KR100201831B1 - Paint composition for using colorful glass - Google Patents
Paint composition for using colorful glassInfo
- Publication number
- KR100201831B1 KR100201831B1 KR1019960033369A KR19960033369A KR100201831B1 KR 100201831 B1 KR100201831 B1 KR 100201831B1 KR 1019960033369 A KR1019960033369 A KR 1019960033369A KR 19960033369 A KR19960033369 A KR 19960033369A KR 100201831 B1 KR100201831 B1 KR 100201831B1
- Authority
- KR
- South Korea
- Prior art keywords
- glass
- oxide
- pattern
- paint
- treatment
- Prior art date
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10165—Functional features of the laminated safety glass or glazing
- B32B17/10247—Laminated safety glass or glazing containing decorations or patterns for aesthetic reasons
- B32B17/10256—Laminated safety glass or glazing containing decorations or patterns for aesthetic reasons created by printing techniques
- B32B17/10266—Laminated safety glass or glazing containing decorations or patterns for aesthetic reasons created by printing techniques on glass pane
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
- B32B17/10128—Treatment of at least one glass sheet
- B32B17/10155—Edge treatment or chamfering
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10165—Functional features of the laminated safety glass or glazing
- B32B17/10339—Specific parts of the laminated safety glass or glazing being colored or tinted
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/008—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/02—Surface treatment of glass, not in the form of fibres or filaments, by coating with glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
- C03C17/23—Oxides
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Composite Materials (AREA)
- Surface Treatment Of Glass (AREA)
- Glass Compositions (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
본 발명은 유리면에 임의의 무늬를 성형하는 무늬유리의 제조방법에 관한 것으로, 유리면에 이산화규소와 산화납 및 산화붕소와 산화지르코늄을 주성분으로 한 페인트상의 인쇄잉크로써 무늬를 실크 스크린 인쇄한 다음 700℃ 열처리 강화로 내에서 열처리 및 강화처리하여 인쇄피막층을 유리층과 일체로 접착시켜서 제조한다.The present invention relates to a method of manufacturing a patterned glass for shaping an arbitrary pattern on a glass surface, wherein the pattern is silk-screen printed using a printing ink on the glass surface mainly containing silicon dioxide, lead oxide, boron oxide and zirconium oxide, and then 700 It is manufactured by heat-treating and reinforcing treatment in a heat-treatment furnace in which the printing coating layer is integrally bonded with the glass layer.
강산에 의한 부식방법이 아니라 인쇄피막층을 덧붙이는 방식이므로 불화수소산과 같은 공해물질이 전혀 사용되지 아니하여 환경보호에 크게 기여하고 무늬면이 오손되지 아니하고 깨끗이 유지될 수 있으며 유리의 강도를 크게 강화시킬 수 있는 효과가 있다.It is not a corrosion method by strong acid but a printing coating layer. Therefore, no pollutants such as hydrofluoric acid are used, which greatly contributes to environmental protection, can be kept clean without being damaged, and can greatly strengthen the strength of glass. It has an effect.
Description
[발명의 명칭][Name of invention]
무늬유리의 제조방법Manufacturing Method of Patterned Glass
[발명의 상세한 설명]Detailed description of the invention
[발명의 목적][Purpose of invention]
[발명이 속하는 기술분야 및 그 분야의 종래기술][Technical field to which the invention belongs and the prior art in that field]
본 발명은 아파트 주택 등의 중문, 방창유리, 현관고정창, 드레스룸창과 사무실, 상가등의 인테리어용 유리에 사용함으로써, 건축물 내부의 미적감각을 살리고, 개성에 맞는 다양한 디자인으로 아름다운 실내공간을 창조하는데 필요한 무늬유리 즉, 유리의 표면에 줄무늬나 꽃무늬 또는 완자무늬, 빗살무늬, 정사각형 등의 기하학적무늬, 세살무늬, 새나 기타의 동물무늬, 다이아몬드무늬, 기타 투시방지용 가리개무늬등 원하는 임의의 무늬를 형성한 무늬유리의 제조방법에 관한 것이다.The present invention is used in interior doors such as the middle door, window glass, front door fixing window, dressing room window and office, shopping mall of apartment houses, etc., utilizing the aesthetic sense of the interior of the building, create a beautiful interior space with various designs to suit the individuality Glass pattern, that is, the surface of the glass, such as stripes, floral or ball, pattern, comb, geometric, such as square, three-year-old pattern, bird or other animal pattern, diamond pattern, other blinding pattern It is related with the manufacturing method of the formed patterned glass.
