-hexanediol, 4-ethyl-2-methylene-; 1,5-hexadiene-3,4-diol, 2,3,5-trimethyl-; 1,5-hexadiene-3,4-diol, 5-ethyl-3-methyl-; 1,5-hexanediol, 2- (1-methylethenyl)-; 1,6-hexanediol, 2-ethenyl-; 1-hexene-3,4-diol, 5,5-dimethyl-; 1-hexene-3,4-diol, 5,5-dimethyl-; 2-hexene-1,5-diol, 4-ethenyl-2,5-dimethyl-; 3-hexene-1,6-diol, 2-ethenyl-2,5-dimethyl-; 3-hexene-1,6-diol, 2-allyl-; 3-hexene-1,6-diol, 3,4-dimethyl-; 4-hexene-2,3-diol, 2,5-dimethyl-; 4-hexene-2,3-diol, 3,4-dimethyl-; 5-hexene-1,3-diol, 3- (2-propenyl)-; 5-hexene-2,3-diol, 2,3-dimethyl-; 5-hexene-2,3-diol, 3,4-dimethyl-; 5-hexene-2,3-diol, 3,5-dimethyl-; 5-hexene-2,4-diol 3-ethenyl-2,5-dimethyl-; 1,4-heptanediol, 6-methyl-5-methylene-; 1,5-heptadiene-3,4-diol, 2,3-dimethyl-; 1,5-heptadiene-3,4-diol, 2,5-dimethyl-; 1,5-heptadiene-3,4-diol, 3,5-dimethyl-; 1,7-heptanediol, 2,6-bis (methylene)-; 1,7-heptanediol, 4-methylene-; 1-heptene-3,5-diol, 2,4-dimethyl-; 1-heptene-3,5-diol, 2,6-dimethyl-; 1-heptene-3,5-diol, 3-ethenyl-5-methyl, 1-heptene-3,5-diol, 6,6-dimethyl-; 2,4-heptadiene-2,6-diol, 4,6-dimethyl-; 2,5-heptadiene-1,7-diol, 4,4-dimethyl-; 2,6-heptadiene-1,4-diol, 2,5,5-trimethyl-; 2-heptene-1,4-diol, 5,6-dimethyl-; 2-heptene-1,5-diol, 5-ethyl-; 2-heptene-1,7-diol, 2-methyl-; 3-heptene-1,5-diol, 4,6-dimethyl-; 3-hepten-1,7-diol, 3-methyl-6-methylene-; 3-heptene-2,5-diol, 2,4-dimethyl-; 3-heptene-2,5-diol, 2,5-dimethyl-; 3-heptene-2,6-diol, 2,6-dimethyl-; 3-heptene-2,6-diol, 4,6-dimethyl-; 5-heptene-1,3-diol, 2,4-dimethyl-; 5-heptene-1,3-diol, 3,6-dimethyl-; 5-heptene-1,4-diol, 2,6-dimethyl-; 5-heptene-1,4-diol, 3,6-dimethyl-; 5-heptene-2,4-diol, 2,3-dimethyl-; 6-heptene-1,3-diol, 2,2-dimethyl-; 6-heptene-1,4-diol, 4- (2-propenyl)-; 6-heptene-1,4-diol, 5,6-dimethyl-; 6-heptene-1,5-diol, 2,4-dimethyl-; 6-heptene-1,5-diol, 2-ethylidene-6-methyl-; 6-heptene-2,4-diol, 4- (2-propenyl)-; 6-heptene-2,4-diol, 5,5-dimethyl-; 6-heptene-2,5-diol, 4,6-dimethyl-; 6-heptene-2,5-diol, 5-ethenyl-4-methyl-; 1,3-octanediol, 2-methylene-; 1,6-octadiene-3,5-diol, 2,6-dimethyl-; 1,6-octadiene-3,5-diol, 3,7-dimethyl-; 1,7-octadiene-3,6-diol, 2,6-dimethyl-; 1,7-octadiene-3,6-diol, 2,7-dimethyl-; 1,7-octadiene-3,6-diol, 3,6-dimethyl-; 1-octene-3,6-diol, 3-ethenyl-; 2,4,6-octatriene-1,8-diol, 2,7-dimethyl-; 2,4-octadiene-1,7-diol, 3,7-dimethyl-; 2,5-octadiene-1,7-diol, 2,6-dimethyl-; 2,5-octadiene-1,7-diol, 3,7-dimethyl-; 2,6-octadiene-1,4-diol, 3,7-dimethyl- (rosiridol); 2,6-octadiene-l, 8-diol, 2-methyl-; 2,7-octadiene-1,4-diol, 3,7-dimethyl-; 2,7-octadiene-1,5-diol, 2,6-dimethyl-; 2,7-octadiene-1,6-diol, 2,6-dimethyl- (8-hydroxylinalolol); 2,7-octadiene-1,6-diol, 2,7-dimethyl-; 2-octene-1,4-diol; 2-octene-1,7-diol; 2-octene-1,7-diol; 2-methyl-6-methylene-; 3,5-octadiene-1,7-diol, 3,7-dimethyl-; 3,5-octadiene-2,7-diol, 2,7-dimethyl-; 3,5-octanediol, 4-methylene-; 3,7-octadiene-1,6-diol, 2,6-dimethyl-3,7-octadiene-2,5-diol, 2,7-dimethyl-; 3,7-octadiene-2,6-diol, 2,6-dimethyl-; 3-octene-1,5-diol, 4-methyl-; 3-octene-1,5-diol, 5-methyl-; 4,6-octadiene-1,3-diol, 2,2-dimethyl-; 4,7-octadiene-2,3-diol, 2,6-dimethyl-; 4,7-octadiene-2,6-diol, 2,6-dimethyl-; 4-octene-1,6-diol, 7-methyl-; 2,7-bis (methylene)-; 2-methylene-; 5,7-octadiene-1,4-diol, 2,7-dimethyl-; 5,7-octadiene-1,4-diol, 7-methyl-; 5-octene-1,3-diol; 6-octene-1,3-diol, 7-methyl-; 6-octene-1,4-diol, 7-methyl-; 6-octene-1,5-diol, 6-octene-1,5-diol, 7-methyl-; 6-octene-3,5-diol, 2-methyl-; 6-octene-3,5-diol, 4-methyl-; 7-octene-1,3-diol, 2-methyl-, 7-octene-1,3-diol, 4-methyl-; 7-octene-1,3-diol, 7-methyl-; 7-octene-1,5-diol; 7-octene-1,6-diol; 7-octene-1,6-diol, 5-methyl-; 7-octene-2,4-diol, 2-methyl-6-methylene-; 7-octene-2,5-diol, 7-methyl-; 7-octene-3,5-diol, 2-methyl-; 1-nonene-3,5-diol; 1-nonene-3,7-diol; 3-nonene-2,5-diol; 4,6-nonadiene-1,3-diol, 8-methyl-; 4-nonene-2,8-diol; 6,8-nonadiene-1,5-diol; 7-nonene-2,4-diol; 8-nonene-2,4-diol; 8-nonene-2,5-diol; 1,9-decadiene-3,8-diol, and / or 1,9-decadiene-4,6-diol; And

ⅩⅠ. Mixtures thereof;

C. Preferably, low molecular weight water soluble solvents such as ethanol, isopropanol, propylene glycol, 1,3-propanediol, propylene carbonate and the like, in an amount effective to improve transparency and incapable of forming a transparent composition by itself;

D. Preferably, an effective amount of water soluble calcium salt and / or magnesium salt, preferably chloride, to improve transparency; And

E. Balance with water.

Preferably, the fabric softener activator is one in which R is hydrogen or hydroxyalkyl, especially when Y is an amido group, the solvent is not a monool, in particular t-butanol, or 2-methyl-pentanediol.

Preferably, the composition herein is aqueous, translucent or transparent, preferably transparent, and the composition is about 3% to about 95%, preferably about 5% to about 80%, more preferably about 15 % To about 70%, even more preferably about 40% to about 60% water, about 3% to about 40%, preferably about 10% to about 35%, more preferably about 12% to about 25% Even more preferably from about 14% to about 20% of said main alcohol solvent B. The preferred product (composition) is not translucent or transparent without main solvent B. The amount of main solvent B required to prepare the translucent or transparent composition is preferably at least 50%, more preferably at least about 60%, even more preferably at least about 75% of the total organic solvent present.

The main solvent is required to be kept in the lowest amount in order to provide acceptable stability / transparency in the composition of the present invention. The presence of water exerts the important effect required on the main solvent in order to obtain the transparency of the composition. The higher the water content, the greater the amount of main solvent (relative to the amount of softener) is required to obtain product transparency. Conversely, the lower the water content, the less main solvent (relative to the amount of softener) is required. As such, in a small amount of water from about 5% to about 15%, the softener activator: main solvent weight ratio is preferably from about 55:45 to about 85:15, more preferably from about 60:40 to about 80: 20 is. In an amount of water from about 15% to about 70%, the weight ratio of softener active agent to main solvent is preferably from about 45:55 to about 70:30, more preferably from about 55:45 to about 70:30. However, in large amounts of water from about 70% to about 80%, the weight ratio of softener active agent to main solvent is preferably from about 30:70 to about 55:45, more preferably from about 35:65 to about 45: 55. The greater the amount of water, the higher the softener: main solvent ratio.

Some of the solvents are novel compounds and / or mixtures of compounds, as described below.

The pH of the composition should be about 1 to about 7, preferably about 1.5 to about 5, more preferably about 2 to about 3.5.

Detailed description of the invention

I. Fabric Softening Activator

The present invention is typically about 2 to about 80%, preferably about 13 to about 75%, more preferably about 17, of the fabric softener active agent selected from the compounds described below as essential components, based on the weight of the composition To about 70%, even more preferably about 19% to about 65%.

(A) Diester quaternary ammonium fabric softener activator compound (DEQA)

(1) The first type of DEQA preferably contains a compound of formula 1 as the main activator component:

[Formula 1]

Wherein each R substituent is H or a short chain C _1-6 , preferably C _1-3 alkyl or hydroxyalkyl group, for example methyl (most preferred), ethyl, propyl, hydroxyethyl and the like, benzyl Or mixtures thereof; Each m is 2 or 3; Each n is from 1 to about 4; Preferably it is 2, and each Y is -O- (O) C-,-(R) N- (O) C-, -C (O) -N (R)-or -C (O) -O -, Preferably -O (O) C-, and not -OC (O) O-; When Y is -O (O) -C- or-(R) N- (O) C-, the sum of the carbons in each R ¹ plus ¹ is C _6-22 , preferably C _14-20 And the sum of only one YR ¹ is about 12 or less, the sum of other YR ¹ is about 16 or more, and each R ¹ is a long chain C _8-22 (or C _7-21 ) hydrocarbyl, or substituted Hydrocarbyl substituents, preferably C _10-20 (or C _9-19 ) alkyl or alkenyl, most preferably C _12-18 (or C _11-17 ) alkyl or alkenyl, the sum of said carbons being R ¹ for C _16-18 is a straight-chain alkyl or alkenyl group and the iodine value of the parent fatty acid (hereinafter referred to as IV) of said R ¹ group is preferably from about 20 to about 140, more preferably about 50 To about 130 and most preferably from about 70 to about 115 (herein, the iodine value of the 'parent' fatty acid, or 'corresponding' fatty acid, includes the unsaturated groups present in fatty acids containing the same R ¹ groups as above). Means the level of unsaturation of the R ¹ group in the same amount).

The counterpart X ^(-) may be any softener-compatible anion, preferably an anion of a strong acid, for example chloride, bromide, methylsulfate, sulfate, nitrate and the like, more preferably chloride. . The anion may also less preferably have a double charge in which X ⁽⁻⁾ represents a 1/2 group.

Preferred biodegradable quaternary ammonium fabric softening compounds are derived from unsaturated and polyunsaturated fatty acids such as oleic acid, and / or partially hydrogenated fatty acids, and also from vegetable oils and / or partially hydrogenated vegetable oils, such as For example, it may contain-(O) CR ¹ derived from canola oil, safflower oil, peanut oil, sunflower oil, corn oil, soybean oil, tall oil, rice bran oil and the like. Non-limiting examples of DEQA prepared from preferred fatty acids have the following proper distribution:

Fat acyl

DEQA ¹ DEQA ² DEQA ³ DEQA ⁴ DEQA ⁵ C12 a very small amount a very small amount 0 0 0 C14 3 3 0 0 0 C16 4 4 5 5 5 C18 0 0 5 6 6 C14: 1 3 3 0 0 0 C16: 1 11 7 0 0 3 C18: 1 74 73 71 68 67 C18: 2 4 8 8 11 11 C18: 3 0 One One 2 2 C20: 1 0 0 2 2 2 C20 and above 0 0 2 0 0 Unknown 0 0 6 6 7 Sum 99 99 100 100 102 IV 86-90 88-95 99 100 95 Sheath / Trans (C18: 1) 20-30 20-30 4 5 5 TPU 4 9 10 13 13

Mixtures of fatty acids derived from different fatty acids and mixtures of DEQA can be used, which is preferred. Non-limiting examples of DEQAs that can be mixed to form the DEQAs of the present invention are as follows:

Fat acyl DEQA ¹⁰ DEQA ¹¹ C14 0 One C16 11 25 C18 4 20 C14: 1 0 0 C16: 1 One 0 C18: 1 27 45 C18: 2 50 6 C18: 3 7 0 Unknown 0 3 Sum 100 100 IV 125-138 56 Sheath / Trans (C18: 1) Impossible to obtain 7 TPU 57 6

DEQA ¹⁰ is made from soy fatty acids and DEQA ¹¹ is made from slightly hydrogenated resin fatty acids.

Alternatively, but preferably, the R ¹ group may comprise a branched chain, for example from isostearic acid, for at least a portion thereof. The sum of the active ingredients represented by branched chain groups, when present, is typically from about 1 to about 90%, preferably from about 10 to about 70%, more preferably from about 20 to about 50%.

Fat acyl DEQA ¹² DEQA ¹³ DEQA ¹⁴ Isomilistic acid - 1-2 - Myristic acid 7-11 0.5-1 - Isopalmitic acid 6-7 6-7 1-3 Palmitic acid 4-5 6-7 - Isostearic acid 70-76 80-82 60-66 Stearic acid - 2-3 8-10 Isooleic acid - - 13-17 Oleic acid - - 6-12 IV 3 2 7-12

DEQA ¹² to DEQA ¹⁴ are prepared from different isostearic acid commercially available.

More preferred DEQAs are those prepared as a single DEQA, from a mixture of all different fatty acids presented (total fatty acid mixture), rather than from a mixture of mixtures of each final DEQA made from different portions of the total fatty acid mixture.

At least a plurality of the fatty acyl groups, for example about 50 to about 100%, preferably about 55 to about 95%, more preferably about 60 to about 90%, are preferably unsaturated, and also polyunsaturated fatty acyl The sum of the active substance containing groups (TPU) is preferably from about 3 to about 30%, preferably from about 5 to about 25%, more preferably from about 10 to about 18%. The cis / trans ratio of the unsaturated fatty acyl groups is important and the ratio is from 1: 1 to about 50: 1, at least 1: 1, preferably at least 3: 1, and more preferably from about 4: 1 to about 20: 1 (herein, the 'percent of softener activator' containing a given R ¹ group is equal to the percentage of all R ¹ groups used to form all softener activators).

The unsaturated, preferably polyunsaturated, fatty acyl groups described above and below provide surprisingly effective softening and also provide good rewetability, good antistatic properties, and particularly excellent recoverability after freezing and thawing.

Highly unsaturated materials are also easy to prepare into concentrated premixes that maintain their low-viscosity, thus facilitating treatments such as injection, mixing and the like. Typically, only a small amount of solvent bound to the material, ie, by weight of the total softener / solvent mixture, is from about 5 to about 20%, preferably from about 8 to about 25%, more preferably from about 10 to about 20 The highly unsaturated substances containing% are also easy to prepare into the concentrated, stable compositions of the invention even at ambient temperatures. The ability to treat the activator material at low temperatures is particularly important for polyunsaturated groups because it minimizes degradation. Another protection against degradation can be provided when the compound and softener composition contain an effective antioxidant, chelating agent and / or reducing agent as described below.

In the present invention, each Y is -O- (O) C-,-(R) N- (O) C-, -C (O) -N (R)-or -C (O) -O-, preferably Preferably -O- (O) C-, m is 2 or 3, preferably 2, each n is 1 to 4, preferably 2, and each R substituent is H or C _1-6 alkyl , Preferably methyl, ethyl, propyl, benzyl groups and mixtures thereof, more preferably C _1-3 alkyl groups, and each R ¹ , or YR ¹ hydrophobic group is saturated, C _8-14 , preferably C _{12 -14} hydrocarbyl, or substituted hydrocarbyl substituent (IV is preferably about 10 or less, more preferably less than about 5), [the sum of the carbons in the hydrophobic group is R ¹ group, or Y is- Is the number of carbons in the YR ¹ group when O- (O) C- or-(R) N- (O) C-.], The counterion X ^- is the above formula (I) and / or Medium chain biodegradable quaternary ammonium fabric softening compound having formula (2), containing DEQA as a preferred component There. Preferably, X ⁻ does not include a phosphonium salt.

The saturated C _8-14 fatty acyl group may be a pure derivative or have a mixed chain length.

Suitable fatty acid sources of such fatty acyl groups are cocoic acid, lauric acid, caprylic acid and capric acid.

In the case of a C _12-14 (or C _11-13 ) hydrocarbyl group, the group is preferably saturated, for example the IV is preferably about 10 or less, more preferably about 5 or less.

It is to be understood that the substituents R and R ¹ may be optionally substituted with a plurality of groups such as alkoxyl or hydroxyl groups, and may be straight or branched, as long as the R ¹ groups remain essentially hydrophobic. Preferred compounds can be considered to be biodegradable diester variants of diresin dimethyl ammonium chloride (hereinafter referred to as 'DTDMAC') which is a widely used fabric softener.

Preferred long-chain DEQAs are N, N-di (acyl-oxyethyl) -N, which is a group derived from a high content of polyunsaturated fatty acids, ie fatty acids containing sufficient polyunsaturation, such as resin fatty acids and soy fatty acids. DEQA made from raw materials containing N-dimethyl ammonium chloride. Another preferred long chain DEQA is dioleyl (designated) DEQA, ie DEQA whose main component is N, N-di (oleoyl-oxyethyl) -N, N-dimethyl ammonium chloride. Preferred raw materials of fatty acids for the DEQA are those having vegetable oils, and / or partially hydrogenated vegetable oils, for example high content of unsaturated groups such as oleoyl groups. Particularly preferred heavy chain DEQAs are dicoyl DEQA (derived from coco palm fatty acids), ie N, N-di (coco-oil-oxyethyl) -N, N-dimethyl ammonium chloride (hereinafter referred to as DEQA ⁶ ), and N, N-di (lauroyl-oxyethyl) -N, N-dimethyl ammonium chloride.

Specifically, the diester used herein may include the monoester present. Preferably, at least about 80% of the DEQA is in the diester form, and from 0 to about 20% is the DEQA monoester of Formula 1 wherein m is 2 and one YR ¹ group is H or -C (O) OH have. Corresponding diamides and / or mixed ester-amides may comprise an activator in which one long chain hydrophobic group, for example one YR ′ group, is —N (R) H, or —C (O) OH. For softening, under non / low detergent transport laundry conditions, the proportion of monoesters should be as low as possible, preferably about 5%. However, under high, anionic detergent surfactant or detergent former transport conditions, some monoesters may be preferred. The total ratio of diesters to monoesters is from about 100: 1 to about 2: 1, preferably from about 50: 1 to about 5: 1, more preferably from about 13: 1 to about 8: 1. Under high detergent carryover conditions, the di / monoester ratio is preferably about 11: 1. The amount of monoester present can be adjusted in the preparation of DEQA.

The compounds used as materials for biodegradable quaternary ester-amine softening in the practice of the present invention can be prepared using standard reaction chemistry. In one synthesis of a variant of the diester of DTDMAC, the amine of formula RN (CH ₂ CH ₂ OH) ₂ (wherein R is for example alkyl) is substituted on two hydroxyl groups with the formula R ¹ C (O) Esterification with an acid chloride of Cl to form an amine (one R is H), which is a form of softener which can be made cation by acidification, or then quaternized with an alkyl halide of formula RX to give the desired reaction product ( Wherein R and R ¹ are as defined above). However, it will be appreciated by those skilled in the art that such reaction sequences broaden the choice of reagents to be prepared.

Another DEQA softener activator suitable for the preparation of the concentrated, transparent liquid fabric softener composition of the present invention has Formula 1 above, wherein one R group is a C _1-4 hydroxyalkyl group, preferably one R group is a hydroxyethyl group . An example of such hydroxyethyl ester activator is di (acyloxyethyl) (2-hydroxyethyl) methyl ammonium methyl sulphate (hereinafter referred to as DEQA ⁸ ), in which the acyl group is the same as that of DEQA ¹ .

(2) The second type of DEQA has the formula

[Formula 2]

Wherein Y, R, R ¹ and X ^(-) are as defined above.

Such compounds include the formula [CH ₃ ] ₃ N ⁽⁺⁾ [CH ₂ CH (CH ₂ O (O) CR ¹ ) O (O) CR ¹ ] Cl ⁽⁻⁾ , wherein each R is a methyl or ethyl group , Preferably R ¹ is in the range of C _15-19 ). There may be certain branching and substitutions within the alkyl or alkenyl chain. The anion X ⁽⁻⁾ in the molecule is the same as in DEQA of Chemical Formula 1. As used herein, when the diester is embodied, it may include the monoester present. The amount of the monoester that may be present is the same as in DEQA of Formula 1 above. An example of a preferred DEQA of Formula 2 above is an activator 'propyl' ester quaternary ammonium fabric softener activator having an acyl group having the same formula 1,2-di (acyloxy) -3-trimethylammonoprovane chloride as that of DEQA ⁵ , Hereafter illustrated as DEQA ⁹ .

U.S. Patent No. 4,137,180 to Naik et al. (January 30, 1979), which is incorporated herein by reference, discloses reagents of this type and conventional methods for their preparation.

In a preferred softener activator (formulas 1 and 2), each R ¹ is a hydrocarbyl group or a substituted hydrocarbyl group, preferably an alkyl, monounsaturated alkenyl and polyunsaturated alkenyl group, containing polyunsaturated alkenyl groups The softener activator is at least about 3%, preferably at least about 5%, more preferably at least about 10%, and even more preferably at least about 15% by weight of the total softener activator present; The activator preferably contains a mixture of R ¹ groups in particular in the individual molecule, and also optionally, but preferably, the saturated R ¹ group is for at least a part thereof, for example from isostearic acid. Wherein the total amount of active substance represented by the branched chain group is from about 1 to about 90%, preferably from about 10 to about 70%, more preferably from about 20 to about 50%. DEQA herein may contain a low content of fatty acids, which are formed from unreacted starting materials used to form DEQA and / or by-products of any partial decomposition (hydrolysis) of the softener activator in the final composition. Can be. The concentration of the free fatty acids is preferably low, preferably about 10% or less, and more preferably about 5% or less by weight of the fabric softener activator.

II. Main solvent system

The composition of the present invention, based on its weight, has a main solvent of about 40% or less, preferably about 10 to about 35%, more preferably about 12 to about 25%, and even more preferably about 14 to about Contains 20%. The main solvent is selected to minimize solvent odor impact in the composition and to provide low viscosity to the final composition. For example, isopropyl alcohol is not very effective and has a strong odor. n-propyl alcohol is more effective but also has a distinct odor. In addition, various butyl alcohols have odors, but can be used for effective transparency / stability, especially when used as part of the main solvent system to minimize their odors. The alcohol is also selected for optimal low temperature stability. That is, they are liquids having an acceptable low-viscosity, up to about 40 ° F. (about 4.4 ° C.), translucent, preferably transparent, and recoverable after storage at about 20 ° F. (about 6.7 ° C.) Can be formed.

Herein, the suitability of the main solvent for preparing a liquid, concentrated, preferably transparent, fabric softener composition with the required stability is surprisingly optional. Suitable solvents may be selected based on their octanol / water partition coefficient (P). The octanol / water partition coefficient of the main solvent is the ratio between the equilibrium concentrations in octanol and water. The partition coefficients of the main solvent components of the invention are conveniently given in their logarithm to the base 10, ie logP.

The logP of a number of components has been reported. For example, the Pomona 92 database available from Daylight Chemical Information Systems, Inc., Irvine, Calif., Contains many, with citations to early literature. However, the logP value is also most conveniently calculated by the 'CLOGP' program available from Daylight CIS. The program also presents experimental logP values, provided that the logP values are available in the Pomona92 database. The 'calculated logP' (ClogP) is a fragmentary approach by Hansh and Leo (A. Leo, in Comprehensive Medicinal Chemistry, Vol. 4, C. Hansch, PG Sammens, JB Taylor and CA Ramsden, Eds., p. 295, Pergamon Press, 1990). This fractional approach is based on the chemical structure of each component and takes into account the number and type of atoms, the degree of atomic bonding and chemical bonding. The most reliable and widely used ClogP values for evaluating the physicochemical properties are preferably used in place of the experimental logP values in selecting the main solvent component useful in the present invention. Other methods that can be used to calculate ClogP are described, for example, in J. Chem. Inf. Comput. Sci., 27, 21 (1987); fragmentary method of creepen; J. Chem. Inf. Comput. Sci., 29, 163 (1989); fragmentary method of Bisvanadan; And Eur. J. Med. Chem.-Chim. theor., 19, 71 (1984).

Here, the main solvent is selected from those having a ClogP of about 0.15 to about 0.64, preferably about 0.25 to about 0.62, and more preferably about 0.40 to about 0.60, preferably asymmetric, and preferably room temperature It has a melting point or freezing point that becomes liquid at or near room temperature. In addition, biodegradable solvents having low molecular weight are also desirable for some purposes. While highly asymmetric solvents are highly preferred, highly symmetric solvents having a center of symmetry, such as 1,7-heptanediol or 1,4-bis (hydroxymethyl) cyclohexane, have their ClogP values in the desired ranges. Even if used alone, it is not possible to provide an essentially transparent composition. The most suitable main solvent is a composition containing about 27% di (oleoyloxyethyl) dimethylammonium chloride, about 16-20% main solvent and about 4-6% ethanol which is transparent during storage at about 40 ° F. (about 4.4 ° C.). It can be selected by determining whether to remain in the state and recovered after freezing at about 0 ° F (about -18 ° C).

The most preferred main solvent is identified by the appearance of the freeze-dried dilution treatment composition used to treat the fabric. The diluent composition has a dispersion of fabric softeners that exhibits a good single layer appearance compared to conventional fabric softener compositions. As the appearance approaches a monolayer, the performance of the composition is improved. The composition provides very good fabric softening compared to similar compositions prepared in a conventional manner with the same fabric softener actives as above. The composition also provides improved perfume deposition, especially when adding perfume to the composition at or near room temperature, as compared to conventional fabric softening compositions.

Main solvents that can be used are listed below under various lists, for example aliphatic and / or aliphatic cyclic diols having a predetermined carbon atom; Monool; Derivatives of glycerin; Diol alkoxylates; And mixtures thereof. Preferred main solvents are shown in italics and the most preferred main solvents are shown in bold type. The reference number is the Chemical Abstracts Service Registry numbers (CAS No.) for the compounds having the above numbers. The novel compounds have a method as described below, which can be used to prepare the compounds. In addition, for comparison purposes, several main solvents which are not available are also shown below. However, the above usable main solvent can be used as a mixture with the usable main solvent. The main solvents that can be used can be used to prepare concentrated fabric softener compositions that meet the stability / transparency conditions set forth herein.

Multiple diol main solvents having the same formula as above may exist as multiple stereoisomers and / or optical isomers. Each isomer is typically a different CAS No. Is given. For example, different isomers of 4-methyl-2,3-hexanediol can be prepared by at least the following CAS No. Is given: 146452-51-9; 146452-50-8; 146452-49-5; 146452-48-4; 123807-34-1; 123807-33-0; 123807-32-9; And 123807-31-8.

In the list below, each formula is, for simplicity, only one CAS No. Roman only. This is for illustration only and is sufficient to carry out the present invention. This is also non-limiting. Therefore, no other CAS No. Isomers having and also mixtures thereof are also included. In addition, CAS No. When a molecule represents some specific isotope, such as deuterium, tritium, carbon-13, etc., substances containing naturally distributed isotopes are also included, and vice versa. .

Mono-ols CAS No. n-propanol 71-23-8 CAS No. 2-butanol 2-methyl-2-propanol 15892-23-675-65-0 Isomers available 2-methyl-1-propanol 78-83-1

C6 diols Isomers available CAS No. 2,3-butanediol, 2,3-dimethyl- 1,2-butanediol, 2,3-dimethyl- 1,2-butanediol, 3,3-dimethyl- 2,3-pentanediol, 2-methyl- 2,3 -Pentanediol, 3-methyl- 2,3-pentanediol, 4-methyl- 2,3-hexanediol 3,4-hexanediol 1,2 -butanediol, 2-ethyl- 1,2-pentanediol, 2- Methyl- 1,2-pentanediol, 3-methyl- 1,2-pentanediol, 4-methyl- 1,2-hexanediol 76-09-566553-15-959562-82-27795-80-463521-37-97795-79-1617-30-1922-17-866553-16-020667-05-4159623-53-772110-08-96920- 22-5 Unusable Isomers 1,3-propanediol, 2-ethyl-2-methyl-1,3-propanediol, 2-isopropyl-1,3-propanediol, 2-propyl-1,3-butanediol, 2,2-dimethyl- 1,3-butanediol, 2,3-dimethyl-1,3-butanediol, 2-ethyl-1,4-butanediol, 2,2-dimethyl-1,4-butanediol, 2,3-dimethyl-1,4- Butanediol, 2-ethyl-1,3-pentanediol, 2-methyl-1,3-pentanediol, 3-methyl-1,3-pentanediol, 4-methyl-1,4-pentanediol, 2-methyl- 1,4-pentanediol, 3-methyl-1,4-pentanediol, 4-methyl-1,5-pentanediol, 2-methyl-1,5-pentanediol, 3-methyl-2,4-pentanediol , 2-methyl-2,4-pentanediol, 3-methyl-1,3-hexanediol 1,4-hexanediol 1,5-hexanediol 1,6-hexanediol 2,4-hexanediol 2,5- Hexanediol

C7 diols Isomers available CAS No. 1,3-propanediol, 2-butyl-1,3-propanediol, 2,2-diethyl-1,3-propanediol, 2- (1-methylpropyl) -1,3-propanediol, 2- (2-methylpropyl) -1,3-propanediol, 2-methyl-2-propyl-1,2-butanediol, 2,3,3-trimethyl-1,4-butanediol, 2-ethyl-2-methyl- 1,4-butanediol, 2-ethyl-3-methyl-1,4-butanediol, 2-propyl-1,4-butanediol, 2-isopropyl-1,5-pentanediol, 2,2-dimethyl-1, 5-pentanediol, 2,3-dimethyl-1,5-pentanediol, 2,4-dimethyl-1,5-pentanediol, 3,3-dimethyl-2,3-pentanediol, 2,3-dimethyl- 2,3-pentanediol, 2,4-dimethyl-2,3-pentanediol, 3,4-dimethyl-2,3-pentanediol, 4,4-dimethyl-3,4-pentanediol, 2,3- Dimethyl-1,5-pentanediol, 2-ethyl-1,6-hexanediol, 2-methyl-1,6-hexanediol, 3-methyl-2,3-hexanediol, 2-methyl-2,3- Hexanediol, 3-methyl-2,3-hexanediol, 4-methyl-2,3-hexanediol, 5-methyl-3,4-hexanediol, 2-methyl-3,4-hexanediol, 3-methyl -1,3-heptanediol 1,4-heptanediol 1,5-heptanediol 1,6-heptanediol 2612-26-2115-76-433673-01-726462-20-878-26-2 Method B 76651-98-466225-34-162946-68-339497-66-O3121-82-281554-20-32121-69 -953120-74-46931-70-066225-53-437164-04-889851-45-6 Method B 14189-13-025258-92-84089-71-859215-55-3139093-40-6 *** Method B Method B 18938-47-123433-04-740646-07-960096-09-513175-27-4 Preferred Isomers 1,3-propanediol, 2-butyl- 1,4-butanediol, 2-propyl- 1,5-pentanediol, 2-ethyl- 2,3-pentanediol, 2,3-dimethyl- 2,3-pentanediol, 2.4-dimethyl- 2,3-pentanediol, 3,4-dimethyl- 2,3-pentanediol, 4,4-dimethyl- 3,4-pentanediol, 2,3-dimethyl- 1,6-hexanediol, 2-methyl- 1,6-hexanediol, 3-methyl- 1,3-heptanediol 1,4-heptanediol I, 5-heptanediol 1,6-heptanediol 2612-26-262946-68-314189-13-06931-70-066225-53-437164-04-889851-45-6 Method B 25258-92-84089-71-823433-04-740646-07-960096-09 -513175-27-4

More preferred isomers 2,3-pentanediol, 2,3-dimethyl- 6931-70-0 2,3-pentanediol, 2,4-dimethyl- 66225-53-4 2,3-pentanediol, 3,4-dimethyl- 37164 -04-8 2,3-pentanediol, 4,4-dimethyl- 89851-45-6 3,4-pentanediol, 2,3-dimethyl- Method B Unusable Isomers 1,3-propanediol, 2-methyl-2-isopropyl-1,2-butanediol, 2-ethyl-3-methyl-1,3-butanediol, 2,2,3-trimethyl-1,3-butanediol, 2-ethyl-2-methyl-1,3-butanediol, 2-ethyl-3-methyl-1,3-butanediol, 2-isopropyl-1,3-butanediol, 2-propyl-1,4-butanediol, 2 , 2,3-trimethyl-1,4-butanediol, 3-ethyl-1-methyl-1,2-pentanediol, 2,3-dimethyl-1,2-pentanediol, 2,4-dimethyl-1,2 -Pentanediol, 3,3-dimethyl-1,2-pentanediol, 3,4-dimethyl-1,2-pentanediol, 4,4-dimethyl-1,2-pentanediol, 2-ethyl-1,3 -Pentanediol, 2,2-dimethyl-1,3-pentanediol, 2,3-dimethyl-1,3-pentanediol, 2,4-dimethyl-1,3-pentanediol, 2-ethyl-1,3 -Pentanediol, 3,4-dimethyl-1,3-pentanediol, 4,4-dimethyl-1,4-pentanediol, 2,2-dimethyl-1,4-pentanediol, 2,3-dimethyl-1 , 4-pentanediol, 2,4-dimethyl-1,4-pentanediol, 3,3-dimethyl-1,4-pentanediol, 3,4-dimethyl-2,4-pentanediol, 2,3-dimethyl -2,4-pentanediol, 2,4-dimethyl-2,4-pentanediol, 3,3-dimethyl-1,2-hexanediol, 2-methyl-1,2-hexane Ol, 3-methyl-1,2-hexanediol, 4-methyl-1,2-hexanediol, 5-methyl-1,3-hexanediol, 2-methyl-1,3-hexanediol, 3-methyl- 1,3-hexanediol, 4-methyl-1,3-hexanediol, 5-methyl-1,4-hexanediol, 2-methyl-

1,4-hexanediol, 3-methyl-1,4-hexanediol, 4-methyl-1,4-hexanediol, 5-methyl-1,5-hexanediol, 2-methyl-1,5-hexanediol , 3-methyl-1,5-hexanediol, 4-methyl-1,5-hexanediol, 5-methyl-2,4-hexanediol, 2-methyl-2,4-hexanediol, 3-methyl-2 , 4-hexanediol, 4-methyl-2,4-hexanediol, 5-methyl-2,5-hexanediol, 2-methyl-2,5-hexanediol, 3-methyl-1,2-heptanediol 2 , 3-heptane diol 2,4-heptane diol 2,5-heptane diol 2,6-heptane diol 3,4-heptane diol 1,7-heptane diol 3,5-heptane diol *** 146452-51-9; 146452-50-8; 146452-49-5; 146452-48-4; 123807-34-1; 123807-33-0; 123807-32-9; 123807-31-8; Mixtures thereof.

Octanediol Isomers Propanediol derivatives Chemical Name CAS No. Isomers 1,3-propanediol, 2- (2-methylbutyl) -87194-40-91,3-propanediol, 2- (1,1 -dimethylpropyl) -method D 1,3-propanediol, 2- (1,2-dimethylpropyl) -method D 1,3-propanediol, 2- (1-ethylpropyl) -25462-28-61,3-propanediol, 2- (1-methylbutyl)-22131 -29-91,3-propanediol, 2- (2,2-dimethylpropyl)-Method D 1,3-propanediol, 2- (3-methylbutyl) -25462-27-51,3-propanediol, 2-butyl-2-methyl-3121-83-31,3-propanediol, 2-ethyl-2-isopropyl- 24765-55-71,3-propanediol, 2-ethyl-2-propyl-25450-88 -81,3-propanediol, 2-methyl-2- (1-methylpropyl)-813-60-51,3-propanediol, 2-methyl-2- (2-methylpropyl) -25462-42-41 , 3-propanediol, 2-t-butyl-2-methyl-25462-45-7 More preferred isomer l, 3-propanediol, 2- (1,1-dimethylpropyl) -method D , 3-propanediol, 2- (1,2-dimethylpropyl) -method D 1,3-propanediol, 2- (1-ethylpropyl) -25462-28-6 l, 3-propanediol, 2- (2,2-dimethylpropyl ) -method D l, 3-propanediol, 2-ethyl-2-isopropyl- 24765-55-7 l, 3-propanediol, 2-methyl-2- (1-methylpropyl) -813-60-5 l, 3-propanediol, 2-methyl-2- (2-methylpropyl)- 25462-42-4 l, 3-propanediol, 2-t-butyl-2-methyl- 25462-45-7 Unusable Isomers 1,3-propanediol, 2-pentyl-

Butanediol derivatives Isomers usable 1,3-butanediol, 2,2-diethyl- 99799-77-61,3-butanediol, 2- (1-methylpropyl) -method C 1,3-butanediol, 2-butyl- 83988-22 -11,3-butanediol, 2-ethyl-2,3-dimethyl- Method D 1,3-butanediol, 2- (1,1-dimethylethyl) -67271-58-31,3-butanediol, 2- (2 - methylpropyl) - method C 1,3- butanediol, 2-methyl-2-isopropyl-method C 1,3- butanediol, 2-methyl-2-propyl-99799-79-81,3- butanediol, 3 Methyl-2-isopropyl- method C 1,3-butanediol, 3-methyl-2-propyl- method D 1,4-butanediol, 2,2-diethyl- method H 1,4-butanediol, 2-diethyl -2-propyl- method H 1,4-butanediol, 2- (1-methylpropyl) -method H 1,4-butanediol, 2-ethyl-2,3-dimethyl- method F 1,4-butanediol, 2- Ethyl-3,3-dimethyl- method F 1,4-hexanediol, 2- (1,1-dimethylethyl)-36976-70-21,4-butanediol, 2- (2-methylpropyl) -method F 1 , 4-butanediol, 2-methyl-3-propyl- 90951-76-11,4-butanediol, 3-methyl-2-isopropyl- 99799-24-3 Preferred Isomers 1,3-butanediol, 2,2-diethyl- 99799-77-6 1,3-butanediol, 2- (1-methylpropyl) -method C 1,3-butanediol, 2-butyl- 83988-22 -1 1,3-butanediol, 2-ethyl-2,3-dimethyl- Method D 1,3-hexanediol, 2- (1,1-dimethylethyl) -67271-58-3 1,3-butanediol, 2 - (2-methylpropyl) - method C 1,3-butanediol, 2-methyl-2-isopropyl- method C 1,3-butanediol, 2-methyl-2-propyl-99799-79-8 1,3 Butanediol, 3-methyl-2-propyl- method D 1,4-butanediol, 2,2-diethyl- method H 1,4-butanediol, 2-ethyl-2,3-dimethyl- method F 1,4-butanediol , 2-ethyl-3,3-dimethyl- method F 1,4-butanediol, 2- (1,1-dimethylethyl) -36976-70-2 1,4-butanediol, 3-methyl-2-isopropyl- 99799-24-3

More Preferred Isomers l, 3-butanediol, 2- (l- methylpropyl) -method C l, 3-butanediol, 2- (2-methylpropyl) -method C l, 3-butanediol, 2-butyl- 83988-22 -L , 3-butanediol, 2-methyl-2-propyl 99799-79-8 l, 3-butanediol, 3-methyl-2-propyl- method D 1,4-butanediol, 2,2-diethyl- method H 1,4-butanediol, 2-ethyl-2,3-dimethyl- method F 1,4-butanediol, 2-ethyl-2,3-dimethyl- method F 1,4-butanediol, 2- (1,1- Dimethylethyl) -36976-70-2 Unusable isomers 1,4-butanediol, 2-butyl-1,2-butanediol, 2-ethyl-3,3-dimethyl-1,4-butanediol, 2-methyl-2-isopropyl-1,2-butanediol, 3-methyl-2-isopropyl-1,4-butanediol, 2,2,3,3-tetramethyl-

Trimethylpentanediol Isomer Isomers 1,3-pentanediol, 2,2,3-trimethyl- 35512-54-01,3-pentanediol, 2,2,4-trimethyl- 144-19-41,3-pentanediol, 2, 3,4-trimethyl-116614-13-21,3-pentanediol, 2,4,4-trimethyl-109387-36-21,3-pentanediol, 3,4,4-trimethyl- 81756-50-51, 4-pentanediol, 2,2,3-trimethyl- method H 1,4-pentanediol, 2,2,4-trimethyl- 80864-10-41,4-pentanediol, 2,3,3-trimethyl- method H 1,4-pentanediol, 2,3,4-trimethyl- 92340-74-41,4-pentanediol, 3,3,4-trimethyl-16466-35-61,5-pentanediol, 2,2, 3-trimethyl-method F1,5-pentanediol, 2,2,4-trimethyl-3465-14-31,5-pentanediol, 2,3,3-trimethyl- method A 1,5-pentanediol, 2, 3,4-trimethyl- 85373-83-72,4-pentanediol, 2,3,3-trimethyl- 24892-51-12,4-pentanediol, 2,3,4-trimethyl- 24892-52-2 Preferred Isomers 1,3-pentanediol, 2,2,3-trimethyl- 35512-54-0 1,3-pentanediol, 2,2,4-trimethyl- 144-19-4 1,3-pentanediol, 2 , 3,4-trimethyl- 116614-13-2 1,3-pentanediol, 2,4,4-trimethyl- 109387-36-2 1,3-pentanediol, 3,4,4-trimethyl- 81756-50 -5 1,4-pentanediol, 2,2,3-trimethyl- method H 1,4-pentanediol, 2,2,4-trimethyl- 80864-10-4 1,4-pentanediol, 2,3, 3-trimethyl- method F 1,4-pentanediol, 2,3.4-trimethyl- 92340-74-4 1,4-pentanediol, 3,3,4-trimethyl- 16466-35-6 1,5-pentanediol , 2,2,3-trimethyl- method A 1,5-pentanediol, 2,2,4-trimethyl- 3465-14-3 1,5-pentanediol, 2,3,3-trimethyl- method A 2, 4-pentanediol, 2,3,4-trimethyl- 24892-52-2 More preferred isomer 1,3-pentanediol, 2,3,4-trimethyl- 116614-13-2 1,4.pentanediol , 2,3,4-trimethyl- 92340-74-4 1,5-pentanediol, 2,2,3-trimethyl- method A 1,5- pentanediol, 2,2,4-trimethyl- 3465-14-3 1,5-pentadiol, 2,3,3-trimethyl- method A

Unusable isomers 1,2-pentanediol, 2,3,3-trimethyl-1,2-pentanediol, 2,3,4-trimethyl-1,2-pentanediol, 2,4,4-trimethyl-1, 2-pentanediol, 3,3,4-trimethyl-1,2-pentanediol, 3,4,4-trimethyl-2,3-pentanediol, 2,3,4-trimethyl-2,3-pentanediol, 2,4,4-trimethyl-2,3-pentanediol, 3,4,4-trimethyl-

Ethylmethylpentanediol isomer Isomers 1,3-pentanediol, 2-ethyl-2-methyl- method C 1,3-pentanediol, 2-ethyl-3-methyl- method D 1,3-pentanediol, 2-ethyl-4- Methyl-148904-97-61,3-pentanediol, 3-ethyl-2-methyl-55661-05-71,4-pentanediol, 2-ethyl-2-methyl- method H 1,4-pentanediol, 2 -Ethyl-3-methyl- method F 1,4-pentanediol, 2-ethyl-4-methyl- method G 1,4-pentanediol, 3-ethyl-2-methyl- method F 1,4-pentanediol, 3-ethyl-3-methyl- method F 1,5-pentanediol, 2-ethyl-2-methyl- method F 1.5-pentanediol, 2-ethyl-3-methyl- 54886-83-81.5-pentanediol, 2 -Ethyl-4-methyl- method F 1,5-pentanediol, 3-ethyl-3-methyl- 57740-12-22,4-pentanediol, 3-ethyl-2-methyl- method G More preferred isomer 1,3-pentanediol, 2-ethyl-2-methyl- method C 1,3-pentanediol, 2-ethyl-3-methyl- method D 1,3-pentanediol, 2-ethyl-4- Methyl- 148904-97-6 1,3-pentanediol, 3-ethyl-2-methyl- 55661-05-7 1,4-pentanediol, 2-ethyl-2-methyl- method H 1,4-pentanediol , 2-ethyl-3-methyl- method F 1,4-pentanediol, 2-ethyl-4-methyl- method G 1,5-pentanediol, 3-ethyl-3-methyl- 57740-12-2 2, 4-pentanediol, 3-ethyl-2-methyl- method G Unusable isomers 1,2-pentanediol, 2-ethyl-3-methyl-1,2-pentanediol, 2-ethyl-4-methyl-1,2-pentanediol, 3-ethyl-2-methyl-1, 2-pentanediol, 3-ethyl-3-methyl-1,2-pentanediol, 3-ethyl-4-methyl-1,3-pentanediol, 3-ethyl-4-methyl-1,4-pentanediol, 3-ethyl-4-methyl-1,5-pentanediol, 3-ethyl-2-methyl-2,3-pentanediol, 3-ethyl-2-methyl-2,3-pentanediol, 3-ethyl-4 -Methyl-2,4-pentanediol, 3-ethyl-3-methyl-

Propylpentanediol Isomers Isomers 1,3-pentanediol, 2-isopropyl- method D 1,3-pentanediol, 2-propyl- method C 1,4-pentanediol, 2-isopropyl- method H 1,4-pentanediol , 2-propyl- method H 1,4-pentanediol, 3-isopropyl- method H 1,5-pentanediol, 2-isopropyl- 90951-89-62,4-pentanediol, 3-propyl- method C More preferred isomers l, 3-pentanediol, 2-isopropyl- Method D l, 3-pentanediol, 2-propyl- Method C 1,4-pentanediol, 2-isopropyl- Method H 1,4-pentanediol, 2-propyl- Method H 1,4-pentanediol, 3-isopropyl- Method H 2,4-pentanediol, 3-propyl- Method C Unusable Isomers 1,2-pentanediol, 2-propyl-1,2-pentanediol, 2-isopropyl-1,4-pentanediol, 3-propyl-1,5-pentanediol, 2-propyl-2, 4-pentanediol, 3-isopropyl-

Dimethylhexanediol Isomer Isomers 1,3-hexanediol, 2,2-dimethyl- 22006-96-81,3-hexanediol, 2,3-dimethyl- method D 1,3-hexanediol, 2,4-dimethyl- 78122- 99-31,3-hexanediol, 2,5-dimethyl- method C 1,3-hexanediol, 3,4-dimethyl- method D 1,3-hexanediol, 3,5-dimethyl- method D 1,3 -Hexanediol, 4,4-dimethyl- method C 1,3-hexanediol, 4,5-dimethyl- method C 1,4-hexanediol, 2,2-dimethyl- method F 1,4-hexanediol, 2 , 3-dimethyl- method F 1,4-hexanediol, 2,4-dimethyl- method G 1,4-hexanediol, 2,5-dimethyl- 22417-60-31,4-hexanediol, 3,3- Dimethyl- method F 1,4-hexanediol, 3,4-dimethyl- method E 1,4-hexanediol, 3,5-dimethyl- method H 1,4-hexanediol, 4,5-dimethyl- method E 1 , 4-hexanediol, 5,5-dimethyl- 38624-38-31,5-hexanediol, 2,2-dimethyl- method A 1,5-hexanediol, 2,3-dimethyl- 62718-05-21, 5-hexanediol, 2,4-dimethyl- 73455-82-01,5-hexanediol, 2,5-dimethyl- 58510-28-41,5-hexanediol, 3,3-dimethyl- 41736-99-61 , 5-hexanediol, 3,4-dimethyl- method A 1,5-hexanediol, 3,5-dimethyl- method G 1,5-hexanediol, 4,5-dimethyl- method F 1,6-hexanediol, 2,2-dimethyl- 13622-91-81, 6-hexanediol, 2,3-dimethyl- method F 1,6-hexanediol, 2,4-dimethyl- method F 1,6-hexanediol, 2,5-dimethyl- 49623-11-21,6-hexane Diol, 3,3-dimethyl- method F 1,6-hexanediol, 3,4-dimethyl- 65363-45-32,4-hexanediol, 2,3-dimethyl- 26344-17-22,4-hexanediol , 2,4-dimethyl- 29649-22-72,4-hexanediol, 2,5-dimethyl- 3899-89-62,4-hexanediol, 3,3-dimethyl- 42412-51-12,4-hexane Diol, 3,4-dimethyl- 90951-83-02,4-hexanediol, 3,5-dimethyl-159300-34-22,4-hexanediol, 4,5-dimethyl- method D 2,4-hexanediol , 5,5-dimethyl-108505-10-82,5-hexanediol, 2,3-dimethyl- method G 2,5-hexanediol, 2,4-dimethyl- method G 2,5-hexanediol, 2, 5-dimethyl-110-03-22,5-hexanediol, 3,3-dimethyl- method H 2,5-hexanediol, 3,4-dimethyl- 99799-30-12,6-hexanediol, 3,3 -Dimethyl- method A

More preferred isomer 1,3-hexanediol, 2,2-dimethyl- 22006-96-8 l, 3-hexanediol, 2,3-dimethyl- method D 1,3-hexanediol, 2,4-dimethyl- 78122 -99-3 l, 3-hexanediol, 2,5-dimethyl- method C l, 3-hexanediol, 3,4-dimethyl- method D l, 3-hexanediol, 3,5-dimethyl- method D l , 3-hexanediol, 4,4-dimethyl- method C l, 3-hexanediol, 4,5-dimethyl- method C 1,4-hexanediol, 2,2-dimethyl- method H 1.4-hexanediol, 2 , 3-dimethyl- method F 1,4-hexanediol, 2,4-dimethyl- method G 1,4-hexanediol, 2,5-dimethyl- 22417-60-3 1,4-hexanediol, 3,3 -Dimethyl- method F 1,4-hexanediol, 3,4-dimethyl- method E 1,4-hexanediol, 3,5-dimethyl- method H 1,4-hexanediol, 4,5-dimethyl- method E 1,4-hexanediol, 5,5-dimethyl- 38624-38-3 1,5-hexanediol, 2,2-dimethyl- method A 1,5-hexanediol, 2,3-dimethyl- 62718-05- 2 1,5-hexanediol, 2,4-dimethyl- 73455-82-0 1,5-hexanediol, 2,5-dimethyl- 58510-28-4 1,5-hexanediol, 3,3-dimethyl- 41736-99-6 1,5-hexanediol, 3,4- Til - A method 1,5- hexanediol, 3,5-dimethyl- Method G 1,5- hexanediol, 4,5-dimethyl- Method F 2,6- hexanediol, 3,3-dimethyl- Method A

Unusable Isomers 1,2-hexanediol, 2,3-dimethyl-1,2-hexanediol, 2,4-dimethyl-1,2-hexanediol, 2,5-dimethyl-1,2-hexanediol, 3 , 3-dimethyl-1,2-hexanediol, 3,4-dimethyl-1,2-hexanediol, 3,5-dimethyl-1,2-hexanediol, 4,4-dimethyl-1,2-hexanediol , 4,5-dimethyl-1,2-hexanediol, 5,5-dimethyl-2,3-hexanediol, 2,3-dimethyl-2,3-hexanediol, 2,4-dimethyl-2,3- Hexanediol, 2,5-dimethyl-2,3-hexanediol, 3,4-dimethyl-2,3-hexanediol, 3,5-dimethyl-2,3-hexanediol, 4,4-dimethyl-2, 3-hexanediol, 4,5-dimethyl-2,3-hexanediol, 5,5-dimethyl-3,4-hexanediol, 2,2-dimethyl-3,4-hexanediol, 2,3-dimethyl- 3,4-hexanediol, 2,4-dimethyl-3,4-hexanediol, 2,5-dimethyl-3,4-hexanediol, 3,4-dimethyl-

Ethylhexanediol isomer More preferred isomer 1,3-hexanediol, 2-ethyl- 94-96-2 l, 3-hexanediol, 4-ethyl- method C 1,4-hexanediol, 2-ethyl- 148904-97-6 1, 4-hexanediol, 4-ethyl- 1113-00-4 1,5-hexanediol, 2-ethyl- 58374-34-8 2,4-hexanediol, 3-ethyl- method C 2,4-hexanediol, 4-ethyl- 33683-47-5 2,5-hexanediol, 3-ethyl- method F Unusable Isomers 1,5-hexanediol, 4-ethyl-1,6-hexanediol, 2-ethyl-1,4-hexanediol, 3-ethyl-1,5-hexanediol, 3-ethyl-1,6 -Hexanediol, 3-ethyl-1,2-hexanediol, 2-ethyl-1,2-hexanediol, 3-ethyl-1,2-hexanediol, 4-ethyl2,3-hexanediol, 3-ethyl -2,3-hexanediol, 4-ethyl-3,4-hexanediol, 3-ethyl-1,3-hexanediol, 3-ethyl-

Methylheptane Diol Isomer Isomers usable 1,3-heptanediol, 2-methyl-109417-38-11,3-heptanediol, 3-methyl-165326-88-51,3-heptanediol, 4-methyl- method C 1,3- Heptanediol, 5-methyl- method D 1,3-heptanediol, 6-methyl- method C 1,4-heptanediol, 2-methyl-15966-03-71,4-heptanediol, 3-methyl-7748- 38-11,4-heptanediol, 4-methyl- 72473-94-01,4-heptanediol, 5-methyl- 63003-04-31,4-heptanediol, 6-methyl- 99799-25-41,5 -Heptanediol, 2-methyl-141605-00-71,5-heptanediol, 3-methyl- method A 1,5-heptanediol, 4-methyl- method A 1,5-heptanediol, 5-methyl- 99799 -26-51,5-heptanediol, 6-methyl-57740-00-81,6-heptanediol, 2-methyl-132148-22-21,6-heptanediol, 3-methyl- method G 1,6- Heptanediol, 4-methyl-156307-84-51,6-heptanediol, 5-methyl- method A 1,6-heptanediol, 6-methyl-5392-57-42,4-heptanediol, 2-methyl- 38836-26-92,4-heptanediol, 3-methyl-6964-04-12,4-heptanediol, 4-methyl-165326-87-42,4-heptanediol, 5-methyl- method C 2,4 -Heptanediol, 6-methyl- 79356-95-92, 5-heptanediol, 2-methyl- 141605-02-92,5-heptanediol, 3-methyl- method G 2,5-heptanediol, 4-methyl-156407-38-42,5-heptanediol, 5-methyl-148843-72-52,5 -Heptanediol, 6-methyl- 51916-46-22,6-heptanediol, 2-methyl- 73304-48-02,6-heptanediol, 3-methyl- 29915-96-62, 6-heptanediol, 4 -Methyl- 106257-69-63,4-heptanediol, 3-methyl-18938-50-63,5-heptanediol, 2-methyl- method C 3,5-heptanediol, 3-methyl- 99799-27- 63,5-heptanediol, 4-methyl-156407-37-3

More preferred isomer l, 3-heptanediol, 2-methyl- 109417-38-1 l, 3-heptanediol, 3-methyl- 165326-88-5 l, 3-heptanediol, 4-methyl- method C l, 3-heptanediol, 5-methyl- method D 1,3-heptanediol, 6-methyl- method C 1,4-heptanediol, 2-methyl- 15966-03-7 1,4-heptanediol, 3-methyl - 7748-38-1 1,4-heptane-diol, 4-methyl- 72473-94-0 1,4-heptane-diol, 5-methyl- 63003-04-3 1,4-heptane-diol, 6-methyl-99 799 -25-4 1,5-heptanediol, 2-methyl- 141605-00-7 1,5-heptanediol, 3-methyl- method A 1,5-heptanediol, 4-methyl- method A 1,5- Heptanediol , 5-methyl- 99799-26-5 l, 5-heptanediol, 6-methyl- 57740-00-8 1,6-heptanediol, 2-methyl- 132148-22-2 1,6-heptanediol , 3-methyl- method G 1,6-heptanediol, 4-methyl- 156307-84-5 1,6-heptanediol, 5-methyl- method A 1,6-heptanediol, 6-methyl- 5392-57 -4 2,4-heptanediol, 2-methyl- 38836-26-9 2,4-heptanediol, 3-methyl- 6964-04-1 2,4-heptanediol, 4-methyl- 165326-87-4 2,4-heptane-diol, 5-methyl- method C 2,4-heptane-diol, 6-methyl- 79356-95-9 2,5 Tan-diol, 2-methyl- 141605-02-9 2,5-heptane-diol, 3-methyl- Method H 2,5-heptane-diol, 4-methyl- 156407-38-4 2,5-heptane-diol, 5- Methyl- 148843-72-5 2,5-heptanediol, 6-methyl- 51916-46-2 2,6-heptanediol, 2-methyl- 73304-48-0 2,6-heptanediol, 3-methyl- 29915-96-6 2,6-heptanediol, 4-methyl- 106257-69-6 3,4-heptanediol, 3-methyl- 18938-50-6 3,5-heptanediol, 2-methyl- method C 3,5-heptanediol, 4-methyl- 156407-37-3

Unusable Isomers 1,7-heptanediol, 2-methyl-1,7-heptanediol, 3-methyl-1,7-heptanediol, 4-methyl-2,3-heptanediol, 2-methyl-2,3 -Heptanediol, 3-methyl-2,3-heptanediol, 4-methyl-2,3-heptanediol, 5-methyl-2,3-heptanediol, 6-methyl-3,4-heptanediol, 2- Methyl-3,4-heptanediol, 4-methyl-3,4-heptanediol, 5-methyl-3,4-heptanediol, 6-methyl-1,2-heptanediol, 2-methyl-1,2- Heptanediol, 3-methyl-1,2-heptanediol, 4-methyl-1,2-heptanediol, 5-methyl-1,2-heptanediol, 6-methyl-

Octanediol Isomers More Preferred Isomers 2,4-octanediol 90162-24-6 2,5-octanediol 4527-78-0 2,6-octanediol Method A 2,7-octanediol 19686-96-5 3,5-octanediol 24892-55-5 3,6-octanediol 24434-09-1 Unusable Isomers 1,2-octanediol 1117-86-81,3-octanediol 23433-05-81,4-octanediol 51916-47-31,5-octanediol 2736-67-61,6-octanediol 4060 -76-61,7-octanediol 13175-32-11,8-octanediol 629-41-42,3-octanediol eg, 98464-24-53,4-octanediol eg, 99799-31-23,5 Octanediol eg, 129025-63-4

Nonanediol Isomers Chemical Name CAS No. Preferred Isomers 2,4-pentanediol, 2,3,3,4-tetramethyl- 19424-43-2 Isomers 2,4-pentanediol available, 3-t-butyl-142205-14-92,4-hexanediol, 2,5,5-trimethyl- 97460-08-72,4-hexanediol, 3,3, 4-trimethyl- method D 2,4-hexanediol, 3,3,5-trimethyl- 27122-58-32,4-hexanediol, 3,5,5-trimethyl- method D 2,4-hexanediol, 4 , 5,5-trimethyl- method D 2,5-hexanediol, 3,3,4-trimethyl- method H 2,5-hexanediol, 3,3,5-trimethyl- method G Unusable Isomers There are at least 500 unusable isomers including: 2,4-hexanediol, 2,4,5-trimethyl- 36587-81-22,4-hesandiol, 2,3,5-trimethyl Erythro-26344-20-72,4-hexanediol, 2,3,5-trimethyl-, threo-26343-49-71,3-propanediol, 2-butyl-2-ethyl-115-84-42 , 4-hexanediol, 2,3,5-trimethyl-, threo-26343-49-7

Alkyl glyceryl ethers, di (hydroxyalkyl) ethers, and aryl glyceryl ethers Preferred Monoglycerol Ethers and Derivatives 1,2-propanediol, 3- (butyloxy)-, triethoxylated 1,2-propanediol, 3- (butyloxy)-, tetraethoxylated More preferred mono-glycerol ethers, and derivatives CAS No. 1,2-propanediol, 3- (n-pentyloxy) -22636-32-4 1,2-propanediol, 3- (2-pentyloxy)-1,2- propanediol, 3- (3-pentyl Oxy) -1,2-propanediol, 3- (2-methyl-1-butyloxy)-1,2- propanediol, 3- (iso-amyloxy )-1,2- propanediol, 3- (3 -Methyl-2-butyloxy) 1,2-propanediol, 3- (cyclohexyloxy) 1,2-propanediol, 3- (1-cyclohex-1-enyloxy) -1,3 -propanediol , 2- (pentyloxy) -1,3 -propanediol, 2- (2-pentyloxy) -1,3 -propanediol, 2- (3-pentyloxy) -1,3 -propanediol, 2- ( 2-methyl-1-butyloxy) -1,3 -propanediol, 2- (iso-amyloxy) -1,3 -propanediol, 2- (3-methyl-2-butyloxy) -1,3- Propanediol, 2- (cyclohexyloxy) -1,3-propanediol, 2- (1-cyclohex-1-enyloxy) 1,2-propanediol, 3- (butyloxy)-, pentaethoxy Shisa 1,2-propanediol, 3- (butyloxy)-, hexaethoxylated 1,2-propanediol, 3- (butyloxy)-, hepethoxylated 1,2-propanediol, 3- (butyl oxy) -, octanoyl the Messenger ethoxylated 1,2 Ropan-diol, 3- (butyloxy) -, the Messenger ethoxylated 1,2-propanediol, 3- (butyloxy) na -, mono-propoxylated 1,2-propanediol, 3- (butyloxy) -, di Butyleneoxylated 1,2-propanediol, 3- (butyloxy)-, tributyleneoxylated More preferred di (hydroxyalkyl) ether Bis (2-hydroxybutyl) ether Bis (2-hydroxycyclopentyl) ether Unusable monoglycerol ether 1,2-propanediol, 3-ethyloxy-1,2-propanediol, 3-propyloxy-1,2-propanediol, 3-isopropyloxy-1,2-propanediol, 3 -Butyloxy-1,2-propanediol, 3-isobutyloxy-1,2-propanediol, 3-t-butyloxy-1,2-propanediol, 3-octyloxy-1,2-propanediol, 3- (2-ethylhexyloxy) -1,2-propanediol, 3- (cyclopentyloxy) -1,2-propanediol, 3- (1-cyclohex-2-enyloxy) -1,3 Propanediol, 2- (1-cyclohex-2-enyloxy)-

Aromatic glyceryl ethers 1,2-propanediol, 3-phenyloxy-1,2-propanediol, 3-benzyloxy-1,2-propanediol, 3- (2-phenylethyloxy) -1,2-propanediol, 3- (1-phenyl-2-propaneyloxy) -1,3-propanediol, 2-phenyloxy-1,3-propanediol, 2- (m-cresyloxy) -1,3-propanediol, 2- (p-cresyloxy) -1,3-propanediol, 2-benzyloxy-1,3-propanediol, 2- (2-phenylethyloxy) -1,3-propanediol, 2- (1-phenyl Ethyloxy)- Preferred Aromatic Glyceryl Ethers 1,2-propanediol, 3-phenyloxy- 1,2-propanediol, 3-benzyloxy- 1,2-propanediol, 3- (2-phenylethyloxy)- 1,3-propanediol, 2- (m-cresyloxy)- 1,3-propanediol, 2- (p-cresyloxy)- 1,3-propanediol, 2-benzyloxy- 1,3-propanediol, 2- (2-phenylethyloxy)- Preferred Aromatic Glyceryl Ethers 1,2-propanediol, 3-phenyloxy- 1,2-propanediol, 3-benzyloxy- 1,2-propanediol, 3- (2-phenylethyloxy)- l, 3-propanediol, 2- (m-cresyloxy)- 1,3-propanediol, 2- (p-cresyloxy)- 1,3-propanediol, 2- (2-phenylethyloxy)-

Aliphatic Cyclic Diols and Derivatives Chemical Name CAS No. Preferred Cyclic Diols and Derivatives 1-isopropyl-1,2-cyclobutanediol 59895-32-8 3-ethyl-4-methyl-1,2-cyclobutanediol 3-propyl-1,2-cyclobutanediol 3-isopropyl -1,2-cyclobutanediol 42113-90-6 1-ethyl-1,2-cyclopentanediol 67396-17-2 1,2-dimethyl-1,2-cyclopentanediol 33046-20-7 1,4- Dimethyl-1,2-cyclopentanediol 89794-56-9 2,4,5-trimethyl-1,3-cyclopentanediol 3,3-dimethyl-1,2-cyclopentanediol 89794-57-0 3,4 -Dimethyl-1,2-cyclopentanediol 70051-69-3 3,5-dimethyl-1,2-cyclopentanediol 89794-58-1 3-ethyl-1,2-cyclopentanediol 4,4-dimethyl- 1,2-cyclopentanediol 70197-54-5 4-ethyl-1,2-cyclopentanediol 1,1-bis (hydroxymethyl) cyclohexane 2658-60-8 1,2-bis (hydroxymethyl) Cyclohexane 76155-27-6 1,2-dimethyl-1,3-cyclohexanediol 53023-07-7 1,3-bis (hydroxymethyl) cyclohexane 13022-98-5 1,3-dimethyl-1, 3-cyclohexanediol 128749-93-9 1,6-dimethyl-1,3- cycle Hexane diol 164713-16-0 1-hydroxy-cyclohexane-ethanol 40894-17-5 l- hydroxy-cyclohexane methanol 15753-47-6 1-ethyl-1,3-cyclohexanediol 10601-18-0 1-methyl-1,2-cyclohexanediol 52718-65-7 2,2-dimethyl-1,3-cyclohexanediol 114693-83-3 2,3-dimethyl-1,4-cyclohexanediol 70156-82 -0 2,4-dimethyl-1,3-cyclohexanediol 2,5-dimethyl-1,3-cyclohexanediol 2,6-dimethyl-1,4-cyclohexanediol 34958-42-4 2-ethyl- 1,3-cyclohexanediol 155433-88-8 2-hydroxycyclohexaneethanol 24682-42-6 2-hydroxyethyl-1-cyclohexanol 2-hydroxymethylcyclohexanol 89794-52-5 3- Hydroxyethyl-1-cyclohexanol 3-hydroxycyclohexaneethanol 86576-87-6 3-hydroxymethylcyclohexanol 3-methyl -1,2-cyclohexanediol 23477-91-0 4,4-dimethyl -1,3-cyclohexanediol 14203-50-0 4,5-dimethyl-1,3-cyclohexanediol 4,6-dimethyl-1,3-cyclohexanediol 16066-66-3 4-ethyl-1 , 3-cyclocarboxylic diol 4-hydroxyethyl-1-cyclohexanol 4-hydroxymethylcyclohexanol 33893-85-5 4-methyl-1,2-cyclohexanediol 23832-27-1 5,5-dimethyl-1,3- Cyclohexanediol 51335-83-2

5-ethyl-1,3-cyclohexanediol 1,2-cycloheptanediol 108268-28-6 2-methyl-1,3-cycloheptanediol 101375-80-8 2-methyl-1,4-cycloheptanedol 4-methyl-1,3-cycloheptanediol 5-methyl-1,3-cycloheptanediol 5-methyl-1,4-cycloheptanediol 90201-00-6 6-methyl-1,4-cycloheptanediol 1 , 3-cyclooctanediol 101935-36-8 1,4-cyclooctanediol 73982-04-4 1,5-cyclooctanediol 23418-82-8 1,2-cyclohexanediol, diethoxylate 1,2- Cyclohexanediol, triethoxylate 1,2-cyclohexanediol, tetraethoxylate 1,2-cyclohexanediol, pentaethoxylate 1,2-cyclohexanediol, hexaethoxylate 1,2-cyclohexane Diol, heptaethoxylate 1,2-cyclohexanediol, octaethoxylate 1,2-cyclohexanediol, nonaethoxylate 1,2-cyclohexanediol, monopropoxylate 1,2-cyclohexanediol, monobutyl alkyleneoxy rate of 1,2-cyclohexanediol, di-butylene-oxyl-ray 1,2-cyclohexanediol, tri-butylene oxylate

Chemical Name CAS No. More preferred cyclic diols and derivatives 1-isopropyl-1,2-cyclobutanediol 59395-32-9 3-ethyl-4-methyl-1,2-cyclobutanediol 3-propyl-1,2-cyclobutanediol 3-iso Propyl-1,2-cyclobutanediol 42113-90-6 1-ethyl-l, 2-cyclopentanediol 67396-17-2 1,2-dimethyl-1,2-cyclopentanediol 33046-20-7 1,4 -Dimethyl-1,2-cyclopentanediol 89794-56-9 3,3-dimethyl-l, 2-cyclopentanediol 89794-57-0 3,4-dimethyl-1,2-cyclopentanediol 70051-69- 3 3,5-dimethyl-l, 2-cyclopentanediol 89794-58-1 3-ethyl-1,2-cyclopentanediol 4,4-dimethyl-1,2-cyclopentanediol 70197-54-5 4- Ethyl-1,2-cyclopentanediol 1,1-bis (hydroxymethyl) cyclohexane 2658-60-8 1,2-bis (hydroxymethyl) cyclohexane 76155-27-6 1,2-dimethyl-1 , 3-cyclohexanediol 53023-07-7 1,3-bis (hydroxymethyl) cyclohexane 13022-98-5 1-hydroxy-cyclohexanemethanol 15753-47-6 1-methyl-1,2-cyclo Hexanediol 52719-65-7 3-hydroxyme Butyl cyclohexanol, 3-methyl-1,2-cyclohexanediol 23477-91-0 4,4-dimethyl-1,3-cyclohexanediol 14203-50-0 4,5-dimethyl-1,3-cyclohexane diol 4,6-dimethyl -l, 3- cyclohexanediol 16066-66-3 4-ethyl -l, 3- cyclohexanediol 4-hydroxyethyl-1-cyclohexanol, 4-hydroxymethyl-cyclohexanol 33893 -85-5 4-methyl-1,2-cyclohexanediol 23832-27-1 1,2-cycloheptanedol 108268-28-6 1,2-cyclohexanediol, pentaethoxylate 1,2-cyclohexane Diol, hexaethoxylate 1,2-cyclohexanediol, heptaethoxylate 1,2-cyclohexanediol, octaethoxylate 1,2-cyclohexanediol, nonaethoxylate 1,2-cyclohexanediol, Monopropoxylate 1,2-cyclohexanediol, dibutyleneoxylate

Unsaturated aliphatic cyclic diols include the following known unsaturated aliphatic cyclic diols:

Unsaturated aliphatic cyclic diols usable Chemical Name CAS No. 1,2-cyclobutanediol, 1-ethenyl-2-ethyl- 58016-14-13-cyclobutene-1,2-diol, 1,2,3,4-tetramethyl- 90112-64-43-cyclobutene -1,2-diol, 3,4-diethyl-142543-60-03-cyclobutene-1,2-diol, 3- (l, l-dimethylethyl) -142543-56-43-cyclobutene-1 , 2-diol, 3-butyl-142543-55-31,2-cyclopentanediol, 1,2-dimethyl-4-methylene-103150-02-31,2-cyclopentanediol, 1-ethyl-3-methylene 90314-52-61,2-cyclopentanediol, 4- (1-propenyl) 128173-45-53-cyclopentene-1,2-diol, l-ethyl-3-methyl- 90314-43-51, 2-cyclohexanediol, 1-ethenyl-134134-16-01,2-cyclohexanediol, 1-methyl-3-methylene- 98204-78-51,2-cyclohexanediol, 1-methyl-4-methylene 133358-53-91,2-cyclohexanediol, 3-ethenyl-55310-51-51,2-cyclohexanediol, 4-ethenyl-85905-16-43-cyclohexene-1,2-diol, 2,6-dimethyl-81969-75-73-cyclohexene-1,2-diol, 6,6-dimethyl- 61875-93-24-cyclohexene-1,2-diol, 3,6-dimethyl-156808- 73-04 -Cyclohexene-1,2-diol, 4,5-dimethyl-154351-54-93-cyclooctene-1,2-diol 170211-27-54-cyclooctene-1,2-diol 124791-61-35- Cyclooctene-1,2-diol 117468-07-2 Unusable unsaturated cyclic diols 1,2-cyclopentanediol, 1- (1-methylethenyl) -61447-83-41,2-propanediol, 1-cyclopentyl-55383-20-51,3-cyclo Pentanediol, 2- (1-methylethylidene)-65651-46-91,3-propanediol, 2- (1-cyclopenten-1-yl)-77192-43-91,3-propanediol, 2 -(2-cyclopenten-1-yl) -25462-31-11,2-ethanediol, 1- (1-cyclohexen-1-yl) -151674-61-21,2-ethanediol, 1- ( 3-cyclohexen-1-yl) 64011-53-62-cyclohexene-1,4-diol, 5,5-dimethyl- 147274-55-34-cyclohexene-1,3-diol, 3,6-dimethyl 127716-90-91,3-cycloheptanedol, 2-methylene- 132292-67-25-cycloheptene-1,3-diol, 1-methyl- 160813-33-25-cycloheptene-1,3-diol , 5-methyl- 160813-32-12-cyclooctene-1,4-diol 37996-40-0

C ₃ C ₇ Diol alkoxylated derivatives

In the table below, 'EO' means polyethoxylate, ie,-(CH ₂ CH ₂ O) _n H and Me-E _n is methyl-capped polyethoxylate-(CH ₂ CH ₂ 0) _n CH ₃ , '2 (Me-En)' means the 2 Me-En group required, 'PO' means polypropoxylate,-(CH (CH ₃ ) CH ₂ 0) _n H 'BO' means polybutyleneoxy group, (CH (CH ₂ CH ₃ ) CH ₂ 0) _n H, and 'n-BO' means poly (n-butyleneoxy) or poly (tetramethylene) oxy group -(CH ₂ CH ₂ CH ₂ CH ₂ 0) _n means H. All of the indicated alkoxylated derivatives are available, with the preferred ones in bold and listed in the second line. The method for preparing the alkoxylated derivatives is not limited and typical synthetic methods are shown below.

