KR0180685B1 - Cosmetic composition for skin cleansing - Google Patents

Cosmetic composition for skin cleansing Download PDF

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KR0180685B1
KR0180685B1 KR1019950047932A KR19950047932A KR0180685B1 KR 0180685 B1 KR0180685 B1 KR 0180685B1 KR 1019950047932 A KR1019950047932 A KR 1019950047932A KR 19950047932 A KR19950047932 A KR 19950047932A KR 0180685 B1 KR0180685 B1 KR 0180685B1
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oil
phase
skin cleansing
microemulsion
weight
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KR1019950047932A
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KR970032842A (en
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김기선
이성준
강태준
윤명석
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성재갑
주식회사엘지화학
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04Dispersions; Emulsions
    • A61K8/06Emulsions
    • A61K8/068Microemulsions
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/14Preparations for removing make-up

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  • Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
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  • Cosmetics (AREA)
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Abstract

본 발명은 물을 전혀 사용하지 않은 비수유화물인 오일상/다가알콜상의 분산상태를 갖는 마이크로에멀젼형 피부세정용 화장료 조성물에 관한 것이다.The present invention relates to a microemulsion-type skin cleansing cosmetic composition having a dispersed state of an oil phase / polyalcohol phase that is a non-hydrated water that does not use any water.

본 발명의 피부세정용 화장료 조성물은 오일상은 40~90중량부와 계면활성제상 5~30중량부 및 다가알콜상 5~30중량부로 구성되며, 경시안정성, 피부세정효과 및 헹굼성이 매우 우수하다.The cosmetic composition for skin cleansing according to the present invention comprises an oil phase of 40 to 90 parts by weight, a surfactant phase of 5 to 30 parts by weight, and a polyhydric alcohol phase of 5 to 30 parts by weight, and are excellent in aging stability, skin cleansing effect and rinsing property. .

Description

[발명의 명칭][Name of invention]

피부세정용 화장료 조성물Cosmetic composition for skin cleansing

[발명의 상세한 설명]Detailed description of the invention

본 발명은 오일상/다가알콜상(이하, O/P라 한다)의 분산상태를 갖는 마이크로에멀젼형 피부세정용 화장료 조성물에 관한 것으로서, 더욱 상세하게는 보존 안정성, 세정성, 헹굼성이 우수한 O/P 마이크로에멀젼형 피부세정욜 화장료 조성물에 관한 것이다.The present invention relates to a microemulsion-type skin cleaning cosmetic composition having a dispersed state of oil phase / polyalcohol phase (hereinafter referred to as O / P), more specifically O excellent in storage stability, detergency, and rinsability / P relates to a microemulsion-type skin cleansing cosmetic composition.

종래부터 색조화장이나 각종 피부오염을 제거하기 위하여, 크림류, 로션류, 화장수류, 폼클렌징비누류, 수성젤류 및 유성마이크로에멀젼젤류 등 다양한 피부 세정용 화장료가 사용되어 왔다. 특히 최근 색조 화장의 증가와 색조화장료의 내수성 강화로 더욱 강력한 피부 세정용 화장료가 요구되고 있다. 이러한 피부 세정용 화장료의 품질 요건으로서는 피부오염의 세정력이 우수하여야 하며, 피부 자극이 적고 세정후에 잔여감없이 산뜻해야 한다. 이러한 품질요건을 충족시키기 위한 연구가 진행되고 있으며, 그중 유성오염물질 제거능력이 뛰어나 색조화장품 제거가 유리한 크림류, 유성마이크로에멀젼젤류의 연구가 활발히 진행되고 있다. 이들 크림류나 유성마이크로에멀젼젤류는 오일을 다량 함유하고 유성오염 물질을 쉽게 용해시킬 수 있다는 장점을 이용한 것이다. 그러나 크림류는 계면활성제가 소량 사용되어 유성젤보다 세정성이 떨어지고, 특히 물헹굼성이 약해 티슈로 제거하며 그로 인해 세정후에도 유성감이 남아 산뜻하지 못한 결점을 갖고 있다.Conventionally, various skin cleaning cosmetics, such as creams, lotions, lotions, foam cleansing soaps, aqueous gels and oil-based microemulsion gels, have been used to remove color cosmetics and various skin contaminations. In particular, more powerful skin cleansing cosmetics are required due to an increase in color cosmetics and water resistance of color cosmetics. As a quality requirement of the cosmetics for skin cleansing, the skin cleansing power should be excellent, the skin irritation should be low, and the cleansing after cleansing should be fresh. In order to satisfy these quality requirements, research is being conducted, and among them, researches on creams and oil-based microemulsion gels which are excellent in removing oily pollutants and advantageous in removing color cosmetics are being actively conducted. These creams or oil-based microemulsion gels utilize the advantage of containing a large amount of oil and easily dissolving oily contaminants. However, since creams are used in a small amount of surfactants, they are inferior to oil gels, and in particular, water rinsing properties are weak, so they are removed with tissues.

