KR100259392B1 - Refinement treatment composition of silk fabric and pattern formation method of silk fabric using the same - Google Patents

Refinement treatment composition of silk fabric and pattern formation method of silk fabric using the same Download PDF

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KR100259392B1
KR100259392B1 KR1019980019690A KR19980019690A KR100259392B1 KR 100259392 B1 KR100259392 B1 KR 100259392B1 KR 1019980019690 A KR1019980019690 A KR 1019980019690A KR 19980019690 A KR19980019690 A KR 19980019690A KR 100259392 B1 KR100259392 B1 KR 100259392B1
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silk fabric
weight
silk
composition
fabric
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KR1019980019690A
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Korean (ko)
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KR19990086607A (en
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전유헌
이재덕
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전유헌
정기철
동우섬유주식회사
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
    • D06L1/02—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using organic solvents
    • D06L1/04—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using organic solvents combined with specific additives
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01C—CHEMICAL OR BIOLOGICAL TREATMENT OF NATURAL FILAMENTARY OR FIBROUS MATERIAL TO OBTAIN FILAMENTS OR FIBRES FOR SPINNING; CARBONISING RAGS TO RECOVER ANIMAL FIBRES
    • D01C3/00—Treatment of animal material, e.g. chemical scouring of wool
    • D01C3/02—De-gumming silk
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B11/00—Treatment of selected parts of textile materials, e.g. partial dyeing
    • D06B11/0056—Treatment of selected parts of textile materials, e.g. partial dyeing of fabrics
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06Q—DECORATING TEXTILES
    • D06Q1/00—Decorating textiles
    • D06Q1/06—Decorating textiles by local treatment of pile fabrics with chemical means
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2211/00—Protein-based fibres, e.g. animal fibres
    • D10B2211/01—Natural animal fibres, e.g. keratin fibres
    • D10B2211/04—Silk

Abstract

PURPOSE: Provided are a scouring agent composition for a silk fabric and a pattern forming method of the silk fabric by using the scouring agent composition which is characterized by uniform dyeing effect on both sides of the silk fabric by dissolving specific protein of a silk surface selectively, thereby forming a desired pattern. CONSTITUTION: The scouring agent composition is comprised of 20-30wt.% of a scouring agent, 2-3wt.% of sodium bicarbonate, 10-20wt.% of urea, 10-20wt.% of thickening agent, 4-6wt.% of glycerine, 2-4wt.% of soap as a surfactant, monogene or a mixture thereof and 7-48wt.% of water. The pattern forming method of the silk fabric comprises the steps of: treating the desired pattern on the silk fabric with the scouring agent composition at 30-70deg.C at pH7-9; steeping the silk fabric into an aqueous solution dissolved 0.1-0.2% of monogene, 2.5-3.5 wt.% of sodium bicarbonate and 9-11wt.% of soap for 5-10minutes; and then drying and washing.

Description

견직물의 정련처리제 조성물 및 그를 이용한 견직물의 무늬형성방법Refinement treatment composition of silk fabric and pattern formation method of silk fabric using the same

본발명은 견직물의 정련처리제 조성물 및 그를 이용한 견직물의 무늬형성방법에 관한 것으로서, 보다 상세하게는 견사의 표피부에 형성된 특정 단백질을 선택적으로 분해시키는 작용을 나타내는 정련제를 견직물의 표면에 처리하여 줌으로써 침염시 이종 단백질간의 염색도의 차이에 의하여 원하는 무늬를 형성시킬 수 있도록 한 견직물의 정련처리제 조성물 및 그를 이용한 견직물의 무늬형성방법에 관한 것이다.The present invention relates to a refining agent composition of the silk fabric and a method of forming a pattern of the silk fabric using the same, and more particularly, by treating the surface of the silk fabric with a refining agent that selectively decomposes a specific protein formed on the skin of the silk. The present invention relates to a scouring agent composition of a silk fabric capable of forming a desired pattern by a difference in staining degree between different heterologous proteins and a pattern formation method of the silk fabric using the same.

