KR0173556B1 - Shell solution and fabrication method thereof - Google Patents
Shell solution and fabrication method thereof Download PDFInfo
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- KR0173556B1 KR0173556B1 KR1019960008296A KR19960008296A KR0173556B1 KR 0173556 B1 KR0173556 B1 KR 0173556B1 KR 1019960008296 A KR1019960008296 A KR 1019960008296A KR 19960008296 A KR19960008296 A KR 19960008296A KR 0173556 B1 KR0173556 B1 KR 0173556B1
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- South Korea
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- shell
- solution
- vinegar
- present
- citric acid
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Links
- 238000000034 method Methods 0.000 title claims abstract description 7
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 39
- 239000007788 liquid Substances 0.000 claims abstract description 23
- 235000021419 vinegar Nutrition 0.000 claims abstract description 22
- 239000000052 vinegar Substances 0.000 claims abstract description 22
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 8
- 239000011707 mineral Substances 0.000 claims abstract description 8
- 229920001661 Chitosan Polymers 0.000 claims description 19
- 238000004090 dissolution Methods 0.000 claims description 3
- 238000005507 spraying Methods 0.000 abstract description 12
- 239000002689 soil Substances 0.000 abstract description 8
- 235000013305 food Nutrition 0.000 abstract description 7
- 238000010411 cooking Methods 0.000 abstract description 5
- 239000000463 material Substances 0.000 abstract description 4
- 238000009372 pisciculture Methods 0.000 abstract description 2
- 235000019688 fish Nutrition 0.000 description 6
- 241000251468 Actinopterygii Species 0.000 description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- 229910052791 calcium Inorganic materials 0.000 description 4
- 239000002440 industrial waste Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 229920002101 Chitin Polymers 0.000 description 3
- 241000206607 Porphyra umbilicalis Species 0.000 description 3
- 201000010099 disease Diseases 0.000 description 3
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 3
- 244000005700 microbiome Species 0.000 description 3
- 101150067361 Aars1 gene Proteins 0.000 description 2
- 241000238876 Acari Species 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical group [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- 241000237502 Ostreidae Species 0.000 description 2
- 244000269722 Thea sinensis Species 0.000 description 2
- 238000009360 aquaculture Methods 0.000 description 2
- 244000144974 aquaculture Species 0.000 description 2
- 235000013339 cereals Nutrition 0.000 description 2
- 230000035784 germination Effects 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 235000020636 oyster Nutrition 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 235000015170 shellfish Nutrition 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 244000025254 Cannabis sativa Species 0.000 description 1
- 241000555825 Clupeidae Species 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 241000287231 Serinus Species 0.000 description 1
- 240000003768 Solanum lycopersicum Species 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 235000013527 bean curd Nutrition 0.000 description 1
- 235000008429 bread Nutrition 0.000 description 1
- 235000012970 cakes Nutrition 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000002361 compost Substances 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 235000011194 food seasoning agent Nutrition 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000006166 lysate Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 235000010746 mayonnaise Nutrition 0.000 description 1
- 239000008268 mayonnaise Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 235000012149 noodles Nutrition 0.000 description 1
- 229920001542 oligosaccharide Polymers 0.000 description 1
- 150000002482 oligosaccharides Chemical class 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 235000012015 potatoes Nutrition 0.000 description 1
- 230000005070 ripening Effects 0.000 description 1
- 235000019512 sardine Nutrition 0.000 description 1
- 235000015067 sauces Nutrition 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000014214 soft drink Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 235000019614 sour taste Nutrition 0.000 description 1
- 235000013555 soy sauce Nutrition 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
- B09B3/80—Destroying solid waste or transforming solid waste into something useful or harmless involving an extraction step
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/80—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in fisheries management
- Y02A40/81—Aquaculture, e.g. of fish
Landscapes
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Fertilizers (AREA)
- General Preparation And Processing Of Foods (AREA)
- Processing Of Solid Wastes (AREA)
- Soil Conditioners And Soil-Stabilizing Materials (AREA)
- Coloring Foods And Improving Nutritive Qualities (AREA)
Abstract
본 발명에 따르면 구연산을 1∼3중량% 함유한 식초에 패각을 용해함으로써, 인체에 유용한 미네럴 성분을 1.5중량% 이상 함유시킨 것을 특징으로 하는 패각 용해액이 제공된다. 또한 본 발명에 따르면 구연산을 1∼3중량% 함유한 식초의 pH가 6.8∼7.0이 될 때까지 식초에 분쇄한 패각을 용해시키는 것을 특징으로 하는 패각 용해액의 제조 방법이 제공된다.According to the present invention, there is provided a shell dissolving solution comprising 1.5 wt% or more of a mineral component useful for the human body by dissolving the shell in vinegar containing 1-3 wt% citric acid. According to the present invention, there is also provided a method for producing a shell solution, wherein the shell pulverized in vinegar is dissolved until the pH of the vinegar containing 1 to 3% by weight of citric acid becomes 6.8 to 7.0.