Substrate ^(a) Description CAS No. EO 1 (Me-En) 2 (Me-En) PO n-BO BO (b) (c) (d) (e) (f) (g) 1,2-propanediol (C3) 57-55-6 1-4 3-4 4 1,2-propanediol, 2-methyl- (C4) 558-43-0 4-10 8-10 One 3 One 1,3-propanediol (C3) 504-63-2 6-8 8 5-6 6 1,3-propanediol, 2,3-diethyl- (C7) 115-76-4 1-7 4-7 One 1-2 2 1,3-propanediol, 2,2-dimethyl- (C5) 126-30-7 1-2 3-4 4 1,3-propanediol, 2- (1-methylpropyl)-(C7) 33673-01-7 1-7 4-7 One 1-2 2 1,3-propanediol, 2- (2-methylpropyl)-(C7) 26462-20-8 1-7 4-7 One 1-2 2 1,3-propanediol, 2-ethyl- (C5) 2612-29-5 6-10 9-10 One 3 1,3-propanediol, 2-ethyl-2-methyl- (C6) 77-84-9 1-6 3-6 2 One 1,3-propanediol, 2-isopropyl- (C6) 2612-27-3 1-6 3-6 2 One 1,3-propanediol, 2-methyl- (C4) 2163-42-0 2-5 4-5 4-5 5 2 1,3-propanediol, 2-methyl-2-isopropyl- (C7) 2109-23-1 2-9 6-9 One 1-3 2-3 1,3-propanediol, 2-methyl-2-propyl- (C7) 78-26-2 1-7 4-7 One 1-2 2 1,3-propanediol, 2-propyl- (C6) 2612-28-4 1-4 2 One (a) In the above and in Table 8 below, both the number of alkoxylated groups indicated are usable, with the usual ranges listed in the first line and the preferred ones in the bold form in the second line. . the average number of the ethoxylated derivatives (CH ₂ CH ₂ O) group (c) be the column are each one guided body methyl-average number of substituents of the cargo ethoxylates capped poly (CH ₂ CH ₂ O) groups (d) The number of rows in this column is the average number of (CH ₂ CH ₂ O) groups in the two 2 methyl-cap polyethoxylate substituents in each derivative. CH (CH ₃₎ the average number of CH ₂ 0) group. (f) be the column is the average number of polytetramethylene oxy Chemistry derivatives _{(CH 2 CH 2 CH 2 CH} 2 0) group. (g) the column The number is the average number of (CH (CH ₂ CH ₃ ) CH ₂ 0) groups in the polybutoxylated derivatives.

Substrate ^(a) Description CAS No. EO 1 (Me-En) 2 (Me-En) PO n-BO BO (b) (c) (d) (e) (f) (g) 1,2-butanediol (C4) 584-3-2 2-8 6-8 2-3 One 1,2-butanediol, 2,3-dimethyl- (C6) 66553-15-9 1-6 2-5 1-2 1 1,2-butanediol, 2-ethyl- (C6) 66553-16-0 1-3 One 1,2-butanediol, 2-methyl- (C5) 41051-72-3 1-2 One 1,2-butanediol, 2,2-dimethyl- (C6) 59562-82-2 1-6 2-5 1-2 1 1,2-butanediol, 3-methyl- (C5) 50468-22-9 1-2 One 1,3-butanediol (C4) 107-88-0 3-6 5-6 5 2 1,3-butanediol, 2,2,3-trimethyl- (C7) 16343-75-2 1-3 1-2 2 1,3-butanediol, 2,2-dimethyl- (C6) 76-35-7 3-8 6-8 3 1,3-butanediol, 2,3-dimethyl- (C6) 24893-35-4 3-8 6-8 3 1,3-butanediol, 2-ethyl- (C6) 66553--17-1 1-6 4-6 2-3 One 1,3-butanediol, 2-ethyl-2-methyl (C7) Method C One One 2-4 3 1,3-butanediol, 2-ethyl-2-methyl- (C7) 68799-03-1 One One 2-4 3 1,3-butanediol, 2-isopropyl- (C7) 66567-04-2 One One 2-4 3

Substrate ^(a) Base material CAS No. EO 1 (Me-En) 2 (Me-En) PO n-BO BO (b) (c) (d) (e) (f) (g) 1,2-pentanediol (C5) 5343-92-0 3-10 7-10 One 2-3 3 1,2-pentanediol, 2-methyl- (C6) 20667-05-4 1-3 One 1,2-pentanediol, 3-methyl- (C6) 159623-53-7 1-3 One 1,2-pentanediol, 4-methyl- (C6) 72110-08-8 1-3 One 1,3-pentanediol (C5) 3174-67-2 1-2 3-4 1,3-pentanediol, 2,2-dimethyl- (C7) 2157-31-5 One One 2-4 3 1,3-pentanediol, 2,3-dimethyl- (C7) 66225-52-3 One One 2-4 3 1,3-pentanediol, 2,4-dimethyl- (C7) 60712-38-1 One One 2-4 3 1,3-pentanediol, 2-ethyl- (C7) 29887-11-4 2-9 6-8 One 1-3 2-3 1,3-pentanediol, 2-methyl- (C6) 149-31-5 1-6 4-6 2-3 One 1,3-pentanediol, 3,4-dimethyl- (C7) 129851-50-9 One One 2-43 1,3-pentanediol, 3-methyl- (C6), 33879-72-0 1-6 4-6 2-3 One 1,3-pentanediol, 4,4-dimethyl- (C7) 30458-16-3 One One 2-4 3 1,3-pentanediol, 4-methyl- (C6) 54876-99-2 1-6 4-6 2-3 One 1,4-pentanediol (C5) 626-95-9 1-2 3-4 1,4-pentanediol, 2,2-dimethyl- (C7) Method F One One 2-4 3 1,4-pentanediol, 2,3-dimethyl- (C7) Method F One One 2-4 3 1,4-pentanediol, 2,4-dimethyl- (C7) Method F One One 2-4 3 1,4-pentanediol, 2-methyl- (C6) 6287-17-8 1-6 4-6 2-3 One 1,4-pentanediol, 3,3-dimethyl- (C7) 81887-62-9 One One 2-4 3 1,4-pentanediol, 3,4-dimethyl- (C7) 63521-36-8 One One 2-4 3 1,4-pentanediol, 3-methyl- (C6) 26787-63-3 1-6 4-6 2-3 One 1,4-pentanediol, 4-methyl- (C6) 1462-10-8 1-6 4-6 2-3 One

Substrate ^(a) Base material CAS No. EO 1 (Me-En) 2 (Me-En) PO n-BO BO (b) (c) (d) (e) (f) (g) 1,5-pentanediol (C5) 111-29-5 4-10 8-10 One 3 1,5-pentanediol, 2,2-dimethyl- (C7) 3121-82-2 1-7 4-7 One 1-2 2 1,5-pentanediol, 2,3-dimethyl- (C7) 81554-20-3 1-7 4-7 One 1-2 2 1,5-pentanediol, 2,4-dimethyl- (C7) 2121-69-9 1-7 4-7 One 1-2 2 1,5-pentanediol, 2-ethyl- (C7) 14189-13-0 1-5 2-5 1-2 2 1,5-pentanediol, 2-methyl- (C6) 42856-62-2 1-4 2 1,5-pentanediol, 3,3-dimethyl- (C7) 53120-74-4 1-7 4-7 One 1-2 2 1,5-pentanediol, 3-methyl- (C6) 4457-71-0 1-4 2 2,3-pentanediol (C5) 42027-23-6 1-3 2 2,3-pentanediol, 2-methyl- (C6) 7795-80-4 1-7 4-7 One 1-2 2 2,3-pentanediol, 3-methyl- (C6) 63521-37-9 1-7 4-7 One 1-2 2 2,3-pentanediol, 4-methyl- (C6) 7795-79-1 1-7 4-7 One 1-2 2 2,4-pentanediol (C5) 625-69-4 1-4 2-4 4 2,4-pentanediol, 2,3-dimethyl- (C7) 24893-39-8 1-4 2-4 2 2,4-pentanediol, 2,4-dimethyl- (C7) 24892-49-7 1-4 2-4 2 2,4-pentanediol, 2-methyl- (C6) 107-41-5 5-10 8-10 3 2,4-pentanediol, 3,3-methyl- (C7) 24892-50-0 1-4 2-4 2 2,4-pentanediol, 3-methyl- (C6) Method H 5-10 8-10 3 (a) In the above table, all of the indicated alkoxylated groups are usable, with the usual ranges listed in the first line and the preferred ones in bold form in the second line. the is the average number of (CH ₂ CH ₂ O) group derivative (c) be the column are each guided body one methyl - the average number of cargo substituents ethoxylates capped poly (CH ₂ CH ₂ O) groups (d The number of rows in this column is the average number of (CH ₂ CH ₂ O) groups in the two methyl-cap polyethoxylate substituents in each derivative. (E) The number of columns in the polypropoxylated derivatives (CH (CH ₃ ) CH ₂ is the average number of 0) group. (f) be the column is the average number of polytetramethylene oxy screen the _{(CH 2 CH 2 CH 2 CH} 2 0) of the derivative group. (g) be the column of poly-butoxy Is the average number of (CH (CH ₂ CH ₃ ) CH ₂ 0) groups in the synthesized derivative.

Substrate ^(a) Base material CAS No. EO 1 (Me-En) PO n-BO BO (b) (c) (e) (f) (g) 1,3-hexanediol (C6) 21531-91-9 1-5 2-5 2 One 1,3-hexanediol, 2-methyl- (C7) 66072-21-7 2-9 6-8 One 1-3 2-3 One 1,3-hexanediol, 3-methyl- (C7) Method D 2-9 6-8 One 1-3 2-3 1,3-hexanediol, 4-methyl- (C7) Method C 2-9 6-8 One 1-3 2-3 1,3-hexanediol, 5-methyl- (C7) 109863-14-1 2-9 6-8 One 1-3 2-3 1,4-hexanediol (C6) 16432-53-4 1-5 2-5 2 One 1,4-hexanediol, 2-methyl- (C7) Method F 2-9 6-8 One 1-3 2-3 1,4-hexanediol, 3-methyl- (C7) 66225-36-3 2-9 6-8 One 1-3 2-3 1,4-hexanediol, 4-methyl- (C7) 40646-08-0 2-9 6-8 One 1-3 2-3 1,4-hexanediol, 5-methyl- (C7) 38624-36-1 2-9 6-8 One 1-3 2-3 1,5-hexanediol (C6) 928-40-5 1-5 2-5 2 One 1,5-hexanediol, 2-methyl- (C7) Method F 2-9 6-8 One 1-3 2-3 1,5-hexanediol, 3-methyl- (C7) Method F 2-9 6-8 One 1-3 2-3 1,5-hexanediol, 4-methyl- (C7) 66225-37-4 2-9 6-8 One 1-3 2-3 1,5-hexanediol, 5-methyl- (C7) 1462-11-9 2-9 6-8 One 1-3 2-3 1,6-hexanediol (C6) 629-11-8 1-2 1-2 4 1,6-hexanediol, 2-methyl- (C7) 25258-92-8 1-5 2-5 1-2 1 1,6-hexanediol, 3-methyl- (C7) 4089-71-8 1-5 2-5 1-2 1 2,3-hexanediol (C6) 617-30-1 1-5 2-5 1-2 1

Substrate ^(a) Base material CAS No. EO 1 (Me-En) PO n-BO BO (b) (c) (e) (f) (g) 2,4-hexanediol (C6) 19780-90-6 3-8 5-8 3 2,4-hexanediol, 2-methyl- (C7) 66225-35-2 1-2 1-2 2,4-hexanediol, 3-methyl- (C7) 116530-79-1 1-2 1-2 2,4-hexanediol, 4-methyl- (C7) 38836-25-8 1-2 1-2 2,4-hexanediol, 5-methyl- (C7) 54877-00-8 1-2 1-2 2,5-hexanediol (C6) 2935-44-6 3-8 5-8 3 2,5-hexanediol, 2-methyl- (C7) 29044-06-2 1-2 1-2 2,5-hexanediol, 3-methyl- (C7) Method H 1-2 1-2 3,4-hexanediol (C6) 922-17-8 1-5 2-5 One (a) In the above table, all of the indicated alkoxylated groups are usable, with the usual ranges listed in the first line and the preferred ones in bold form in the second line. the is the average number of (CH ₂ CH ₂ O) group derivative (c) be the column are each guided body one methyl - the average number of cargo substituents ethoxylates capped poly (CH ₂ CH ₂ O) group (e The number of columns is the average number of (CH (CH ₃ ) CH ₂ 0) groups in the polypropoxylated derivative. (F) The number of columns is (CH ₂ CH ₂ CH ₂ CH in the polytetramethyleneoxylated derivative. ₂ 0) is the average number of groups. (G) The number of columns is the average number of (CH (CH ₂ CH ₃ ) CH ₂ 0) groups in the polybutoxylated derivative.

Substrate ^(a) Base material CAS No. EO 1 (Me-En) PO n-BO (b) (c) (e) (f) 1,3-heethanediol (C7) 23433-04-7 1-7 3-6 One 1-2 2 1,4-heptanediol (C7) 40646-07-9 1-7 3-6 One 1-2 2 1,5-heptanediol (C7) 60096-09-5 1-7 3-6 One 1-2 2 1,6-heptanediol (C7) 13175-27-4 1-7 3-6 One 1-2 2 1,7-hexanediol (C7) 629-30-1 1-2 One 2,4-heptanediol (C7) 20748-86-1 3-10 7-10 One 3 2,5-heptanediol (C7) 70444-25-6 3-10 7-10 One One 3 2,6-heptanediol (C7) 5969-12-0 3-10 7-10 One One 3 3,5-heptanediol (C7) 86632-40-8 3-10 7-10 One One 3 (a) In the above table, all of the indicated alkoxylated groups are usable, with the usual ranges listed in the first line and the preferred ones in bold form in the second line. the is the average number of (CH ₂ CH ₂ O) group derivative (c) be the column are each guided body 1-methyl-average number of cargo substituents ethoxylates capped poly (CH ₂ CH ₂ O) group (e). The number of columns is the average number of (CH (CH ₃ ) CH ₂ 0) groups in the polypropoxylated derivative. (F) The number of columns is (CH ₂ CH ₂ CH ₂ CH _{2 in the} polytetramethyleneoxylated derivatives. 0) The average number of groups.

Aromatic diols Chemical Name CAS No. Aromatic diols usable 1-phenyl-1,2-ethanediol 93-56-11-phenyl-1,2-propanediol 1855-09-02-phenyl-1,2-propanediol 87760-50-73-phenyl -1,2-propanediol 17131-14-51- (3-methylphenyl) -1,3-propanediol 51699-43-51- (4-methylphenyl) -1,3-propanediol 159266-06-52-methyl -1-phenyl-1,3-propanediol 139068-60-31-phenyl-1,3-butanediol 118100-60-03-phenyl-1,3-butanediol 68330-54-11-phenyl-1,4-butanediol 136173-88-12-phenyl-1,4-butanediol 95840-73-61-phenyl-2,3-butanediol 169437-68-7 Preferred Aromatic Diols 1-phenyl-1,2-ethanediol 93-56-1 1-phenyl-1,2-propanediol 1855-09-0 2-phenyl-1,2-propanediol 87760-50-7 3-phenyl-1,2-propanediol 17131-14-5 1- (3-methylphenyl) -1,3-propanediol 51699-43-5 1- (4-methylphenyl) -1,3-propanediol 159266-06-5 2-methyl-1-phenyl-1,3-propanediol 139068-60-3 1-phenyl-1,3-butanediol 118100-60-0 3-phenyl-1,3-butanediol 68330-54-1 1-phenyl-1,4-butanediol 136173-88-1 More preferred aromatic diols 1-phenyl-l, 2-propanediol 1855-09-0 2 -phenyl-1,2-propanediol 37760-50-7 3-phenyl-1,2-propanediol 17131-14-5 1- (3-methylphenyl) -1,3-propanediol 51699-43-5 1- (4 -methylphenyl) -1,3 -propanediol 159266-06-5 2-methyl-1-phenyl- 1,3- Propanediol 139068-60-3 3-phenyl-l, 3-butanediol 69330-54-1 1-phenyl-1,4-butanediol 136173-88-1 Unusable aromatic diols 1-phenyl-1,3-propanediol2-phenyl-1,3-propanediol1-phenyl-1,2-butanediol 154902-08-62-phenyl-1,2-butanediol 157008-55 -43-phenyl-1,2-butanediol 141505-72-84-phenyl-1,2-butanediol 143615-31-02-phenyl-1,3-butanediol 103941-94-24-phenyl-1,3-butanediol 81096 -91-52-phenyl-2,3-butanediol 138432-94-7

X. The total number of hydrogen atoms is increased by one or more additional CH ₂ groups, and the total number of hydrogen atoms is useful as the main solvent which is an analog or homologue of the above structure maintained by the same number by introducing a double bond, for example Known compounds of.

Examples of unsaturated compounds Unsaturated diols usable are 1,3-propanediol, 2,2-di-2-propenyl-55038-13-61,3-propanediol, 2- (1-pentenyl) -138436-18-71, 3-propanediol, 2- (2-methyl-2-propenyl) -2- (2-propenyl)-121887-76-11,3-propanediol, 2- (3-methyl-1-butenyl) 139436-17-61,3-propanediol, 2- (4-pentenyl)-73012-46-11,3-propanediol, 2-ethyl-2- (2-methyl-2-propenyl) -91367 -61-21,3-propanediol, 2-ethyl-2- (2-propenyl)-27606-26-41,3-propanediol, 2-methyl-2- (3-methyl-3-butenyl) 132130-95-11,3-butanediol, 2,2-diallyl-103985-49-51,3-butanediol, 2- (1-ethyl-1-propenyl)-116103-35-61,3-butanediol , 2- (2-butenyl) -2-methyl-92207-83-51,3-butanediol, 2- (3-methyl-2-butenyl) -98955-19-21,3-butanediol, 2-ethyl -2- (2-propenyl) -122761-93-71,3-butanediol, 2-methyl-2- (1-methyl-2-propenyl) -141585-58-21,4-butanediol, 2,3 -Bis (1-methylethylidene)-52127-63-61,4-butanediol, 2- (3-methyl -2-butenyl) -3-methylene-115895-78-82-butene-1,4-diol, 2- (l, 1-dimethylpropyl) -91154-01-72-butene-1,4-diol, 2- (1-methylpropyl) -91154-00-62-butene-1,4-diol, 2-butyl-153943-66-9

1,3-pentanediol, 2-ethenyl-3-ethyl-104683-37-61,3-pentanediol, 2-ethenyl-4,4-dimethyl-143447-08-91,4-pentanediol, 3 -Methyl-2- (2-propenyl)-139301-86-31,5-pentanediol, 2- (1-propenyl)-84143-44-21,5-pentanediol, 2- (2-propenyl )-134757-01-01,5-pentanediol, 2-ethylidene-3-methyl-42178-93-81,5-pentanediol, 2-propylidene- 58203-50-22,4-pentanediol, 3 -Ethylidene-2,4-dimethyl- 88610-19-94-pentene-1,3-diol, 2- (1,1-dimethylethyl) -109789-04-74-pentene-1,3-diol, 2 -Ethyl-2,3-dimethyl- 90676-97-41,4-hexanediol, 4-ethyl-2-methylene- 66950-87-61,5-hexadiene-3,4-diol, 2,3,5 -Trimethyl- 18984-03-71,5-hexadiene-3,4-diol, 5-ethyl-3-methyl- 18927-12-31,5-hexanediol, 2- (1-methylethenyl)-96802 -18-51,6-hexanediol, 2-ethenyl- 66747-31-71-hexene-3,4-diol, 5,5-dimethyl- 169736-29-21-hexene-3,4-diol, 5 , 5-dimethyl- 120191-04-02-hexene-1,5-diol, 4-ethenyl-2,5-dimethyl- 70101-76-73-hexene-1,6-diol, 2-ethenyl-2,5-dimethyl-112763-52-73-hexene-1,6-diol, 2-ethyl-84143-45-33-hexene -1,6-diol, 3,4-dimethyl- 125032-66-84-hexene-2,3-diol, 2,5-dimethyl-13295-61-94-hexene-2,3-diol, 3,4 -Dimethyl- 135367-17-85-hexene-1,3-diol, 3- (2-propenyl)-74693-24-65-hexene-2,3-diol, 2,3-dimethyl-154386-00- 25-hexene-2,3-diol, 3,4-dimethyl-135096-13-85-hexene-2,3-diol, 3,5-dimethyl- 134626-63-45-hexene-2,4-diol, 3-ethenyl-2,5-dimethyl-155751-24-91,4-heptanediol, 6-methyl-5-methylene-100590-29-21,5-heptadiene-3,4-diol, 2,3 -Dimethyl-18927-06-51,5-heptadiene-3,4-diol, 2,5-dimethyl-22607-16-51,5-heptadiene-3,4-diol, 3,5-dimethyl-18938 -51-71,7-heptanediol, 2,6-bis (methylene) -139618-24-91,7-heptanediol, 4-methylene-71370-08-61-heptene-3,5-diol, 2, 4-Dimethyl-155932-77-71-heptene-3,5-diol, 2,6-dimethyl-132157-35-81-heptene-3,5-diol, 3-in Carbonyl-5-methyl-heptene-3,5-61841-10-91- diol, 6,6-dimethyl- 109788-01-4

2,4-heptadiene-2,6-diol, 4,6-dimethyl- 102605-95-82,5-heptadiene-1,7-diol, 4,4-dimethyl- 162816-19-52,6- Heptadiene-1,4-diol, 2,5,5--trimethyl-115346-30-02-heptene-1,4-diol, 5,6-dimethyl-103867-76-12-heptene-1,5- Diol, 5-ethyl-104683-39-82-heptene-1,7-diol, 2-methyl- 74868-68-13-heptene-1,5-diol, 4,6-dimethyl-147028-45-33- Heptene-1,7-diol, 3-methyl-6-methylene-109750-55-23-heptene-2,5-diol, 2,4-dimethyl- 98955-40-93-heptene-2,5-diol, 2,5-dimethyl- 24459-23-23-heptene-2,6-diol, 2,6-dimethyl- 160524-66-33-heptene-2,6-diol, 4,6-dimethyl- 59502-66- 85-heptene-1,3-diol, 2,4-dimethyl-123363-69-95-heptene-1,3-diol, 3,6-dimethyl-96924-52-65-heptene-1,4-diol, 2,6-dimethyl- 106777-98-45-heptene-1,4-diol, 3,6-dimethyl-106777-99-55-heptene-2,4-diol, 2,3-dimethyl- 104651-56- 16-heptene-1,3-diol, 2,2-dimethyl- 140192-39-86-heptene-1,4-diol, 4- (2-propenyl) -1727-87-36-heptene-1,4 -Dior, 5, 6-Dimethyl-152344-16-66-heptene-1,5-diol, 2,4-dimethyl- 74231-27-96-heptene-1,5-diol, 2-ethylidene-6-methyl- 91139-73 -06-heptene-2,4-diol, 4- (2-propenyl) -101536-75-86-heptene-2,4-diol, 5,5-dimethyl-98753-77-66-heptene-2, 5-diol, 4,6-dimethyl-134876-94-16-heptene-2,5-diol, 5-ethenyl, 4-methyl- 65757-31-51,3-octanediol, 2-methylene- 108086- 78-81,6-octadiene-3,5-diol, 2,6-dimethyl- 91140-06-61,6-octadiene-3,5-diol, 3,7-dimethyl- 75654-19-21, 7-octadiene-3,6-diol, 2,6-dimethyl- 51276-33-61,7-octadiene-3,6-diol, 2,7-dimethyl-26947-10-41,7-octadiene -3,6-diol, 3,6-dimethyl- 31354-73-11-octene-3,6-diol, 3-ethenyl- 65757-34-82,4,6-octatriene-l, 8- Diol, 2,7-dimethyl-162648-63-72,4-octadiene-1,7-diol, 3,7-dimethyl- 136054-24-52,5-octadiene-1,7-diol, 2, 6-dimethyl- 91140-07-72,5-octadiene-1,7-diol, 3,7-dimethyl- 117935-59-82,6-octadiene-1,4-diol, 3,7-dime (Rosiridol) 101391-01-92,6-octadiene-1,8-diol, 2-methyl-149112-02-72,7-octadiene-1,4-diol, 3,7-dimethyl- 91140 -08-82,7-octadiene-1,5-diol, 2,6-dimethyl- 91140-09-92,7-octadiene-1,6-diol, 2,6-dimethyl- (8-hydroxy Silinalool) 103619-06-32,7-octadiene-1,6-diol, 2,7-dimethyl- 60250-14-8

2-octene-1,4-diol 40735-15-72-octene-1,7-diol 73842-95-22-octene-1,7-diol, 2-methyl-6-methylene-91140-16-83, 5-octadiene-1,7-diol, 3,7-dimethyl 62875-09-63,5-octadiene-2,7-diol, 2,7-dimethyl-7177-18-63,5-octanediol, 4-Methylene- 143233-15-23,7-octadiene-1,6-diol, 2,6-dimethyl-127446-29-13,7-octadiene-2,5-diol, 2,7-dimethyl- 171436-39-83,7-octadiene-2,6-diol, 2,6-dimethyl-150283-67-33-octene-1,5-diol, 4-methyl-147028-43-13-octene-1 , 5-diol, 5-methyl- 19764-77-34,6-octadiene-1,3-diol, 2,2-dimethyl- 39824-01-64,7-octadiene-2,3-diol, 2 , 6-dimethyl- 51117-38-54,7-octadiene-2,6-diol, 2,6-dimethyl-59076-71-04-octene-1,6-diol, 7-methyl-84538-24- 94-octene-1,8-diol, 2,7-bis (methylene) -109750-56-34-octene-1,8-diol, 2-methylene-109750-58-55,7-octadiene-1, 4-diol, 2,7-dimethyl- 105676-78-65,7-octadiene-1,4-diol, 7-methyl-105676-80-05-octene-1,3-di 130272-38-76-octene-1,3-diol, 7-methyl-110971-19-26-octene-1,4-diol, 7-methyl-152715-87-26-octene-1,5-diol, 145623-79-66-octene-1,5-diol, 7-methyl-116214-61-06-octene-3,5-diol, 2-methyl-65534-66-96-octene-3,5-diol, 4-Methyl-l56414-25-47-octene-1,3-diol, 2-methyl-155295-38-87-octene-1,3-diol, 4-methyl-142459-25-47-octene-1, 3-diol, 7-methyl-132130-96-27-octene-1,5-diol 7310-51-27-octene-1,6-diol 159099-43-17-octene-1,6-diol, 5- Methyl-144880-56-87-octene-2,4-diol, 2-methyl-6-methylene-72446-81-27-octene-2,5-diol, 7-methyl-152344-12-27-octene- 3,5-diol, 2-methyl-98753-85-61-nonene-3,5-diol 119554-56-21-nonene-3,7-diol 23966-97-93-nonene-2,5-diol 165746 -84-94,6-nonadiene-1,3-diol, 8-methyl-124099-52-14-nonene-2,8-diol 154600-80-3

6,8-nonadiene-1,5-diol 108586-O3-47-nonene-2,4-diol 30625-41-38-nonene-2,4-diol 119785-59-0B-nonene-2,5- Diol 132381-58-91,9-decadiene-3,8-diol 103984-04-91,9-decadiene-4,6-diol 138835-67-3 Preferred unsaturated diols 1,3-butanediol, 2, 2-diallyl-103985-49-51,3-butanediol, 2- (1-ethyl-1-propenyl)-116103-35-61,3-butanediol, 2- (2-butenyl) -2-methyl 92 207-83-51,3-butanediol, 2- (3-methyl-2-butenyl) -98955-19-21,3-butanediol, 2-ethyl-2- (2-propenyl) -122761-93 -71,3-butanediol, 2-methyl-2- (1-methyl-2-propenyl)-141585-58-21,4-butanediol, 2,3-bis (1-methylethylidene)-52127 63-61,3-pentanediol, 2-ethenyl-3-ethyl-104683-37-61,3-pentanediol, 2-ethenyl-4,4-dimethyl-143447-08-91,4-pentanediol , 3-methyl-2- (2-propenyl)-139301-86-34-pentene-1,3-diol, 2- (1,1-dimethylethyl) -109788-04-74-pentene-1,3 -Diol, 2-ethyl-2,3-dimethyl- 90676-97-41,4-hexanediol, 4-ethyl- 2-methylene- 66950-87-61,5-hexadiene-3,4-diol, 2,3,5-trimethyl- 18984-03-71,5-hexanediol, 2- (1-methylethenyl)- 96802-18-52-hexene-1,5-diol, 4-ethenyl-2,5-dimethyl- 70101-76-71,4-heptanediol, 6-methyl-5-methylene-100590-29-22, 4-heptadiene-2,6-diol, 4,6-dimethyl- 102605-95-82,6-heptadiene-1,4-diol, 2,5,5-trimethyl- 115346-30-02-heptene- 1,4-diol, 5,6-dimethyl-103867-76-13-heptene-1,5-diol, 4,6-dimethyl-147028-45-35-heptene-1,3-diol, 2,4- Dimethyl-123363-69-95-heptene-1,3-diol, 3,6-dimethyl-96924-52-65-heptene-1,4-diol, 2,6-dimethyl- 106777-98-45-heptene- 1,4-diol, 3,6-dimethyl- 106777-99-56-heptene-1,3-diol, 2,2-dimethyl- 140192-39-86-heptene-1,4-diol, 5,6- Dimethyl- 152344-16-66-heptene-1,5-diol, 2,4-dimethyl- 74231-27-96-heptene-1,5-diol, 2-ethylidene-6-methyl- 91139-73-06 -Heptene-2,4-diol, 4- (2-propenyl) -101536-75-8

1-octene-3,6-diol, 3-ethenyl- 65757-34-82,4,6-octatriene-1,8-diol, 2,7-dimethyl- 162648-63-72,5-octa Diene-1, 7-diol, 2,6-dimethyl-91140-O7-72,5-octadiene-1, 7-diol, 3,7-dimethyl- 117935-59-82,6-octadiene-1, 4-diol, 3,7-dimethyl- (rosiridol) 101391-01-92,6-octadiene-1,8-diol, 2-methyl-149112-02-72,7-octadiene-1,4- Diol, 3,7-dimethyl-91140-08-82,7-octadiene-], 5-diol, 2,6-dimethyl-91140-09-92,7-octadiene-1,6.diol, 2, 6.Dimethyl- (8-hydroxylinalol) 103619-06-32,7-octadiene-1,6-diol, 2,7-dimethyl- 60250-14-82-octene-1,7-diol, 2-Methyl-6-methylene-91140-l4-83,5-octadiene-2,7-diol, 2,7-dimethyl-7177-18-63,5-octanediol, 4-methylene-143233-15- 23,7-octadiene-1,6-diol, 2,6-dimethyl-127446-29-14-octene-1,8-diol, 2-methylene-109750-58-56-octene-3,5-diol , 2-methyl-65534-66-96-octene-3,5-diol, 4-methyl-156414-25-47-octene-2,4-diol, 2-methyl-6-methyl Lene- 72446-81-27-octene-2,5-diol, 7-methyl-152344-12-27-octene-3,5-diol, 2-methyl- 98753-85-61-nonene-3,5- Diol 119554-56-21-nonene-3,7-diol 23866-97-93-nonen-2,5-diol 165746-84-94-nonen-2,8-diol 154600-80-36,8-nonadiene -1,5-diol 108586-03-47-nonen-2,4-diol 30625-41-38-nonen-2,4-diol 119785-59-08-nonen-2,5-diol 132381-58-91 , 9-decadiene-3,8-diol 103984-04-91,9-decadiene-4,6-diol 138835-67-3

; And

ⅩⅠ. Its mixture

There is no C _1-2 mono-ol which provides the clear concentrated fabric softener composition of the present invention. Only one C ₃ mono-ol, n-propanol, although the boiling point (BP) is undesirably low (forms a transparent product, remains transparent at a temperature of about 4 ° C., or re-warms to room temperature) Acceptable performance). Of the C ₄ mono-ols, only 2-butanol and 2-methyl-2-propanol provide very good performance, but the 2-methyl-2-propanol has an undesirably low BP. Except for the unsaturated mono-ols described above and below, there is no C _5-6 mono-ol that provides a clear product.

Several main solvents having two hydroxyl groups in the formula are known to be suitable for use in preparing the liquid, concentrated, transparent fabric softener compositions according to the present invention. The suitability of each main solvent was surprisingly found to be very selective, depending on the number of carbon atoms, the isomeric arrangement of molecules having the same number of carbon atoms, the degree of unsaturation, and the like. Main solvents having similar solubility characteristics as the main solvents and at least some asymmetry will provide the same advantages as above. Suitable main solvents have a ClogP of about 0.15 to about 0.64, preferably about 0.25 to about 0.62, and more preferably about 0.40 to about 0.60.

For example, for a 1,2-alkanediol main solvent family having the formula HO-CH ₂ -CHOH- (CH ₂ ) _n -H, where n is 1 to 8, an effective of about 0.15 to about 0.64 Only 1,2-hexanediol (n = 4) having a ClogP value in the ClogP range of about 0.53 is a good main solvent and is included within the scope of the present invention, but is effective in others, for example in the range of 0.15 to 0.64 1,2-propanediol, 1,2-butanediol, 1,2-pentanediol, 1,2-octanediol, 1,2-decanediol with deviating ClogP values are not good main solvents. In addition, among the isomers of hexanediol, 1,2-hexanediol is a good main solvent, and 1,3-hexanediol, 1,4-hexanediol, 1, having a ClogP value outside the effective range of 0.15 to 0.64. 5-hexanediol, 1,6-hexanediol, 2,4-hexanediol and 2,5-hexanediol are not good main solvents. This is illustrated in Examples and Comparative Examples IA and IB (see below).

There is no C _3-5 diol present herein which provides a clear concentrated composition.

There are a number of C ₆ diols which are possible isomers, but only those given above are suitable for preparing transparent products, among which 1,2-butanediol, 2,3-dimethyl-; 1,2-butanediol, 3,3-dimethyl-; 2,3-pentanediol, 2-methyl-; 2,3-pentanediol, 3-methyl-; 2,3-pentanediol, 4-methyl-; 2,3-hexanediol; 3,4-hexanediol; 1,2-butanediol, 2-ethyl-; 1,2-pentanediol, 2-methyl-; 1,2-pentanediol, 3-methyl-; 1,2-pentanediol, 4-methyl-; And 1,2-hexanediol are preferable, 1,2-butanediol and 2-ethyl-; 1,2-pentanediol, 2-methyl-; 1,2-pentanediol, 3-methyl-; 1,2-pentanediol, 4-methyl-; And 1,2-hexanediol are most preferred.

While there are more possible C ₇ diol isomers, only those given above provide transparent products, among which 1,3-butanediol, 2-butyl-; 1,4-butanediol and 2-propyl-; 1,5-pentanediol, 2-ethyl-; 2,3-pentanediol and 2,3-dimethyl-; 2,3-pentanediol and 2,4-dimethyl-; 2,3-pentanediol, 4,4-dimethyl-; 3,4-pentanediol, 2,3-dimethyl-; 1,6-hexanediol, 2-methyl-; 1,6-hexanediol, 3-methyl-; 1,3-heptanediol; 1,4-heptanediol; 1,5-heptanediol; 1,6-heptane diol is preferable and 2,3-pentanediol and 2,3-dimethyl-; 2,3-pentanediol and 2,4-dimethyl-; 2,3-pentanediol, 3,4-dimethyl-; 2,3-pentanediol, 4,4-dimethyl-; And 3,4-pentanediol, 2,3-dimethyl- are particularly preferred.

Similarly, even more possible C ₈ diol isomers exist, but only those set forth above provide transparent products, among which 1,3-propanediol, 2- (1,1-dimethylpropyl)-; 1,3-propanediol, 2- (1,2-dimethylpropyl)-; 1,3-propanediol and 2- (1-ethylpropyl)-; 1,3-propanediol and 2- (2,2-dimethylpropyl)-; 1,3-propanediol and 2-ethyl-2-isopropyl-; 1,3-propanediol, 2-methyl-2- (1-methylpropyl)-; 1,3-propanediol, 2-methyl-2- (2-methylpropyl)-; 1,3-propanediol, 2-t-butyl-2-methyl-; 1,3-butanediol and 2,2-diethyl-; 1,3-butanediol and 2- (1-methylpropyl)-; 1,3-butanediol and 2-butyl-; 1,3-butanediol and 2-ethyl-2,3-dimethyl-; 1,3-butanediol and 2- (1,1-dimethylethyl)-; 1,3-butanediol and 2- (2-methylpropyl)-; 1,3-butanediol and 2-methyl-2-propyl-; 1,3-butanediol and 3-methyl-2-isopropyl-; 1,3-butanediol and 3-methyl-2-propyl-; 1,4-butanediol and 2,2-diethyl-; 1,4-butanediol and 2-ethyl-2,3-dimethyl-; 1,4-butanediol and 2-ethyl-3,3-dimethyl-; 1,4-butanediol and 2- (1,1-dimethylethyl)-; 1,4-butanediol and 3-methyl-2-isopropyl-; 1,3-pentanediol, 2,2,3-trimethyl-; 1,3-pentanediol, 2,2,4-trimethyl-; 1,3-pentanediol, 2,3,4-trimethyl-; 1,3-pentanediol, 2,4,4-trimethyl-; 1,3-pentanediol, 3,4,4-trimethyl-; 1,4-pentanediol, 2,2,3-trimethyl-; 1,4-pentanediol, 2,2,4-trimethyl-; 1,4-pentanediol, 2,3,3-trimethyl-; 1,4-pentanediol, 2,3,4-trimethyl-; 1,4-pentanediol, 3,3,4-trimethyl-; 1,5-pentanediol, 2,2,3-trimethyl-; 1,5-pentanediol, 2,2,4-trimethyl-; 1,5-pentanediol, 2,3,3-trimethyl-; 2,4-pentanediol, 2,3,4-trimethyl-; 1,3-pentanediol and 2-ethyl-2-methyl-; 1,3-pentanediol, 2-ethyl-3-methyl-; 1,3-pentanediol and 2-ethyl-4-methyl-; 1,3-pentanediol and 3-ethyl-2-methyl-; 1,4-pentanediol and 2-ethyl-2-methyl-; 1,4-pentanediol, 2-ethyl-3-methyl-; 1,4-pentanediol and 2-ethyl-4-methyl-; 1,5-pentanediol, 3-ethyl-3-methyl-; 2,4-pentanediol, 3-ethyl-2-methyl-; 1,3-pentanediol and 2-isopropyl-; 1,3-pentanediol, 2-propyl-; 1,4-pentanediol and 2-isopropyl-; 1,4-pentanediol, 2-propyl-; 1,4-pentanediol and 3-isopropyl-; 2,4-pentanediol, 3-propyl-; 1,3-hexanediol, 2,2-dimethyl-; 1,3-hexanediol, 2,3-dimethyl-; 1,3-hexanediol, 2,4-dimethyl-; 1,3-hexanediol, 2,5-dimethyl-; 1,3-hexanediol, 3,4-dimethyl-; 1,3-hexanediol, 3,5-dimethyl-; 1,3-hexanediol, 4,4-dimethyl-; 1,3-hexanediol, 4,5-dimethyl-; 1,4-hexanediol, 2,2-dimethyl-; 1,4-hexanediol, 2,3-dimethyl-; 1,4-hexanediol and 2,4-dimethyl-; 1,4-hexanediol, 2,5-dimethyl-; 1,4-hexanediol, 3,3-dimethyl-; 1,4-hexanediol, 3,4-dimethyl-; 1,4-hexanediol, 3,5-dimethyl-; 1,4-hexanediol, 4,5-dimethyl-; 1,4-hexanediol, 5,5-dimethyl-; 1,5-hexanediol, 2,2-dimethyl-; 1,5-hexanediol, 2,3-dimethyl-; 1,5-hexanediol, 2,4-dimethyl-; 1,5-hexanediol, 2,5-dimethyl-; 1,5-hexanediol, 3,3-dimethyl-; 1,5-hexanediol, 3,4-dimethyl-; 1,5-hexanediol, 3,5-dimethyl-; 1,5-hexanediol, 4,5-dimethyl-; 2,6-hexanediol, 3,3-dimethyl-; 1,3-hexanediol, 2-ethyl-; 1,3-hexanediol, 4-ethyl-; 1,4-hexanediol, 2-ethyl-; 1,4-hexanediol, 4-ethyl-; 1,5-hexanediol, 2-ethyl-; 2,4-hexanediol, 3-ethyl-; 2,4-hexanediol, 4-ethyl-; 2,5-hexanediol, 3-ethyl-; 1,3-heptanediol, 2-methyl-; 1,3-heptanediol, 3-methyl-; 1,3-heptanediol, 4-methyl-; 1,3-heptanediol, 5-methyl-; 1,3-heptanediol, 6-methyl-; 1,4-heptanediol, 2-methyl-; 1,4-heptanediol, 3-methyl-; 1,4-heptanediol, 4-methyl-; 1,4-heptanediol, 5-methyl-; 1,4-heptanediol, 6-methyl-; 1,5-heptanediol, 2-methyl-; 1,5-heptanediol, 3-methyl-; 1,5-heptanediol, 4-methyl-; 1,5-heptanediol, 5-methyl-; 1,5-heptanediol, 6-methyl-; 1,6-heptanediol, 2-methyl-; 1,6-heptanediol, 3-methyl-; 1,6-heptanediol, 4-methyl-; 1,6-heptanediol, 5-methyl-; 1,6-heptanediol, 6-methyl-; 2,4-heptanediol, 2-methyl-; 2,4-heptanediol, 3-methyl-; 2,4-heptanediol, 4-methyl-; 2,4-heptanediol, 5-methyl-; 2,4-heptanediol, 6-methyl-; 2,5-heptanediol, 2-methyl-; 2,5-heptanediol, 3-methyl-; 2,5-heptanediol, 4-methyl-; 2,5-heptanediol, 5-methyl-; 2,5-heptanediol, 6-methyl-; 2,6-heptanediol, 2-methyl-; 2,6-heptanediol, 3-methyl-; 2,6-heptanediol, 4-methyl-; 3,4-heptanediol, 3-methyl-; 3,5-heptanediol, 2-methyl-; 3,5-heptanediol, 4-methyl-; 2,4-octanediol; 2,5-octanediol; 2,6-octanediol; 2,7-octanediol; 3,5-octanediol; And / or 3,6-octanediol is preferable, and double, 1,3-propanediol, 2- (1,1-dimethylpropyl)-; 1,3-propanediol, 2- (1,2-dimethylpropyl)-; 1,3-propanediol and 2- (1-ethylpropyl)-; 1,3-propanediol and 2- (2,2-dimethylpropyl)-; 1,3-propanediol and 2-ethyl-2-isopropyl-; 1,3-propanediol, 2-methyl-2- (1-methylpropyl)-; 1,3-propanediol, 2-methyl-2- (2-methylpropyl)-; 1,3-propanediol, 2-t-butyl-2-methyl-; 1,3-butanediol and 2- (1-methylpropyl)-; 1,3-butanediol and 2- (2-methylpropyl)-; 1,3-butanediol and 2-butyl-; 1,3-butanediol and 2-methyl-2-propyl-; 1,3-butanediol and 3-methyl-2-propyl-; 1,4-butanediol and 2,2-diethyl-; 1,4-butanediol and 2-ethyl-2,3-dimethyl-; 1,4-butanediol and 2-ethyl-3,3-dimethyl-; 1,4-butanediol and 2- (1,1-dimethylethyl)-; 1,3-pentanediol, 2,3,4-trimethyl-; 1,5-pentanediol, 2,2,3-trimethyl-; 1,5-pentanediol, 2,2,4-trimethyl-; 1,5-pentanediol, 2,3,3-trimethyl-; 1,3-pentanediol and 2-ethyl-2-methyl-; 1,3-pentanediol, 2-ethyl-3-methyl-; 1,3-pentanediol and 2-ethyl-4-methyl-; 1,3-pentanediol and 3-ethyl-2-methyl-; 1,4-pentanediol and 2-ethyl-2-methyl-; 1,4-pentanediol, 2-ethyl-3-methyl-; 1,4-pentanediol and 2-ethyl-4-methyl-; 1,5-pentanediol, 3-ethyl-3-methyl-; 2,4-pentanediol, 3-ethyl-2-methyl-; 1,3-pentanediol and 2-isopropyl-; 1,3-pentanediol, 2-propyl-; 1,4-pentanediol and 2-isopropyl-; 1,4-pentanediol, 2-propyl-; 1,4-pentanediol and 3-isopropyl-; 2,4-pentanediol, 3-propyl-; 1,3-hexanediol, 2,2-dimethyl-; 1,3-hexanediol, 2,3-dimethyl-; 1,3-hexanediol, 2,4-dimethyl-; 1,3-hexanediol, 2,5-dimethyl-; 1,3-hexanediol, 3,4-dimethyl-; 1,3-hexanediol, 3,5-dimethyl-; 1,3-hexanediol, 4,4-dimethyl-; 1,3-hexanediol, 4,5-dimethyl-; 1,4-hexanediol, 2,2-dimethyl-; 1,4-hexanediol, 2,3-dimethyl-; 1,4-hexanediol and 2,4-dimethyl-; 1,4-hexanediol, 2,5-dimethyl-; 1,4-hexanediol, 3,3-dimethyl-; 1,4-hexanediol, 3,4-dimethyl-; 1,4-hexanediol, 3,5-dimethyl-; 1,4-hexanediol, 4,5-dimethyl-; 1,4-hexanediol, 5,5-dimethyl-; 1,5-hexanediol, 2,2-dimethyl-; 1,5-hexanediol, 2,3-dimethyl-; 1,5-hexanediol, 2,4-dimethyl-; 1,5-hexanediol, 2,5-dimethyl-; 1,5-hexanediol, 3,3-dimethyl-; 1,5-hexanediol, 3,4-dimethyl-; 1,5-hexanediol, 3,5-dimethyl-; 1,5-hexanediol, 4,5-dimethyl-; 2,6-hexanediol, 3,3-dimethyl-; 1,3-hexanediol, 2-ethyl-; 1,3-hexanediol, 4-ethyl-; 1,4-hexanediol, 2-ethyl-; 1,4-hexanediol, 4-ethyl-; 1,5-hexanediol, 2-ethyl-; 2,4-hexanediol, 3-ethyl-; 2,4-hexanediol, 4-ethyl-; 2,5-hexanediol, 3-ethyl-; 1,3-heptanediol, 2-methyl-; 1,3-heptanediol, 3-methyl-; 1,3-heptanediol, 4-methyl-; 1,3-heptanediol, 5-methyl-; 1,3-heptanediol, 6-methyl-; 1,4-heptanediol, 2-methyl-; 1,4-heptanediol, 3-methyl-; 1,4-heptanediol, 4-methyl-; 1,4-heptanediol, 5-methyl-; 1,4-heptanediol, 6-methyl-; 1,5-heptanediol, 2-methyl-; 1,5-heptanediol, 3-methyl-; 1,5-heptanediol, 4-methyl-; 1,5-heptanediol, 5-methyl-; 1,5-heptanediol, 6-methyl-; 1,6-heptanediol, 2-methyl-; 1,6-heptanediol, 3-methyl-; 1,6-heptanediol, 4-methyl-; 1,6-heptanediol, 5-methyl-; 1,6-heptanediol, 6-methyl-; 2,4-heptanediol, 2-methyl-; 2,4-heptanediol, 3-methyl-; 2,4-heptanediol, 4-methyl-; 2,4-heptanediol, 5-methyl-; 2,4-heptanediol, 6-methyl-; 2,5-heptanediol, 2-methyl-; 2,5-heptanediol, 3-methyl-; 2,5-heptanediol, 4-methyl-; 2,5-heptanediol, 5-methyl-; 2,5-heptanediol, 6-methyl-; 2,6-heptanediol, 2-methyl-; 2,6-heptanediol, 3-methyl-; 2,6-heptanediol, 4-methyl-; 3,4-heptanediol, 3-methyl-; 3,5-heptanediol, 2-methyl-; 3,5-heptanediol, 4-methyl-; 2,4-octanediol; 2,5-octanediol; 2,6-octanediol; 2,7-octanediol; 3,5-octanediol; And / or 3,6-octanediol is most preferred.

Preferred mixtures of C ₈ -1,3-diol are mixtures of butyraldehyde, isobutyraldehyde and / or methyl ethyl ketone (2-butanone) as long as two or more of the reactants are present in the reaction mixture. , Condensation in the presence of a highly alkaline catalyst and then converted by hydrogenation to a mixture of C ₈ -1,3-diols, for example 2,2,4-trimethyl-1,3-pentanediol; 2-ethyl-1,3-hexanediol; 2,2-dimethyl-1,3-hexanediol; 2-ethyl-4-methyl-1,3-pentanediol; 2-ethyl-3-methyl-1,3-pentanediol; 3,5-octanediol; A mixture of C ₈ -1,3-diol consisting mainly of 2,2-dimethyl-2,4-hexanediol, 2-methyl-3,5-heptanediol and / or 3-methyl-3,5-heptanediol And 2,2,4-trimethyl-1,3-pentanediol, whereby the concentration of the 2,2,4-trimethyl-1,3-pentanediol is possibly calculated from condensation of the methylene group of 2-butanone (if present) instead of the methyl group With other very few isomers of which are less than one half of any mixture.

Formulations of some of the undesirable C _6-8 diols, as set forth in Tables 2 to 4 above, and other properties such as odor, flow, lowering of melting point, etc., can be improved by polyalkoxylation. Also preferred are some C _3-5 diols that are alkoxylated. Preferred alkoxylated derivatives of the C _3-8 diols include compounds of the following 1 to 7 [In the following, 'EO' is polyethoxylate, and 'E _n ' is (CH ₂ CH ₂ O) _n H , 'Me-E _n ' is methyl capped polyethoxylate-(CH ₂ CH ₂ O) _n CH ₃ , '2 (Me-E _n )' is the required 2 Me-E _n group, 'PO' Is polypropoxylate- (CH (CH ₃ ) CH ₂ O) _n H, 'BO' is a polybutyleneoxy group (CH (CH ₂ CH ₃ ) CH ₂ O) _n H, and 'n-BO' is Poly (n-butyleneoxy) group-(CH ₂ CH ₂ CH ₂ CH ₂ O) _n H]:

1. 1,2-propanediol (C3) 2 (Me-E _3-4 ); 1,2-propanediol (C3) P0 ₄ ; 1,2-propanediol, 2-methyl- (C4) (Me-E _8-10 ); 1,2-propanediol, 2-methyl- (C4) 2 (Me-E ₁ ); 1,2-propanediol 2-methyl- (C4) PO ₃ ; 1,3-propanediol (C3) 2 (Me-E ₈ ); 1,3-propanediol (C3) PO ₆ ; 1,3-propanediol, 2,2-diethyl- (C7) E _4-7 ; 1,3-propanediol, 2,2-diethyl- (C7) PO ₁ ; 1,3-propanediol, 2,2-diethyl- (C7) n-BO ₂ ; 1,3-propanediol, 2,2-dimethyl- (C5) 2 (Me E _1-2 ); 1,3-propanediol, 2,2-dimethyl- (C5) PO ₄ ; 1,3-propanediol, 2- (1-methylpropyl)-(C7) E _4-7 ; 1,3-propanediol, 2- (1-methylpropyl)-(C7) PO ₁ ; 1,3-propanediol, 2- (1-methylpropyl)-(C7) n-BO ₂ ; 1,3-propanediol, 2- (2-methylpropyl)-(C7) E _4-7 ; 1,3-propanediol, 2- (2-methylpropyl)-(C7) PO ₁ ; 1,3-propanediol, 2- (2-methylpropyl) (C7) n-BO ₂ ; 1,3-propanediol, 2-ethyl- (C5) (Me E _9-10 ); 1,3-propanediol, 2-ethyl (C5) 2 (Me E ₁ ); 1,3-propanediol, 2-ethyl- (C5) PO ₃ ; 1,3-propanediol, 2-ethyl-2-methyl- (C6) (Me E _3-6 ); 1,3-propanediol, 2-ethyl-2-methyl- (C6) PO ₂ ; 1,3-propanediol, 2-ethyl-2-methyl- (C6) BO ₁ ; 1,3-propanediol, 2-isopropyl- (C6) (Me E _3-6 ); 1,3-propanediol, 2-isopropyl- (C6) PO ₂ ; 1,3-propanediol, 2-isopropyl- (C6) BO ₁ ; 1,3-propanediol, 2-methyl- (C4) 2 (Me E _4-5 ); 1,3-propanediol, 2-methyl- (C4) PO ₅ ; 1,3-propanediol, 2-methyl- (C4) BO ₂ ; 1,3-propanediol, 2-methyl-2-isopropyl- (C7) E _6-9 ; 1,3-propanediol, 2-methyl-2-isopropyl- (C7) PO ₁ ; 1,3-propanediol, 2-methyl-2-isopropyl- (C7) n-BO _2-3 ; 1,3-propanediol, 2-methyl-2-propyl- (C7) E _4-7 ; 1,3-propanediol, 2-methyl-2-propyl- (C7) PO ₁ ; 1,3-propanediol, 2-methyl-2-propyl- (C7) n-BO ₂ ; 1,3-propanediol, 2-propyl- (C6) (Me E _1-4 ); 1,3-propanediol, 2-propyl- (C6) PO ₂ ;

2. 1,2-butanediol (C4) (Me E _6-8 ); 1,2-butanediol (C4) PO _2-3 ; 1,2-butanediol (C4) BO ₁ ; 1,2-butanediol, 2,3-dimethyl- (C6) E _2-5 ; 1,2-butanediol, 2,3-dimethyl- (C6) n-BO ₁ ; 1,2-butanediol, 2-ethyl- (C6) E _1-3 ; 1,2-butanediol, 2-ethyl- (C6) n-BO ₁ ; 1,2-butanediol, 2-methyl- (C5) (Me E _1-2 ); 1,2-butanediol, 2-methyl- (C5) PO ₁ ; 1,2-butanediol, 3,3-dimethyl- (C6) E _2-5 ; 1,2-butanediol, 3,3-dimethyl- (C6) n-BO ₁ ; 1,2-butanediol, 3-methyl- (C5) (Me E _1-2 ); 1,2-butanediol, 3-methyl- (C5) PO ₁ ; 1,3-butanediol (C4) 2 (Me E _5-6 ); 1,3-butanediol (C4) BO ₂ ; 1,3-butanediol, 2,2,3-trimethyl- (C7) (Me E _1-3 ); 1,3-butanediol, 2,2,3-trimethyl- (C7) PO ₂ ; 1,3-butanediol, 2,2-dimethyl- (C6) (Me E _6-8 ); 1,3-butanediol, 2,2-dimethyl- (C6) PO ₃ ; 1,3-butanediol, 2,3-dimethyl- (C6) (Me E _6-8 ); 1,3-butanediol, 2,3-dimethyl- (C6) PO ₃ ; 1,3-butanediol, 2-ethyl- (C6) (Me E _4-6 ); 1,3-butanediol, 2-ethyl- (C6) PO _2-3 ; 1,3-butanediol, 2-ethyl- (C6) BO ₁ ; 1,3-butanediol, 2-ethyl-2-methyl- (C7) (Me E ₁ ); 1,3-butanediol, 2-ethyl-2-methyl- (C7) PO ₁ ; 1,3-butanediol, 2-ethyl-2-methyl- (C7) n-BO ₃ ; 1,3-butanediol, 2-ethyl-3-methyl- (C7) (Me E ₁ ); 1,3-butanediol, 2-ethyl-3-methyl- (C7) PO ₁ ; 1,3-butanediol, 2-ethyl-3-methyl- (C7) n-BO ₃ ; 1,3-butanediol, 2-isopropyl- (C7) (Me E ₁ ); 1,3-butanediol, 2-isopropyl- (C7) PO ₁ ; 1,3-butanediol, 2-isopropyl- (C7) n-BO ₃ ; 1,3-butanediol 2-methyl- (C5) 2 (Me E _2-3 ); 1,3-butanediol, 2-methyl- (C5) PO ₄ ; 1,3-butanediol, 2-propyl- (C7) E _6-8 ; 1,3-butanediol, 2-propyl- (C7) PO ₁ ; 1,3-butanediol, 2-propyl- (C7) n-BO _2-3 ; 1,3-butanediol, 3-methyl- (C5) 2 (Me E _2-3 ); 1,3-butanediol, 3-methyl- (C5) PO ₄ ; 1,4-butanediol (C4) 2 (Me E _3-4 ); 1,4-butanediol (C4) PO _4-5 ; 1,4-butanediol, 2,2,3-trimethyl- (C7) E _6-9 ; 1,4-butanediol, 2,2,3-trimethyl- (C7) PO ₁ ; 1,4-butanediol, 2,2,3-trimethyl- (C7) n-BO _2-3 ; 1,4-butanediol, 2,2-dimethyl- (C6) (Me E _3-6 ); 1,4-butanediol, 2,2-dimethyl- (C6) PO ₂ ; 1,4-butanediol, 2,2-dimethyl- (C6) BO ₁ ; 1,4-butanediol, 2,3-dimethyl- (C6) (Me E _3-6 ); 1,4-butanediol, 2,3-dimethyl- (C6) PO ₂ ; 1,4-butanediol, 2,3-dimethyl- (C6) BO ₁ ; 1,4-butanediol, 2-ethyl- (C6) (Me E _1-4 ); 1,4-butanediol, 2-ethyl- (C6) PO ₂ ; 1,4-butanediol, 2-ethyl-2-methyl- (C7) E _4-7 ; 1,4-butanediol, 2-ethyl-2-methyl- (C7) PO ₁ ; 1,4-butanediol, 2-ethyl-2-methyl- (C7) nBO ₂ ; 1,4-butanediol, 2-ethyl-3-methyl- (C7) E _4-7 ; 1,4-butanediol, 2-ethyl-3-methyl- (C7) PO ₁ ; 1,4-butanediol, 2-ethyl-3-methyl- (C7) n-BO ₂ ; 1,4-butanediol, 2-isopropyl- (C7) E _4-7 ; 1,4-butanediol, 2-isopropyl- (C7) PO ₁ ; 1,4-butanediol, 2-isopropyl- (C7) n-BO ₂ ; 1,4-butanediol, 2-methyl- (C5) (Me E _9-10 ); 1,4-butanediol, 2-methyl- (C5) 2 (Me E ₁ ); 1,4-butanediol, 2-methyl- (C5) PO ₃ ; 1,4-butanediol, 2-propyl- (C7) E _2-5 ; 1,4-butanediol, 2-propyl- (C7) n-BO ₁ ; 1,4-butanediol, 3-ethyl-l-methyl- (C7) E _6-8 ; 1,4-butanediol, 3-ethyl-1-methyl- (C7) PO ₁ ; 1,4-butanediol, 3-ethyl-l-methyl- (C7) n-BO _2-3 ; 2,3-butanediol (C4) (Me E _9-10 ); 2,3-butanediol (C4) 2 (Me E ₁ ); 2,3-butanediol (C4) PO _3-4 ; 2,3-butanediol, 2,3-dimethyl- (C6) E _7-9 ; 2,3-butanediol, 2,3-dimethyl- (C6) PO ₁ ; 2,3-butanediol, 2,3-dimethyl- (C6) BO _2-3 ; 2,3-butanediol, 2-methyl- (C5) (Me E _2-5 ); 2,3-butanediol, 2-methyl- (C5) PO ₂ ; 2,3-butanediol, 2-methyl- (C5) BO ₁ ;

3. 1,2-pentanediol (C5) E _7-10 ; 1,2-pentanediol, (C5) PO ₁ ; 1,2-pentanediol, (C5) n-BO ₃ ; 1,2-pentanediol, 2-methyl (C6) E _1-3 ; 1,2-pentanediol, 2-methyl (C6) n-BO ₁ ; 1,2-pentanediol, 3-methyl (C6) E _1-3 ; 1,2-pentanediol, 3-methyl (C6) n-BO ₁ ; 1,2-pentanediol, 4-methyl (C6) E _1-3 ; 1,2-pentanediol, 4-methyl (C6) n-BO ₁ ; 1,3-pentanediol (C5) 2 (Me-E _1-2 ); 1,3-pentanediol (C5) PO _3-4 ; 1,3-pentanediol, 2,2-dimethyl- (C7) (Me-E ₁ ); 1,3-pentanediol, 2,2-dimethyl- (C7) PO ₁ ; 1,3-pentanediol, 2,2-dimethyl- (C7) n-BO ₃ ; 1,3-pentanediol, 2,3-dimethyl- (C7) (Me-E ₁ ); 1,3-pentanediol, 2,3-dimethyl- (C7) PO ₁ ; 1,3-pentanediol, 2,3-dimethyl- (C7) n-BO ₃ ; 1,3-pentanediol, 2,4-dimethyl (C7) (Me-E ₁ ); 1,3-pentanediol, 2,4-dimethyl- (C7) PO ₁ ; 1,3-pentanediol, 2,4-dimethyl- (C7) n-BO ₃ ; 1,3-pentanediol, 2-ethyl- (C7) E _6-8 ; 1,3-pentanediol, 2-ethyl- (C7) PO ₁ ; 1,3-pentanediol, 2-ethyl- (C7) n-BO _2-3 ; 1,3-pentanediol, 2-methyl- (C6) 2 (Me-E _4-6 ); 1,3-pentanediol, 2-methyl- (C6) PO _2-3 ; 1,3-pentanediol, 3,4-dimethyl- (C7) (Me-E ₁ ); 1,3-pentanediol, 3,4-dimethyl- (C7) PO ₁ ; 1,3-pentanediol, 3,4-dimethyl- (C7) n-BO ₃ ; 1,3-pentanediol, 3-methyl- (C6) (Me-E _4-6 ); 1,3-pentanediol, 3-methyl- (C6) PO _2-3 ; 1,3-pentanediol, 4,4-dimethyl- (C7) (Me-E ₁ ); 1,3-pentanediol, 4,4-dimethyl- (C7) PO ₁ ; 1,3-pentanediol, 4,4-dimethyl- (C7) n-BO ₃ ; 1,3-pentanediol, 4-methyl- (C6) 2 (Me-E _4-6 ); 1,3-pentanediol, 4-methyl- (C6) PO _2-3 ; 1,4-pentanediol, (C5) 2 (Me-E _1-2 ); 1,4-pentanediol, (C5) PO _3-4 ; 1,4-pentanediol, 2,2-dimethyl- (C7) (Me-E ₁ ); 1,4-pentanediol, 2,2-dimethyl- (C7) PO ₁ ; 1,4-pentanediol, 2,2-dimethyl- (C7) n-BO ₃ ; 1,4-pentanediol, 2,3-dimethyl- (C7) (Me-E ₁ ); 1,4-pentanediol, 2,3-dimethyl- (C7) PO ₁ ; 1,4-pentanediol, 2,3-dimethyl- (C7) n-BO ₃ ; 1,4-pentanediol, 2,4-dimethyl- (C7) (Me-E ₁ ); 1,4-pentanediol, 2,4-dimethyl- (C7) PO ₁ ; 1,4-pentanediol, 2,4-dimethyl- (C7) n-BO ₃ ; 1,4-pentanediol, 2-methyl- (C6) (Me-E _4-6 ); 1,4-pentanediol, 2-methyl- (C6) PO _2-3 ; 1,4-pentanediol, 3,3-dimethyl- (C7) (Me-E ₁ ); 1,4-pentanediol, 3,3-dimethyl- (C7) PO ₁ ; 1,4-pentanediol, 3,3-dimethyl- (C7) n-BO ₃ ; 1,4-pentanediol, 3,4-dimethyl- (C7) (Me-E ₁ ), 1,4-pentanediol, 3,4-dimethyl- (C7) PO ₁ ; 1,4-pentanediol, 3,4-dimethyl (C7) n-BO ₃ ; 1,4-pentanediol, 3-methyl- (C6) 2 (Me-E _4-6 ); 1,4-pentanediol, 3-methyl- (C6) PO _2-3 ; 1,4-pentanediol, 4-methyl- (C6) 2 (Me-E _4-6 ); 1,4-pentanediol, 4-methyl- (C6) PO _2-3 ; 1,5-pentanediol, (C5) (Me-E _8-10 ); 1,5-pentanediol (C5) 2 (Me-E ₁ ); 1,5-pentanediol (C5) PO ₃ ; 1,5-pentanediol, 2,2-dimethyl- (C7) E _4-7 ; 1,5-pentanediol, 2,2-dimethyl- (C7) PO ₁ ; 1,5-pentanediol, 2,2-dimethyl- (C7) n-BO ₂ ; 1,5-pentanediol, 2,3-dimethyl- (C7) E _4-7 ; 1,5-pentanediol, 2,3-dimethyl- (C7) PO ₁ ; 1,5-pentanediol, 2,3-dimethyl- (C7) n-BO ₂ ; 1,5-pentanediol, 2,4-dimethyl- (C7) E _4-7 ; 1,5-pentanediol, 2,4-dimethyl- (C7) PO ₁ ; 1,5-pentanediol, 2,4-dimethyl- (C7) n-BO ₂ ; 1,5-pentanediol, 2-ethyl- (C7) E _2-5 ; 1,5-pentanediol, 2-ethyl- (C7) n-BO ₁ ; 1,5-pentanediol, 2-methyl- (C6) (Me-E _1-4 ); 1,5-pentanediol, 2-methyl- (C6) PO ₂ ; 1,5-pentanediol, 3,3-dimethyl- (C7) E _4-7 ; 1,5-pentanediol, 3,3-dimethyl- (C7) PO ₁ ; 1,5-pentanediol, 3,3-dimethyl- (C7) n-BO ₂ ; 1,5-pentanediol, 3-methyl- (C6) (Me-E _1-4 ); 1,5-pentanediol, 3-methyl- (C6) PO ₂ ; 2,3-pentanediol, (C5) (Me-E _1-3 ); 2,3-pentanediol, (C5) PO ₂ ; 2,3-pentanediol, 2-methyl- (C6) E _4-7 ; 2,3-pentanediol, 2-methyl- (C6) PO ₁ ; 2,3-pentanediol, 2-methyl- (C6) n-BO ₂ ; 2,3-pentanediol, 3-methyl- (C6) E _4-7 ; 2,3-pentanediol, 3-methyl- (C6) PO ₁ ; 2,3-pentanediol, 3-methyl- (C6) n-BO ₂ ; 2,3-pentanediol, 4-methyl- (C6) E _4-7 ; 2,3-pentanediol, 4-methyl- (C6) PO ₁ ; 2,3-pentanediol, 4-methyl- (C6) n-BO ₂ ; 2,4-pentanediol, (C5) 2 (Me-E _2-4 ); 2,4-pentanediol (C5) PO ₄ ; 2,4-pentanediol, 2,3-dimethyl- (C7) (Me-E _2-4 ); 2,4-pentanediol, 2,3-dimethyl- (C7) PO ₂ ; 2,4-pentanediol, 2,4-dimethyl- (C7) (Me-E _2-4 ); 2,4-pentanediol, 2,4-dimethyl- (C7) PO ₂ ; 2,4-pentanediol, 2-methyl- (C7) (Me-E _8-10 ); 2,4-pentanediol, 2-methyl- (C7) PO ₃ ; 2,4-pentanediol, 3,3-dimethyl (C7) (Me-E _2-4 ); 2,4-pentanediol, 3,3-dimethyl- (C7) PO ₂ ; 2,4-pentanediol, 3-methyl- (C6) (Me-E _8-10 ); 2,4-pentanediol, 3-methyl- (C6) PO ₃ ;

4. 1,3-hexanediol (C6) (Me-E _2-5 ); 1,3-hexanediol (C6) PO ₂ ; 1,3-hexanediol (C6) BO ₁ ; 1,3-hexanediol, 2-methyl- (C7) E _6-8 ; 1,3-hexanediol, 2-methyl- (C7) PO ₁ ; 1,3-hexanediol, 2-methyl- (C7) n-BO _2-3 ; 1,3-hexanediol, 3-methyl- (C7) E _6-8 ; 1,3-hexanediol, 3-methyl (C7) PO ₁ ; 1,3-hexanediol, 3-methyl- (C7) n-BO _2-3 ; 1,3-hexanediol, 4-methyl- (C7) E _6-8 ; 1,3-hexanediol, 4-methyl- (C7) PO ₁ ; 1,3-hexanediol, 4-methyl- (C7) n-BO _2-3 ; 1,3-hexanediol, 5-methyl- (C7) E _6-8 ; 1,3-hexanediol, 5-methyl- (C7) PO ₁ ; 1,3-hexanediol, 5-methyl- (C7) n-BO _2-3 ; 1,4-hexanediol (C6) (Me-E _2-5 ); 1,4-hexanediol (C6) PO ₂ ; 1,4-hexanediol (C6) BO ₁ ; 1,4-hexanediol, 2-methyl- (C7) E _6-8 ; 1,4-hexanediol, 2-methyl- (C7) PO ₁ ; 1,4-hexanediol, 2-methyl- (C7) n-BO _2-3 ; 1,4-hexanediol, 3-methyl- (C7) E _6-8 ; 1,4-hexanediol, 3-methyl- (C7) PO ₁ ; 1,4-hexanediol, 3-methyl- (C7) n-BO _2-3 ; 1,4-hexanediol, 4-methyl- (C7) E _6-8 ; 1,4-hexanediol, 4-methyl- (C7) PO ₁ ; 1,4-hexanediol, 4-methyl- (C7) n-BO _2-3 ; 1,4-hexanediol, 5-methyl- (C7) E _6-8 ; 1,4-hexanediol, 5-methyl- (C7) PO ₁ ; 1,4-hexanediol, 5-methyl- (C7) n-BO _2-3 ; 1,5-hexanediol (C6) (Me-E _2-5 ); 1,5-hexanediol (C6) PO ₂ ; 1,5-hexanediol (C6) BO ₁ ; 1,5-hexanediol, 2-methyl- (C7) E _6-8 ; 1,5-hexanediol, 2-methyl- (C7) PO ₁ ; 1,5-hexanediol, 2-methyl- (C7) n-BO _2-3 ; 1,5-hexanediol, 3-methyl- (C7) E _6-8 ; 1,5-hexanediol, 3-methyl- (C7) PO ₁ ; 1,5-hexanediol, 3-methyl- (C7) n-BO _2-3 ; 1,5-hexanediol, 4-methyl- (C7) E _6-8 ; 1,5-hexanediol, 4-methyl- (C7) PO ₁ ; 1,5-hexanediol, 4-methyl- (C7) n-BO _2-3 ; 1,5-hexanediol, 5-methyl- (C7) E _6-8 ; 1,5-hexanediol, 5-methyl- (C7) PO ₁ ; 1,5-hexanediol, 5-methyl- (C7) n-BO _2-3 ; 1,6-hexanediol (C6) (Me-E _1-2 ); 1,6-hexanediol (C6) PO _1-2 ; 1,6-hexanediol (C6) n-BO ₄ ; 1,6-hexanediol, 2-methyl- (C7) E _2-5 ; 1,6-hexanediol, 2-methyl- (C7) n-BO ₁ ; 1,6-hexanediol, 3-methyl- (C7) E _2-5 ; 1,6-hexanediol, 3-methyl- (C7) n-BO ₁ ; 2,3-hexanediol (C6) E _2-5 ; 2,3-hexanediol (C6) n-BO ₁ ; 2,4-hexanediol (C6) (Me-E _5-8 ); 2,4-hexanediol (C6) PO ₃ ; 2,4-hexanediol, 2-methyl- (C7) (Me-E _1-2 ); 2,4-hexanediol, 2-methyl- (C7) PO _1-2 ; 2,4-hexanediol, 3-methyl- (C7) (Me-E _1-2 ); 2,4-hexanediol, 3-methyl- (C7) PO _1-2 ; 2,4-hexanediol, 4-methyl- (C7) (Me-E _1-2 ); 2,4-hexanediol, 4-methyl- (C7) PO _1-2 ; 2,4-hexanediol, 5-methyl- (C7) (Me-E _1-2 ); 2,4-hexanediol, 5-methyl- (C7) PO _1-2 ; 2,5-hexanediol (C6) (Me-E _5-8 ); 2,5-hexanediol (C6) PO ₃ ; 2,5-hexanediol, 2-methyl (C7) (Me-E _1-2 ); 2,5-hexanediol, 2-methyl- (C7) PO _1-2 ; 2,5-hexanediol, 3-methyl- (C7) (Me-E _1-2 ); 2,5-hexanediol, 3-methyl- (C7) PO _1-2 ; 3,4-hexanediol (C6) EO _2-5 ; 3,4-hexanediol (C6) n-BO ₁ ;

5. 1,3-heptanediol (C7) E _3-6 ; 1,3-heptanediol (C7) PO ₁ ; 1,3-heptanediol (C7) n-BO ₂ ; 1,4-heptanediol (C7) E _3-6 ; 1,4-heptanediol (C7) PO ₁ ; 1,4-heptanediol (C7) n-BO ₂ ; 1,5-heptanediol (C7) E _3-6 ; 1,5-heptanediol (C7) PO ₁ ; 1,5-heptanediol (C7) n-BO ₂ ; 1,6-heptanediol (C7) E _3-6 ; 1,6-heptanediol (C7) PO ₁ ; 1,6-heptanediol (C7) n-BO ₂ ; 1,7-heptanediol (C7) E _1-2 ; 1,7-heptanediol (C7) n-BO ₁ ; 2,4-heptanediol (C7) E _7-10 ; 2,4-heptanediol (C7) (Me-E ₁ ); 2,4-heptanediol (C7) PO ₁ ; 2,4-heptanediol (C7) n-BO ₃ ; 2,5-heptanediol (C7) E _7-10 ; 2,5-heptanediol (C7) (Me-E ₁ ); 2,5-heptanediol (C7) PO ₁ ; 2,5-heptanediol (C7) n-BO ₃ ; 2,6-heptanediol (C7) E _7-10 ; 2,6-heptanediol (C7) (Me-E ₁ ); 2,6-heptanediol (C7) PO ₁ ; 2,6-heptanediol (C7) n-BO ₃ ; 3,5-heptanediol (C7) E _7-10 ; 3,5-heptanediol (C7) (Me-E ₁ ); 3,5-heptanediol (C7) PO ₁ ; 3,5-heptanediol (C7) n-BO ₃ ;

6. 1,3-butanediol, 3-methyl-2-isopropyl- (C8) PO ₁ ; 2,4-pentanediol, 2,3,3-trimethyl- (C8) PO ₁ ; 1,3-butanediol, 2,2-diethyl- (C8) E _2-5 ; 2,4-hexanediol, 2,3-dimethyl- (C8) E _2-5 ; 2,4-hexanediol, 2,4-dimethyl- (C8) E _2-5 ; 2,4-hexanediol, 2,5-dimethyl- (C8) E _2-5 ; 2,4-hexanediol, 3,3-dimethyl- (C8) E _2-5 ; 2,4-hexanediol, 3,4-dimethyl- (C8) E _2-5 ; 2,4-hexanediol, 3,5-dimethyl- (C8) E _2-5 ; 2,4-hexanediol, 4,5-dimethyl- (C8) E _2-5 ; 2,4-hexanediol, 5,5-dimethyl- (C8) E _2-5 ; 2,5-hexanediol, 2,3-dimethyl- (C8) E _2-5 ; 2,5-hexanediol, 2,4-dimethyl- (C8) E _2-5 ; 2,5-hexanediol, 2,5-dimethyl- (C8) E _2-5 ; 2,5-hexanediol, 3,3-dimethyl- (C8) E _2-5 ; 2,5-hexanediol, 3,4-dimethyl- (C8) E _2-5 ; 3,5-heptanediol, 3-methyl- (C8) E _2-5 ; 1,3-butanediol, 2,2-diethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 2,3-dimethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 2,4-dimethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 2,5-dimethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 3,3-dimethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 3,4-dimethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 3,5-dimethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 4,5-dimethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 5,5-dimethyl-, n-BO _1-2 ; 2,5-hexanediol, 2,3-dimethyl (C8) n-BO _1-2 ; 2,5-hexanediol, 2,4-dimethyl- (C8) n-BO _1-2 ; 2,5-hexanediol, 2,5-dimethyl- (C8) n-BO _1-2 ; 2,5-hexanediol, 3,3-dimethyl- (C8) n-BO _1-2 ; 2,5-hexanediol, 3,4-dimethyl- (C8) n-BO _1-2 ; 3,5-heptanediol, 3-methyl- (C8) n-BO _1-2 ; 1,3-propanediol, 2- (1,2-dimethylpropyl)-(C8) n-BO ₁ ; 1,3-butanediol, 2-ethyl-2,3-dimethyl- (C8) n-BO ₁ ; 1,3-butanediol, 2-methyl-2-isopropyl- (C8) n-BO ₁ ; 1,4-butanediol, 3-methyl-2-isopropyl- (C8) n-BO ₁ ; 1,3-pentanediol, 2,2,3-trimethyl (C8) n-BO ₁ ; 1,3-pentanediol, 2,2,4-trimethyl- (C8) n-BO ₁ ; 1,3-pentanediol, 2,4,4-trimethyl- (C8) n-BO ₁ ; 1,3-pentanediol, 3,4,4-trimethyl- (C8) n-BO ₁ ; 1,4-pentanediol, 2,2,3-trimethyl- (C8) n-BO ₁ ; 1,4-pentanediol, 2,2,4-trimethyl- (C8) n-BO ₁ ; 1,4-pentanediol, 2,3,3-trimethyl- (C8) n-BO ₁ ; 1,4-pentanediol, 2,3,4-trimethyl (C8) n-BO ₁ ; 1,4-pentanediol, 3,3,4-trimethyl- (C8) n-BO ₁ ; 2,4-pentanediol, 2,3,4-trimethyl- (C8) n-BO ₁ ; 2,4-hexanediol, 4-ethyl- (C8) n-BO ₁ ; 2,4-heptanediol, 2-methyl- (C8) n-BO ₁ ; 2,4-heptanediol, 3-methyl- (C8) n-BO ₁ ; 2,4-heptanediol, 4-methyl- (C8) n-BO ₁ ; 2,4-heptanediol, 5-methyl- (C8) n-BO ₁ ; 2,4-heptanediol, 6-methyl- (C8) n-BO ₁ ; 2,5-heptanediol, 2-methyl- (C8) n-BO ₁ ; 2,5-heptanediol, 3-methyl- (C8) n-BO ₁ ; 2,5-heptanediol, 4-methyl- (C8) n-BO ₁ ; 2,5-heptanediol, 5-methyl- (C8) n-BO ₁ ; 2,5-heptanediol, 6-methyl- (C8) n-BO ₁ ; 2,6-heptanediol, 2-methyl- (C8) n-BO ₁ ; 2,6-heptanediol, 3-methyl- (C8) n-BO ₁ ; 2,6-heptanediol, 4-methyl- (C8) n-BO ₁ ; 3,5-heptanediol, 2-methyl- (C8) n-BO ₁ ; 1,3-propanediol, 2- (1,2-dimethylpropyl)-(C8) E _1-3 ; 1,3-butanediol, 2-ethyl-2,3-dimethyl- (C8) E _1-3 ; 1,3-butanediol, 2-methyl-2-isopropyl- (C8) E _1-3 ; 1,4-butanediol, 3-methyl-2-isopropyl- (C8) E _1-3 ; 1,3-pentanediol, 2,2,3-trimethyl- (C8) E _1-3 ; 1,3-pentanediol, 2,2,4-trimethyl- (C8) E _1-3 ; 1,3-pentanediol, 2,4,4-trimethyl- (C8) E _1-3 ; 1,3-pentanediol, 3,4,4-trimethyl- (C8) E _1-3 ; 1,4-pentanediol, 2,2,3-trimethyl- (C8) E _1-3 ; 1,4-pentanediol, 2,2,4-trimethyl- (C8) E _1-3 ; 1,4-pentanediol, 2,3,3-trimethyl- (C8) E _1-3 ; 1,4-pentanediol, 2,3,4-trimethyl- (C8) E _1-3 ; 1,4-pentanediol, 3,3,4-trimethyl- (C8) E _1-3 ; 2,4-pentanediol, 2,3,4-trimethyl- (C8) E _1-3 ; 2,4-hexanediol, 4-ethyl- (C8) E _1-3 ; 2,4-heptanediol, 2-methyl- (C8) E _1-3 ; 2,4-heptanediol, 3-methyl- (C8) E _1-3 ; 2,4-heptanediol, 4-methyl- (C8) E _1-3 ; 2,4-heptanediol, 5-methyl- (C8) E _1-3 ; 2,4-heptanediol, 6-methyl- (C8) E _1-3 ; 2,5-heptanediol, 2-methyl- (C8) E _1-3 ; 2,5-heptanediol, 3-methyl- (C8) E _1-3 ; 2,5-heptanediol, 4-methyl- (C8) E _1-3 ; 2,5-heptanediol, 5-methyl- (C8) E _1-3 ; 2,5-heptanediol, 6-methyl- (C8) E _1-3 ; 2,6-heptanediol, 2-methyl- (C8) E _1-3 ; 2,6-heptanediol, 3-methyl- (C8) E _1-3 ; 2,6-heptanediol, 4-methyl- (C8) E _1-3 ; And / or 3,5-heptanediol, 2-methyl- (C8) E _1-3 ; And

7. Mixtures of these.

Of these nonane isomers, only 2,4-pentanediol, 2,3,3,4-tetramethyl- are very preferred.