일반적으로 견직물에 색상을 부여하거나 무늬를 형성시키기 위한 방법으로써 종래에는 주로 다양한 염색방법이 적용되었는데, 예를 들어 다색 염색의 경우 날염 또는 실크스크린을 이용한 염색방법을 이용하여 견직물에 다양한 무늬를 부여할 수 있었으며 단색 인쇄의 경우 일반적으로 침염에 의한 염색공정을 수행하여 원하는 색상을 나타내는 견직물을 얻을 수 있었다.In general, various dyeing methods have been conventionally applied as a method for imparting colors or forming patterns to silk fabrics. For example, in the case of multicolor dyeing, various patterns may be applied to silk fabrics using dyeing or printing using silk screens. In the case of monochromatic printing, a silk fabric having a desired color could be obtained by performing a dyeing process by dyeing.

그러나, 상기 설명한 종래의 무늬형성방법중 날염에 의한 방법의 경우, 날염호에 함유된 과량의 호료에 의하여 견직물 고유의 부드러운 질감을 손상시키는 문제점이 있을 뿐만 아니라, 이러한 날염방법은 견직물의 일면에만 염색이 가능하여 견직물의 염색되지 않은 다른 일면은 조잡한 염색상태를 나타낼 수 밖에 없는 문제점이 있었다.However, in the conventional pattern forming method described above, there is a problem in that the soft texture inherent to the silk fabric is damaged by an excessive amount of paint contained in the printing foil, and the printing method is dyed only on one surface of the silk fabric. This is possible because the other side of the silk non-dyed had a problem that can not only represent a crude dyeing state.

또한, 통상적인 실크스크린 다색 염색방법에 의하여 견직물에 다양한 무늬를 형성시키고자 하는 방법은 상기한 날염방법에 비하여 견직물 고유의 질감 저하정도는 다소 미미하지만 이 또한 염색된 견직물의 일면과 염색되지 않은 일면과의 염색도 차이가 심하여 이러한 견직물을 반투명 색조가 요구되는 옷감이나 포장재 또는 장식재로써 적용하고자 하는 경우 한계를 드러내는 문제점이 있었다.In addition, the method of forming a variety of patterns on the silk fabric by the conventional silk-screen multi-color dyeing method is slightly less inherent in the texture of the silk fabric than the printing method described above, but also one side and the other side of the dyed silk fabric There is a problem that reveals a limit when applying the silk fabric as a cloth, packaging material or decorative material that requires a translucent color tone due to the difference in the degree of dyeing.

이러한 날염 또는 실크스크린에 의한 염색방법에 의한 무늬형성방법과는 달리 침염에 의한 염색방법은 견직물의 양면에 동일 색상의 염색이 가능한 장점이 있는 반면, 이는 단색 염색에 국한된 것으로 다양한 무늬를 나타낼 수 없는 문제점이 있었다.Unlike the method of forming the pattern by the dyeing method by printing or silk screen, the dyeing method by dip dyeing has the advantage that the same color can be dyed on both sides of the silk fabric, but it is limited to the monochromatic dyeing. There was a problem.

본발명의 상기한 종래 방법의 문제점을 해결하기 위한 것으로써, 견직물에의 무늬형성을 위한 염색시 이미 설명한 바와 같이 견사의 표피부에 형성된 특정 단백질을 선택적으로 분해시키는 작용을 나타내는 정련제를 견직물의 표면에 처리하여 줌으로써 침염시 이종 단백질간의 염색도의 차이에 의하여 원하는 무늬를 형성시킬 수 있을 뿐만 아니라, 견직물 양면의 균일한 염색 색상을 나타낼 수 있도록 한 견직물의 정련처리제 조성물 및 그를 이용한 견직물의 무늬형성방법을 제공함에 그 목적이 있다.In order to solve the problems of the above-described conventional method of the present invention, the surface of the silk fabric with a refining agent exhibiting the action of selectively decomposing a specific protein formed on the epidermis of the silk as described above when staining for pattern formation on the silk fabric By treating in a dyeing process, it is possible not only to form a desired pattern due to the difference in dyeing degree between heterologous proteins, but also to a uniform dyeing color on both sides of the silk fabric, and a method of forming a silk fabric using the same. The purpose is to provide.