종래 이와같은 용도의 무늬유리는 대별하여 다음의 2가지 방법에 의하여 제조하였는바, 그 첫째는 샌드블라스팅에 의한 방법이고 그 둘째는 화학에칭 방법이다.Conventionally, the patterned glass for such use was manufactured by the following two methods, firstly by sandblasting and secondly by chemical etching.
유리의 무늬를 성형할 부분을 고압으로 분사되는 모래로 타격하여 미세한 요철면을 형성함으로써 필요한 무늬를 성형하는 샌드블라스팅방법은 유리면의 무늬가 성형되지 아니하는 부분을 보호필름으로 가리고 원하는 무늬 부분만이 모래의 타격에 노출되도록 하는 과정을 거치는 것이므로 보호필름에서 무늬부에 해당하는 부분을 수작업 등으로 오려내는 작업을 선행하여야 함에 따라 무늬성형 공정이 복잡하고 정교한 무늬의 형성이 불가능하여 제품생산성이 크게 떨어지고 성형된 무늬에 있어서도 요철면이 비교적 거칠어 무늬면이 매끄럽지 못하고 먼지등의 이물질이 부착되기 쉬우므로 상품가치가 떨어지는 문제점이 있었다.The sandblasting method of forming the required pattern by hitting the part to be formed with the glass pattern with sand sprayed at high pressure to form a fine uneven surface is to cover the part where the pattern of the glass surface is not formed with a protective film and only the desired pattern part Since the process of exposing to the impact of sand is required to cut out the portion of the protective part by hand, etc. in the protective film, the pattern forming process is complicated and it is impossible to form a precise pattern. Even in the molded pattern, the uneven surface is relatively rough, so that the surface of the pattern is not smooth and foreign matters such as dust are easily attached.
그리고, 용제중에 불화 수소산(HF)을 함유하는 잉크로써 유리면에 필요한 무늬를 실크스크린 인쇄하여 불화수소산으로 유리면을 부식시켜서 요구되는 무늬를 얻는 화학에칭방법은 실크스크린 인쇄방법을 사용함에 따라 정교한 무늬의 형성이 가능하고 생산성을 크게 향상시킬 수 있으며 무늬부분을 비교적 매끄럽게 형성할 수 있어서 상품가치를 제고시킬 수 있는 장점은 있는 반면에, 인쇄부식완료후 유리면에는 강산으로서 1급환경 오염물질인 불화수소산이 그대로 남아있어 사람과 접촉하면 산에 의한 피해를 입으므로 인체와의 접촉방지를 위하여 완성제품의 화학 에칭부위를 반드시 물로 세척처리하여 주어야 하였고, 이에따라 무늬유리의 대량생산이 강산이 섞인 산업폐수가 대량으로 발생하여 공해문제가 대두되고, 폐수처리비용의 과중한 부담으로 영세업자가 그대로 방류시키는 문제점이 있었다.In addition, the chemical etching method of silk-printing the necessary pattern on the glass surface with the ink containing hydrofluoric acid (HF) in the solvent to corrode the glass surface with hydrofluoric acid to obtain the required pattern has a sophisticated pattern according to the silk screen printing method. It can be formed and productivity can be greatly improved, and the pattern part can be formed relatively smoothly, which has the advantage of improving product value.However, hydrofluoric acid, which is a first class environmental pollutant, is a strong acid on the glass surface after printing is completed. Because it remains as it is, it is damaged by acid when it comes into contact with humans. To prevent contact with the human body, the chemical etching part of the finished product must be washed with water, and accordingly, the mass production of patterned glass is mixed with strong acid. Pollution problems, and heavy costs of wastewater treatment costs There was a small problem with that contractor still stocked.