In addition to the aliphatic diol main solvents described above and below, and some alkoxylated derivatives thereof, certain specific diol ethers have also been found to be suitable main solvents for the preparation of the liquid, concentrated, transparent fabric softener compositions of the present invention. Similar to the aliphatic diol main solvent, the suitability of each main solvent was found to be highly selective, depending on the number of carbon atoms in the particular diol ether molecule. For example, as shown in Table 6 above, for the glyceryl ether family having the formula HOCH ₂ -CHOH-CH ₂ -OR, wherein R is C _2-8 alkyl, only the formula HOCH _2- Preferred monopentyl ethers (3-pentyloxy-1,2-propanediol) with CHOH-CH ₂ -OC ₅ H ₁₁ (wherein the C ₅ H ₁₁ groups contain different pentyl isomers) of about 0.25 to about 0.62 It has a ClogP value within the ClogP value and is suitable for preparing the liquid, concentrated, transparent fabric softener of the present invention. In addition, cyclohexyl derivatives other than cyclopentyl derivatives have proven to be suitable. Similarly, selectivity is indicated in the selection of aryl glyceryl ethers. Among the many possible aromatic groups, very few phenol derivatives are suitable.

Such narrow selectivity is also found in di (hydroxyalkyl) ethers. Bis (2-hydroxybutyl) ether, but not bis (2-hydroxypentyl) ether, has proven to be suitable. In the case of di (cyclic hydroxyalkyl) analogs, bis (2-hydroxycyclopentyl) ethers other than bis (2-hydroxycyclohexyl) ethers are suitable. Non-limiting examples of synthetic methods for the preparation of some preferred di (hydroxyalkyl) ethers are described below.

Butyl monoglycerol ether (also 3-butyloxy-1,2-propanediol) is not sufficiently suitable to form the liquid, concentrated, transparent fabric softener of the present invention. However, as shown in Table 6 above, polyethoxylated derivatives thereof, preferably about triethoxylated to about nonaethoxylated derivatives, more preferably pentaethoxylated to octaethoxylated derivatives, Suitable main solvent.

All preferred alkyl glyceryl ethers and / or di (hydroxyalkyl) ethers identified are shown in Table 6 above, wherein double, 1,2-propanediol, 3- (n-pentyloxy)-; 1,2-propanediol, 3- (2-pentyloxy)-; 1,2-propanediol, 3- (3-pentyloxy)-; 1,2-propanediol, 3- (2-methyl-1-butyloxy)-; 1,2-propanediol, 3- (iso-amyloxy)-; 1,2-propanediol, 3- (3-methyl-2-butyloxy)-; 1,2-propanediol, 3- (cyclohexyloxy)-; 1,2-propanediol, 3- (1-cyclohex-1-enyloxy)-; 1,3-propanediol and 2- (pentyloxy)-; 1,3-propanediol and 2- (2-pentyloxy)-; 1,3-propanediol and 2- (3-pentyloxy)-; 1,3-propanediol and 2- (2-methyl-1-butyloxy)-; 1,3-propanediol, 2- (iso-amyloxy)-; 1,3-propanediol and 2- (3-methyl-2-butyloxy)-; 1,3-propanediol and 2- (cyclohexyloxy)-; 1,3-propanediol and 2- (1-cyclohex-1-enyloxy)-; 1,2-propanediol, 3- (butyloxy)-, pentaethoxylation; 1,2-propanediol, 3- (butyloxy)-, hexaethoxylated; 1,2-propanediol, 3- (butyloxy)-, heptaethoxylation; 1,2-propanediol, 3- (butyloxy), octaethoxylation; 1,2-propanediol, 3- (butyloxy)-, nonaethoxylation; 1,2-propanediol, 3- (butyloxy)-, monopropoxylated; 1,2-propanediol, 3- (butyloxy)-, dibutyleneoxylation; And / or 1,2-propanediol, 3- (butyloxy)-, tributyleneoxylation are most preferred. Preferred aromatic glyceryl ethers include 1,2-propanediol, 3-phenyloxy-; 1,2-propanediol, 3-benzyloxy-; 1,2-propanediol, 3- (2-phenylethyloxy)-; 1,2-propanediol, 1,3-propanediol, 2- (m-cresyloxy)-; 1,3-propanediol, 2- (p-cresyloxy)-; 1,3-propanediol and 2-benzyloxy-; Most preferred are 1,3-propanediol, 2- (2-phenylethyloxy)-and mixtures thereof. More preferred aromatic glyceryl ethers include 1,2-propanediol and 3-phenyloxy-; 1,2-propanediol, 3-benzyloxy-; 1,2-propanediol, 3- (2-phenylethyloxy)-; 1,2-propanediol, 1,3-propanediol, 2- (m-cresyloxy)-; 1,3-propanediol, 2- (p-cresyloxy)-; 1,3-propanediol, 2- (2-phenylethyloxy)-and mixtures thereof. Most preferred di (hydroxyalkyl) ethers include bis (2-hydroxybutyl) ether and bis (2-hydroxycyclopentyl) ether.

Illustrative and non-limiting examples of synthetic methods for preparing preferred alkyl and aryl monoglyceryl ethers are described below.

Preferred aliphatic cyclic diols and derivatives thereof include (1) 1-isopropyl-1,2-cyclobutanediol; 3-ethyl-4-methyl-1,2-cyclobutanediol; 3-propyl-1,2-cyclobutanediol; 3-isopropyl-1,2-cyclobutanediol; 1-ethyl-1,2-cyclopentanediol; 1,2-dimethyl-1,2-cyclopentanediol; 1,4-dimethyl-1,2-cyclopentanediol; 2,4,5-trimethyl-1,3-cyclopentanediol; 3,3-dimethyl-1,2-cyclopentanediol; 3,4-dimethyl-1,2-cyclopentanediol; 3,5-dimethyl-1,2-cyclopentanediol; 3-ethyl-1,2-cyclopentanediol; 4,4-dimethyl-1,2-cyclopentanediol; 4-ethyl-1,2-cyclopentanediol; 1,1-bis (hydroxymethyl) cyclohexane; 1,2-bis (hydroxymethyl) cyclohexane; 1,2-dimethyl-1,3-cyclohexanediol; 1,3-bis (hydroxymethyl) cyclohexane; 1,3-dimethyl-1,3-cyclohexanediol; 1,6-dimethyl-1,3-cyclohexanediol; 1-hydroxy cyclohexane ethanol; 1-hydroxycyclohexanemethanol; 1-ethyl-1,3-cyclohexanediol; 1-methyl-1,2-cyclohexanediol; 2,2-dimethyl-1,3-cyclohexanediol; 2,3-dimethyl-1,4-cyclohexanediol; 2,4-dimethyl-1,3-cyclohexanediol; 2,5-dimethyl-1,3-cyclohexanediol; 2,6-dimethyl-1,4-cyclohexanediol; 2-ethyl-1,3-cyclohexanediol; 2-hydroxycyclohexane ethanol; 2-hydroxyethyl-1-cyclohexanol; 2-hydroxymethylcyclohexanol; 3-hydroxyethyl-1-cyclohexanol; 3-hydroxycyclohexane ethanol; 3-hydroxymethylcyclohexanol; 3-methyl-1,2-cyclohexanediol; 4,4-dimethyl-1,3-cyclohexanediol; 4,5-dimethyl-1,3-cyclohexanediol; 4,6-dimethyl-1,3-cyclohexanediol; 4-ethyl-1,3-cyclohexanediol; 4-hydroxyethyl-1-cyclohexanol; 4-hydroxymethylcyclohexanol; 4-methyl-1,2-cyclohexanediol; 5,5-dimethyl-1,3-cyclohexanediol; 5-ethyl-1,3-cyclohexanediol; 1,2-cycloheptanediol; 2-methyl-1,3-cycloheptanediol; 2-methyl-1,4-cycloheptanediol; 4-methyl-1,3-cycloheptanediol; 5-methyl-1,3-cycloheptanediol; 5-methyl-1,4-cycloheptanediol; 6-methyl-l, 4-cycloheptanediol; 1,3-cyclooctanediol; 1,4-cyclooctanediol; 1,5-cyclooctanediol; 1,2-cyclohexanediol and diethoxylate; 1,2-cyclohexanediol and triethoxylate; 1,2-cyclohexanediol and tetraethoxylate; 1,2-cyclohexanediol and pentaethoxylate; 1,2-cyclohexanediol and hexaethoxylate; 1,2-cyclohexanediol and heptaethoxylate; 1,2-cyclohexanediol and octaethoxylate; 1,2-cyclohexanediol and nonaethoxylate; 1,2-cyclohexanediol and monopropoxylate; 1,2-cyclohexanediol and monobutylene oxylate; 1,2-cyclohexanediol and dibutylene oxylate; And / or saturated diols including 1,2-cyclohexanediol, tributyleneoxylate and derivatives thereof. Most preferred saturated aliphatic cyclic diols and derivatives thereof are 1-isopropyl-1,2-cyclobutanediol; 3-ethyl-4-methyl-1,2-cyclobutanediol; 3-propyl-1,2-cyclobutanediol; 3-isopropyl-1,2-cyclobutanediol; 1-ethyl-1,2-cyclopentanediol; 1,2-dimethyl-1,2-cyclopentanediol; 1,4-dimethyl-1,2-cyclopentanediol; 3,3-dimethyl-1,2-cyclopentanediol; 3,4-dimethyl-1,2-cyclopentanediol; 3,5-dimethyl-1,2-cyclopentanediol; 3-ethyl-1,2-cyclopentanediol; 4,4-dimethyl-1,2-cyclopentanediol; 4-ethyl-1,2-cyclopentanediol; 1,1-bis (hydroxymethyl) cyclohexane; 1,2-bis (hydroxymethyl) cyclohexane; 1,2-dimethyl-1,3-cyclohexanediol; 1,3-bis (hydroxymethyl) cyclohexane; 1-hydroxycyclohexanemethanol; 1-methyl-1,2-cyclohexanediol; 3-hydroxymethylcyclohexanol; 3-methyl-1,2-cyclohexanediol; 4,4-dimethyl-1,3-cyclohexanediol; 4,5-dimethyl-1,3-cyclohexanediol; 4,6-dimethyl-1,3-cyclohexanediol; 4-ethyl-1,3-cyclohexanediol; 4-hydroxyethyl-1-cyclohexanol; 4-hydroxymethylcyclohexanol; 4-methyl-1,2-cyclohexanediol; 1,2-cycloheptanediol; 1,2-cyclohexanediol and pentaethoxylate; 1,2-cyclohexanediol and hexaethoxylate; 1,2-cyclohexanediol and heptaethoxylate; 1,2-cyclohexanediol and octaethoxylate; 1,2-cyclohexanediol and nonaethoxylate; 1,2-cyclohexanediol and monopropoxylate; And / or 1,2-cyclohexanediol, dibutyleneoxylate.

Preferred aromatic diols include 1-phenyl-1,2-ethanediol, 1-phenyl-1,2-propanediol, 2-phenyl-1,2-propanediol, 3-phenyl-1,2-propanediol, 1 -(3-methylphenyl) -1,3-propanediol, 1- (4-methylphenyl) -1,3-propanediol, 2-methyl-1-phenyl-1,3-propanediol, 1-phenyl-1, 3-butanediol, 3-phenyl-1,3-butanediol and / or 1-phenyl-1,4-butanediol, of which 1-phenyl-1,2-propanediol, 2-phenyl-1,2-propane Diol, 3-phenyl-1,2-propanediol, 1- (3-methylphenyl) -1,3-propanediol, 1- (4-methylphenyl) -1,3-propanediol, 2-methyl-1-phenyl Most preferred are -1,3-propanediol and / or 1-phenyl-1,4-butanediol.

As mentioned above, all unsaturated substances having one more CH ₂ group than the corresponding saturated main solvents, which are related to the other preferred main solvents herein by the same relationship as above, and which have a value within the effective ClogP range are preferred. . However, certain preferred unsaturated diol main solvents are 1,3-butanediol, 2,2-diallyl-; 1,3-butanediol and 2- (1-ethyl-1-propenyl)-; 1,3-butanediol and 2- (2-butenyl) -2-methyl-; 1,3-butanediol and 2- (3-methyl-2-butenyl)-; 1,3-butanediol and 2-ethyl-2- (2-propenyl)-; 1,3-butanediol and 2-methyl-2- (1-methyl-2-propenyl)-; 1,4-butanediol and 2,3-bis (1-methylethylidene)-; 1,3-pentanediol and 2-ethenyl-3-ethyl-; 1,3-pentanediol, 2-ethenyl-4,4-dimethyl-; 1,4-pentanediol, 3-methyl-2- (2-propenyl)-; 4-pentene-1,3-diol, 2- (1,1-dimethylethyl)-; 4-pentene-1,3-diol, 2-ethyl-2,3-dimethyl-; 1,4-hexanediol and 4-ethyl-2-methylene-; 1,5-hexadiene-3,4-diol, 2,3,5-trimethyl-; 1,5-hexanediol, 2- (1-methylethenyl)-; 2-hexene-1,5-diol, 4-ethenyl-2,5-dimethyl-; 1,4-heptanediol, 6-methyl-5-methylene-; 2,4-heptadiene-2,6-diol, 4,6-dimethyl-; 2,6-heptadiene-1,4-diol, 2,5,5-trimethyl-; 2-heptene-1,4-diol, 5,6-dimethyl-; 3-heptene-1,5-diol, 4,6-dimethyl-; 5-heptene-1,3-diol, 2,4-dimethyl-; 5-heptene-1,3-diol, 3,6-dimethyl-; 5-heptene-1,4-diol, 2,6-dimethyl-; 5-heptene-1,4-diol, 3,6-dimethyl-; 6-heptene-1,3-diol, 2,2-dimethyl-; 6-heptene-1,4-diol, 5,6-dimethyl-; 6-heptene-1,5-diol, 2,4-dimethyl-; 6-heptene-1,5-diol, 2-ethylidene-6-methyl-; 6-heptene-2,4-diol, 4- (2-propenyl)-; 1-octene-3,6-diol, 3-ethenyl-; 2,4,6-octatriene-1,8-diol, 2,7-dimethyl-; 2,5-octadiene-1,7-diol, 2,6-dimethyl-; 2,5-octadiene-1,7-diol, 3,7-dimethyl-; 2,6-octadiene-1,4-diol, 3,7-dimethyl- (rosiridol); 2,6-octadiene-1,8-diol, 2-methyl-; 2,7-octadiene-1,4-diol, 3,7-dimethyl-; 2,7-octadiene-1,5-diol, 2,6-dimethyl-; 2,7-octadiene-1,6-diol, 2,6-dimethyl- (8-hydroxylinalol); 2,7-octadiene-1,6-diol, 2,7-dimethyl-; 2-octene-1,7-diol, 2-methyl-6-methylene-; 3,5-octadiene-2,7-diol, 2,7-dimethyl; 3,5-octanediol and 4-methylene-; 3,7-octadiene-1,6-diol, 2,6-dimethyl-; 4-octene-1,8-diol, 2-methylene-; 6-octene-3,5-diol, 2-methyl-; 6-octene-3,5-diol, 4-methyl-; 7-octene-2,4-diol, 2-methyl-6-methylene-; 7-octene-2,5-diol, 7-methyl-; 7-octene-3,5-diol, 2-methyl-; 1-nonene-3,5-diol-; 1-nonene-3,7-diol; 3-nonene-2,5-diol; 4-nonene-2,8-diol; 6,8-nonadiene-1,5-diol; 7-nonene-2,4-diol; 8-nonene-2,4-diol; 8-nonene-2,5-diol; 1,9-decadiene-3,8-diol-; And / or 1,9-decadiene-4,6-diol.

The main alcohol solvent is also preferably 2,5-dimethyl-2,5-hexanediol, 2-ethyl-1,3-hexanediol, 2-methyl-2-propyl-1,3-propanediol, 1, 2-hexanediol and mixtures thereof. More preferably, the main alcohol solvent is composed of 2-ethyl-1,3-hexanediol, 2-methyl-2-propyl-1,3-propanediol, 1,2-hexanediol and mixtures thereof Is selected. Even more preferably, the main alcohol solvent is selected from the group consisting of 2-ethyl-1,3-hexanediol, 1,2-hexanediol and mixtures thereof.

Multiple derivatives of the diols having different alkyleneoxy groups can be used, for example 2-methyl-2,3-butanediol having 3 to 5 ethyleneoxy groups or 2 propyleneoxy groups or 1 butyleneoxy group In this case, it is preferable to use a derivative having the smallest number of groups, i.e., a derivative having one butyleneoxy group in this case. However, when only about 1 to about 4 ethyleneoxy groups are required to provide good formulation, the derivatives are also preferred.

Unsaturated diols

Surprisingly, it has been found that there is a clear similarity between the tolerability (formulationability) of saturated diols and their unsaturated homologs having higher molecular weights, or analogs. When the unsaturated main solvent has conditions with one additional methylene (ie CH ₂ ) group for each double bond in the chemical formula, the unsaturated homologue / analogue has the same formulation as the parent saturated main solvent. In other words, for each good saturated main solvent of the present invention, there is a clear 'additional rule' suitable for the formulation of a clear, concentrated fabric softener composition, for each CH ₂ group added with one or more CH ₂ groups added. Suitable to maintain a constant number of hydrogen atoms in the molecule as compared to the chemical formula of the 'parent' saturated main solvent by removing two hydrogen atoms from the adjacent carbon atoms in the molecule to form one carbon-carbon double bond Unsaturated main solvent is present. This means that adding -CH ₂ -groups to the solvent chemical formula has the effect of increasing its ClogP value by about 0.53, whereas removing two adjacent hydrogen atoms to form a double bond nearly equals its Clogp value, That is due to the surprising fact that by having an effect of reducing about 0.48, it almost compensates for the CH ₂ -addition. Thus, each additional CH, in place of the preferred saturated main solvent, as long as the ClogP value of the new solvent is in the range of effective values of 0.15 to 0.64, preferably about 0.25 to about 0.62, more preferably about 0.40 to about 0.60. Preferred unsaturated main solvents are used which contain one or more carbon atoms by adding one double bond to _two groups so that the total number of hydrogen atoms remains the same as in the parent saturated main solvent. Illustrative examples are shown below:

2,2-dimethyl-6-heptene-1,3-diol (CAS No. 140192-39-8) is the preferred C9-diol main solvent and the following preferred C8-diol main solvent: 2-methyl-1,3 It can be considered to be derived by appropriate addition of one CH ₂ group and one double bond to each of -heptanediol or 2,2-dimethyl-1,3-hexanediol.

2,4-dimethyl-5-heptene-1,3-diol (CAS No. 123363-69-9) is the preferred C9-diol main solvent and the following preferred C8-diol main solvent: 2-methyl-1,3 It can be considered to be derived by appropriate addition of one CH ₂ group and one double bond to each of -heptane diol or 2,4-dimethyl-1,3-hexanediol.

2- (1-ethyl-1-propenyl) -1,3-butanediol (CAS No. 116103-35-6) is the preferred C9-diol main solvent and the following preferred C8-diol main solvents: 2- (1 It can be considered derived from the appropriate addition of one CH ₂ group and one double bond to each of -ethylpropyl) -1,3-propanediol or 2- (1-methylpropyl) -1,3-butanediol. .

2-ethenyl-3-ethyl-1,3-pentanediol (CAS No. 104683-37-6) is the preferred C9-diol main solvent and the following preferred C8-diol main solvent: 3-ethyl-2-methyl It can be considered derived from the appropriate addition of one CH ₂ group and one double bond to each of -1,3-pentanediol or 2-ethyl-3-methyl-1,3-pentanediol.

3,6-dimethyl-5-heptene-1,4-diol (e.g., CAS No. 106777-99-5) is the preferred C9-diol main solvent and the following preferred C8-diol main solvent: 3-methyl -1,4-heptanediol; 6-methyl-1,4-heptanediol; Or by appropriately adding one CH ₂ group and one double bond to each of 3,5-dimethyl-1,4-hexanediol.

5,6-dimethyl-6-heptene-1,4-diol (e.g. CAS No. 152344-16-6) is the preferred C9-diol main solvent and the following preferred C8-diol main solvent: 5-methyl -1,4-heptanediol; 6-methyl-1,4-heptanediol; Or it can be considered derived by appropriate addition of one CH ₂ group and one double bond to each of 4,5-dimethyl-1,3-hexanediol.

4-Methyl-6-octene-3,5-diol (CAS No. 156414-254) is the preferred C9-diol main solvent and the following preferred C8-diol main solvents: 3,5-octanediol, 3-methyl- It can be considered to be derived by appropriate addition of one CH ₂ group and one double bond to each of 2,4-heptanediol or 4-methyl-3,5-heptanediol.

Rossiridol (CAS No. 101391-01-9) and Isorosiridol (CAS No. 149252-15-3) are the 3,7-dimethyl-2,6-octadiene-1,4-diol As a binary isomer, it is a preferred C10-diol main solvent. These include the following preferred C8-diol main solvents: 2-methyl-1,3-heptanediol; 6-methyl-1,3-heptanediol; 3-methyl-1,4-heptanediol, 6-methyl-1,4-heptanediol, 2,5-dimethyl-1,3-hexanediol; Or by appropriately adding two CH ₂ groups and two double bonds to each of 3,5-dimethyl-1,4-hexanediol.

8-hydroxylinalool (CAS No. 103619-06-3, 2,6-dimethyl-2,7-octadiene-1,6-diol) is the preferred C1O-diol main solvent, Preferred C8-diol main solvents: 2-methyl-1,5-heptanediol; 5-methyl-1,5-heptanediol; 2-methyl-1,6-heptanediol; 6-methyl-1,6-heptanediol; Or by appropriately adding two CH ₂ groups and two double bonds to each of 2,4-dimethyl-1,4-hexanediol.

2,7-dimethyl-3,7-octadiene-2,5-diol (CAS No. 171436-39-8) is the preferred C1O-diol main solvent and the following preferred C8-diol main solvents: 2,5- Octanediol; 6-methyl-1,4-heptanediol; 2-methyl-2,4-heptanediol; 6-methyl-2,4-heptanediol; 2-methyl-2,5-heptanediol; 6-methyl-2,5-heptanediol; And 2,5-dimethyl-2,4-hexanediol, respectively, to be derived by appropriate addition of two CH ₂ groups and two double bonds.

4-butyl-2-butene-1,4-diol (CAS No. 153943-66-9) is the preferred C8-diol main solvent and the following preferred C7-diol main solvent: 2-propyl-1,4-butanediol Or by appropriate addition of one CH ₂ group and one double bond to each of 2-butyl-1,3-propanediol.

For the same reason, there are cases where the high molecular weight unsaturated homologs derived from inferior, unusable saturated solvents are inferior solvents themselves. For example, 3,5-dimethyl-5-hexene-2,4-diol (e.g. CAS No. 160429-40-3) is an inferior unsaturated C8 solvent and the inferior saturated C7 solvent: 3-methyl -2,4-hexanediol; 5-methyl-2,4-hexanediol; Or it may be derived from 2,4-dimethyl-1,3-pentanediol; 2,6-dimethyl-5-heptene-1,2-diol (e.g. CAS No. 141505-71-7) is an inferior unsaturated C9 solvent and the inferior saturated C8 solvent: 2-methyl-1,2 Heptanediol; 6-methyl-1,2-heptanediol; Or from 2,5-dimethyl-1,2-hexanediol.

Surprisingly, it has also been found that there is an exception to this additional rule that saturated main solvents always have unsaturated analogs / homologs that have the same degree of tolerance. The exception relates to saturated diol main solvents having two hydroxy groups located on two adjacent carbon atoms. In some cases, but not always, the insertion of one or more CH ₂ groups between two adjacent hydroxy groups in an inferior solvent results in higher molecular weight unsaturated homologs that are more suitable for transparent concentrated fabric softener formulation. For example, unsaturated 6,6-dimethyl-1-hepten-3,5-diol (CAS No. 109788-01-4) without preferred adjacent hydroxy groups may be selected from 2,2-dimethyl-3 with unusable adjacent hydroxy groups, It can be considered to be derived from 4-hexanediol. In this case, 6,6-dimethyl-1-heptene-3,5-diol is both a preferred main solvent and 2-methyl-3,5-heptanediol or 5,5-dimethyl-2,4 without adjacent hydroxy groups It is more certain to consider that it can be derived from either hexanediol. Conversely, insertion of a CH ₂ group between adjacent hydroxyl groups of a preferred main solvent may result in an unusable high molecular weight unsaturated diol solvent. For example, preferred 2,3-dimethyl-2, in which unusable unsaturated 2,4-dimethyl-5-hexene-2,4-diol (CAS No. 87604-24-8) without adjacent hydroxy groups, has adjacent hydroxy groups, It can be considered to be derived from 3-pentanediol. In this case, both unusable solvents and unsaturated 2,4-dimethyl-5-hexene which are unavailable from either 2-methyl-2,4-hexanediol or 4-methyl-2,4-hexanediol without adjacent hydroxy groups It is more obvious to induce -2,4-diol. In addition, unusable solvents having an adjacent hydroxy group, such as 4,5-dimethyl-6-hexene-1,3-diol and 3,4-dimethyl-1,2-pentanediol pair, have an adjacent hydroxy group In some cases, it may be considered that it can be derived from. Thus, to infer the formulaability of unsaturated solvents without adjacent hydroxy groups, one should start with low molecular weight saturated homologues without adjacent hydroxy groups. That is, in general, the correlation is more certain when the distance / correlation of two hydroxyl groups is maintained. That is, it is certain to start with a saturated solvent having adjacent hydroxy groups in order to infer the formulaability of high molecular weight unsaturated homologs having adjacent hydroxy groups.

It has been found that when using these specific main alcohol solvents, transparent, low viscosity, stable fabric softener compositions can be produced at surprisingly low main solvent concentrations, ie, up to about 40% by weight of the composition. It is also possible to produce highly concentrated fabric softener compositions that can produce low concentrations of fabric softeners that are stable when using primary alcohol solvents and are still stable even when diluted to, for example, from about 2: 1 to about 10: 1. Turned out.

As mentioned above, the main solvent is intended to be kept at the lowest viable amount in the composition of the present invention for obtaining translucency or transparency. The presence of water exerts the important effect required on the main solvent in order to obtain the transparency of the composition. The higher the water content, the greater the amount of main solvent (relative to the amount of softener) is required to obtain product transparency. Conversely, the lower the water content, the less main solvent (relative to the amount of softener) is required. As such, in a small amount of water from about 5% to about 15%, the softener activator: main solvent weight ratio is preferably from about 55:45 to about 85:15, more preferably from about 60:40 to about 80: 20 is. In an amount of water from about 15% to about 70%, the weight ratio of softener active agent to main solvent is preferably from about 45:55 to about 70:30, more preferably from about 55:45 to about 70:30. However, in large amounts of water from about 70% to about 80%, the weight ratio of softener active agent to main solvent is preferably from about 30:70 to about 55:45, more preferably from about 35:65 to about 45: 55. The greater the amount of water, the higher the softener: main solvent ratio.

Since one of the problems associated with large amounts of solvents is safety, mixtures of these main solvents are particularly preferred. The mixtures reduce the amount of either substance present. In particular, if one of the main solvents is volatile and / or has an odor (often a low molecular weight material), the odor and flame resistance can also be minimized by the compatibility of the mixture. Suitable solvents that can be used at concentrations not sufficient to produce a clear product include 2,2,4-trimethyl-1,3-pentanediol; Ethoxide, diethoxyde, or triethoxylate derivatives of 2,2,4-trimethyl-1,3-pentanediol; And / or 2-ethyl-1,3-hexanediol. For the purposes of the present invention, the solvents should only be used at concentrations which will not give a stable or transparent product. Preferred mixtures are those in which the majority of the solvent is one or more of those found to be most preferred above. In particular, when one or more preferred main solvents are solid at room temperature, the use of solvent mixtures is also preferred. In such cases, the mixtures are liquid or have a low melting point to improve the processability of the softener composition.

As long as the usable effective amount of the main solvent (s) of the present invention is still present in the liquid concentrate, transparent fabric softener composition, a part of the main solvent or main solvent mixture of the present invention can be used alone as the main solvent of the present invention. It has also been found that it is possible to substitute a second solvent which is not, or a mixture of second solvents. If at least about 15% of the softener active agent is also present, the effective amount of the main solvent (s) of the present invention is at least about 5%, preferably at least about 7%, more preferably at least about 10% of the composition. The substitution solvent (s) may be used at all concentrations but preferably up to the amount of usable main solvent present in the fabric softener composition and defined above.

For example, 1,2-pentanediol, 1,3-octanediol, and the following structural formula:

HO-CH ₂ -C (CH ₃ ) ₂ -CH ₂ -0-CO-C (CH ₃ ) ₂ -CH ₂ -OH (CAS # 1115-20-4)

Although hydroxy pivalyl hydroxy pivalate (hereinafter HPHP) having an unusable solvent according to the present invention, a mixture of the above solvents and the main solvent, for example, a preferred 1,2-hexanediol main solvent Mixtures with 1,2-hexanediol main solvent present in effective concentrations also provide a liquid, concentrated, transparent fabric softener composition.

Some of the secondary solvents that may be used are listed as unavailable as described above or below, as well as some parent nonalkoxylation solvents described in Tables 8a-8b.

The main solvent can be used to make the composition translucent or transparent, or the composition can be used to lower the translucent or transparent temperature. Thus, the present invention adds a main solvent at the concentrations indicated above to make the composition translucent or transparent in a composition that is not translucent or transparent or exhibits a temperature at which the instability is too high, or, for example, at ambient temperature, or in particular When the composition is transparent below the temperature, a method of lowering the temperature at which instability appears is preferably to about 5 ° C. or more, more preferably to about 10 ° C. or more. The main advantage of the main solvent is that it provides the maximum benefit for a given weight of solvent. As used herein, the 'solvent' relates to the effect of the main solvent and not to its physical form at a given temperature (some main solvents are solid at ambient temperature).

Alkyl lactate

Some alkyl lactate esters, such as ethyl lactate and isopropyl lactate, have ClogP values within the effective range of about 0.15 to about 0.64, and are concentrated transparent fabrics of liquids using the fabric softener activators of the present invention. Softener compositions may be formed but need to be used at slightly higher concentrations than effective diol solvents such as 1,2-hexanediol. They may also be used to substitute a portion of the other main solvents of the present invention to form a liquid concentrated concentrated fabric softener composition. The above is illustrated in Examples I-C.

New compounds

Some of the main solvents are novel compounds comprising:

1,2-butanediol, 2,3,3-trimethyl-; 3,4-pentanediol, 2,3-dimethyl-; 2,3-hexanediol, 4-methyl-; 2,3-hexanediol, 5-methyl-; 3,4-hexanediol, 2-methyl-; 3,4-pentanediol, 2,3-dimethyl-; 1,3-propanediol, 2- (1,1-dimethylpropyl)-; 1,3-propanediol, 2- (1,2-dimethylpropyl)-; 1,3-propanediol, 2- (2,2-dimethylpropyl)-; 1,3-butanediol, 2- (1-methylpropyl)-; 1,3-butanediol, 2-ethyl-2,3-dimethyl-; 1,3-butanediol, 2- (2-methylpropyl)-; 1,3-butanediol, 2-methyl-2-isopropyl-; 1,3-butanediol, 3-methyl-2-isopropyl-; 1,3-butanediol, 3-methyl-2-propyl-; 1,4-butanediol, 2,2-diethyl-; 1,4-butanediol, 2-methyl-2-propyl-; 1,4-butanediol, 2- (1-methylpropyl)-; 1,4-butanediol, 2-ethyl-2,3-dimethyl-; 1,4-butanediol, 2-ethyl-3,3-dimethyl-; 1,4-butanediol, 2- (2-methylpropyl)-; 1,4-pentanediol, 2,2,3-trimethyl-; 1,4-pentanediol, 2,3,3-trimethyl-; 1,5-pentanediol, 2,2,3-trimethyl-; 1,5-pentanediol, 2,3,3-trimethyl-; 1,3-pentanediol, 2-ethyl-2-methyl-; 1,4-pentanediol, 2-ethyl-2-methyl-; 1,4-pentanediol, 2-ethyl-3-methyl-; 1,4-pentanediol, 2-ethyl-4-methyl-; 1,4-pentanediol, 3-ethyl-2-methyl-; 1,4-pentanediol, 3-ethyl-3-methyl-; 1,5-pentanediol, 2-ethyl-2-methyl-; 1,5-pentanediol, 2-ethyl-4-methyl-; 2,4-pentanediol, 3-ethyl-2-methyl-; 1,3-pentanediol, 2-isopropyl-; 1,3-pentanediol, 2-propyl-; 1,4-pentanediol, 2-isopropyl-; 1,4-pentanediol, 2-propyl-; 1,4-pentanediol, 3-isopropyl-; 2,4-pentanediol, 3-propyl-; 1,3-hexanediol, 2,3-dimethyl-; 1,3-hexanediol, 2,5-dimethyl-; 1,3-hexanediol, 3,4-dimethyl-; 1,3-hexanediol, 3,5-dimethyl-; 1,3-hexanediol, 4,5-dimethyl-; 1,4-hexanediol, 2,2-dimethyl-; 1,4-hexanediol, 2,3-dimethyl-; 1,4-hexanediol, 2,4-dimethyl-; 1,4-hexanediol, 3,3-dimethyl-; 1,4-hexanediol, 3,4-dimethyl-; 1,4-hexanediol, 3,5-dimethyl-; 1,3-hexanediol, 4,4-dimethyl-; 1,4-hexanediol, 4,5-dimethyl-; 1,5-hexanediol, 2,2-dimethyl-; 1,5-hexanediol, 3,4-dimethyl-; 1,5-hexanediol, 3,5-dimethyl-; 1,5-hexanediol, 4,5-dimethyl-; 1,6-hexanediol, 2,3-dimethyl-; 1,6-hexanediol, 2,4-dimethyl-; 1,6-hexanediol, 3,3-dimethyl-; 2,4-hexanediol, 4,5-dimethyl-; 2,5-hexanediol, 2,3-dimethyl-; 2,5-hexanediol, 2,4-dimethyl-; 2,5-hexanediol, 3,3-dimethyl-; 2,6-hexanediol, 3,3-dimethyl-; 1,3-hexanediol, 4-ethyl-; 2,4-hexanediol, 3-ethyl-; 2,5-hexanediol, 3-ethyl-; 1,3-heptanediol, 4-methyl-; 1,3-heptanediol, 5-methyl-; 1,3-heptanediol, 6-methyl-; 1,5-heptanediol, 3-methyl-; 1,5-heptanediol, 4-methyl-; 1,6-heptanediol, 3-methyl-; 1,6-heptanediol, 5-methyl-; 2,4-heptanediol, 5-methyl-; 2,5-heptanediol, 3-methyl-; 3,5-heptanediol, 2-methyl-; 2,6-octanediol; 2,4-hexanediol, 3,3,4-trimethyl-; 2,4-hexanediol, 3,5,5-trimethyl-; 2,4-hexanediol, 4,5,5-trimethyl-; 2,5-hexanediol, 3,3,4-trimethyl-; 2,5-hexanediol, 3,3,5-trimethyl-; 1,2-propanediol, 3- (butyloxy)-, triethoxylated; 1,2-propanediol, 3- (butyloxy)-, tetraethoxylated; 1,2-propanediol, 3- (2-pentyloxy)-; 1,2-propanediol, 3- (3-pentyloxy)-; 1,2-propanediol, 3- (2-methyl-1 -butyloxy)-; 1,2-propanediol, 3- (iso-amyloxy)-; 1,2-propanediol, 3- (3-methyl-2-butyloxy)-; 1,2-propanediol, 3- (cyclohexyloxy)-; 1,2-propanediol, 3- (1-cyclohex-1-ethyloxy)-; 1,3-propanediol, 2- (pentyloxy)-; 1,3-propanediol, 2- (2-pentyloxy)-; 1,3-propanediol, 2- (3-pentyloxy)-; 1,3-propanediol, 2- (2-methyl-1 -butyloxy)-; 1,3-propanediol, 2- (iso-amyloxy)-; 1,3-propanediol, 2- (3-methyl-2-butyloxy)-; 1,3-propanediol, 2- (cyclohexyloxy)-; 1,3-propanediol, 2- (1-cyclohex-1-enyloxy)-; 1,2-propanediol, 3- (butyloxy)-, pentaethoxylated; 1,2-propanediol, 3- (butyloxy)-, hexaethoxylated; 1,2-propanediol, 3- (butyloxy)-, heptaethoxylation; 1,2-propanediol, 3- (butyloxy)-, octaethoxylation; 1,2-propanediol, 3- (butyloxy)-, nonaethoxylation; Bis (2-hydroxybutyl) ether; And bis (2-hydroxycyclopentyl) ether.

Similarly, the unsaturated analogs of the main solvents usable are novel, in particular unsaturated C _7-12 diols, more preferably unsaturated C _8-10 diols, with the exception of the specifically mentioned unsaturated diols listed in Table 9 above. have. Both main solvents provide the obscure benefits described below.

III. Random ingredient

(A) low molecular weight water soluble solvent

Low molecular weight water soluble solvents may also be used in amounts of from 0 to about 12%, preferably from about 1 to about 10%, more preferably from about 2 to about 8%. The water-soluble solvent may not provide a transparent product when used in the same amount as the above-described main solvent, but may provide a transparent product when the main solvent is insufficient to provide a completely transparent product. Therefore, the presence of the water soluble solvent is very desirable. The solvent includes ethanol, isopropanol, 1,2-propanediol, 1,3-propanediol, propylene carbonate and the like, but does not include any main solvent (B). The water soluble solvent has a better affinity for water in the presence of hydrophobic materials such as softener activator materials as compared to the main solvent.

(B) bleach

The compositions of the present invention may also optionally contain about 0.005 to 5% by weight of certain types of hydrophilic optical bleach that acts as a dye transfer inhibitor. When used, the composition of the present invention preferably contains about 0.001 to 1% by weight of the optical bleach.

Hydrophilic optical bleaches useful in the present invention have the formula:

Wherein R ₁ is selected from anilino, N-2-bis-hydroxyethyl and NH-2-hydroxyethyl, and R ₂ is N-2-bis-hydroxyethyl, N-2-hydroxy Selected from ethyl-N-methylamino, morpholino, chloro and amino, M is a salt-forming cation such as sodium or potassium.

In the above formula, when R ₁ is anilino, R ₂ is N-2-bis-hydroxyethyl, and M is a cation such as sodium, the bleaching agent is 4,4'-bis [(4-anilino- 6- (N-2-bis-hydroxyethyl) -s-triazin-2-yl) amino] -2,2'-stilbenedsulfonic acid and disodium salt. This particular bleach is marketed under the trade name Tinopal-UNPA-GX from Ciba-Geigy Corporation. Said Tinopal-UNPA-GX is a preferred hydrophilic optical bleach useful in the rinse-addition compositions herein.

In the above formula, when R ₁ is anilino, R ₂ is N-2-hydroxyethyl-N-2-methylamino, and M is a cation such as sodium, the bleaching agent is 4,4'-bis [( 4-anilino-6- (N-2-hydroxyethyl-N-methylamino) -s-triazin-2-yl) amino] -2,2'-stilbenedsulfonic acid disodium salt. This particular bleach is marketed under the trade name Tinopal-5BM-GX from Ciba Geigy Corporation.

In the above formula, when R ₁ is anilino, R ₂ is morpholino, and M is a cation such as sodium, the bleaching agent is 4,4'-bis [(4-anilino-6-morpholino- s-triazin-2-yl) amino] -2,2'-stilbenedsulfonic acid, sodium salt. This particular bleach is marketed under the trade name AMS-GX from Ciba-Geigy Corporation.

(C) dispersing aids

(J) any viscosity / dispersity modifier

Relatively concentrated compositions containing saturated and unsaturated diester ammonium compounds can be prepared stably without the addition of concentration aids. However, the compositions of the present invention may require organic and / or inorganic thickening aids to be performed at high concentrations and / or to meet high stability standards that depend on other ingredients. These thickening aids, which may be typical viscosity modifiers, may be needed, or to ensure stability under extreme conditions when certain softener activator concentrations are used. Surfactant concentration aids include (1) a single long chain alkyl cationic surfactant; (2) nonionic surfactants; (3) amine oxides; (4) fatty acids; And (5) mixtures thereof.

These adjuvants are disclosed in page 14, line 12 to page 20, line 12 of Pending Application Serial No. 08 / 461,207 (June 5, 1995) (Wahl et al.) To P & G, which is incorporated herein by reference. It is.

When present, the dispersing aid is, based on the weight of the composition, in total, typically from about 2 to about 25%, preferably from about 3 to about 17%, more preferably from about 4 to about 15%, more More preferably from about 5 to about 13%.

These materials are added as part of the reactant softener activator raw material (Formula 1) used for forming the biodegradable fabric softener activator as described above, for example as long chain monoalkyl cationic surfactants and / or fatty acids. Or as separate components. The total amount of dispersing aid includes any amount that may be present as part of component (Formula 1).

(1) Monoalkyl Cationic Quaternary Ammonium Compounds

When present, the monoalkyl cationic quaternary ammonium compound, based on the weight of the composition, is typically about 2 to about 25%, preferably about 3 to about 17%, more preferably about 4 to about 15 %, And even more preferably in an amount of about 5 to about 13%, and the total monoalkyl cationic quaternary ammonium compound is at least an effective amount.

Said monoalkyl cationic quaternary ammonium compounds useful in the present invention are preferably quaternary ammonium salts having the general formula:

[R ⁴ N ⁺ (R ⁵ ) ₃ ] X ^-

In the above formula,

R ⁴ is a C _8-22 alkyl or alkenyl group, preferably a C _10-18 alkyl or alkenyl group, more preferably a C _10-14 or C _16-18 alkyl or alkenyl group;

Each R ⁵ represents a C _1-6 alkyl or substituted alkyl group (eg hydroxyalkyl group), preferably a C _1-3 alkyl group (eg methyl (most preferred), ethyl, propyl group, etc.), benzyl group, Hydrogen, polyethoxylate chains having about 2 to about 20 oxyethylene units, preferably about 2.5 to about 13 oxyethylene units, more preferably about 3 to about 10 oxyethylene units, and mixtures thereof And;

X ⁻ is as defined for Formula 1 above.

Particularly preferred dispersing aids are monolauryl trimethyl ammonium chloride and monoresin trimethyl ammonium chloride sold under the trade name Varisoft 471 by Witco, and monooleyl trimethyl ammonium chloride sold by Witco under the trade name Varisoft 417.

The R ⁴ group may also be bonded to the cationic nitrogen atom via a group containing one or more esters, amides, ethers, amines and the like which may be desirable for increasing the concentration of the component (I). Such bond groups are preferably nitrogen atoms having from about 1 to about 3 carbon atoms.

The monoalkyl cationic quaternary ammonium compounds also include C _8-22 alkyl chlorine esters. Preferred dispersing aids of this type have the formula:

R ^One C (O) -O-CH ₂ CH ₂ N ⁺ (R) ₃ X ^-

Wherein R ¹ , R and X ⁻ are as defined above.

Highly preferred dispersion aids include C _12-14 coco chlorine esters and C _16-18 resin chlorine esters.

Suitable biodegradable single long chain alkyl dispersion aids containing ester linkages in the long chain are disclosed in US Pat. No. 4,840,738 (June 20, 1989) (Hardy and Walley), which is incorporated herein by reference.

If the dispersing aid comprises an alkyl chlorine ester, preferably the composition also contains a small amount, preferably about 2 to about 5%, of organic acid, by weight thereof. Such organic acids are disclosed in European Patent Application No. 404,471 (December 27, 1990) (Machin et al.), Incorporated herein by reference. Preferably, the organic acid is selected from the group consisting of glycolic acid, acetic acid, citric acid and mixtures thereof.

Ethoxylated quaternary ammonium compounds that can serve as dispersion aids include ethylbis (polyethoxy ethanol) alkylammonium ethyl-sulfate (available under the trade name Variquat 66 from Sherex Chemical Company) with 17 moles of ethylene oxide; Polyethylene glycol (15) oleammonium chloride (available under the trade name Ethoquad O / 25 from Akzo); And polyethylene glycol (15) cocomonium chloride (available under the trade name Ethoquad C / 25 from Akzo).

The main function of the dispersing aid is to improve the dispersibility of the ester softener, but preferably the dispersing aid of the invention also has some softening properties to increase the softening performance of the composition. Therefore, it is preferable that the composition of the present invention does not contain a non-nitrogen ethoxylated nonionic dispersing aid which essentially lowers its overall softening performance.

In addition, quaternary compounds having only one long alkyl chain may protect the cationic softener by interacting with a detergent forming agent and / or anionic surfactant carried over from the wash solution to the rinse.

(2) amine oxide

Suitable amine oxides include about C ₈ to about C ₂₂ , preferably about C ₁₀ to about C ₁₈ , more preferably about C ₈ to about C ₁₄ , one alkyl or hydroxyalkyl moiety, and about C ₁ to And those having two alkyl moieties selected from the group consisting of alkyl groups and hydroxyalkyl groups of about C ₃ .

Examples thereof include dimethyloctylamine oxide, diethyldecylamine oxide, bis- (2-hydroxyethyl) dodecyl-amine oxide, dimethyldodecylamine oxide, dipropyltetradecylamine oxide, methylethylhexadecylamine oxide, Dimethyl-2-hydroxyoctadecylamine oxide and coco fatty alkyl dimethylamine oxide.

(D) stabilizer

Stabilizers may be present in the compositions of the present invention. 'Stabilizers' herein include antioxidants and reducing agents. These additives are present in an amount of from 0 to about 2%, preferably from about 0.01 to about 0.2%, more preferably from about 0.035 to about 0.1% of antioxidant and from about 0.01 to about 0.2% of reducing agent. do. They ensure good odor stability under prolonged storage conditions. Antioxidants and reduction stabilizers are particularly important in products that are malodorous or low in odor (products with low or no odor).

Examples of antioxidants that may be added to the compositions of the present invention include mixtures of ascorbic acid, ascorbic palmitate, propyl gallate (available under the trade names Tenox PG and Tenox S-1 from Eastman Chemical Products, Inc.); Mixtures of BHT (butylated hydroxytoluene), BHA (butylated hydroxyanisol), propyl gallate and citric acid (available under the trade name Tenox-6 from Eastman Chemical Products, Inc.); Butylated hydroxytoluene (available under the trade name Sustane BHT from UOP Process Division); Tertiary butylhydroquinone (available under the trade name Tenox TBHQ from Eastman Chemical Products, Inc.); Natural tocopherols (available under the trade name Tenox GT-1 / GT-2 from Eastman Chemical Products, Inc.); And butylated hydroxyanisole (available under the trade name BHA from Eastman Chemical Products, Inc.); Long chain esters of gallic acid (C _8-22 ), for example dodecyl gallate; Irganox ™ 1010; Irganox ™ 1035; Irganox® B 1171; Irganox ™ 1425; Irganox ™ 3114; Irganox ™ 3125, and mixtures thereof; Preferably Irganox ™ 3125; Irganox ™ 1425; Irganox ™ 3114, and mixtures thereof; More preferably Irganox® 3125 alone or in combination with citric acid and / or other chelating agents such as isopropyl citrate, Dequest® 2010 (available from Monsanto, chemical name: 1-hydroxyethylidene- 1,1-diphosphoric acid (ethedronic acid)), Tiron (trade name) (available from Kodak, chemical name: 4,5-dihydroxy-m-benzenesulfonic acid / sodium salt), and DTPA (trade name) (available from Aldrich) , Chemical name: diethylenetriaminepentaacetic acid). The chemical names and CAS No. of some of these stabilizers that may be used in the compositions of the invention. Is shown in Table 1 below.

(E) Soil Release Agent

In the present invention, any dirt removal agent can be added. The addition of the dirt remover may occur prior to or after the addition of the electrolyte, or after the final composition has been prepared, in combination with the premix, in combination with the acid / water seat. The flexible composition prepared by the process of the present invention may contain from 0 to about 10%, preferably 0.2 to about 5% of said dirt remover. Preferably the dirt remover is a polymer. Polymeric dirt removers useful in the present invention include block copolymers of terephthalate and polyethylene oxide or polypropylene oxide.

Preferred dirt removers are copolymers having terephthalate and polyethylene oxide blocks. More specifically, these polymers consist of 25:75 to about 35:65 molar ratios of ethylene terephthalate units and polyethylene oxide terephthalate units, and the polyethylene oxide terephthalate having the polyethylene oxide block has a molecular weight of about 300 to about 2,000. . The molecular weight of the polymeric dirt remover ranges from about 5,000 to about 55,000.

Another preferred polymeric dirt remover is about 10 to about 15 weight percent of ethylene terephthalate units with about 10 to about 50 weight percent of polyoxyethylene terephthalate units derived from polyoxyethylene glycols having an average molecular weight of about 300 to about 6,000. Is a crystalline polyester containing as a repeating unit, and the molar ratio of ethylene terephthalate units to polyoxyethylene terephthalate units in the crystalline polymer compound is 2: 1 to 6: 1. Examples of such polymers are the commercially available materials Zelcon 4780 (trade name) (Dupont) and Milease T (trade name) (IC).

Very preferred dirt removers are polymers having the formula:

Wherein each X may be a suitable capping group and is typically selected from the group consisting of H and from about C ₁ to about C ₄ alkyl or acyl groups; p is selected for water solubility and is usually about 6 to about 113, preferably about 20 to about 50; u is important for the preparation of liquid compositions having relatively high ionic strength.

There should be very few substances with u greater than 10. In addition, materials with u of about 3 to about 5 should be at least about 20%, preferably at least about 40%.

The R ¹⁴ moiety is basically a 1,4-phenylene moiety. Wherein the 'R ¹⁴ moiety is essentially a 1,4-phenylene moiety' means that the R ¹⁴ moiety consists entirely of 1,4-phenylene moiety, or other arylene or alxarylene moieties, alkylene moieties, A compound partially substituted by an alkenylene moiety or a mixture thereof. Arylene and alxarylene moieties that may be partially substituted for 1,4-phenylene include 1,3-phenylene, 1,2-phenylene, 1,8-naphthylene, 1,4-naphthylene , 2,2-biphenylene, 4,4-biphenylene and mixtures thereof. Alkylene and alkenylene moieties that may be partially substituted include 1,2-propylene, 1,4-butylene, 1,5-pentylene, 1,6-hexamethylene, 1,7-heptamethylene, 1, 8-octamethylene, 1,4-cyclohexylene and mixtures thereof.

In the R ¹⁴ moiety, the degree of partial substitution by parts other than 1,4-phenylene should be such that the dirt removal property of the compound is not significantly affected. Typically, the degree of allowable partial substitution depends on the backbone length of the compound. That is, the longer backbone has a greater degree of partial substitution for the 1,4-phenylene moiety. Typically, compounds in which the R ¹⁴ moiety contains about 50 to about 100% of the 1,4-phenylene moiety (0 to about 50% for moieties other than 1,4-phenylene) have adequate dirt removal activity. For example, polyesters having a molar ratio of 40:60 isophthalic (1,3-phenylene) acid to terephthal (1,4-phenylene) acid, prepared according to the present invention, have adequate dirt removal activity. . However, since most polyesters used in fiber production contain ethylene terephthalate units, it is usually desirable to minimize the degree of partial substitution by parts other than 1,4-phenylene for the best dirt removal activity. . Preferably, the R ¹⁴ moiety consists entirely of (ie 100%) 1,4-phenylene moiety. That is, each R ¹⁴ moiety is 1,4-phenylene.

In the R ¹⁵ moiety, suitable ethylene or substituted ethylene moieties include ethylene, 1,2-propylene, 1,2-butylene, 1,2-hexylene, 3-methoxy-1,2-propylene and these There is a mixture of. Preferably, the R ¹⁵ moiety is basically an ethylene moiety, a 1,2-propylene moiety or a mixture thereof. Inclusion of higher proportions of ethylene portion tends to increase the dirt removal activity of the compound. Surprisingly, the inclusion of higher proportions of 1,2-propylene moieties tends to increase the water-solubility of the compounds.

Therefore, the use of 1,2-propylene moieties or similar branched equivalents is preferred for incorporating any substantial amount of dirt removal component into the liquid fabric softener composition. Preferably, about 75 to about 100% is a 1,2-propylene moiety.

Each p value is at least about 6, and preferably at least about 10. Each n value typically ranges from about 12 to about 113. Typically, each p value ranges from about 12 to about 43.

A more detailed description of the dirt remover is described in U.S. Patent Nos. 4,661,267 (Decker, Konig, Straathof and Gosselink) (April 28, 1987) and 4,711,730 (Gosselink and Diehl) (December 1987) 8), 4,749,596 (Evans, Huntington, Stewart, Wolf and Zimmerer) (June 7, 1988), 4,818,569 (Trinh, Gosselink and Rattinger) (4 April 1989), 4,877,896 (4) Maldonado, Trinh and Gosselink (October 31, 1989), 4,956,447 (Gosselink et al.) (September 11, 1990) and 4,976,879 (Maldonado, Trinh and Gosselink) (December 11, 1990). Is disclosed.

The dirt remover may also act as tailings dispersant.

(F) tailings dispersant

In the present invention, the preliminary mixture can be heated at a melting point or higher of the components after being combined with any tailings dispersant, rather than a dirt remover.

Preferred tailings dispersants herein are formed by highly ethoxylating hydrophobic materials. The hydrophobic material can be a fatty alcohol, a fatty acid, a fatty amine, a fatty acid amide, an amine oxide, a quaternary ammonium compound, or a hydrophobic portion used to form a dirt removal polymer. The preferred tailings dispersant is highly ethoxylated. That is, the tailings dispersant contains, on average, at least about 17 moles, preferably at least about 25 moles, more preferably at least about 40 moles of ethylene oxide per molecule, and the proportion of polyethylene oxide is about about the total weight of the molecule. 76 to about 97%, preferably about 81 to about 94%.

The concentration of tailings dispersant is sufficient to maintain the tailings in an amount acceptable to the consumer, preferably unacceptable to the consumer, under conditions of use, but not to adversely affect the softening. For some purposes, it is desirable that no tailings exist. Depending on the amount of anionic or nonionic detergent used in the washing cycle of a conventional laundry process, the efficiency of the rinsing step prior to injecting the composition of the present invention, and the water-hardness, anionic added to the fabric (laundry) or The amounts of nonionic detergent surfactants and detergent formers (particularly phosphates and zeolites) vary. In general, a minimum amount of tailings dispersant should be used to avoid adversely affecting the casting properties. Typically, at least about 2%, preferably at least about 4% (due to at least 6% and preferably at least 10%) tailings dispersant, relative to the amount of softener activator, is required. However, when the amount is about 10% or more (relative to the softener material), there is a risk that the softening efficacy of the product is lost, especially if the fabric contains a high proportion of nonionic surfactant absorbed during the washing operation.

Preferred tailings dispersants are Brij 700 (trade name), Varonic U-250 (trade name), Genapol T-500 (trade name), Genapol T-800 (trade name), Plurafac A-79 (trade name) and Neodol 25-50 (trade name). .

(G) fungicide

Examples of fungicides used in the compositions of the present invention include glutaraldehyde, formaldehyde, 2-bromo-2-nitro-propane-1,3-diol (trade name Bronopol® from Inolex Chemicals, Philadelphia, PA). Commercially available), and a mixture of 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin-3-one (trade name Kathon® in the Rohm and Haas Company). Commercially available) and they are present in amounts of about 1 to about 1,000 ppm by weight.

(H) fragrance

The present invention may contain any perfume that is compatible with the softening agent. Suitable perfumes are disclosed in US Pat. No. 5,500,138 (Bacon et al.) (March 19, 1996), which is incorporated herein by reference.

The fragrances used in the present invention include natural fragrance substances (i.e., flowers, grasses, leaves, roots, bark, trees, seed plants or substances obtained by extraction of plants), artificial fragrance substances (e.g. different natural oils or Mixtures of oil components) and mixtures or fragrances of substances, including synthetic fragrances (ie, synthetically prepared substances). Such materials are often obtained by auxiliary substances such as fixers, extenders, stabilizers and solvents. These adjuvants are also included in the sense of the perfume of the present invention. Typically, the fragrance is a complex mixture of a plurality of organic compounds.

Perfumes useful in the compositions of the present invention include, but are not limited to:

Hexyl cinnamic aldehyde; Amyl cinnamic aldehyde; Amyl salicylate; Hexyl salicylate; Terpinol; 3,7-dimethyl-cis-2,6-octadien-1-ol; 2,6-dimethyl-2-octanol; 2,6-dimethyl-7-octen-2-ol; 3,7-dimethyl-3-octanol; 3,7-dimethyl-trans-2,6-octadien-1-ol; 3,7-dimethyl-6-octen-1-ol; 3,7-dimethyl-1-octanol; 2-methyl-3- (p-t-butylphenyl) -propionaldehyde; 4- (4-hydroxy-4-methylpentyl) -3-cyclohexene-1-carboxaldehyde; Tricyclodecenyl propionate; Tricyclodecenyl acetate; Anisealdehyde; 2-methyl-2- (p-iso-propylphenyl) -propionaldehyde; Ethyl-3-methyl-3-phenyl glycidate; 4- (p-hydroxyphenyl) -butan-2-one; 1- (2,6,6-trimethyl-2-cyclohexen-1-yl) -2-buten-1-one; p-methoxyacetophenol; p-methoxy-alpha-phenylpropene; Methyl-2-n-hexyl-3-oxo-cyclopentane carboxylate; Undecaractone gamma.

Additional examples of perfume materials include, but are not limited to:

Orange oil, lemon oil, grapefruit oil, bergamot oil, clove oil; Dodecaractone gamma; Methyl-2- (2-pentyl-3-oxo-cyclopentyl) acetate; Beta-naphthol methylether, methyl-beta-naphthylketone; Coumarin; Decylaldehyde; Benzaldehyde; 4-t-butylcyclohexyl acetate; Alpha, alpha-dimethylphenethyl acetate; Methylphenylcarvinyl acetate; Ship bases of 4- (4-hydroxy-4-methylpentyl) -3-cyclohexene-1-carboxaldehyde and methyl anthranilate; Cyclic ethylene glycol diesters of tridecanedioic acid; 3,7-dimethyl-2,6-octadiene-1-nitrile; Ionone gamma methyl; Ionone alpha; Ionone beta; Petite grains; Methyl cedrone; 7-acetyl-1,2,3,4,5,6,7,8-octahydro-1,1,6,7-tetramethyl-naphthylene; Ionone methyl; Methyl-1,6,10-trimethyl-2,5,9-cyclododecatrien-1-yl ketone; 7-acetyl-1,1,3,4,4,6-hexamethyl tetralin; 4-acetyl-6-t-butyl-1,1-dimethyl indane; Benzophenones; 6-acetyl-1,1,2,3,3,5-hexamethyl indane; 5-acetyl-3-isopropyl-1,1,2,6-tetramethyl indane; 1-dodecanal; 7-hydroxy-3,7-dimethyl octanal; 10-undecen-1-al; Iso-hexenyl cyclohexyl carboxaldehyde; Formyl tricyclodecane; Cyclopentadedecanoid; 1,6-hydroxy-9-hexadecenoic acid lactone; 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylcyclopenta-gamma-2-benzopyran; Ambroxane; Dodecahydro-3a, 6,6,9a-tetramethylnaphtho [2,1b] furan; Cedrol; 5- (2,2,3-trimethylcyclopent-3-enyl) -3-methylpentan-2-ol; 2-ethyl-4- (2,2,3-trimethyl-3-cyclopenten-1-yl) -2-buten-1-ol; Cariophyllene alcohol; Cedryl acetate; p-t-butylcyclohexyl acetate; Part cowl; Olivanum fpsinoids; Lavdanum; Betty butt; Copaiba balsam; Fur balsam; And hydroxycitronellal and methyl anthranilate; Hydroxycitronellal and indole; Phenyl acetaldehyde and diols; Condensate of 4- (4-hydroxy-4-methyl pentyl) -3-cyclohexene-1-carboxytmaldehyde with methyl anthranilate.

More examples of perfume ingredients are as follows:

Geraniol; Geranyl acetate; Linalool; Linalyl acetate; Tetrahydrolinalol; Citronellol; Citronelyl acetate; Dihydromirsenol; Dihydromyrsenyl acetate; Tetrahydromirsenol; Terfinyl acetate; Nopol; Nofil acetate; 2-phenylethanol; 2-phenylethyl acetate; Benzyl alcohol; Benzyl acetate; Benzyl salicylate; Benzyl benzoate; Styralyl acetate; Dimethylbenzylcarbinol; Trichloromethylphenylcarvinyl methylphenylcarvinyl acetate; Isononyl acetate; Betiberyl acetate; Vetiberol; 2-methyl-3- (p-t-butylphenyl) -propanal; 2-methyl-3- (p-isopropylphenyl) -propanal; 3- (p-t-butylphenyl) -propanal; 4- (4-methyl-3-pentenyl) -3-cyclohexenecarbaldehyde; 4-acetoxy-3-pentyltetrahydropyran; Methyl dihydrojasmonate; 2-n-peptylcyclopentanone; 3-methyl-2-pentyl-cyclopentanone; n-decanal; n-dodecanal; 9-desenol-1; Phenoxyethyl isobutyrate; Phenylacetalaldehyde dimethylacetal; Phenylacetalaldehyde diethyl acetal; Geranonitrile; Citronellonitrile; Cydrill acetal; 3-isocamphorcyclohexanol; Cedryl methyl ether; Isonyl polanone; Aubepin nitrile; Aubepin; Heliotropin; Eugenol; vanillin; Diphenyl oxide; Hydroxycitronellal ionone; Methyl ionone; Isomethyl ionomer; Iron; Cis-3-hexenol and esters thereof; Indan musk flavoring; Tetralin musk flavoring; Isocroman Musk flavors; Macrocyclic ketones; Macrolactone musk fragrances; Ethylene brasylate.

Perfumes useful in the present invention are substantially free of halogenated materials and nitromusks.

Solvents suitable for the aforementioned perfume components; Diluents or carriers are, for example, ethanol, isopropanol, diethylene glycol, monoethyl ether, dipropylene glycol, diethyl phthalate, triethyl citrate and the like. The amount of said solvent, diluent or carrier in combination with the perfume is preferably kept to the minimum required to provide a uniform perfume solution.

The fragrance is present from 0% to about 10%, preferably from about 0.1% to about 5%, more preferably from about 0.2% to about 3% of the final composition. The fabric softening composition of the present invention provides improved fabric perfume deposition.

(I) Chelating Agent

The compositions and methods of the present invention may optionally use one or more copper and / or nickel chelating agents, in addition to the chelating agents that are part of the stabilizer. The water soluble chelating agent may be selected from the group consisting of amino carboxylates, amino phosphonates, multifunctional-substituted aromatic chelating agents and mixtures thereof, and all described below. The whiteness and / or lightness of the fabric is sufficiently improved or restored by the chelating agent and the stability of the material in the composition is improved.

Amino carboxylates useful as chelating agents in the present invention include ethylenediaminetetraacetate (EDTA), N-hydroxyethylethylenediaminetriacetate, nitrilotriacetate (NTA), ethylenediamine tetrapropionate, ethylenediamine-N, N'-diglutamate, 2-hydroxypropylenediamine-N, N'-disuccinate, triethylenetetraaminehexaacetate, diethylenetriaminepentaacetate (DETPA) and ethanol diglycine, and also their water-soluble salts (Such as alkali metal salts, ammonium salts and substituted ammonium salts) and mixtures thereof.

In addition, when at least a small amount of total phosphorus is allowed in the detergent composition, amino phosphonates are also suitable for use as chelating agents in the compositions of the invention, such as ethylenediaminetetrakis (methylenephosphonate), diethylene Triamine-N, N, N ', N', N'-pentakis (methane phosphonate) (DETMP) and 1-hydroxyethane-1,1-diphosphonate (HEDP). Preferably, these amino phosphonates do not contain alkyl or alkylene groups of at least about C ₆ .

The chelating agent is used in the rinsing process of the present invention, typically in an amount of about 2 to about 25 ppm during soaking of 1 minute to several hours or less.

Preferred EDDS (also known as ethylenediamine-N, N'-disuccinate) chelating agents used in the present invention are the materials disclosed in U.S. Patent No. 4,704,233, cited above, and are shown in the following formula (free acid form) Has:

As disclosed in this patent, EDDS can be prepared using maleic anhydride and ethylenediamine. Preferred biodegradable [S, S] isomers of EDDS can be prepared by reacting L-aspartic acid with 1,2-dibromoethane. The EDDS is effective in chelating copper and nickel cations, is available in biodegradable form, and has advantages over other chelating agents in that it does not contain phosphorus. EDDS used as a chelating agent in the present invention is typically in the form of a salt in which at least one of the four acidic hydrogens is replaced with a water soluble cation M such as sodium, potassium, ammonium, triethanol ammonium or the like. As mentioned above, EDDS chelating agents are also used in the rinsing process of the present invention, typically in amounts of about 2 to about 25 ppm during soaking of 1 minute to several hours or less. At certain pH, EDDS is preferably used in combination with zinc cations.

As can be seen from the foregoing, a wide range of chelating agents can be used in the present invention. Indeed, while not as effective as amino carboxylates and phosphonates, simple polycarboxylates such as citrate, oxydisuccinate and the like can also be used based on weight. Therefore, due to the different degree of chelating effect, the amount of use can be adjusted. The chelating agent of the present invention has a stabilization constant of (fully ionized chelating agent) for copper ions of about 5 or more, preferably about 7 or more. Typically, the chelating agent constitutes from about 0.5 to about 10%, more preferably from about 0.75 to about 5% of the weight of the composition of the present invention in addition to the chelating agent in the stabilizer. Preferred chelating agents are DETMP, DETPA, NTA, EDDS and mixtures thereof.

(J) other optional ingredients

The present invention relates to any component conventionally used in textile treatment compositions, such as colorants, preservatives, surfactants, antishrinkants, fabric softeners, drops, fungicides, fungicides, antioxidants (e.g. butylated hydroxytoluene ), Corrosion inhibitors and the like.

Particularly preferred components include water soluble calcium and / or magnesium compounds that provide additional stability. Chloride salts are preferred, but salts such as acetates, nitrates and the like can be used. The amount of calcium and / or magnesium salt is from 0 to about 2%, preferably from about 0.05 to about 0.5%, more preferably from about 0.1 to about 0.25%.

The present invention also discloses pending application serial numbers 08 / 372,068 (Rusche et al., Jan. 12, 1995), 08 / 372,490 (Shaw et al.), Jan. 12, 1995, which is incorporated herein by reference. ) And other compatible ingredients, including those disclosed in US 08 / 277,558 (Hartman et al., July 19, 1994).

Preparation of main solvent

Preparation of Diol Main Solvent

Many synthetic methods can be used to prepare the main diol solvent of the present invention. Appropriate methods are selected according to the specific structural requirements of each of the main solvents. Moreover, most major solvents can also be prepared by one or more methods. Therefore, the methods cited herein for each particular main solvent are for illustrative purposes only and are not intended to be limiting.

Method A

Preparation of 1,5-, 1,6-, and 1,7-diols

Method 1

This synthetic method is a general method for preparing α, ω-type diols derived from substituted cyclic alkenes. Examples of cyclic alkenes are the alkylated isomers of cyclopentene, cyclohexene, and cycloheptene. General formulas of useful alkylated cyclic alkenes are:

Wherein each R is H, or C ₁ -C ₄ -alkyl and x is 3, 4 or 5.

Cyclic alkenes can be converted to terminal diols by a three step reaction sequence.

Step 1 is to react cyclic alkenes and ozone (O ₃ ) in a solvent such as anhydrous ethyl acetate to form an intermediate ozonate. Step 2 is to reduce the ozonate, for example by palladium catalyst / H ₂ to form dialdehyde, which is converted to the desired diol by borohydride reduction in step 3.

1,2-diol is generally prepared by direct hydroxylation of suitably substituted olefins. For example:

[Wherein each R is H, alkyl or the like]

In a typical reaction, alkenes are reacted with hydrogen peroxide (30%) and a catalytic amount of osmium tetraoxide in t-butyl alcohol or other suitable solvent. The reaction is cooled to about 0 ° C. and left overnight. Unreacted compounds and solvents are removed by distillation and the desired 1,2-diol is isolated by distillation or crystallization.

Method 2 An alternative method is to convert olefins to epoxides by reaction of m-chloroperbenzoic acid, or peracetic acid, in a solvent such as methylene chloride at a temperature below about 25 ° C. Epoxides produced by this chemistry are then hydrolyzed to diol, for example by dilute sulfuric acid.

Step 3 forms the desired diol by borohydride reduction.

Method 3

An alternative method for preparing these compounds is to directly hydroxylate hydrogen peroxide and catalytic amounts of osmium tetraoxide and cyclic alkenes. The reaction produces cyclic diols which are converted to open chain dialdehydes by periodate or lead tetraacetate. The dialdehyde is then reduced to borohydride as in Method 1 to produce the desired 1,5- or 1,6-diol and the like.

Method B

Preparation of 1,2-diols

Method 1

Method C

Preparation of 1,3-diols

Acylation of Enamines

This method of preparation relates to the general form of 1,3-diol and accommodates various structural features. Enamines are formed from both ketones and aldehydes and react with acid chlorides to form acylated products. Acylated amine derivatives are hydrolyzed to their acylated carbonyl compounds, which are 1,3-dicarbonyl precursors to the desired 1,3-diol. Diols are produced by borohydride reduction of 1,3-dicarbonyl compounds.

Thus acetaldehyde (aldehydes) can be heated to reflux in a solvent such as toluene and reacted with a catalytic amount of p-toluene sulfonic acid and secondary amines, preferably cyclic amines such as pyrrolidine or morpholine. As the amine reacts (condenses) with the carbonyl compound, water is produced which is removed, for example, by reflux through a water trap. After removing the theoretical amount of water, the reaction mixture is removed if necessary (acylation can in most cases be carried out in the same solvent system), for example by stripping under vacuum to remove the solvent.