상기한 목적을 달성하기 위한 본발명은 정련제 20 내지 30중량%와 중탄산나트륨 2 내지 3중량%와 요소 10 내지 20중량%와 호료 10 내지 20중량%와 글리세린 4 내지 6중량%와 계면활성제로서 비누 또는 모노겐의 단독 또는 혼합물 2 내지 4중량%와 물 7 내지 48중량%로 이루어짐을 특징으로 하는 견직물의 정련처리제 조성물을 제공한다.The present invention for achieving the above object is 20-30% by weight of refiner, 2-3% by weight of sodium bicarbonate, 10-20% by weight of urea, 10-20% by weight of fertilizer, 4-6% by weight of glycerin and soap as surfactant Or 2 to 4% by weight of monogen or a mixture of monogen and 7 to 48% by weight of water.

또한, 정련제 20 내지 30중량%와 중탄산나트륨 2 내지 3중량%와 요소 10 내지 20중량%와 호료 10 내지 20중량%와 글리세린 4 내지 6중량%와 계면활성제로써 비누 또는 모노겐의 단독 또는 혼합물 2 내지 4중량%와 물 7 내지 48중량%로 이루어진 정련제 조성물을 30 내지 70℃온도 및 pH 7 내지 9의 조건하에서 견직물에 원하는 무늬로 처리한 다음 건조 및 수세후 염색시킴을 특징으로 하는 견직물의 무늬형성방법을 제공한다.In addition, solely or mixture of 20-30% by weight of refiner, 2-3% by weight of sodium bicarbonate, 10-20% by weight of urea, 10-20% by weight of glaze, 4-6% by weight of glycerin and surfactant or surfactant 2 The silk fabric composition, characterized in that the scouring agent composition consisting of 4 to 4% by weight and 7 to 48% by weight of water is treated with a desired pattern on a silk fabric at a temperature of 30 to 70 ° C and a pH of 7 to 9, followed by drying and washing with water. It provides a formation method.

본발명에서 피염물로써 사용되는 견직물은 견사(絹絲)를 직조하여 제조된 동물성 섬유로써 상기의 견사는 중심부와 표피부로 된 이종 단백질로 구성되는데, 중심부를 형성하는 단백질 성분은 섬유성 경단백질인 피브로인(fibroin)이며, 표피부는 아교질 성분과 유사한 세리신(sericin) 성분으로 된 단백질로 구성되어 있다.In the present invention, the silk fabric used as a chlorinated material is an animal fiber manufactured by weaving silk thread. The silk thread is composed of a heterologous protein composed of a central part and an epidermal part, and the protein component forming the central part is a fibrous light protein. Infibroin (fibroin), the epidermis is composed of a protein of sericin component similar to the gelatinous component.

상기 언급된 본발명의 정련처리제 조성물은 상기한 견사의 표피부에 구성된 세리신을 선택적으로 분해시키는 작용을 나타내며, 본발명의 정련처리제를 견직물에 원하는 무늬로 처리하여 줄 경우 정련처리된 부분에 직조된 견사는 세리신 성분이 분해된 상태로 피브로인 성분만이 남게 된다.The above-described refining agent composition of the present invention exhibits the action of selectively decomposing sericin formed on the epidermis of the silk, and when the refining agent of the present invention is treated with a desired pattern on the silk fabric, Silk is decomposed into sericin, leaving only the fibroin component.

이러한 세리신과 피브로인은 염색성상에 있어서 커다란 차이를 나타내므로 침염시에는 견직물 표면에 정련처리된 무늬부분과 정련처리되지 않은 기타부분과의 염색도 차이에 의하여 원하는 무늬를 형성시킬 수 있는 것이며, 견직물의 양면에 색상차이를 나타내지 않는 피염물을 얻을 수 있는 것이다.Since sericin and fibroin have a great difference in staining properties, the sericin and fibroin can form a desired pattern by dyeing the patterned part of the silk fabric on the surface of the silk fabric by the difference in the degree of dyeing between the other parts that are not refined. It is possible to obtain a salt solution that does not show a color difference on both sides.