본 발명에 따르면 산업 폐기물화하고 있는 패각을 적은 비용으로 용해 처리할 수 있으며, 상기 패각 용해액을 식품가공액, 조리액, 농작물 살포액, 토양살포액, 양식어장 살포액 등으로 사용하여 기타 산업분야의 자재로서 유효하게 이용함으로써 패각처리가 동시에 이루어져 패각의 폐기로 야기되는 공해 문제도 아울러 해결할 수 있다.According to the present invention, it is possible to dissolve and process the shell which is being industrialized at low cost, and use the shell melt as a food processing solution, cooking liquid, crop spraying liquid, soil spraying liquid, or farm fish farming spraying liquid. Effective use as a material in the field can also solve the pollution problem caused by the disposal of the shell by the shell treatment at the same time.
Description
본 발명은 산업 폐기물로서 전국의 수산업 기지에서 그 처리에 고통을 받고 있는 패각(조개류 껍데기)을 용해 처리한 패각 용해액 및 그 용해 처리 방법에 관한 것이다.The present invention relates to a shell dissolving solution in which shells (shell shells), which are suffering from the treatment at fisheries bases in Japan, are treated as industrial wastes, and a dissolution treatment method thereof.
현재, 산업 폐기물로서 전국의 수산업 기지에서 그 처리에 고심하고 있는 패각으로는 진주양식장의 진주조개 껍데기, 굴조개 양식장의 굴조개 껍데기, 바닥 조개 양식장의 바다조개 껍데기, 기타 수산 가공업자가 폐기하는 각종 조개류 껍데기등이 있다.Currently, the shells that are being treated as industrial wastes at fisheries bases around the country include pearl shells of pearl farms, shell shells of oyster shells, shell shells of bottom shell farms, and various shellfish discarded by other fisheries processors. There are shells.
종래의 패각 처리 방법으로는 굴조개 껍데기를 분쇄하여 바다에 버리거나, 진주조개 껍데기를 분쇄하여 농업용 토양 개량제로서 사용하는 방법등이 있었으나 거의 실용화되지는 못하고 있는 실정이다. 기타의 패각은 쓰레기로서 버려졌으나 야적된 상태로 방치되어 일부 지역에서는 공해 문제를 야기시키고 있는 실정이다.Conventional shell treatment methods, such as oyster shells are crushed and discarded in the sea, or pearl shells are crushed and used as an agricultural soil improving agent, but the situation is not practically used. Other shells have been thrown away as rubbish but left unattended, causing pollution problems in some areas.
따라서 본 발명의 목적은 산업 폐기물화되고 있는 패각을 적은 비용으로 용해 처리하여 패각 용해액을 제조하고, 이렇게 제조된 패각 용해액을 식품가공액, 조리액, 농작물 살포액, 토양살포액, 양식어장 살포액 등의 다른 산업 분야의 자재로서 효과적으로 이용함으로써 패각의 폐기로 인하여 야기되는 공해 문제를 해결하는데에 있다.Therefore, an object of the present invention is to produce a shell melt by dissolving the shell which is being industrial waste at a low cost, the shell melt is prepared by the food processing solution, cooking liquid, crop spraying solution, soil spray liquid, farm Effective use as a material in other industrial fields such as spreading liquids is to solve the pollution problem caused by the disposal of shells.