또, 이와같은 부식방법은 부식된 부분에서 결과적으로 부식되어 없어진량 만큼의 유리두께가 얇아져 강도가 크게 떨어지는 결점도 있었다.In addition, this method of corrosion also had the drawback that the thickness of the glass was reduced as much as the amount of the resulting corrosion in the corroded portion.
그 뿐만아니라, 종래 샌드블라스팅방법이나 화학 에칭방법 모두에 있어서는 또한 모래를 고압으로 분사시키는데에서 발생하는 분진이나 인체에 유독한 산처리작업에 따른 인체에 유해한 작업환경에서 생산 작업이 이루어지므로 작업자의 건강을 크게 위협하고, 열악한 작업환경에서 기인한 생산성도 저조한 문제점이 나타났다.In addition, both conventional sandblasting methods and chemical etching methods also produce workers in a work environment that is harmful to humans due to dust generated from sand spraying at high pressure or acid treatment work that is toxic to humans. And the productivity was low due to the poor working environment.
[발명이 이루고자 하는 기술적 과제][Technical problem to be achieved]
본 발명은 전술의 종래 문제점을 개선한 새로운 방식의 무늬유리의 제조방법을 제공하기 위한 것이다.The present invention is to provide a method of manufacturing a patterned glass of a novel method to improve the above-mentioned conventional problems.
이와같은 목적을 가지는 본 발명은 불화수소산으로 유리면을 부식시키는 방법과는 전혀 상이한 방법 즉, 인쇄잉크가 인쇄된 유리면을 부식시키지 아니하고, 이산화규소와 산화납 및 산화붕소를 주성분으로 한 인쇄잉크의 인쇄피막층을 열처리 및 강화처리하여 유리와 페인트를 반영구적으로 접착시킴으로써 페인트가 박리되지 아니하여 정교하고도 균일한 무늬성형이 가능함은 물론 유리의 강도를 크게 향상시키며 제조원가가 저렴하고, 제조과정에서 불화수소산을 사용하지 아니하여 공해가 발생하지 아니하며 제조작업 환경을 크게 개선시킴으로써 본 발명의 소기의 목적을 달성할 수 있도록 구성한 것인데, 이하, 본 발명 무늬유리의 제조방법을 구체적으로 설명하면 다음과 같다.The present invention having the above object is completely different from the method of corroding the glass surface with hydrofluoric acid, that is, the printing ink does not corrode the printed glass surface and prints the printing ink mainly composed of silicon dioxide, lead oxide and boron oxide. By heat-treating and reinforcing the coating layer to semi-permanently bond the glass and paint, the paint is not peeled off, so it is possible to form a precise and uniform pattern. It also greatly improves the strength of the glass, and the manufacturing cost is low. Pollution does not occur because it is not used, and it is configured to achieve the desired purpose of the present invention by greatly improving the manufacturing working environment. Hereinafter, the manufacturing method of the patterned glass of the present invention will be described in detail.