상기의 세리신 분해작용은 상기 정련처리제 조성물에 함유된 정련제 성분에 의한 것인데, 본발명에서 사용되는 정련제 성분은 세린형 단백질분해효소(serin-type protease)로서 견사의 표피부에 구성된 세리신 성분을 선택적으로 분해하는 작용을 나타낼 수 있는 것이다.The sericin decomposition action is due to the scouring agent component contained in the scouring agent composition. The scouring agent component used in the present invention is a serin-type protease, which selectively binds to the sericin component of the silk skin. It can show the action of decomposition.

이러한 단백질 분해효소는 30 내지 70℃의 온도조건 및 pH 7 내지 9의 알카리성 분위기하에서 우수한 분해성을 나타내는데, 이를 위하여 상기 정련제 처리 조성물에는 pH조절제로써 중탄산나트륨을 첨가하게 되며, 그 첨가량이 2중량%미만일 경우에는 바람직한 pH조절 효과를 얻기 어려우며, 3중량%이상으로 첨가될 경우에는 후처리 과정인 침염과정에서 잔존 알카리염성분에 의하여 염색성이 저하되는 문제점이 발생할 수 있다.This protease shows excellent degradability under the temperature condition of 30 to 70 ℃ and alkaline atmosphere of pH 7 to 9, for this purpose, sodium bicarbonate is added to the refiner treatment composition as a pH regulator, the addition amount is less than 2% by weight In case it is difficult to obtain a desirable pH control effect, when added in more than 3% by weight may cause a problem that the dyeability is reduced by the remaining alkaline salt component in the post-treatment process.

또한, 정련제조성물의 점도가 지나치게 낮으면 상기 조성물을 견직물에 처리하는 경우 번짐현상이 발생하여 원하는 무늬의 원활한 형성에 어려움이 있으므로 합성호료를 첨가하여 점도를 적절히 조절하여 줌이 바람직하며 이를 위하여 합성호료의 첨가량이 10중량%이상으로 하되 20중량%를 초과시킬 필요는 없다.In addition, if the viscosity of the refining composition is too low, when the composition is treated on a silk fabric, bleeding occurs, and it is difficult to form a desired pattern smoothly. Therefore, it is preferable to adjust the viscosity appropriately by adding a synthetic paint. The added amount of is not less than 10% by weight but need not exceed 20% by weight.

이와 함께 상기 정련제조성물에 첨가되는 유기화합물과 무기화합물의 상용성을 향상시키기 위하여 본발명에서는 계면활성제로써 비누 또는 모노겐의 단독 또는 혼합물을 상기한 바와 같이 2중량%이상 내지 4 중량%이내로 첨가한다.In addition, in order to improve the compatibility of the organic compound and the inorganic compound added to the refining composition, in the present invention, a soap or monogen alone or as a mixture is added within 2% to 4% by weight as a surfactant. .

이러한 계면활성제의 첨가로 인하여 정련제 조성물의 교반시 거품이 발생하게 되는데 본발명에서는 소포제로써 요소를 10 내지 20중량%로 첨가하여 교반시 액체의 표면장력을 낮추어 줌으로써 거품 발생을 방지할 수 있는 것이다.Due to the addition of the surfactant, foaming occurs when stirring the refiner composition. In the present invention, by adding 10 to 20% by weight of urea as an antifoaming agent, foaming can be prevented by lowering the surface tension of the liquid during stirring.