이와 같은 본 발명의 목적을 달성하기 위해, 본 발명자는 다양한 방법으로 패각을 처리하는 방법을 연구한 결과, 구연산을 함유한 식초에 패각을 용해시킴으로써 패각중에 함유되어 있는 인체에 유용한 미네럴 성분을 추출하여 패각 용해액을 제조할 수 있음을 발견하고 본 발명을 완성하기에 이르렀다.In order to achieve the object of the present invention, the present inventors have studied the method of treating the shell by a variety of methods, by dissolving the shell in vinegar containing citric acid to extract the mineral components useful to the human body contained in the shell It was found that a shell solution could be prepared and came to complete the present invention.
따라서 본 발명에 따르면 구연산을 1∼3중량% 함유한 식초에 패각을 용이하게 용해시킬 수 있을 뿐 아니라 인체에 유용한 미네럴 성분이 1.5중량% 이상 함유된 패각 용해액을 제조할 수 있게 되었다. 패각 용해액에 함유되는 상기 미네럴 성분으로는 나트륨, 칼륨, 칼슘, 철, 인, 마그네슘등을 들 수 있다.Therefore, according to the present invention, not only the shell can be easily dissolved in vinegar containing 1 to 3 wt% citric acid, but also a shell solution containing 1.5 wt% or more of a mineral component useful for the human body can be prepared. As said mineral component contained in a shell solution, sodium, potassium, calcium, iron, phosphorus, magnesium, etc. are mentioned.
또한 본 발명에 따르면, 상기 패각 용해액에 키토산 용해액을 혼합시킨 패각 용해액이 제공된다. 키토산 용해액으로는 식초에 5∼10중량%의 키토산을 용해시킨 용해액을 사용할 수 있다. 상기 패각 용해액과 키토산 용해액의 혼합 중량비는 사용되는 목적에 따라 1:99 내지 99:1의 범위내에서 적절히 선택할 수 있다.According to the present invention, there is also provided a shell solution in which the chitosan solution is mixed with the shell solution. As a chitosan solution, the solution which melt | dissolved 5-10 weight% of chitosan in vinegar can be used. The mixing weight ratio of the shell solution and the chitosan solution can be appropriately selected within the range of 1:99 to 99: 1 depending on the purpose of use.
또한, 본 발명에 따르면 상기 패각 용해액의 제조 방법이 제시되는바, 본 발명에 따르는 패각 용해액의 제조 방법은 구연산을 1∼3중량% 함유한 식초의 pH가 6.8∼7.0이 될 때까지, 분쇄된 패각을 식초에 용해시키는 것을 특징으로 한다. 구연산을 1∼3중량% 함유한 식초의 pH가 6.8∼7.0 이하인 경우에는, 식초의 자극적인 신맛과 특유의 냄새가 나서 식품에 사용하기 곤란하기 때문에 구연산을 1∼3중량% 함유한 식초의 pH가 6.8∼7.0이 될 때까지, 분쇄된 패각을 식초에 용해시키는 것이고, 중성이기 때문에 농작물 살포액등으로 이용할 때에도 좋다.In addition, according to the present invention, a method for producing a shell solution according to the present invention is provided. It is characterized by dissolving the ground shell in vinegar. If the pH of the vinegar containing 1-3 wt% of citric acid is 6.8-7.0 or less, the pH of the vinegar containing 1-3 wt% of citric acid is difficult to use for food because it has an irritating sour taste and characteristic smell. The pulverized shell is dissolved in vinegar until it is 6.8 to 7.0, and since it is neutral, it is good also when using it as a crop spreading liquid.
본 발명의 패각 용해액은 식품 가공액, 조리액, 농작물 살포액, 양식어장 살포액 등으로 이용된다. 따라서 인체 안전성 및 위생적인 면을 고려하여 패각을 용해시키기 위한 용액으로서 식초를 사용하고 있으나, 식초로는 양조 식초 또는 합성 식초등의 어느 것을 사용하여도 무방하다.The shell solution of the present invention is used as a food processing liquid, cooking liquid, crop spraying liquid, aquaculture fish farming liquid and the like. Therefore, vinegar is used as a solution for dissolving the shell in consideration of human safety and hygiene, but vinegar or synthetic vinegar may be used as the vinegar.