이러한 결점을 극복하기 위하여 최근 유성마이크로에멀젼젤류가 활발히 연구되고 있고 상품도 개발되고 있다. 그에 대한 연구로는 일본 특허 193426, 일본 특허 2129110, 일본 특허 92-062288, 일본특허 274799등 여러 가지가 있다. 이들 유성마이크로에멀젼젤류는 다량의 오일, 계면활성제 및 물로 구성되어 세정성과 헹굼성이 우수하나 보존 또는 사용시 물이 증발하여 전상(phase inversion)되고, 그로 인해 쉽게 마이크로에멀젼젤이 파괴되는 보존안정성에 문제점을 안고 있다.In order to overcome these drawbacks, oil-based microemulsion gels have been actively studied and products have been developed recently. There are various studies on Japanese Patent No. 193426, Japanese Patent 2129110, Japanese Patent 92-062288, Japanese Patent 274799, and the like. These oily microemulsion gels are composed of a large amount of oils, surfactants and water, so they are excellent in cleaning and rinsing ability, but when they are stored or used, water evaporates, causing phase inversion, which leads to problems of preservation stability in which microemulsion gels are easily destroyed. Is holding.

본 발명자들은 이러한 유성마이크로에멀젼젤의 결점을 극복하기 위하여 예의 연구한 결과, 물을 전혀 사용하지 않는 비수유화물인 O/P 마이크로 에멀젼형 화장료를 완성, 보존안정성은 물론 세정성 및 헹굼성이 우수한 피부세정용 화장료를 만들 수 있었다. 여기서 O/P 마이크로 에멀젼형 화장료란 내상인 오일이 폴리올로 구성되는 외상에 분산된 마이크로유화물로서 입자가 미세하여 투명 또는 반투명의 광학적 특성을 가지며 통상의 보관조건에서 상변화가 없어 안정성이 뛰어난 장점을 갖는다. 또한 오일 및 계면활성제를 충분히 사용할 수 있어 세정력이 뛰어나고 세정 후 물로 헹구면 물이 공급되어 수중유(이하 O/W라 칭한다)형 유화물로 바뀌게 되고 그로 인해 피부중의 유성오염은 물론 수성오염까지 쉽게 제거할 수 있게 된다.The present inventors earnestly researched to overcome the drawbacks of oily microemulsion gel, and as a result, they completed the O / P microemulsion-type cosmetics, which are non-hydrated waters, which do not use water at all. Cleaning cosmetics could be made. Here, O / P microemulsion-type cosmetics are microemulsions in which the oil as the inner phase is dispersed in the outer phase composed of polyols, which have fine particles, which have transparent or translucent optical characteristics, and have excellent stability because there is no phase change under normal storage conditions. Have In addition, the oil and surfactant can be used sufficiently, so it has excellent cleaning power and when washed with water after washing, the water is supplied to change into oil-in-water (hereinafter referred to as O / W) type emulsion, which makes it easy to remove oil pollution in the skin as well as water pollution. You can do it.