상기한 비율의 각 첨가물질과 함께 최종적으로 물 7 내지 48중량%를 첨가하여 본발명의 정련제 조성물을 제조할 수 있는 것이며, 이때 수분의 발산을 방지함으로써 저장성을 향상시키기 위하여 본발명에서는 습윤제로써 글리세린을 첨가하게 되는데 바람직한 습윤효과를 얻기 위해서는 4중량%이상으로 첨가하되 6중량%이상 첨가할 필요는 없다.Finally, 7 to 48% by weight of water can be prepared together with each of the additives in the above-mentioned ratios to prepare a refiner composition of the present invention, wherein glycerin is used as a humectant in the present invention to improve shelf life by preventing the dissipation of water. In order to obtain a desirable wetting effect, it is added in more than 4% by weight but need not add more than 6% by weight.

이상 설명한 방법으로 제조된 본발명의 정련제 조성물을 견직물에 처리시에는 작업자의 의도에 따라 브러쉬를 이용한 수작업 또는 공지된 바의 실크스크린법 등을 이용하여 견직물에 원하는 무늬의 형상에 따라 처리한 후 수세 및 건조한 다음 발현하고 하는 색상의 염욕에 침지시키게 되면 정련제로 처리된 세리신과 처리되지 않은 피브로인의 염색성상의 차이에 따라 견직물의 표면에 소기한 무늬를 형성시킬 수 있는 것이며, 이렇게 염색된 견직물은 양표면의 염색도 차이가 없이 동일한 색상으로 염색처리될 수 있는 것이다.When treating the silk fabric of the refiner composition of the present invention prepared by the above-described method to the silk fabric according to the intention of the operator or by using a silk screen method of the well-known bar, and the like to wash the silk fabric according to the desired pattern shape And after being dipped in a dye bath of the color which is expressed after drying, it is possible to form a desired pattern on the surface of the silk fabric according to the difference in the dyeing properties of the sericin treated with the scouring agent and the untreated fibroin. It can be dyed with the same color without any difference.

상기한 방법에 의하여 견직물의 표면에 정련제 조성물의 처리하고자 하는 경우 본발명의 조성물을 견직물에 직접 처리할 수도 있으나, 견직물 자체의 계면활성도를 향상시키고 알카리 분위기를 미리 조성하여 정련제 처리에 의한 세리신 분해 효과를 더욱 용이하게 할 수 있도록 하기 위하여 상기 정련제 조성물의 처리전에 견직물을 모노겐 0.1 내지 0.2%와 중탄산나트륨 2.5 내지 3.5중량% 및 비누 9 내지 11중량%가 용해된 수용액에 약 5 내지 30분간 침지시킨 후 건조 및 수세하는 방법으로 전처리하여 주는 것이 보다 바람직하다.In the case of treating the refiner composition on the surface of the silk fabric by the above-described method, the composition of the present invention may be treated directly on the silk fabric, but the sericin decomposition effect by the refiner treatment is improved by improving the surface activity of the silk fabric itself and forming an alkaline atmosphere in advance. To further facilitate the treatment, the silk fabric was immersed in an aqueous solution in which 0.1 to 0.2% of monogen, 2.5 to 3.5% by weight of sodium bicarbonate, and 9 to 11% by weight of soap were dissolved for about 5 to 30 minutes before treatment of the refiner composition. It is more preferable to pretreat by the method of drying and washing with water afterwards.

이하 본발명을 하기의 실시예 및 비교예에 의하여 보다 상세히 설명하기로 한다.Hereinafter, the present invention will be described in more detail with reference to the following Examples and Comparative Examples.

〈정련제 조성물 제조 실시예1〉<Refining Example 1 of Refining Agent Composition>

노보노디스크(Novor Nordisk)사에서 제조된 디거밍(degumming)용 단백질(세리신)분해효소(상품명:알카라아제) 3kg과 중탄산나트륨 200g과 요소 1kg과 합성호료 1kg과 글리세린 500g과 비누 200g과 모노겐 200g 및 물 4.8리터를 혼합한 후 충분히 교반하여 pH가 약 8인 균질한 상태의 정련제 조성물을 제조하였다.3 kg of degumming protein (sericin) degrading enzyme (trade name: Alkalase) manufactured by Novor Nordisk, 200 g of sodium bicarbonate, 1 kg of urea, 1 kg of synthetic paste, 500 g of glycerin, 200 g of soap, and mono After mixing 200 g of gen and 4.8 liters of water, the mixture was sufficiently stirred to prepare a homogeneous refiner composition having a pH of about 8.