[발명의 구성 및 작용][Configuration and Function of Invention]
본 발명 무늬유리의 제조방법에 있어서도, 큰 원판을 규격에 맞게 절단하는 원판재단공정과, 강화처리시 반드시 필요한 공정인 유리의 모서리 부분을 연마하는 면취공정 및, 면취한 유리를 세척하고 건조시키는 세척공정, 그리고, 유리표면에 페인트 형태의 잉크로 원하는 각종 무늬를 실크스크린 인쇄하는 인쇄공정을 거쳐서 무늬유리를 제조하는 것은 화학 에칭방법과 비슷하지만, 본 발명 제조방법에서 특이한 것은 유리의 인쇄면을 에칭처리하는 것이 아니라 이산화규소(SiO2)와 산화납(PbO) 및 산화붕소(B2O3)를 주성분으로 한 플럭스(FLUX)에 산화지르코늄(ZrO2)등의 착색제를 혼합하여 테르펜 알코올이나 에틸셀룰로오스계 유기용제로 배합조성한 인쇄잉크를 사용하여 요구되는 무늬를 실크스크린 인쇄한 후 인쇄피막층을 열처리 및 강화처리하여 유리와 페인트를 반영구적으로 결합시킴으로써 페인트가 유리층과 일체화상태로 유리화되고 박리되지 아니하도록 함과 함께 강화처리에 의하여 유리의 강도가 3배 이상으로 강화되도록 무늬유리를 제조하는 것이다.Also in the manufacturing method of the patterned glass of the present invention, a disc cutting process of cutting a large disc to a standard, a chamfering process of polishing a corner portion of the glass which is an essential step for reinforcing treatment, and a washing to wash and dry the chamfered glass Although the manufacturing of the patterned glass is similar to the chemical etching method through the process and the printing process of silkscreen printing the desired pattern on the glass surface with ink in the form of paint, the specific thing in the manufacturing method of the present invention is etching the printing surface of the glass. Instead of treating, terpene alcohol by mixing a colorant such as zirconium oxide (ZrO 2 ) into a flux (FLUX) based on silicon dioxide (SiO 2 ), lead oxide (P b O) and boron oxide (B 2 O 3 ) Silkscreen printing the required pattern using a printing ink formulated with an organic cellulose-based organic solvent, and then heat-treat and reinforce the printing film layer. By semi-permanently bonding the glass and the paint, the glass is integrated into the glass layer so that the glass is not vitrified and peeled off, and the patterned glass is prepared to be strengthened by three times or more by the strengthening treatment.
본 발명에 의하면 본 발명에 사용되는 인쇄잉크의 조성예는 다음과 같다.According to the present invention, a composition example of the printing ink used in the present invention is as follows.
또 본 발명에 의하면 인쇄잉크의 주성분인 플럭스의 조성예는 다음과 같다.Moreover, according to this invention, the composition example of the flux which is a main component of a printing ink is as follows.
또한, 본 발명에 의한 인쇄잉크중의 착색제(COLOR STAIN)의 조성예는 다음과 같다.In addition, the composition example of the coloring agent (COLOR STAIN) in the printing ink by this invention is as follows.
그리고, 본 발명에 의하면 유기용제의 조성예는 다음과 같다.And according to this invention, the composition example of the organic solvent is as follows.
위의 조성예(1)과 같은 조성비로 구성된 페인트상의 인쇄잉크를 사용하여 유리의 가공면에 원하는 무늬를 실크스크린 인쇄한 다음 인쇄된 유리를 700℃로 가열되는 열처리 강화로 내에 투입하고 700℃로 가열함과 함께 열처리 강화로 내를 왕복이동시키면서 다수의 노즐로 공기를 불어주면 무늬가 인쇄된 유리표면층에서 압축응력과 인장응력이 발생하여 유리가 보통유리에 비하여 3배이상의 강도로 강화처리됨과 아울러 무늬부를 구성하는 페인트의 인쇄피막층이 유리층과 함께 일체로 유Silk-screen printing the desired pattern on the processed surface of the glass using the printing ink of the paint composition composed of the composition ratio as the composition example (1) above, and then put the printed glass into the heat treatment tempering furnace heated to 700 ° C and then to 700 ° C. Blowing air through a number of nozzles while reciprocating through the heat treatment reinforcement furnace while heating, compressive and tensile stresses are generated in the patterned glass surface layer, and the glass is strengthened to three times stronger than ordinary glass. The print coating layer of the paint constituting the pattern portion is integral with the glass layer.