이하 본 발명을 상세히 설명한다.Hereinafter, the present invention will be described in detail.

본 발명은 오일상(유성성분) 40~90중량부, 계면활성제상 5~30중량부, 다가알콜상 5~30중량부의 조성을 갖는 O/P 마이크로에멀젼형 화장료 조성물에 관한 것이다. 본 발명에서 오일상으로는 유동파라핀, 스쿠알란, 에스테르유 및 실리콘유 중에서 1종 이상을 최대량으로 사용하였고, 계면활성제성분으로는 비이온계면활성제, 음이온 계면활성제 및 아미노산계 계면활성제 중 1종 이상을 사용하였고, 다가알콜상은 추가로 물을 가하지 않고 OH기가 2개 이상의 탄화수소인 다가알콜을 최대량으로 하고 여기에서 다가알콜로는 글리세린, 1,3-부틸렌글리콜, 프로필렌글리콜, 말티톨, 만니톨, 프로필렌글리콜 중에서 선택된 1종이상을 사용하였다.The present invention relates to an O / P microemulsion cosmetic composition having a composition of 40 to 90 parts by weight of an oil phase (oil component), 5 to 30 parts by weight of a surfactant phase, and 5 to 30 parts by weight of a polyalcoholic phase. In the present invention, in the oil phase, at least one of liquid paraffin, squalane, ester oil, and silicone oil was used in the maximum amount, and at least one of nonionic surfactant, anionic surfactant, and amino acid surfactant was used as the surfactant component. The polyhydric alcohol phase is the maximum amount of polyhydric alcohol having two or more hydrocarbons of OH group without additional water, wherein the polyhydric alcohol is selected from glycerin, 1,3-butylene glycol, propylene glycol, maltitol, mannitol, and propylene glycol. One or more kinds were used.

이하 비교예 및 실시예를 통하여 본 발명을 상세하게 설명한다.Hereinafter, the present invention will be described in detail with reference to comparative examples and examples.

[실시예 1~6 및 비교예 1~2]EXAMPLES 1-6 AND COMPARATIVE EXAMPLES 1-2

표 1의 비교예 및 실시예 중 비교예 1은 통상의 수중유형의 클렌징크림이고, 비교예 2는 물 및 다가알콜의 다가알콜상, 계면활성제, 오일상으로 구성되어지는 마이크로에멀젼형의 젤, 실시예1~6은 비교예2에서 수분이 제거된 O/P 마이크로에멀젼형 화장료이다. 제조방법으로는 통상의 유화방식을 적용하였다. 즉, 유상과 다가알콜상을 각각 75~80℃로 가열하고 다가알콜상에 유상을 서서히 첨가하여 호모믹서를 사용하여 4000rpm~6000rpm으로 3~5분간 교반하여 실온까지 냉각하여 제조하였다.In Comparative Examples and Examples of Table 1, Comparative Example 1 is a conventional oil-in-water cleansing cream, Comparative Example 2 is a microemulsion gel consisting of a polyalcohol phase, a surfactant, and an oil phase of water and a polyalcohol, Examples 1 to 6 are O / P microemulsion cosmetics from which moisture was removed in Comparative Example 2. As a manufacturing method, a conventional emulsification method was applied. That is, the oil phase and the polyhydric alcohol phase were heated to 75 to 80 ° C., respectively, and the oil phase was gradually added to the polyhydric alcohol phase. Then, the mixture was stirred at 4000 rpm to 6000 rpm using a homomixer and cooled to room temperature.