〈정련제 조성물 제조 실시예2〉<Refining agent composition production example 2>

노보노디스크(Novor Nordisk)사에서 제조된 디거밍(degumming)용 단백질(세리신)분해효소(상품명:알카라아제) 2kg과 중탄산나트륨 200g과 요소 1kg과 합성호료 1kg과 글리세린 500g과 비누 300g 및 물 4.8리터를 혼합한 후 충분히 교반하여 pH가 약 8.2인 균질한 상태의 정련제 조성물을 제조하였다.2 kg of degumming protein (sericin) degrading enzyme (trade name: Alkalase) manufactured by Novor Nordisk, 200 g of sodium bicarbonate, 1 kg of urea, 1 kg of synthetic paste, 500 g of glycerin, 300 g of soap, and water After mixing 4.8 liters, the mixture was sufficiently stirred to prepare a homogeneous refiner composition having a pH of about 8.2.

〈정련제 조성물 제조 실시예3〉<Refining Example 3 for Refining Agent Composition>

노보노디스크(Novor Nordisk)사에서 제조된 디거밍(degumming)용 단백질(세리신)분해효소(상품명:알카라아제) 4kg과 중탄산나트륨 250g과 요소 1kg과 합성호료 1kg과 글리세린 600g과 모노겐 300g 및 물 4.8리터를 혼합한 후 충분히 교반하여 pH가 약 8.9인 균질한 상태의 정련제 조성물을 제조하였다.4 kg of degumming protein (sericin) degrading enzyme (trade name: Alkalase) manufactured by Novor Nordisk, 250 g of sodium bicarbonate, 1 kg of urea, 1 kg of synthetic paste, 600 g of glycerin, 300 g of monogen, After mixing 4.8 liters of water, the mixture was sufficiently stirred to prepare a homogeneous refiner composition having a pH of about 8.9.

〈견직물 무늬형성 실시예1〉<Woven Fabric Patterning Example 1>

가로, 세로의 길이가 각각 50cm로 제단된 견직물에 기하학적 무늬로 현상된 실크스크린 프레임을 부착한 상태에서 상기 정련제 제조 실시예1로부터 제조된 정련제 조성물을 약 50±2℃로 승온시킨 상태로 처리한 후 약 30분동안 유지시켰다.The refiner composition prepared in Example 1 of the refining agent manufacturing process was heated at a temperature of about 50 ± 2 ° C. in a state in which a silkscreen frame developed with a geometric pattern was attached to a silk fabric fabricated at 50 cm in length and width, respectively. It was then maintained for about 30 minutes.

계속하여 상기 처리된 견직물을 건조시킨 후 약 45℃의 물로 수세하고 건조한 다음 녹색의 반응성 염료가 분산된 염색조에서 침염시켰다.The treated silk was then dried, washed with water at about 45 [deg.] C. and dried and then dyed in a dye bath in which the green reactive dye was dispersed.

〈견직물 무늬형성 실시예2〉<Woven Fabric Patterning Example 2>

상기 견직물의 무늬형성 실시예1과 동일하게 실시하되, 정련제 조성물로써 상기 정련제 조성물 제조 실시예2로부터 사용된 조성물을 사용하였다.The patterning of the silk fabric was carried out in the same manner as in Example 1, but the composition used in the refiner composition preparation Example 2 was used as the refiner composition.

〈견직물 무늬형성 실시예3〉<Woven Fabric Patterning Example 3>

상기 견직물의 무늬형성 실시예1과 동일하게 실시하되, 정련제 조성물로써 상기 정련제 조성물 제조 실시예3으로부터 사용된 조성물을 사용하였다.The patterning of the silk fabric was carried out in the same manner as in Example 1, but the composition used in the refiner composition preparation Example 3 was used as the refiner composition.