또한, 본 발명의 패각 용해액에 함유된 구연산은 패각의 탄산 칼슘의 분해를 촉진하는 작용을 한다. 더욱이 구연산은, 미네럴 성분인 칼슘과 같이 식용할 경우, 칼슘의 인체 흡수율을 상승시키는 작용을 하기 때문에 본 발명의 패각 용해액에 구연산을 함유시키는 것이 바람직하다.In addition, citric acid contained in the shell solution of the present invention serves to accelerate the decomposition of calcium carbonate in the shell. In addition, citric acid preferably contains citric acid in the shell solution of the present invention because it acts to increase the human absorption rate of calcium when edible together with calcium, which is a mineral component.
이하 본 발명을 실시예에 의해 상세히 설명하겠으나, 본 발명이 이에 한정되는 것은 아니다.Hereinafter, the present invention will be described in detail with reference to Examples, but the present invention is not limited thereto.
[실시예 1]Example 1
본 발명의 패각 용해액을 제조하기 위해, 먼저 패각을 깨끗한 물로 세척한 다음, 건조하고 파쇄하여 분말화한다. 이어서, 폴리 용기에 구연산을 2중량% 함유한 초산 함량 5%인 양조 곡물초 20리터에 상기 패각 분말을 2kg 투입하여 교반한다. 이어서 12∼48시간 경과후, 여과시켜 본 발명의 패각 용해액을 얻었다. 그리고 나머지 패각 분말은 재사용할 수 있다. 또한 12∼48시간 경과후에도 패각 용해액의 pH가 6.7∼7.0 이하인 경우에는, 패각이 식초액에 대하여 포화 상태까지 용해되지 않고 있는 것이므로 다시 용해시킬 수 있다.To prepare shell solutions of the present invention, shells are first washed with clean water, then dried and crushed to powder. Subsequently, 2 kg of the shell powder is added to 20 liters of brewed grain vinegar containing 5% acetic acid containing 2% by weight citric acid in a poly container, followed by stirring. Subsequently, after 12 to 48 hours, the solution was filtered to obtain a shell solution of the present invention. And the remaining shell powder can be reused. In addition, when the pH of the shell dissolution liquid is 6.7-7.0 or less even after 12 to 48 hours, since a shell does not melt | dissolve to a saturation state with respect to vinegar liquid, it can dissolve again.
이와 같이 하여 얻어진 본 발명의 패각용해액에 함유된 인체에 유용한 미네럴 성분의 성분을 분석을 하였다. 그 결과를 표 1에 나타낸다.The components of the mineral component useful for the human body contained in the shell solution of the present invention thus obtained were analyzed. The results are shown in Table 1.
이와 같은 방법으로 제조한 본 발명의 패각용해액을 50∼200배로 희석하고, 이하에 표시한 식품의 가공 조리액등으로 사용하면 한국인의 1인당 칼슘 섭취량 600mg을 용이하게 섭취할 수 있다.When the shell solution of the present invention prepared in this manner is diluted 50-200 times and used as a processed cooking solution for foods shown below, it is possible to easily consume 600 mg of calcium intake per person of Koreans.
상기 식품으로는, 밥, 떡, 빵, 면류, 과자류, 두부, 짱아치, 저전생선, 쨈, 청량음료수, 조미로(된장, 간장, 소스, 마요네즈등), 튀김용 튀김 재료, 담근장등을 들 수 있다.Examples of the foods include rice, rice cake, bread, noodles, confectionary, tofu, chan-chan, low-powered fish, 쨈, soft drink, seasoning (soybean paste, soy sauce, sauce, mayonnaise, etc.), fried ingredients Can be.
[실시예 2]Example 2
폴리 용기에 양조 곡물초 20리터를 넣어 키토산 분말 1kg을 투입하고 잘 교반한다. 폴리 용기에 뚜껑을 덮어 48시간 경과후, 쨈 형태의 용해물을 얻는다. 이 쨈 형태의 용해물 6kg을 실시예 1에서 얻은 패각 용해액 12리터에 혼합하여 교반한다.Put 20 liters of brewed grain grass in a poly container, add 1 kg of chitosan powder, and stir well. The lid is covered with a poly container, and after 48 hours, a lysate of lye form is obtained. 6 kg of the K-form melt was mixed with 12 liters of the shell solution obtained in Example 1 and stirred.