Crude anhydrous enamines containing some excess amine react with an appropriate acid chloride at about 20 ° C. to produce acylated enamines. This reaction is generally allowed to stir overnight at room temperature. The entire reaction mixture is then poured onto crushed ice and stirred and the mixture is made acidic with 20% HCl. This treatment hydrolyzes the enamine to an acylated dicarbonyl compound. The intermediate is then isolated by distillation to remove the extraction and low boiling impurities, which is then reduced to sodium borohydride to produce the desired 1,3-diol.

Method D

Preparation of 1,4-diol by Aldol Condensation and Reduction

Typical reactions include one or more aldehydes, one or more ketones and mixtures thereof, which have one or more alpha hydrogen atoms in the carbon atoms in contact with the carbonyl group. Typical examples of some reactants and some potential end products are:

2R-CH ₂ -CHO → HO-CH ₂ -CH (R) -CHOH-CH ₂ -R

R-CH ₂ -CHO + R'-CH ₂ -CHO → HO-CH ₂ -CH (R) -CHOH-CH ₂ -R +

HO-CH ₂ -CH (R ')-CHOH-CH ₂ -R' +

HO-CH ₂ -CH (R ')-CHOH-CH ₂ -R +

HO-CH ₂ -CH (R) -CHOH-CH ₂ -R '

R-CH ₂ -CHO + R'-CO-CH ₃ → HO-CH ₂ -CH (R) -CHOH-CH ₂ -R +

R-CH ₂ -CHOHCH ₂ -CHOH-R '

The aldehydes, ketones, or mixtures thereof to be condensed are placed in an autoclave under an inert atmosphere with a solvent such as butanol or a phase transfer medium such as polyethylene glycol. When mixed condensation of ketones with aldehydes is desired, typically both reactants are used in a molar ratio of about 1: 1. A catalytically strong alkaline catalyst, such as sodium methoxide, is typically added in an amount of about 0.5-10 mole% of the reactants. The autoclave is sealed and the mixture is heated at about 35-100 ° C., typically from about 5 minutes to about 3 hours, until most of the raw reactants are converted. The crude mixture is neutralized and the carbonyl functional groups present are reduced by hydrogenation on Raney Ni at about 100 ° C. and about 50 atmospheres for about 1 hour. The volatile components are removed by distillation and the desired diol main solvent is obtained by vacuum distillation.

Further information on this method of preparation is described in Synthesis, (3), 164-5 (1975), A. Porcini and al. Ungaro]; PCT International Application WO 9,507,254, Kulmala et al., March 16, 1995; Japanese Patent Application No. 40,333, Sato et al., February 9, 1990; Japanese Patent Application No. 299,240, Sato et al., December 4, 1989; European Patent Application No. 367,743, Anchner et al., May 9, 1990; All of these documents and patents are incorporated herein by reference.

General Example:

Condensation of butyraldehyde and / or isobutyraldehyde and conversion to form 8-carbon-1,3-diol

Sodium is dissolved in some n-butanol (about 148 g, about 2 moles, Aldrich) in a 500 ml three-neck round bottom flask with a stir bar, internal thermometer, cooler, and connections for blanketing into a nitrogen atmosphere. Until treated with metal sodium (about 2.3 g, about 0.1 mol, Aldrich). Then, a mixture of butyraldehyde (about 72 g, about 1 mole, Aldrich) and isobutyraldehyde (about 72 g, about 1 mole, Aldrich) is added and the system is about 40 ° C. until most of the initial aldehyde has proceeded to the reaction. To keep. The base catalyst is neutralized by the careful addition of sulfuric acid, the salt is removed by filtration, and the solution is hydrogenated over Raney Ni at about 100 ° C. at a pressure of about 50 atm to give 8-carbon-1,3-diol Produces a mixture. Butanol solvent and isobutanol formed during hydrogenation were removed by distillation to give 2,2,4-trimethyl-1,3-pentanediol; 2-ethyl-1,3-hexanediol; 2,2-dimethyl-1,3-hexanediol; And an 8-carbon-1,3-diol mixture of 2-ethyl-4-methyl-1,3-pentanediol. If desired, these mixtures are further purified by vacuum distillation or by decolorizing with activated carbon. The recovered solvent is used for further batches of diol preparation.

When butyraldehyde alone is used in the reaction, the main product obtained is 2-ethyl-1,3-hexanediol.

When only isobutyraldehyde is used in the reaction, the main product obtained is 2,2,4-trimethyl-1,3-pentanediol.

Mixed condensation of butyraldehyde and methyl ethyl ketone and conversion to form an 8-carbon-1,3-diol mixture

Conditions A. Some sodium n-butanol (about 148 g, about 2 moles, Aldrich) in a 500 ml three-necked round bottom flask with a stir bar, an internal thermometer, a cooler, and a connection for blanketing into the nitrogen atmosphere was dissolved in sodium. Treat with metal sodium (about 2.3 g, about 0.1 mole, Aldrich) until all are dissolved. Then, a mixture of butyraldehyde (about 72 g, about 1 mole, Aldrich) and 2-butanone (about 72 g, about 1 mole, Aldrich) is added and the system is about 40 until most of the initial aldehyde has proceeded. Keep at ℃. The base catalyst is neutralized by the careful addition of sulfuric acid and the salts are removed by filtration. If desired, unreacted starting material is removed by distillation with the reaction solvent. The mixture containing the condensation product was hydrogenated on Raney Ni at about 100 ° C. and about 50 atm for about 1 hour to yield 2-ethyl-1,3-hexanediol, 2-ethyl-3-methyl-1,3-pentanediol, Mixtures of 8-carbon-1,3-diol containing 3,5-octanediol, 3-methyl-3,5-heptanediol; And small amounts of 1,3-diol isomers such as 3-methyl-2,4-heptanediol and 3,4-dimethyl-2,4-hexanediol. The crude diol mixture can be further purified by fractional distillation.

Condition B. The reaction is repeated except for 2 moles of butyraldehyde for each mole of 2-butanone. The result is self-condensation of aldehydes (eg 2-ethyl-1,3-hexanediol), and aldehydes and 2-butanone (eg 2-ethyl-3-methyl-1,3-pentanediol and 3,5- A high proportion of diols resulting from mixed condensation of octanediol, and self-condensation of 2-butanone (eg, 3-methyl-3,5-heptanediol and 3,4-dimethyl-2,4-hexanediol) A lower proportion of diol produced in the soot is produced as reaction product.

Conditions C. The condensation is repeated except that about 1 mole of 2-butanone is added to the reaction vessel together with a solvent and a catalyst, and about 1 mole of butyraldehyde is added dropwise. The conditions are controlled so that the self-condensation rate of 2-butanone is slow and reacts as soon as carbonyl of the more reactive aldehyde is added. This results in a high proportion of diols resulting from the condensation of 2-butanone and butyraldehyde and the condensation of 2-butanol itself and a low proportion of diols resulting from the self-condensation of butyraldehyde as reaction products.

Condition D. The condition C is repeated under low temperature conditions. About 1.0 mole of 2-butanone is dissolved in about 5 volumes of anhydrous tetrahydrofuran. The solution is cooled to about -78 ° C and about 0.95 moles of potassium hydride are added in small portions. After the hydrogen evolution has ceased, the solution is left to stand for about 1 hour to equilibrate to a more stable enolate, and then 1 mole of n-butyraldehyde is slowly added while stirring well while maintaining a temperature of about -78 ° C. do. After the addition is complete, the solution is slowly warmed to room temperature and neutralized by careful addition of sulfuric acid. Salt is removed by filtration. If desired, unreacted starting material is removed by distillation with the reaction solvent. The mixture containing the condensation product was hydrogenated on Raney Ni at about 100 ° C. and about 50 atm for about 1 hour to mainly produce diol, 3,5-octanediol, resulting from the condensation of 2-butanone with the enoleate of butyraldehyde. Create Purification is optionally completed by distillation.

Mixed condensation of isobutyraldehyde and methyl ethyl ketone and conversion to form an 8-carbon-1,3-diol mixture

The reaction of Condition A is repeated except that butyraldehyde is replaced with isobutyraldehyde. Condensation and reduction proceed similarly and the final diol product is mainly 2,2,4-trimethyl-1,3-pentanediol; 2,2,3-trimethyl-1,3-pentanediol; 2-methyl-3,5-heptanediol; And 3-methyl-3,5-heptanediol.

Mixed condensation of butyraldehyde, isobutyraldehyde and methyl ethyl ketone and conversion to form an 8-carbon-1,3-diol mixture

The reaction of Condition A is repeated except that about 1 mole of each butyraldehyde, isobutyraldehyde, and 2-butanone is used. Condensation and reduction proceed similarly to 2,2,4-trimethyl-1,3-pentanediol; 2-ethyl-1,3-hexanediol; 2,2-dimethyl-1,3-hexanediol; 2-ethyl-4-methyl-1,3-pentanediol; 2-ethyl-3-methyl-1,3-pentanediol; 3,5-octanediol; 2,2,3-trimethyl-1,3-pentanediol; 2-methyl-3,5-heptanediol; And a mixture of 8-carbon-1,3-diol consisting mainly of 3-methyl-3,5-heptanediol with a small amount of other isomers resulting from condensation on methylene of 2-butanone instead of methyl.

The mixture prepared by condensation of butyraldehyde, isobutyraldehyde, and / or methyl ethyl ketone may be up to about 90% by weight, preferably up to about 80% by weight, more preferably up to 70% by weight, even more preferably about Up to 60% by weight and most preferably up to 50% by weight of certain compounds. In addition, the reaction mixture contains up to about 95 weight percent, preferably up to about 90 weight percent, more preferably up to about 85 weight percent, and most preferably up to about 80 weight percent butyraldehyde or isobutyraldehyde. Should not.

Method E

Preparation of 1,4-diol by adding acetylide to carbonyl compound

Bimetallic acetyl lead Na ^{+ -:} C≡C: ^- aldehyde or a Na ⁺ to react with a ketone to form an unsaturated alcohol, for example the following example:

The resulting acetylene diol is then reduced to alkenes or completely to saturated diols. The reaction can also be converted to sodium salts using an 18% slurry of carbonyl compound and mono-sodium acetylide and acetylene alcohol which can be reacted with another mole of carbonyl compound to yield unsaturated 1,4-diol It is done by forming a. If mixed carbonyl compounds are used with diacetylides, diol mixtures will be produced. When mono-acetylides are used, certain structures are made in high yields.

General Example: Preparation of 6-methyl-2,5-heptanediol

Sodium acetylide (about 18% in xylene) slurry is reacted with isobutyraldehyde to form acetylene alcohol.

(CH ₃ ) ₂ CH-CHO + NaC≡CH → (CH ₃ ) ₂ CH-CHOH-C≡CH

Acetylene (ethynyl) alcohol is converted to sodium acetylide R-CHOH-C≡CNa using a base, which is then reacted with 1 mole of acetaldehyde to react with ethynyl diol R-CHOH-C≡C-CHOH-R ' Create This compound, (CH ₃ ) ₂ CH-CHOH-C≡C-CHOH-CH ₃ , can be isolated with unsaturated diols and, if necessary, reduced to catalytic hydrogenation to contain a corresponding double bond instead of an acetylene bond. Or further reduced by catalytic hydrogenation to form saturated 1,4-diol.

Method F

Preparation of Substituted Diols Derived from Esters of Cyclic Anhydrides, Lactones and Dicarboxylic Acids

This method of preparation relates to diols derived from dicarboxylic acid anhydrides, diesters and lactones, in particular some 1,4-diols, and is not limited to 1,4-diol or 4-carbon diacids.

Diols of this type are generally synthesized by reducing sodium bis (2-methoxyethoxy) aluminum hydride (Red-Al) and the parent anhydride, lactone or diester as reducing agent. This reducing agent is commercially available as a 3.1 molar solution dissolved in toluene and delivers 1 mole of hydrogen per mole of reagent. Diesters and cyclic anhydrides require about 3 moles of Red-Al per mole of substrate. To illustrate this method, alkyl substituted succinic anhydrides are used and typical reduction is carried out as follows.

The anhydride is first dissolved in anhydrous toluene and placed in a reaction vessel equipped with a reflux funnel, a mechanical stirrer, a thermometer and a reflux condenser connected to calcium chloride and soda lime and carbon dioxide to exclude moisture. The reducing agent in toluene is placed in a dropping funnel and slowly added to the stirred anhydrous solution. The reaction is exothermic and the temperature is adjusted to about 80 ° C. It is maintained at about 80 ° C. for the remaining addition time and for about 2 hours after addition.

The reaction mixture is then cooled to room temperature. The mixture is then added to a stirred aqueous solution of HCl (concentration of about 20%) cooled in an ice bath and the temperature is maintained at about 20 to 30 ° C. After acidification, the mixture is separated in a separating funnel and the organic layer is washed with dilute salt solution until the pH paper is neutral. The neutral diol solution is dried over anhydrous magnesium sulfate, filtered and then stripped under vacuum to produce the desired 1,4-diol.

Method G

Preparation of Diols Having One or Two Secondary or Tertiary Alcohol Functional Groups

This is a common method for preparing substituted diols from lactones and / or diesters by alkylating carboxyl group (s) using methyl magnesium bromide (Grignard reagent) or alkyl lithium compounds generally methyl lithium. It is as follows.

This form of alkylation can extend to diesters. Excess methylation will yield diols with two alcohol groups tertiary.

Method H

Preparation of Substituted 1,3-, 1,4- and 1,5-Diols

This method is a general preparation of several 1,3-, 1,4- and 1,5-diols using the schematic chemistry of Methods A-1 and A-2. The modification here is to use cyclic alkandienes instead of the cyclic alkenes described in Method A. The general formula of the starting material is:

[Wherein each R is H, or C ₁ -C ₄ -alkyl and x is 1,2 or 3]

The reaction is carried out for each mole of the target diol share, in which one mole of ethylene glycol is, for example, 2,2-dimethyl-1,4-hexanediol from 1-ethyl-5,5-dimethyl-1,3-cyclohexanediol. A variation of Method A of forming a solvent is, for example, the following (CAS No. 79419-18-4):

Preparation of Polyethoxylated Derivatives

Polyethoxylated derivatives of the diol main solvent are typically prepared in high pressure reactors under a nitrogen atmosphere. Appropriate amount of ethylene oxide is added to the mixture of high temperature (about 80 ° C. to about 170 ° C.) diol solvent and potassium hydroxide. The amount of ethylene oxide is calculated for a predetermined amount of diol solvent to add the correct number of ethylene oxide groups per mole of diol. When the reaction is complete, for example after about 1 hour, the remaining unreacted ethylene oxide is removed in vacuo.

General Example: Preparation of Tetraethoxylated 3,3-dimethyl-1,2-butanediol

A 2 liter Parr reactor equipped with a temperature control system is charged with about 354 g (about 3.0 moles) of 3,3-dimethyl-1,2-butanediol and about 0.54 g of potassium hydroxide. Nitrogen is sparged into the reactor and evacuated three times under a pressure of about 30 mm Hg. The reactor is then again charged with nitrogen to atmospheric pressure and heated to about 130 ° C. The pressure in the reactor is then adjusted slightly below atmospheric pressure by applying a slight vacuum. Ethylene oxide (about 528 g, about 12.0 moles) is added over 1 hour while adjusting the temperature to about 130 ° C. After an additional reaction time of 1 hour, the contents are cooled to about 90 ° C. and vacuum is removed to remove residual ethylene oxide.

Preparation of Methyl Capped Polyethoxylated Derivatives

The methyl-capped polyethoxylated derivatives of the diols are selected from the selected diols and methoxypoly (ethoxy) ethyl chloride of the desired chain length (e.g. CH ₃ O- (CH ₂ CH ₂ O) _n -CH ₂ CH ₂ -Cl) or methyl-capped polyethylene glycol (e.g., CH ₃ O- (CH ₂ CH ₂ O) _n -CH ₂ CH _{2 of the} desired chain length with the epoxy precursor of the diol -OH), or a combination of these methods.

Example: (CH ₃ ) ₂ C (OH) CH (CH ₃ ) (OCH ₂ CH ₂ ) ₄ OCH ₃ , Synthesis of methyl capped tetraethoxylated derivatives of 2-methyl-2,3-butanediol.

Tetraethylene glycol methyl ether (about 208 g, about 1.0 mole) and sodium metal (Aldrich, in a 1-liter three-neck round-bottomed flask equipped with a magnetic stir bar, cooler, thermometer, and thermostat (Tr. Thermowatch I ² R) About 2.3 g, about 0.10 mole) is added and the mixture is heated to about 100 ° C. under argon. After sodium is dissolved, 2-methyl-2,3-epoxybutane (about 86 g, about 1.0 mole) is added and the solution is stirred at about 120 ° C. under argon overnight. ¹³ C-NMR (dmso-d ₆ ) indicates the reaction was complete due to disappearance of the epoxide peak. The reaction mixture is cooled, poured into equal volume of water, neutralized with 6N HCl, saturated with sodium chloride and then extracted twice with dichloromethane. The combined dichloromethane layer is dried over sodium sulfate and the solvent is stripped to produce the desired polyether alcohol in crude form. If desired, purification is accomplished by fractional vacuum distillation.

Synthesis of Methoxytriethoxyethyl Chloride

Tetraethylene glycol methyl ether (about 208 g, about 1.0 mole) is added under argon to a 1 liter three necked round bottom flask with a magnetic stir bar, a cooler, and a thermostat (registered Thermowatch I ² R). Thionyl chloride (about 256.0 g, about 2.15 moles) is added dropwise with good stirring over about 3 hours, maintaining the temperature in the 50-60 ° C range. The reaction mixture is then heated at about 55 ° C overnight. ¹³ C-NMR (D ₂ O) shows a small peak at only -60 ppm for unreacted alcohol and a significant peak at -43.5 ppm indicating chlorinated product (-CH ₂ Cl). Saturated sodium chloride solution is added to the material until thionyl chloride is destroyed. The material is dissolved in about 300 ml of saturated sodium chloride solution and extracted with about 500 ml of methylene chloride. The organic layer is dried and the solvent stripped on a rotary evaporator to produce crude methoxyethoxyethyl chloride. If desired, purification is accomplished by fractional vacuum distillation.

C ₂ H ₅ CH (OH) CH (CH ₃ ) CH ₂ (OCH ₂ CH ₂ ) ₄ OCH ₃ , Synthesis of methyl capped tetraethoxylated derivatives of 2-methyl-1,3-pentanediol.

Alcohol, C ₂ H ₅ CH (OH) CH (CH ₃ ) CH ₂ OH (about 116 g, about 1.0 mole), 1 liter with magnetic stir bar, cooler, and thermostat (registered Thermowatch, I ² R) Into a three necked round bottom flask are placed with about 100 ml of tetrahydrofuran as solvent. To this solution is added sodium hydride (about 32 g, about 1.24 moles) in small portions and kept under reflux until gas evolution stops. Methoxytriethoxyethyl chloride (about 242 g, about 1.2 moles, prepared as above) is added and the system is held at reflux for about 48 hours. The reaction mixture is cooled to room temperature and continuously added dropwise with water while stirring to decompose excess hydride. Tetrahydrofuran is removed by stripping in a rotary evaporator. The crude product is dissolved in about 400 ml of water and sufficient sodium chloride is dissolved in water to near saturation level. The mixture is then extracted twice with about 300 ml of dichloromethane. The combined dichloromethane layer is dried over sodium sulfate and the solvent is then stripped with a rotary evaporator to produce the crude product. If desired, purification is achieved by further stripping the unreacted starting material and the low molecular weight by-product using a kugelrohr apparatus at about 150 ° C. under vacuum. If desired, further purification by vacuum distillation yields the title polyether.

Preparation of Polypropoxylated Derivatives

Attach a three-neck round bottom flask with a magnetic stir bar, solid CO ₂ -cooled cooler, addition funnel, thermometer, and thermostat (Therm-O-Watch, I2R). The system is equipped with nitrogen to remove air through a stream of nitrogen and then blanket the reaction mixture. To the reaction flask is added anhydrous alcohol or diol to be propoxylated. Carefully add about 0.1-5 mole% sodium metal to the reaction vessel in small portions and allow all sodium to react if necessary. The reaction mixture is then heated to about 80-130 ° C. and propylene oxide (Aldrich) is added dropwise from the dropping funnel at a rate that maintains a small amount of reflux from the solid CO ₂ -cooled cooler. Propylene oxide is added continuously until the desired amount is added for the desired degree of propoxylation. Heating is continued until all reflux of propylene oxide has stopped and the temperature is held at an additional temperature for about 1 hour to allow the reaction to complete completely. The reaction mixture is then cooled to room temperature and neutralized by careful addition of a convenient acid such as methanesulfonic acid. The salt is removed by filtration to give the desired propoxylated product. Average propoxylation degree is typically confirmed by integrating the ¹ H-NMR spectrum.

Preparation of Polybutoxylated Derivatives

Attach a three-neck round bottom flask with a magnetic stir bar, solid CO ₂ -cooled cooler, addition funnel, thermometer, and thermostat (Therm-O-Watch, I2R). The system is equipped with nitrogen to remove air through a stream of nitrogen and then blanket the reaction mixture. To the reaction flask is added anhydrous alcohol or diol to be butoxylated. Carefully continue to add about 0.1-5 mole% sodium metal to the reaction vessel in small portions, allowing all sodium to react if necessary. The reaction mixture is then heated to about 80-130 ° C. and α-butylene oxide (Aldrich) is added dropwise from the dropping funnel at a rate that maintains a small amount of reflux from the solid CO ₂ -cooled cooler. Butylene oxide is added continuously until the desired amount is added for the desired degree of butoxylation. Heating is continued until reflux of the butylene oxide stops and the temperature is maintained for about 1 or 2 hours further to complete the reaction. The reaction mixture is then cooled to room temperature and neutralized by careful addition of a convenient acid such as methanesulfonic acid. The salt is removed by filtration to give the desired butoxylated product. Average butoxylation is typically confirmed by integrating the ¹ H-NMR spectrum.

Preparation of Polytetramethyleneoxylated Derivatives

The dry portion of about one mole of the alcohol or diol starting material is placed in a three neck round bottom flask equipped with a magnetic stirrer, cooler, internal thermometer and argon blanket system. If the desired average 'tetramethyleneoxylation' degree is about 1 per hydroxy group, about 0.11 mole of 2- (4-chlorobutoxy) tetrahydropyran (ICI) is added per mole of alcohol functional group. A solvent such as anhydrous tetrahydrofuran, dioxane or dimethylformamide is added if necessary. Sodium hydride (about 5 mole% excess relative to chloro compound) is then added with good stirring in small portions, maintaining a temperature of about 30-120 ° C. After all the hydrides have reacted, the temperature is generally maintained for about 4-24 hours until all alcohol groups are alkylated. After the reaction is complete, it is cooled and excess hydride is decomposed by careful addition of methanol in small portions. An equal volume of water is then added and the pH is adjusted to about 2 with sulfuric acid. After warming to about 40 ° C., it is held for about 15 minutes to hydrolyze the tetrahydropyranyl protecting group, the reaction mixture is neutralized with sodium hydroxide, and the solvent is stripped with a rotary evaporator. The residue is dissolved in ether or methylene chloride and the salts are removed by filtration. The residue is dissolved in ether or methylene chloride and salts are removed by filtration. Stripping produces crude tetramethyleneoxylated alcohol or diols. If a final average tetramethyleneoxylation degree of less than 1 is desired, correspondingly smaller amounts of chloro compounds and hydrides are used. If the average tetramethyleneoxylation is greater than 1, the whole process repeats the cycle until the desired level is reached.

Preparation of Alkyl and Aryl Monoglyceryl Ethers

A convenient method for preparing alkyl and / or aryl monoglycerol ethers consists first of preparing the corresponding alkyl glycidyl ether precursors. It is then converted to ketals and then hydrolyzed to form monoglyceryl ether (diol). The following is a general example of the preparation of the preferred n-pentyl monoglycerol ethers (ie 3- (pentyloxy) -1,2-propanediol) nC ₅ H ₁₁ -O-CHOHCH ₂ OH.

Preparation of 3- (pentyloxy) -1,2-propanediol

To a two liter three necked round bottom flask (with head stirrer, cold water cooler, mercury thermometer and addition funnel) about 546 g of aqueous NaOH (about 50% concentration) and about 38.5 g of hydrogen tetrabutylammonium sulfate (PTC, phase Transition catalyst). The contents of the flask are stirred to dissolve and then about 200 g of 1-pentanol is added together with about 400 ml of hexane (mixture of isomers, about 85% n-hexane). The addition funnel is filled with about 418 g of epichlorohydrin which is slowly added dropwise into the stirred reaction mixture. Because of the exothermic reaction, the temperature is gradually raised to about 68. After the addition of epichlorohydrin is complete the reaction continues for 1 hour (no heat is added).

The crude reaction mixture is diluted with about 500 ml of warm water and stirred gently followed by standing and removing the aqueous layer. The hexane layer is again diluted with about 1 liter of warm water and the pH of the mixture is adjusted to about 6.5 by addition of dilute sulfuric acid solution. The aqueous layer is separated and discarded again and the hexane layer is then washed three times with fresh water. The hexane layer is then separated and evaporated to dryness on a rotary evaporator to give crude n-pentyl glycidyl ether.

Acetoneization (Conversion to Ketal)

Two liter three neck round bottom flasks (attached with a head stirrer, a cold water cooler, a mercury thermometer and an addition funnel) are charged with about one liter of acetone. To acetone is added about 1 ml of SnCl ₄ with stirring. To the addition funnel on the reaction flask is added about 200 g of just prepared n-pentyl glycidyl ether. Glycidyl ether is added very slowly to the stirring acetone solution (rate is adjusted to control exotherm). The reaction proceeds for about 1 hour after the addition of glycidyl ether is complete (maximum temperature about 52 ° C.).

Hydrolysis

The apparatus is converted for distillation and a heating mantle and thermostat are added. The crude reaction mixture is concentrated by distilling about 600 ml of acetone. To the cooled concentrated solution is added about 1 liter of aqueous sulfuric acid solution (concentration of about 20%) and about 500 ml of hexane. The contents of the flask are then heated to about 50 ° C. with stirring (the apparatus is adjusted to collect and separate the released acetone. The hydrolysis reaction is continued until TLC (thin layer chromatography) analysis confirms the completion of the reaction). do.

The crude reaction mixture is cooled and the aqueous layer is separated and discarded. The organic layer is then diluted with about 1 liter of warm water and the pH adjusted to about 7 by addition of dilute aqueous NaOH (1N) solution. The aqueous layer is separated again and the organic phase is washed three times with fresh water. The organic phase is then separated and evaporated through a rotary evaporator. The residue is then diluted with fresh hexanes and the desired product is extracted with a methanol / water solution (about 70/30 weight ratio). The methanol / water solution is evaporated to dryness again on a rotary evaporator (additional methanol is added to facilitate water evaporation). The residue is then filtered hot through glass micro fiber filter paper to give n-pentyl monoglycerol ether.

Preparation of Di (hydroxyalkyl) Ether

Synthesis of Bis (2-hydroxybutyl) ether

Argon is poured into a 500 ml three neck round bottom flask equipped with a magnetic stirrer, internal thermometer, addition funnel, cooler, argon feeder, and heating mantle. Then 1,2-butanediol (about 270 g, about 3 moles, Aldrich) is added, sodium metal (about 1.2 g, about 0.05 moles, Aldrich) is added and sodium is dissolved. The reaction mixture is then heated to about 100 ° C. and the epoxybutane (about 7.1 g, about 1 mole, Aldrich) is added dropwise with stirring. Heating is continued until reflux of the epoxybutane is stopped and heating is continued for an additional hour to complete the conversion. The reaction mixture is neutralized with sulfuric acid, the salt is removed by filtration and the liquid is fractionally distilled under vacuum to recover excess butanediol. The desired ether is obtained as a residue. If desired, further vacuum distillation is purified.

Synthesis of Bis (2-hydroxycyclopentyl) ether

Argon is poured into a 1 l three necked round bottom flask equipped with a magnetic stirrer, internal thermometer, addition funnel, cooler, argon feeder, and heating mantle. Then 1,2-cyclopentanediol (about 306 g, about 3 moles, Aldrich) is added and boron trifluoride diethyl etherate (about 0.14 g, about 0.01 mole, cis-trans isomer mixture, Aldrich) is added. . The reaction mixture is then maintained at about 10-40 ° C. when cyclopentene oxide (about 84 g, about 1 mole, Aldrich) is added dropwise while stirring until all cyclopentene oxide has reacted. The reaction mixture is neutralized with sodium hydroxide and the liquid is fractionally distilled under vacuum to recover excess cyclopentanediol. The desired ether is obtained as a residue. In some cases, further vacuum distillation purifies.

The methods disclosed above have been described solely for the purpose of assisting those skilled in the art for the practice of the invention, and the invention is not limited thereto.

All percentages, ratios, and ratios herein are by weight unless otherwise specified, and all numbers are approximations. All documents cited are hereby incorporated by reference in their appropriate places.

The following non-limiting examples show a transparent or translucent product having an acceptable viscosity.

In the following examples the composition is made by first preparing an oil sheet which is a DEQA softener active at room temperature. If the softener activator is not fluid at room temperature, the softener activator may be heated, for example, until it melts at about 130-150 ° F. (about 55-66 ° C.). The active softener is mixed using a trademark IKA RW 25 mixer at about 150 rpm for about 2 to about 5 minutes. Separately, acid / water sheets are prepared at room temperature by mixing HCl with deionized (DI) water. If the softener activator and / or main solvent (s) are not fluid at room temperature and need to be heated, the acid / water sheet should also be heated to a suitable temperature, for example about 100 ° F. (about 38 ° C.) Maintain the temperature in a water bath. Main solvent (s) (melted at appropriate temperature if their melting point is above room temperature) is added to the softener premix and the premix is mixed for about 5 minutes. The acid / water sheet is then added to the softener premix and mixed for about 20 to about 30 minutes or until the composition is clear and uniform. The composition is left to air to ambient temperature.

The following is a suitable N, N-di (fatty acid acyl-oxyethyl) -N, N-dimethyl ammonium chloride fabric softener activator (DEQA) with appropriately distributed fatty acyl groups, which is then used to prepare the following compositions. .

Fat acyl DEQA ¹ DEQA ² DEQA ³ DEQA ⁴ DEQA ⁵ C12 a very small amount a very small amount 0 0 0 C14 3 3 0 0 0 C16 4 4 5 5 5 C18 0 0 5 6 6 C14: 1 3 3 0 0 C16: 1 11 7 0 0 3 C18: 1 74 73 71 68 67 C18: 2 4 8 8 11 11 C18: 3 0 One One 2 2 C20: 1 0 0 2 2 2 C20 or higher 0 0 2 0 0 Unknown sample 0 0 6 6 7 all 99 99 100 100 102 Ⅳ 86-90 88-95 99 100 95 Sheath / Trans 20-30 20-30 4 5 5 TPU 4 9 10 13 13 TPU = total polyunsaturated fatty acyl group, weight

Example I

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% 8% by weight DEQA ¹ 26.6 43.2 - 26.6 - 26.6 26.6 26.6 DEQA ⁶ - - 27.5 - 27.5 - - - ethanol 6 10 5.1 6 3.1 6 4 6 2-ethyl-1,3-hexanediol 8 - - 8 9 8 9 - 1,2-hexanediol 8 20 16 8 9 8 9 16 HCl (pH 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 Fragrance - - - - - 1.0 - - Carton - - 3 ppm 3 ppm - - - - DI number balance balance balance balance balance balance balance balance DEQA ⁶ N, N-di (coco-oil-oxyethyl) -N, N-dimethyl ammonium chloride.

The ClogP values for 2-ethyl-1,3-hexanediol and 1,2-hexanediol are 0.60 and 0.53, respectively, which are within the preferred ClogP range.

The above examples show transparent or translucent products with acceptable viscosities.

Example IA

ingredient 8% by weight Comparative 8A weight% Comparative 8B weight% Comparative 8C weight% Comparative 8D weight% Comparative 8E weight% Comparative 8F weight% DEQA ¹ 26.6 26.6 26.6 26.6 26.6 26.6 26.6 1,2-hexanediol 16 - - - - - - 1,2-propanediol - 16 - - - - - 1,2-butanediol - - 16 - - - - 1,2-pentanediol - - - 16 - - - 1,2-heptanediol - - - - 16 - - 1,2-octanediol - - - - - 16 - 1,2-decanediol - - - - - - 16 ethanol 6 6 6 6 6 6 6 HCl (pH 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

All 1,2-alkanediols of Example IA except 1,2-hexanediol are outside the effective range of 0.15 to 0.64 in ClogP values. Only the composition of Example I-8 containing 1,2-hexanediol is a transparent composition having an acceptable viscosity at room temperature and at 40 ° F. (about 4 ° C.). The compositions of Comparative Examples I-8A to I-8F do not have transparency and / or acceptable viscosity.

Example IB

ingredient 8% by weight Comparative 8G weight% Comparative 8H weight% Comparative 8I wt% Comparative 8J weight% Comparative 8K weight% Comparative 8 L weight% DEQA ¹ 26.6 26.6 26.6 26.6 26.6 26.6 26.6 1,2-hexanediol 16 - - - - - - 1,3-hexanediol - 16 - - - - - 1,4-hexanediol - - 16 - - - - 1,5-hexanediol - - - 16 - - - 1,6-hexanediol - - - - 16 - - 2,4-hexanediol - - - - - 16 - 2,5-hexanediol - - - - - - 16 ethanol 6 6 6 6 6 6 6 HCl (pH 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

All hexanediol isomers of Example IB except 1,2-hexanediol were outside the effective range of 0.15 to 0.64 in the ClogP value. Only the composition of Example I-8 containing 1,2-hexanediol is a transparent composition having an acceptable viscosity at room temperature and at 40 ° F. (about 4 ° C.). The compositions of Comparative Examples I-8G to I-8L do not have transparency and / or acceptable viscosity.

Example IC

ingredient 8% by weight 8M% by weight 8N% by weight 8O wt% 8P% by weight Comparative 8Q weight% DEQA ¹ 26.6 26.6 26.6 26.6 26.6 26.6 1,2-hexanediol 16 9.2 13 9 9 - 1,2-pentanediol - 6.8 2 - - 6.8 1,2-octanediol - - One - - 9.2 Ethyl lactate - - - 9 - - Isopropyl lactate - - - - 9 - ethanol 6 6 6 6 6 6 HCl (pH 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance

Compositions of Examples I-8, I-8M and I-8N containing effective 1,2-hexanediol main solvents at effective levels are transparent compositions having acceptable viscosities both at room temperature and at 40 ° F. (about 4 ° C.). to be. The compositions of Examples I-8O and I-8P containing effective 1,2-hexanediol main solvents at effective levels are transparent compositions with acceptable viscosities at room temperature and separated at the top at about 40 ° F. (about 4 ° C.). However, it is a transparent composition with a small layer that returns to room temperature and returns to transparent. The composition of Comparative Example I-8Q, which does not contain an effective amount of the preferred 1,2-hexanediol, does not have transparency and / or acceptable viscosity.

Example II

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ - 26.6 - 20.0 20.0 26.6 - DEQA ⁶ 27.5 - 27.5 6.8 6.8 - 27.5 ethanol 5.1 6 5.1 3.8 - 4 5.1 Isopropanol - - - - - 2 - 2-ethyl-1,3-hexanediol - - - 16 18 - - 1,2-hexanediol 16 - - - - 16 - 2,5-dimethyl-2,5-hexanediol - - - - - - 16 2-methyl, 2-propyl-1,3-propanediol - 16 16 - - - - HCl (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example III

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ - 26.6 - 26.6 26.6 26.6 - DEQA ² 26 - 26 - - - 26 ethanol 5.1 6 5.1 3.8 - 4 5.1 Isopropanol - - - - - 2 - n-propanol 18 - - - - - - 2-butanol - 16 - - - - - 2-methyl-1-propanol - - 18 - - 2 - 2-methyl-2-propanol - - - 20 - - - 2,3-butanediol, 2,3-dimethyl- - - - - 18 - - 1,2-butanediol, 2,3-dimethyl- - - - - - 16 - 1,2-butanediol, 3,3-dimethyl- - - - - - - 18 CaCl ₂ - 0.25 - - - - - HCl (pH 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example IV

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ³ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 2,3-pentanediol, 2-methyl- 18 - - - - - - 2,3-pentanediol, 3-methyl- - 18 - - - - - 2,3-pentanediol, 4-methyl- - - 18 - - - - 2,3-hexanediol - - - 17 - - - 3,4-hexanediol - - - - 18 - - 1,2-butanediol, 2-ethyl- - - - - - 17 - 1,2-pentanediol, 2-methyl- - - - - - - 18 HCl (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example Ⅴ

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁴ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,2-pentanediol, 3-methyl- 18 - - - - - - 1,2-pentanediol, 4-methyl- - 18 - - - - - 1,2-hexanediol - - 18 - - - - 1,3-propanediol, 2-butyl- - - - 17 - - - 1,3-propanediol, 2,2-diethyl- - - - - 18 - - 1,3-propanediol, 2- (1-methylpropyl)- - - - - - 17 - 1,3-propanediol, 2- (2-methylpropyl)- - - - - - - 18 HCl (about pH 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example VI

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁵ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,2-butanediol, 2,3,3-trimethyl- 18 - - - - - - 1,4-butanediol, 2-ethyl-2-methyl- - 18 - - - - - 1,4-butanediol, 2-ethyl-3-methyl- - - 18 - - - - 1,4-butanediol, 2-propyl- - - - 17 - - - 1,4-butanediol, 2-isopropyl- - - - - 18 - - 1,5-pentanediol, 2,2-dimethyl- - - - - - 17 - 1,5-pentanediol, 2,3-dimethyl- - - - - - - 18 HCl (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example Ⅶ

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight DEQA ⁵ - 26.6 - 20.0 20.0 26.6 DEQA ² 27.5 - 27.5 6.8 6.8 - ethanol 5.1 6 5.1 3.8 - 4 Isopropanol - - - - - 2 1,5-pentanediol, 2,4-dimethyl- 18 - - - - - 1,5-pentanediol, 3,3-dimethyl- - 18 - - - - 2,3-pentanediol, 2,3-dimethyl- - - 18 - - - 2,3-pentanediol, 2,4-dimethyl- - - - 16 - - 2,3-pentanediol, 3,4-dimethyl- - - - - 18 - 2,3-pentanediol, 4,4-dimethyl- - - - - - 16 HCl (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance

Example Ⅷ

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ⁵ 26.6 26.6 - - 26 26 - DEQA ³ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 3,4-pentanediol, 2,3-dimethyl- 18 - - - - - - 1,5-pentanediol, 2-ethyl- - 18 - - - - - 1,6-hexanediol, 2-methyl- - - 18 - - - - 1,6-hexanediol, 3-methyl- - - - 17 - - - 2,3-hexanediol, 2-methyl- - - - - 18 - - 2,3-hexanediol, 3-methyl- - - - - - 17 - 2,3-hexanediol, 4-methyl- - - - - - - 18 HCl (pH 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example Ⅸ

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ⁵ 26.6 26.6 - - 26 26 - DEQA ⁴ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 2,3-hexanediol, 5-methyl- 18 - - - - - - 3,4-hexanediol, 2-methyl- - 18 - - - - - 3,4-hexanediol, 3-methyl- - - 18 - - - - 1,3-heptanediol - - - 17 - - - 1,4-heptanediol - - - - 18 - - 1,5-heptanediol - - - - - 17 - 1,6-heptanediol - - - - - - 18 HCl (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example Ⅹ

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁵ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,3-propanediol, 2- (2-methylbutyl)- 18 - - - - - - 1,3-propanediol, 2- (1-methylpropyl)- - 18 - - - - - 1,3-propanediol, 2- (1,1-dimethylpropyl)- - - 18 - - - - 1,3-propanediol, 2- (1,2-dimethylpropyl)- - - - 17 - - - 1,3-propanediol, 2- (1-ethylpropyl)- - - - - 18 - - 1,3-propanediol, 2- (1-methylbutyl)- - - - - - 17 - 1,3-propanediol, 2- (2,2-dimethylpropyl)- - - - - - - 18 HCl (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example XI

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ² - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,3-propanediol, 2- (3-methylbutyl)- 18 - - - - - - 1,3-propanediol, 2-butyl-2-methyl- - 18 - - - - - 1,3-propanediol, 2-ethyl-2-isopropyl- - - 18 - - - - 1,3-propanediol, 2-ethyl-2-propyl- - - - 17 - - - 1,3-propanediol, 2-methyl-2- (1-methylpropyl)- - - - - 18 - - 1,3-propanediol, 2-methyl-2- (2-methylpropyl)- - - - - - 17 - 1,3-propanediol, 2-tert-butyl-2-methyl- - - - - - - 18 HCl (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example XII

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ³ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,3-butanediol, 2,2-diethyl- 18 - - - - - - 1,3-butanediol, 2,2-diethyl- - 18 - - - - - 1,3-butanediol, 2- (1-methylpropyl)- - - 18 - - - - 1,3-butanediol, 2-butyl- - - - 17 - - - 1,3-butanediol, 2-ethyl-2,3-dimethyl- - - - - 18 - - 1,3-butanediol, 2- (1,1-dimethylethyl)- - - - - - 17 - 1,3-butanediol, 2- (2-methylpropyl)- - - - - - - 18 HCl (pH 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example XIII

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁴ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,3-butanediol, 2-methyl-2-isopropyl- 18 - - - - - - 1,3-butanediol, 2-methyl-2-propyl- - 18 - - - - - 1,3-butanediol, 3-methyl-2-isopropyl- - - 18 - - - - 1,3-butanediol, 3-methyl-2-propyl- - - - 17 - - - 1,4-butanediol, 2,2-diethyl- - - - - 18 - - 1,4-butanediol, 2-methyl-2-propyl- - - - - - 17 - 1,4-butanediol, 2- (1-methylpropyl)- - - - - - - 18 HCl (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example IV

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁵ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,4-butanediol, 2-ethyl-2,3-dimethyl- 18 - - - - - - 1,4-butanediol, 2-ethyl-3,3-dimethyl- - 18 - - - - - 1,4-butanediol, 2- (1,1-dimethylethyl)- - - 18 - - - - 1,4-butanediol, 2- (2-methylpropyl)- - - - 17 - - - 1,4-butanediol, 2-methyl-3-propyl- - - - - 18 - - 1,4-butanediol, 3-methyl-2-isopropyl- - - - - - 17 - 1,4-butanediol, 3-methyl-2-isopropyl- - - - - - - 18 HCl (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example VV

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁵ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,3-pentanediol, 2,2,3-trimethyl- 18 - - - - - - 1,3-pentanediol, 2,2,4-trimethyl- - 18 - - - - - 1,3-pentanediol, 2,3,4-trimethyl- - - 18 - - - - 1,3-pentanediol, 2,4,4-trimethyl- - - - 17 - - - 1,3-pentanediol, 3,4,4-trimethyl- - - - - 18 - - 1,4-pentanediol, 2,2,3-trimethyl- - - - - - 17 - 1,4-pentanediol, 2,2,4-trimethyl- - - - - - - 18 HCl (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example VI

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ⁵ 26.6 26.6 - - 26 26 - DEQA ² - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,4-pentanediol, 2,3,3-trimethyl- 18 - - - - - - 1,4-pentanediol, 2,3,4-trimethyl- - 18 - - - - - 1,4-pentanediol, 3,3,4-trimethyl- - - 18 - - - - 1,5-pentanediol, 2,2,3-trimethyl- - - - 17 - - - 1,5-pentanediol, 2,2,4-trimethyl- - - - - 18 - - 1,5-pentanediol, 2,3,3-trimethyl- - - - - - 17 - 1,5-pentanediol, 2,3,4-trimethyl- - - - - - - 18 HCl (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example ⅩⅦ

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ⁵ 26.6 26.6 - - 26 26 - DEQA ³ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 2,4-pentanediol, 2,3,4-trimethyl- 18 - - - - - - 2,4-pentanediol, 2,3,3-trimethyl- - 18 - - - - - 2,4-pentanediol, 2,3,4-trimethyl- - - 18 - - - - 2,4-pentanediol, 2,3,3-trimethyl- - - - 17 - - - 2,4-pentanediol, 2,3,3-trimethyl- - - - - 18 - - 2,4-pentanediol, 2,3,4-trimethyl- - - - - - 17 - 1,3-pentanediol, 2-ethyl-2-methyl- - - - - - - 18 HCl (pH 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example ⅩⅧ

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ⁵ 26.6 26.6 - - 26 26 - DEQA ⁴ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,3-pentanediol, 2-ethyl-3-methyl- 18 - - - - - - 1,3-pentanediol, 2-ethyl-4-methyl- - 18 - - - - - 1,3-pentanediol, 3-ethyl-2-methyl- - - 18 - - - - 1,4-pentanediol, 2-ethyl-2-methyl- - - - 17 - - - 1,4-pentanediol, 2-ethyl-3-methyl- - - - - 18 - - 1,4-pentanediol, 2-ethyl-4-methyl- - - - - - 17 - 1,4-pentanediol, 3-ethyl-2-methyl- - - - - - - 18 HCl (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example ⅩⅨ

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁶ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,4-pentanediol, 3-ethyl-3-methyl- 18 - - - - - - 1,5-pentanediol, 2-ethyl-2-methyl- - 18 - - - - - 1,5-pentanediol, 2-ethyl-3-methyl- - - 18 - - - - 1,5-pentanediol, 2-ethyl-4-methyl- - - - 17 - - - 1,5-pentanediol, 3-ethyl-3-methyl- - - - - 18 - - 1,5-pentanediol, 2-ethyl-4-methyl- - - - - - 17 - 1,5-pentanediol, 3-ethyl-3-methyl- - - - - - - 18 HCl (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example ⅩⅩ

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁵ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 2,4-pentanediol, 3-ethyl-2-methyl- 18 - - - - - - 2,4-pentanediol, 3-ethyl-2-methyl- - 18 - - - - - 1,3-pentanediol, 2-isopropyl- - - 18 - - - - 1,3-pentanediol, 2-propyl- - - - 17 - - - 1,4-pentanediol, 2-isopropyl- - - - - 18 - - 1,4-pentanediol, 2-propyl- - - - - - 17 - 1,4-pentanediol, 3-isopropyl- - - - - - - 18 HCl (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example XI

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ² - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,5-pentanediol, 2-isopropyl- 18 - - - - - - 2,4-pentanediol, 3-propyl- - 18 - - - - - 1,3-hexanediol, 2,2-dimethyl- - - 18 - - - - 1,3-hexanediol, 2,3-dimethyl- - - - 17 - - - 1,3-hexanediol, 2,4-dimethyl- - - - - 18 - - 1,3-hexanediol, 2,5-dimethyl- - - - - - 17 - 1,3-hexanediol, 3,4-dimethyl- - - - - - - 18 HCl (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example XII

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ³ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,3-hexanediol, 3,5-dimethyl- 18 - - - - - - 1,3-hexanediol, 4,5-dimethyl- - 18 - - - - - 1,4-hexanediol, 2,2-dimethyl- - - 18 - - - - 1,4-hexanediol, 2,3-dimethyl- - - - 17 - - - 1,4-hexanediol, 2,4-dimethyl- - - - - 18 - - 1,4-hexanediol, 2,5-dimethyl- - - - - - 17 - 1,4-hexanediol, 3,3-dimethyl- - - - - - - 18 HCl (pH 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example XIII

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ⁵ - 26.6 - 20.0 20.0 26.6 - DEQA ⁶ 27.5 - 27.5 6.8 6.8 - 27.5 ethanol 5.1 6 5.1 3.8 - 4 5.1 Isopropanol - - - - - 2 - 1,4-hexanediol, 3,4-dimethyl- 18 - - - - - - 1,4-hexanediol, 3,5-dimethyl- - 18 - - - - - 1,3-hexanediol, 4,4-dimethyl- - - 18 - - - - 1,4-hexanediol, 4,5-dimethyl- - - - 17 - - - 1,4-hexanediol, 5,5-dimethyl- - - - - 18 - - 1,5-hexanediol, 2,2-dimethyl- - - - - - 16 - 1,5-hexanediol, 2,3-dimethyl- - - - - - - 18 HCl (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example IV

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ³ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,5-hexanediol, 2,4-dimethyl- 18 - - - - - - 1,5-hexanediol, 2,5-dimethyl- - 18 - - - - - 1,5-hexanediol, 3,3-dimethyl- - - 18 - - - - 1,5-hexanediol, 3,4-dimethyl- - - - 17 - - - 1,5-hexanediol, 3,5-dimethyl- - - - - 18 - - 1,5-hexanediol, 4,5-dimethyl- - - - - - 17 - 1,6-hexanediol, 2,2-dimethyl- - - - - - - 18 HCl (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example VV

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁴ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,6-hexanediol, 2,3-dimethyl- 18 - - - - - - 1,6-hexanediol, 2,4-dimethyl- - 18 - - - - - 1,6-hexanediol, 2,5-dimethyl- - - 18 - - - - 1,6-hexanediol, 3,3-dimethyl- - - - 17 - - - 1,6-hexanediol, 3,4-dimethyl- - - - - 18 - - 2,4-hexanediol, 2,3-dimethyl- - - - - - 17 - 2,4-hexanediol, 2,4-dimethyl- - - - - - - 18 HCl (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example VI

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁵ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 2,4-hexanediol, 2,5-dimethyl- 18 - - - - - - 2,4-hexanediol, 3,3-dimethyl- - 18 - - - - - 2,4-hexanediol, 3,4-dimethyl- - - 18 - - - - 2,4-hexanediol, 3,5-dimethyl- - - - 17 - - - 2,4-hexanediol, 4,5-dimethyl- - - - - 18 - - 2,4-hexanediol, 5,5-dimethyl- - - - - - 17 - 2,5-hexanediol, 2,3-dimethyl- - - - - - - 18 HCl (pH 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example XXVII

ingredient One 2 3 4 5 6 7 weight % weight % weight % weight % weight % weight % weight % DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁵ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 2,5-hexanediol, 2,4-dimethyl- 18 - - - - - - 2,5-hexanediol, 2,5-dimethyl- - 18 - - - - - 2,5-hexanediol, 3,3-dimethyl- - - 18 - - - - 2,5-hexanediol, 3,4-dimethyl- - - - 17 - - - 2,6-hexanediol, 3,3-dimethyl- - - - - 18 - - 1,3-hexanediol, 2-ethyl- - - - - - 17 - 1,3-hexanediol, 4-ethyl- - - - - - - 18 Hydrochloric acid (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example XXVIII

ingredient One 2 3 4 5 6 7 weight % weight % weight % weight % weight % weight % weight % DEQA ⁵ 26.6 26.6 - - 26 26 - DEQA ⁶ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,3-hexanediol, 2-ethyl- 18 - - - - - - 1,3-hexanediol, 4-ethyl- - 18 - - - - - 1,4-hexanediol, 2-ethyl- - - 18 - - - - 1,4-hexanediol, 4-ethyl- - - - 17 - - - 1,5-hexanediol, 2-ethyl- - - - - 18 - - 1,4-hexanediol, 4-ethyl- - - - - - 17 - 1,5-hexanediol, 2-ethyl- - - - - - - 18 Hydrochloric acid (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example XXXIX

ingredient One 2 3 4 5 6 7 weight % weight % weight % weight % weight % weight % weight % DEQA ² 26.6 26.6 - - 26 26 - DEQA ⁵ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 2,4-hexanediol, 3-ethyl- 18 - - - - - - 2,4-hexanediol, 4-ethyl- - 18 - - - - - 2,5-hexanediol, 3-ethyl- - - 18 - - - - 2,5-hexanediol, 3-ethyl- - - - 17 - - - 1,3-heptanediol, 2-methyl- - - - - 18 - - 1,3-heptanediol, 3-methyl- - - - - - 17 - 1,3-heptanediol, 4-methyl- - - - - - - 18 Hydrochloric acid (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example XXX

Furtherance One 2 3 4 5 6 7 weight % weight % weight % weight % weight % weight % weight % DEQA ³ 26.6 26.6 - - 26 26 - DEQA ⁵ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,3-heptanediol, 5-methyl- 18 - - - - - - 1,3-heptanediol, 6-methyl- - 18 - - - - - 1,4-heptanediol, 2-methyl- - - 18 - - - - 1,4-heptanediol, 3-methyl- - - - 17 - - - 1,4-heptanediol, 4-methyl- - - - - 18 - - 1,4-heptanediol, 5-methyl- - - - - - 17 - 1,4-heptanediol, 6-methyl- - - - - - - 18 Spices One 1.2 One 1.35 One One 1.3 Hydrochloric acid (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example XXXI

ingredient One 2 3 4 5 6 7 weight % weight % weight % weight % weight % weight % weight % DEQA ⁵ 26.6 26.6 - - 26 26 - DEQA ⁴ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,5-heptanediol, 2-methyl- 18 - - - - - - 1,5-heptanediol, 3-methyl- - 18 - - - - - 1,5-heptanediol, 4-methyl- - - 18 - - - - 1,5-heptanediol, 5-methyl- - - - 17 - - - 1,5-heptanediol, 6-methyl- - - - - 18 - - 1,6-heptanediol, 2-methyl- - - - - - 17 - 1,6-heptanediol, 3-methyl- - - - - - - 18 Hydrochloric acid (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example XXXIA

ingredient One 2 3 4 5 6 7 weight % weight % weight % weight % weight % weight % weight % DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁵ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,6-heptanediol, 4-methyl- 18 - - - - - - 1,6-heptanediol, 5-methyl- - 18 - - - - - 1,6-heptanediol, 6-methyl- - - 18 - - - - 2,4-heptanediol, 2-methyl- - - - 17 - - - 2,4-heptanediol, 3-methyl- - - - - 18 - - 2,4-heptanediol, 4-methyl- - - - - - 17 - 2,4-heptanediol, 5-methyl- - - - - - - 18 Hydrochloric acid (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example XXXIB

ingredient One 2 3 4 5 6 7 weight % weight % weight % weight % weight % weight % weight % DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁶ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 2,4-heptanediol, 6-methyl- 18 - - - - - - 2,5-heptanediol, 2-methyl- - 18 - - - - - 2,5-heptanediol, 3-methyl- - - 18 - - - - 2,5-heptanediol, 4-methyl- - - - 17 - - - 2,5-heptanediol, 5-methyl- - - - - 18 - - 2,5-heptanediol, 6-methyl- - - - - - 17 - 2,6-heptanediol, 2-methyl- - - - - - - 18 Hydrochloric acid (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example XXXIC

ingredient One 2 3 4 5 6 7 weight % weight % weight % weight % weight % weight % weight % DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ² - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 2,6-heptanediol, 3-methyl- 18 - - - - - - 2,6-heptanediol, 4-methyl- - 18 - - - - - 3,4-heptanediol, 3-methyl- - - 18 - - - - 3,5-heptanediol, 2-methyl- - - - 17 - - - 3,5-heptanediol, 3-methyl- - - - - 18 - - 3,5-heptanediol, 4-methyl- - - - - - 17 - 2,4-octanediol - - - - - - 18 Hydrochloric acid (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example XXXID

ingredient One 2 3 4 5 6 7 weight % weight % weight % weight % weight % weight % weight % DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ³ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 2,5-octanediol 18 - - - - - - 2,7-octanediol - 18 - - - - - 3,5-octanediol - - 18 - - - - 3,6-octanediol - - - 17 - - - 2,4-pentanediol, 2,3,3,4-tetramethyl- - - - - 18 - - 2,4-pentanediol, 3-tert-butyl - - - - - 17 - 2,4-hexanediol, 2,5,5-trimethyl - - - - - - 18 Hydrochloric acid (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example XXXII

ingredient One 2 3 4 5 6 7 weight % weight % weight % weight % weight % weight % weight % DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁴ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 2,4-hexanediol, 3,3,4-trimethyl- 18 - - - - - - 2,4-hexanediol, 3,3,5-trimethyl- - 18 - - - - - 2,4-hexanediol, 3,5,5-trimethyl- - - 18 - - - - 2,4-hexanediol, 4,5,5-trimethyl- - - - 17 - - - 2,5-hexanediol, 3,3,4-trimethyl- - - - - 18 - - 2,5-hexanediol, 3,3,5-trimethyl- - - - - - 17 - 1,2-propanediol, 3- (n-pentyloxy)- - - - - - - 18 Hydrochloric acid (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example XXXIIA

ingredient 7 Comparative Example 7A Comparative Example 7B Comparative Example 7C Comparative Example 7D Comparative Example 7E Comparative Example 7F weight % weight % weight % weight % weight % weight % weight % DEQA ¹ 26.6 26.6 26.6 26.6 26.6 26.6 26.6 1,2-propanediol, 3- (n-pentyloxy)- 16 - - - - - - 1,2-propanediol, 3-ethyloxy- - 16 - - - - - 1,2-propanediol, 3-butyloxy- - - 16 - - - - 1,2-propanediol, 3-octyloxy- - - - 16 - - - 1,2-propanediol, 3- (2-ethylhexyloxy)- - - - - 16 - - Glyceryl Monooleate - - - - - 16 - Glyceryl Monostearate - - - - - - 16 ethanol 6 6 6 6 6 6 6 CaCl ₂ 0.5 0.5 0.5 0.5 0.5 0.5 0.5 HCl (pH 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

The ClogP value of 3- (n-pentyloxy) -1,2-propanediol is 0.54, preferably in the range of 0.40 to 0.60, and all ClogP values of Example XXXIIA except 1,2-propanediol derivatives are in the effective range. Phosphorus is out of 0.15 to 0.64. Only the composition of Example XXXII-7 containing 3- (n-pentyloxy) -1,2-propanediol is a transparent composition having an acceptable viscosity both at room temperature and at 40 ° F. (about 4 ° C.). The compositions of Comparative Examples XXXII-7A to XXXII-7F do not have transparency and / or acceptable viscosity.

Example XXXIII

Furtherance One 2 3 4 5 6 7 weight % weight % weight % weight % weight % weight % weight % DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁵ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,2-propanediol, 3- (2-pentyloxy)- 18 - - - - - - 1,2-propanediol, 3- (3-pentyloxy)- - 18 - - - - - 1,2-propanediol, 3- (2-methyl-1-butyloxy)- - - 18 - - - - 1,2-propanediol, 3- (iso-amyloxy)- - - - 17 - - - 1,2-propanediol, 3- (3-methyl-2-butyloxy)- - - - - 18 - - 1,3-pentanediol, 2-propyl - - - - - 17 - 2,6-octanediol - - - - - - 18 Hydrochloric acid (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example XXXIV

Furtherance One 2 3 4 5 6 7 weight % weight % weight % weight % weight % weight % weight % DEQA ⁵ 26.6 26.6 - - 26 26 26 DEQA ⁶ - - 26 26 - - - ethanol 4 6 6 6 - 4 4 Isopropanol 2 - - - 6 2 2 1-isopropyl-1,2-cyclobutanediol 18 - - - - - - 3-ethyl-4-methyl-1,2-cyclobutanediol - 18 - - - - - 3-propyl-1,2-cyclobutanediol - - 18 - - - - 3-isopropyl-1,2-cyclobutanediol - - - 17 - - - 1-ethyl-1,2-cyclopentanediol - - - - 18 - - 1,2-dimethyl-1,2-cyclopentanediol - - - - - 17 - 2,4-pentanediol, 2,3,4-trimethyl-n-BO ₁ - - - - - - 18 Hydrochloric acid (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance

Example XXXV

Furtherance One 2 3 4 5 6 7 weight % weight % weight % weight % weight % weight % weight % DEQA ² 26.6 26.6 - - 26 26 - DEQA ⁵ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,4-dimethyl-1,2-cyclopentanediol 18 - - - - - - 2,4,5-trimethyl-1,3-cyclopentanediol - 18 - - - - - 3,3-dimethyl-1,2-cyclopentanediol - - 18 - - - - 3,4-dimethyl-1,2-cyclopentanediol - - - 17 - - - 3,5-dimethyl-1,2-cyclopentanediol - - - - 18 - - 3-ethyl-1,2-cyclopentanediol - - - - - 17 - 1-phenyl-1,2-ethanediol - - - - - - 18 Hydrochloric acid (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example XXXVA

ingredient 5 Comparative Example 5A Comparative Example 5B Comparative Example 5C weight % weight % weight % weight % DEQA ¹ 26.6 26.6 26.6 26.6 Cis-1,2-bis (hydroxymethyl) cyclohexane 16 - - - 1,4-bis (hydroxymethyl) cyclohexane - 16 - - 1,2-cyclohexanediol - - 16 - 4,5-dimethyl-1,2-cyclohexanediol - - - 16 ethanol 6 6 6 6 Hydrochloric acid (pH 2-3.5) 0.005 0.005 0.005 0.005 DI number balance balance balance balance

The ClogP value of cis-1,2-bis (hydroxymethyl) cyclohexane is 0.47, with a range of 0.40 to 0.60 being preferred. 1,4-bis (hydroxymethyl) cyclohexane Also the ClogP value is 0.47, preferably in the range of 0.40 to 0.60, but with a center of symmetry and does not form an acceptable composition (composition XXXVA-5A). 1,2-cyclohexanediol and 4,5-dimethyl-1,2-cyclohexanediol are outside the effective range of 0.15 to 0.64 with ClogP values. Only the composition of Example XXXVA-5 is a clear composition having an acceptable viscosity at room temperature and at 40 ° F. (about 4 ° C.). The compositions of Comparative Examples XXXVA-5A to XXXVA-5C do not have transparency and / or acceptable viscosity.

Example XXXVI

ingredient One 2 3 4 5 6 7 weight % weight % weight % weight % weight % weight % weight % DEQA ⁵ 26.6 26.6 - - 26 26 - DEQA ³ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,2-propanediol 2 (Me-E ₃ ) 18 - - - - - - 1,2-propanediol PO ₄ - 18 - - - - - 1,2-propanediol, 2-methyl- (Me-E ₈ ) - - 18 - - - - 1,2-propanediol, 2-methyl-2 (Me-E ₁ ) - - - 17 - - - 1,2-propanediol, 2-methyl-PO ₃ - - - - 18 - - 1,3-propanediol, 2 (Me-E ₈ ) - - - - - 17 - 1,3-propanediol PO ₆ - - - - - - 18 Hydrochloric acid (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example XXXVII

ingredient One 2 3 4 5 6 7 weight % weight % weight % weight % weight % weight % weight % DEQA ⁵ 26.6 26.6 - - 26 26 - DEQA ⁴ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,3-propanediol, 2,2-diethyl-E ₅ 18 - - - - - - 1,3-propanediol, 2,2-diethyl-PO ₁ - 18 - - - - - 1,3-propanediol, 2,2-dimethyl-2 (MeE ₂ ) - - 18 - - - - 1,3-propanediol, 2,2-dimethyl-PO ₄ - - - 17 - - - 1,3-propanediol, 2- (1-methylpropyl) -E ₅ - - - - 18 - - 1,3-propanediol, 2- (1-methylpropyl) -PO ₁ - - - - - 17 - 1,3-propanediol, 2- (2-methylpropyl) -E ₅ - - - - - - 18 Hydrochloric acid (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example XXXVIII

ingredient One 2 3 4 5 6 7 weight % weight % weight % weight % weight % weight % weight % DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁵ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,3-propanediol, 2- (2-methylpropyl) -PO ₁ 18 - - - - - - 1,3-propanediol, 2-ethyl- (MeE ₉ ) - 18 - - - - - 1,3-propanediol, 2-ethyl-2 (MeE ₁ ) - - 18 - - - - 1,3-propanediol, 2-ethyl-PO ₃ - - - 17 - - - 1,3-propanediol, 2-ethyl-2-methyl- (MeE ₄ ) - - - - 18 - - 1,3-propanediol, 2-ethyl-2-methyl-PO ₂ - - - - - 17 - 1,3-propanediol, 2-ethyl-2-methyl-BO ₁ - - - - - - 18 Hydrochloric acid (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example XXXIX

ingredient One 2 3 4 5 6 7 weight % weight % weight % weight % weight % weight % weight % DEQA ⁵ 26.6 26.6 - - 26 26 - DEQA ¹ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,3-propanediol, 2-isopropyl- (MeE ₄ ) 18 - - - - - - 1,3-propanediol, 2-isopropyl-PO ₂ - 18 - - - - - 1,3-propanediol, 2-isopropyl-BO ₁ - - 18 - - - - 1,3-propanediol, 2-methyl-2 (MeE ₄ ) - - - 17 - - - 1,3-propanediol, 2-methyl-PO ₅ - - - - 18 - - 1,3-propanediol, 2-methyl-BO ₂ - - - - - 17 - 1,3-propanediol, 2-methyl-2-isopropyl-E ₆ - - - - - - 18 Hydrochloric acid (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example XXXX

Furtherance One 2 3 4 5 6 7 weight % weight % weight % weight % weight % weight % weight % DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁶ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,3-propanediol, 2-methyl-2-isopropyl-PO ₁ 18 - - - - - - 1,3-propanediol, 2-methyl-2-propyl-E ₄ - 18 - - - - - 1,3-propanediol, 2-methyl-2-propyl-PO ₁ - - 18 - - - - 1,3-propanediol, 2-propyl- (MeE ₃ ) - - - 17 - - - 1,3-propanediol, 2-propyl-PO ₂ - - - - 18 - - 1,2-butanediol, 2-ethyl-E ₂ - - - - - 17 - 1,2-butanediol, 2-ethyl-n-BO ₁ - - - - - - 18 Hydrochloric acid (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example XXXXI

Furtherance One 2 3 4 5 6 7 weight % weight % weight % weight % weight % weight % weight % DEQA ² 26.6 26.6 - - 26 26 - DEQA ¹ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,2-butanediol, 2-methyl- (MeE ₂ ) 18 - - - - - - 1,2-butanediol, 2-methyl-PO ₁ - 18 - - - - - 1,2-butanediol, 3,3-dimethyl-E ₄ - - 18 - - - - 1,2-butanediol, 3,3-dimethyl-n-BO ₁ - - - 17 - - - 1,2-butanediol, 3-methyl- (MeE ₂ ) - - - - 18 - - 1,2-butanediol, 3-methyl-PO ₁ - - - - - 17 - 1,3-butanediol 2 (MeE ₅ ) - - - - - - 18 Hydrochloric acid (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example XXXXII

Furtherance One 2 3 4 5 6 7 weight % weight % weight % weight % weight % weight % weight % DEQA ³ 26.6 26.6 - - 26 26 - DEQA ¹ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,3-butanediol PO ₅ 18 - - - - - - 1,3-butanediol BO ₂ - 18 - - - - - 1,3-butanediol 2,2,3-trimethyl- (MeE ₂ ) - - 18 - - - - 1,3-butanediol, 2,2,3-trimethyl-PO ₂ - - - 17 - - - 1,3-butanediol, 2,2-dimethyl- (MeE ₆ ) - - - - 18 - - 1,3-butanediol, 2,2-dimethyl-PO ₃ - - - - - 17 - 1,3-butanediol, 2,3-dimethyl- (MeE ₆ ) - - - - - - 18 Hydrochloric acid (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example XXXXIII

ingredient One 2 3 4 5 6 7 weight % weight % weight % weight % weight % weight % weight % DEQA ⁴ 26.6 26.6 - - 26 26 - DEQA ¹ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,3-butanediol, 2,3-dimethyl-PO ₃ 18 - - - - - - 1,3-butanediol, 2-ethyl (Me E ₄ ) - 18 - - - - - 1,3-butanediol, 2-ethyl-PO ₂ - - 18 - - - - 1,3-butanediol, 2-ethyl-BO ₁ - - - 17 - - - 1,3-butanediol, 2-ethyl-2-methyl (Me E ₁ ) - - - - 18 - - 1,3-butanediol, 2-ethyl-2-methyl-PO ₁ - - - - - 17 - 1,3-butanediol, 2-ethyl-3-methyl (Me E ₁ ) - - - - - - 18 Hydrochloric acid (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example XXXXIV

ingredient One 2 3 4 5 6 7 weight % weight % weight % weight % weight % weight % weight % DEQA ⁵ 26.6 26.6 - - 26 26 - DEQA ¹ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,3-butanediol, 2-ethyl-3-methyl-PO ₁ 18 - - - - - - 1,3-butanediol, 2-isopropyl (Me E ₁ ) - 18 - - - - - 1,3-butanediol, 2-isopropyl-PO ₁ - - 18 - - - - 1,3-butanediol, 2-methyl-2 (Me E ₂ ) - - - 17 - - - 1,3-butanediol, 2-methyl-PO ₄ - - - - 18 - - 1,3-butanediol, 2-propyl-E ₆ - - - - - 17 - 1,3-butanediol, 2-propyl-PO ₁ - - - - - - 18 Hydrochloric acid (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example XXXXV

ingredient One 2 3 4 5 6 7 weight % weight % weight % weight % weight % weight % weight % DEQA ⁵ 26.6 26.6 - - 26 26 - DEQA ⁶ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,3-butanediol, 3-methyl 2 (Me E ₂ ) 18 - - - - - - 1,3-butanediol, 3-methyl-PO ₄ - 18 - - - - - 1,4-butanediol 2 (Me E ₃ ) - - 18 - - - - 1,4-butanediol PO ₄ - - - 17 - - - 1,4-butanediol BO ₂ - - - - 18 - - 1,4-butanediol, 2,2,3-trimethyl-E ₆ - - - - - 17 - 1,4-butanediol, 2,2,3-trimethyl-PO ₁ - - - - - - 18 Hydrochloric acid (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example XXXXVI

ingredient One 2 3 4 5 6 7 weight % weight % weight % weight % weight % weight % weight % DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ² - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,4-butanediol, 2,2-dimethyl (Me E ₄ ) 18 - - - - - - 1,4-butanediol, 2,2-dimethyl-PO ₂ - 18 - - - - - 1,4-butanediol, 2,2-dimethyl-BO ₁ - - 18 - - - - 1,4-butanediol, 2,3-dimethyl (Me E ₅ ) - - - 17 - - - 1,4-butanediol, 2,3-dimethyl-PO ₂ - - - - 18 - - 1,4-butanediol, 2,3-dimethyl-BO ₁ - - - - - 17 - 1,4-butanediol, 2-ethyl (Me E ₃ ) - - - - - - 18 Hydrochloric acid (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example XXXXVII

ingredient One 2 3 4 5 6 7 weight % weight % weight % weight % weight % weight % weight % DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ³ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,4-butanediol, 2-ethyl-BO ₁ 18 - - - - - - 1,4-butanediol, 2-ethyl- (C ₆ ) PO ₂ - 18 - - - - - 1,4-butanediol, 2-ethyl-2-methyl-E ₄ - - 18 - - - - 1,4-butanediol, 2-ethyl-2-methyl-PO ₁ - - - 17 - - - 1,4-butanediol, 2-ethyl-3-methyl-E ₄ - - - - 18 - - 1,4-butanediol, 2-ethyl-3-methyl-PO ₁ - - - - - 17 - 1,4-butanediol, 2-isopropyl-E ₄ - - - - - - 18 Hydrochloric acid (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example XXXXVIII

ingredient One 2 3 4 5 6 7 weight % weight % weight % weight % weight % weight % weight % DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁴ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,4-butanediol, 2-isopropyl-PO ₁ 18 - - - - - - 1,4-butanediol, 2-methyl (Me E ₈ ) - 18 - - - - - 1,4-butanediol, 2-methyl 2 (Me E ₁ ) - - 18 - - - - 1,4-butanediol, 2-methyl-PO ₃ - - - 17 - - - 1,4-butanediol, 2-propyl-E ₅ - - - - 18 - - 1,4-butanediol, 3-ethyl-1-methyl-E ₆ - - - - - 17 - 1,4-butanediol, 3-ethyl- ₁ -methyl-PO ₁ - - - - - - 18 Hydrochloric acid (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example IL

ingredient One 2 3 4 5 6 7 weight % weight % weight % weight % weight % weight % weight % DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁵ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 2,3-butanediol (Me E ₉ ) 18 - - - - - - 2,3-butanediol 2 (Me E ₁ ) - 18 - - - - - 2,3-butanediol PO ₄ - - 18 - - - - 2,3-butanediol, 2,3-dimethyl-E ₇ - - - 17 - - - 2,3-butanediol, 2,3-dimethyl-PO ₁ - - - - 18 - - 2,3-butanediol, 2,3-dimethyl-n-BO ₂ - - - - - 17 - 2,3-butanediol, 2-methyl (Me E ₄ ) - - - - - - 18 Hydrochloric acid (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example L

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁶ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 2,3-butanediol, 2-methylPO ₂ 18 - - - - - - 2,3-butanediol, 2-methylBO ₁ - 17 - - - - - 1,2-pentanediol E ₇ - - 18 - - - - 1,2-pentanediolPO ₁ - - - 17 - - - 1,2-pentanediol n-BO ₃ - - - - 18 - - 1,2-pentanediol2-methylE ₂ - - - - - 17 - 1,2-pentanediol2-methyln-BO ₁ - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LI

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ² 26.6 26.6 - - 26 26 - DEQA ⁵ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,2-pentanediol3-methylE ₂ 18 - - - - - - 1,2-pentanediol3-methyln-BO ₁ - 18 - - - - - 1,2-pentanediol4-methylE ₂ - - 18 - - - - 1,2-pentanediol4-methyln-BO ₁ - - - 17 - - - 1,3-pentanediol 2 (Me-E ₂ ) - - - - 18 - - 1,3-pentanediolPO ₄ - - - - - 17 - 1,3-pentanediol, 2,2-dimethyl- (Me-E ₁ ) - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LII

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ³ 26.6 26.6 - - 26 26 - DEQA ⁵ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,3-pentanediol2,3-dimethyl- (Me-E ₁ ) 18 - - - - - - 1,3-pentanediol2,3-dimethyl-PO ₁ - 18 - - - - - 1,3-pentanediol2,4-dimethyl- (Me-E ₁ ) - - 18 - - - - 1,3-pentanediol2,4-dimethyl-PO ₁ - - - 17 - - - 1,3-pentanediol, 2-ethyl-E ₆ - - - - 18 - - 1,3-pentanediol, 2-ethyl-PO ₁ - - - - - 17 - 1,3-pentanediol, 2-methyl-2 (Me-E ₄ ) - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LIII

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ⁴ 26.6 26.6 - - 26 26 - DEQA ⁵ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,3-pentanediol, 2-methyl-PO ₂ 18 - - - - - - 1,3-pentanediol, 2-methyl-BO ₁ - 18 - - - - - 1,3-pentanediol3,4-dimethyl- (Me-E ₁ ) - - 18 - - - - 1,3-pentanediol3,4-dimethyl-PO ₁ - - - 17 - - - 1,3-pentanediol, 3-methyl-2 (Me-E ₄ ) - - - - 18 - - 1,3-pentanediol, 3-methyl-PO ₃ - - - - - 17 - 1,3-pentanediol, 3-methylBO ₁ - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LIV

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁵ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,3-pentanediol, 4,4-dimethyl- (Me-E ₁ ) 18 - - - - - - 1,3-pentanediol4,4-dimethyl-PO ₁ - 18 - - - - - 1,3-pentanediol, 4-methyl-PO ₃ - - 18 - - - - 1,3-pentanediol, 4-methyl-BO ₁ - - - 17 - - - 1,4-pentanediol 2 (Me-E ₂ ) - - - - 18 - - 1,4-pentanediolPO ₃ - - - - - 17 - 1,4-pentanediol, 2,2-dimethyl- (Me-E ₁ ) - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LV