[실시예]EXAMPLE
소정크기로 재단하여 모서리부분을 면취하고 세척건조시킨 유리의 표면에 산화납(PbO) 12.75g, 이산화규소(SiO2) 47.6g, 산화붕소(B2O) 12.1125g, 산화나트륨(Na2O) 4.25g, 산화리튬(Li2O3) 2.3375g, 산화칼륨(K2O) 0.85g, 산화알루미늄(Aℓ2O3) 5.1g의 배합비로 된 전체 85g의 플럭스 백색분말에 산화세륨(CeO) 1.5g, 산화지르코늄(ZrO2) 8.5g의 조성비로 배합된 착색제 10g을 배합하고 1g의 왁스와 테르펜 알코올 3g, 에틸셀룰로오스 1g, 도합 4g의 배합비로 된 유기용제를 혼합하여서 된 페인트상의 인쇄잉크를 사용하여 스크린 인쇄방법으로 요구되는 무늬를 인쇄하였다.12.75 g of lead oxide (P b O), 47.6 g of silicon dioxide (SiO 2 ), 12.1125 g of boron oxide (B 2 O), sodium oxide (Na 2 O) 4.25g, lithium oxide (Li 2 O 3) 2.3375g, potassium oxide (K 2 O) 0.85g, aluminum oxide (Aℓ 2 O 3) cerium oxide in a total proportion of 5.1g to 85g of a white powder flux (CeO) 1.5 g, zirconium oxide (ZrO 2 ) 8.5 g of a colorant blended with a composition ratio of 1 g of wax, terpene alcohol 3 g, ethyl cellulose 1 g, a total of 4 g of organic solvent mixture of 4 g of a paint The printing ink was used to print the pattern required by the screen printing method.
인쇄면이 건조된 무늬유리를 700℃로 가열되는 열처리 강화로에 투입하여 700℃로 가열함과 함께 좌우로 강화로 내를 왕복이동시키면서 다수의 노즐로 공기를 불어주어 유리가 강화처리되면서 무늬부의 페인트 인쇄피막층이 유리층과 일체로 유리화되어 결합되게 함으로써 원하는 무늬유리를 제조하였다.The patterned glass with the printed surface is put into the heat treatment reinforcement furnace heated to 700 ℃ and heated to 700 ℃ and the air is blown through a number of nozzles while reciprocating the reinforcement furnace from side to side. The desired patterned glass was prepared by allowing the paint print coating layer to be vitrified and bonded integrally with the glass layer.
제조된 무늬유리는 인쇄피막층이 유리층과 함께 일체화 결합되어 있어서 피막이 박리되거나 먼지등에 오염되는 일이 없었고, 강산에 의한 부식처리방법을 사용하지 아니함에 따라 공해물질이 전혀 발생하지 아니할 뿐만 아니라 일반유리보다 강도가 3배이상 강화되는 이점을 나타냈다.The patterned glass is printed film layer integrated with the glass layer so that the film is not peeled off or contaminated with dust. Since the corrosion treatment method by strong acid is not used, it does not generate any pollutants. It showed the advantage of more than three times the strength.
Claims (4)
Priority Applications (1)
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KR1019960033369A KR100201831B1 (en) | 1996-08-12 | 1996-08-12 | Paint composition for using colorful glass |
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KR1019960033369A KR100201831B1 (en) | 1996-08-12 | 1996-08-12 | Paint composition for using colorful glass |
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KR100201831B1 true KR100201831B1 (en) | 1999-06-15 |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100655151B1 (en) | 2005-11-28 | 2006-12-08 | 김동윤 | Manufacturing method of shaped glass and glass tray thereof |
KR101136043B1 (en) | 2010-02-02 | 2012-04-18 | (주)에스알 아이텍 | A Coating Method for prevention fingerprint of tempered glass |
Families Citing this family (2)
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KR20040042492A (en) * | 2002-11-14 | 2004-05-20 | 안명희 | Transparency design manufacturing process of low reflection-plate glase |
KR100698767B1 (en) * | 2004-06-09 | 2007-03-26 | 금보이엔지 주식회사 | Process for preparing Ornamental Glass Panels |
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1996
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100655151B1 (en) | 2005-11-28 | 2006-12-08 | 김동윤 | Manufacturing method of shaped glass and glass tray thereof |
KR101136043B1 (en) | 2010-02-02 | 2012-04-18 | (주)에스알 아이텍 | A Coating Method for prevention fingerprint of tempered glass |
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KR980001893A (en) | 1998-03-30 |
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