[경시 안정성][Stability over time]

표1의 실시예 1-6과 비교예 1-2에 따라 제조된 제품의 경시안정성을 알아보기 위해, 제품을 10그람 용량의 마개달린 폴리에칠렌 재질의 투명한 튜브에 넣고 실온(25℃), 고온(45℃), 저온(0℃) 및 사이클챔버(Freeze Thaw chamber, 45℃~-10℃, 24시간주기)에 보관하여 관찰한 결과를 표 2에 나타내었다.In order to determine the time-lapse stability of the product prepared according to Example 1-6 and Comparative Example 1-2 of Table 1, the product was placed in a transparent tube of 10 grams of capped polyethylene and room temperature (25 ° C.) and high temperature ( Table 2 shows the observed results in the low temperature (0 ° C.) and the cycle chambers (Freeze Thaw chamber, 45 ° C .-- 10 ° C., 24 hour cycle).

표 2에서 보는 바와 같이, 비교예 1과 수분이 제거된 O/P마이크로에멀젼형의 경시 안정성이 우수한 반면, 비교예 2의 마이크로에멀젼형 젤은 안정성이 떨어지는 것으로 나타났는데, 이는 수분증발에 의한 상전이로 이해 계를 불안전하게 한 것으로 추측된다. 그리고 일반적으로 보존안정성이 뛰어난 수중유형 크림타입 비교예 1에 비해서도 본 발명의 각 실시예들이 대등하게 보존안정성이 우수함을 알수 있다.As shown in Table 2, while Comparative Example 1 and the water-removed O / P microemulsion type was excellent in stability over time, the microemulsion type gel of Comparative Example 2 was found to be inferior in stability, which is phase transition by evaporation of water It is presumed that the system of understanding is unsafe. In addition, it can be seen that each of the embodiments of the present invention has superior storage stability in comparison with the oil-in-water type cream type Comparative Example 1 having excellent storage stability in general.

[피부세정효과][Skin cleansing effect]

표 3은 비교예와 실시예의 제품의 세정효과를 측정하여 그 결과를 나타낸 것이다.Table 3 shows the results of measuring the cleaning effect of the product of the comparative example and the example.

시험방법으로는 성인 남녀 30명을 대상으로 오일케익화운데이션을 각각의 피시험자의 팔하박부 안쪽부분에 4×4cm 넓이에 일정량을 균일하게 도포한 후 각각의 비교예와 실시예의 제품을 일정량 취하여 애플리케이트(applicator)로 일정한 힘과 무게로 50회 왕복후 화장지를 사용하여 일정한 압력으로 2회 눌러 화운데이션을 닦아내고 잔여 화운데이션을 유동파라핀으로 완전히 제거하여 UV분광광도계로 540nm에서 흡광도를 측정하여 검정선과 비교하여 화운데이션양을 측정하였다.As a test method, an oil cake foundation was uniformly applied to the inner part of the lower arm of each subject by applying a certain amount of 4 × 4 cm width to 30 adult men and women, and then a certain amount of the product of each Comparative Example and Example was applied. After reciprocating 50 times with constant force and weight with (applicator), wipe the foundation by pressing it twice with a constant pressure using toilet paper, and remove the remaining foundation completely with liquid paraffin. Measure the absorbance at 540nm with UV spectrophotometer and compare it with the black line The amount was measured.

표 3에서 나타난 바와 같이, 실시예1-6은 보통의 수중유형 크림에 비해 피부세정효과가 우수하게 나타났고, 비슷한 제형인 비교예 2에 비해 대등한 결과를 나타내었다.As shown in Table 3, Example 1-6 showed an excellent skin cleaning effect compared to the ordinary oil-in-water cream, and showed a comparable result compared to Comparative Example 2, which is a similar formulation.

[헹굼성][Rinsing properties]

헹굼성은 20-30대 여성 피시험자를 대상으로 설문평가를 실시하여, 그 결과를 표4에 나타내었다.Rinsing was carried out a questionnaire evaluation for female subjects in their 20s to 30s, the results are shown in Table 4.

시험방법으로는 각 제품에서 일정량의 시료(약 2그람)를 팔 하박부 안쪽에 취해 균일하게 도포하여 3분간 마사지한 후 흐르는 물에 30초간 헹구고 난 후 산뜻함 정도를 비교하였다.As a test method, a certain amount of sample (approximately 2 grams) of each product was taken inside the lower arm of the arm, uniformly applied, massaged for 3 minutes, rinsed with running water for 30 seconds, and then the degree of freshness was compared.