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁶ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,4-pentanediol, 2,2-dimethyl-PO ₁ 18 - - - - - - 1,4-pentanediol, 2,3-dimethyl- (Me-E ₁ ) - 18 - - - - - 1,4-pentanediol, 2,3-dimethyl-PO ₁ - - 18 - - - - 1,4-pentanediol, 2,4-dimethyl- (Me-E ₁ ) - - - 17 - - - 1,4-pentanediol, 2,4-dimethyl-PO ₁ - - - - 18 - - 1,4-pentanediol, 2-methyl-2 (Me-E ₄ ) - - - - - 17 - 1,4-pentanediol, 2-methyl-PO ₃ - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LVI

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ⁵ 26.6 26.6 - - 26 26 - DEQA ² - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,4-pentanediol, 2-methyl-BO ₁ 18 - - - - - - 1,4-pentanediol, 3,3-dimethyl- (Me-E ₁ ) - 18 - - - - - 1,4-pentanediol, 3,3-dimethyl-PO ₁ - - 18 - - - - 1,4-pentanediol, 3,4-dimethyl- (Me-E ₁ ) - - - 17 - - - 1,4-pentanediol, 3,4-dimethyl-PO ₁ - - - - 18 - - 1,4-pentanediol, 3-methyl-2 (Me-E ₄ ) - - - - - 17 - 1,4-pentanediol, 3-methyl-PO ₃ - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LVII

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ⁵ 26.6 26.6 - - 26 26 - DEQA ³ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,4-pentanediol, 3-methyl-BO ₁ 18 - - - - - - 1,4-pentanediol, 4-methyl-2 (Me-E ₄ ) - 18 - - - - - 1,4-pentanediol, 4-methyl-PO ₃ - - 18 - - - - 1,4-pentanediol, 4-methyl-BO ₁ - - - 17 - - - 1,5-pentanediol (Me-E ₆ ) - - - - 18 - - 1,5-pentanediol 2 (Me-E ₁ ) - - - - - 17 - 1,5-pentanediolPO ₃ - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LVIII

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ⁵ 26.6 26.6 - - 26 26 - DEQA ⁴ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,5-pentanediol, 2,2-dimethyl-E ₅ 18 - - - - - - 1,5-pentanediol, 2,2-dimethyl-PO ₁ - 18 - - - - - 1,5-pentanediol, 2,3-dimethyl-E ₄ - - 18 - - - - 1,5-pentanediol, 2,3-dimethyl-PO ₁ - - - 17 - - - 1,5-pentanediol, 2,4-dimethyl-E ₅ - - - - 18 - - 1,5-pentanediol, 2,4-dimethyl-PO ₁ - - - - - 17 - 1,5-pentanediol, 2-ethyl-E ₄ - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LIX

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁵ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,5-pentanediol, 2-methyl- (Me-E ₂ ) 18 - - - - - - 1,5-pentanediol, 2-methyl-PO ₂ - 18 - - - - - 1,5-pentanediol, 3,3-dimethyl-E ₄ - - 18 - - - - 1,5-pentanediol, 3,3-dimethyl-PO ₁ - - - 17 - - - 1,5-pentanediol, 3-methyl- (MeE ₂ ) - - - - 18 - - 1,5-pentanediol, 3-methyl-PO ₂ - - - - - 17 - 2,3-pentanediol (Me-E ₂ ) - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LX

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁶ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 2,3-pentanediol PO ₂ 18 - - - - - - 2,3-pentanediol, 2-methyl-E ₄ - 18 - - - - - 2,3-pentanediol, 2-methyl-PO ₁ - - 18 - - - - 2,3-pentanediol, 2-methyl-n-BO ₂ - - - 17 - - - 1,3-pentanediol, 2,2-dimethyl-PO ₁ - - - - 18 - - 2,3-pentanediol, 3-methyl-E ₄ - - - - - 17 - 2,3-pentanediol, 3-methyl-PO ₁ - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LXI

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ² - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,4-butanediol, 3-ethyl-1-methyl-n-BO ₂ 18 - - - - - - 2,3-pentanediol, 3-methyl-n-BO ₂ - 18 - - - - - 2,3-pentanediol, 4-methyl-E ₄ - - 18 - - - - 2,3-pentanediol, 4-methyl-PO ₁ - - - 17 - - - 2,3-pentanediol, 4-methyl-n-BO ₂ - - - - 18 - - 1,3-pentanediol, 2,2-dimethyl-n-BO ₃ - - - - - 17 - 2,4-pentanediol 2 (Me-E ₃ ) - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LXII

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ³ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 2,4-pentanediolPO ₄ 18 - - - - - - 2,4-pentanediol, 2,3-dimethyl- (Me-E ₃ ) - 18 - - - - - 2,4-pentanediol, 2,3-dimethyl-PO ₂ - - 18 - - - - 2,4-pentanediol, 2,4-dimethyl- (Me-E ₃ ) - - - 17 - - - 2,4-pentanediol, 2,4-dimethyl-PO ₂ - - - - 18 - - 2,4-pentanediol, 2-methyl- (Me-E ₈ ) - - - - - 17 - 2,4-pentanediol, 2-methyl-PO ₃ - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LXIII

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁴ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 2,4-pentanediol, 3,3-dimethyl- (Me-E ₂ ) 18 - - - - - - 2,4-pentanediol, 3,3-dimethyl-PO ₂ - 18 - - - - - 2,4-pentanediol, 3-methyl- (Me-E ₈ ) - - 18 - - - - 2,4-pentanediol, 3-methyl-PO ₃ - - - 17 - - - 1,3-hexanediol (Me-E ₃ ) - - - - 18 - - 1,3-hexanediol PO ₂ - - - - - 17 - 1,3-hexanediol BO ₁ - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LXIV

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁵ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,3-hexanediol, 2-methyl-E ₆ 18 - - - - - - 1,3-hexanediol, 2-methyl-PO ₁ - 18 - - - - - 1,3-hexanediol, 3-methyl-E ₆ - - 18 - - - - 1,3-hexanediol, 3-methyl-PO ₁ - - - 17 - - - 1,3-hexanediol, 4-methyl-E ₅ - - - - 18 - - 1,3-hexanediol, 4-methyl-PO ₁ - - - - - 17 - 1,3-hexanediol, 5-methyl-E ₅ - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LXV

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁶ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,3-hexanediol, 5-methyl-PO ₁ 18 - - - - - - 1,4-hexanediol (Me-E ₃ ) - 18 - - - - - 1,4-hexanediol BO ₁ - - 18 - - - - 1,4-hexanediol PO ₂ - - - 17 - - - 1,4-hexanediol, 2-methyl-E ₆ - - - - 18 - - 1,4-hexanediol, 2-methyl-PO ₁ - - - - - 17 - 1,4-hexanediol, 3-methyl-E ₆ - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LXVI

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ² 26.6 26.6 - - 26 26 - DEQA ⁵ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,4-hexanediol, 3-methyl-PO ₁ 18 - - - - - - 1,4-hexanediol, 4-methyl-E ₆ - 18 - - - - - 1,4-hexanediol, 4-methyl-PO ₁ - - 18 - - - - 1,4-hexanediol, 5-methyl-E ₆ - - - 17 - - - 1,4-hexanediol, 5-methyl-PO ₁ - - - - 18 - - 1,5-hexanediol (Me-E ₃ ) - - - - - 17 - 1,5-hexanediol PO ₂ - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LXVII

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ³ 26.6 26.6 - - 26 26 - DEQA ⁵ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,5-hexanediol BO ₁ 18 - - - - - - 1,5-hexanediol, 2-methyl-E ₆ - 18 - - - - - 1,5-hexanediol, 2-methyl-PO ₁ - - 18 - - - - 1,5-hexanediol, 3-methyl-E ₆ - - - 17 - - - 1,5-hexanediol, 3-methyl-PO ₁ - - - - 18 - - 1,5-hexanediol, 4-methyl-E ₅ - - - - - 17 - 1,5-hexanediol, 4-methyl-PO ₁ - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LXVIII

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ⁴ 26.6 26.6 - - 26 26 - DEQA ⁵ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,5-hexanediol, 5-methyl-E ₅ 18 - - - - - - 1,5-hexanediol, 5-methyl-PO ₁ - 18 - - - - - 1,6-hexanediol (Me-E ₂ ) - - 18 - - - - 1,6-hexanediolPO ₂ - - - 17 - - - 1,6-hexanediol, 2-methyl-E ₃ - - - - 18 - - 1,6-hexanediol, 3-methyl-E ₃ - - - - - 17 - 2,3-hexanediol E ₃ - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LXIX

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁵ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 2,3-hexanediol n-BO ₁ 18 - - - - - - 2,4-hexanediol (Me-E ₅ ) - 18 - - - - - 2,4-hexanediol PO ₃ - - 18 - - - - 2,4-hexanediol, 2-methyl- (Me-E ₂ ) - - - 17 - - - 2,4-hexanediol, 2-methyl-PO ₂ - - - - 18 - - 2,4-hexanediol, 3-methyl- (Me-E ₂ ) - - - - - 17 - 2,4-hexanediol3-methyl-PO ₂ - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LXX

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ⁵ 26.6 26.6 - - 26 26 - DEQA ⁶ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 2,4-hexanediol, 4-methyl- (Me-E ₂ ) 18 - - - - - - 2,4-hexanediol4-methylPO ₂ - 18 - - - - - 2,4-hexanediol, 5-methyl (Me-E ₂ ) - - 18 - - - - 2,4-hexanediol, 5-methyl-PO ₂ - - - 17 - - - 2,5-hexanediol (Me-E ₅ ) - - - - 18 - - 2,5-hexanediol PO ₃ - - - - - 17 - 2,5-hexanediol, 2-methyl- (Me-E ₂ ) - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LXXI

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ - 26.6 - 20.0 20.0 20.0 20.0 DEQA ² 26 - 27 6.8 6.8 6.8 6.8 ethanol 5 4 5.1 4 - - - Isopropanol - - - 2 - - - 2,5-hexanediol2-methyl-PO ₂ 18 - - - - - - 2,5-hexanediol, 3-methyl (Me-E ₂ ) - 18 - - - - - 2,5-hexanediol3-methyl-PO ₁ - - 18 - - - - 3,4-hexanediol E ₃ - - - 17 - - - 3,4-hexanediol n-BO ₁ - - - - 18 - - 4-ethyl-1,2-cyclopentanediol - - - - - 18 - Bis (2-hydroxycyclopentyl) ether - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LXXII

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ³ 26.6 26.6 - - 26 26 - DEQA ¹ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 4,4-dimethyl-1,2-cyclopentadiol 18 - - - - - - 1,3-heptanediol E ₄ - 18 - - - - - 1,3-heptanediol PO ₁ - - 18 - - - - 1,3-heptanediol n-BO ₂ - - - 17 - - - 1,4-heptanediol E ₄ - - - - 18 - - 1,4-heptanediol PO ₁ - - - - - 17 - 1,4-heptanediol n-BO ₂ - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LXXIII

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ⁵ 26.6 26.6 - - 26 26 - DEQA ⁶ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,5-heptanediol E ₄ 18 - - - - - - 1,5-heptanediol PO ₁ - 18 - - - - - 1,5-heptanediol n-BO ₂ - - 18 - - - - 1,6-heptanediol E ₄ - - - 17 - - - 1,6-heptanediol PO ₁ - - - - 18 - - 1,6-heptanediol n-BO ₂ - - - - - 17 - 1,7-heptanediol E ₁ - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LXXIV

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁴ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,7-heptanediol n-BO ₁ 18 - - - - - - 2,4-heptanediol E ₇ - 18 - - - - - 2,4-heptanediol (Me-E ₁ ) - - 18 - - - - 2,4-heptanediol PO ₁ - - - 17 - - - 2,4-heptanediol n-BO ₃ - - - - 18 - - 2,5-heptanediol E ₇ - - - - - 17 - 2,5-heptanediol (Me-E ₁ ) - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LXXV

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ² 26.6 26.6 - - 26 26 - DEQA ⁵ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 3-cyclooctene-1,2-diol 18 - - - - - - 4-cyclooctene-1,2-diol - 18 - - - - - 5-cyclooctene-1,2-diol - - 18 - - - - 4-cyclohexene-1,2-diol, 3,6-dimethyl- - - - 17 - - - 4-cyclohexene-1,2-diol, 4,5-dimethyl- - - - - 18 - - 1,2-cyclobutanediol, 1-ethenyl-2-ethyl- - - - - - 17 - 3-cyclobutene-1,2-diol, 1,2,3,4-tetramethyl- - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LXXVI

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ⁵ 26.6 26.6 - - 26 26 - DEQA ³ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 3-cyclobutene-1,2-diol, 3,4-diethyl- 18 - - - - - - 3-cyclobutene-1,2-diol, 3- (1,1-dimethylethyl)- - 18 - - - - - 3-cyclobutene-1,2-diol, 3-butyl- - - 18 - - - - 1,2-cyclopentanediol, 1,2-dimethyl-4-methylene- - - - 17 - - - 1,2-cyclopentanediol, 1-ethyl-3-methylene- - - - - 18 - - 1,2-cyclopentanediol, 4- (1-propenyl) - - - - - 17 - 3-cyclopentene-1,2-diol, 1-ethyl-3-methyl- - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LXXVII

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ⁵ 26.6 26.6 - - 26 26 - DEQA ⁴ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,2-cyclohexanediol, 1-ethenyl- 18 - - - - - - 1,2-cyclohexanediol, 1-methyl-3-methylene- - 18 - - - - - 1,2-cyclohexanediol, 1-methyl-4-methylene- - - 18 - - - - 1,2-cyclohexanediol, 3-ethenyl- - - - 17 - - - 1,2-cyclohexanediol, 4-ethenyl- - - - - 18 - - 3-cyclohexene-1,2-diol, 2,6-dimethyl- - - - - - 17 - 3-cyclohexene-1,2-diol, 6,6-dimethyl- - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LXXVIII

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ⁶ 26.6 26.6 - - 26 26 - DEQA ¹ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,3-propanediol, 2,2-di-2-propenyl- 18 - - - - - - 1,3-propanediol, 2- (1-pentenyl)- - 18 - - - - - 1,3-propanediol, 2- (2-methyl-2-propenyl) -2- (2-propenyl)- - - 18 - - - - 1,3-propanediol, 2- (3-methyl-1-butenyl)- - - - 17 - - - 1,3-propanediol, 2- (4-pentenyl)- - - - - 18 - - 1,3-propanediol, 2-ethyl-2- (2-methyl-2-propenyl)- - - - - - 17 - 1,3-propanediol, 2-ethyl-2 (2-propenyl)- - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LXXIX

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁵ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,3-propanol, 2-methyl-2- (3-methyl-3-butenyl)- 18 - - - - - - 1,3-butanediol, 2,2-diallyl- - 18 - - - - - 1,3-butanediol, 2- (1-ethyl-1-propenyl)- - - 18 - - - - 1,3-butanediol, 2- (2-butenyl) -2-methyl- - - - 17 - - - 1,3-butanediol, 2- (3-methyl-2-butenyl)- - - - - 18 - - 1,3-butanediol, 2-ethyl-2- (2-propenyl)- - - - - - 17 - 1,3-butanediol, 2-methyl-2- (1-methyl-2-propenyl)- - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LXXX

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ² 26.6 26.6 - - 26 26 - DEQA ⁵ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,4-butanediol, 2,3-bis (1-methylethylidene)- 18 - - - - - - 1,4-butanediol, 2- (3-methyl-2-butenyl) -3-methylene- - 18 - - - - - 2-butene-1,4-diol, 2- (1,1-dimethylpropyl)- - - 18 - - - - 2-butene-1,4-diol, 2- (1-methylpropyl)- - - - 17 - - - 2-butene-1,4-diol, 2-butyl- - - - - 18 - - 1,3-pentanediol, 2-ethenyl-3-ethyl- - - - - - 17 - 1,3-pentanediol, 2-ethenyl-4,4-dimethyl- - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LXXXI

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ³ 26.6 26.6 - - 26 26 - DEQA ⁵ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,4-pentanediol, 3-methyl-2- (2-propenyl)- 18 - - - - - - 1,5-pentanediol, 2- (1-propenyl)- - 18 - - - - - 1,5-pentanediol, 2- (2-propenyl)- - - 18 - - - - 1,5-pentanediol, 2-ethylidene-3-methyl- - - - 17 - - - 1,5-pentanediol, 2-propylidene- - - - - 18 - - 2,4-pentanediol, 3-ethylidene-2,4-dimethyl- - - - - - 17 - 4-pentene-1,3-diol, 2- (1,1-dimethylethyl)- - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LXXXII

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ⁴ 26.6 26.6 - - 26 26 - DEQA ⁵ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 4-pentene-1,3-diol, 2-ethyl-2,3-dimethyl- 18 - - - - - - 1,4-hexanediol, 4-ethyl-2-methylene- - 18 - - - - - 1,5-hexadiene-3,4-diol, 2,3,5-trimethyl- - - 18 - - - - 1,5-hexadiene-3,4-diol, 5-ethyl-3-methyl- - - - 17 - - - 1,5-hexanediol, 2- (1-methylethenyl)- - - - - 18 - - 1,6-hexanediol, 2-ethenyl- - - - - - 17 - 1-hexene-3,4-diol, 5,5-dimethyl- - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LXXXIII

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ⁵ 26.6 26.6 - - 26 26 - DEQA ¹ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1-hexene-3,4-diol, 5,5-dimethyl- 18 - - - - - - 2-hexene-1,5-diol, 4-ethenyl-2,5-dimethyl- - 18 - - - - - 3-hexene-1,6-diol, 2-ethenyl-2,5-dimethyl- - - 18 - - - - 3-hexene-1,6-diol, 2-ethyl- - - - 17 - - - 3-hexene-1,6-diol, 3,4-dimethyl- - - - - 18 - - 4-hexene-2,3-diol, 2,5-dimethyl- - - - - - 17 - 4-hexene-2,3-diol, 3,4-dimethyl- - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LXXXIV

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ⁶ 26.6 26.6 - - 26 26 - DEQA ¹ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 5-hexene-1,3-diol, 3- (2-propenyl)- 18 - - - - - - 5-hexene-2,3-diol, 2,3-dimethyl- - 18 - - - - - 5-hexene-2,3-diol, 3,4-dimethyl- - - 18 - - - - 5-hexene-2,3-diol, 3,5-dimethyl- - - - 17 - - - 5-hexene-2,4-diol, 3-ethenyl-2,5-dimethyl- - - - - 18 - - 1,4-heptanediol, 6-methyl-5-methylene- - - - - - 17 - 1,5-heptadiene-3,4-diol, 2,3-dimethyl- - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LXXXV

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ² - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,5-heptadiene-3,4-diol, 2,5-dimethyl- 18 - - - - - - 1,5-heptadiene-3,4-diol, 3,5-dimethyl- - 18 - - - - - 1,7-heptanediol, 2,6-bis (methylene)- - - 18 - - - - 1,7-heptanediol, 4-methylene- - - - 17 - - - 1-heptene-3,5-diol, 2,4-dimethyl- - - - - 18 - - 1-heptene-3,5-diol, 2,6-dimethyl- - - - - - 17 - 1-heptene-3,5-diol, 3-ethenyl-5-methyl - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LXXXVI

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ³ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1-heptene-3,5-diol, 6,6-dimethyl- 18 - - - - - - 2,4-heptadiene-2,6-diol, 4,6-dimethyl- - 18 - - - - - 2,5-heptadiene-1,7-diol, 4,4-dimethyl- - - 18 - - - - 2,6-heptadiene-1,4-diol, 2,5,5-trimethyl- - - - 17 - - - 2-heptene-1,4-diol, 5,6-dimethyl- - - - - 18 - - 2-heptene-1,5-diol, 5-ethyl- - - - - - 17 - 2-heptene-1,7-diol, 2-methyl- - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LXXXVII

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁴ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 3-heptene-1,5-diol, 4,6-dimethyl- 18 - - - - - - 3-heptene-1,7-diol, 3-methyl-6-methylene- - 18 - - - - - 3-heptene-2,5-diol, 2,4-dimethyl- - - 18 - - - - 3-heptene-2,5-diol, 2,5-dimethyl- - - - 17 - - - 3-heptene-2,6-diol, 2,6-dimethyl- - - - - 18 - - 3-heptene-2,6-diol, 4,6-dimethyl- - - - - - 17 - 5-heptene-1,3-diol, 2,4-dimethyl- - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LXXXVIII

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁵ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 5-heptene-1,3-diol, 3,6-dimethyl- 18 - - - - - - 5-heptene-1,4-diol, 2,6-dimethyl- - 18 - - - - - 5-heptene-1,4-diol, 3,6-dimethyl- - - 18 - - - - 5-heptene-2,4-diol, 2,3-dimethyl- - - - 17 - - - 6-heptene-1,3-diol, 2,2, -dimethyl- - - - - 18 - - 6-heptene-1,4-diol, 4- (2-propenyl)- - - - - - 17 - 6-heptene-1,4-diol, 5,6-dimethyl- - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LXXXIX

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ⁵ 26.6 26.6 - - 26 26 - DEQA ² - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 6-heptene-1,5-diol, 2,4-dimethyl- 18 - - - - - - 6-heptene-1,5-diol, 2-ethylidene-6-methyl- - 18 - - - - - 6-heptene-2,4-diol, 4- (2-propenyl)- - - 18 - - - - 6-heptene-2,4-diol, 5,5-dimethyl- - - - 17 - - - 6-heptene-2,5-diol, 4,6-dimethyl- - - - - 18 - - 6-heptene-2,5-diol, 5-ethenyl-4-methyl- - - - - - 17 - 1,3-octanediol, 2-methylene- - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LXXXX

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ³ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,6-octadiene-3,5-diol, 2,6-dimethyl- 18 - - - - - - 1,6-octadiene-3,5-diol, 3,7-dimethyl- - 18 - - - - - 1,7-octadiene-3,6-diol, 2,6-dimethyl- - - 18 - - - - 1,7-octadiene-3,6-diol, 2,7-dimethyl- - - - 17 - - - 1,7-octadiene-3,6-diol, 3,6-dimethyl- - - - - 18 - - 1-octene-3,6-diol, 3-ethenyl- - - - - - 17 - 2,4,6-octatriene-1,8-diol, 2,7-dimethyl- - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LXXXXI

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ⁵ 26.6 26.6 - - 26 26 - DEQA ⁵ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 2,4-octadiene-1,7-diol, 3,7-dimethyl- 18 - - - - - - 2,5-octadiene-1,7-diol, 2,6-dimethyl- - 18 - - - - - 2,5-octadiene-1,7-diol, 3,7-dimethyl- - - 18 - - - - 2,6-octadiene-1,4-diol, 3,7-dimethyl- (rosiridol) - - - 17 - - - 2,6-octadiene-1,8-diol, 2-methyl- - - - - 18 - - 2,7-octadiene-1,4-diol, 3,7-dimethyl- - - - - - 17 - 2,7-octadiene-1,5-diol, 2,6-dimethyl- - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LXXXXII

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ⁵ 26.6 26.6 - - 26 26 - DEQA ⁶ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 2,7-octadiene-1,6-diol, 2,6-dimethyl- (8-hydroxylinaloyl) 18 - - - - - - 2,7-octadiene-1,6-diol, 2,7-dimethyl- - 18 - - - - - 2-octene-1,4-diol - - 18 - - - - 2-octene-1,7-diol - - - 17 - - - 2-octene-1,7-diol, 2-methyl-6-methylene- - - - - 18 - - 1,4-pentanediol, 2,2,4-trimethyln-BO ₁ - - - - - 17 - 3,5-octadiene-1,7-diol, 3,7-dimethyl- - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LXXXXIII

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ² - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 3,5-octadiene-2,7-diol, 2,7-dimethyl- 18 - - - - - - 3,5-octanediol, 4-methylene- - 18 - - - - - 3,7-octadiene-1,6-diol, 2,6-dimethyl- - - 18 - - - - 3,7-octadiene-2,5-diol, 2,7-dimethyl- - - - 17 - - - 3,7-octadiene-2,6-diol, 2,6-dimethyl- - - - - 18 - - 3-octene-1,5-diol, 4-methyl- - - - - - 17 - 3-octene-1,5-diol, 5-methyl- - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LXXXXIV

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ³ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 4,6-octadiene-1,3-diol, 2,2-dimethyl- 18 - - - - - - 4,7-octadiene-2,3-diol, 2,6-dimethyl- - 18 - - - - - 4,7-octadiene-2,6-diol, 2,6-dimethyl- - - 18 - - - - 4-octene-1,6-diol, 7-methyl- - - - 17 - - - 1,4-pentanediol, 2,3,3-trimethyln-BO ₁ - - - - 18 - - 4-octene-1,8-diol, 2,7-bis (methylene)- - - - - - 17 - 4-octene-1,8-diol, 2-methylene- - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LXXXXV

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁴ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 5,7-octadiene-1,4-diol, 2,7-dimethyl- 18 - - - - - - 5,7-octadiene-1,4-diol, 7-methyl- - 18 - - - - - 5-octene-1,3-diol - - 18 - - - - 6-octene-1,3-diol, 7-methyl- - - - 17 - - - 6-octene-1,4-diol, 7-methyl- - - - - 18 - - 6-octene-1,5-diol - - - - - 17 - 6-octene-1,5-diol, 7-methyl- - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LXXXXVI

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁵ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 6-octene-3,5-diol, 2-methyl- 18 - - - - - - 6-octene-3,5-diol, 4-methyl- - 18 - - - - - 7-octene-1,3-diol, 2-methyl- - - 18 - - - - 7-octene-1,3-diol, 4-methyl- - - - 17 - - - 7-octene-1,3-diol, 7-methyl- - - - - 18 - - 7-octene-1,5-diol - - - - - 17 - 7-octene-1,6-diol - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LXXXXVII

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁶ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 7-octene-1,6-diol, 5-methyl- 18 - - - - - - 7-octene-2,4-diol, 2-methyl-6-methylene- - 18 - - - - - 7-octene-2,5-diol, 7-methyl- - - 18 - - - - 7-octene-3,5-diol, 2-methyl- - - - 17 - - - 1-nonene-3,5-diol - - - - 18 - - 1-nonene-3,7-diol - - - - - 17 - 1-nonene-3,7-diol - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example LXXXXVIII

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ⁵ 26.6 26.6 - - 26 26 - DEQA ² - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 3-nonene-2,5-diol 18 - - - - - - 3-nonene-2,5-diol - 18 - - - - - 4,6-nonadiene-1,3-diol, 8-methyl- - - 18 - - - - 4-nonene-2,8-diol - - - 17 - - - 6,8-nonadiene-1,5-diol - - - - 18 - - 7-nonene-2,4-diol - - - - - 17 - 8-nonene-2,4-diol - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example IC

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ⁵ 26.6 26.6 - - 26 26 - DEQA ³ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 8-nonene-2,5-diol 18 - - - - - - 1,9-decadiene-3,8-diol - 18 - - - - - 1,9-decadiene-4,6-diol - - 18 - - - - Bis (2-hydroxycyclopentyl) ether - - - 17 - - - 1,2-propanediol, 3-butyloxy-, dibutyleneoxylation - - - - 18 - - 1,2-propanediol, 3-butyloxy-, tributyleneoxylation - - - - - 17 - 1- (3-methylphenyl) -1,3-propanediol - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example C

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ⁵ 26.6 26.6 - - 26 26 - DEQA ⁴ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1- (4-methylphenyl) -1,3-propanediol 18 - - - - - - 2-methyl-1-phenyl-1,3-propanediol - 18 - - - - - 1,2-propanediol, 3- (cyclohexyloxy)- - - 18 - - - - 1,2-propanediol, 3- (1-cyclohex-1-enyloxy)- - - - 17 - - - 1,3-propanol, 2- (pentyloxy)- - - - - 18 - - 1,3-propanediol, 2- (2-pentyloxy)- - - - - - 17 - 1,3-propanediol, 2- (3-pentyloxy)- - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example CI

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ⁵ 26.6 26.6 - - 26 26 - DEQA ⁶ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,3-propanediol, 2- (2-methyl-1-butyloxy)- 18 - - - - - - 1,3-propanediol, 2- (isoamyloxy)- - 18 - - - - - 1,3-propanediol, 2- (3-methyl-2-butyloxy)- - - 18 - - - - 1,3-propanediol, 2- (cyclohexyloxy)- - - - 17 - - - 1,3-propanediol, 2- (1-cyclohex-1-enyloxy)- - - - - 18 - - 1,2-propanediol, 3- (butyloxy)-, triethoxylated - - - - - 17 - 1,2-propanediol, 3- (butyloxy)-, tetraethoxylation - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example CII

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ⁶ 26.6 26.6 - - 26 26 - DEQA ¹ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,2-propanediol, 3- (butyloxy)-, pentaethoxylated 18 - - - - - - 1,2-propanediol, 3- (butyloxy)-, hexaethoxylated - 18 - - - - - 1,2-propanediol, 3- (butyloxy)-, heptaethoxylated - - 18 - - - - 1,2-propanediol, 3- (butyloxy)-, octaethoxylated - - - 17 - - - 1,2-propanediol, 3- (butyloxy)-, nonaethoxylated - - - - 18 - - 2,6-octanediol - - - - - 17 - 3,5-octanediol - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example CIII

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ² - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 4,4-dimethyl-1,2-cyclopentanediol 18 - - - - - - 4-ethyl-1,2-cyclopentanediol - 18 - - - - - 1,1-bis (hydroxymethyl) -cyclohexane - - 18 - - - - 1,2-bis (hydroxymethyl) -cyclohexane - - - 17 - - - 1,2-dimethyl-1,3-cyclohexanediol - - - - 18 - - 1,3-bis (hydroxymethyl) -cyclohexane - - - - - 17 - 1,3-dimethyl-1,3-cyclohexanediol - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example CIV

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ³ 26.6 26.6 - - 26 26 - DEQA ¹ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,6-dimethyl-1,3-cyclohexanediol 18 - - - - - - 1-hydroxycyclohexaneethanol - 18 - - - - - 1-hydroxycyclohexanemethanol - - 18 - - - - 1-ethyl-1,3-cyclohexanediol - - - 17 - - - 1-methyl-1,2-cyclohexanediol - - - - 18 - - 2,2-dimethyl-1,3-cyclohexanediol - - - - - 17 - 2,3-dimethyl-1,4-cyclohexanediol - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example CV

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁴ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 2,4-dimethyl-1,3-cyclohexanediol 18 - - - - - - 2,5-dimethyl-1,3-cyclohexanediol - 18 - - - - - 2,6-dimethyl-1,4-cyclohexanediol - - 18 - - - - 2-ethyl-1,3-cyclohexanediol - - - 17 - - - 2-hydroxycyclohexaneethanol - - - - 18 - - 2-hydroxyethyl-1-cyclohexanol - - - - - 17 - 2-hydroxymethylcyclohexanol - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example CVI

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁵ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 3-hydroxyethyl-1-cyclohexanol 18 - - - - - - 3-hydroxycyclohexaneethanol - 18 - - - - - 3-hydroxymethylcyclohexanol - - 18 - - - - 3-methyl-1,2-cyclohexanediol - - - 17 - - - 4,4-dimethyl-1,3-cyclohexanediol - - - - 18 - - 4,5-dimethyl-1,3-cyclohexanediol - - - - - 17 - 4,6-dimethyl-1,3-cyclohexanediol - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example CVII

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁶ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 4-ethyl-1,3-cyclohexanediol 18 - - - - - - 4-hydroxyethyl-1-cyclohexanol - 18 - - - - - 4-hydroxymethyl-cyclohexanol - - 18 - - - - 4-methyl-1,2-cyclohexanediol - - - 17 - - - 5,5-dimethyl-1,3-cyclohexanediol - - - - 18 - - 5-ethyl-1,3-cyclohexanediol - - - - - 17 - 1,2-cycloheptanediol - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example CVIII

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ⁶ 26.6 26.6 - - 26 26 - DEQA ⁵ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 2-methyl-1,3-cycloheptanediol 18 - - - - - - 2-methyl-1,4-cycloheptanediol - 18 - - - - - 4-methyl-1,3-cycloheptanediol - - 18 - - - - 5-methyl-1,3-cycloheptanediol - - - 17 - - - 5-methyl-1,4-cycloheptanediol - - - - 18 - - 6-methyl-1,4-cycloheptanediol - - - - - 17 - 1,3-cyclooctanediol - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example CIX

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ⁵ 26.6 26.6 - - 26 26 - DEQA ² - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,4-cyclooctanediol 18 - - - - - - 1,5-cyclooctanediol - 18 - - - - - 1,2-cyclohexanediol, diethoxylate - - 18 - - - - 1,2-cyclohexanediol, triethoxylate - - - 17 - - - 1,2-cyclohexanediol, tetraethoxylate - - - - 18 - - 1,2-cyclohexanediol, pentaethoxylate - - - - - 17 - 1,2-cyclohexanediol, hexaethoxylate - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example CX

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ⁵ 26.6 26.6 - - 26 26 - DEQA ³ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,2-cyclohexanediol, heptaethoxylate 18 - - - - - - 1,2-cyclohexanediol, octaethoxylate - 18 - - - - - 1,2-cyclohexanediol, nonaethoxylate - - 18 - - - - 1,2-cyclohexanediol, monopropoxylate - - - 17 - - - 1,2-cyclohexanediol, monobutyleneoxylate - - - - 18 - - 1,2-cyclohexanediol, dibutyleneoxylate - - - - - 17 - 1,2-cyclohexanediol, tributyleneoxylate - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example CXI

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ⁴ 26.6 26.6 - - 26 26 - DEQA ⁵ - - 26 26 - - 26 ethanol 2.3 6 6 6 - 4 6 Isopropanol - - - - 6 2 - 1,2-hexanediol 16 - - 8 - - - 1-phenyl-1,2-propanediol - 18 - - - - - 2-phenyl-1,2-propanediol - - 18 8 - - - 3-phenyl-1,2-propanediol - - - - 18 - - 1- (3-methylphenyl) -1,3-propanediol - - - - - 18 - 1- (4-methylphenyl) -1,3-propanediol - - - - - - 18 MgCl ₂ 0.125 - - - - - - HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example CXII

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁶ - - 26 26 - - 26 ethanol 6 6 6 6 - 4 6 Isopropanol - - - - 6 2 - 2-methyl-1-phenyl-1,3-propanediol 18 - - - - - - 1-phenyl-1,3-butanediol - 18 - - - - - 3-phenyl-1,3-butanediol - - 18 - - - - 1-phenyl-1,4-butanediol - - - 18 - - - 2-phenyl-1,4-butanediol - - - - 18 - - 1-phenyl-2,3-butanediol - - - - - 18 - 1,2-propanediol, 3-phenyloxy- - - - - - - 18 MgCl ₂ 0.125 - - - - - - HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example CXIII

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26.6 26.6 - DEQA ² - - 26.6 26.6 - - 26.6 ethanol 4 6 4 6 - 4 6 Isopropanol - - - - 6 2 - Propylene carbonate 2 - 2 - - - - 1,2-propanediol, 3-benzyloxy- 18 1,2-propanediol, 3- (2-phenylethyloxy)- - 18 - - - - - 1,2-propanediol, 3- (1-phenyl-2-propanoloxy)- - - 18 - - - - 1,3-propanediol, 2-phenyloxy- - - - 18 - - - 1,3-propanediol, 2- (m-cresyloxy)- - - - - 18 - - 1,3-propanediol, 2- (p-cresyloxy)- - - - - - 18 - 1,3-propanediol, 2-benzyloxy- - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example CXIV

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ³ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,3-propanediol, 2- (2-phenylethyloxy)- 18 - - - - - - 1,3-propanediol, 2- (1-phenylethyloxy)- - 18 - - - - - 1,3-butanediol, 3-methyl-2-isopropyl-PO ₁ - - 18 - - - - 2,4-pentanediol, 2,3,3-trimethyl-PO ₁ - - - 17 - - - 1,3-butanediol, 2,2-diethyl-n-BO ₂ - - - - 18 - - 1,3-butanediol, 2,2-diethyl-E ₄ - - - - - 17 - 1,3-butanediol, 2-ethyl-2,3-dimethyl-n-BO ₁ - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example CXV

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁴ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,3-butanediol, 2-methyl-2-isopropyl-n-BO ₁ 18 - - - - - - 1,3-pentanediol, 2,2,3-trimethyl-n-BO ₁ - 18 - - - - - 1,3-pentanediol, 2,2,4-trimethyl-n-BO ₁ - - 18 - - - - 2,4-hexanediol, 2,3-dimethyl-n-BO ₂ - - - 17 - - - 2,4-hexanediol, 2,3-dimethyl-E ₄ - - - - 18 - - 2,4-hexanediol, 2,4-dimethyl-n-BO ₁ - - - - - 17 - 2,4-hexanediol, 2,4-dimethyl-E ₃ - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example CXVI

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁵ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 2,4-hexanediol, 2,5-dimethyl-n-BO ₂ 18 - - - - - - 2,4-hexanediol, 2,5-dimethyl-E ₄ - 18 - - - - - 2,4-hexanediol, 3,3-dimethyl-n-BO ₂ - - 18 - - - - 2,4-hexanediol, 3,3-dimethyl-E ₃ - - - 17 - - - 2,4-hexanediol, 3,4-dimethyl-n-BO ₂ - - - - 18 - - 2,4-hexanediol, 3,4-dimethyl-E ₄ - - - - - 17 - 2,4-hexanediol, 3,5-dimethyl-n-BO ₁ - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example CXVII

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ⁵ 26.6 26.6 - - 26 26 - DEQA ² - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 2,4-hexanediol, 3,5-dimethyl-E ₃ 18 - - - - - - 2,4-hexanediol, 4,5-dimethyl-n-BO ₂ - 18 - - - - - 2,4-hexanediol, 4,5-dimethyl-E ₄ - - 18 - - - - 2,4-hexanediol, 5,5-dimethyl-n-BO ₂ - - - 17 - - - 2,4-hexanediol, 5,5-dimethyl-E ₃ - - - - 18 - - 2,5-hexanediol, 2,3-dimethyl-n-BO ₁ - - - - - 17 - 2,5-hexanediol, 2,3-dimethyl-E ₄ - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example CXVIII

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ⁵ 26.6 26.6 - - 26 26 - DEQA ³ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 2,5-hexanediol, 2,4-dimethyl-n-BO ₁ 17 - - - - - - 2,5-hexanediol, 2,4-dimethyl-E ₄ - 18 - - - - - 2,5-hexanediol, 2,5-dimethyl-n-BO ₂ - - 18 - - - - 2,5-hexanediol, 2,5-dimethyl-E ₄ - - - 18 - - - 2,5-hexanediol, 3,3-dimethyl-n-BO ₁ - - - - 17 - - 2,5-hexanediol, 3,3-dimethyl-E ₄ - - - - - 18 - 2,5-hexanediol, 3,4-dimethyl-n-BO ₂ - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example CXIX

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ⁵ 26.6 26.6 - - 26 26 - DEQA ⁴ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 2,5-hexanediol, 3,4-dimethyl-E ₄ 18 - - - - - - 3,5-heptanediol, 3-methyl-n-BO ₁ - 18 - - - - - 3,5-heptanediol, 3-methyl-E ₃ - - 18 - - - - 1,3-propanediol, 2- (1,2-dimethylpropyl) -E ₃ - - - 17 - - - 1,3-butanediol, 2-ethyl-2,3-dimethyl-E ₃ - - - - 18 - - 1,3-butanediol, 2-methyl-2-isopropyl-E ₃ - - - - - 17 - 1,4-butanediol, 3-methyl-2-isopropyl-E ₃ - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example CXX

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁶ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,3-pentanediol, 2,2,3-trimethyl-E ₃ 18 - - - - - - 1,3-pentanediol, 2,2,4-trimethyl-E ₃ - 18 - - - - - 1,3-pentanediol, 2,4,4-trimethyl-E ₃ - - 18 - - - - 1,3-pentanediol, 3,4,4-trimethyl-E ₃ - - - 17 - - - 1,4-pentanediol, 2,2,3-trimethyl-E ₃ - - - - 18 - - 1,4-pentanediol, 2,2,4-trimethyl-E ₃ - - - - - 17 - 1,4-pentanediol, 2,3,3-trimethyl-E ₃ - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example CXXI

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ² - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,4-pentanediol, 3,3,4-trimethyl-E ₃ 18 - - - - - - 1,3-pentanediol, 2,4,4-trimethyl-n-BO ₁ - 18 - - - - - 2,4-pentanediol, 2,3,4-trimethyl-E ₃ - - 18 - - - - 1,3-pentanediol, 3,4,4-trimethyl-n-BO ₁ - - - 17 - - - 1,3-propanol, 2- (1,2-dimethylpropyl) -n-BO ₁ - - - - 18 - - 2,4-hexanediol, 4-ethyl-E ₂ - - - - - 17 - 2,4-hexanediol, 4-ethyl-E ₂ - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example CXXII

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ³ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 2,4-heptanediol, 2-methyl-E ₂ 18 - - - - - - 2,4-heptanediol, 3-methyl-E ₂ - 18 - - - - - 2,4-heptanediol, 4-methyl-E ₂ - - 18 - - - - 2,4-heptanediol, 5-methyl-E ₂ - - - 17 - - - 2,4-heptanediol, 6-methyl-E ₂ - - - - 18 - - 2,5-heptanediol, 2-methyl-E ₂ - - - - - 17 - 2,5-heptanediol, 3-methyl-E ₂ - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example CXXIII

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁴ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 2,5-heptanediol, 4-methyl-E ₂ 18 - - - - - - 2,5-heptanediol, 5-methyl-E ₂ - 18 - - - - - 2,5-heptanediol, 6-methyl-E ₂ - - 18 - - - - 2,6-heptanediol, 2-methyl-E ₂ - - - 17 - - - 2,6-heptanediol, 3-methyl-E ₂ - - - - 18 - - 2,6-heptanediol, 4-methyl-E ₂ - - - - - 17 - 3,5-heptanediol, 2-methyl-E ₂ - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example CXXIV

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁵ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,4-butanediol, 3-methyl-2-isopropyl-n-BO ₁ 18 - - - - - - 1,4-pentanediol, 2,2,3-trimethyl-n-BO ₁ - 18 - - - - - 2,4-hexanediol, 4-ethyl-n-BO ₁ - - 18 - - - - 2,4-hexanediol, 4-ethyl-n-BO ₁ - - - 17 - - - 2,4-heptanediol, 2-methyl-n-BO ₁ - - - - 18 - - 2,4-heptanediol, 3-methyl-n-BO ₁ - - - - - 17 - 2,4-heptanediol, 4-methyl-n-BO ₁ - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example CXXV

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁶ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 2,4-heptanediol, 5-methyl-n-BO ₁ 18 - - - - - - 2,4-heptanediol, 6-methyl-n-BO ₁ - 18 - - - - - 2,5-heptanediol, 2-methyl-n-BO ₁ - - 18 - - - - 2,5-heptanediol, 3-methyl-n-BO ₁ - - - 17 - - - 2,5-heptanediol, 4-methyl-n-BO ₁ - - - - 18 - - 2,5-heptanediol, 5-methyl-n-BO ₁ - - - - - 17 - 2,5-heptanediol, 6-methyl-n-BO ₁ - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example CXXVI

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ² 26.6 26.6 - - 26 26 - DEQA ⁵ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 2,6-heptanediol, 2-methyl-n-BO ₁ 18 - - - - - - 2,6-heptanediol, 3-methyl-n-BO ₁ - 18 - - - - - 2,6-heptanediol, 4-methyl-n-BO ₁ - - 18 - - - - 3,5-heptanediol, 2-methyl- (C8) n-BO ₁ - - - 17 - - - 1,2-hexanediol - - - - 8 8 8 1,3-pentanediol, 2,2,4-trimethyl- - - - - 8 - - 1,3-hexanediol, 2-ethyl- - - - - - 8 8 Spices 1.2 1.35 1.2 1.35 1.2 1.35 1.3 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example CXXVII

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ³ 26.6 26.6 - - 26.6 26.6 - DEQA ⁵ - - 26 26 - - 26 ethanol 4 2.3 6 4 - 4 2 Isopropanol - - - 4 2 1,2-hexanediol 10 10 10 10 12 9 9 1,3-propanediol, 2-ethyl- 7 - - - - - - 1,3-propanediol, 2-methyl-2-propyl- - 8 - - - - - 1,3-butanediol, 2,3-dimethyl- - - 6 - - - - 1,3-pentanediol, 2-methyl- - - - 7 - - - 2,4-pentanediol, 2-methyl- - - - - 6 - - 2,4-hexanediol - - - - - 8 - 2,4-hexanediol, 5-methyl- - - - - - - 8 Spices One One One 1.35 1.35 1.35 1.2 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example CXXVIII

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ⁴ 26.6 26.6 - - 26 26 - DEQA ⁵ - - 26 26 - - 26 ethanol 4 4 4 4 - 4 6 Isopropanol - - 2 - 2 - 1,3-pentanediol, 2,2,4-trimethyl- 10 - 9 - 10 10 - 1,3-pentanediol, 2,2,4-trimethyl-E ₂ - 10 - 9 - - 10 1,3-propanediol, 2-ethyl- 8 8 - - - - - 1,3-butanediol, 2,3-dimethyl- - - 9 - - - - 1,3-pentanediol, 2-methyl- - - - 9 - - - 2,4-pentanediol, 2-methyl- - - - - 9 - - 2,4-hexanediol - - - - - 7 - 2,4-hexanediol, 5-methyl- - - - - - - 8 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example CXXIX

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ⁸ (hydroxyethyl ester quart) 29.8 29.8 29.8 - 29.8 29.8 - DEQA ⁹ (propyl ester quart) - - - 29.6 - - 29.6 ethanol 2 2 2 - - 3 2 Isopropanol - - - 2 2 - 1,2-hexanediol 16 - - 17 8 8 8 1,3-hexanediol, 2-ethyl- - 16 - - 8 - 8 1.3-pentanediol, 2,2,4-trimethyl- - - 16 - - 8 - CaCl ₂ - 0.125 - - - - - MgCl ₂ - - 0.125 - - - - HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

DEQA ⁸ di (acyloxyethyl) (2-hydroxyethyl) methyl ammonium methyl sulfate, wherein the acyl group is identical to the acyl group of DEQA ¹ and is about 89.4% active in ethanol.

DEQA ⁹ 1,2-di (oleoyloxy) -3-trimethylammoniotropane chloride, wherein the acyl group is identical to the acyl group of DEQA ⁵ and is about 88% active in ethanol.

Example CXXX

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁶ - - 26 26 - - 26 ethanol 4 6 6 6 4 - 4 1,2-hexanediol 9 8 10 8 - 10 9 1,3-propanediol, 2,2,4-trimethyl- - - - - 9 - - 1,2-propanediol, 3- (n-pentyloxy)- 8 - - - - - - 1,2-propanediol, 3-cyclohexyloxy- - 8 - - - - - Bis (2-hydroxybutyl) ether - - 6 - - - - 1,2-propanediol, 3-benzyloxy- - - - 8 - - - 1,2-bis (hydroxymethyl) -cyclohexane - - - - 8 - - 1,2-propanediol, 2-phenyl- - - - - - - - 2,6-octadiene-1,4-diol, 3,7-dimethyl- - - - - - - 8 CaCl ₂ - - - - - 0.25 - HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example CXXXI

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ³ 26.6 26.6 - - 26 26 - DEQA ¹ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 2,5-heptanediol PO ₁ 18 - - - - - - 2,5-heptanediol n-BO ₃ - 18 - - - - - 2,6-heptanediol E ₇ - - 18 - - - - 2,6-heptanediol (Me-E ₁ ) - - - 17 - - - 2,6-heptanediol PO ₁ - - - - 18 - - 2,6-heptanediol-n-BO ₃ - - - - - 17 - 2,7-heptanediol E ₇ - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example CXXXII

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ⁵ 26.6 26.6 - - 26 26 - DEQA ⁶ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 2,7-heptanediol (Me-E ₁ ) 18 - - - - - - 2,7-heptanediol PO ₁ - 18 - - - - - 2,7-heptanediol-n-BO ₃ - - 18 - - - - 1,3-propanediol, 2,2-diethyl-n-BO ₂ - - - 17 - - - 1,3-propanediol, 2- (1-methylpropyl) -n-BO ₂ - - - - 18 - - 1,3-propanediol, 2- (2-methylpropyl) -n-BO ₂ - - - - - 17 - 1,3-butanediol, 2-ethyl-2-methyl-n-BO ₃ - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example CXXXIII

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁴ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,3-propanediol, 2-methyl-2-isopropyl-n-BO ₂ 18 - - - - - - 1,3-propanediol, 2-methyl-2-propyl-n-BO ₂ - 18 - - - - - 1,2-butanediol (Me-E ₆ ) - - 18 - - - - 1,2-butanediolPO ₂ - - - 17 - - - 1,2-butanediolBO ₁ - - - - 18 - - 1,2-butanediol, 2,3-dimethylE ₄ - - - - - 17 - 1,2-butanediol, 2,3-dimethyln-BO ₁ - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example CXXXIV

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ⁵ 26.6 26.6 - - 26 26 - DEQA ³ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,3-butanediol, 2-ethyl-3-methyl-n-BO ₃ `` 18 - - - - - - 1,3-butanediol, 2-isopropyl-n-BO ₃ - 18 - - - - - 1,3-butanediol, 2-propyl-n-BO ₃ - - 18 - - - - 1,4-butanediol, 2,2,3-trimethyl-n-BO ₂ - - - 17 - - - 1,4-butanediol, 2-ethyl-2-methyl-n-BO ₂ - - - - 18 - - 1,4-butanediol, 2-ethyl-3-methyl-n-BO ₂ - - - - - 17 - 1,4-butanediol, 2-isopropyl-n-BO ₂ - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example CXXXV

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ⁵ 26.6 26.6 - - 26 26 - DEQA ⁴ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,4-butanediol, 2-propyl-n-BO ₁ 18 - - - - - - 1,3-pentanediol, 2,4-dimethyl-n-BO ₃ - 18 - - - - - 1,3-pentanediol, 2-ethyl-n-BO ₂ - - 18 - - - - 1,3-pentanediol, 3,4-dimethyl-n-BO ₃ - - - 17 - - - 1,3-pentanediol, 4,4-dimethyl-n-BO ₃ - - - - 18 - - 1,3-pentanediol, 4-methyl- (Me-E ₅ ) - - - - - 17 - 1,4-pentanediol, 2,2-dimethyl-n-BO ₃ - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example CXXXVI

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ² 26.6 26.6 - - 26 26 - DEQA ¹ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,4-pentanediol, 2,3-dimethyl-n-BO ₃ 18 - - - - - - 1,4-pentanediol, 2,4-dimethyl-n-BO ₃ - 18 - - - - - 1,4-pentanediol, 3,3-dimethyl-n-BO ₃ - - 18 - - - - 1,4-pentanediol, 3,4-dimethyl-n-BO ₃ - - - 17 - - - 1,5-pentanediol, 2,2-dimethyl-n-BO ₂ - - - - 18 - - 1,5-pentanediol, 2,3-dimethyl-n-BO ₂ - - - - - 17 - 1,5-pentanediol, 2,4-dimethyl-n-BO ₂ - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example CXXXVII

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ³ 26.6 26.6 - - 26 26 - DEQA ¹ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,5-pentanediol, 2-ethyl-n-BO ₁ 18 - - - - - - 1,5-pentanediol, 3,3-dimethyl-n-BO ₂ - 8 - - - - - 1,3-hexanediol, 2-methyl-n-BO ₂ - - 18 - - - - 1,3-hexanediol, 3-methyl-n-BO ₂ - - - 17 - - - 1,3-hexanediol, 4-methyl-n-BO ₂ - - - - 18 - - 1,3-hexanediol, 5-methyl-n-BO ₂ - - - - - 17 - 1,4-hexanediol, 2-methyl-n-BO ₂ - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example CXXXVIII

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ 26.6 26.6 - - 26 26 - DEQA ⁴ - - 26 26 - - 26 ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 - 1,4-hexanediol, 3-methyl-n-BO ₂ 18 - - - - - - 1,4-hexanediol, 4-methyl-n-BO ₂ - 18 - - - - - 1,4-hexanediol, 5-methyl-n-BO ₂ - - 18 - - - - 1,5-hexanediol, 2-methyl-n-BO ₂ - - - 17 - - - 1,5-hexanediol, 3-methyl-n-BO ₂ - - - - 18 - - 1,5-hexanediol, 4-methyl-n-BO ₂ - - - - - 17 - 1,5-hexanediol, 5-methyl-n-BO ₂ - - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

Example CXXXIX

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight DEQA ² 26.6 26.6 - 26.6 26.6 - DEQA ⁵ - - 26 - - 26 ethanol 4 6 6 4 6 6 Isopropanol 2 - - 2 - - 1,6-hexanediol, n-BO ₄ 18 - - - - - 1,6-hexanediol, 2-methyl-n-BO ₁ - 18 - - - - 1,6-hexanediol, 3-methyl-n-BO ₁ - - 18 - - - 1,4-pentanediol, 2,3,4-dimethyl- - - - 18 - - 1,4-pentanediol, 2,3,4-dimethyl-n-BO ₁ - - - - 18 - 1,4-pentanediol, 2,3,4-dimethyl-E ₃ - - - - - 18 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance

Example CXXXX

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% 6% by weight 7 wt% DEQA ¹ - 9.1 - 9.1 - - - DEQA ⁵ - - 9.1 9.1 - - DEQA ¹⁰ 17.7 - - - - - - DEQA ¹¹ 8.3 - - - - - - DEQA ¹² - 16.9 16.9 - - - - DEQA ¹³ - - - 16.9 - - - DEQA ¹⁴ - - - - 16.9 - - DEQA ¹⁵ - - - - - 26 - DEQA ¹⁶ - - - - - - 26 ethanol 6.6 6.6 6.6 6.6 6.6 6.6 6.6 1,2-hexanediol 17 17 17 17 17 17 17 HCl (pH2-2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 DI number balance balance balance balance balance balance balance

EQA ¹⁵ : N, N-di (acyloxyethyl) -N, N-dimethyl ammonium chloride, wherein the acyl group is about 65:35 weight ratio of partially hydrogenated soy fatty acid (fatty acid of DEQA ¹⁰ ) and slightly hydrogenated resin ( V) derived from a mixture of fatty acids (fatty acids of DEQA ¹¹ ).

DEQA ¹⁶ : N, N-di (acyloxyethyl) -N, N-dimethylammonium chloride, wherein the acyl group is derived from a mixture of fatty acids of DEQA ¹ and isostearic acid of DEQA ¹² in an about 65:35 weight ratio.

In mixed branched and unsaturated chain DEQAs, where R ¹ is long chain C ₅ -C ₂₁ (or C ₆ -C ₂₂ ), preferably C ₁₀ -C ₂₀ (or C ₉ -C ₁₉ ) branched alkyl or unsaturated alkyl Most preferably C ₁₂ -C ₁₈ (or C ₁₁ -C ₁₇ ) branched alkyl and unsaturated alkyl, and the ratio of branched alkyl to unsaturated alkyl is preferably from about 95: 5 to about 5:95, more preferably From about 75:25 to about 25:75, more preferably from about 50:50 to about 30:70, and for unsaturated alkyl groups, the iodine value of the raw fatty acid of the R ¹ group is preferably from about 20 to about 140 , More preferably about 50 to about 130, most preferably about 70 to about 115.

Processing aspect

Main solvent B and, as described above, several mixtures of main solvent B and a secondary solvent may comprise softener activator A (about 55% to about 85% by weight of the premix, preferably about 60% to about 80% by weight, more Preferably about 65% to about 75% by weight); Main solvent B (about 10% to about 30% by weight of the premix, preferably about 13% to about 25% by weight, more preferably about 15% to about 20% by weight); And optionally, a water-soluble solvent C (about 5% to about 20% by weight of the premix, preferably about 5% to about 17% by weight, more preferably about 5% to 15% by weight). Prepare the premix. Main solvent B may optionally be replaced with a mixture of an effective amount of main solvent B and some of the unusable solvents as described above. This premix contains a desired amount of fabric flexible activator A and sufficient main solvent B, and optionally solvent C in order to give the premix the desired viscosity in the desired temperature range. Typical viscosities suitable for processing are less than about 1000 cps, preferably less than about 500 cps, more preferably less than about 300 cps. The use of low temperatures improves stability by minimizing solvent evaporation, minimizes degradation and / or loss of materials such as biodegradable fabric softeners, fragrances, etc., and reduces processing costs by reducing the need for heating. Further protection for the softener activator can be achieved by addition of a chelant such as ethylenediaminepentaacetic acid during the preparation of the activator. The result is improved environmental impact and stability in manufacturing operations.

Examples of premixes and processes using them include, for example, about 10% to about 30%, preferably about 13% to about 25%, more preferably about 15% to about 20% of a main solvent such as 1,2-hexanediol And about 5% to about 20%, preferably about 5% to about 15% of a water-soluble solvent C, such as ethanol and / or isopropanol, as exemplified by DEQA ¹ and DEQA ⁸ in the foregoing embodiments. , Premixes typically containing from about 55% to about 85%, preferably from about 60% to about 80%, more preferably from about 65% to about 75% of fabric flexible activator A are included.

As described above, when DEQA ¹ containing about 13% ethanol is used as the fabric softener activator and 1,2-hexanediol is used as the main solvent, the premix is transparent and / or for different concentrations of the main solvent. The liquidus temperature is as follows:

About 25% 1,2-hexanediol = transparent at about -5 ° C or less, liquid at about -10 ° C or less

About 17% 1,2-hexanediol = clear to about 0 ℃, liquid to about -10 ℃

About 0% 1,2-hexanediol = clear up to about 17 ℃, liquid up to about 0 ℃

The premix can be used to formulate the final composition in a process consisting of the following steps:

1. fabric softener activator, such as about 72% DEQA^One, A premix of about 11% ethanol and about 17% main solvent such as 1,2-hexanediol is prepared and cooled to ambient temperature.

2. Mix the spices into the premix.

3. Crude with HCl and water at ambient temperature. Optionally add chelants.

4. Add the premix to water under good stirring.

5. Adjust to the desired viscosity with CaCl ₂ solution.

6. Add dye solution to get desired color.

Fabric softener actives (DEQAs); Main solvent B; And optionally, the water soluble solvent can be formulated as a premix that can be used to prepare the following compositions.

Example CXXXXI

ingredient 1 wt% 2 wt% 3 wt% 4 wt% 5 wt% DEQA ¹ (100% active) 2 5 10.5 10.5 - DEQA ⁸ (100% active) - - - - 10.5 ethanol 0.35 0.88 1.85 1.85 - Isopropanol - - - - 1.16 1,2-hexanediol 0.48 1.2 2.53 2.53 2.39 Spices 0.7 0.16 1.75 1.75 1.75 Kiland - - - 250 ppm 250 ppm HCl (100%) 0.02 0.02 0.02 0.02 0.02 CaCl ₂ - - 630 ppm 675 ppm 495 ppm dyes 3 ppm 3 ppm 6 ppm 6 ppm 6 ppm DI number balance balance balance balance balance

For commercial purposes, the above-mentioned composition is present in a container, specifically a bottle, more specifically a transparent bottle (but translucent bottle can be used) made of polypropylene (but can be replaced with glass, oriented polyethylene, etc.). To a bottle of pale blue tint (although for a short time, a completely clear product, a clear container or other shades can be used), and internals, in particular highly unsaturated activators, which offset any yellow color that may be expressed during storage Incorporates into a bottle with an ultraviolet absorbent (absorbent may also be present on the surface) that minimizes the effect of ultraviolet radiation on. The overall effect of the container demonstrating transparency and transparency of the composition assures the quality of the product to the consumer.

Claims (44)