〈견직물 무늬형성 실시예4〉<Woven Fabric Patterning Example 4>

상기 견직물의 무늬형성 실시예1과 동일하게 실시하되, 상기 견직물을 모노겐0.1%와 중탄산나트륨 3% 및 비누10%로된 수용액에 약 30분 동안 침지시킨 후 수세 및 건조시켜 사용하였다.The silk fabric was formed in the same manner as in Example 1, but the silk fabric was immersed in an aqueous solution of monogen 0.1%, sodium bicarbonate 3%, and soap 10% for about 30 minutes and then washed with water and dried.

〈견직물 무늬형성 실시예5〉<Woven Fabric Patterning Example 5>

상기 견직물의 무늬형성 실시예2와 동일하게 실시하되, 상기 견직물을 모노겐0.1%와 중탄산나트륨 3% 및 비누10%로 된 수용액에 약 30분 동안 침지시킨 후 수세 및 건조시켜 사용하였다.The silk fabric was formed in the same manner as in Example 2 except that the silk fabric was immersed in an aqueous solution of monogen 0.1%, sodium bicarbonate 3%, and soap 10% for about 30 minutes and then washed with water and dried.

〈견직물 무늬형성 실시예6〉<Woven Fabric Patterning Example 6>

상기 견직물의 무늬형성 실시예3과 동일하게 실시하되, 상기 견직물을 모노겐0.1%와 중탄산나트륨 3% 및 비누10%로 된 수용액에 약 30분 동안 침지시킨 후 수세 및 건조시켜 사용하였다.The silk fabric was formed in the same manner as in Example 3, except that the silk fabric was immersed in an aqueous solution of monogen 0.1%, sodium bicarbonate 3%, and soap 10% for about 30 minutes, and then washed with water and dried.

상기 견직물 무늬형성 실시예1 내지 6으로부터 제조된 견직물을 관찰한 결과, 본발명의 정련제로 처리한 무늬부분은 연두색으로 염색되었으며, 처리되지 않은 이외의 부분은 염료의 색과 동일한 짙은 녹색으로 염색되어 미려한 무늬가 형성되어 있음을 확인할 수 있었으며, 무늬의 경계면에 일체의 번짐현상이 발생하지 않았을 뿐만 아니라, 종래의 날염 또는 실크스크린 염색방법에서 발견할 수 있는 견직물의 양면의 색상 차이를 전혀 발견할 수 없었다.As a result of observing the silk fabrics prepared from the silk fabric pattern forming examples 1 to 6, the patterned portion treated with the refiner of the present invention was dyed to a light green color, and the portions other than the untreated portion were dyed to the same dark green color as the color of the dye. It was confirmed that a beautiful pattern was formed, and there was not any bleeding phenomenon at the boundary of the pattern, and it was possible to find any color difference between both sides of the silk fabric which can be found in the conventional printing or silk screen dyeing method. There was no.

이상 설명한 바와 같이, 본발명은 견직물에의 무늬형성을 위한 염색시 견사의 표피부에 형성된 특정 단백질을 선택적으로 분해시키는 작용을 나타내는 정련제를 견직물의 표면에 처리하여 주는 신규한 무늬형성방법으로써, 침염시 이종 단백질간의 염색도의 차이에 의하여 원하는 무늬를 형성시킬 수 있어 견직물 양면의 균일한 염색 색상을 나타낼 수 있도록 한 견직물의 정련처리제 조성물 및 그를 이용한 견직물의 무늬형성방법을 제공하는 유용한 발명인 것이다.As described above, the present invention is a novel patterning method for treating the surface of silk fabrics with a refining agent that selectively decomposes a specific protein formed on the skin of the silk during dyeing for the formation of the silk fabric. It is a useful invention to provide a refining agent composition of the silk fabric and a method of forming the silk fabric using the same, which can form a desired pattern due to the difference in the degree of dyeing between different proteins.