이와 같이 키토산을 투입하는 것은 식초로서 양조 식초를 사용하면 미생물이 번식하기 쉬우므로 미생물의 발생을 방지하기 위해서이다. 공지된 바와 같이 키토산은 미생물에 대하여 강력한 항균성을 가지고 있다(키틴, 키토산 및 올리고당의 항균성과 그 응용, 키틴, 키토산의 응용 pp71-98, 키틴, 키토산 연구회(편), 기보당출판, 동경(1994)).The chitosan is introduced in this way to prevent the occurrence of microorganisms because brewing vinegar is used to make microorganisms easier to breed. As is well known, chitosan has strong antimicrobial properties against microorganisms (antibacterial and application of chitin, chitosan and oligosaccharides, application of chitin and chitosan pp71-98, chitin, chitosan study group (ed), Kibosugar Publishing, Tokyo (1994) )).
다음에 실시예 2에서 얻은 본 발명의 키토산을 혼합한 패각 용해액을 50∼200배로 희석하고 이하에 표시한 사양으로 토양살포액, 종자나 종묘의 침지액, 농작물 살포액, 양식 어장용 자재로서 사용했다.Next, the shell solution containing the chitosan of the present invention obtained in Example 2 was diluted by 50 to 200 times, and as the soil spray solution, the immersion liquid of the seed or seedling, the crop spraying liquid, and the material for aquaculture farms according to the specifications shown below. Used.
[토양살포액][Soil Spray]
경전전의 작물 예정지에, 완숙 퇴비를 10아아르당 3∼5톤 시비한 다음, 상기 키토산을 혼합한 패각용해액을 10아아르당 1톤 살포했다. 살포후 경전하여 경작한바, 토양중의 미네럴 성분의 보강, 토양균 밸런스의 회복, 작물의 질병방제, 작물의 품질 향상등이 실현되었다.After ripening compost was fertilized 3 to 5 tons per 10 aars, the shell solution containing chitosan was sprayed 1 ton per 10 aars. After cultivation after cultivation, cultivation of minerals in soil, restoration of soil balance, control of diseases of crops and improvement of crop quality were realized.
[종자종묘의 침지액][Immersion liquid of seed seedling]
경작할 작물의 종자나 종묘를 상기 키토산을 혼합한 패각 용해액에 24시간 침지한바, 싹이 트기까지의 시간이 단축되고, 발아후의 성장도 촉진되었다. 또 질병에 잘 걸리지 않았다.When the seeds and seedlings of the crops to be cultivated were immersed in a shell solution in which chitosan was mixed for 24 hours, the time to sprouting was shortened, and growth after germination was also promoted. The disease did not take well.
[농작물 살포액][Crop spray]
발아후 1주간 경과한 작물의 잎의 표리, 몽어리, 뿌리에 걸쳐, 작물 면적 10아아르당 상기 키토산을 혼합한 패각 용해액을 200∼600리터 살포하였다. 이어서, 2주간에 1회, 감자, 토마토, 옥수수의 경우에는, 3∼4회의 비율로 상기 키토산을 혼합한 패각 용해액을 살포하였다. 그 결과 민바퀴, 진드기, 슬립 등 해충의 방제에 크게 도움되었다. 과수, 차에 살포하면, 농약 살포를 필요로 하지 않았다. 차는 민바퀴, 진드기의 방제로 수확량이 생잎으로 30% 증산됨과 동시에 품질이 향상되었다.200-600 liters of shell solution containing chitosan was sprayed per 10 acres of crop area over the front and back of the leaves, the monks and the roots of the crops that had passed one week after germination. Then, once every two weeks, in the case of potatoes, tomatoes, and corn, the shell solution in which chitosan was mixed was sprayed at a rate of 3 to 4 times. As a result, they helped to control pests such as wheels, ticks and slips. Spraying on fruit trees, tea, did not need pesticide spraying. The quality of tea was improved by increasing the yield by 30% with fresh leaves by controlling the wheels and ticks.