A stable aqueous fabric softener composition containing the following A, B, E and which may contain C and D: A. 2% to 80% fabric softener active agent selected from the group consisting of: 1. A fabric softener compound having the formula: [Formula 1] Wherein each R substituent is H, or a short chain C ₁ -C ₆ alkyl or hydroxyalkyl group, benzyl or mixtures thereof; Each m is 2 or 3; Each n is 1-4; Each Y is -O- (O) C-,-(R) N- (O) C-, -C (O) -N (R)-or -C (O) -O, but -OC (O Not O-; When Y is -O- (O) C- or-(R) N- (O) C-, the sum of the carbons of each R ¹ or YR ¹ is C ₆ -C ₂₂ , but one R ¹ or If the sum of the carbons of YR ¹ is 12 or less, the sum of other R ¹ or YR ¹ is 16 or more, wherein each R ¹ is a long-chain hydrocarbyl or substituted hydrocarbyl substituent, and R ¹ or YR ¹ , For C ₁₆ -C ₂₀ hydrocarbyl or substituted hydrocarbyl substituents, the iodine number of the YR ¹ fatty acid containing the R ¹ group is 20-140 and R ¹ or YR ¹ , C ₈ -C ₁₄ hydrocarbyl Or with respect to the substituted hydrocarbyl substituent, the iodine number of the fatty acid containing the R ¹ group is 10 or less; 2. Fabric softener compounds having the formula: [Formula 2] Wherein each Y, R, R ¹ and X ^(-) have the same meaning as above; And 3. mixtures thereof; B. 2,2,4-trimethyl-1,3-pentanediol; A solvent selected from the group consisting of ethoxylated, diethoxylated or triethoxylated derivatives of 2,2,4-trimethyl-1,3-pentanediol is contained in an insufficient amount to provide a stable aqueous composition by itself 40 wt% or less of the main solvent composition having a ClogP of 0.15 to 0.64 and some or more asymmetry; C. Low molecular weight water soluble solvents such as ethanol, isopropanol, propylene glycol, 1,3-propanediol and propylene carbonate, which do not form a transparent composition by themselves and are sufficient to improve transparency; D. Effective amounts of water soluble calcium salts, magnesium salts or both salts to improve transparency; And E. Balance with water. A stable aqueous fabric softener composition according to claim 1 comprising the following A, B, E and which may contain C and D: A. 13% to 75% fabric softener active agent selected from the group consisting of: 1. A fabric softener compound having the formula: [Formula 1] Wherein each R substituent is H, or a short chain C ₁ -C ₃ alkyl or hydroxyalkyl group, benzyl or mixtures thereof; Each m is 2; Each n is 2 to 3; Each Y is -O- (O) C-; Each R ¹ is a long chain C ₉ -C ₁₉ hydrocarbyl or substituted hydrocarbyl substituent, and with respect to R ¹ C ₁₅ -C ₁₉ hydrocarbyl or substituted hydrocarbyl substituent, the corresponding fatty acid of the R ¹ group Iodine number is from 50 to 130, and for the R ¹ C ₇ -C ₁₃ or substituted hydrocarbyl substituent, the iodine number of the corresponding fatty acid of the R ¹ group is 10 or less; 2. Fabric softener compounds having the formula: [Formula 2] Wherein each Y, R, R ¹ and X ^(-) have the same meaning as described above; And 3. mixtures thereof; B. 10 to 35 weight percent of the composition having a main solvent having a ClogP of 0.25 to 0.62; C. low molecular weight water soluble solvents such as 1% to 10% ethanol, isopropanol, propylene glycol, 1,3-propanediol and propylene carbonate, which do not form a transparent composition on their own and are sufficient to improve transparency; D. 0% to 2% of a water soluble calcium salt, magnesium salt or both salts sufficient to improve transparency or to obtain the desired viscosity, or to improve transparency and to obtain the desired viscosity; And E. 10% to 80% water. 3. A stable aqueous fabric softener composition according to claim 2, which contains the following A, B, E and may contain C and D: A. 17% to 70% fabric softener active agent selected from the group consisting of: 1. A fabric softener compound having the formula: [Formula 1] Wherein each R substituent is H, or a short chain C ₁ -C ₃ alkyl or hydroxyalkyl group, benzyl or mixtures thereof; Each m is 2; Each n is 2 to 3; Each Y is -O- (O) C-; Each R ¹ is a long chain C ₇ -C ₁₇ hydrocarbyl or substituted hydrocarbyl substituent, and for a R ¹ C ₁₅ -C ₁₇ hydrocarbyl or substituted hydrocarbyl substituent, the corresponding fatty acid of the R ¹ group The iodine number of is from 70 to 115, and for the R ¹ C ₇ -C ₁₃ hydrocarbyl or substituted hydrocarbyl substituent, the iodine number of the corresponding fatty acid of the R ¹ group is 5 or less; 2. Fabric softener compounds having the formula: [Formula 2] Wherein each Y, R, R ¹ and X ^(-) have the same meaning as above; And 3. mixtures thereof; B. 12% to 35% by weight of the composition of the main solvent having a ClogP of 0.40 to 0.60; C. low molecular weight water soluble solvents such as 2% to 8% ethanol, isopropanol, propylene glycol, 1,3-propanediol and propylene carbonate sufficient to improve transparency; D. 0.05% to 0.5% of a water soluble calcium salt, magnesium salt or both salts sufficient to improve transparency or to obtain the desired viscosity, or to improve transparency and to obtain the desired viscosity; And E. 20% to 80% water. 4. A stable aqueous fabric softener composition according to claim 3, comprising the following A, B, E and which may contain C and D: A. 19% to 65% by weight of the composition of the fabric softener: 1. A fabric softener compound having the formula: [Formula 1] Wherein each R substituent is methyl, ethyl, propyl, hydroxyethyl, benzyl or mixtures thereof; Each n is 2; Each R ¹ is long chain C ₁₃ -C ₁₇ straight chain alkyl or alkylene, and for the R ¹ C ₁₅ -C ₁₇ hydrocarbyl or substituted hydrocarbyl substituent, the iodine value of the corresponding fatty acid of the R ¹ group is from 70 to Is 115; B. 14 to 35 weight percent of the composition comprising a main solvent having a ClogP of 0.40 to 0.60; C. a low molecular weight water soluble solvent selected from the group consisting of 2% to 8% ethanol, isopropanol, propylene glycol, 1,3-propanediol and propylene carbonate sufficient to improve transparency; D. 0.1% to 0.25% water soluble calcium or magnesium chloride, acetate or nitrate sufficient to improve transparency or to obtain the desired viscosity, or sufficient to improve transparency and to obtain the desired viscosity; And E. 30% to 70% water. The composition of claim 1, wherein the ClogP is from 0.25 to 0.62. The method of claim 1, wherein the main solvent is n-propanol; 2-butanol; 2-methyl-2-propanol; And mixtures thereof. The process according to any one of claims 1 to 5, wherein the main solvent is 2,3-butanediol, 2,3-dimethyl-; 1,2-butanediol, 2,3-dimethyl; 1,2-butanediol, 3,3-dimethyl; 2,3-pentanediol, 2-methyl-; 2,3-pentanediol, 3-methyl-; 2,3-pentanediol, 4-methyl-; 2,3-hexanediol; 3,4-hexanediol; 1,2-butanediol, 2-ethyl-; 1,2-pentanediol, 2-methyl; 1,2-pentanediol, 3-methyl-; 1,2-pentanediol, 4-methyl-; Composition selected from the group consisting of 1,2-hexanediol and mixtures thereof. 8. The process of claim 7, wherein the main solvent is 1,2-butanediol, 2,3-dimethyl-; 1,2-butanediol, 3,3-dimethyl; 2,3-pentanediol, 2-methyl-; 2,3-pentanediol, 3-methyl-; 2,3-pentanediol, 4-methyl-; 2,3-hexanediol; 3,4-hexanediol; 1,2-butanediol, 2-ethyl-; 1,2-pentanediol, 2-methyl; 1,2-pentanediol, 3-methyl-; 1,2-pentanediol, 4-methyl-; Composition selected from the group consisting of 1,2-hexanediol and mixtures thereof. The method of claim 8, wherein the main solvent is 1,2-butanediol, 2-ethyl; 1,2-pentanediol, 2-methyl-; 1,2-pentanediol, 3-methyl-; 1,2-pentanediol, 4-methyl-; Composition selected from the group consisting of 1,2-hexanediol and mixtures thereof. 10. The composition of claim 9, wherein said main solvent is 1,2-hexanediol. The process according to any one of claims 1 to 5, wherein the main solvent is 1,3-propanediol, 2-butyl; 1,3-propanediol, 2,2-diethyl-; 1,3-propanediol, 2- (1-methylpropyl)-; 1,3-propanediol, 2- (2-methylpropyl)-; 1,3-propanediol, 2-methyl-2-propyl-; 1,2-butanediol, 2,3,3-trimethyl-; 1,4-butanediol, 2-ethyl-2-methyl-; 1,4-butanediol, 2-ethyl-3-methyl-; 1,4-butanediol, 2-propyl-; 1,4-butanediol, 2-isopropyl-; 1,5-pentanediol, 2,2-dimethyl-; 1,5-pentanediol, 2,3-dimethyl-; 1,5-pentanediol, 2,4-dimethyl-; 1,5-pentanediol, 3,3-dimethyl-; 2,3-pentanediol, 2,3-dimethyl-; 2,3-pentanediol, 2,4-dimethyl-; 2,3-pentanediol, 3,4-dimethyl; 2,3-pentanediol, 4,4-dimethyl-; 3,4-pentanediol, 2,3-dimethyl-; 1,5-pentanediol, 2-ethyl-; 1,6-hexanediol, 2-methyl-; 1,6-hexanediol, 3-methyl-; 2,3-hexanediol, 2-methyl-; 2,3-hexanediol, 3-methyl-; 2,3-hexanediol, 4-methyl-; 2,3-hexanediol, 5-methyl-; 3,4-hexanediol, 2-methyl-; 3,4-hexanediol, 3-methyl-; 1,3-heptanediol; 1,4-heptanediol; 1,5-heptanediol; 1,6-heptanediol and a mixture thereof. 12. The composition of claim 11, wherein the main solvent is 1,3-propanediol, 2-butyl-; 1,4-butanediol, 2-propyl-; 1,5-pentanediol, 2-ethyl-; 2,3-pentanediol, 2,3-dimethyl-; 2,3-pentanediol, 2,4-dimethyl-; 2,3-pentanediol, 3,4-dimethyl-; 2,3-pentanediol, 4,4-dimethyl-; 3,4-pentanediol, 2,3-dimethyl-; 1,6-hexanediol, 2-methyl-; 1,6-hexanediol, 3-methyl-; 1,3-heptanediol; 1,4-heptanediol; 1,5-heptanediol; 1,6-heptanediol and a mixture thereof. 13. The composition of claim 12, wherein the main solvent is 2,3-pentanediol, 2,3-dimethyl-; 2,3-pentanediol, 2,4-dimethyl-; 2,3-pentanediol, 3,4-dimethyl; 2,3-pentanediol, 4,4-dimethyl-; 3,4-pentanediol, 2,3-dimethyl-; And mixtures thereof. The composition of claim 1, wherein said main solvent is selected from the group consisting of: 1,3-propanediol, 2- (2-methylbutyl)-; 1,3-propanediol, 2- (1,1-dimethylpropyl)-; 1,3-propanediol, 2- (1,2-dimethylpropyl)-; 1,3-propanediol, 2- (1-ethylpropyl)-; 1,3-propanediol, 2- (1-methylbutyl)-; 1,3-propanediol, 2- (2,2-dimethylpropyl)-; 1,3-propanediol, 2- (3-methylbutyl)-; 1,3-propanediol, 2-butyl-2-methyl-; 1,3-propanediol, 2-ethyl-2-isopropyl-; 1,3-propanediol, 2-ethyl-2-propyl-; 1,3-propanediol, 2-methyl-2- (1-methylpropyl)-; 1,3-propanediol, 2-methyl-2- (2-methylpropyl)-; 1,3-propanediol, 2-t-butyl-2-methyl-; 1,3-butanediol, 2,2-diethyl-; 1,3-butanediol, 2- (1-methylpropyl)-; 1,3-butanediol, 2-butyl-; 1,3-butanediol, 2-ethyl-2,3-dimethyl; 1,3-butanediol, 2- (1,1-dimethylethyl)-; 1,3-butanediol, 2- (2-methylpropyl)-; 1,3-butanediol, 2-methyl-2-isopropyl-; 1,3-butanediol, 2-methyl-2-propyl; 1,3-butanediol, 3-methyl-2-isopropyl-; 1,3-butanediol, 3-methyl-2-propyl-; 1,4-butanediol, 2,2-diethyl-; 1,4-butanediol, 2-methyl-2-propyl-; 1,4-butanediol, 2- (1-methylpropyl)-; 1,4-butanediol, 2-ethyl-2,3-dimethyl-; 1,4-butanediol, 2-ethyl-3,3-dimethyl-; 1,4-butanediol, 2- (1,1-dimethylethyl)-; 1,4-butanediol, 2- (2-methylpropyl)-; 1,4-butanediol, 2-methyl-3-propyl-; 1,4-butanediol, 3-methyl-2-isopropyl-; 1,3-pentanediol, 2,2,3-trimethyl-; 1,3-pentanediol, 2,2,4-trimethyl-; 1,3-pentanediol, 2,3,4-trimethyl-; 1,3-pentanediol, 2,4,4-trimethyl-; 1,3-pentanediol, 3,4,4-trimethyl-; 1,4-pentanediol, 2,2,3-trimethyl-; 1,4-pentanediol, 2,2,4-trimethyl-; 1,4-pentanediol, 2,3,3-trimethyl-; 1,4-pentanediol, 2,3,4-trimethyl-; 1,4-pentanediol, 3,3,4-trimethyl-; 1,5-pentanediol, 2,2,3-trimethyl-; 1,5-pentanediol, 2,2,4-trimethyl-; 1,5-pentanediol, 2,3,3-trimethyl-; 1,5-pentanediol, 2,3,4-trimethyl-; 2,4-pentanediol, 2,3,3-trimethyl-; 2,4-pentanediol, 2,3,4-trimethyl-; 1,3-pentanediol, 2-ethyl-2-methyl-; 1,3-pentanediol, 2-ethyl-3-methyl-; 1,3-pentanediol, 2-ethyl-4-methyl-; 1,3-pentanediol, 3-ethyl-2-methyl-; 1,4-pentanediol, 2-ethyl-2-methyl-; 1,4-pentanediol, 2-ethyl-3-methyl-; 1,4-pentanediol, 2-ethyl-4-methyl; 1,4-pentanediol, 3-ethyl-2-methyl-; 1,4-pentanediol, 3-ethyl-3-methyl-; 1,5-pentanediol, 2-ethyl-2-methyl-; 1,5-pentanediol, 2-ethyl-3-methyl-; 1,5-pentanediol, 2-ethyl-4-methyl-; 1,5-pentanediol, 3-ethyl-3-methyl-; 2,4-pentanediol, 3-ethyl-2-methyl-; 1,3-pentanediol, 2-isopropyl-; 1,3-pentanediol, 2-propyl-; 1,4-pentanediol, 2-isopropyl; 1,4-pentanediol, 2-propyl-; 1,4-pentanediol, 3-isopropyl-; 1,5-pentanediol, 2-isopropyl-; 2,4-pentanediol, 3-propyl-; 1,3-hexanediol, 2,2-dimethyl-; 1,3-hexanediol, 2,3-dimethyl-; 1,3-hexanediol, 2,4-dimethyl-; 1,3-hexanediol, 2,5-dimethyl-; 1,3-hexanediol, 3,4-dimethyl-; 1,3-hexanediol, 3,5-dimethyl-; 1,3-hexanediol, 4,4-dimethyl-; 1,3-hexanediol, 4,5-dimethyl-; 1,4-hexanediol, 2,2-dimethyl-; 1,4-hexanediol, 2,3-dimethyl-; 1,4-hexanediol, 2,4-dimethyl-; 1,4-hexanediol, 2,5-dimethyl-; 1,4-hexanediol, 3,3-dimethyl-; 1,4-hexanediol, 3,4-dimethyl-; 1,4-hexanediol, 3,5-dimethyl-; 1,4-hexanediol, 4,5-dimethyl-; 1,4-hexanediol, 5,5-dimethyl-; 1,5-hexanediol, 2,2-dimethyl-; 1,5-hexanediol, 2,3-dimethyl-; 1,5-hexanediol, 2,4-dimethyl-; 1,5-hexanediol, 2,5-dimethyl-; 1,5-hexanediol, 3,3-dimethyl-; 1,5-hexanediol, 3,4-dimethyl-; 1,5-hexanediol, 3,5-dimethyl-; 1,5-hexanediol, 4,5-dimethyl-; 1,6-hexanediol, 2,2-dimethyl-; 1,6-hexanediol, 2,3-dimethyl-; 1,6-hexanediol, 2,4-dimethyl-; 1,6-hexanediol, 2,5-dimethyl-; 1,6-hexanediol, 3,3-dimethyl-; 1,6-hexanediol, 3,4-dimethyl; 2,4-hexanediol, 2,3-dimethyl- 2,4-hexanediol, 2,4-dimethyl-; 2,4-hexanediol, 2,5-dimethyl-; 2,4-hexanediol, 3,3-dimethyl-; 2,4-hexanediol, 3,4-dimethyl-; 2,4-hexanediol, 3,5-dimethyl-; 2,4-hexanediol, 4,5-dimethyl-; 2,4-hexanediol, 5,5-dimethyl-; 2,5-hexanediol, 2,3-dimethyl-; 2,5-hexanediol, 2,4-dimethyl-; 2,5-hexanediol, 2,5-dimethyl-; 2,5-hexanediol, 3,3-dimethyl-; 2,5-hexanediol, 3,4-dimethyl-; 2,6-hexanediol, 3,3-dimethyl-; 1,3-hexanediol, 2-ethyl-; 1,3-hexanediol, 4-ethyl-; 1,4-hexanediol, 2-ethyl-; 1,4-hexanediol, 4-ethyl-; 1,5-hexanediol, 2-ethyl-; 2,4-hexanediol, 3-ethyl-; 2,4-hexanediol, 4-ethyl-; 2,5-hexanediol, 3-ethyl-; 1,3-heptanediol, 2-methyl-; 1,3-heptanediol, 3-methyl-; 1,3-heptanediol, 4-methyl-; 1,3-heptanediol, 5-methyl-; 1,3-heptanediol, 6-methyl-; 1,4-heptanediol, 2-methyl-; 1,4-heptanediol, 3-methyl-; 1,4-heptanediol, 4-methyl-; 1,4-heptanediol, 5-methyl-; 1,4-heptanediol, 6-methyl-; 1,5-heptanediol, 2-methyl-; 1,5-heptanediol, 3-methyl-; 1,5-heptanediol, 4-methyl-; 1,5-heptanediol, 5-methyl-; 1,5-heptanediol, 6-methyl-; 1,6-heptanediol, 2-methyl-; 1,6-heptanediol, 3-methyl-; 1,6-heptanediol, 4-methyl-; 1,6-heptanediol, 5-methyl-; 1,6-heptanediol, 6-methyl-; 2,4-heptanediol, 2-methyl-; 2,4-heptanediol, 3-methyl-; 2,4-heptanediol, 4-methyl-; 2,4-heptanediol, 5-methyl-; 2,4-heptanediol, 6-methyl-; 2,5-heptanediol, 2-methyl-; 2,5-heptanediol, 3-methyl-; 2,5-heptanediol, 4-methyl-; 2,5-heptanediol, 5-methyl-; 2,5-heptanediol, 6-methyl-; 2,6-heptanediol, 2-methyl-; 2,6-heptanediol, 3-methyl-; 2,6-heptanediol, 4-methyl-; 3,4-heptanediol, 3-methyl-; 3,5-heptanediol, 2-methyl-; 3,5-heptanediol, 3-methyl-; 3,5-heptanediol, 4-methyl-; 2,4-octanediol; 2,5-octanediol; 2,6-octanediol; 2,7-octanediol; 3,5-octanediol; 3,6-octanediol and mixtures thereof. The composition of claim 14 wherein said main solvent is selected from the group consisting of: 1,3-propanediol, 2- (1,1-dimethylpropyl)-; 1,3-propanediol, 2- (1,2-dimethylpropyl)-; 1,3-propanediol, 2- (1-ethylpropyl)-; 1,3-propanediol, 2- (2,2-dimethylpropyl)-; 1,3-propanediol, 2-ethyl-2-isopropyl-; 1,3-propanediol, 2-methyl-2- (1-methylpropyl)-; 1,3-propanediol, 2-methyl-2- (2-methylpropyl)-; 1,3-propanediol, 2-t-butyl-2-methyl-; 1,3-butanediol, 2,2-diethyl-; 1,3-butanediol, 2- (1-methylpropyl)-; 1,3-butanediol, 2-butyl-; 1,3-butanediol, 2-ethyl-2,3-dimethyl-; 1,3-butanediol, 2- (1,1-dimethylethyl)-; 1,3-butanediol, 2- (2-methylpropyl)-; 1,3-butanediol, 2-methyl-2-propyl; 1,3-butanediol, 3-methyl-2-isopropyl-; 1,3-butanediol, 3-methyl-2-propyl-; 1,4-butanediol, 2,2-diethyl-; 1,4-butanediol, 2-ethyl-2,3-dimethyl-; 1,4-butanediol, 2-ethyl-3,3-dimethyl-; 1,4-butanediol, 2- (1,1-dimethylethyl)-; 1,4-butanediol, 3-methyl-2-isopropyl-; 1,3-pentanediol, 2,2,3-trimethyl-; 1,3-pentanediol, 2,2,4-trimethyl-; 1,3-pentanediol, 2,3,4-trimethyl-; 1,3-pentanediol, 2,4,4-trimethyl-; 1,3-pentanediol, 3,4,4-trimethyl-; 1,4-pentanediol, 2,2,3-trimethyl-; 1,4-pentanediol, 2,2,4-trimethyl-; 1,4-pentanediol, 2,3,3-trimethyl-; 1,4-pentanediol, 2,3,4-trimethyl-; 1,4-pentanediol, 3,3,4-trimethyl-; 1,5-pentanediol, 2,2,3-trimethyl-; 1,5-pentanediol, 2,2,4-trimethyl-; 1,5-pentanediol, 2,3,3-trimethyl-; 2,4-pentanediol, 2,3,4-trimethyl-; 1,3-pentanediol, 2-ethyl-2-methyl-; 1,3-pentanediol, 2-ethyl-3-methyl-; 1,3-pentanediol, 2-ethyl-4-methyl-; 1,3-pentanediol, 3-ethyl-2-methyl-; 1,4-pentanediol, 2-ethyl-2-methyl-; 1,4-pentanediol, 2-ethyl-3-methyl-; 1,4-pentanediol, 2-ethyl-4-methyl-; 1,5-pentanediol, 3-ethyl-3-methyl-; 2,4-pentanediol, 3-ethyl-2-methyl-; 1,3-pentanediol, 2-isopropyl-; 1,3-pentanediol, 2-propyl-; 1,4-pentanediol, 2-isopropyl-; 1,4-pentanediol, 2-propyl-; 1,4-pentanediol, 3-isopropyl-; 2,4-pentanediol, 3-propyl-; 1,3-hexanediol, 2,2-dimethyl-; 1,3-hexanediol, 2,3-dimethyl-; 1,3-hexanediol, 2,4-dimethyl-; 1,3-hexanediol, 2,5-dimethyl-; 1,3-hexanediol, 3,4-dimethyl-; 1,3-hexanediol, 3,5-dimethyl-; 1,3-hexanediol, 4,4-dimethyl-; 1,3-hexanediol, 4,5-dimethyl-; 1,4-hexanediol, 2,2-dimethyl-; 1,4-hexanediol, 2,3-dimethyl-; 1,4-hexanediol, 2,4-dimethyl-; 1,4-hexanediol, 2,5-dimethyl-; 1,4-hexanediol, 3,3-dimethyl-; 1,4-hexanediol, 3,4-dimethyl-; 1,4-hexanediol, 3,5-dimethyl-; 1,4-hexanediol, 4,5-dimethyl-; 1,4-hexanediol, 5,5-dimethyl-; 1,5-hexanediol, 2,2-dimethyl-; 1,5-hexanediol, 2,3-dimethyl-; 1,5-hexanediol, 2,4-dimethyl-; 1,5-hexanediol, 2,5-dimethyl-; 1,5-hexanediol, 3,3-dimethyl-; 1,5-hexanediol, 3,4-dimethyl-; 1,5-hexanediol, 3,5-dimethyl-; 1,5-hexanediol, 4,5-dimethyl-; 2,6-hexanediol, 3,3-dimethyl-; 1,3-hexanediol, 2-ethyl-; 1,3-hexanediol, 4-ethyl-; 1,4-hexanediol, 2-ethyl-; 1,4-hexanediol, 4-ethyl-; 1,5-hexanediol, 2-ethyl-; 2,4-hexanediol, 3-ethyl-; 2,4-hexanediol, 4-ethyl-; 2,5-hexanediol, 3-ethyl-; 1,3-heptanediol, 2-methyl-; 1,3-heptanediol, 3-methyl-; 1,3-heptanediol, 4-methyl-; 1,3-heptanediol, 5-methyl-; 1,3-heptanediol, 6-methyl-; 1,4-heptanediol, 2-methyl-; 1,4-heptanediol, 3-methyl-; 1,4-heptanediol, 4-methyl-; 1,4-heptanediol, 5-methyl-; 1,4-heptanediol, 6-methyl-; 1,5-heptanediol, 2-methyl-; 1,5-heptanediol, 3-methyl-; 1,5-heptanediol, 4-methyl-; 1,5-heptanediol, 5-methyl-; 1,5-heptanediol, 6-methyl-; 1,6-heptanediol, 2-methyl-; 1,6-heptanediol, 3-methyl-; 1,6-heptanediol, 4-methyl-; 1,6-heptanediol, 5-methyl-; 1,6-heptanediol, 6-methyl-; 2,4-heptanediol, 2-methyl-; 2,4-heptanediol, 3-methyl-; 2,4-heptanediol, 4-methyl-; 2,4-heptanediol, 5-methyl-; 2,4-heptanediol, 6-methyl-; 2,5-heptanediol, 2-methyl-; 2,5-heptanediol, 3-methyl-; 2,5-heptanediol, 4-methyl-; 2,5-heptanediol, 5-methyl-; 2,5-heptanediol, 6-methyl-; 2,6-heptanediol, 2-methyl-; 2,6-heptanediol, 3-methyl-; 2,6-heptanediol, 4-methyl-; 3,4-heptanediol, 3-methyl-; 3,5-heptanediol, 2-methyl-; 3,5-heptanediol, 4-methyl-; 2,4-octanediol; 2,5-octanediol; 2,6-octanediol; 2,7-octanediol; 3,5-octanediol; 3,6-octanediol; And mixtures thereof. The composition of claim 15 wherein said main solvent is selected from the group consisting of: 1,3-propanediol, 2- (1,1-dimethylpropyl)-; 1,3-propanediol, 2- (1,2-dimethylpropyl)-; 1,3-propanediol, 2- (1-ethylpropyl)-; 1,3-propanediol, 2- (2,2-dimethylpropyl)-; 1,3-propanediol, 2-ethyl-2-isopropyl-; 1,3-propanediol, 2-methyl-2- (1-methylpropyl)-; 1,3-propanediol, 2-methyl-2- (2-methylpropyl)-; 1,3-propanediol, 2-t-butyl-2-methyl-; 1,3-butanediol, 2- (1-methylpropyl)-; 1,3-butanediol, 2- (2-methylpropyl)-; 1,3-butanediol, 2-butyl-; 1,3-butanediol, 2-methyl-2-propyl-; 1,3-butanediol, 3-methyl-2-propyl-; 1,4-butanediol, 2,2-diethyl-; 1,4-butanediol, 2-ethyl-2,3-dimethyl-; 1,4-butanediol, 2-ethyl-3,3-dimethyl-; 1,4-butanediol, 2- (1,1-dimethylethyl)-; 1,3-pentanediol, 2,3,4-trimethyl-; 1,4-pentanediol, 2,3,4-trimethyl-; 1,5-pentanediol, 2,2,3-trimethyl-; 1,5-pentanediol, 2,2,4-trimethyl-; 1,5-pentanediol, 2,3,3-trimethyl-; 1,3-pentanediol, 2-ethyl-2-methyl-; 1,3-pentanediol, 2-ethyl-3-methyl-; 1,3-pentanediol, 2-ethyl-4-methyl-; 1,3-pentanediol, 3-ethyl-2-methyl-; 1,4-pentanediol, 2-ethyl-2-methyl-; 1,4-pentanediol, 2-ethyl-3-methyl-; 1,4-pentanediol, 2-ethyl-4-methyl-; 1,5-pentanediol, 3-ethyl-3-methyl-; 2,4-pentanediol, 3-ethyl-2-methyl-; 1,3-pentanediol, 2-isopropyl-; 1,3-pentanediol, 2-propyl-; 1,4-pentanediol, 2-isopropyl-; 1,4-pentanediol, 2-propyl-; 1,4-pentanediol, 3-isopropyl-; 2,4-pentanediol, 3-propyl-; 1,3-hexanediol, 2,2-dimethyl-; 1,3-hexanediol, 2,3-dimethyl-; 1,3-hexanediol, 2,4-dimethyl-; 1,3-hexanediol, 2,5-dimethyl-; 1,3-hexanediol, 3,4-dimethyl-; 1,3-hexanediol, 3,5-dimethyl-; 1,3-hexanediol, 4,4-dimethyl-; 1,3-hexanediol, 4,5-dimethyl-; 1,4-hexanediol, 2,2-dimethyl-; 1,4-hexanediol, 2,3-dimethyl-; 1,4-hexanediol, 2,4-dimethyl-; 1,4-hexanediol, 2,5-dimethyl-; 1,4-hexanediol, 3,3-dimethyl-; 1,4-hexanediol, 3,4-dimethyl-; 1,4-hexanediol, 3,5-dimethyl-; 1,4-hexanediol, 4,5-dimethyl-; 1,4-hexanediol, 5,5-dimethyl-; 1,5-hexanediol, 2,2-dimethyl-; 1,5-hexanediol, 2,3-dimethyl-; 1,5-hexanediol, 2,4-dimethyl-; 1,5-hexanediol, 2,5-dimethyl-; 1,5-hexanediol, 3,3-dimethyl-; 1,5-hexanediol, 3,4-dimethyl-; 1,5-hexanediol, 3,5-dimethyl-; 1,5-hexanediol, 4,5-dimethyl-; 2,6-hexanediol, 3,3-dimethyl-; 1,3-hexanediol, 2-ethyl-; 1,3-hexanediol, 4-ethyl-; 1,4-hexanediol, 2-ethyl-; 1,4-hexanediol, 4-ethyl-; 1,5-hexanediol, 2-ethyl-; 2,4-hexanediol, 3-ethyl-; 2,4-hexanediol, 4-ethyl-; 2,5-hexanediol, 3-ethyl-; 1,3-heptanediol, 2-methyl-; 1,3-heptanediol, 3-methyl-; 1,3-heptanediol, 4-methyl-; 1,3-heptanediol, 5-methyl-; 1,3-heptanediol, 6-methyl-; 1,4-heptanediol, 2-methyl-; 1,4-heptanediol, 3-methyl-; 1,4-heptanediol, 4-methyl-; 1,4-heptanediol, 5-methyl-; 1,4-heptanediol, 6-methyl-; 1,5-heptanediol, 2-methyl-; 1,5-heptanediol, 3-methyl-; 1,5-heptanediol, 4-methyl-; 1,5-heptanediol, 5-methyl-; 1,5-heptanediol, 6-methyl-; 1,6-heptanediol, 2-methyl-; 1,6-heptanediol, 3-methyl-; 1,6-heptanediol, 4-methyl-; 1,6-heptanediol, 5-methyl-; 1,6-heptanediol, 6-methyl-; 2,4-heptanediol, 2-methyl-; 2,4-heptanediol, 3-methyl-; 2,4-heptanediol, 4-methyl-; 2,4-heptanediol, 5-methyl-; 2,4-heptanediol, 6-methyl-; 2,5-heptanediol, 2-methyl-; 2,5-heptanediol, 3-methyl-; 2,5-heptanediol, 4-methyl-; 2,5-heptanediol, 5-methyl-; 2,5-heptanediol, 6-methyl-; 2,6-heptanediol, 2-methyl-; 2,6-heptanediol, 3-methyl-; 2,6-heptanediol, 4-methyl-; 3,4-heptanediol, 3-methyl-; 3,5-heptanediol, 2-methyl-; 3,5-heptanediol, 4-methyl-; 2,4-octanediol; 2,5-octanediol; 2,6-octanediol; 2,7-octanediol; 3,5-octanediol; Or 3,6-octanediol and mixtures thereof. The method of claim 16, wherein the main solvent is 2,4-pentanediol, 2,3,3,4-tetramethyl-; 2,4-pentanediol, 3-t-butyl-; 2,4-hexanediol, 2,5,5-trimethyl-; 2,4-hexanediol, 3,3,4-trimethyl-; 2,4-hexanediol, 3,3,5-trimethyl-; 2,4-hexanediol, 3,5,5-trimethyl-; 2,4-hexanediol, 4,5,5-trimethyl-; 2,5, -hexanediol, 3,3,4-trimethyl-; 2,5-hexanediol, 3,3,5-trimethyl-; And mixtures thereof. 18. The composition of claim 17, wherein said main solvent is 2,4-pentanediol, 2,3,3,4-tetramethyl. The composition of claim 1, wherein said main solvent is selected from the group consisting of: 1,2-propanediol, 3- (n-pentyloxy)-; 1,2-propanediol, 3- (2-pentyloxy)-; 1,2-propanediol, 3- (3-pentyloxy)-; 1,2-propanediol, 3- (2-methyl-1-butyloxy)-; 1,2-propanediol, 3- (iso-amyloxy)-; 1,2-propanediol, 3- (3-methyl-2-butyloxy)-; 1,2-propanediol, 3- (cyclohexyloxy)-; 1,2-propanediol, 3- (1-cyclohex-1-enyloxy)-; 1,3-propanediol, 2- (pentyloxy)-; 1,3-propanediol, 2- (2-pentyloxy)-; 1,3-propanediol, 2- (3-pentyloxy)-; 1,3-propanediol, 2- (2-methyl-1-butyloxy)-; 1,3-propanediol, 2- (isoamyloxy)-; 1,3-propanediol, 2- (3-methyl-2-butyloxy)-; 1,3-propanediol, 2- (cyclohexyloxy)-; 1,3-propanediol, 2- (1-cyclohex-1-enyloxy)-; 1,2-propanediol, 3- (butyloxy)-, triethoxylated; 1,2-propanediol, 3- (butyloxy)-, tetraethoxylated; 1,2-propanediol, 3- (butyloxy) -pentaethoxylation; 1,2-propanediol, 3- (butyloxy)-, hexaethoxylated; 1,2-propanediol, 3- (butyloxy)-, heptaethoxylation; 1,2-propanediol, 3- (butyloxy)-, octaethoxylation; 1,2-propanediol, 3- (butyloxy)-, nonaethoxylation; 1,2-propanediol, 3-phenyloxy-; 1,2-propanediol, 3-benzyloxy-; 1,2-propanediol, 3- (2-phenylethyloxy)-; 1,2-propanediol, 3- (1-phenyl-2-propanyloxy)-; 1,3-propanediol, 2-phenyloxy-; 1,3-propanediol, 2- (m-cresyloxy)-; 1,3-propanediol, 2- (p-cresyloxy)-; 1,3-propanediol, 2-benzyloxy-; 1,3-propanediol, 2- (2-phenylethyloxy)-; 1,3-propanediol, 2- (1-phenylethyloxy)-; Bis (2-hydroxybutyl) ether; Bis (2-hydroxycyclopentyl) ether and mixtures thereof. The composition of claim 19 wherein said main solvent is selected from the group consisting of: 1,2-propanediol, 3- (n-pentyloxy)-; 1,2-propanediol, 3- (2-pentyloxy)-; 1,2-propanediol, 3- (3-pentyloxy)-; 1,2-propanediol, 3- (2-methyl-1-butyloxy)-; 1,2-propanediol, 3- (iso-amyloxy)-; 1,2-propanediol, 3- (3-methyl-2-butyloxy)-; 1,2-propanediol, 3- (cyclohexyloxy)-; 1,2-propanediol, 3- (1-cyclohex-1-enyloxy)-; 1,3-propanediol, 2- (pentyloxy)-; 1,3-propanediol, 2- (2-pentyloxy)-; 1,3-propanediol, 2- (3-pentyloxy)-; 1,3-propanediol, 2- (2-methyl-1-butyloxy)-; 1,3-propanediol, 2- (iso-amyloxy)-; 1,3-propanediol, 2- (3-methyl-2-butyloxy)-; 1,3-propanediol, 2- (cyclohexyloxy)-; 1,3-propanediol, 2- (1-cyclohex-1-enyloxy)-; 1,2-propanediol, 3- (butyloxy)-, pentaethoxylated; 1,2-propanediol, 3- (butyloxy)-, hexaethoxylated; 1,2-propanediol, 3- (butyloxy)-, heptaethoxylation; 1,2-propanediol, 3- (butyloxy)-, octaethoxylation; 1,2-propanediol, 3- (butyloxy)-, nonaethoxylation; 1,2-propanediol, 3-phenyloxy-; 1,2-propanediol, 3-benzyloxy-; 1,2-propanediol, 3- (2-phenylethyloxy)-; 1,3-propanediol, 2- (m-cresyloxy)-; 1,3-propanediol, 2- (p-cresyloxy)-; 1,3-propanediol, 2-benzyloxy-; 1,3-propanediol, 2- (2-phenylethyloxy)-; Bis (2-hydroxybutyl) ether; Bis (2-hydroxycyclopentyl) ether and mixtures thereof. The composition of claim 20 wherein said main solvent is selected from the group consisting of: 1,2-propanediol, 3- (n-pentyloxy)-; 1,2-propanediol, 3- (2-pentyloxy)-; 1,2-propanediol, 3- (3-pentyloxy)-; 1,2-propanediol, 3- (2-methyl-1-butyloxy)-; 1,2-propanediol, 3- (iso-amyloxy)-; 1,2-propanediol, 3- (3-methyl-2-butyloxy)-; 1,2-propanediol, 3- (cyclohexyloxy)-; 1,2-propanediol, 3- (1-cyclohex-1-enyloxy)-; 1,3-propanediol, 2- (pentyloxy)-; 1,3-propanediol, 2- (2-pentyloxy)-; 1,3-propanediol, 2- (3-pentyloxy)-; 1,3-propanediol, 2- (2-methyl-1-butyloxy)-; 1,3-propanediol, 2- (iso-amyloxy)-; 1,3-propanediol, 2- (3-methyl-2-butyloxy)-; 1,3-propanediol, 2- (cyclohexyloxy)-; 1,3-propanediol, 2- (1-cyclohex-1-enyloxy)-; 1,2-propanediol, 3- (butyloxy)-, pentaethoxylated; 1,2-propanediol, 3- (butyloxy)-, hexaethoxylated; 1,2-propanediol, 3- (butyloxy)-, heptaethoxylation; 1,2-propanediol, 3- (butyloxy)-, octaethoxylation; 1,2-propanediol, 3- (butyloxy)-, nonaethoxylation; 1,2-propanediol, 3-phenyloxy-; 1,2-propanediol, 3-benzyloxy-; 1,2-propanediol, 3- (2-phenylethyloxy)-; 1,3-propanediol, 2- (m-cresyloxy)-; 1,3-propanediol, 2- (p-cresyloxy)-; 1,3-propanediol, 2- (2-phenylethyloxy)-; Bis (2-hydroxybutyl) ether; Bis (2-hydroxycyclopentyl) ether and mixtures thereof. The composition of claim 1 wherein the main solvent is selected from the group consisting of: 1-isopropyl-1,2-cyclobutanediol; 3-ethyl-4-methyl-1,2-cyclobutanediol; 3-propyl-1,2-cyclobutanediol; 3-isopropyl-1,2-cyclobutanediol; 1-ethyl-1,2-cyclopentanediol; 1,2-dimethyl-1,2-cyclopentanediol; 1,4-dimethyl-1,2-cyclopentanediol; 2,4,5-trimethyl-1,3-cyclopentanediol; 3,3-dimethyl-1,2-cyclopentanediol; 3,4-dimethyl-1,2-cyclopentanediol; 3,5-dimethyl-1,2-cyclopentanediol; 3-ethyl-1,2-cyclopentanediol; 4,4-dimethyl-1,2-cyclopentanediol; 4-ethyl-1,2-cyclopentanediol; 1,1-bis (hydroxymethyl) cyclohexane; 1,2-bis (hydroxymethyl) cyclohexane; 1,2-dimethyl-1,3-cyclohexanediol; 1,3-bis (hydroxymethyl) cyclohexane; 1,3-dimethyl-1,3-cyclohexanediol; 1,6-dimethyl-1,3-cyclohexanediol; 1-hydroxycyclohexaneethanol; 1-hydroxy-cyclohexanemethanol; 1-ethyl-1,3-cyclohexanediol; 1-methyl-1,2-cyclohexanediol; 2,2-dimethyl-1,3-cyclohexanediol; 2,3-dimethyl-1,4-cyclohexanediol; 2,4-dimethyl-1,3-cyclohexanediol; 2,5-dimethyl-1,3-cyclohexanediol; 2,6-dimethyl-1,4-cyclohexanediol; 2-ethyl-1,3-cyclohexanediol; 2-hydroxycyclohexaneethanol; 2-hydroxyethyl-1-cyclohexanol; 2-hydroxymethylcyclohexanol; 3-hydroxyethyl-1-cyclohexanol; 3-hydroxycyclohexaneethanol; 3-hydroxymethylcyclohexanol; 3-methyl-1,2-cyclohexanediol; 4,4-dimethyl-1,3-cyclohexanediol; 4,5-dimethyl-1,3-cyclohexanediol; 4,6-dimethyl-1,3-cyclohexanediol; 4-ethyl-1,3-cyclohexanediol; 4-hydroxyethyl-1-cyclohexanol; 4-hydroxymethylcyclohexanol; 4-methyl-1,2-cyclohexanediol; 5,5-dimethyl-1,3-cyclohexanediol; 5-ethyl-1,3-cyclohexanediol; 1,2-cycloheptanediol; 2-methyl-1,3-cycloheptanediol; 2-methyl-1,4-cycloheptanediol; 4-methyl-1,3-cycloheptanediol; 5-methyl-1,3-cycloheptanediol; 5-methyl-1,4-cycloheptanediol; 6-methyl-1,4-cycloheptanediol; 1,3-cyclooctanediol; 1,4-cyclooctanediol; 1,5-cyclooctanediol; 1,2-cyclohexanediol, diethoxylation; 1,2-cyclohexanediol, triethoxylation; 1,2-cyclohexanediol, tetraethoxylation; 1,2-cyclohexanediol, pentaethoxylation; 1,2-cyclohexanediol, hexaethoxylation; 1,2-cyclohexanediol, heptaethoxylation; 1,2-cyclohexanediol, octaethoxylation; 1,2-cyclohexanediol, nonaethoxylation; 1,2-cyclohexanediol, monopropoxylation; 1,2-cyclohexanediol, monobutyleneoxylation; 1,2-cyclohexanediol, dibutyleneoxylation; 1,2-cyclohexanediol, tributyleneoxylation; 1,2-cyclobutanediol, 1-ethenyl-2-ethyl-; 3-cyclobutene-1,2-diol, 1,2,3,4-tetramethyl-; 3-cyclobutene-1,2-diol, 3,4-diethyl-; 3-cyclobutene-1,2-diol, 3- (1, l-dimethylethyl)-; 3-cyclobutene-1,2-diol, 3-butyl-; 1,2-cyclopentanediol, 1,2-dimethyl-4-methylene-; 1,2-cyclopentanediol, 1-ethyl-3-methylene-; 1,2-cyclopentanediol, 4- (1-propenyl); 3-cyclopentene-1,2-diol, 1-ethyl-3-methyl-; 1,2-cyclohexanediol, 1-ethenyl-; 1,2-cyclohexanediol, 1-methyl-3-methylene-; 1,2-cyclohexanediol, 1-methyl-4-methylene-; 1,2-cyclohexanediol, 3-ethenyl-; 1,2-cyclohexanediol, 4-ethenyl-; 3-cyclohexene-1,2-diol, 2,6-dimethyl-; 3-cyclohexene-1,2-diol, 6,6-dimethyl-; 4-cyclohexene-1,2-diol, 3,6-dimethyl-; 4-cyclohexene-1,2-diol, 4,5-dimethyl-; 3-cyclooctene-1,2-diol; 4-cyclooctene-1,2-diol; 5-cyclooctene-1,2-diol; And mixtures thereof. The composition of claim 22 wherein said main solvent is selected from the group consisting of: 1-isopropyl-1,2-cyclobutanediol; 3-ethyl-4-methyl-1,2-cyclobutanediol; 3-propyl-1,2-cyclobutanediol; 3-isopropyl-1,2-cyclobutanediol; 1-ethyl-1,2-cyclopentanediol; 1,2-dimethyl-1,2-cyclopentanediol; 1,4-dimethyl-1,2-cyclopentanediol; 3,3-dimethyl-1,2-cyclopentanediol; 3,4-dimethyl-1,2-cyclopentanediol; 3.5-dimethyl-1,2-cyclopentanediol; 3-ethyl-1,2-cyclopentanediol; 4,4-dimethyl-1,2-cyclopentanediol; 4-ethyl- 1,2-cyclopentanediol; 1,1-bis (hydroxymethyl) cyclohexane; 1,2-bis (hydroxymethyl) cyclohexane; 1,2-dimethyl-1,3-cyclohexanediol; 1,3-bis (hydroxymethyl) cyclohexane; 1-hydroxy-cyclohexanemethanol; 1-methyl-1,2-cyclohexanediol; 3-hydroxymethylcyclohexanol; 3-methyl-1,2-cyclohexanediol; 4,4-dimethyl-1,3-cyclohexanediol; 4,5-dimethyl-1,3-cyclohexanediol; 4,6-dimethyl-1,3-cyclohexanediol; 4-ethyl-1,3-cyclohexanediol; 4-hydroxyethyl-1-cyclohexanol; 4-hydroxymethylcyclohexanol; 4-methyl-1,2-cyclohexanediol; 1,2-cycloheptanediol; 1,2-cyclohexanediol, pentaethoxylation; 1,2-cyclohexanediol, hexaethoxylation; 1,2-cyclohexanediol, heptaethoxylation; 1,2-cyclohexanediol, octaethoxylation; 1,2-cyclohexanediol, nonaethoxylation; 1,2-cyclohexanediol, monopropoxylation; 1,2-cyclohexanediol, dibutyleneoxylation; And mixtures thereof. The composition of claim 1, wherein said main solvent is selected from the group consisting of: 1. 1,2-propanediol (C3) 2 (Me-E _1-4 ); 1.2-propanediol (C3) P0 ₄ ; 1,2-propanediol, 2-methyl- (C4) (Me-E _4-10 ); 1,2-propanediol, 2-methyl- (C4) 2 (Me-E _l ); 1,2-propanediol, 2-methyl- (C4) PO ₃ ; 1,2-propanediol, 2-methyl- (C4) BO ₁ ; 1,3-propanediol (C3) 2 (Me-E _6-8 ); 1,3-propanediol (C3) P0 _5-6 ; 1,3-propanediol, 2,2-diethyl- (C7) _El-7 ; 1,3-propanediol, 2,2-diethyl- (C7) PO ₁ ; 1,3-propanediol, 2,2-diethyl- (C7) n-BO _1-2 ; 1,3-propanediol, 2,2-dimethyl- (C5) 2 (Me E _l-2 ); 1,3-propanediol, 2,2-dimethyl- (C5) PO _3-4 ; 1,3-propanediol, 2- (1-methylpropyl)-(C7) _El-7 ; 1,3-propanediol, 2- (1-methylpropyl)-(C7) PO ₁ ; 1,3-propanediol, 2- (1-methylpropyl)-(C7) n-BO _1-2 ; 1,3-propanediol, 2- (2-methylpropyl)-(C7) _El-7 ; 1,3-propanediol, 2- (2-methylpropyl)-(C7) PO ₁ ; 1,3-propanediol, 2- (2-methylpropyl)-(C7) n-BO _1-2 ; 1,3-propanediol, 2-ethyl- (C5) (Me E _6-10 ); 1,3-propanediol, 2-ethyl- (C5) 2 (Me _El ); 1,3-propanediol, 2-ethyl- (C5) P0 ₃ ; 1,3-propanediol, 2-ethyl-2-methyl- (C6) (Me _El-6 ); 1,3-propanediol, 2-ethyl-2-methyl- (C6) P0 ₂ ; 1,3-propanediol, 2-ethyl-2-methyl- (C6) BO ₁ ; 1,3-propanediol, 2-isopropyl- (C6) (Me _El-6 ); 1,3-propanediol, 2-isopropyl- (C6) PO ₂ ; 1,3-propanediol, 2-isopropyl- (C6) BO ₁ ; 1,3-propanediol, 2-methyl- (C4) 2 (Me E _2-5 ); 1,3-propanediol, 2-methyl- (C4) P0 _4-5 ; 1,3-propanediol, 2-methyl- (C4) B0 ₂ ; 1,3-propanediol, 2-methyl-2-isopropyl- (C7) E _2-9 ; 1,3-propanediol, 2-methyl-2-isopropyl- (C7) PO ₁ ; 1,3-propanediol, 2-methyl-2-isopropyl- (C7) n-BO _1-3 ; 1,3-propanediol, 2-methyl-2-propyl- (C7) _El-7 ; 1,3-propanediol, 2-methyl-2-propyl- (C7) PO ₁ ; 1,3-propanediol, 2-methyl-2-propyl- (C7) n-BO _1-2 ; 1,3-propanediol, 2-propyl- (C6) (Me _El-4 ); 1,3-propanediol 2-propyl- (C6) PO ₂ ; 1,3-propanediol 2-propyl- (C6) BO ₁ ; 2. 1,2-butanediol (C4) (Me E _2-8 ); 1,2-butanediol (C4) P0 _2-3 ; 1,2-butanediol (C4) BO ₁ ; 1,2-butanediol, 2,3-dimethyl- (C6) _El-6 ; 1,2-butanediol, 2,3-dimethyl- (C6) n-BO _1-2 ; 1,2-butanediol, 2-ethyl- (C6) _El-3 ; 1,2-butanediol, 2-ethyl- (C6) n-BO ₁ ; 1,2-butanediol, 2-methyl- (C5) (Me E _l-2 ); 1,2-butanediol, 2-methyl- (C5) PO ₁ ; 1,2-butanediol, 3,3-dimethyl- (C6) _El-6 ; 1,2-butanediol, 3,3-dimethyl- (C6) n-BO _1-2 , 1,2-butanediol 3-methyl- (C5) (Me E _l-2 ); 1,2-butanediol, 3-methyl- (C5) PO ₁ ; 1,3-butanediol (C4) 2 (Me E _3-6 ); 1,3-butanediol (C4) P0 ₅ ; 1,3-butanediol (C4) B0 ₂ ; 1,3-butanediol, 2,2,3-trimethyl- (C7) (Me E _l-3 ); 1,3-butanediol, 2,2,3-trimethyl- (C7) PO _1-2 ; 1,3-butanediol, 2,2-dimethyl- (C6) (Me E _3-8 ); 1,3-butanediol, 2,2-dimethyl- (C6) PO ₃ , 1,3-butanediol, 2,3-dimethyl- (C6) (Me E _3-8 ); 1,3-butanediol, 2,3-dimethyl- (C6) PO ₃ ; 1,3-butanediol, 2-ethyl- (C6) (Me _El-6 ); 1,3-butanediol 2-ethyl- (C6) P0 _2-3 ; 1,3-butanediol, 2-ethyl- (C6) B0 ₁ ; 1,3-butanediol, 2-ethyl-2-methyl- (C7) (Me _El ); 1,3-butanediol, 2-ethyl-2-methyl- (C7) PO ₁ ; 1,3-butanediol, 2-ethyl-2-methyl- (C7) n-BO _2-4 ; 1,3-butanediol, 2-ethyl-3-methyl- (C7) (Me _El ); 1,3-butanediol, 2-ethyl-3-methyl- (C7) PO ₁ ; 1,3-butanediol, 2-ethyl-3-methyl- (C7) n-BO _2-4 ; 1,3-butanediol, 2-isopropyl- (C7) (Me _El ); 1,3-butanediol, 2-isopropyl- (C7) PO ₁ ; 1,3-butanediol, 2-isopropyl- (C7) n-BO _2-4 ; 1,3-butanediol, 2-methyl- (C5) 2 (Me E _l-3 ); 1,3-butanediol, 2-methyl- (C5) P0 ₄ ; 1,3-butanediol, 2-propyl- (C7) E _2-9 ; 1,3-butanediol, 2-propyl- (C7) PO ₁ ; 1,3-butanediol, 2-propyl- (C7) n-BO _1-3 ; 1,3-butanediol, 3-methyl- (C5) 2 (Me El _l-3 ); 1,3-butanediol, 3-methyl- (C5) P0 ₄ ; 1,4-butanediol (C4) 2 (Me E _2-4 ); 1,4-butanediol (C4) P0 _4-5 ; 1,4-butanediol (C4) B0 ₂ ; 1,4-butanediol, 2,2,3-trimethyl- (C7) E _2-9 ; 1,4-butanediol, 2,2,3-trimethyl- (C7) PO ₁ ; 1,4-butanediol, 2,2,3-trimethyl- (C7) n-BO _1-3 ; 1,4-butanediol 2,2-dimethyl- (C6) (Me _El-6 ); 1,4-butanediol, 2,2-dimethyl- (C6) PO ₂ ; 1,4-butanediol, 2,2-dimethyl- (C6) BO ₁ ; 1,4-butanediol, 2,3-dimethyl- (C6) (Me E _1-6 ); 1,4-butanediol, 2,3-dimethyl- (C6) PO ₂ ; 1,4-butanediol, 2,3-dimethyl- (C6) BO ₁ ; 1,4-butanediol, 2-ethyl- (C6) (Me E _1-4 ); 1,4-butanediol, 2-ethyl- (C6) P0 ₂ ; 1,4-butanediol, 2-ethyl- (C6) BO ₁ ; 1,4-butanediol, 2-ethyl-2-methyl- (C7) _El-7 ; 1,4-butanediol, 2-ethyl-2-methyl- (C7) PO ₁ ; 1,4-butanediol, 2-ethyl-2-methyl- (C7) n-BO _1-2 ; 1,4-butanediol, 2-ethyl-3-methyl- (C7) _El-7 ; 1,4-butanediol, 2-ethyl-3-methyl- (C7) PO ₁ ; 1,4-butanediol, 2-ethyl-3-methyl- (C7) n-BO _1-2 ; 1,4-butanediol, 2-isopropyl- (C7) _El-7 ; 1,4-butanediol, 2-isopropyl- (C7) PO ₁ ; 1,4-butanediol, 2-isopropyl- (C7) n-BO _1-2 ; 1,4-butanediol, 2-methyl- (C5) (Me E _6-10 ); 1,4-butanediol, 2-methyl- (C5) 2 (Me _El ); 1,4-butanediol, 2-methyl- (C5) PO ₃ ; 1,4-butanediol, 2-methyl- (C5) BO ₁ ; 1,4-butanediol, 2-propyl- (C7) _El-5 ; 1,4-butanediol, 2-propyl- (C7) n-BO _1-2 ; 1,4-butanediol, 3-ethyl-l-methyl- (C7) E _2-9 ; 1,4-butanediol, 3-ethyl-l-methyl- (C7) PO ₁ ; 1,4-butanediol, 3-ethyl-l-methyl- (C7) n-BO _1-3 ; 2,3-butanediol (C4) (Me E _6-10 ); 2,3-butanediol (C4) 2 (Me _El ); 2,3-butanediol (C4) PO _3-4 ; 2,3-butanediol (C4) BO ₁ ; 2,3-butanediol, 2,3-dimethyl- (C6) E _3-9 ; 2,3-butanediol, 2,3-dimethyl- (C6) PO ₁ ; 2,3-butanediol, 2,3-dimethyl- (C6) n-BO _1-3 ; 2,3-butanediol, 2-methyl- (C5) (Me _El-5 ); 2,3-butanediol, 2-methyl- (C5) PO ₂ ; 2,3-butanediol, 2-methyl- (C5) BO ₁ ; 3. 1,2-pentanediol (C5) E _3-10 ; 1,2-pentanediol, (C5) PO ₁ ; 1,2-pentanediol, (C5) n-BO _2-3 ; 1,2-pentanediol, 2-methyl (C6) _El-1 ; 1,2-pentanediol, 2-methyl (C6) n-BO ₁ ; 1,2-pentanediol, 2-methyl (C6) BO ₁ ; 1,2-pentanediol, 3-methyl (C6) _El-3 ; 1,2-pentanediol, 3-methyl (C6) n-BO ₁ ; 1,2-pentanediol, 4-methyl (C6) _El-1 ; 1,2-pentanediol, 4-methyl (C6) n-BO ₁ ; 1,3-pentanediol (C5) 2 (Me-E _1-2 ); 1,3-pentanediol (C5) P0 _3-4 ; 1,3-pentanediol, 2,2-dimethyl- (C7) (Me-E _l ); 1,3-pentanediol, 2,2-dimethyl- (C7) PO ₁ ; 1,3-pentanediol, 2,2-dimethyl- (C7) n-BO _2-4 ; 1,3-pentanediol, 2,3-dimethyl- (C7) (Me-E _l ); 1,3-pentanediol 2,3-dimethyl- (C7) PO ₁ ; 1,3-pentanediol, 2,3-dimethyl- (C7) n-BO _2-4 ; 1,3-pentanediol, 2,4-dimethyl (C7) (Me-E _l ); 1,3-pentanediol, 2,4-dimethyl- (C7) PO ₁ ; 1,3-pentanediol, 2,4-dimethyl- (C7) n-BO _2-4 ; 1,3-pentanediol, 2-ethyl- (C7) E _2-9 ; 1,3-pentanediol, 2-ethyl- (C7) PO ₁ ; 1,3-pentanediol, 2-ethyl- (C7) n-BO _1-3 ; 1,3-pentanediol, 2-methyl (C6) 2 (Me-E _1-6 ); 1,3-pentanediol, 2-methyl- (C6) P0 _2-3 ; 1,3-pentanediol, 2-methyl- (C6) BO ₁ ; 1,3-pentanediol, 3,4-dimethyl- (C7) (Me-E _l ); 1,3-pentanediol, 3,4-dimethyl- (C7) PO ₁ ; 1,3-pentanediol, 3,4-dimethyl- (C7) n-BO _2-4 ; 1,3-pentanediol, 3-methyl- (C6) (Me-E _1-6 ); 1,3-pentanediol, 3-methyl- (C6) P0 _2-3 ; 1,3-pentanediol, 3-methyl- (C6) BO ₁ ; 1,3-pentanediol, 4,4-dimethyl- (C7) (Me-E _l ); 1,3-pentanediol, 4,4-dimethyl- (C7) PO ₁ ; 1,3-pentanediol, 4,4-dimethyl- (C7) n-BO _2-4 ; 1,3-pentanediol, 4-methyl- (C6) (Me-E _1-6 ); 1,3-pentanediol, 4-methyl- (C6) P0 _2-3 ; 1,3-pentanediol, 4-methyl- (C6) BO ₁ ; 1,4-pentanediol, (C5) 2 (Me-E _1-2 ); 1,4-pentanediol (C5) PO _3-4 ; 1,4-pentanediol, 2,2-dimethyl- (C7) (Me-E _l ); 1,4-pentanediol, 2,2-dimethyl- (C7) PO ₁ ; 1,4-pentanediol, 2,2-dimethyl- (C7) n-BO _2-4 ; 1,4-pentanediol, 2,3-dimethyl- (C7) (Me-E _l ); 1,4-pentanediol, 2,3-dimethyl- (C7) PO ₁ ; 1,4-pentanediol, 2,3-dimethyl- (C7) n-BO _2-4 ; 1,4-pentanediol, 2,4-dimethyl (C7) (Me-E _l ); 1,4-pentanediol, 2,4-dimethyl- (C7) PO ₁ ; 1,4-pentanediol, 2,4-dimethyl- (C7) n-BO _2-4 ; 1,4-pentanediol, 2-methyl- (C6) (Me-E _1-6 ); 1,4-pentanediol, 2-methyl- (C6) P0 _2-3 ; 1,4-pentanediol, 2-methyl- (C6) BO ₁ ; 1,4-pentanediol, 3,3-dimethyl- (C7) (Me-E _l ); 1,4-pentanediol, 3,3-dimethyl- (C7) PO ₁ ; 1,4-pentanediol, 3,3-dimethyl- (C7) n-BO _2-4 ; 1,4-pentanediol, 3,4-dimethyl- (C7) (Me-E _l ); 1,4-pentanediol, 3,4-dimethyl- (C7) PO ₁ ; 1,4-pentanediol, 3,4-dimethyl- (C7) n-BO _2-4 ; 1,4-pentanediol, 3-methyl- (C6) 2 (Me-E _1-6 ); 1,4-pentanediol, 3-methyl- (C6) P0 _2-3 ; 1,4-pentanediol, 3-methyl- (C6) BO ₁ ; 1,4-pentanediol, 4-methyl- (C6) 2 (Me-E _1-6 ); 1,4-pentanediol, 4-methyl- (C6) P0 _2-3 ; 1,4-pentanediol, 4-methyl- (C6) BO ₁ ; 1,5-pentanediol, (C5) (Me-E _4-10 ); 1,5-pentanediol (C5) 2 (Me _El ); 1,5-pentanediol (C5) P0 ₃ ; 1,5-pentanediol, 2,2-dimethyl- (C7) _El-7 ; 1,5-pentanediol, 2,2-dimethyl- (C7) PO ₁ ; 1,5-pentanediol, 2,2-dimethyl- (C7) n-BO _1-2 ; 1,5-pentanediol, 2,3-dimethyl- (C7) _El-7 ; 1,5-pentanediol, 2,3-dimethyl- (C7) PO ₁ ; 1,5-pentanediol 2,3-dimethyl- (C7) n-BO _1-2 ; 1,5-pentanediol, 2,4-dimethyl- (C7) _El-7 ; 1,5-pentanediol, 2,4-dimethyl- (C7) PO ₁ ; 1,5-pentanediol, 2,4-dimethyl- (C7) n-BO _1-2 ; 1,5-pentanediol, 2-ethyl- (C7) _El-5 ; 1,5-pentanediol, 2-ethyl- (C7) n-BO _1-2 ; 1,5-pentanediol, 2-methyl- (C6) (Me-E _1-4 ); 1,5-pentanediol, 2-methyl- (C6) PO ₂ ; 1,5-pentanediol, 3,3-dimethyl- (C7) _El-7 ; 1,5-pentanediol, 3,3-dimethyl- (C7) PO ₁ ; 1,5-pentanediol, 3,3-dimethyl- (C7) n-BO _1-2 ; 1,5-pentanediol, 3-methyl- (C6) (Me E _1-4 ); 1,5-pentanediol, 3-methyl- (C6) P0 ₂ ; 2,3-pentanediol (C5) (Me-E _1-3 ); 2,3-pentanediol (C5) P0 ₂ ; 2,3-pentanediol, 2-methyl- (C6) _El-7 ; 2,3-pentanediol, 2-methyl- (C6) PO ₁ ; 2,3-pentanediol, 2-methyl- (C6) n-BO _1-2 ; 2,3-pentanediol, 3-methyl- (C6) _El-7 ; 2,3-pentanediol, 3-methyl- (C6) PO ₁ ; 2,3-pentanediol, 3-methyl- (C6) n-BO _1-2 ; 2,3-pentanediol, 4-methyl- (C6) _El-7 ; 2,3-pentanediol, 4-methyl- (C6) PO ₁ ; 2,3-pentanediol, 4-methyl- (C6) n-BO _1-2 ; 2,4-pentanediol, (C5) 2 (Me-E _1-4 ); 2,4-pentanediol (C5) P0 ₄ ; 2,4-pentanediol, 2,3-dimethyl- (C7) (Me-E _1-4 ); 2,4-pentanediol, 2,3-dimethyl- (C7) PO ₂ ; 2,4-pentanediol, 2,4-dimethyl- (C7) (Me E _1-4 ); 2,4-pentanediol, 2,4-dimethyl- (C7) PO ₂ ; 2,4-pentanediol, 2-methyl- (C7) (Me-E _5-10 ); 2,4-pentanediol, 2-methyl- (C7) PO ₃ ; 2,4-pentanediol, 3,3-dimethyl- (C7) (Me-E _1-4 ); 2,4-pentanediol, 3,3-dimethyl- (C7) PO ₂ ; 2,4-pentanediol, 3-methyl- (C6) (Me-E _5-10 ); 2,4-pentanediol, 3-methyl- (C6) PO ₃ ; 4. 1,3-hexanediol (C6) (Me-E _1-5 ); 1,3-hexanediol (C6) P0 ₂ ; 1,3-hexanediol (C6) BO ₁ ; 1,3-hexanediol, 2-methyl- (C7) E _2-9 ; 1,3-hexanediol, 2-methyl- (C7) PO ₁ ; 1,3-hexanediol, 2-methyl- (C7) n-BO _1-3 ; 1,3-hexanediol, 2-methyl- (C7) BO ₁ ; 1,3-hexanediol, 3-methyl- (C7) E _2-9 ; 1,3-hexanediol, 3-methyl- (C7) PO ₁ ; 1,3-hexanediol, 3-methyl- (C7) n-BO _1-3 ; 1,3-hexanediol, 4-methyl- (C7) E _2-9 ; 1,3-hexanediol, 4-methyl- (C7) PO ₁ ; 1,3-hexanediol, 4-methyl- (C7) n-BO _1-3 ; 1,3-hexanediol, 5-methyl- (C7) E _2-9 ; 1,3-hexanediol, 5-methyl- (C7) PO ₁ ; 1,3-hexanediol, 5-methyl- (C7) n-BO _1-3 ; 1,4-hexanediol (C6) (Me-E _1-5 ); 1,4-hexanediol (C6) P0 ₂ ; 1,4-hexanediol (C6) BO ₁ ; 1,4-hexanediol, 2-methyl- (C7) E _2-9 ; 1,4-hexanediol, 2-methyl- (C7) PO ₁ ; 1,4-hexanediol, 2-methyl- (C7) n-BO _1-3 ; 1,4-hexanediol, 3-methyl- (C7) E _2-9 ; 1,4-hexanediol, 3-methyl- (C7) PO ₁ ; 1,4-hexanediol, 3-methyl- (C7) n-BO _1-3 ; 1,4-hexanediol, 4-methyl- (C7) E _2-9 ; 1,4-hexanediol, 4-methyl- (C7) PO ₁ ; 1,4-hexanediol, 4-methyl- (C7) n-BO _1-3 ; 1,4-hexanediol, 5-methyl- (C7) E _2-9 ; 1,4-hexanediol, 5-methyl- (C7) PO ₁ ; 1,4-hexanediol, 5-methyl- (C7) n-BO _1-3 ; 1,5-hexanediol (C6) (Me-E _1-5 ); 1,5-hexanediol (C6) P0 ₂ ; 1,5-hexanediol (C6) BO ₁ ; 1,5-hexanediol, 2-methyl- (C7) E _2-9 ; 1,5-hexanediol, 2-methyl- (C7) PO ₁ ; 1,5-hexanediol, 2-methyl- (C7) n-BO _1-3 ; 1,5-hexanediol, 3-methyl- (C7) E _2-9 ; 1,5-hexanediol, 3-methyl- (C7) PO ₁ ; 1,5-hexanediol, 3-methyl- (C7) n-BO _1-3 ; 1,5-hexanediol, 4-methyl- (C7) E _2-9 ; 1,5-hexanediol, 4-methyl- (C7) PO ₁ ; 1,5-hexanediol, 4-methyl- (C7) n-BO _1-3 ; 1,5-hexanediol, 5-methyl- (C7) E _2-9 ; 1,5-hexanediol, 5-methyl- (C7) PO ₁ ; 1,5-hexanediol, 5-methyl- (C7) n-BO _1-3 ; 1,6-hexanediol (C6) (Me-E _1-2 ); 1,6-hexanediol (C6) PO _1-2 ; 1,6-hexanediol (C6) n-BO ₄ ; 1,6-hexanediol 2-methyl- (C7) _El-5 ; 1,6-hexanediol, 2-methyl- (C7) n-BO _1-2 ; 1,6-hexanediol, 3-methyl- (C7) _El-5 ; 1,6-hexanediol, 3-methyl- (C7) n-BO _1-2 ; 2,3-hexanediol (C6) _El-5 ; 2,3-hexanediol (C6) n-BO ₁ ; 2,3-hexanediol (C6) BO ₁ ; 2,4-hexanediol (C6) (Me-E _3-8 ); 2,4-hexanediol (C6) P0 ₃ ; 2,4-hexanediol, 2-methyl- (C7) (Me-E _1-2 ); 2,4-hexanediol 2-methyl- (C7) PO _1-2 ; 2,4-hexanediol, 3-methyl- (C7) (Me-E _1-2 ); 2,4-hexanediol, 3-methyl- (C7) PO _1-2 ; 2,4-hexanediol, 4-methyl- (C7) (Me-E _1-2 ); 2,4-hexanediol, 4-methyl- (C7) PO _1-2 ; 2,4-hexanediol, 5-methyl- (C7) (Me-E _1-2 ); 2,4-hexanediol, 5-methyl- (C7) PO _1-2 ; 2,5-hexanediol (C6) (Me-E _3-8 ); 2,5-hexanediol (C6) P0 ₃ ; 2,5-hexanediol, 2-methyl- (C7) (Me-E _1-2 ); 2,5-hexanediol, 2-methyl- (C7) PO _1-2 ; 2,5-hexanediol, 3-methyl- (C7) (Me-E _1-2 ); 2,5-hexanediol, 3-methyl- (C7) PO _1-2 ; 3,4-hexanediol (C6) EO _1-5 ; 3,4-hexanediol (C6) n-BO ₁ ; 3,4-hexanediol (C6) BO ₁ ; 5. 1,3-heptanediol (C7) _El-7 ; 1,3-heptanediol (C7) PO ₁ ; 1,3-heptanediol (C7) n-BO _1-2 ; 1,4-heptanediol (C7) _El-7 ; 1,4-heptanediol (C7) PO ₁ ; 1,4-heptanediol (C7) n-BO _1-2 ; 1,5-heptanediol (C7) _El-7 ; 1,5-heptanediol (C7) PO ₁ ; 1,5-heptanediol (C7) n-BO _1-2 ; 1,6-heptanediol (C7) _El-7 ; 1,6-heptanediol (C7) PO ₁ ; 1,6-heptanediol (C7) n-BO _1-2 ; 1,7-heptanediol (C7) El _-1 ; 1,7-heptanediol (C7) n-BO ₁ ; 2,4-heptanediol (C7) E _3-10 ; 2,4-heptanediol (C7) (Me-E ₁ ); 2,4-heptanediol (C7) PO ₁ ; 2,4-heptanediol (C7) n-BO ₃ ; 2,5-heptanediol (C7) E _3-10 ; 2,5-heptanediol (C7) (Me-E _l ); 2,5-heptanediol (C7) PO ₁ ; 2,5-heptanediol (C7) n-B0 ₃ ; 2,6-heptanediol (C7) E _3-10 ; 2,6-heptanediol (C7) (Me-E _l ); 2,6-heptanediol (C7) PO ₁ ; 2,6-heptanediol (C7) n-BO ₃ ; 3,5-heptanediol (C7) E _3-10 ; 3,5-heptanediol (C7) (Me-E _l ); 3,5-heptanediol (C7) PO ₁ ; 3,5-heptanediol (C7) n-BO ₃ ; 6. 1,3-butanediol, 3-methyl-2-isopropyl- (C8) PO ₁ ; 2,4-pentanediol, 2,3,3-trimethyl- (C8) PO ₁ ; 1,3-butanediol, 2,2-diethyl- (C8) E _2-5 ; 2,4-hexanediol, 2,3-dimethyl- (C8) E _2-5 ; 2,4-hexanediol, 2,4-dimethyl- (C8) E _2-5 ; 2,4-hexanediol, 2,5-dimethyl- (C8) E _2-5 ; 2,4-hexanediol, 3,3-dimethyl- (C8) E _2-5 ; 2,4-hexanediol, 3,4-dimethyl- (C8) E _2-5 ; 2,4-hexanediol, 3,5-dimethyl- (C8) E _2-5 ; 2,4-hexanediol, 4,5-dimethyl- (C8) E _2-5 ; 2,4-hexanediol, 5,5-dimethyl- (C8) E _2-5 ; 2,5-hexanediol, 2,3-dimethyl- (C8) E _2-5 ; 2,5-hexanediol, 2,4-dimethyl- (C8) E _2-5 ; 2,5-hexanediol, 2,5-dimethyl- (C8) E _2-5 ; 2,5-hexanediol, 3,3-dimethyl- (C8) E _2-5 ; 2,5-hexanediol, 3,4-dimethyl- (C8) E _2-5 ; 3,5-heptanediol, 3-methyl- (C8) E _2-5 ; 1,3-butanediol, 2,2-diethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 2,3-dimethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 2,4-dimethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 2,5-dimethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 3,3-dimethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 3,4-dimethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 3,5-dimethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 4,5-dimethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 5,5-dimethyl-, n-BO _1-2 ; 2,5-hexanediol, 2,3-dimethyl- (C8) n-BO _1-2 ; 2,5-hexanediol, 2,4-dimethyl- (C8) n-BO _1-2 ; 2,5-hexanediol, 2,5-dimethyl- (C8) n-BO _1-2 ; 2,5-hexanediol, 3,3-dimethyl- (C8) n-BO _1-2 ; 2,5-hexanediol, 3,4-dimethyl- (C8) n-BO _1-2 ; 3,5-heptanediol, 3-methyl- (C8) n-BO _1-2 ; 1,3-propanediol, 2- (1,2-dimethylpropyl)-(C8) n-BO ₁ ; 1,3-butanediol, 2-ethyl-2,3-dimethyl- (C8) n-BO ₁ ; 1,3-butanediol, 2-methyl-2-isopropyl- (C8) n-BO ₁ ; 1,4-butanediol, 3-methyl-2-isopropyl- (C8) n-BO ₁ ; 1,3-pentanediol, 2,2,3-trimethyl- (C8) n-BO ₁ ; 1,3-pentanediol, 2,2,4-trimethyl- (C8) n-BO ₁ ; 1,3-pentanediol, 2,4,4-trimethyl- (C8) n-BO ₁ ; 1,3-pentanediol, 3,4,4-trimethyl- (C8) n-BO ₁ ; 1,4-pentanediol, 2,2,3-trimethyl- (C8) n-BO ₁ ; 1,4-pentanediol, 2,2,4-trimethyl- (C8) n-BO ₁ ; 1,4-pentanediol, 2,3,3-trimethyl- (C8) n-BO ₁ ; 1,4-pentanediol, 3,3,4-trimethyl (C8) n-BO ₁ ; 2,4-pentanediol, 2,3,4-trimethyl- (C8) n-BO ₁ ; 2,4-hexanediol, 4-ethyl (C8) n-BO ₁ ; 2,4-heptanediol, 2-methyl- (C8) n-BO ₁ ; 2,4-heptanediol, 3-methyl- (C8) n-BO ₁ ; 2,4-heptanediol, 4-methyl- (C8) n-BO ₁ ; 2,4-heptanediol, 5-methyl- (C8) n-BO ₁ ; 2,4-heptanediol, 6-methyl- (C8) n-BO ₁ ; 2,5-heptanediol, 2-methyl- (C8) n-BO ₁ ; 2,5-heptanediol, 3-methyl- (C8) n-BO ₁ ; 2,5-heptanediol, 4-methyl- (C8) n-BO ₁ ; 2,5-heptanediol, 5-methyl- (C8) n-BO ₁ ; 2,5-heptanediol, 6-methyl- (C8) n-BO ₁ ; 2,6-heptanediol, 2-methyl- (C8) n-BO ₁ ; 2,6-heptanediol, 3-methyl- (C8) n-BO ₁ ; 2,6-heptanediol, 4-methyl- (C8) n-BO ₁ ; 3,5-heptanediol, 2-methyl- (C8) n-BO ₁ ; 1,3-propanediol, 2- (1,2-dimethylpropyl)-(C8) _El-3 ; 1,3-butanediol, 2-ethyl-2,3-dimethyl- (C8) _El-1 ; 1,3-butanediol, 2-methyl-2-isopropyl- (C8) _El-3 ; 1,4-butanediol, 3-methyl-2-isopropyl- (C8) _El-1 ; 1,3-pentanediol, 2,2,3-trimethyl- (C8) El _-1 ; 1,3-pentanediol, 2,2,4-trimethyl- (C8) _El-1 ; 1,3-pentanediol, 2,4,4-trimethyl- (C8) El _-1 ; 1,3-pentanediol, 3,4,4-trimethyl- (C8) El _-1 ; 1,4-pentanediol, 2,2,3-trimethyl- (C8) El _-1 ; 1,4-pentanediol, 2,2,4-trimethyl- (C8) _El-1 ; 1,4-pentanediol, 2,3,3-trimethyl- (C8) El _-1 ; 1,4-pentanediol, 3,3,4-trimethyl- (C8) El _-1 ; 2,4-pentanediol, 2,3,4-trimethyl- (C8) _El-1 ; 2,4-hexanediol, 4-ethyl- (C8) _El-1 ; 2,4-heptanediol, 2-methyl- (C8) _El-1 ; 2,4-heptanediol, 3-methyl- (C8) E _1-3 ; 2,4-heptanediol, 4-methyl- (C8) _El-1 ; 2,4-heptanediol, 5-methyl- (C8) _El-1 ; 2,4-heptanediol, 6-methyl- (C8) _El-1 ; 2,5-heptanediol, 2-methyl- (C8) _El-1 ; 2,5-heptanediol, 3-methyl- (C8) _El-1 ; 2,5-heptanediol, 4-methyl- (C8) _El-1 ; 2,5-heptanediol, 5-methyl- (C8) _El-1 ; 2,5-heptanediol, 6-methyl- (C8) _El-1 ; 2,6-heptanediol, 2-methyl- (C8) _El-3 ; 2,6-heptanediol, 3-methyl- (C8) _El-1 ; 2,6-heptanediol, 4-methyl- (C8) _El-1 ; Or 3,5-heptanediol, 2-methyl- (C8) _El-1 ; And 7. A mixture thereof. The composition of claim 24 wherein said main solvent is selected from the group consisting of: 1. 