Claims (3)

정련제 20 내지 30중량%와 중탄산나트륨 2 내지 3중량%와 요소 10 내지 20중량%와 호료 10 내지 20중량%와 글리세린 4 내지 6중량%와 계면활성제로서 비누 또는 모노겐의 단독 또는 혼합물 2 내지 4중량%와 물 7 내지 48중량%로 이루어짐을 특징으로 하는 견직물의 정련처리제 조성물.20 to 30% by weight of refiner, 2 to 3% by weight of sodium bicarbonate, 10 to 20% by weight of urea, 10 to 20% by weight of fertilizer, 4 to 6% by weight of glycerin and soap or monogen alone or mixture 2-4 as surfactant Refinement composition of the silk fabric, characterized in that consisting of 7% by weight to 48% by weight of water. 정련제 20 내지 30중량%와 중탄산나트륨 2 내지 3중량%와 요소 10 내지 20중량%와 호료 10 내지 20중량%와 글리세린 4 내지 6중량%와 계면활성제로써 비누 또는 모노겐의 단독 또는 혼합물 2 내지 4중량%와 물 7 내지 48중량%로 이루어진 정련제 조성물을 30 내지 70℃온도 및 pH 7 내지 9의 조건하에서 견직물에 원하는 무늬로 처리한 다음 건조 및 수세 후 염색시킴을 특징으로 하는 견직물의 무늬형성방법.20 to 30% by weight of refiner, 2 to 3% by weight of sodium bicarbonate, 10 to 20% by weight of urea, 10 to 20% by weight of fertilizer, 4 to 6% by weight of glycerin, and sole or mixture of soap or monogen 2 to 4 as surfactant The patterning method of the silk fabric, characterized in that the refining composition consisting of 7% to 48% by weight of water and treated with a desired pattern on the silk fabric under the conditions of 30 to 70 ℃ temperature and pH 7-9, and then dyed after drying and washing with water. . 제2항에 있어서, 상기 견직물을 모노겐 0.1 내지 0.2%와 중탄산나트륨 2.5 내지 3.5중량% 및 비누 9 내지 11중량%가 용해된 수용액에 5 내지 30분 동안 침지시킨 후 건조 수세한 것임을 특징으로 하는 견직물의 무늬형성방법.The method of claim 2, wherein the silk fabric is immersed in an aqueous solution in which 0.1 to 0.2% of monogen, 2.5 to 3.5% by weight of sodium bicarbonate and 9 to 11% by weight of soap is dissolved for 5 to 30 minutes, and then washed with dry water. Pattern formation method of silk fabric.
KR1019980019690A 1998-05-29 1998-05-29 Refinement treatment composition of silk fabric and pattern formation method of silk fabric using the same KR100259392B1 (en)

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KR100397654B1 (en) * 2000-07-18 2003-09-13 박건용 Dyeing Method for Silk Fabrics
EP2759644A4 (en) * 2011-09-22 2015-11-11 Sei Tanaka Agent for lowering vapor pressure of water, method for preventing seal breakage in drain trap using agent for lowering vapor pressure of water, antifreezing agent for water, method for preventing seal breakage in drain trap using antifreezing agent for water, and antifreezing agent for plant

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KR20040022903A (en) * 2002-09-10 2004-03-18 에스케이케미칼주식회사 Procedure of scouring for silk textiles

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100397654B1 (en) * 2000-07-18 2003-09-13 박건용 Dyeing Method for Silk Fabrics
EP2759644A4 (en) * 2011-09-22 2015-11-11 Sei Tanaka Agent for lowering vapor pressure of water, method for preventing seal breakage in drain trap using agent for lowering vapor pressure of water, antifreezing agent for water, method for preventing seal breakage in drain trap using antifreezing agent for water, and antifreezing agent for plant
US9353510B2 (en) 2011-09-22 2016-05-31 Tetsuya Shibano Vapor pressure lowering agent for seal water in drain trap, method for preventing seal breakage in drain trap by using vapor pressure lowering agent for seal water in drain trap, antifreezing agent for water, and method for preventing seal breakage in drain trap by using antifreezing agent for water

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