상기 표 4의 평과결과에서 알수 있듯이, 실시예 1-6과 비교예 2는 계면활성제의 양이 상대적으로 적은 비교예 1에 비해 산뜻한 느낌이 우수한 것으로 나타났다.As can be seen from the evaluation results of Table 4, Examples 1-6 and Comparative Example 2 was found to be superior to the fresh feeling compared to Comparative Example 1 where the amount of the surfactant is relatively small.

이상의 실험결과에서 볼 수 있듯이, 본 발명에 의한 O/P 마이크로에멀젼젤은 보존안정성, 세정성, 헹굼성의 모든 측면에서 기존의 수중유형의 크림타입이나 마이크로에멀젼젤 보다 우수함을 알 수 있었다.As can be seen from the above experimental results, it was found that the O / P microemulsion gel according to the present invention is superior to the conventional oil-in-water type cream type or microemulsion gel in all aspects of storage stability, detergency, and rinsability.

Claims (2)

유동파라핀, 스쿠알란, 에스테르유 및 실리콘유에서 선택된 1종 이상을 포함하는 오일상 40~90중량부와 비이온 계면활성제, 음이온 계면활성제 및 아미노산계 계면활성제 중에서 선택된 1종 이상의 계면활성제 5~30중량부 및 추가로 물을 가하지 않고 기가 2개이상의 탄화수소인 다가알콜을 포함하는 다가알콜상 5~30중량부를 함유하여 구성된 마이크로에멀젼형 피부세정용 화장료 조성물.40 to 90 parts by weight of an oil phase including at least one selected from liquid paraffin, squalane, ester oil and silicone oil, and 5 to 30 parts by weight of at least one surfactant selected from nonionic surfactants, anionic surfactants and amino acid surfactants. A microemulsion-type skin cleansing composition comprising 5 to 30 parts by weight of a polyhydric alcohol comprising a polyhydric alcohol having two or more hydrocarbons without adding water. 제1항에 있어서, 다가알콜이 글리세린, 1,3-부틸렌글리콜, 프로필렌글리콜, 말티톨, 만니톨 및 프로필렌글리콜 중에서 선택된 1종 이상을 함유하는 것을 특징으로 하는 마이크로에멀젼형 피부세정용 화장료 조성물.2. The microemulsion type skin cleansing composition according to claim 1, wherein the polyhydric alcohol contains at least one selected from glycerin, 1,3-butylene glycol, propylene glycol, maltitol, mannitol and propylene glycol.
KR1019950047932A 1995-12-08 1995-12-08 Cosmetic composition for skin cleansing KR0180685B1 (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100405870B1 (en) * 2000-10-27 2003-11-15 애경산업(주) Oil-free and surfactant-free oil-powder disperse system and method for stabilizing thereof
KR100522208B1 (en) * 1997-12-26 2006-04-20 주식회사 엘지생활건강 Composition of water soluble cleaning cream
KR20230148515A (en) 2022-04-18 2023-10-25 박노면 Method for manufacturing of natural cosmetic composition

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100481631B1 (en) * 1996-12-28 2005-08-17 주식회사 엘지생활건강 Face wash cosmetic composition
KR100695607B1 (en) * 2001-01-04 2007-03-14 애경산업(주) Cosmetics of water in silicon type for facewashing
KR100519726B1 (en) * 2002-09-19 2005-10-10 이대성 Cleansing composition and cleansing composition manufacturing method

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100522208B1 (en) * 1997-12-26 2006-04-20 주식회사 엘지생활건강 Composition of water soluble cleaning cream
KR100405870B1 (en) * 2000-10-27 2003-11-15 애경산업(주) Oil-free and surfactant-free oil-powder disperse system and method for stabilizing thereof
KR20230148515A (en) 2022-04-18 2023-10-25 박노면 Method for manufacturing of natural cosmetic composition

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