1,2-propanediol (C3) 2 (Me-E _3-4 ); 1,2-propanediol (C3) P0 ₄ ; 1,2-propanediol, 2-methyl- (C4) (Me-E _8-10 ); 1,2-propanediol, 2-methyl- (C4) 2 (Me _El ); 1,2-propanediol, 2-methyl- (C4) PO ₃ ; 1,3-propanediol (C3) 2 (Me-E ₈ ); 1,3-propanediol (C3) P0 ₆ ; 1,3-propanediol, 2,2-diethyl- (C7) E _4-7 ; 1,3-propanediol, 2,2-diethyl- (C7) PO ₁ ; 1,3-propanediol, 2,2-diethyl- (C7) n-BO ₂ ; 1,3-propanediol, 2,2-dimethyl- (C5) 2 (Me E _l-2 ); 1,3-propanediol, 2,2-dimethyl- (C5) PO ₄ ; 1,3-propanediol, 2- (1-methylpropyl)-(C7) E _4-7 ; 1,3-propanediol, 2- (1-methylpropyl) (C7) PO ₁ ; 1,3-propanediol, 2- (1-methylpropyl)-(C7) n-BO ₂ ; 1,3-propanediol, 2- (2-methylpropyl)-(C7) E _4-7 ; 1,3-propanediol, 2- (2-methylpropyl)-(C7) PO ₁ ; 1,3-propanediol, 2- (2-methylpropyl)-(C7) n-BO ₂ ; 1,3-propanediol, 2-ethyl- (C5) (Me E _9-10 ); 1,3-propanediol, 2-ethyl- (C5) 2 (Me _El ); 1,3-propanediol, 2-ethyl- (C5) P0 ₃ ; 1,3-propanediol, 2-ethyl-2-methyl- (C6) (Me E _3-6 ); 1,3-propanediol, 2-ethyl-2-methyl- (C6) P0 ₂ ; 1,3-propanediol, 2-ethyl-2-methyl- (C6) BO ₁ ; 1,3-propanediol, 2-isopropyl- (C6) (Me E _3-6 ); 1,3-propanediol, 2-isopropyl- (C6) PO ₂ ; 1,3-propanediol, 2-isopropyl- (C6) BO ₁ ; 1,3-propanediol, 2-methyl- (C4) 2 (Me E _4-5 ); 1,3-propanediol, 2-methyl- (C4) P0 ₅ ; 1,3-propanediol, 2-methyl- (C4) B0 ₂ ; 1,3-propanediol, 2-methyl-2-isopropyl- (C7) E _6-9 ; 1,3-propanediol, 2-methyl-2-isopropyl- (C7) PO ₁ ; 1,3-propanediol, 2-methyl-2-isopropyl- (C7) n-BO _2-3 ; 1,3-propanediol, 2-methyl-2-propyl- (C7) E _4-7 ; 1,3-propanediol, 2-methyl-2-propyl- (C7) PO ₁ ; 1,3-propanediol, 2-methyl-2-propyl- (C7) n-BO ₂ ; 1,3-propanediol, 2-propyl- (C6) (Me _El-4 ); 1,3-propanediol, 2-propyl- (C6) PO ₂ ; 2. 1,2-butanediol (C4) (Me E _6-8 ); 1,2-butanediol (C4) P0 _2-3 ; 1,2-butanediol (C4) BO ₁ ; 1,2-butanediol, 2,3-dimethyl- (C6) E _2-5 ; 1,2-butanediol, 2,3-dimethyl- (C6) n-BO ₁ ; 1,2-butanediol, 2-ethyl- (C6) _El-3 ; 1,2-butanediol, 2-ethyl- (C6) n-BO ₁ ; 1,2-butanediol, 2-methyl- (C5) (Me _El-2 ), 1,2-butanediol, 2-methyl- (C5) PO ₁ ; 1,2-butanediol, 3,3-dimethyl- (C6) E _2-5 ; 1,2-butanediol, 3,3-dimethyl- (C6) n-BO ₁ ; 1,2-butanediol, 3-methyl- (C5) (Me _El-1 ); 1,2-butanediol, 3-methyl- (C5) PO ₁ ; 1,3-butanediol (C4) 2 (Me E _5-6 ); 1,3-butanediol (C4) B0 ₂ ; 1,3-butanediol, 2,2,3-trimethyl- (C7) (Me E _l-3 ); 1,3-butanediol, 2,2,3-trimethyl- (C7) PO ₂ ; 1,3-butanediol, 2,2-dimethyl- (C6) (Me E _6-8 ); 1,3-butanediol, 2,2-dimethyl- (C6) PO ₃ ; 1,3-butanediol, 2,3-dimethyl- (C6) (Me E _6-8 ); 1,3-butanediol, 2,3-dimethyl- (C6) PO ₃ ; 1,3-butanediol, 2-ethyl- (C6) (Me E _4-6 ); 1,3-butanediol, 2-ethyl- (C6) P0 _2-3 ; 1,3-butanediol, 2-ethyl- (C6) BO ₁ ; 1,3-butanediol, 2-ethyl-2-methyl- (C7) (Me E ₁ ); 1,3-butanediol, 2-ethyl-2-methyl- (C7) PO ₁ ; 1,3-butanediol, 2-ethyl-2-methyl- (C7) n-BO ₃ ; 1,3-butanediol, 2-ethyl-3-methyl- (C7) (Me _El ); 1,3-butanediol, 2-ethyl-3-methyl- (C7) PO ₁ ; 1,3-butanediol, 2-ethyl-3-methyl- (C7) n-BO ₃ ; 1,3-butanediol, 2-isopropyl- (C7) (Me _El ); 1,3-butanediol, 2-isopropyl- (C7) PO ₁ ; 1,3-butanediol, 2-isopropyl- (C7) n-BO ₃ ; 1,3-butanediol, 2-methyl- (C5) 2 (Me E _2-3 ), 1,3-butanediol, 2-methyl- (C5) PO ₄ ; 1,3-butanediol, 2-propyl- (C7) E _6-8 ; 1,3-butanediol, 2-propyl (C7) PO ₁ ; 1,3-butanediol, 2-propyl- (C7) n-BO _2-3 ; 1,3-butanediol, 3-methyl- (C5) 2 (Me E _2-3 ); 1,3-butanediol, 3-methyl- (C5) P0 ₄ ; 1,4-butanediol (C4) 2 (Me E _3-4 ); 1,4-butanediol (C4) P0 _4-5 ; 1,4-butanediol, 2,2,3-trimethyl- (C7) E _6-9 ; 1,4-butanediol, 2,2,3-trimethyl- (C7) PO ₁ ; 1,4-butanediol, 2,2,3-trimethyl- (C7) n-BO _2-3 ; 1,4-butanediol, 2,2-dimethyl- (C6) (Me E _3-6 ); 1,4-butanediol, 2,2-dimethyl- (C6) PO ₂ ; 1,4-butanediol, 2,2-dimethyl- (C6) BO ₁ ; 1,4-butanediol, 2,3-dimethyl- (C6) (Me E _3-6 ); 1,4-butanediol, 2,3-dimethyl- (C6) PO ₂ ; 1,4-butanediol, 2,3-dimethyl- (C6) BO ₁ ; 1,4-butanediol, 2-ethyl- (C6) (Me E _1-4 ); 1,4-butanediol, 2-ethyl- (C6) P0 ₂ ; 1,4-butanediol, 2-ethyl-2-methyl- (C7) E _4-7 ; 1,4-butanediol, 2-ethyl-2-methyl- (C7) PO ₁ ; 1,4-butanediol, 2-ethyl-2-methyl- (C7) n-BO ₂ ; 1,4-butanediol, 2-ethyl-3-methyl- (C7) E _4-7 ; 1,4-butanediol, 2-ethyl-3-methyl- (C7) PO ₁ ; 1,4-butanediol, 2-ethyl-3-methyl- (C7) n-BO ₂ ; 1,4-butanediol, 2-isopropyl- (C7) E _4-7 ; 1,4-butanediol, 2-isopropyl- (C7) PO ₁ ; 1,4-butanediol, 2-isopropyl- (C7) n-BO ₂ ; 1,4-butanediol, 2-methyl- (C5) (Me E _9-10 ); 1,4-butanediol, 2-methyl- (C5) 2 (Me _El ); 1,4-butanediol, 2-methyl- (C5) PO ₃ ; 1,4-butanediol, 2-propyl- (C7) E _2-5 ; 1,4-butanediol, 2-propyl (C7) n-BO ₁ ; 1,4-butanediol, 3-ethyl-l-methyl- (C7) E _6-8 ; 1,4-butanediol, 3-ethyl-l-methyl- (C7) PO ₁ ; 1,4-butanediol, 3-ethyl-l-methyl- (C7) n-BO _2-3 ; 2,3-butanediol (C4) (Me E _9-10 ); 2,3-butanediol (C4) 2 (Me _El ); 2,3-butanediol (C4) PO _3-4 , 2,3-butanediol, 2,3-dimethyl- (C6) E _7-9 ; 2,3-butanediol, 2,3-dimethyl- (C6) PO ₁ ; 2,3-butanediol, 2,3-dimethyl- (C6) B0 _2-3 ; 2,3-butanediol, 2-methyl- (C5) (Me E _2-5 ); 2,3-butanediol, 2-methyl- (C5) PO ₂ ; 2,3-butanediol, 2-methyl- (C5) BO ₁ ; 3. 1,2-pentanediol (C5) E _7-10 ; 1,2-pentanediol, (C5) PO ₁ ; 1,2-pentanediol, (C5) n-BO ₃ ; 1,2-pentanediol, 2-methyl (C6) _El-1 ; 1,2-pentanediol, 2-methyl (C6) n-BO ₁ ; 1,2-pentanediol, 3-methyl (C6) _El-3 ; 1,2-pentanediol, 3-methyl (C6) n-BO ₁ ; 1,2-pentanediol, 4-methyl (C6) E _1-3 ; 1,2-pentanediol, 4-methyl (C6) n-BO ₁ ; 1,3-pentanediol (C5) 2 (Me-E _1-2 ); 1,3-pentanediol (C5) P0 _3-4 ; 1,3-pentanediol, 2,2-dimethyl- (C7) (Me-E _l ); 1,3-pentanediol, 2,2-dimethyl- (C7) PO ₁ ; 1,3-pentanediol, 2,2-dimethyl- (C7) n-BO ₃ ; 1,3-pentanediol, 2,3-dimethyl- (C7) (Me-E _l ); 1,3-pentanediol, 2,3-dimethyl- (C7) PO ₁ ; 1,3-pentanediol, 2,3-dimethyl- (C7) n-BO ₃ ; 1,3-pentanediol, 2,4-dimethyl- (C7) (Me-E _l ), 1,3-pentanediol, 2,4-dimethyl- (C7) PO ₁ ; 1,3-pentanediol, 2,4-dimethyl- (C7) n-BO ₃ ; 1,3-pentanediol, 2-ethyl- (C7) E _6-8 ; 1,3-pentanediol, 2-ethyl- (C7) PO ₁ ; 1,3-pentanediol, 2-ethyl- (C7) n-BO _2-3 ; 1,3-pentanediol, 2-methyl- (C6) 2 (Me-E _4-6 ); 1,3-pentanediol, 2-methyl (C6) P0 _2-3 ; 1,3-pentanediol, 3,4-dimethyl- (C7) (Me-E _l ); 1,3-pentanediol, 3,4-dimethyl- (C7) PO ₁ ; 1,3-pentanediol, 3,4-dimethyl- (C7) n-BO ₃ ; 1,3-pentanediol, 3-methyl- (C6) 2 (Me-E _4-6 ); 1,3-pentanediol, 3-methyl- (C6) P0 _2-3 ; 1,3-pentanediol, 4,4-dimethyl- (C7) (Me-E _l ); 1,3-pentanediol, 4,4-dimethyl- (C7) PO ₁ ; 1,3-pentanediol, 4,4-dimethyl- (C7) n-BO ₃ ; 1,3-pentanediol, 4-methyl- (C6) 2 (Me-E _4-6 ); 1,3-pentanediol, 4-methyl- (C6) P0 _2-3 ; 1,4-pentanediol (C5) 2 (Me-E _1-2 ); 1,4-pentanediol (C5) PO _3-4 ; 1,4-pentanediol, 2,2-dimethyl- (C7) (Me-E _l ); 1,4-pentanediol, 2,2-dimethyl- (C7) PO ₁ ; 1,4-pentanediol, 2,2-dimethyl- (C7) n-BO ₃ ; 1,4-pentanediol, 2,3-dimethyl- (C7) (Me-E _l ); 1,4-pentanediol, 2,3-dimethyl- (C7) PO ₁ ; 1,4-pentanediol, 2,3-dimethyl- (C7) n-BO ₃ ; 1,4-pentanediol, 2,4-dimethyl (C7) (Me-E _l ); 1,4-pentanediol, 2,4-dimethyl- (C7) PO ₁ ; 1,4-pentanediol, 2,4-dimethyl- (C7) n-BO ₃ ; 1,4-pentanediol, 2-methyl- (C6) (Me-E _4-6 ); 1,4-pentanediol, 2-methyl- (C6) P0 _2-3 ; 1,4-pentanediol, 3,3-dimethyl- (C7) (Me-E _l ); 1,4-pentanediol, 3,3-dimethyl- (C7) PO ₁ ; 1,4-pentanediol, 3,3-dimethyl- (C7) n-BO ₃ ; 1,4-pentanediol, 3,4-dimethyl- (C7) (Me-E _l ); 1,4-pentanediol, 3,4-dimethyl- (C7) PO ₁ ; 1,4-pentanediol, 3,4-dimethyl- (C7) n-BO ₃ ; 1,4-pentanediol, 3-methyl- (C6) 2 (Me-E _4-6 ); 1,4-pentanediol, 3-methyl- (C6) P0 _2-3 ; 1,4-pentanediol, 4-methyl (C6) 2 (Me-E _4-6 ); 1,4-pentanediol, 4-methyl- (C6) P0 _2-3 ; 1,5-pentanediol, (C5) (Me-E _8-10 ); 1,5-pentanediol (C5) 2 (Me-E ₁ ); 1,5-pentanediol (C5) P0 ₃ ; 1,5-pentanediol, 2,2-dimethyl- (C7) E _4-7 ; 1,5-pentanediol, 2,2-dimethyl- (C7) PO ₁ ; 1,5-pentanediol, 2,2-dimethyl- (C7) n-BO ₂ ; 1,5-pentanediol, 2,3-dimethyl- (C7) E _4-7 ; 1,5-pentanediol, 2,3-dimethyl- (C7) PO ₁ ; 1,5-pentanediol, 2,3-dimethyl- (C7) n-B0 ₂ ; 1,5-pentanediol, 2,4-dimethyl- (C7) E _4-7 ; 1,5-pentanediol, 2,4-dimethyl- (C7) PO ₁ ; 1,5-pentanediol, 2,4-dimethyl- (C7) n-BO ₂ ; 1,5-pentanediol, 2-ethyl- (C7) E _2-5 ; 1,5-pentanediol, 2-ethyl- (C7) n-BO ₁ ; 1,5-pentanediol, 2-methyl- (C6) (Me-E _1-4 ); 1,5-pentanediol, 2-methyl- (C6) PO ₂ ; 1,5-pentanediol, 3,3-dimethyl- (C7) E _4-7 ; 1,5-pentanediol, 3,3-dimethyl- (C7) PO ₁ ; 1,5-pentanediol, 3,3-dimethyl- (C7) n-BO ₂ ; 1,5-pentanediol, 3-methyl- (C6) (Me-E _1-4 ); 1,5-pentanediol, 3-methyl- (C6) P0 ₂ ; 2,3-pentanediol (C5) (Me-E _1-3 ); 2,3-pentanediol (C5) P0 ₂ ; 2,3-pentanediol, 2-methyl- (C6) E _4-7 ; 2,3-pentanediol, 2-methyl- (C6) PO ₁ ; 2,3-pentanediol, 2-methyl (C6) n-BO ₂ ; 2,3-pentanediol, 3-methyl- (C6) E _4-7 ; 2,3-pentanediol, 3-methyl- (C6) PO ₁ ; 2,3-pentanediol, 3-methyl- (C6) n-BO ₂ ; 2,3-pentanediol, 4-methyl- (C6) E _4-7 ; 2,3-pentanediol, 4-methyl- (C6) PO ₁ ; 2,3-pentanediol, 4-methyl- (C6) n-BO ₂ ; 2,4-pentanediol (C5) 2 (Me-E _2-4 ); 2,4-pentanediol (C5) P0 ₄ ; 2,4-pentanediol, 2,3-dimethyl- (C7) (Me-E _2-4 ); 2,4-pentanediol, 2,3-dimethyl- (C7) PO ₂ ; 2,4-pentanediol, 2,4-dimethyl- (C7) (Me-E _2-4 ); 2,4-pentanediol, 2,4-dimethyl- (C7) PO ₂ ; 2,4-pentanediol, 2-methyl- (C7) (Me-E _8-10 ); 2,4-pentanediol, 2-methyl- (C7) PO ₃ ; 2,4-pentanediol, 3,3-dimethyl- (C7) (Me-E _2-4 ); 2,4-pentanediol, 3,3-dimethyl- (C7) PO ₂ ; 2,4-pentanediol, 3-methyl- (C6) (Me-E _8-10 ); 2,4-pentanediol, 3-methyl- (C6) PO ₃ ; 4. 1,3-hexanediol (C6) (Me-E _2-5 ); 1,3-hexanediol (C6) P0 ₂ ; 1,3-hexanediol (C6) BO ₁ ; 1,3-hexanediol, 2-methyl- (C7) E _6-8 ; 1,3-hexanediol, 2-methyl- (C7) PO ₁ ; 1,3-hexanediol, 2-methyl- (C7) n-BO _2-3 ; 1,3-hexanediol, 3-methyl- (C7) E _6-8 ; 1,3-hexanediol, 3-methyl- (C7) PO ₁ ; 1,3-hexanediol, 3-methyl (C7) n-BO _2-3 ; 1,3-hexanediol, 4-methyl- (C7) E _6-8 ; 1,3-hexanediol, 4-methyl- (C7) PO ₁ ; 1,3-hexanediol, 4-methyl- (C7) n-BO _2-3 ; 1,3-hexanediol, 5-methyl- (C7) E _6-8 ; 1,3-hexanediol, 5-methyl- (C7) PO ₁ ; 1,3-hexanediol, 5-methyl- (C7) n-BO _2-3 ; 1,4-hexanediol (C6) (Me-E _2-5 ); 1,4-hexanediol (C6) P0 ₂ ; 1,4-hexanediol (C6) BO ₁ ; 1,4-hexanediol, 2-methyl- (C7) E _6-8 ; 1,4-hexanediol, 2-methyl- (C7) PO ₁ ; 1,4-hexanediol, 2-methyl- (C7) n-BO _2-3 ; 1,4-hexanediol, 3-methyl- (C7) E _6-8 ; 1,4-hexanediol, 3-methyl- (C7) PO ₁ ; 1,4-hexanediol, 3-methyl- (C7) n-BO _2-3 ; 1,4-hexanediol, 4-methyl- (C7) E _6-8 ; 1,4-hexanediol, 4-methyl- (C7) PO ₁ ; 1,4-hexanediol, 4-methyl- (C7) n-BO _2-3 ; 1,4-hexanediol, 5-methyl- (C7) E _6-8 ; 1,4-hexanediol, 5-methyl- (C7) PO ₁ ; 1,4-hexanediol, 5-methyl- (C7) n-BO _2-3 ; 1,5-hexanediol (C6) (Me-E _2-5 ); 1,5-hexanediol (C6) P0 ₂ ; 1,5-hexanediol (C6) BO ₁ ; 1,5-hexanediol, 2-methyl- (C7) E _6-8 ; 1,5-hexanediol, 2-methyl- (C7) PO ₁ ; 1,5-hexanediol, 2-methyl- (C7) n-BO _2-3 ; 1,5-hexanediol, 3-methyl- (C7) E _6-8 ; 1,5-hexanediol, 3-methyl- (C7) PO ₁ ; 1,5-hexanediol, 3-methyl- (C7) n-BO _2-3 ; 1,5-hexanediol, 4-methyl- (C7) E _6-8 ; 1,5-hexanediol, 4-methyl- (C7) PO ₁ ; 1,5-hexanediol, 4-methyl- (C7) n-BO _2-3 ; 1,5-hexanediol, 5-methyl- (C7) E _6-8 ; 1,5-hexanediol, 5-methyl- (C7) PO ₁ ; 1,5-hexanediol, 5-methyl- (C7) n-BO _2-3 ; 1,6-hexanediol (C6) (Me-E _1-2 ); 1,6-hexanediol (C6) PO _1-2 ; 1,6-hexanediol (C6) n-B0 ₄ ; 1,6-hexanediol, 2-methyl- (C7) E _2-5 ; 1,6-hexanediol, 2-methyl- (C7) n-BO ₁ ; 1,6-hexanediol, 3-methyl- (C7) E _2-5 ; 1,6-hexanediol, 3-methyl- (C7) n-BO ₁ ; 2,3-hexanediol (C6) E _2-5 ; 2,3-hexanediol (C6) n-BO ₁ ; 2,4-hexanediol (C6) (Me-E _5-8 ); 2,4-hexanediol (C6) P0 ₃ ; 2,4-hexanediol, 2-methyl- (C7) (Me-E _1-2 ); 2,4-hexanediol, 2-methyl- (C7) PO _1-2 ; 2,4-hexanediol, 3-methyl- (C7) (Me-E _1-2 ); 2,4-hexanediol, 3-methyl- (C7) PO _1-2 ; 2,4-hexanediol, 4-methyl- (C7) (Me-E _1-2 ); 2,4-hexanediol, 4-methyl- (C7) PO _1-2 ; 2,4-hexanediol, 5-methyl- (C7) (Me-E _1-2 ); 2,4-hexanediol, 5-methyl- (C7) PO _1-2 ; 2,5-hexanediol (C6) (Me-E _5-8 ); 2,5-hexanediol (C6) P0 ₃ ; 2,5-hexanediol, 2-methyl- (C7) (Me-E _1-2 ); 2,5-hexanediol, 2-methyl- (C7) PO _1-2 ; 2,5-hexanediol, 3-methyl- (C7) (Me-E _1-2 ); 2,5-hexanediol, 3-methyl- (C7) PO _1-2 ; 3,4-hexanediol (C6) E0 _2-5 ; 3,4-hexanediol (C6) n-BO ₁ ; 5. 1,3-heptanediol (C7) E _3-6 ; 1,3-heptanediol (C7) PO ₁ ; 1,3-heptanediol (C7) n-BO ₂ ; 1,4-heptanediol (C7) E _3-6 ; 1,4-heptanediol (C7) PO ₁ ; 1,4-heptanediol (C7) n-BO ₂ ; 1,5-heptanediol (C7) E _3-6 ; 1,5-heptanediol (C7) PO ₁ ; 1,5-heptanediol (C7) n-BO ₂ ; 1,6-heptanediol (C7) E _3-6 ; 1,6-heptanediol (C7) PO ₁ ; 1,6-heptanediol (C7) n-BO ₂ ; 1,7-heptanediol (C7) El _-1 ; 1,7-heptanediol (C7) n-BO ₁ ; 2,4-heptanediol (C7) E _7-10 ; 2,4-heptanediol (C7) (Me-E _l ); 2,4-heptanediol (C7) PO ₁ ; 2,4-heptanediol (C7) n-BO ₃ ; 2,5-heptanediol (C7) E _7-10 ; 2,5-heptanediol (C7) (Me-E _l ); 2,5-heptanediol (C7) PO ₁ ; 2,5-heptanediol (C7) n-BO ₃ ; 2,6-heptanediol (C7) E _7-10 ; 2,6-heptanediol (C7) (Me-E _l ); 2,6-heptanediol (C7) PO ₁ ; 2,6-heptanediol (C7) n-BO ₃ ; 3,5-heptanediol (C7) E _7-10 ; 3,5-heptanediol (C7) (Me-E ₁ ); 3,5-heptanediol (C7) PO ₁ ; 3,5-heptanediol (C7) n-BO ₃ ; 6. 1,3-butanediol, 3-methyl-2-isopropyl- (C8) PO ₁ ; 2,4-pentanediol, 2,3,3-trimethyl- (C8) PO ₁ ; 1,3-butanediol, 2,2-diethyl- (C8) E _2-5 ; 2,4-hexanediol, 2,3-dimethyl- (C8) E _2-5 ; 2,4-hexanediol, 2,4-dimethyl- (C8) E _2-5 ; 2,4-hexanediol, 2,5-dimethyl- (C8) E _2-5 ; 2,4-hexanediol, 3,3-dimethyl- (C8) E _2-5 ; 2,4-hexanediol, 3,4-dimethyl- (C8) E _2-5 ; 2,4-hexanediol, 3,5-dimethyl- (C8) E _2-5 ; 2,4-hexanediol, 4,5-dimethyl- (C8) E _2-5 ; 2,4-hexanediol, 5,5-dimethyl- (C8) E _2-5 ; 2,5-hexanediol, 2,3-dimethyl- (C8) E _2-5 ; 2,5-hexanediol, 2,4-dimethyl- (C8) E _2-5 ; 2,5-hexanediol, 2,5-dimethyl- (C8) E _2-5 ; 2,5-hexanediol, 3,3-dimethyl- (C8) E _2-5 ; 2,5-hexanediol, 3,4-dimethyl- (C8) E _2-5 ; 3,5-heptanediol, 3-methyl- (C8) E _2-5 ; 1,3-butanediol, 2,2-diethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 2,3-dimethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 2,4-dimethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 2,5-dimethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 3,3-dimethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 3,4-dimethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 3,5-dimethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 4,5-dimethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 5,5-dimethyl-, n-BO _1-2 ; 2,5-hexanediol, 2,3-dimethyl (C8) n-BO _1-2 ; 2,5-hexanediol, 2,4-dimethyl- (C8) n-BO _1-2 ; 2,5-hexanediol, 2,5-dimethyl- (C8) n-BO _1-2 ; 2,5-hexanediol, 3,3-dimethyl- (C8) n-BO _1-2 ; 2,5-hexanediol, 3,4-dimethyl- (C8) n-BO _1-2 ; 3,5-heptanediol, 3-methyl- (C8) n-BO _1-2 ; 1,3-propanediol, 2- (1,2-dimethylpropyl)-(C8) n-BO ₁ ; 1,3-butanediol, 2-ethyl-2,3-dimethyl- (C8) n-BO ₁ ; 1,3-butanediol, 2-methyl-2-isopropyl- (C8) n-BO ₁ ; 1,4-butanediol, 3-methyl-2-isopropyl- (C8) n-BO ₁ ; 1,3-pentanediol, 2,2,3-trimethyl (C8) n-BO ₁ ; 1,3-pentanediol, 2,2,4-trimethyl- (C8) n-BO ₁ ; 1,3-pentanediol, 2,4,4-trimethyl- (C8) n-BO ₁ ; 1,3-pentanediol, 3,4,4-trimethyl- (C8) n-BO ₁ ; 1,4-pentanediol, 2,2,3-trimethyl- (C8) n-BO ₁ ; 1,4-pentanediol, 2,2,4-trimethyl- (C8) n-BO ₁ ; 1,4-pentanediol, 2,3,3-trimethyl- (C8) n-BO ₁ ; 1,4-pentanediol, 2,3,4-trimethyl (C8) n-BO ₁ ; 1,4-pentanediol, 3,3,4-trimethyl- (C8) n-BO ₁ ; 2,4-pentanediol, 2,3,4-trimethyl- (C8) n-BO ₁ ; 2,4-hexanediol, 4-ethyl- (C8) n-BO ₁ ; 2,4-heptanediol, 2-methyl- (C8) n-BO ₁ ; 2,4-heptanediol, 3-methyl- (C8) n-BO ₁ ; 2,4-heptanediol, 4-methyl- (C8) n-BO ₁ ; 2,4-heptanediol, 5-methyl- (C8) n-BO ₁ ; 2,4-heptanediol, 6-methyl- (C8) n-BO ₁ ; 2,5-heptanediol, 2-methyl- (C8) n-BO ₁ ; 2,5-heptanediol, 3-methyl- (C8) n-BO ₁ ; 2,5-heptanediol, 4-methyl- (C8) n-BO ₁ ; 2,5-heptanediol, 5-methyl- (C8) n-BO ₁ ; 2,5-heptanediol, 6-methyl- (C8) n-BO ₁ ; 2,6-heptanediol, 2-methyl- (C8) n-BO ₁ ; 2,6-heptanediol, 3-methyl- (C8) n-BO ₁ ; 2,6-heptanediol, 4-methyl- (C8) n-BO ₁ ; 3,5-heptanediol, 2-methyl- (C8) n-BO ₁ ; 1,3-propanediol, 2- (1,2-dimethylpropyl)-(C8) _El-3 ; 1,3-butanediol, 2-ethyl-2,3-dimethyl- (C8) _El-1 ; 1,3-butanediol, 2-methyl-2-isopropyl- (C8) _El-3 ; 1,4-butanediol, 3-methyl-2-isopropyl- (C8) _El-1 ; 1,3-pentanediol, 2,2,3-trimethyl- (C8) El _-1 ; 1,3-pentanediol, 2,2,4-trimethyl- (C8) _El-1 ; 1,3-pentanediol, 2,4,4-trimethyl- (C8) El _-1 ; 1,3-pentanediol, 3,4,4-trimethyl- (C8) El _-1 ; 1,4-pentanediol, 2,2,3-trimethyl- (C8) El _-1 ; 1,4-pentanediol, 2,2,4-trimethyl- (C8) _El-1 ; 1,4-pentanediol, 2,3,3-trimethyl- (C8) El _-1 ; 1,4-pentanediol, 2,3,4-trimethyl- (C8) _El-1 ; 1,4-pentanediol, 3,3,4-trimethyl (C8) E _1-3 ; 2,4-pentanediol, 2,3,4-trimethyl- (C8) E _1-3 ; 2,4-hexanediol, 4-ethyl- (C8) _El-1 ; 2,4-heptanediol, 2-methyl- (C8) _El-1 ; 2,4-heptanediol, 3-methyl- (C8) _El-1 ; 2,4-heptanediol, 4-methyl- (C8) _El-1 ; 2,4-heptanediol, 5-methyl- (C8) _El-1 ; 2,4-heptanediol, 6-methyl- (C8) _El-1 ; 2,5-heptanediol, 2-methyl- (C8) _El-1 ; 2,5-heptanediol, 3-methyl- (C8) _El-1 ; 2,5-heptanediol, 4-methyl- (C8) _El-1 ; 2,5-heptanediol, 5-methyl- (C8) _El-1 ; 2,5-heptanediol, 6-methyl- (C8) _El-1 ; 2,6-heptanediol, 2-methyl- (C8) _El-3 ; 2,6-heptanediol, 3-methyl- (C8) _El-1 ; 2,6-heptanediol, 4-methyl- (C8) _El-1 ; Or 3,5-heptanediol, 2-methyl- (C8) _El-1 ; And 7. A mixture thereof. The composition of claim 1, wherein said main solvent is selected from the group consisting of: 1-phenyl-1,2-ethanediol; 1-phenyl-1,2-propanediol; 2-phenyl-1,2-propanediol; 3-phenyl-1,2-propanediol; 1- (3-methylphenyl) -1,3-propanediol; 1- (4-methylphenyl) -1,3-propanediol; 2-methyl-1-phenyl-1,3-propanediol; 1-phenyl-1,3-butanediol; 3-phenyl-1,3-butanediol; 1-phenyl-1,4-butanediol; 2-phenyl-1,4-butanediol; 1-phenyl-2,3-butanediol and mixtures thereof. The composition of claim 26 wherein said main solvent is selected from the group consisting of: 1-phenyl-1,2-ethanediol; 1-phenyl-1,2-propanediol; 2-phenyl-1,2-propanediol; 3-phenyl-1,2-propanediol; 1- (3-methylphenyl) -1,3-propanediol; 1- (4-methylphenyl) -1,3-propanediol; 2-methyl-1-phenyl-1,3-propanediol; 1-phenyl-1,3-butanediol; 3-phenyl-1,3-butanediol; 1-phenyl-1,4-butanediol; And mixtures thereof. The composition of claim 27 wherein said main solvent is selected from the group consisting of: 1-phenyl-1,2-propanediol; 2-phenyl-1,2-propanediol; 3-phenyl-1,2-propanediol; 1- (3-methylphenyl) -1,3-propanediol; 1- (4-methylphenyl) -1,3-propanediol; 2-methyl-1-phenyl-1,3-propanediol; Or 1-phenyl-1,4-butanediol; And mixtures thereof. 6. One carbon-carbon double according to claim 1, wherein at least one CH ₂ group is bonded and two hydrogen atoms are removed from adjacent carbon atoms in the molecule for each CH ₂ group bonded thereto. Wherein by forming a bond, the main solvent is selected from the group consisting of solvents which are homologues or analogs of the parent compound, wherein the number of hydrogen atoms in the molecule remains constant: I. a, b or a monool comprising a and b: a. n-propanol; b. 2-butanol or 2-methyl-2-propanol; II. Hexane diol isomers comprising: 2,3-butanediol, 2,3-dimethyl-; 1,2-butanediol, 2,3-dimethyl-; 1,2-butanediol, 3,3-dimethyl-; 2,3-pentanediol, 2-methyl-; 2,3-pentanediol, 3-methyl-; 2,3-pentanediol. 4-methyl-; 2,3-hexanediol; 3,4-hexanediol; 1,2-butanediol, 2-ethyl-; 1,2-pentanediol, 2-methyl-; 1,2-pentanediol, 3-methyl-; 1,2-pentanediol, 4-methyl-; Or 1,2-hexanediol; III. Heptane diol isomers comprising: 1,3-propanediol, 2-butyl-; 1,3-propanediol, 2,2-diethyl-; 1,3-propanediol, 2- (l-methylpropyl)-; 1,3-propanediol, 2- (2-methylpropyl)-; 1,3-propanediol, 2-methyl-2-propyl-; 1,2-butanediol, 2,3,3-trimethyl; 1,4-butanediol, 2-ethyl-2-methyl-; 1.4-butanediol, 2-ethyl-3-methyl-; 1,4-butanediol, 2-propyl-; 1,4-butanediol, 2-isopropyl-; 1,5-pentanediol, 2,2-dimethyl-; 1,5-pentanediol, 2,3-dimethyl-; 1,5-pentanediol, 2,4-dimethyl-; 1,5-pentanediol, 3,3-dimethyl-; 2,3-pentanediol, 2,3-dimethyl-; 2,3-pentanediol, 2,4-dimethyl-; 2,3-pentanediol, 3,4-dimethyl-; 2,3-pentanediol, 4,4-dimethyl-; 3,4-pentanediol, 2,3-dimethyl-; 1,5-pentanediol, 2-ethyl-; 1,6-hexanediol, 2-methyl-; 1,6-hexanediol, 3-methyl-; 2,3-hexanediol, 2-methyl-; 2,3-hexanediol, 3-methyl-; 2,3-hexanediol, 4-methyl-; 2,3-hexanediol, 5-methyl-; 3,4-hexanediol, 2-methyl-; 3,4-hexanediol, 3-methyl-; 1,3-heptanediol; 1,4-heptanediol; 1,5-heptanediol; Or 1,6-heptanediol; Ⅳ. Octane diol isomers comprising: 1,3-propanediol, 2- (2-methylbutyl)-; 1,3-propanediol, 2- (1,1-dimethylpropyl)-; 1,3-propanediol, 2- (1,2-dimethylpropyl)-; 1,3-propanediol, 2- (l-ethylpropyl)-; 1,3-propanediol, 2- (l-methylbutyl)-; 1,3-propanediol, 2- (2,2-dimethylpropyl)-; 1,3-propanediol, 2- (3-methylbutyl)-; 1,3-propanediol, 2-butyl-2-methyl-; 1,3-propanediol, 2-ethyl-2-isopropyl-; 1,3-propanediol, 2-ethyl-2-propyl-; 1,3-propanediol, 2-methyl-2- (1-methylpropyl)-; 1,3-propanediol, 2-methyl-2- (2-methylpropyl)-; 1,3-propanediol, 2-t-butyl-2-methyl-; 1,3-butanediol, 2,2-diethyl-; 1,3-butanediol, 2- (1-methylpropyl)-; 1,3-butanediol, 2-butyl-; 1,3-butanediol, 2-ethyl-2,3-dimethyl-; 1,3-butanediol, 2- (1,1-dimethylethyl)-; 1,3-butanediol, 2- (2-methylpropyl)-; 1,3-butanediol, 2-methyl-2isopropyl-; 1,3-butanediol, 2-methyl-2-propyl-; 1,3-butanediol, 3-methyl-2-isopropyl-; 1,3-butanediol, 3-methyl-2-propyl-; 1,4-butanediol, 2,2-diethyl-; 1,4-butanediol, 2-methyl-2-propyl-; 1,4-butanediol, 2- (1-methylpropyl)-; 1,4-butanediol, 2-ethyl-2,3-dimethyl-; 1,4-butanediol, 2-ethyl-3,3-dimethyl-; 1,4-butanediol, 2- (1,1-dimethylethyl)-; 1,4-butanediol, 2- (2-methylpropyl)-; 1,4-butanediol, 2-methyl-3-propyl-; 1,4-butanediol, 3-methyl-2-isopropyl-; 1,3-pentanediol, 2,2,3-trimethyl-; 1,3-pentanediol, 2,2,4-trimethyl-; 1,3-pentanediol, 2,3,4-trimethyl-; 1,3-pentanediol, 2,4,4-trimethyl-; 1,3-pentanediol, 3,4,4-trimethyl-; 1,4-pentanediol, 2,2,3-trimethyl-; 1,4-pentanediol, 2,2,4-trimethyl-; 1,4-pentanediol, 2,3,3-trimethyl-; 1,4-pentanediol, 2,3,4-trimethyl-; 1,4-pentanediol, 3,3,4-trimethyl-; 1,5-pentanediol, 2,2,3-trimethyl-; 1,5-pentanediol, 2,2,4-trimethyl-; 1,5-pentanediol, 2,3,3-trimethyl-; 1,5-pentanediol, 2,3,4-trimethyl-; 2,4-pentanediol, 2,3,3-trimethyl-; 2,4-pentanediol, 2,3,4-trimethyl-; 1,3-pentanediol, 2-ethyl-2-methyl-; 1,3-pentanediol, 2-ethyl-3-methyl-; 1,3-pentanediol, 2-ethyl-4-methyl-; 1,3-pentanediol, 3-ethyl-2-methyl-; 1,4-pentanediol, 2-ethyl-2-methyl-; 1,4-pentanediol, 2-ethyl-3-methyl-; 1,4-pentanediol, 2-ethyl-4-methyl-; 1,4-pentanediol, 3-ethyl-2-methyl-; 1,4-pentanediol, 3-ethyl-3-methyl-; 1,5-pentanediol, 2-ethyl-2-methyl-; 1,5-pentanediol, 2-ethyl-3-methyl-; 1,5-pentanediol, 2-ethyl-4-methyl-; 1,5-pentanediol, 3-ethyl-3-methyl-; 2,4-pentanediol, 3-ethyl-2-methyl-; 1,3-pentanediol, 2-isopropyl-; 1,3-pentanediol, 2-propyl-; 1,4-pentanediol, 2-isopropyl-; 1,4-pentanediol, 2-propyl-; 1,4-pentanediol, 3-isopropyl-; 1,5-pentanediol, 2-isopropyl-; 2,4-pentanediol, 3-propyl-; 1,3-hexanediol, 2,2-dimethyl-; 1,3-hexanediol, 2,3-dimethyl-; 1,3-hexanediol, 2,4-dimethyl-; 1,3-hexanediol, 2,5-dimethyl-; 1,3-hexanediol, 3,4-dimethyl-; 1,3-hexanediol, 3,5-dimethyl-; 1,3-hexanediol, 4,5-dimethyl-; 1,4-hexanediol, 2,2-dimethyl-; 1,4-hexanediol, 2,3-dimethyl-; 1,4-hexanediol, 2,4-dimethyl-; 1,4-hexanediol, 2,4-dimethyl-; 1,4-hexanediol, 3,3-dimethyl-; 1,4-hexanediol, 3,4-dimethyl-; 1,4-hexanediol, 3,5-dimethyl-; 1,3-hexanediol, 4,4-dimethyl-; 1,4-hexanediol, 4,5-dimethyl-; 1,4-hexanediol, 5,5-dimethyl-; 1,5-hexanediol, 2,2-dimethyl-; 1,5-hexanediol, 2,3-dimethyl-; 1,5-hexanediol, 2,4-dimethyl-; 1,5-hexanediol, 2,5-dimethyl-; 1,5-hexanediol, 3,3-dimethyl-; 1,5-hexanediol, 3,4-dimethyl-; 1,5-hexanediol, 3,5-dimethyl-; 1,5-hexanediol, 4,5-dimethyl-; 1,6-hexanediol, 2,2-dimethyl-; 1,6-hexanediol, 2,3-dimethyl-; 1,6-hexanediol, 2,4-dimethyl-; 1,6-hexanediol, 2,5-dimethyl-; 1,6-hexanediol, 3,3-dimethyl-; 1,6-hexanediol, 3,4-dimethyl-; 2,4-hexanediol, 2,3-dimethyl-; 2,4-hexanediol, 2,4-dimethyl-; 2,4-hexanediol, 2,5-dimethyl-; 2,4-hexanediol, 3,3-dimethyl-; 2,4-hexanediol, 3,4-dimethyl-; 2,4-hexanediol, 3,5-dimethyl-; 2,4-hexanediol, 4,5-dimethyl-; 2,4-hexanediol, 5,5-dimethyl-; 2,5-hexanediol, 2,3-dimethyl-; 2,5-hexanediol, 2,4-dimethyl-; 2,5-hexanediol, 2,5-dimethyl-; 2,5-hexanediol, 3,3-dimethyl-; 2,5-hexanediol, 3,4-dimethyl-; 2,6-hexanediol, 3,3-dimethyl-; 1,3-hexanediol, 2-ethyl-; 1,3-hexanediol, 4-ethyl-; 1,4-hexanediol, 2-ethyl-; 1,4-hexanediol, 4-ethyl-; 1,5-hexanediol, 2-ethyl-; 2,4-hexanediol, 3-ethyl-; 2,4-hexanediol, 4-ethyl-; 2,5-hexanediol, 3-ethyl-; 1,3-heptanediol, 2-methyl-; 1,3-heptanediol, 3-methyl-; 1,3-heptanediol, 4-methyl-; 1,3-heptanediol, 5-methyl-; 1,3-heptanediol, 6-methyl-; 1,4-heptanediol, 2-methyl-; 1,4-heptanediol, 3-methyl-; 1,4-heptanediol, 4-methyl-; 1,4-heptanediol, 5-methyl-; 1,4-heptanediol, 6-methyl-; 1,5-heptanediol, 2-methyl-; 1,5-heptanediol, 3-methyl-; 1,5-heptanediol, 4-methyl-; 1,5-heptanediol, 5-methyl-; 1,5-heptanediol, 6-methyl-; 1,6-heptanediol, 2-methyl-; 1,6-heptanediol, 3-methyl-; 1,6-heptanediol, 4-methyl-; 1,6-heptanediol, 5-methyl-; 1,6-heptanediol, 6-methyl-; 2,4-heptanediol, 2-methyl-; 2,4-heptanediol, 3-methyl-; 2,4-heptanediol, 4-methyl-; 2,4-heptanediol, 5-methyl-; 2,4-heptanediol, 6-methyl-; 2,5-heptanediol, 2-methyl-; 2,5-heptanediol, 3-methyl-; 2,5-heptanediol, 4-methyl-; 2,5-heptanediol, 5-methyl-; 2,5-heptanediol, 6-methyl-; 2,6-heptanediol, 2-methyl-; 2,6-heptanediol, 3-methyl-; 2,6-heptanediol, 4-methyl-; 3,4-heptanediol, 3-methyl-; 3,5-heptanediol, 2-methyl-; 3,5-heptanediol, 3-methyl-; 3,5-heptanediol, 4-methyl-; 2,4-octanediol; 2,5-octanediol; 2,6-octanediol; 2,7-octanediol; 3,5-octanediol; Or 3,6-octanediol; V nonan diol isomers comprising: 2,4-pentanediol, 2,3,3,4-tetramethyl-; 2,4-pentanediol, 3-t-butyl-; 2,4-hexanediol, 2,5,5-trimethyl-; 2,4-hexanediol, 3,3,4-trimethyl-; 2,4-hexanediol, 3,3,5-trimethyl-; 2,4-hexanediol, 3,5,5-trimethyl-; 2,4-hexanediol, 4,5,5-trimethyl-; 2,5-hexanediol, 3,3,4-trimethyl-; Or 2,5-hexanediol, 3,3,5-trimethyl-; Ⅵ. Glyceryl ethers, di (hydroxyalkyl) ethers or both comprising: 1,2-propanediol, 3- (n-pentyloxy)-; 1,2-propanediol, 3- (2-pentyloxy)-; 1,2-propanediol, 3- (3-pentyloxy)-; 1,2-propanediol, 3- (2-methyl-1 -butyloxy)-; 1,2-propanediol, 3- (iso-amyloxy)-; 1,2-propanediol, 3- (3-methyl-2-butyloxy)-; 1,2-propanediol, 3- (cyclohexyloxy)-; 1,2-propanediol, 3- (1-cyclohex-1-enyloxy)-; 1,3-propanediol, 2- (pentyloxy)-; 1,3-propanediol, 2- (2-pentyloxy)-; 1,3-propanediol, 2- (3-pentyloxy)-; 1,3-propanediol, 2- (2-methyl-1 -butyloxy)-; 1,3-propanediol, 2- (iso-amyloxy)-; 1,3-propanediol, 2- (3-methyl-2-butyloxy)-; 1,3-propanediol, 2- (cyclohexyloxy)-; 1,3-propanediol, 2- (1-cyclohex-1-enyloxy)-; 1,2-propanediol, 3- (butyloxy)-, triethoxylated; 1,2-propanediol, 3- (butyloxy)-, tetraethoxylated; 1,2-propanediol, 3- (butyloxy)-, pentaethoxylated; 1,2-propanediol, 3- (butyloxy)-, hexaethoxylated; 1,2-propanediol, 3- (butyloxy)-, heptaethoxylation; 1,2-propanediol, 3- (butyloxy)-, octaethoxylation; Or 1,2-propanediol, 3- (butyloxy)-, nonaethoxylation; Iii. Saturated and unsaturated aliphatic cyclic diols and derivatives thereof comprising: (a) saturated diols and derivatives thereof comprising: 1-isopropyl-1,2-cyclobutanediol; 3-ethyl-4-methyl-1,2-cyclobutanediol; 3-propyl-1,2-cyclobutanediol; 3-isopropyl-1,2-cyclobutanediol; 1-ethyl-1,2-cyclopentanediol; 1,2-dimethyl-1,2-cyclopentanediol; 1,4-dimethyl-1,2-cyclopentanediol; 2,4,5-trimethyl-1,3-cyclopentanediol; 3,3-dimethyl-1,2-cyclopentanediol; 3,4-dimethyl-1,2-cyclopentanediol; 3,5-dimethyl-1,2-cyclopentanediol; 3-ethyl-1,2-cyclopentanediol; 4,4-dimethyl-1,2-cyclopentanediol; 4-ethyl-1,2-cyclopentanediol; 1,1-bis (hydroxymethyl) cyclohexane; 1,2-bis (hydroxymethyl) cyclohexane; 1,2-dimethyl1,3-cyclohexanediol; 1,3-bis (hydroxymethyl) cyclohexane; 1,3-dimethyl-1,3-cyclohexanediol; 1,6-dimethyl-1,3-cyclohexanediol; 1-hydroxycyclohexaneethanol; 1-hydroxy-cyclohexanemethanol; 1-ethyl-1,3-cyclohexanediol; 1-methyl-1,2-cyclohexanediol; 2,2-dimethyl-1,3-cyclohexanediol; 2,3-dimethyl-1,4-cyclohexanediol; 2,4-dimethyl-1,3-cyclohexanediol; 2,5-dimethyl-1,3-cyclohexanediol; 2,6-dimethyl-1,4-cyclohexanediol; 2-ethyl-1,3-cyclohexanediol; 2-hydroxycyclohexaneethanol; 2-hydroxyethyl-1-cyclohexanol; 2-hydroxymethylcyclohexanol; 3-hydroxyethyl-1-cyclohexanol; 3-hydroxycyclohexaneethanol; 3-hydroxymethylcyclohexanol; 3-methyl-1,2-cyclohexanediol; 4,4-dimethyl-1,3-cyclohexanediol; 4,5-dimethyl-1,3-cyclohexanediol; 4,6-dimethyl-1,3-cyclohexanediol; 4-ethyl-1,3-cyclohexanediol; 4-hydroxyethyl-1-cyclohexanol; 4-hydroxymethylcyclohexanol; 4-methyl-1,2-cyclohexanediol; 5,5-dimethyl-1,3-cyclohexanediol; 5-ethyl-1,3-cyclohexanediol; 1,2-cycloheptanediol; 2-methyl-1,3-cycloheptanediol; 2-methyl-1,4-cycloheptanediol; 4-methyl-1,3-cycloheptanediol; 5-methyl-1,3-cycloheptanediol; 5-methyl-1,4-cycloheptanediol; 6-methyl-1,4-cycloheptanediol; 1,3-cyclooctanediol; 1,4-cyclooctanediol; 1,5-cyclooctanediol; 1,2-cyclohexanediol, diethoxylation; 1,2-cyclohexanediol, triethoxylation; 1,2-cyclohexanediol, tetraethoxylation; 1,2-cyclohexanediol, pentaethoxylation; 1,2-cyclohexanediol, hexaethoxylation; 1,2-cyclohexanediol, heptaethoxylation; 1,2-cyclohexanediol, octaethoxylation; 1,2-cyclohexanediol, nonaethoxylation; 1,2-cyclohexanediol, monopropoxylation; 1,2-cyclohexanediol, monobutyleneoxylation; 1,2-cyclohexanediol, dibutyleneoxylation; Or 1,2-cyclohexanediol, tributyleneoxylation; And (b) unsaturated aliphatic cyclic diols comprising: 1,2-cyclobutanediol, 1-ethenyl-2-ethyl-; 3-cyclobutene-1,2-diol, 1,2,3,4-tetramethyl-; 3-cyclobutene-1,2-diol, 3,4-diethyl-; 3-cyclobutene-1,2-diol, 3- (1,1-dimethylethyl)-; 3-cyclobutene-1,2-diol, 3-butyl-; 1,2-cyclopentanediol, 1,2-dimethyl-4-methylene-; 1,2-cyclopentanediol, 1-ethyl-3-methylene-; 1,2-cyclopentanediol, 4- (1-propenyl); 3-cyclopentene-1,2-diol, 1-ethyl-3-methyl-; 1,2-cyclohexanediol, 1-ethenyl-; 1,2-cyclohexanediol, 1-methyl-3-methylene-; 1,2-cyclohexanediol, 1-methyl-4-methylene-; 1,2-cyclohexanediol, 3-ethenyl-; 1,2-cyclohexanediol, 4-ethenyl-; 3-cyclohexene-1,2-diol, 2,6-dimethyl-; 3-cyclohexene-1,2-diol, 6,6-dimethyl-; 4-cyclohexene-1,2-diol, 3,6-dimethyl-; 4-cyclohexene-1,2-diol, 4,5-dimethyl-; 3-cyclooctene-1,2-diol; 4-cyclooctene-1,2-diol; Or 5-cyclooctene-1,2-diol; Iii. _Alkoxylated derivatives of C _3-8 diols comprising: 1. 1,2-propanediol (C3) 2 (Me-E _11-14 ); 1,2-propanediol (C3) P0 ₄ ; 1,2-propanediol (C3) BO ₁ ; 1,2-propanediol, 2-methyl- (C4) (Me-E _4-10 ); 1,2-propanediol, 2-methyl- (C4) 2 (Me-E ₁ ); 1,2-propanediol, 2-methyl- (C4) PO ₃ ; 1,2-propanediol, 2-methyl- (C4) n-BO _1-2 ; 1,3-propanediol (C3) 2 (Me-E _6-8 ); 1,3-propanediol (C3) P0 _5-6 ; 1,3-propanediol, 2,2-diethyl- (C7) _El-7 ; 1,3-propanediol, 2,2-diethyl- (C7) PO ₁ ; 1,3-propanediol, 2,2-diethyl- (C7) n-BO _1-2 ; 1,3-propanediol, 2,2-dimethyl- (C5) 2 (Me E _l-2 ); 1,3-propanediol, 2,2-dimethyl- (C5) PO _3-4 ; 1,3-propanediol, 2- (1-methylpropyl)-(C7) _El-7 ; 1,3-propanediol, 2- (1-methylpropyl) (C7) PO ₁ ; 1,3-propanediol, 2- (1-methylpropyl)-(C7) n-BO _1-2 ; 1,3-propanediol, 2- (2-methylpropyl)-(C7) _El-7 ; 1,3-propanediol, 2- (2-methylpropyl)-(C7) PO ₁ ; 1,3-propanediol, 2- (2-methylpropyl)-(C7) n-BO _1-2 ; 1,3-propanediol, 2-ethyl- (C5) (Me E _6-10 ); 1,3-propanediol, 2-ethyl- (C5) 2 (Me _El ); 1,3-propanediol, 2-ethyl- (C5) P0 ₃ ; 1,3-propanediol, 2-ethyl- (C5) BO ₁ ; 1,3-propanediol, 2-ethyl-2-methyl- (C6) (Me _El-6 ); 1,3-propanediol, 2-ethyl-2-methyl- (C6) P0 ₂ ; 1,3-propanediol, 2-ethyl-2-methyl- (C6) BO ₁ ; 1,3-propanediol, 2-isopropyl- (C6) (Me _El-6 ); 1,3-propanediol, 2-isopropyl- (C6) PO ₂ ; 1,3-propanediol, 2-isopropyl- (C6) BO ₁ ; 1,3-propanediol, 2-methyl- (C4) 2 (Me E _2-5 ); 1,3-propanediol, 2-methyl- (C4) P0 _4-5 ; 1,3-propanediol, 2-methyl- (C4) B0 ₂ ; 1,3-propanediol, 2-methyl-2-isopropyl- (C7) E _2-9 ; 1,3-propanediol, 2-methyl-2-isopropyl- (C7) PO ₁ ; 1,3-propanediol, 2-methyl-2-isopropyl- (C7) n-BO _1-3 ; 1,3-propanediol, 2-methyl-2-propyl- (C7) _El-7 ; 1,3-propanediol, 2-methyl-2-propyl- (C7) PO ₁ ; 1,3-propanediol, 2-methyl-2-propyl (C7) n-BO _1-2 ; 1,3-propanediol, 2-propyl- (C6) (Me _{El 1-14} ); 1,3-propanediol, 2-propyl- (C6) PO ₂ ; 1,3-propanediol, 2-propyl- (C6) BO ₁ ; 2. 1,2-butanediol (C4) (Me E _2-8 ); 1,2-butanediol (C4) P0 _2-3 ; 1,2-butanediol (C4) BO ₁ ; 1,2-butanediol, 2,3-dimethyl- (C6) _El-6 ; 1,2-butanediol, 2,3-dimethyl- (C6) BO _1-2 ; 1,2-butanediol, 2-ethyl- (C6) _El-3 ; 1,2-butanediol, 2-ethyl (C6) BO ₁ ; 1,2-butanediol, 2-methyl- (C5) (Me E _l-2 ); 1,2-butanediol, 2-methyl- (C5) PO ₁ ; 1,2-butanediol, 3,3-dimethyl- (C6) _El-6 , 1,2-butanediol, 3,3-dimethyl- (C6) BO _1-2 ; 1,2-butanediol, 3-methyl- (C5) (Me _El-1 ); 1,2-butanediol, 3-methyl- (C5) PO ₁ ; 1,3-butanediol (C4) 2 (Me _{El 1-14} ); 1,3-butanediol (C4) P0 ₅ ; 1,3-butanediol (C4) B0 ₂ ; 1,3-butanediol, 2,2,3-trimethyl- (C7) (Me E _l-3 ); 1,3-butanediol, 2,2,3-trimethyl- (C7) PO _1-2 ; 1,3-butanediol, 2,2-dimethyl- (C6) (Me E _3-8 ); 1,3-butanediol, 2,2-dimethyl- (C6) PO ₃ ; 1,3-butanediol, 2,3-dimethyl- (C6) (Me E _3-8 ); 1,3-butanediol, 2,3-dimethyl- (C6) PO ₃ ; 1,3-butanediol, 2-ethyl- (C6) (Me _El-6 ); 1,3-butanediol, 2-ethyl- (C6) P0 _2-3 ; 1,3-butanediol, 2-ethyl- (C6) BO ₁ ; 1,3-butanediol, 2-ethyl methyl --2- _{- (C7) (Me E l} ); 1,3-butanediol, 2-ethyl-2-methyl- (C7) PO ₁ ; 1,3-butanediol, 2-ethyl-2-methyl- (C7) n-BO _2-4 ; 1,3-butanediol, 2-ethyl-3-methyl- (C7) (Me _El ); 1,3-butanediol, 2-ethyl-3-methyl- (C7) PO ₁ ; 1,3-butanediol, 2-ethyl-3-methyl- (C7) n-BO _2-4 ; 1,3-butanediol, 2-isopropyl- (C7) (Me _El ); 1,3-butanediol, 2-isopropyl- (C7) PO ₁ ; 1,3-butanediol, 2-isopropyl- (C7) n-BO _2-4 ; 1,3-butanediol, 2-methyl- (C5) 2 (Me E _l-3 ); 1,3-butanediol, 2-methyl- (C5) P0 ₄ ; 1,3-butanediol, 2-propyl- (C7) E _2-9 ; 1,3-butanediol, 2-propyl- (C7) PO ₁ ; 1,3-butanediol, 2-propyl- (C7) n-BO _1-3 ; 1,3-butanediol, 3-methyl- (C5) 2 (Me El _l-3 ); 1,3-butanediol, 3-methyl- (C5) P0 ₄ ; 1,4-butanediol (C4) 2 (Me E _2-4 ); 1,4-butanediol (C4) P0 _4-5 ; 1,4-butanediol (C4) B0 ₂ ; 1,4-butanediol, 2,2,3-trimethyl- (C7) E _2-9 ; 1,4-butanediol, 2,2,3-trimethyl- (C7) PO ₁ ; 1,4-butanediol, 2,2,3-trimethyl- (C7) n-BO _1-3 ; 1,4-butanediol, 2,2-dimethyl- (C6) (Me _El-6 ); 1,4-butanediol, 2,2-dimethyl- (C6) PO ₂ ; 1,4-butanediol, 2,2-dimethyl- (C6) BO ₁ ; 1,4-butanediol, 2,3-dimethyl- (C6) (Me _El-6 ); 1,4-butanediol, 2,3-dimethyl- (C6) PO ₂ ; 1,4-butanediol, 2,3-dimethyl- (C6) BO ₁ ; 1,4-butanediol, 2-ethyl- (C6) (Me _{El 1-14} ); 1,4-butanediol, 2-ethyl- (C6) P0 ₂ ; 1,4-butanediol, 2-ethyl- (C6) BO ₁ ; 1,4-butanediol, 2-ethyl-2-methyl- (C7) _El-7 ; 1,4-butanediol, 2-ethyl-2-methyl- (C7) PO ₁ ; 1,4-butanediol, 2-ethyl-2-methyl- (C7) n-BO _1-2 ; 1,4-butanediol, 2-ethyl-3-methyl- (C7) _El-7 ; 1,4-butanediol, 2-ethyl-3-methyl- (C7) PO ₁ ; 1,4-butanediol, 2-ethyl-3-methyl- (C7) n-BO _1-2 ; 1,4-butanediol, 2-isopropyl- (C7) _El-7 ; 1,4-butanediol, 2-isopropyl- (C7) PO ₁ ; 1,4-butanediol, 2-isopropyl- (C7) n-BO _1-2 ; 1,4-butanediol, 2-methyl- (C5) (Me E _6-10 ); 1,4-butanediol, 2-methyl- (C5) 2 (Me _El ); 1,4-butanediol, 2-methyl- (C5) PO ₃ ; 1,4-butanediol, 2-methyl- (C5) BO ₁ ; 1,4-butanediol, 2-propyl- (C7) _El-5 ; 1,4-butanediol, 2-propyl- (C7) n-BO _1-2 ; 1,4-butanediol, 3-ethyl-l-methyl- (C7) E _2-9 ; 1,4-butanediol, 3-ethyl-l-methyl- (C7) PO ₁ ; 1,4-butanediol, 3-ethyl-l-methyl- (C7) n-BO _1-3 ; 2,3-butanediol (C4) (Me _El-6 ); 2,3-butanediol (C4) 2 (Me _El ); 2,3-butanediol (C4) PO _3-4 ; 2,3-butanediol (C4) BO ₁ ; 2,3-butanediol, 2,3-dimethyl- (C6) E _3-9 ; 2,3-butanediol, 2,3-dimethyl- (C6) PO ₁ ; 2,3-butanediol, 2,3-dimethyl- (C6) BO _1-3 ; 2,3-butanediol, 2-methyl- (C5) (Me _El-5 ); 2,3-butanediol, 2-methyl- (C5) 2PO ₂ ; 2,3-butanediol, 2-methyl- (C5) n-BO ₁ ; 2,3-butanediol, 2-methyl- (C5) BO ₁ ; 3. 1,2-pentanediol (C5) E _3-10 ; 1,2-pentanediol, (C5) PO ₁ ; 1,2-pentanediol, (C5) n-BO _2-3 ; 1,2-pentanediol, 2-methyl (C6) E _1-3 ; 1,2-pentanediol, 2-methyl (C6) n-BO ₁ ; 1,2-pentanediol, 2-methyl (C6) BO ₁ ; 1,2-pentanediol, 3-methyl (C6) _El-3 ; 1,2-pentanediol, 3-methyl (C6) n-BO ₁ ; 1,2-pentanediol, 3-methyl (C6) BO ₁ ; 1,2-pentanediol, 4-methyl (C6) _El-1 ; 1,2-pentanediol, 4-methyl (C6) n-BO ₁ ; 1,2-pentanediol, 4-methyl (C6) BO ₁ ; 1,3-pentanediol (C5) 2 (Me-E _1-2 ); 1,3-pentanediol (C5) P0 _3-4 ; 1,3-pentanediol, 2,2-dimethyl- (C7) (Me-E _l ); 1,3-pentanediol, 2,2-dimethyl- (C7) PO ₁ ; 1,3-pentanediol, 2,2-dimethyl- (C7) n-BO _2-4 ; 1,3-pentanediol, 2,3-dimethyl- (C7) (Me-E _l ); 1,3-pentanediol, 2,3-dimethyl- (C7) PO ₁ ; 1,3-pentanediol, 2,3-dimethyl- (C7) n-BO _2-4 ; 1,3-pentanediol, 2,4-dimethyl (C7) (Me-E _l ); 1,3-pentanediol, 2,4-dimethyl- (C7) PO ₁ ; 1,3-pentanediol, 2,4-dimethyl- (C7) n-BO _2-4 ; 1,3-pentanediol, 2-ethyl- (C7) E _2-9 ; 1,3-pentanediol, 2-ethyl- (C7) PO ₁ ; 1,3-pentanediol, 2-ethyl- (C7) n-BO _1-3 ; 1,3-pentanediol, 2-methyl (C6) 2 (Me-E _1-6 ); 1,3-pentanediol, 2-methyl- (C6) P0 _2-3 ; 1,3-pentanediol, 2-methyl- (C6) n-BO ₁ ; 1,3-pentanediol, 2-methyl- (C6) BO ₁ ; 1,3-pentanediol, 3,4-dimethyl- (C7) (Me-E _l ); 1,3-pentanediol, 3,4-dimethyl- (C7) PO ₁ ; 1,3-pentanediol, 3,4-dimethyl- (C7) n-BO _2-4 , 1,3-pentanediol, 3-methyl- (C6) 2 (Me-E _1-6 ); 1,3-pentanediol, 3-methyl- (C6) P0 _2-3 ; 1,3-pentanediol, 3-methyl- (C6) n-BO ₁ ; 1,3-pentanediol, 3-methyl- (C6) BO ₁ ; 1,3-pentanediol, 4,4-dimethyl- (C7) (Me-E _l ); 1,3-pentanediol, 4,4-dimethyl- (C7) PO ₁ ; 1,3-pentanediol, 4,4-dimethyl- (C7) n-BO _2-4 ; 1,3-pentanediol, 4-methyl- (C6) 2 (Me-E _1-6 ); 1,3-pentanediol, 4-methyl- (C6) P0 _2-3 ; 1,3-pentanediol, 4-methyl- (C6) BO ₁ ; 1,4-pentanediol, (C5) 2 (Me-E _1-2 ); 1,4-pentanediol (C5) PO _3-4 ; 1,4-pentanediol, 2,2-dimethyl- (C7) (Me-E _l ), 1,4-pentanediol, 2,2-dimethyl- (C7) PO ₁ ; 1,4-pentanediol, 2,2-dimethyl- (C7) n-BO _2-4 ; 1,4-pentanediol, 2,3-dimethyl- (C7) (Me-E _l ); 1,4-pentanediol, 2,3-dimethyl- (C7) PO ₁ ; 1,4-pentanediol, 2,3-dimethyl- (C7) n-BO _2-4 ; 1,4-pentanediol, 2,4-dimethyl- (C7) (Me-E _l ); 1,4-pentanediol, 2,4-dimethyl- (C7) PO ₁ ; 1,4-pentanediol, 2,4-dimethyl- (C7) n-BO _2-4 ; 1,4-pentanediol, 2-methyl- (C6) (Me-E _1-6 ); 1,4-pentanediol, 2-methyl- (C6) P0 _2-3 ; 1,4-pentanediol, 2-methyl- (C6) n-BO ₁ ; 1,4-pentanediol, 2-methyl- (C6) BO ₁ ; 1,4-pentanediol, 3,3-dimethyl- (C7) (Me-E _l ); 1,4-pentanediol, 3,3-dimethyl- (C7) PO ₁ ; 1,4-pentanediol, 3,3-dimethyl- (C7) n-BO _2-4 ; 1,4-pentanediol, 3,4-dimethyl- (C7) (Me-E _l ); 1,4-pentanediol, 3,4-dimethyl- (C7) PO ₁ ; 1,4-pentanediol, 3,4-dimethyl- (C7) n-BO _2-4 ; 1,4-pentanediol, 3-methyl- (C6) 2 (Me-E _1-6 ); 1,4-pentanediol, 3-methyl- (C6) P0 _2-3 ; 1,4-pentanediol, 3-methyl- (C6) BO ₁ ; 1,4-pentanediol, 4-methyl- (C6) 2 (Me-E _1-6 ); 1,4-pentanediol, 4-methyl- (C6) P0 _2-3 ; 1,4-pentanediol, 4-methyl- (C6) BO ₁ ; 1,5-pentanediol, (C5) (Me-E _4-110 ); 1,5-pentanediol (C5) 2 (Me-E ₁ ); 1,5-pentanediol (C5) P0 ₃ ; 1,5-pentanediol, 2,2-dimethyl- (C7) _El-7 ; 1,5-pentanediol, 2,2-dimethyl- (C7) PO ₁ ; 1,5-pentanediol, 2,2-dimethyl- (C7) n-BO _1-2 ; 1,5-pentanediol, 2,3-dimethyl- (C7) _El-7 ; 1,5-pentanediol, 2,3-dimethyl- (C7) PO ₁ ; 1,5-pentanediol, 2,3-dimethyl- (C7) n-BO _1-2 ; 1,5-pentanediol, 2,4-dimethyl- (C7) _El-7 ; 1,5-pentanediol, 2,4-dimethyl- (C7) PO ₁ ; 1,5-pentanediol, 2,4-dimethyl- (C7) n-BO _1-2 ; 1,5-pentanediol, 2-ethyl- (C7) _El-5 ; 1,5-pentanediol, 2-ethyl- (C7) n-BO _1-2 ; 1,5-pentanediol, 2-methyl- (C6) (Me-E _11-14 ); 1,5-pentanediol, 2-methyl- (C6) PO ₂ ; 1,5-pentanediol, 3,3-dimethyl- (C7) _El-7 ; 1,5-pentanediol, 3,3-dimethyl- (C7) PO ₁ ; 1,5-pentanediol, 3,3-dimethyl- (C7) nBO _1-2 ; 1,5-pentanediol, 3-methyl- (C6) (Me-E _l1-14 ); 1,5-pentanediol, 3-methyl (C6) P0 ₂ ; 2,3-pentanediol, (C5) (Me-E _1-3 ); 2,3-pentanediol, (C5) PO ₂ ; 2,3-pentanediol, 2-methyl- (C6) _El-7 ; 2,3-pentanediol, 2-methyl- (C6) PO ₁ ; 2,3-pentanediol, 2-methyl- (C6) n-BO _1-2 ; 2,3-pentanediol, 3-methyl- (C6) _El-7 ; 2,3-pentanediol, 3-methyl- (C6) PO ₁ ; 2,3-pentanediol, 3-methyl- (C6) n-BO _1-2 ; 2,3-pentanediol, 4-methyl- (C6) _El-7 ; 2,3-pentanediol, 4-methyl- (C6) PO ₁ ; 2,3-pentanediol, 4-methyl- (C6) n-BO _1-2 ; 2,4-pentanediol, (C5) 2 (Me- _Ell-14 ); 2,4-pentanediol (C5) P0 ₄ ; 2,4-pentanediol, 2,3-dimethyl- (C7) (Me-E _ll-14 ); 2,4-pentanediol, 2,3-dimethyl- (C7) PO ₂ ; 2,4-pentanediol, 2,4-dimethyl- (C7) (Me-E _11-14 ); 2,4-pentanediol, 2,4-dimethyl- (C7) PO ₂ ; 2,4-pentanediol, 2-methyl- (C7) (Me E _5-10 ); 2,4-pentanediol, 2-methyl- (C7) PO ₃ ; 2,4-pentanediol, 3,3-dimethyl- (C7) (Me-E _ll-14 ); 2,4-pentanediol, 3,3-dimethyl- (C7) PO ₂ ; 2,4-pentanediol, 3-methyl- (C6) (Me-E _5-10 ); 2,4-pentanediol, 3-methyl- (C6) PO ₃ ; 4. 1,3-hexanediol (C6) (Me-E _1-5 ); 1,3-hexanediol (C6) P0 ₂ ; 1,3-hexanediol (C6) BO ₁ ; 1,3-hexanediol, 2-methyl- (C7) E _2-9 ; 1,3-hexanediol, 2-methyl- (C7) PO ₁ ; 1,3-hexanediol, 2-methyl- (C7) n-BO _1-3 ; 1,3-hexanediol, 2-methyl- (C7) BO ₁ ; 1,3-hexanediol, 3-methyl- (C7) E _2-9 ; 1,3-hexanediol, 3-methyl (C7) PO ₁ ; 1,3-hexanediol, 3-methyl- (C7) n-BO _1-3 ; 1,3-hexanediol, 4-methyl- (C7) E _2-9 ; 1,3-hexanediol, 4-methyl- (C7) PO ₁ ; 1,3-hexanediol, 4-methyl- (C7) n-BO _1-3 ; 1,3-hexanediol, 5-methyl- (C7) E _2-9 ; 1,3-hexanediol, 5-methyl- (C7) PO ₁ ; 1,3-hexanediol, 5-methyl- (C7) n-BO _1-3 ; 1,4-hexanediol (C6) (Me-E _1-5 ); 1,4-hexanediol (C6) P0 ₂ ; 1,4-hexanediol (C6) BO ₁ ; 1,4-hexanediol, 2-methyl- (C7) E _2-9 ; 1,4-hexanediol, 2-methyl- (C7) PO ₁ ; 1,4-hexanediol, 2-methyl- (C7) n-BO _1-3 ; 1,4-hexanediol, 3-methyl- (C7) E _2-9 ; 1,4-hexanediol, 3-methyl- (C7) PO ₁ ; 1,4-hexanediol, 3-methyl- (C7) n-BO _1-3 ; 1,4-hexanediol, 4-methyl- (C7) E _2-9 ; 1,4-hexanediol, 4-methyl- (C7) PO ₁ ; 1,4-hexanediol, 4-methyl- (C7) n-BO _1-3 ; 1,4-hexanediol, 5-methyl- (C7) E _2-9 ; 1,4-hexanediol, 5-methyl- (C7) PO ₁ ; 1,4-hexanediol, 5-methyl- (C7) n-BO _1-3 ; 1,5-hexanediol (C6) (Me-E _1-5 ); 1,5-hexanediol (C6) P0 ₂ ; 1,5-hexanediol (C6) BO ₁ ; 1,5-hexanediol, 2-methyl- (C7) E _2-9 ; 1,5-hexanediol, 2-methyl- (C7) PO ₁ ; 1,5-hexanediol, 2-methyl- (C7) n-BO _1-3 ; 1,5-hexanediol, 3-methyl- (C7) E _2-9 ; 1,5-hexanediol, 3-methyl- (C7) PO ₁ ; 1,5-hexanediol, 3-methyl- (C7) n-BO _1-3 ; 1,5-hexanediol, 4-methyl- (C7) E _2-9 ; 1,5-hexanediol, 4-methyl- (C7) PO ₁ ; 1,5-hexanediol, 4-methyl- (C7) n-BO _1-3 ; 1,5-hexanediol, 5-methyl- (C7) E _2-9 ; 1,5-hexanediol, 5-methyl- (C7) PO ₁ ; 1,5-hexanediol, 5-methyl- (C7) n-BO _1-3 ; 1,6-hexanediol (C6) (Me-E _1-2 ); 1,6-hexanediol (C6) PO _1-2 ; 1,6-hexanediol (C6) n-BO ₄ ; 1,6-hexanediol, 2-methyl- (C7) _El-5 ; 1,6-hexanediol, 2-methyl- (C7) n-BO _1-2 ; 1,6-hexanediol, 3-methyl- (C7) _El-5 ; 1,6-hexanediol, 3-methyl- (C7) n-BO _1-2 ; 2,3-hexanediol (C6) _El-5 ; 2,3-hexanediol (C6) n-BO ₁ ; 2,3-hexanediol (C6) BO ₁ ; 2,4-hexanediol (C6) (Me-E _3-8 ); 2,4-hexanediol (C6) PO ₃ ; 2,4-hexanediol, 2-methyl- (C7) (Me-E _1-2 ); 2,4-hexanediol, 2-methyl- (C7) PO _1-2 ; 2,4-hexanediol, 3-methyl- (C7) (Me-E _1-2 ); 2,4-hexanediol 3-methyl- (C7) PO _1-2 ; 2,4-hexanediol, 4-methyl- (C7) (Me-E _1-2 ); 2,4-hexanediol 4-methyl- (C7) PO _1-2 ; 2,4-hexanediol, 5-methyl- (C7) (Me-E _1-2 ); 2,4-hexanediol 5-methyl- (C7) PO _1-2 ; 2,5-hexanediol (C6) (Me-E _3-8 ); 2,5-hexanediol (C6) P0 ₃ ; 2,5-hexanediol, 2-methyl- (C7) (Me-E _1-2 ); 2,5-hexanediol, 2-methyl- (C7) PO _1-2 ; 2,5-hexanediol, 3-methyl- (C7) (Me-E _1-2 ); 2,5-hexanediol, 3-methyl- (C7) PO _1-2 ; 3,4-hexanediol (C6) EO _1-5 ; 3,4-hexanediol (C6) n-BO ₁ ; 3,4-hexanediol (C6) BO ₁ ; 5. 1,3-heptanediol (C7) _El-7 ; 1,3-heptanediol (C7) PO ₁ ; 1,3-heptanediol (C7) n-BO _1-2 ; 1,4-heptanediol (C7) _El-7 ; 1,4-heptanediol (C7) PO ₁ ; 1,4-heptanediol (C7) n-BO _1-2 ; 1,5-heptanediol (C7) _El-7 ; 1,5-heptanediol (C7) PO ₁ ; 1,5-heptanediol (C7) n-BO _1-2 ; 1,6-heptanediol (C7) _El-7 ; 1,6-heptanediol (C7) PO ₁ ; 1,6-heptanediol (C7) n-BO _1-2 ; 1,7-heptanediol (C7) El _-1 ; 1,7-heptanediol (C7) n-BO ₁ ; 2,4-heptanediol (C7) E _3-10 ; 2,4-heptanediol (C7) (Me-E ₁ ); 2,4-heptanediol (C7) PO ₁ ; 2,4-heptanediol (C7) n-BO ₃ ; 2,5-heptanediol (C7) E _3-10 ; 2,5-heptanediol (C7) (Me-E _l ); 2,5-heptanediol (C7) PO ₁ ; 2,5-heptanediol (C7) n-B0 ₃ ; 2,6-heptanediol (C7) E _3-10 ; 2,6-heptanediol (C7) (Me-E _l ); 2,6-heptanediol (C7) PO ₁ ; 2,6-heptanediol (C7) n-BO ₃ ; 3,5-heptanediol (C7) E _3-10 ; 3,5-heptanediol (C7) (Me-E _l ); 3,5-heptanediol (C7) PO ₁ ; 3,5-heptanediol (C7) n-BO ₃ ; 6. 