[양식어장용 자재][Fish farm]
양식어의 미끼에 사용하는 냉동 정어리, 까나리 등을 선상에서 분쇄기를 사용하여 치어군에게 줄 때, 상기 키토산을 혼합한 패각 용해액을 3%중량비로 혼입하면 약식어의 병사 사망률이 낮아진다. 또한, 김 양식어장에서, 만족시에 김망의 수면에 1m 당 3∼4리터 살포하면 김의 질병이 방제되었다. 또한, 김망을 상기 키토산을 혼합한 패각 용해액에 침지하여 망의 섬유에 함침시키면 김의 생육이 양호해졌었다.When frozen sardines, canaries, and the like used for bait for farmed fish are fed to a group of fry using a grinder on board, mixing the shell solution with chitosan mixed at a 3% weight ratio lowers the mortality rate of abbreviated fish. Also, at the fish farm, 1m on the surface of Kim Mang when satisfied Spraying 3 to 4 liters of sugar per year prevented Kim's disease. In addition, when laver was immersed in the shell solution in which chitosan was mixed and impregnated in the fibers of the laver, the growth of laver was improved.
따라서 본 발명은 전술한 바와 같이, 산업 폐기물화한 패각류를 적은 비용으로 용해 처리할 수 있고, 또한 이 패각 용해액을 식품가공액, 조리액, 농작물 살포액, 토양살포액, 양식어장 살포액등으로서 타 산업 분야의 자재로서 유효하게 이용함으로써 패각 처리가 동시에 이루어져 패각의 폐기로 야기되는 공해 문제를 효과적으로 해결할 수 있게 되었다.Therefore, as described above, the present invention can dissolve and treat industrial waste shellfish at a low cost, and furthermore, the shell melt can be processed into food processing liquid, cooking liquid, crop spraying liquid, soil spraying liquid, and fish farm spraying liquid. By effectively using it as a material for other industries, the shell treatment is performed at the same time, thereby effectively solving the pollution problem caused by the disposal of the shell.
Claims (4)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019960008296A KR0173556B1 (en) | 1996-03-26 | 1996-03-26 | Shell solution and fabrication method thereof |
| TW085114318A TW360499B (en) | 1996-03-26 | 1996-11-21 | Shell solution and fabrication method thereof |
| AU75425/96A AU722916B2 (en) | 1996-03-26 | 1996-12-17 | Shell solution and fabrication method thereof |
| NZ314055A NZ314055A (en) | 1996-03-26 | 1997-01-10 | Dissolution of shell in acetic acid containing 1-3 wt% of citric acid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019960008296A KR0173556B1 (en) | 1996-03-26 | 1996-03-26 | Shell solution and fabrication method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR970064756A KR970064756A (en) | 1997-10-13 |
| KR0173556B1 true KR0173556B1 (en) | 1999-02-01 |
Family
ID=19453928
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019960008296A KR0173556B1 (en) | 1996-03-26 | 1996-03-26 | Shell solution and fabrication method thereof |
Country Status (4)
| Country | Link |
|---|---|
| KR (1) | KR0173556B1 (en) |
| AU (1) | AU722916B2 (en) |
| NZ (1) | NZ314055A (en) |
| TW (1) | TW360499B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101357078B1 (en) * | 2012-09-18 | 2014-02-03 | 주식회사 서진바이오텍 | Process for seperation of cutoffs having anti-inflamentary or osteoarthritis inhibition effects using oyster shells |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103651223B (en) * | 2014-01-03 | 2015-08-05 | 鲁东大学 | A kind of appraisal procedure of long oyster soft body weight in wet base |
-
1996
- 1996-03-26 KR KR1019960008296A patent/KR0173556B1/en not_active IP Right Cessation
- 1996-11-21 TW TW085114318A patent/TW360499B/en active
- 1996-12-17 AU AU75425/96A patent/AU722916B2/en not_active Ceased
-
1997
- 1997-01-10 NZ NZ314055A patent/NZ314055A/en unknown
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101357078B1 (en) * | 2012-09-18 | 2014-02-03 | 주식회사 서진바이오텍 | Process for seperation of cutoffs having anti-inflamentary or osteoarthritis inhibition effects using oyster shells |
| US9937210B2 (en) | 2012-09-18 | 2018-04-10 | Seojin Biotech Co., Ltd. | Method for isolating fraction having anti-inflammatory or osteoarthritis-inhibiting effects by using oyster shell chips |
Also Published As
| Publication number | Publication date |
|---|---|
| AU722916B2 (en) | 2000-08-17 |
| TW360499B (en) | 1999-06-11 |
| KR970064756A (en) | 1997-10-13 |
| AU7542596A (en) | 1997-10-16 |
| NZ314055A (en) | 1997-03-24 |
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