1,3-butanediol, 3-methyl-2-isopropyl- (C8) PO ₁ ; 2,4-pentanediol, 2,3,3-trimethyl- (C8) PO ₁ ; 1,3-butanediol, 2,2-diethyl- (C8) E _2-5 ; 2,4-hexanediol, 2,3-dimethyl- (C8) E _2-5 ; 2,4-hexanediol, 2,4-dimethyl- (C8) E _2-5 ; 2,4-hexanediol, 2,5-dimethyl- (C8) E _2-5 ; 2,4-hexanediol, 3,3-dimethyl- (C8) E _2-5 ; 2,4-hexanediol, 3,4-dimethyl- (C8) E _2-5 ; 2,4-hexanediol, 3,5-dimethyl- (C8) E _2-5 ; 2,4-hexanediol, 4,5-dimethyl- (C8) E _2-5 ; 2,4-hexanediol, 5,5-dimethyl- (C8) E _2-5 ; 2,5-hexanediol, 2,3-dimethyl- (C8) E _2-5 ; 2,5-hexanediol, 2,4-dimethyl- (C8) E _2-5 ; 2,5-hexanediol, 2,5-dimethyl- (C8) E _2-5 ; 2,5-hexanediol, 3,3-dimethyl- (C8) E _2-5 ; 2,5-hexanediol, 3,4-dimethyl- (C8) E _2-5 ; 3,5-heptanediol, 3-methyl- (C8) E _2-5 ; 1,3-butanediol, 2,2-diethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 2,3-dimethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 2,4-dimethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 2,5-dimethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 3,3-dimethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 3,4-dimethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 3,5-dimethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 4,5-dimethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 5,5-dimethyl-, n-BO _1-2 ; 2,5-hexanediol, 2,3-dimethyl (C8) n-BO _1-2 ; 2,5-hexanediol, 2,4-dimethyl- (C8) n-BO _1-2 ; 2,5-hexanediol, 2,5-dimethyl- (C8) n-BO _1-2 ; 2,5-hexanediol, 3,3-dimethyl- (C8) n-BO _1-2 ; 2,5-hexanediol, 3,4-dimethyl- (C8) n-BO _1-2 ; 3,5-heptanediol, 3-methyl- (C8) n-BO _1-2 ; 1,3-propanediol, 2- (1,2-dimethylpropyl)-(C8) n-BO ₁ ; 1,3-butanediol, 2-ethyl-2,3-dimethyl- (C8) n-BO ₁ ; 1,3-butanediol, 2-methyl-2-isopropyl- (C8) n-BO ₁ ; 1,4-butanediol, 3-methyl-2-isopropyl- (C8) n-BO ₁ ; 1,3-pentanediol, 2,2,3-trimethyl (C8) n-BO ₁ ; 1,3-pentanediol, 2,2,4-trimethyl- (C8) n-BO ₁ ; 1,3-pentanediol, 2,4,4-trimethyl- (C8) n-BO ₁ ; 1,3-pentanediol, 3,4,4-trimethyl- (C8) n-BO ₁ ; 1,4-pentanediol, 2,2,3-trimethyl- (C8) n-BO ₁ ; 1,4-pentanediol, 2,2,4-trimethyl- (C8) n-BO ₁ ; 1,4-pentanediol, 2,3,3-trimethyl- (C8) n-BO ₁ ; 1,4-pentanediol, 2,3,4-trimethyl- (C8) n-BO ₁ ; 1,4-pentanediol, 3,3,4-trimethyl- (C8) n-BO ₁ ; 2,4-pentanediol, 2,3,4-trimethyl- (C8) n-BO ₁ ; 2,4-hexanediol, 4-ethyl- (C8) n-BO ₁ ; 2,4-heptanediol, 2-methyl- (C8) n-BO ₁ ; 2,4-heptanediol, 3-methyl- (C8) n-BO ₁ ; 2,4-heptanediol, 4-methyl- (C8) n-BO ₁ ; 2,4-heptanediol, 5-methyl- (C8) n-BO ₁ ; 2,4-heptanediol, 6-methyl- (C8) n-BO ₁ ; 2,5-heptanediol, 2-methyl- (C8) n-BO ₁ ; 2,5-heptanediol, 3-methyl- (C8) n-BO ₁ ; 2,5-heptanediol, 4-methyl- (C8) n-BO ₁ ; 2,5-heptanediol, 5-methyl- (C8) n-BO ₁ ; 2,5-heptanediol, 6-methyl- (C8) n-BO ₁ ; 2,6-heptanediol, 2-methyl- (C8) n-BO ₁ ; 2,6-heptanediol, 3-methyl- (C8) n-BO ₁ ; 2,6-heptanediol, 4-methyl- (C8) n-BO ₁ ; 3,5-heptanediol, 2-methyl- (C8) n-BO ₁ ; 1,3-propanediol, 2- (1,2-dimethylpropyl)-(C8) _El-3 ; 1,3-butanediol, 2-ethyl-2,3-dimethyl- (C8) _El-1 ; 1,3-butanediol, 2-methyl-2-isopropyl- (C8) _El-3 ; 1,4-butanediol, 3-methyl-2-isopropyl- (C8) _El-1 ; 1,3-pentanediol, 2,2,3-trimethyl- (C8) El _-1 ; 1,3-pentanediol, 2,2,4-trimethyl- (C8) _El-1 ; 1,3-pentanediol, 2,4,4-trimethyl- (C8) El _-1 ; 1,3-pentanediol, 3,4,4-trimethyl- (C8) El _-1 ; 1,4-pentanediol, 2,2,3-trimethyl- (C8) El _-1 ; 1,4-pentanediol, 2,2,4-trimethyl- (C8) _El-1 ; 1,4-pentanediol, 2,3,3-trimethyl- (C8) El _-1 ; 1,4-pentanediol, 2,3,4-trimethyl- (C8) _El-1 ; 1,4-pentanediol, 3,3,4-trimethyl (C8) E _1-3 ; 2,4-pentanediol, 2,3,4-trimethyl- (C8) E _1-3 ; 2,4-hexanediol, 4-ethyl- (C8) _El-1 ; 2,4-heptanediol, 2-methyl- (C8) _El-1 ; 2,4-heptanediol, 3-methyl- (C8) _El-1 ; 2,4-heptanediol, 4-methyl- (C8) _El-1 ; 2,4-heptanediol, 5-methyl- (C8) _El-1 ; 2,4-heptanediol, 6-methyl- (C8) _El-1 ; 2,5-heptanediol, 2-methyl- (C8) _El-1 ; 2,5-heptanediol, 3-methyl- (C8) _El-1 ; 2,5-heptanediol, 4-methyl- (C8) _El-1 ; 2,5-heptanediol, 5-methyl- (C8) _El-1 ; 2,5-heptanediol, 6-methyl- (C8) _El-1 ; 2,6-heptanediol, 2-methyl- (C8) _El-3 ; 2,6-heptanediol, 3-methyl- (C8) _El-1 ; 2,6-heptanediol, 4-methyl- (C8) _El-1 ; Or 3,5-heptanediol, 2-methyl- (C8) _El-1 ; And 7. mixtures thereof; Iii. Aromatic diols comprising: 1-phenyl-1,2-ethanediol; 1-phenyl-1,2-propanediol; 2-phenyl-1,2-propanediol; 3-phenyl-1,2-propanediol; 1- (3-methylphenyl) -1,3-propanediol; 1- (4-methylphenyl) -1,3-propanediol; 2-methyl-1-phenyl-1,3-propanediol; 1-phenyl-1,3-butanediol; 3-phenyl-1,3-butanediol; 1-phenyl-1,4-butanediol; 2-phenyl-1,4-butanediol; Or 1-phenyl-2,3-butanediol; And Iii. Mixtures thereof. The composition of claim 1, wherein said main solvent is selected from the group consisting of: 1,3-propanediol, 2,2-di-2-propenyl-; 1,3-propanediol, 2- (1-pentenyl)-; 1,3-propanediol, 2- (2-methyl-2-propenyl) -2- (2-propenyl)-; 1,3-propanediol, 2- (3-methyl-1-butenyl)-; 1,3-propanediol, 2- (4-pentenyl)-; 1,3-propanediol, 2-ethyl-2- (2-methyl2-propenyl)-; 1,3-propanediol, 2-ethyl-2- (2-propenyl)-; 1,3-propanediol, 2-methyl-2- (3-methyl-3-butenyl)-; 1,3-butanediol, 2,2-diallyl-; 1,3-butanediol, 2- (1-ethyl-1-propenyl)-; 1,3-butanediol, 2- (2-butenyl) -2-methyl-; 1,3-butanediol, 2- (3-methyl-2-butenyl)-; 1,3-butanediol, 2-ethyl-2- (2-propenyl)-; 1,3-butanediol, 2-methyl-2- (1-methyl-2-propenyl)-; 1,4-butanediol, 2,3-bis (1-methylethylidene)-; 1,4-butanediol, 2- (3-methyl-2-butenyl) -3-methylene-; 2-butene-1,4-diol, 2- (1,1-dimethylpropyl)-; 2-butene-1,4-diol, 2- (1-methylpropyl)-; 2-butene-1,4-diol, 2-butyl-; 1,3-pentanediol, 2-ethenyl-3-ethyl-; 1,3-pentanediol, 2-ethenyl-4,4-dimethyl-; 1,4-pentanediol, 3-methyl-2- (2-propenyl)-; 1,5-pentanediol, 2- (1-propenyl)-; 1,5-pentanediol, 2- (2-propenyl)-; 1,5-pentanediol, 2-ethylidene-3-methyl-; 1,5-pentanediol, 2-propylidene-; 2,4-pentanediol, 3-ethylidene-2,4-dimethyl-; 4-pentene-1,3-diol, 2- (1,1-dimethylethyl)-; 4-pentene-1,3-diol, 2-ethyl-2,3-dimethyl-; 1,4-hexanediol, 4-ethyl-2-methylene-; 1,5-hexadiene-3,4-diol, 2,3,5-trimethyl-; 1,5-hexadiene-3,4-diol, 5-ethyl-3-methyl-; 1,5-hexanediol, 2- (1-methylethenyl)-; 1,6-hexanediol, 2-ethenyl-; 1-hexene-3,4-diol, 5,5-dimethyl-; 1-hexene-3,4-diol, 5,5-dimethyl-; 2-hexene-1,5-diol, 4-ethenyl-2,5-dimethyl-; 3-hexene-1,6-diol, 2-ethenyl-2,5-dimethyl-; 3-hexene-1,6-diol, 2-ethyl-; 3-hexene-1,6-diol, 3,4-dimethyl-; 4-hexene-2,3-diol, 2,5-dimethyl-; 4-hexene-2,3-diol, 3,4-dimethyl-; 5-hexene-1,3-diol, 3- (2-propenyl)-; 5-hexene-2,3-diol, 2,3-dimethyl-; 5-hexene-2,3-diol, 3,4-dimethyl-; 5-hexene-2,3-diol, 3,5-dimethyl-; 5-hexene-2,4-diol, 3-ethenyl-2,5-dimethyl-; 1,4-heptanediol, 6-methyl-5-methylene-; 1,5-heptadiene-3,4-diol, 2,3-dimethyl-; 1,5-heptadiene-3,4-diol, 2,5-dimethyl-; 1,5-heptadiene-3,4-diol, 3,5-dimethyl-; 1,7-heptanediol, 2,6-bis (methylene)-; 1,7-heptanediol, 4-methylene-; 1-heptene-3,5-diol, 2,4-dimethyl-; 1-heptene-3,5-diol, 2,6-dimethyl-; 1-heptene-3,5-diol, 3-ethenyl-5-methyl; 1-heptene-3,5-diol, 6,6-dimethyl-; 2,4-heptadiene-2,6-diol, 4,6-dimethyl-; 2,5-heptadiene-1,7-diol, 4,4-dimethyl-; 2,6-heptadiene-1,4-diol, 2,5,5-trimethyl-; 2-heptene-1,4-diol, 5,6-dimethyl-; 2-heptene-1,5-diol, 5-ethyl-; 2-heptene-1,7-diol, 2-methyl-; 3-heptene-1,5-diol, 4,6-dimethyl-; 3-hepten-1,7-diol, 3-methyl-6-methylene-; 3-heptene-2,5-diol, 2,4-dimethyl-; 3-heptene-2,5-diol, 2,5-dimethyl-; 3-heptene-2,6-diol, 2,6-dimethyl-; 3-heptene-2,6-diol, 4,6-dimethyl-; 5-heptene-1,3-diol, 2,4-dimethyl-; 5--heptene-1,3-diol, 3,6-dimethyl-; 5-heptene-1,4-diol, 2,6-dimethyl-; 5-heptene-1,4-diol, 3,6-dimethyl-; 5-heptene-2,4-diol, 2,3-dimethyl-; 6-heptene-1,3-diol, 2,2-dimethyl-; 6-heptene-1,4-diol, 4- (2-propenyl)-; 6-heptene-1,4-diol, 5,6-dimethyl-; 6-heptene-1,5-diol, 2,4-dimethyl-; 6-heptene-1,5-diol, 2-ethylidene-6-methyl-; 6-heptene-2,4-diol, 4- (2-propenyl)-; 6-heptene-2,4-diol, 5,5-dimethyl-; 6-heptene-2,5-diol, 4,6-dimethyl-; 6-heptene-2,5-diol, 5-ethenyl-4-methyl-; 1,3-octanediol, 2-methylene-; 1,6-octadiene-3,5-diol, 2,6-dimethyl-; 1,6-octadiene-3,5-diol, 3,7-dimethyl-; 1,7-octadiene-3,6-diol, 2,6-dimethyl-; 1,7-octadiene-3,6-diol, 2,7-dimethyl-; 1,7-octadiene-3,6-diol, 3,6-dimethyl-; 1-octene-3,6-diol, 3-ethenyl-; 2,4,6-octatriene-1,8-diol, 2,7-dimethyl-; 2,4-octadiene-1,7-diol, 3,7-dimethyl-; 2,5-octadiene-1,7-diol, 2,6-dimethyl-; 2,5-octadiene-1,7-diol, 3,7-dimethyl-; 2,6-octadiene-1,4-diol, 3,7-dimethyl- (rosiridol); 2,6-octadiene-1,8-diol, 2-methyl-; 2,7-octadiene-1,4-diol, 3,7-dimethyl-; 2,7-octadiene-1,5-diol, 2,6-dimethyl-; 2,7-octadiene-1,6-diol, 2,6-dimethyl- (8-hydroxylinalolol); 2,7-octadiene-1,6-diol, 2,7-dimethyl-; 2-octene-1,4-diol; 2-octene-1,7-diol; 2-octene-1,7-diol, 2-methyl-6-methylene-; 3,5-octadiene-1,7-diol, 3,7-dimethyl-; 3,5-octadiene-2,7-diol, 2,7-dimethyl-; 3,5-octanediol, 4-methylene-; 3,7-octadiene-1,6-diol, 2,6-dimethyl-; 3,7-octadiene-2,5-diol, 2,7-dimethyl-; 3,7-octadiene-2,6-diol, 2,6-dimethyl-; 3-octene-1,5-diol, 4-methyl-; 3-octene-1,5-diol, 5-methyl-; 4,6-octadiene-1,3-diol, 2,2-dimethyl-; 4,7-octadiene-2,3-diol, 2,6-dimethyl-; 4,7-octadiene-2,6-diol, 2,6-dimethyl-; 4-octene-1,6-diol, 7-methyl-; 2,7-bis (methylene)-; 2-methylene-; 5,7-octadiene-1,4-diol, 2,7-dimethyl-; 5,7-octadiene-1,4-diol, 7-methyl-; 5-octene-1,3-diol; 6-octene-1,3-diol, 7-methyl-; 6-octene-1,4-diol, 7-methyl-; 6-octene-1,5-diol; 6-octene-1,5-diol 7-methyl-; 6-octene-3,5-diol, 2-methyl-; 6-octene-3,5-diol, 4-methyl-; 7-octene-1,3-diol, 2-methyl-; 7-octene-1,3-diol, 4-methyl-; 7-octene-1,3-diol, 7-methyl-; 7-octene-1,5-diol; 7-octene-1,6-diol; 7-octene-1,6-diol, 5-methyl-; 7-octene-2,4-diol, 2-methyl-6-methylene-; 7-octene-2,5-diol, 7-methyl-; 7-octene-3,5-diol, 2-methyl-; 1-nonene-3,5-diol; 1-nonene-3,7-diol; 3-nonene-2,5-diol; 4,6-nonadiene-1,3-diol, 8-methyl-; 4-nonene-2,8-diol; 6,8-nonadiene-1,5-diol; 7-nonene-2,4-diol; 8-nonene-2,4-diol; 8-nonene-2,5-diol; 1,9-decadiene-3,8-diol; 1,9-decadiene-4,6-diol; And mixtures thereof. The composition of claim 1, wherein said main solvent is selected from the group consisting of: 1,3-butanediol, 2,2-diallyl-; 1,3-butanediol, 2- (1-ethyl-1-propenyl)-; 1,3-butanediol, 2- (2-butenyl) -2-methyl-; 1,3-butanediol, 2- (3-methyl-2-butenyl)-; 1,3-butanediol, 2-ethyl-2- (2-propenyl)-; 1,3-butanediol, 2-methyl-2- (1-methyl-2-propenyl)-; 1,4-butanediol, 2,3-bis (1-methylethylidene)-; 1,3-pentanediol, 2-ethenyl-3-ethyl-; 1,3-pentanediol, 2-ethenyl-4,4-dimethyl-; 1,4-pentanediol, 3-methyl-2- (2-propenyl)-; 4-pentene-1,3-diol, 2- (1,1-dimethylethyl)-; 4-pentene-1,3-diol, 2-ethyl-2,3-dimethyl-; 1,4-hexanediol, 4-ethyl-2-methylene-; 1,5-hexadiene-3,4-diol, 2,3,5-trimethyl-; 1,5-hexanediol, 2- (1-methylethenyl)-; 2-hexene-1,5-diol, 4-ethenyl-2,5-dimethyl-; 1,4-heptanediol, 6-methyl-5-methylene-; 2,4-heptadiene-2,6-diol, 4,6-dimethyl-; 2,6-heptadiene-1,4-diol, 2,5,5-trimethyl-; 2-heptene-1,4-diol, 5,6-dimethyl-; 3-heptene-1,5-diol, 4,6-dimethyl-; 5-heptene-1,3-diol, 2,4-dimethyl-; 5-heptene-1,3-diol, 3,6-dimethyl-; 5-heptene-1,4-diol, 2,6-dimethyl-; 5-heptene-1,4-diol, 3,6-dimethyl-; 6-heptene-1,3-diol, 2,2-dimethyl-; 6-heptene-1,4-diol, 5,6-dimethyl-; 6-heptene-1,5-diol, 2,4-dimethyl-; 6-heptene-1,5-diol, 2-ethylidene-6-methyl-; 6-heptene-2,4-diol, 4- (2-propenyl)-; 1-octene-3,6-diol, 3-ethenyl-; 2,4,6-octatriene-l, 8-diol, 2,7-dimethyl-; 2,5-octadiene-1,7-diol, 2,6-dimethyl-; 2,5-octadiene-1,7-diol, 3,7-dimethyl-; 2,6-octadiene-1,4-diol, 3,7-dimethyl- (rosiridol); 2,6-octadiene-1,8-diol, 2-methyl-; 2,7-octadiene-1,4-diol, 3,7-dimethyl-; 2,7-octadiene-1,5-diol, 2,6-dimethyl-; 2,7-octadiene-1,6-diol, 2,6-dimethyl- (8-hydroxylinalolol); 2,7-octadiene-1,6-diol, 2,7-dimethyl-; 2-octene-1,7-diol, 2-methyl-6-methylene-; 3,5-octadiene-2,7-diol, 2,7-dimethyl-; 3,5-octanediol, 4-methylene-; 3,7-octadiene-1,6-diol, 2,6-dimethyl-; 4-octene-l, 8-diol, 2-methylene-; 6-octene-3,5-diol, 2-methyl-; 6-octene-3,5-diol, 4-methyl-; 7-octene-2,4-diol, 2-methyl-6-methylene-; 7-octene-2,5-diol, 7-methyl-; 7-octene-3,5-diol, 2-methyl-; 1-nonene-3,5-diol; 1-nonene-3,7-diol; 3-nonene-2,5-diol; 4-nonene-2,8-diol; 6,8-nonadiene-1,5-diol; 7-nonene-2,4-diol; 8-nonene-2,4-diol; 8-nonene-2,5-diol; 1,9-decadiene-3,8-diol; 1,9-decadiene-4,6-diol; And mixtures thereof. The monoester compound according to any one of claims 1 to 5, wherein the softener active agent is m is 2, and one YR ¹ is -OH, -N (R) H, or -C (O) OH. A composition containing no more than%. 6. The method of any one of claims 1 to 5, wherein the weight ratio of softener activator to main solvent in a small amount of 5% to 15% of water is 55:45 to 85:15; In an amount of water of 15% to 70%, the weight ratio of the softener active agent to the main solvent is 45:55 to 70:30; A composition wherein the weight ratio of softener active agent to main solvent in a large amount of water of 70% to 80% is 30:70 to 55:45. 34. The method of claim 33 wherein the weight ratio of softener active agent to main solvent in a small amount of 5% to 15% of water is 60:40 to 80:20; In an amount of water from 15% to 70%, the weight ratio of softener activator to main solvent is 55:45 to 70:30; A composition wherein the weight ratio of softener activator to main solvent in a large amount of water of 70% to 80% is 35:65 to 45:55. The method according to claim 1, which is translucent or transparent at 25 ° C, contains a solvent other than the main solvent B, the amount of the main solvent B is at least 5% by weight of the composition, and in the absence of the main solvent B, the translucent at 25 ° C or Composition that is not transparent. The composition of any one of claims 1 to 5, which contains one or more of the following optional ingredients: (a) 0.005% to 5% sharpening agent; (b) 2% to 25% of a dispersal aid; (c) 0% to 10% fouling release agent; (d) 2% to 10% of leftover dispersant; (e) 0% to 2% stabilizer selected from antioxidants, reducing agents, chelating agents and mixtures thereof; (f) 0.005% to 5% fungicides; And (g) 0.5% to 10% chelating agent in addition to any chelating agent of (e). The biodegradable fabric softener activator A; The preliminary mixture of the component of any one of Claims 1-5 which essentially contains the said main solvent B, and can contain the said water-soluble solvent C. A product containing the composition of claim 1 in a transparent bottle. 39. The product of claim 38, wherein the bottle is light blue enough to offset the pale yellow of the composition. 40. The article of claim 39, wherein the bottle has a UV absorber bound to the bottle wall to protect the composition. A composition comprising the following A, B, E and which may contain C and D: A. 2% to 80% biodegradable fabric softener active agent selected from the group consisting of: 1. Softeners having the formula: [Formula 1] Wherein each R substituent is H, or a short chain C ₁ -C ₆ alkyl or hydroxyalkyl group, benzyl or mixtures thereof; Each m is 2 or 3; Each n is 1-4; Each Y is -O- (O) C-,-(R) N- (O) C-, -C (O) -N (R)-or -C (O) -C-, where Y is -0 When-(O) C- or-(R) N- (O) C-, the carbon sum of each R ¹ or YR ¹ is C ₆ -C ₂₂ , and if one R ¹ or YR ¹ sum is 12 or less , The sum of other R ¹ or YR ¹ is 16 or more, and each R ¹ is a long chain hydrocarbyl or substituted hydrocarbyl substituent, and R ¹ or YR ¹ containing a C ₁₅ -C ₂₁ straight chain alkyl or alkylene group. In contrast, the iodine number of the fatty acid containing the R ¹ group is 20 to 140, wherein the counterion X ⁻ may be any softener compatible anion; 2. Softeners having the formula: [Formula 2] Wherein each Y, R, R ¹ and X ^(-) has the same meaning as above; And 3. mixtures thereof; B. Up to 40% by weight of the main solvent alcohol selected from the group consisting of: I. Monools comprising at least one of: a. n-propanol; b. 2-butanol, 2-methyl-2-propanol or both; II. Hexane diol isomers comprising: 2,3-butanediol, 2,3-dimethyl-; 1,2-butanediol, 2,3-dimethyl-; 1,2-butanediol, 3,3-dimethyl-; 2,3-pentanediol, 2-methyl-; 2,3-pentanediol, 3-methyl-; 2,3-pentanediol, 4-methyl-; 2,3-hexanediol; 3,4-hexanediol; 1,2-butanediol, 2-ethyl-; 1,2-pentanediol, 2-methyl-; 1,2-pentanediol, 3-methyl-; 1,2-pentanediol, 4-methyl-; Or 1,2-hexanediol; III. Heptane diol isomers comprising: 1,3-propanediol, 2-butyl-; 1,3-propanediol, 2,2-diethyl-; 1,3-propanediol, 2- (l-methylpropyl)-; 1,3-propanediol, 2- (2-methylpropyl)-; 1,3-propanediol, 2-methyl-2-propyl-; 1,2-butanediol, 2,3,3-trimethyl-; 1,4-butanediol, 2-ethyl-2-methyl-; 1,4-butanediol, 2-ethyl-3-methyl-; 1,4-butanediol, 2-propyl-; 1,4-butanediol, 2-isopropyl-; 1,5-pentanediol, 2,2-dimethyl-; 1,5-pentanediol, 2,3-dimethyl-; 1,5-pentanediol, 2,4-dimethyl-; 1,5-pentanediol, 3,3-dimethyl-; 2,3-pentanediol, 2,3-dimethyl-; 2,3-pentanediol, 2,4-dimethyl-; 2,3-pentanediol, 3,4-dimethyl-; 2,3-pentanediol, 4,4-dimethyl-; 3,4-pentanediol, 2,3-dimethyl-; 1,5-pentanediol, 2-ethyl-; 1,6-hexanediol, 2-methyl-; 1,6-hexanediol, 3-methyl-; 2,3-hexanediol, 2-methyl-, 2,3-hexanediol, 3-methyl-; 2,3-hexanediol, 4-methyl-; 2,3-hexanediol, 5-methyl-; 3,4-hexanediol, 2-methyl-; 3,4-hexanediol, 3-methyl-; 1,3-heptanediol; 1,4-heptanediol; 1,5-heptanediol; Or 1,6-heptanediol; Ⅳ. Octane diol isomers comprising: 1,3-propanediol, 2- (2-methylbutyl)-; 1,3-propanediol, 2- (1,1-dimethylpropyl)-; 1,3-propanediol, 2- (1,2-dimethylpropyl)-; 1,3-propanediol, 2- (l-ethylpropyl)-; 1,3-propanediol, 2- (l-methylbutyl)-; 1,3-propanediol, 2- (2,2-dimethylpropyl)-; 1,3-propanediol, 2- (3-methylbutyl)-; 1,3-propanediol, 2-butyl-2-methyl-; 1,3-propanediol, 2-ethyl-2-isopropyl-; 1,3-propanediol, 2-ethyl-2-propyl-; 1,3-propanediol, 2-methyl-2- (1-methylpropyl)-; 1,3-propanediol, 2-methyl-2- (2-methylpropyl)-; 1,3-propanediol, 2-t-butyl-2-methyl-; 1,3-butanediol, 2,2-diethyl-; 1,3-butanediol, 2- (1-methylpropyl)-; 1,3-butanediol, 2-butyl-; 1,3-butanediol, 2-ethyl-2,3-dimethyl-; 1,3-butanediol, 2- (1,1-dimethylethyl)-; 1,3-butanediol, 2- (2-methylpropyl)-; 1,3-butanediol, 2-methyl-2-isopropyl-; 1,3-butanediol, 2-methyl-2-propyl-; 1,3-butanediol, 3-methyl-2-isopropyl; 1,3-butanediol, 3-methyl-2-propyl-; 1,4-butanediol, 2,2-diethyl-; 1,4-butanediol, 2-methyl-2-propyl-; 1,4-butanediol, 2- (1-methylpropyl)-; 1,4-butanediol, 2-ethyl-2,3-dimethyl-; 1,4-butanediol, 2-ethyl-3,3-dimethyl-; 1,4-butanediol, 2- (1,1-dimethylethyl)-; 1,4-butanediol, 2- (2-methylpropyl)-; 1,4-butanediol, 2-methyl-3-propyl-; 1,4-butanediol, 3-methyl-2-isopropyl-; 1,3-pentanediol, 2,2,3-trimethyl-; 1,3-pentanediol, 2,2,4-trimethyl-; 1,3-pentanediol, 2,3,4-trimethyl-; 1,3-pentanediol, 2,4,4-trimethyl-; 1,3-pentanediol, 3,4,4-trimethyl-; 1,4-pentanediol, 2,2,3-trimethyl-, 1,4-pentanediol, 2,2,4-trimethyl-; 1,4-pentanediol, 2,3,3-trimethyl-; 1,4-pentanediol, 2,3,4-trimethyl-; 1,4-pentanediol, 3,3,4-trimethyl-; 1,5-pentanediol, 2,2,3-trimethyl-; 1,5-pentanediol, 2,2,4-trimethyl-; 1,5-pentanediol, 2,3,3-trimethyl-; 1,5-pentanediol, 2,3,4-trimethyl-; 2,4-pentanediol, 2,3,3-trimethyl-; 2,4-pentanediol, 2,3,4-trimethyl-; 1,3-pentanediol, 2-ethyl-2-methyl-; 1,3-pentanediol, 2-ethyl-3-methyl-; 1,3-pentanediol, 2-ethyl-4-methyl-; 1,3-pentanediol, 3-ethyl-2-methyl-; 1,4-pentanediol, 2-ethyl-2-methyl-; 1,4-pentanediol, 2-ethyl-3-methyl-; 1,4-pentanediol, 2-ethyl-4methyl-; 1,4-pentanediol, 3-ethyl-2-methyl-; 1,4-pentanediol, 3-ethyl-3-methyl-; 1,5-pentanediol, 2-ethyl-2-methyl-; 1,5-pentanediol, 2-ethyl-3-methyl-; 1,5-pentanediol, 2-ethyl-4-methyl-; 1,5-pentanediol, 3-ethyl-3-methyl-; 2,4-pentanediol, 3-ethyl-2methyl-; 1,3-pentanediol, 2-isopropyl-; 1,3-pentanediol, 2-propyl-; 1,4-pentanediol, 2-isopropyl-; 1,4-pentanediol, 2-propyl-; 1,4-pentanediol, 3-isopropyl-; 1,5-pentanediol, 2-isopropyl-; 2,4-pentanediol, 3-propyl-; 1,3-hexanediol, 2,2-dimethyl-; 1,3-hexanediol, 2,3-dimethyl-; 1,3-hexanediol, 2,4-dimethyl-; 1,3-hexanediol, 2,5-dimethyl-; 1,3-hexanediol, 3,4-dimethyl-; 1,3-hexanediol, 3,5-dimethyl-; 1,3-hexanediol, 4,5-dimethyl-; 1,4-hexanediol, 2,2-dimethyl-; 1,4-hexanediol, 2,3-dimethyl-; 1,4-hexanediol, 2,4-dimethyl-; 1,4-hexanediol, 2,5-dimethyl-; 1,4-hexanediol, 3,3-dimethyl-; 1,4-hexanediol, 3,4-dimethyl-; 1,4-hexanediol, 3,5-dimethyl-; 1,3-hexanediol, 4,4-dimethyl-; 1,4-hexanediol, 4,5-dimethyl-; 1,4-hexanediol, 5,5-dimethyl-; 1,5-hexanediol, 2,2-dimethyl-; 1,5-hexanediol, 2,3-dimethyl-; 1,5-hexanediol, 2,4-dimethyl-; 1,5-hexanediol, 2,5-dimethyl-; 1,5-hexanediol, 3,3-dimethyl-; 1,5-hexanediol, 3,4-dimethyl-; 1,5-hexanediol, 3,5-dimethyl-; 1,5-hexanediol, 4,5-dimethyl-; 1,6-hexanediol, 2,2-dimethyl-; 1,6-hexanediol, 2,3-dimethyl-; 1,6-hexanediol, 2,4-dimethyl-; 1,6-hexanediol, 2,5-dimethyl-; 1,6-hexanediol, 3,3-dimethyl-; 1,6-hexanediol, 3,4-dimethyl-; 2,4-hexanediol, 2,3-dimethyl-; 2,4-hexanediol, 2,4-dimethyl-; 2,4-hexanediol, 2,5-dimethyl-; 2,4-hexanediol, 3,3-dimethyl-; 2,4-hexanediol, 3,4-dimethyl-; 2,4-hexanediol, 3,5-dimethyl-; 2,4-hexanediol, 4,5-dimethyl-; 2,4-hexanediol, 5,5-dimethyl-; 2,5-hexanediol, 2,3-dimethyl-; 2,5-hexanediol, 2,4-dimethyl-; 2,5-hexanediol, 2,5-dimethyl-; 2,5-hexanediol, 3,3-dimethyl-; 2,5-hexanediol, 3,4-dimethyl-; 2,6-hexanediol, 3,3-dimethyl-; 1,3-hexanediol, 2-ethyl-; 1,3-hexanediol, 4-ethyl-; 1,4-hexanediol, 2-ethyl-; 1,4-hexanediol, 4-ethyl-; 1,5-hexanediol, 2-ethyl-; 2,4-hexanediol, 3-ethyl-; 2,4-hexanediol, 4-ethyl-; 2,5-hexanediol, 3-ethyl-; 1,3-heptanediol, 2-methyl-; 1,3-heptanediol, 3-methyl-; 1,3-heptanediol, 4-methyl-; 1,3-heptanediol, 5-methyl-; 1,3-heptanediol, 6-methyl-; 1,4-heptanediol, 2-methyl-; 1,4- heptanediol, 3-methyl-; 1,4-heptanediol, 4-methyl-; 1,4-heptanediol, 5-methyl-; 1,4-heptanediol, 6-methyl-; 1,5-heptanediol, 2-methyl; 1,5-heptanediol, 3-methyl-; 1,5-heptanediol, 4-methyl-; 1,5-heptanediol, 5-methyl-; 1,5-heptanediol, 6-methyl-; 1,6-heptanediol, 2-methyl-; 1,6-heptanediol, 3-methyl-; 1,6-heptanediol, 4-methyl-; 1,6-heptanediol, 5-methyl-; 1,6-heptanediol, 6-methyl-; 2,4-heptanediol, 2-methyl-; 2,4-heptanediol, 3-methyl-; 2,4-heptanediol, 4-methyl-; 2,4-heptanediol, 5-methyl-; 2,4-heptanediol, 6-methyl-; 2,5-heptanediol, 2-methyl-; 2,5-heptanediol, 3-methyl-; 2,5-heptanediol, 4-methyl-; 2,5-heptanediol, 5-methyl-; 2,5-heptanediol, 6-methyl-; 2,6-heptanediol, 2-methyl-; 2,6-heptanediol, 3-methyl-; 2,6-heptanediol, 4-methyl-; 3,4-heptanediol, 3-methyl-; 3,5-heptanediol, 2-methyl-; 3,5-heptanediol, 3-methyl-; 3,5-heptanediol, 4-methyl-; 2,4-octanediol; 2,5-octanediol; 2,6-octanediol; 2,7-octanediol; 3,5-octanediol; Or 3,6-octanediol; Ⅴ. Nonane diol isomers comprising: 2,4-pentanediol, 2,3,3,4-tetramethyl-; 2,4-pentanediol, 3-t-butyl-; 2,4-hexanediol, 2,5,5-trimethyl-; 2,4-hexanediol, 3,3,4-trimethyl-; 2,4-hexanediol, 3,3,5-trimethyl-; 2,4-hexanediol, 3,5,5-trimethyl-; 2,4-hexanediol, 4,5,5-trimethyl-; 2,5-hexanediol, 3,3,4-trimethyl-; Or 2,5-hexanediol, 3,3,5-trimethyl-; Ⅵ. Glyceryl ethers, di (hydroxyalkyl) ethers or both comprising: 1,2-propanediol, 3- (n-pentyloxy)-; 1,2-propanediol, 3- (2-pentyloxy)-; 1,2-propanediol, 3- (3-pentyloxy)-; 1,2-propanediol, 3- (2-methyl-1 -butyloxy)-; 1.2-propanediol, 3- (iso-amyloxy)-; 1,2-propanediol, 3- (3-methyl-2-butyloxy)-; 1,2-propanediol, 3- (cyclohexyloxy)-; 1,2-propanediol, 3- (1-cyclohex-1-enyloxy)-; 1,3-propanediol, 2- (pentyloxy)-; 1,3-propanediol, 2- (2-pentyloxy)-; 1,3-propanediol, 2- (3-pentyloxy)-; 1,3-propanediol, 2- (2-methyl-1 -butyloxy)-; 1,3-propanediol, 2- (iso-amyloxy)-; 1,3-propanediol, 2- (3-methyl-2-butyloxy)-; 1,3-propanediol, 2- (cyclohexyloxy)-; 1,3-propanediol, 2- (1-cyclohex-1-enyloxy)-; 1,2-propanediol, 3- (butyloxy)-, triethoxylated; 1,2-propanediol, 3- (butyloxy)-, tetraethoxylated; 1,2-propanediol, 3- (butyloxy)-, pentaethoxylated; 1,2-propanediol, 3- (butyloxy)-, hexaethoxylated; 1,2-propanediol, 3- (butyloxy)-, heptaethoxylation; 1,2-propanediol, 3- (butyloxy)-, octaethoxylation; 1,2-propanediol, 3- (butyloxy)-, nonaethoxylation; 1,2-propanediol, 3- (butyloxy)-, monopropoxylation; 1,2-propanediol, 3- (butyloxy)-, dibutyleneoxylation; 1,2-propanediol, 3- (butyloxy)-, tributyleneoxylation; 1,2-propanediol, 3-phenyloxy-; 1,2-propanediol, 3-benzyloxy-; 1,2-propanediol, 3- (2-phenylethyloxy)-; 1,2-propanediol, 3- (1-phenyl-2-propanyloxy)-; 1,3-propanediol, 2-phenyloxy-; 1,3-propanediol, 2- (m-cresyloxy)-; 1,3-propanediol, 2- (p-cresyloxy)-; 1,3-propanediol, -benzyloxy-; 1,3-propanediol, 2- (2-phenylethyloxy)-; 1,3-propanediol, 2- (1-phenylethyloxy)-; Bis (2-hydroxybutyl) ether; Or bis (2-hydroxycyclopentyl) ether; Iii. Saturated and unsaturated aliphatic cyclic diols and derivatives thereof comprising: (a) saturated diols and derivatives thereof comprising: 1-isopropyl-1,2-cyclobutanediol; 3-ethyl-4-methyl-1,2-cyclobutanediol; 3-propyl-1,2-cyclobutanediol; 3-isopropyl-1,2-cyclobutanediol; 1-ethyl-1,2-cyclopentanediol; 1,2-dimethyl-1,2-cyclopentanediol; 1,4-dimethyl-1,2-cyclopentanediol; 2,4,5-trimethyl-1,3-cyclopentanediol; 3,3-dimethyl-1,2-cyclopentanediol; 3,4-dimethyl-1,2-cyclopentanediol; 3,5-dimethyl-1,2-cyclopentanediol; 3-ethyl-1,2-cyclopentanediol; 4,4-dimethyl-1,2-cyclopentanediol; 4-ethyl-1,2-cyclopentanediol; 1, l-bis (hydroxymethyl) cyclohexane; 1,2-bis (hydroxymethyl) cyclohexane; 1,2-dimethyl-1,3-cyclohexanediol; 1,3-bis (hydroxymethyl) cyclohexane; 1,3-dimethyl-1,3-cyclohexanediol; 1,6-dimethyl-1,3-cyclohexanediol; 1-hydroxycyclohexaneethanol; 1-hydroxy-cyclohexanemethanol; 1-ethyl-1,3-cyclohexanediol; 1-methyl-1,2-cyclohexanediol; 2,2-dimethyl-1,3-cyclohexanediol; 2,3-dimethyl-1,4-cyclohexanediol; 2,4-dimethyl-1,3-cyclohexanediol; 2,5-dimethyl-1,3-cyclohexanediol; 2,6-dimethyl-1,4-cyclohexanediol; 2-ethyl-1,3-cyclohexanediol; 2-hydroxycyclohexaneethanol; 2-hydroxyethyl-1-cyclohexanol; 3-hydroxyethyl-1-cyclohexanol; 3-hydroxycyclohexaneethanol; 3-hydroxymethylcyclohexanol; 3-methyl-1,2-cyclohexanediol; 4,4-dimethyl-1,3-cyclohexanediol; 4,5-dimethyl-1,3-cyclohexanediol; 4,6-dimethyl-1,3-cyclohexanediol; 4-ethyl-1,3-cyclohexanediol; 4-hydroxyethyl-1-cyclohexanol; 4-methyl-1,2-cyclohexanediol; 5,5-dimethyl-1,3-cyclohexanediol; 5-ethyl-1,3-cyclohexanediol; 1,2-cycloheptanediol; 2-methyl-1,3-cycloheptanediol; 2-methyl-1,4-cycloheptanediol; 4-methyl-1,3-cycloheptanediol; 5-methyl-1,3-cycloheptanediol; 5-methyl-1,4-cycloheptanediol; 6-methyl-1,4-cycloheptanediol; 1,3-cyclooctanediol; 1,4-cyclooctanediol; 1,5-cyclooctanediol; 1,2-cyclohexanediol, diethoxylation; 1,2-cyclohexanediol, triethoxylation; 1,2-cyclohexanediol, tetraethoxylation; 1,2-cyclohexanediol, pentaethoxylation; 1,2-cyclohexanediol, hexaethoxylation; 1,2-cyclohexanediol, heptaethoxylation; 1,2-cyclohexanediol, octaethoxylation; 1,2-cyclohexanediol, nonaethoxylation; 1,2-cyclohexanediol, monopropoxylation; 1,2-cyclohexanediol, monobutyleneoxylation; 1,2-cyclohexanediol, dibutyleneoxylation; Or 1,2-cyclohexanediol, tributyleneoxylation; And (b). Unsaturated aliphatic cyclic diols comprising: 1,2-cyclobutanediol, 1-ethenyl-2-ethyl-; 3-cyclobutene-1,2-diol, 1,2,3,4-tetramethyl-; 3-cyclobutene-1,2-diol, 3,4-diethyl-; 3-cyclobutene-1,2-diol, 3- (1, l-dimethylethyl)-; 3-cyclobutene-1,2-diol, 3-butyl-; 1,2-cyclopentanediol, 1,2-dimethyl-4-methylene-; 1,2-cyclopentanediol, 1-ethyl-3-methylene-; 1,2-cyclopentanediol, 4- (1-propenyl); 3-cyclopentene-1,2-diol, 1-ethyl-3-methyl-; 1,2-cyclohexanediol, 1-ethenyl-; 1,2-cyclohexanediol, 1-methyl-3-methylene-; 1,2-cyclohexanediol, 1-methyl-4-methylene-; 1,2-cyclohexanediol, 3-ethenyl-; 1,2-cyclohexanediol, 4-ethenyl-; 3-cyclohexene-1,2-diol, 2,6-dimethyl-; 3-cyclohexene-1,2-diol, 6,6-dimethyl-; 4-cyclohexene-1,2-diol, 3,6-dimethyl-; 4-cyclohexene-1,2-diol, 4,5-dimethyl-; 3-cyclooctene-1,2-diol; 4-cyclooctene-1,2-diol; Or 5-cyclooctene-1,2-diol; Iii. C _3-8 alkoxylated derivatives comprising: 1. 1,2-propanediol (C3) 2 (Me-E _1-4 ); 1,2-propanediol (C3) P0 ₄ ; 1,2-propanediol, 2-methyl- (C4) (Me-E _4-10 ); 1,2-propanediol, 2-methyl- (C4) 2 (Me-E _l ); 1,2-propanediol, 2-methyl- (C4) PO ₃ ; 1,2-propanediol, 2-methyl- (C4) BO ₁ ; 1,3-propanediol (C3) 2 (Me-E _6-8 ); 1,3-propanediol (C3) P0 _5-6 ; 1,3-propanediol, 2,2-diethyl- (C7) _El-7 ; 1,3-propanediol, 2,2-diethyl- (C7) PO ₁ ; 1,3-propanediol, 2,2-diethyl- (C7) n-BO _1-2 ; 1,3-propanediol, 2,2-dimethyl- (C5) 2 (Me E _l-2 ); 1,3-propanediol, 2,2-dimethyl- (C5) PO _3-4 ; 1,3-propanediol, 2- (1-methylpropyl)-(C7) _El-7 ; 1,3-propanediol, 2- (1-methylpropyl)-(C7) PO ₁ ; 1,3-propanediol, 2- (1-methylpropyl)-(C7) n-BO _1-2 ; 1,3-propanediol, 2- (2-methylpropyl)-(C7) _El-7 ; 1,3-propanediol, 2- (2-methylpropyl)-(C7) PO ₁ ; 1,3-propanediol, 2- (2-methylpropyl) (C7) n-BO _1-2 ; 1,3-propanediol, 2-ethyl- (C5) (Me E _6-10 ); 1,3-propanediol, 2-ethyl (C5) 2 (Me E ₁ ); 1,3-propanediol, 2-ethyl- (C5) P0 ₃ ; 1,3-propanediol, 2-ethyl-2-methyl- (C6) (Me _El-6 ); 1,3-propanediol, 2-ethyl-2-methyl- (C6) P0 ₂ ; 1,3-propanediol, 2-ethyl-2-methyl- (C6) BO ₁ ; 1,3-propanediol, 2-isopropyl- (C6) (Me _El-6 ); 1,3-propanediol, 2-isopropyl- (C6) PO ₂ ; 1,3-propanediol, 2-isopropyl- (C6) BO ₁ ; 1,3-propanediol, 2-methyl- (C4) 2 (Me E _2-5 ); 1,3-propanediol, 2-methyl- (C4) P0 _4-5 ; 1,3-propanediol, 2-methyl- (C4) B0 ₂ ; 1,3-propanediol, 2-methyl-2isopropyl- (C7) E _2-9 ; 1,3-propanediol, 2-methyl-2-isopropyl- (C7) PO ₁ ; 1,3-propanediol, 2-methyl-2-isopropyl- (C7) n-BO _1-3 ; 1,3-propanediol, 2-methyl-2-propyl- (C7) _El-7 ; 1,3-propanediol, 2-methyl-2-propyl- (C7) PO ₁ ; 1,3-propanediol, 2-methyl-2-propyl- (C7) n-BO _1-2 ; 1,3-propanediol, 2-propyl- (C6) (Me E _1-4 ); 1,3-propanediol, 2-propyl- (C6) PO ₂ ; 1,3-propanediol, 2-propyl- (C6) BO ₁ ; 2. 1,2-butanediol (C4) (Me E _2-8 ); 1,2-butanediol (C4) P0 _2-3 ; 1,2-butanediol (C4) BO ₁ ; 1,2-butanediol, 2,3-dimethyl- (C6) _El-6 ; 1,2-butanediol, 2,3-dimethyl- (C6) n-BO _1-2 ; 1,2-butanediol, 2-ethyl- (C6) _El-3 ; 1,2-butanediol, 2-ethyl- (C6) n-BO ₁ ; 1,2-butanediol, 2-methyl- (C5) (Me E _l-2 ); 1,2-butanediol, 2-methyl- (C5) PO ₁ ; 1,2-butanediol, 3,3-dimethyl- (C6) _El-6 ; 1,2-butanediol, 3,3-dimethyl- (C6) n-BO _1-2 ; 1,2-butanediol, 3-methyl- (C5) (Me _El-1 ); 1,2-butanediol, 3-methyl- (C5) PO ₁ ; 1,3-butanediol (C4) 2 (Me E _3-6 ); 1,3-butanediol (C4) P0 ₅ ; 1,3-butanediol (C4) B0 ₂ ; 1,3-butanediol, 2,2,3-trimethyl- (C7) (Me E _l-3 ); 1,3-butanediol, 2,2,3-trimethyl- (C7) PO _1-2 ; 1,3-butanediol, 2,2-dimethyl- (C6) (Me E _3-8 ); 1,3-butanediol, 2,2-dimethyl- (C6) PO ₃ ; 1,3-butanediol, 2,3-dimethyl- (C6) (Me E _3-8 ); 1,3-butanediol, 2,3-dimethyl- (C6) PO ₃ ; 1,3-butanediol, 2-ethyl- (C6) (Me _El-6 ); 1,3-butanediol, 2-ethyl- (C6) P0 _2-3 ; 1,3-butanediol, 2-ethyl- (C6) BO ₁ ; 1,3-butanediol, 2-ethyl-2-methyl- (C7) (Me _El ); 1,3-butanediol, 2-ethyl-2-methyl- (C7) PO ₁ ; 1,3-butanediol, 2-ethyl-2-methyl- (C7) n-BO _2-4 ; 1,3-butanediol, 2-ethyl-3-methyl- (C7) (Me _El ); 1,3-butanediol, 2-ethyl-3-methyl- (C7) PO ₁ ; 1,3-butanediol, 2-ethyl-3-methyl- (C7) n-BO _2-4 ; 1,3-butanediol, 2-isopropyl- (C7) (Me _El ); 1,3-butanediol, 2-isopropyl- (C7) PO ₁ ; 1,3-butanediol, 2-isopropyl- (C7) n-BO _2-4 ; 1,3-butanediol, 2-methyl- (C5) 2 (Me E _l-3 ); 1,3-butanediol, 2-methyl- (C5) P0 ₄ ; 1,3-butanediol, 2-propyl- (C7) E _2-9 ; 1,3-butanediol, 2-propyl- (C7) PO ₁ ; 1,3-butanediol, 2-propyl- (C7) n-BO _1-3 ; 1,3-butanediol, 3-methyl- (C5) 2 (Me El _l-3 ); 1,3-butanediol, 3-methyl- (C5) P0 ₄ ; 1,4-butanediol (C4) 2 (Me E _2-4 ); 1,4-butanediol (C4) P0 _4-5 ; 1,4-butanediol (C4) B0 ₂ ; 1,4-butanediol, 2,2,3-trimethyl- (C7) E _2-9 ; 1,4-butanediol, 2,2,3-trimethyl- (C7) PO ₁ ; 1,4-butanediol, 2,2,3-trimethyl- (C7) n-BO _1-3 ; 1,4-butanediol, 2,2-dimethyl- (C6) (Me _El-6 ); 1,4-butanediol, 2,2-dimethyl- (C6) PO ₂ ; 1,4-butanediol, 2,2-dimethyl- (C6) BO ₁ ; 1,4-butanediol, 2,3-dimethyl- (C6) (Me _El-6 ); 1,4-butanediol, 2,3-dimethyl- (C6) PO ₂ ; 1,4-butanediol, 2,3-dimethyl- (C6) BO ₁ ; 1,4-butanediol, 2-ethyl- (C6) (Me E _1-4 ); 1,4-butanediol, 2-ethyl- (C6) P0 ₂ ; 1,4-butanediol, 2-ethyl- (C6) BO ₁ ; 1,4-butanediol, 2-ethyl-2-methyl- (C7) _El-7 ; 1,4-butanediol, 2-ethyl-2-methyl- (C7) PO ₁ ; 1,4-butanediol, 2-ethyl-2-methyl- (C7) nBO _1-2 ; 1,4-butanediol, 2-ethyl-3-methyl- (C7) _El-7 ; 1,4-butanediol, 2-ethyl-3methyl- (C7) PO ₁ ; 1,4-butanediol, 2-ethyl-3-methyl- (C7) n-BO _1-2 ; 1,4-butanediol, 2-isopropyl- (C7) _El-7 ; 1,4-butanediol, 2-isopropyl- (C7) PO ₁ ; 1,4-butanediol, 2-isopropyl- (C7) n-BO _1-2 ; 1,4-butanediol, 2-methyl- (C5) (Me E _6-10 ); 1,4-butanediol, 2-methyl- (C5) 2 (Me _El ); 1,4-butanediol, 2-methyl- (C5) PO ₃ ; 1,4-butanediol, 2-methyl- (C5) BO ₁ ; 1,4-butanediol, 2-propyl- (C7) _El-5 ; 1,4-butanediol, 2-propyl- (C7) n-BO _1-2 ; 1,4-butanediol, 3-ethyl-l-methyl- (C7) E _2-9 ; 1,4-butanediol, 3-ethyl-l-methyl- (C7) PO ₁ ; 1,4-butanediol, 3-ethyl-l-methyl- (C7) n-BO _1-3 ; 2,3-butanediol (C4) (Me E _6-10 ); 2,3-butanediol (C4) 2 (Me _El ); 2,3-butanediol (C4) PO _3-4 ; 2,3-butanediol (C4) BO ₁ ; 2,3-butanediol, 2,3-dimethyl- (C6) E _3-9 ; 2,3-butanediol, 2,3-dimethyl- (C6) PO ₁ ; 2,3-butanediol, 2,3-dimethyl- (C6) nBO _1-3 ; 2,3-butanediol, 2-methyl- (C5) (Me _El-5 ); 2,3-butanediol, 2-methyl- (C5) PO ₂ ; 2,3-butanediol, 2-methyl- (C5) BO ₁ ; 3. 1,2-pentanediol (C5) E _3-10 ; 1,2-pentanediol (C5) PO ₁ ; 1,2-pentanediol, (C5) n-BO _2-3 ; 1,2-pentanediol, 2-methyl (C6) _El-1 ; 1,2-pentanediol, 2-methyl (C6) n-BO ₁ ; 1,2-pentanediol, 2-methyl (C6) BO ₁ ; 1,2-pentanediol, 3-methyl (C6) _El-3 ; 1,2-pentanediol, 3-methyl (C6) n-BO ₁ ; 1,2-pentanediol, 4-methyl (C6) _El-1 ; 1,2-pentanediol, 4-methyl (C6) n-BO ₁ ; 1,3-pentanediol (C5) 2 (Me-E _1-2 ); 1,3-pentanediol (C5) P0 _3-4 ; 1,3-pentanediol, 2,2-dimethyl- (C7) (Me-E _l ); 1,3-pentanediol, 2,2-dimethyl- (C7) PO ₁ ; 1,3-pentanediol, 2,2-dimethyl- (C7) n-BO _2-4 ; 1,3-pentanediol, 2,3-dimethyl- (C7) (Me-E _l ); 1,3-pentanediol, 2,3-dimethyl- (C7) PO ₁ ; 1,3-pentanediol, 2,3-dimethyl- (C7) n-BO _2-4 ; 1,3-pentanediol, 2,4-dimethyl (C7) (Me-E _l ); 1,3-pentanediol, 2,4-dimethyl- (C7) PO ₁ ; 1,3-pentanediol, 2,4-dimethyl- (C7) n-BO _2-4 ; 1,3-pentanediol, 2-ethyl- (C7) E _2-9 ; 1,3-pentanediol, 2-ethyl- (C7) PO ₁ ; 1,3-pentanediol, 2-ethyl- (C7) n-BO _1-3 ; 1,3-pentanediol, 2-methyl (C6) 2 (Me-E _1-6 ); 1,3-pentanediol, 2-methyl- (C6) P0 _2-3 ; 1,3-pentanediol, 2-methyl- (C6) BO ₁ ; 1,3-pentanediol, 3,4-dimethyl- (C7) (Me-E _l ); 1,3-pentanediol, 3,4-dimethyl- (C7) PO ₁ ; 1,3-pentanediol, 3,4-dimethyl- (C7) n-BO _2-4 ; 1,3-pentanediol, 3-methyl- (C6) (Me-E _1-6 ); 1,3-pentanediol, 3-methyl- (C6) P0 _2-3 ; 1,3-pentanediol, 3-methyl- (C6) BO ₁ ; 1,3-pentanediol, 4,4-dimethyl- (C7) (Me-E _l ); 1,3-pentanediol, 4,4-dimethyl- (C7) PO ₁ ; 1,3-pentanediol, 4,4-dimethyl- (C7) n-BO _2-4 ; 1,3-pentanediol, 4-methyl- (C6) (Me-E _1-6 ); 1,3-pentanediol, 4-methyl- (C6) P0 _2-3 ; 1,3-pentanediol, 4-methyl- (C6) BO ₁ ; 1,4-pentanediol, (C5) 2 (Me-E _1-2 ); 1,4-pentanediol (C5) PO _3-4 ; 1,4-pentanediol, 2,2-dimethyl- (C7) (Me-E _l ); 1,4-pentanediol, 2,2-dimethyl- (C7) PO ₁ ; 1,4-pentanediol, 2,2-dimethyl- (C7) n-BO _2-4 ; 1,4-pentanediol, 2,3-dimethyl- (C7) (Me-E _l ); 1,4-pentanediol,, 2,3-dimethyl- (C7) PO ₁ ; 1,4-pentanediol, 2,3-dimethyl- (C7) n-BO _2-4 ; 1,4-pentanediol, 2,4-dimethyl (C7) (Me-E _l ); 1,4-pentanediol, 2,4-dimethyl- (C7) PO ₁ ; 1,4-pentanediol, 2,4-dimethyl- (C7) n-BO _2-4 ; 1,4-pentanediol, 2-methyl- (C6) (Me-E _1-6 ); 1,4-pentanediol, 2-methyl- (C6) P0 _2-3 ; 1,4-pentanediol, 2-methyl- (C6) BO ₁ ; 1,4-pentanediol, 3,3-dimethyl- (C7) (Me-E _l ); 1,4-pentanediol, 3,3-dimethyl- (C7) PO ₁ ; 1,4-pentanediol, 3,3-dimethyl- (C7) n-BO _2-4 ; 1,4-pentanediol, 3,4-dimethyl- (C7) (Me-E _l ); 1.4-pentanediol, 3,4-dimethyl- (C7) PO ₁ ; 1,4-pentanediol, 3,4-dimethyl (C7) n-BO _2-4 ; 1,4-pentanediol, 3-methyl- (C6) 2 (Me-E _1-6 ); 1,4-pentanediol, 3-methyl- (C6) P0 _2-3 ; 1,4-pentanediol, 3-methyl- (C6) BO ₁ ; 1,4-pentanediol, 4-methyl- (C6) 2 (Me-E _1-6 ); 1,4-pentanediol, 4-methyl- (C6) P0 _2-3 ; 1,4-pentanediol, 4-methyl- (C6) BO ₁ ; 1,5-pentanediol, (C5) (Me-E _4-10 ); 1,5-pentanediol (C5) 2 (Me-E _l ); 1,5-pentanediol (C5) P0 ₃ ; 1,5-pentanediol, 2,2-dimethyl- (C7) _El-7 ; 1,5 pentanediol, 2,2-dimethyl- (C7) PO ₁ ; 1,5-pentanediol, 2,2-dimethyl- (C7) n-BO _1-2 ; 1,5-pentanediol, 2,3-dimethyl- (C7) _El-7 ; 1,5-pentanediol, 2,3-dimethyl- (C7) PO ₁ ; 1,5-pentanediol 2,3-dimethyl- (C7) n-BO _1-2 ; 1,5-pentanediol, 2,4-dimethyl- (C7) _El-7 ; 1,5-pentanediol, 2,4-dimethyl- (C7) PO ₁ ; 1,5-pentanediol, 2,4-dimethyl- (C7) n-BO _1-2 ; 1,5-pentanediol, 2-ethyl- (C7) _El-5 ; 1,5-pentanediol, 2-ethyl- (C7) n-BO _1-2 ; 1,5-pentanediol, 2-methyl- (C6) (Me-E _1-4 ); 1,5-pentanediol, 2-methyl- (C6) PO ₂ ; 1,5-pentanediol, 3,3-dimethyl- (C7) _El-7 ; 1,5-pentanediol, 3,3-dimethyl- (C7) PO ₁ ; 1,5-pentanediol 3,3-dimethyl- (C7) n-BO _1-2 ; 1,5-pentanediol, 3-methyl- (C6) (Me-E _1-4 ); 1,5-pentanediol, 3-methyl- (C6) P0 ₂ ; 2,3-pentanediol, (C5) (Me-E _1-3 ); 2,3-pentanediol (C5) P0 ₂ ; 2,3-pentanediol, 2-methyl- (C6) _El-7 ; 2,3-pentanediol, 2-methyl- (C6) PO ₁ ; 2,3-pentanediol, 2-methyl- (C6) n-BO _1-2 ; 2,3-pentanediol, 3-methyl- (C6) _El-7 ; 2,3-pentanediol, 3-methyl- (C6) PO ₁ ; 2,3-pentanediol, 3-methyl- (C6) n-BO _1-2 ; 2,3-pentanediol, 4-methyl- (C6) _El-7 ; 2,3-pentanediol, 4-methyl- (C6) PO ₁ ; 2,3-pentanediol, 4-methyl- (C6) n-BO _1-2 ; 2,4-pentanediol, (C5) 2 (Me-E _1-4 ); 2,4-pentanediol (C5) P0 ₄ ; 2,4-pentanediol, 2,3-dimethyl- (C7) (Me-E _1-4 ); 2,4-pentanediol, 2,3-dimethyl- (C7) PO ₂ ; 2,4-pentanediol, 2,4-dimethyl- (C7) (Me E _1-4 ); 2,4-pentanediol, 2,4-dimethyl- (C7) PO ₂ ; 2,4-pentanediol, 2-methyl- (C7) (Me-E _5-10 ); 2,4-pentanediol, 2-methyl- (C7) PO ₃ ; 2,4-pentanediol, 3,3-dimethyl (C7) (Me-E _1-4 ); 2,4-pentanediol, 3,3-dimethyl- (C7) PO ₂ ; 2,4-pentanediol, 3-methyl- (C6) (Me-E _5-10 ); 2,4-pentanediol, 3-methyl- (C6) PO ₃ ; 4. 1,3-hexanediol (C6) (Me-E _1-5 ); 1,3-hexanediol (C6) P0 ₂ ; 1,3-hexanediol (C6) BO ₁ ; 1,3-hexanediol, 2-methyl- (C7) E _2-9 ; 1,3-hexanediol, 2-methyl- (C7) PO ₁ ; 1,3-hexanediol, 2-methyl- (C7) n-BO _1-3 ; 1,3-hexanediol, 2-methyl- (C7) BO ₁ ; 1,3-hexanediol, 3-methyl- (C7) E _2-9 ; 1,3-hexanediol, 3-methyl (C7) PO ₁ ; 1,3-hexanediol, 3-methyl- (C7) n-BO _1-3 ; 1,3-hexanediol, 4-methyl- (C7) E _2-9 ; 1,3-hexanediol, 4-methyl- (C7) PO ₁ ; 1,3-hexanediol, 4-methyl- (C7) n-BO _1-3 ; 1,3-hexanediol, 5-methyl- (C7) E _2-9 ; 1,3-hexanediol, 5-methyl- (C7) PO ₁ ; 1,3-hexanediol, 5-methyl- (C7) n-BO _1-3 ; 1,4-hexanediol (C6) (Me-E _1-5 ); 1,4-hexanediol (C6) P0 ₂ ; 1,4-hexanediol (C6) BO ₁ ; 1,4-hexanediol 2-methyl- (C7) E _2-9 ; 1,4-hexanediol, 2-methyl- (C7) PO ₁ ; 1,4-hexanediol, 2-methyl- (C7) n-BO _1-3 ; 1,4-hexanediol, 3-methyl- (C7) E _2-9 ; 1,4-hexanediol, 3-methyl- (C7) PO ₁ ; 1,4-hexanediol, 3-methyl- (C7) n-BO _1-3 ; 1,4-hexanediol, 4-methyl- (C7) E _2-9 ; 1,4-hexanediol, 4-methyl- (C7) PO ₁ ; 1,4-hexanediol, 4-methyl- (C7) n-BO _1-3 ; 1,4-hexanediol, 5-methyl- (C7) E _2-9 ; 1,4-hexanediol, 5-methyl- (C7) PO ₁ ; 1,4-hexanediol, 5-methyl- (C7) n-BO _1-3 ; 1,5-hexanediol (C6) (Me-E _1-5 ); 1,5-hexanediol (C6) P0 ₂ ; 1,5-hexanediol (C6) BO ₁ ; 1,5-hexanediol 2-methyl- (C7) E _2-9 ; 1,5-hexanediol, 2-methyl- (C7) PO ₁ ; 1,5-hexanediol, 2-methyl- (C7) n-BO _1-3 ; 1,5-hexanediol, 3-methyl- (C7) E _2-9 ; 1,5-hexanediol, 3-methyl- (C7) PO ₁ ; 1,5-hexanediol, 3-methyl- (C7) n-BO _1-3 ; 1,5-hexanediol, 4-methyl- (C7) E _2-9 ; 1,5-hexanediol, 4-methyl- (C7) PO ₁ ; 1,5-hexanediol, 4-methyl- (C7) n-BO _1-3 ; 1,5-hexanediol, 5-methyl- (C7) E _2-9 ; 1,5-hexanediol, 5-methyl- (C7) PO ₁ ; 1,5-hexanediol, 5-methyl- (C7) n-BO _1-3 ; 1,6-hexanediol (C6) (Me-E _1-2 ); 1,6-hexanediol (C6) PO _1-2 ; 1,6-hexanediol (C6) n-BO ₄ ; 1,6-hexanediol, 2-methyl- (C7) _El-5 ; 1,6-hexanediol, 2-methyl- (C7) n-BO _1-2 ; 1,6-hexanediol, 3-methyl- (C7) _El-5 ; 1,6-hexanediol, 3-methyl- (C7) n-BO _1-2 ; 2,3-hexanediol (C6) _El-5 ; 2,3-hexanediol (C6) n-BO ₁ ; 2,3-hexanediol (C6) BO ₁ ; 2,4-hexanediol (C6) (Me-E _3-8 ); 2,4-hexanediol (C6) P0 ₃ ; 2,4-hexanediol, 2-methyl- (C7) (Me-E _1-2 ), 2,4-hexanediol, 2-methyl- (C7) PO _1-2 ; 2,4-hexanediol, 3-methyl- (C7) (Me-E _1-2 ); 2,4-hexanediol, 3-methyl- (C7) PO _1-2 ; 2,4-hexanediol, 4-methyl- (C7) (Me-E _1-2 ); 2,4-hexanediol 4-methyl- (C7) PO _1-2 ; 2,4-hexanediol, 5-methyl- (C7) (Me-E _1-2 ); 2,4-hexanediol 5-methyl- (C7) PO _1-2 ; 2,5-hexanediol (C6) (Me-E _3-8 ); 2,5-hexanediol (C6) P0 ₃ ; 2,5-hexanediol, 2-methyl- (C7) (Me-E _1-2 ); 2,5-hexanediol, 2-methyl- (C7) PO _1-2 ; 2,5-hexanediol, 3-methyl- (C7) (Me-E _1-2 ); 2,5-hexanediol, 3-methyl- (C7) PO _1-2 ; 3,4-hexanediol (C6) EO _1-5 ; 3,4-hexanediol (C6) n-BO ₁ ; 3,4-hexanediol (C6) BO ₁ ; 5. 1,3-heptanediol (C7) _El-7 ; 1,3-heptanediol (C7) PO ₁ ; 1,3-heptanediol (C7) n-BO _1-2 ; 1,4-heptanediol (C7) _El-7 ; 1,4-heptanediol (C7) PO ₁ ; 1,4-heptanediol (C7) n-BO _1-2 ; 1,5-heptanediol (C7) _El-7 ; 1,5-heptanediol (C7) 1,5-heptanediol (C7) n-BO _1-2 ; 1,6-heptanediol (C7) _El-7 ; 1,6-heptanediol (C7) PO ₁ ; 1,6-heptanediol (C7) n-BO _1-2 ; 1,7-heptanediol (C7) El _-1 ; 1,7-heptanediol (C7) n-BO ₁ ; 2,4-heptanediol (C7) E _3-10 ; 2,4-heptanediol (C7) (Me-E _l ); 2,4-heptanediol (C7) PO ₁ ; 2,4-heptanediol (C7) n-BO ₃ ; 2,5-heptanediol (C7) E _3-10 ; 2,5-heptanediol (C7) (Me-E _l ); 2,5-heptanediol (C7) PO ₁ ; 2,5-heptanediol (C7) n-B0 ₃ ; 2,6-heptanediol (C7) E _3-10 ; 2,6-heptanediol (C7) (Me-E _l ); 2,6-heptanediol (C7) PO ₁ ; 2,6-heptanediol (C7) n-BO ₃ ; 3,5-heptanediol (C7) E _3-10 ; 3,5-heptanediol (C7) (Me-E ₁ ); 3,5-heptanediol (C7) PO ₁ ; 3,5-heptanediol (C7) n-BO ₃ ; 6. 1,3-butanediol, 3-methyl-2-isopropyl- (C8) PO ₁ ; 2,4-pentanediol, 2,3,3-trimethyl- (C8) PO ₁ ; 1,3-butanediol, 2,2-diethyl- (C8) E _2-5 ; 2,4-hexanediol, 2,3-dimethyl- (C8) E _2-5 ; 2,4-hexanediol, 2,4-dimethyl- (C8) E _2-5 ; 2,4-hexanediol, 2,5-dimethyl- (C8) E _2-5 ; 2,4-hexanediol, 3,3-dimethyl- (C8) E _2-5 ; 2,4-hexanediol, 3,4-dimethyl- (C8) E _2-5 ; 2,4-hexanediol, 3,5-dimethyl- (C8) E _2-5 ; 2,4-hexanediol, 4,5-dimethyl- (C8) E _2-5 ; 2,4-hexanediol, 5,5-dimethyl- (C8) E _2-5 ; 2,5-hexanediol, 2,3-dimethyl- (C8) E _2-5 ; 2,5-hexanediol, 2,4-dimethyl- (C8) E _2-5 ; 2,5-hexanediol, 2,5-dimethyl- (C8) E _2-5 ; 2,5-hexanediol, 3,3-dimethyl- (C8) E _2-5 ; 2,5-hexanediol, 3,4-dimethyl- (C8) E _2-5 ; 3,5-heptanediol, 3-methyl- (C8) E _2-5 ; 1,3-butanediol, 2,2-diethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 2,3-dimethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 2,4-dimethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 2,5-dimethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 3,3-dimethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 3,4-dimethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 3,5-dimethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 4,5-dimethyl- (C8) n-BO _1-2 ; 2,4-hexanediol, 5,5-dimethyl-, n-BO _1-2 ; 2,5-hexanediol, 2,3-dimethyl (C8) n-BO _1-2 ; 2,5-hexanediol, 2,4-dimethyl- (C8) n-BO _1-2 ; 2,5-hexanediol, 2,5-dimethyl- (C8) n-BO _1-2 ; 2,5-hexanediol, 3,3-dimethyl- (C8) n-BO _1-2 ; 2,5-hexanediol, 3,4-dimethyl- (C8) n-BO _1-2 ; 3,5-heptanediol, 3-methyl- (C8) n-BO _1-2 ; 1,3-propanediol, 2- (1,2-dimethylpropyl)-(C8) n-BO ₁ ; 1,3-butanediol, 2-ethyl-2,3-dimethyl- (C8) n-BO ₁ ; 1,3-butanediol, 2-methyl-2-isopropyl- (C8) n-BO ₁ ; 1,4-butanediol, 3-methyl-2-isopropyl- (C8) n-BO ₁ ; 1,3-pentanediol, 2,2,3-trimethyl- (C8) n-BO ₁ ; 1,3-pentanediol, 2,2,4-trimethyl- (C8) n-BO ₁ ; 1,3-pentanediol, 2,4,4-trimethyl- (C8) n-BO ₁ ; 1,3-pentanediol, 3,4,4-trimethyl- (C8) n-BO ₁ ; 1,4-pentanediol, 2,2,3-trimethyl- (C8) n-BO ₁ ; 1,4-pentanediol, 2,2,4-trimethyl- (C8) n-BO ₁ ; 1,4-pentanediol, 2,3,3-trimethyl- (C8) n-BO ₁ ; 1,4-pentanediol, 2,3,4-trimethyl (C8) n-BO ₁ ; 1,4-pentanediol, 3,3,4-trimethyl- (C8) n-BO ₁ ; 2,4-pentanediol, 2,3,4-trimethyl- (C8) n-BO ₁ ; 2,4-hexanediol, 4-ethyl- (C8) n-BO ₁ ; 2,4-heptanediol, 2-methyl- (C8) n-BO ₁ ; 2,4-heptanediol, 3-methyl- (C8) n-BO ₁ ; 2,4-heptanediol, 4-methyl- (C8) n-BO ₁ ; 2,4-heptanediol, 5-methyl- (C8) n-BO ₁ ; 2,4-heptanediol, 6-methyl- (C8) n-BO ₁ ; 2,5-heptanediol, 2-methyl- (C8) n-BO ₁ ; 2,5-heptanediol, 3-methyl- (C8) n-BO ₁ ; 2,5-heptanediol, 4-methyl- (C8) n-BO ₁ ; 2,5-heptanediol, 5-methyl- (C8) n-BO ₁ ; 2,5-heptanediol, 6-methyl- (C8) n-BO ₁ ; 2,6-heptanediol, 2-methyl- (C8) n-BO ₁ ; 2,6-heptanediol, 3-methyl- (C8) n-BO ₁ ; 2,6-heptanediol, 4-methyl- (C8) n-BO ₁ ; 3,5-heptanediol, 2-methyl- (C8) n-BO ₁ ; 1,3-propanediol, 2- (1,2-dimethylpropyl)-(C8) _El-3 ; 1,3-butanediol, 2-ethyl-2,3-dimethyl- (C8) _El-1 ; 1,3-butanediol, 2-methyl-2-isopropyl- (C8) _El-3 ; 1,4-butanediol, 3-methyl-2-isopropyl- (C8) _El-1 ; 1,3-pentanediol, 2,2,3-trimethyl- (C8) El _-1 ; 1,3-pentanediol, 2,2,4-trimethyl- (C8) _El-1 ; 1,3-pentanediol, 2,4,4-trimethyl- (C8) El _-1 ; 1,3-pentanediol, 3,4,4-trimethyl- (C8) El _-1 ; 1,4-pentanediol, 2,2,3-trimethyl- (C8) El _-1 ; 1,4-pentanediol, 2,2,4-trimethyl- (C8) _El-1 ; 1,4-pentanediol, 2,3,3-trimethyl- (C8) El _-1 ; 1,4-pentanediol, 2,3,4-trimethyl- (C8) _El-1 ; 1,4-pentanediol, 3,3,4-trimethyl (C8) El _-1 ; 2,4-pentanediol, 2,3,4-trimethyl- (C8) _El-1 ; 2,4-hexanediol, 4-ethyl- (C8) _El-1 ; 2,4-heptanediol, 2-methyl- (C8) _El-1 ; 2,4-heptanediol, 3-methyl- (C8) _El-1 ; 2,4-heptanediol, 4-methyl- (C8) _El-1 ; 2,4-heptanediol, 5-methyl- (C8) _El-1 ; 2,4-heptanediol, 6-methyl- (C8) _El-1 ; 2,5-heptanediol, 2-methyl- (C8) _El-1 ; 2,5-heptanediol, 3-methyl- (C8) _El-1 ; 2,5-heptanediol, 4-methyl- (C8) E _1-3 ; 2,5-heptanediol, 5-methyl- (C8) _El-1 ; 2,5-heptanediol, 6-methyl- (C8) _El-1 ; 2,6-heptanediol, 2-methyl- (C8) _El-3 ; 2,6-heptanediol, 3-methyl- (C8) E _1-3 ; 2,6-heptanediol, 4-methyl- (C8) E _1-3 or 3,5-heptanediol, 2-methyl- (C8) E _1-3 ; And 7. mixtures thereof; Iii. Aromatic diols comprising: 1-phenyl-1,2-ethanediol; 1-phenyl-1,2-propanediol; 2-phenyl-1,2-propanediol; 3-phenyl-1,2-propanediol; 1- (3-methylphenyl) -1,3-propanediol; 1- (4-methylphenyl) -1,3-propanediol; 2-methyl-1-phenyl-1,3-propanediol; 1-phenyl-1,3-butanediol; 3-phenyl-1,3-butanediol; 1-phenyl-1,4-butanediol; 2-phenyl-1,4-butanediol; Or 1-phenyl-2,3-butanediol; Iii. Having a ClogP value of 0.15 to 0.64, one or more CH ₂ groups are bonded, and for each bonded CH ₂ group, two hydrogen atoms are removed from adjacent carbon atoms in the molecule to form one carbon-carbon double bond, thereby A homologue or analog of the structure that maintains a constant number of hydrogen atoms in the solvent, the solvent comprising: 1,3-propanediol, 2,2-di-2-propenyl-; 1,3-propanediol, 2- (1-pentenyl)-; 1,3 propanediol, 2- (2-methyl-2-propenyl) -2- (2-propenyl)-; 1,3-propanediol, 2- (3-methyl1-butenyl)-; 1,3-propanediol, 2- (4-pentenyl)-; 1,3-propanediol, 2-ethyl-2- (2-methyl-2-propenyl)-; 1,3-propanediol, 2-ethyl-2- (2-propenyl)-; 1,3-propanediol, 2-methyl-2- (3-methyl-3-butenyl)-; 1,3-butanediol, 2,2-diallyl-; 1,3-butanediol, 2- (1-ethyl-1-propenyl)-; 1,3-butanediol, 2- (2-butenyl) -2-methyl-; 1,3-butanediol, 2- (3-methyl-2-butenyl)-; 1,3-butanediol, 2-ethyl-2- (2-propenyl)-; 1,3-butanediol, 2-methyl-2- (1-methyl-2-propenyl)-; 1,4-butanediol, 2,3-bis (1-methylethylidene)-; 1,4-butanediol, 2- (3-methyl-2-butenyl) -3-methylene-; 2-butene-1,4-diol, 2- (1,1-dimethylpropyl)-; 2-butene-1,4-diol, 2- (1-methylpropyl)-; 2-butene-1,4-diol, 2-butyl-; 1,3-pentanediol, 2-ethenyl-3-ethyl-; 1,3-pentanediol, 2-ethenyl-4,4-dimethyl-; 1,4-pentanediol, 3-methyl-2- (2-propenyl)-; 1,5-pentanediol, 2- (1-propenyl)-; 1,5-pentanediol, 2- (2-propenyl)-; 1,5-pentanediol, 2-ethylidene-3-methyl-; 1,5-pentanediol, 2-propylidene-; 2,4-pentanediol, 3-ethylidene-2,4-dimethyl-; 4-pentene-1,3-diol, 2- (1,1-dimethylethyl)-; 4-pentene-1,3-diol, 2-ethyl-2,3-dimethyl-; 1,4-hexanediol, 4-ethyl-2-methylene-; 1,5-hexadiene-3,4-diol, 2,3,5-trimethyl-; 1,5-hexadiene-3,4-diol, 5-ethyl-3-methyl-; 1,5-hexanediol, 2- (1-methylethenyl)-; 1,6-hexanediol, 2-ethenyl-; 1-hexene-3,4-diol, 5,5-dimethyl-; 1-hexene-3,4-diol, 5,5-dimethyl-; 2-hexene-1,5-diol, 4-ethenyl-2,5-dimethyl-; 3-hexene-1,6-diol, 2-ethenyl-2,5-dimethyl-; 3-hexene-1,6-diol, 2-ethyl-; 3-hexene-1,6-diol, 3,4-dimethyl-; 4-hexene-2,3-diol, 2,5-dimethyl-; 4-hexene-2,3-diol, 3,4-dimethyl-; 5-hexene-1,3-diol, 3- (2-propenyl)-; 5-hexene-2,3-diol, 2,3-dimethyl-; 5-hexene-2,3-diol, 3,4-dimethyl-; 5-hexene-2,3-diol, 3,5-dimethyl-; 5-hexene-2,4-diol 3-ethenyl-2,5-dimethyl-; 1,4-heptanediol, 6-methyl-5-methylene-; 1,5-heptadiene-3,4-diol, 2,3-dimethyl-; 1,5-heptadiene-3,4-diol, 2,5-dimethyl-; 1,5-heptadiene-3,4-diol, 3,5-dimethyl-; 1,7-heptanediol, 2,6-bis (methylene)-; 1,7-heptanediol, 4-methylene-; 1-heptene-3,5-diol, 2,4-dimethyl-; 1-heptene-3,5-diol, 2,6-dimethyl-; 1-heptene-3,5-diol, 3-ethenyl-5-methyl, 1-heptene-3,5-diol, 6,6-dimethyl-; 2,4-heptadiene-2,6-diol, 4,6-dimethyl-; 2,5-heptadiene-1,7-diol, 4,4-dimethyl-; 2,6-heptadiene-1,4-diol, 2,5,5-trimethyl-; 2-heptene-1,4-diol, 5,6-dimethyl-; 2-heptene-1,5-diol, 5-ethyl-; 2-heptene-1,7-diol, 2-methyl-; 3-heptene-1,5-diol, 4,6-dimethyl-; 3-hepten-1,7-diol, 3-methyl-6-methylene-; 3-heptene-2,5-diol, 2,4-dimethyl-; 3-heptene-2,5-diol, 2,5-dimethyl-; 3-heptene-2,6-diol, 2,6-dimethyl-; 3-heptene-2,6-diol, 4,6-dimethyl-; 5-heptene-1,3-diol, 2,4-dimethyl-; 5-heptene-1,3-diol, 3,6-dimethyl-; 5-heptene-1,4-diol, 2,6-dimethyl-; 5-heptene-1,4-diol, 3,6-dimethyl-; 5-heptene-2,4-diol, 2,3-dimethyl-; 6-heptene-1,3-diol, 2,2-dimethyl-; 6-heptene-1,4-diol, 4- (2-propenyl)-; 6-heptene-1,4-diol, 5,6-dimethyl-; 6-heptene-1,5-diol, 2,4-dimethyl-; 6-heptene-1,5-diol, 2-ethylidene-6-methyl-; 6-heptene-2,4-diol, 4- (2-propenyl)-; 6-heptene-2,4-diol, 5,5-dimethyl-; 6-heptene-2,5-diol, 4,6-dimethyl-; 6-heptene-2,5-diol, 5-ethenyl-4-methyl-; 1,3-octanediol, 2-methylene-; 1,6-octadiene-3,5-diol, 2,6-dimethyl-; 1,6-octadiene-3,5-diol, 3,7-dimethyl-; 1,7-octadiene-3,6-diol, 2,6-dimethyl-; 1,7-octadiene-3,6-diol, 2,7-dimethyl-; 1,7-octadiene-3,6-diol, 3,6-dimethyl-; 1-octene-3,6-diol, 3-ethenyl-; 2,4,6-octatriene-1,8-diol, 2,7-dimethyl-; 2,4-octadiene-1,7-diol, 3,7-dimethyl-; 2,5-octadiene-1,7-diol, 2,6-dimethyl-; 2,5-octadiene-1,7-diol, 3,7-dimethyl-; 2,6-octadiene-1,4-diol, 3,7-dimethyl- (rosiridol); 2,6-octadiene-l, 8-diol, 2-methyl-; 2,7-octadiene-1,4-diol, 3,7-dimethyl-; 2,7-octadiene-1,5-diol, 2,6-dimethyl-; 2,7-octadiene-1,6-diol, 2,6-dimethyl- (8-hydroxylinalolol); 2,7-octadiene-1,6-diol, 2,7-dimethyl-; 2-octene-1,4-diol; 2-octene-1,7-diol; 2-octene-1,7-diol; 2-methyl-6-methylene-; 3,5-octadiene-1,7-diol, 3,7-dimethyl-; 3,5-octadiene-2,7-diol, 2,7-dimethyl-; 3,5-octanediol, 4-methylene-; 3,7-octadiene-1,6-diol, 2,6-dimethyl-3,7-octadiene-2,5-diol, 2,7-dimethyl-; 3,7-octadiene-2,6-diol, 2,6-dimethyl-; 3-octene-1,5-diol, 4-methyl-; 3-octene-1,5-diol, 5-methyl-; 4,6-octadiene-1,3-diol, 2,2-dimethyl-; 4,7-octadiene-2,3-diol, 2,6-dimethyl-; 4,7-octadiene-2,6-diol, 2,6-dimethyl-; 4-octene-1,6-diol, 7-methyl-; 2,7-bis (methylene)-; 2-methylene-; 5,7-octadiene-1,4-diol, 2,7-dimethyl-; 5,7-octadiene-1,4-diol, 7-methyl-; 5-octene-1,3-diol; 6-octene-1,3-diol, 7-methyl-; 6-octene-1,4-diol, 7-methyl-; 6-octene-1,5-diol, 6-octene-1,5-diol, 7-methyl-, 6-octene-3,5-diol, 2-methyl-; 6-octene-3,5-diol, 4-methyl-; 7-octene-1,3-diol, 2-methyl-, 7-octene-1,3-diol, 4-methyl-; 7-octene-1,3-diol, 7-methyl-; 7-octene-1,5-diol; 7-octene-1,6-diol; 7-octene-1,6-diol, 5-methyl-; 7-octene-2,4-diol, 2-methyl-6-methylene-; 7-octene-2,5-diol, 7-methyl-; 7-octene-3,5-diol, 2-methyl-; 1-nonene-3,5-diol; 1-nonene-3,7-diol; 3-nonene-2,5-diol; 4,6-nonadiene-1,3-diol, 8-methyl-; 4-nonene-2,8-diol; 6,8-nonadiene-1,5-diol; 7-nonene-2,4-diol; 8-nonene-2,4-diol; 8-nonene-2,5-diol; 1,9-decadiene-3,8-diol, or 1,9-docadiene-4,6-diol; And ⅩⅠ. Mixtures thereof, wherein the main solvent is 2,2,4-trimethyl-1,3-pentane diol; Ethoxylated, diethoxylated or triethoxylated derivatives of 2,2,4-trimethyl-1,3-pentane diol; Or a solvent selected from the group consisting of 2-ethylhexyl-1,3-diol in an amount insufficient to provide a stable aqueous product; C. low molecular weight water soluble solvents such as ethanol, isopropanol, propylene glycol, 1,3-propanediol, propylene carbonate and the like in an amount sufficient to improve transparency and incapable of forming a transparent composition by itself; D. Effective amounts of water soluble calcium salts, magnesium salts or both salts to improve transparency; And E. Balance with water. 42. The composition of claim 41, wherein said main solvent B is present in an effective amount up to the amount required to obtain stability and said composition is stabilized by the addition of another solvent in which it is not possible to obtain stability by itself. Using a preliminary mixture of claim 37, a transparent fabric containing water and an acid which brings the pH to 1.5 to 5 and adding the preliminary mixture to a toilet which may contain an effective amount of a water soluble calcium salt, magnesium salt or both salts. Process for the preparation of the flexible composition. 42. The composition of claim 41 wherein the salt of D is chloride.