KR0144012B1 - Mortar compositin for finishing construction - Google Patents

Mortar compositin for finishing construction

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Publication number
KR0144012B1
KR0144012B1 KR1019960004564A KR19960004564A KR0144012B1 KR 0144012 B1 KR0144012 B1 KR 0144012B1 KR 1019960004564 A KR1019960004564 A KR 1019960004564A KR 19960004564 A KR19960004564 A KR 19960004564A KR 0144012 B1 KR0144012 B1 KR 0144012B1
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South Korea
Prior art keywords
weight
mortar
elvan
present
building
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KR1019960004564A
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Korean (ko)
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KR970061818A (en
Inventor
한정수
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한정수
주식회사동우하이테크
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Priority to KR1019960004564A priority Critical patent/KR0144012B1/en
Publication of KR970061818A publication Critical patent/KR970061818A/en
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Publication of KR0144012B1 publication Critical patent/KR0144012B1/en

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • C04B14/06Quartz; Sand
    • C04B14/066Precipitated or pyrogenic silica
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • C04B14/041Aluminium silicates other than clay
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B16/00Use of organic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of organic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B16/04Macromolecular compounds
    • C04B16/06Macromolecular compounds fibrous
    • C04B16/0616Macromolecular compounds fibrous from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B16/065Polyacrylates; Polymethacrylates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482Coating or impregnation materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

본 발명은 맥반석을 함유하는 건축물 미장용 모르타르 조성물에 관한 것으로, 좀 더 상세하게는 100메쉬 이상으로 분쇄된 맥반석 10∼20중량%, 아크릴수지 15∼30중량%, 실리카 50∼70중량%, 틱소트로피 에전트 0.1∼0.8중량%, 물 3∼10중량% 및 기타첨가제로 이루어진 건축물 미장용 모르타르 조성물에 관한 것이다. 상기 조성물은 고급주택, 사무실, 병원의 바닥 및 벽면, 특히 온돌방바닥, 지하실벽면 등의 미장제로 사용되어 접착력, 내마모성, 방염성 등을 부여할 수 있다.The present invention relates to a mortar composition for building plaster containing elvan, more specifically 10 to 20% by weight of gantherite, 15 to 30% by weight of acrylic resin, 50 to 70% by weight of silica, thixo It relates to a mortar composition for building plaster composed of 0.1 to 0.8% by weight of the trophy agent, 3 to 10% by weight of water and other additives. The composition may be used as a plastering agent such as floors and walls of luxury houses, offices, hospitals, in particular, ondol floors, basement walls, and the like, to impart adhesion, wear resistance, and flame resistance.

Description

맥반석을 함유하는 건축물 미장용 모르타르 조성물Mortar composition for building plaster containing elvan

본 발명은 맥반석을 함유하는 건축물 미장용 모르타르 조성물에 관한 것으로, 좀 더 상세하게는 고급주택, 사무실, 병원의 바닥 및 벽면, 특히 온돌방바닥, 지하실벽면 등의 미장제로 사용되어 접착력, 내충격성, 내마모성, 방염성 등이 우수한 맥반석을 함유하는 건축물 미장용 모르타르 조성물에 관한 것이다.The present invention relates to a mortar composition for building plaster containing elvan rock, and more particularly, it is used as a plastering agent for floors and walls of luxury houses, offices, hospitals, especially ondol floors, basement walls, and the like. The present invention relates to a mortar composition for plastering of buildings, which contains elvan, excellent in flame retardancy and the like.

종래의 건축물의 바닥 및 벽면 미장제는 시멘트, 모레 및 물로 이루어진 시멘트 모르타르 조성물을 적절히 혼합하여 사용하여 왔다. 그러나, 통상의 방법으로 제조된 건축용 재로는 사용하여 축조한 건축물은 사람 또는 동물들이 거주함에 따라 여러 가지 냄새가 건축물 내부에 스며들게 되므로 불쾌감을 느끼게 되며, 습기가 많을 경우 특히, 우기시에는 건축물 내부의 습도가 상승되어 호홉기 질환을 유발하며, 인체에 유해한 세균이 발생되어 질병의 원인으로 작용하게 된다.Conventional building floor and wall plasters have been used with a suitable mix of cement mortar compositions consisting of cement, sand and water. However, a building constructed using a building material manufactured by a conventional method is unpleasant because various smells are permeated into the building as people or animals dwell, and when the humidity is high, especially during the rainy season, Humidity is increased to cause a hop hop disease, and harmful bacteria are generated in the human body to act as a cause of the disease.

따라서, 상술한 냄새를 없애거나 감소시키기 위해서 화학적으로 제조된 탈취제를 사용하거나 방향제를 사용하여 불쾌감을 주는 냄새를 감지할 수 없도록 하였으며, 건축물내의 습기를 제거하기 위해서는 난방을 하거나 탈수제를 사용하여 왔다.Therefore, to remove or reduce the odor described above, it is not possible to detect an unpleasant odor using a chemically prepared deodorant or a fragrance, and to remove moisture in a building, heating or a dehydrating agent has been used.

그러나, 이와 같이 화학적으로 제조한 탈취제, 방향제 또는 탈수제를 사용함으로서 시간이 경과함에 따라 효과가 감소할 뿐만 아니라 충분한 효과를 얻을 수 없었으며, 화학제품을 구입해야 하고, 하절기에 난방을 해야하므로 더위를 느끼는 등 여러가지의 문제점이 있었다.However, the use of such chemically prepared deodorants, fragrances or dehydrating agents not only reduced the effects over time, but also could not achieve sufficient effects, and it was necessary to purchase chemicals and heat them in summer. There were various problems such as feeling.

이러한 문제점을 해결하기 위하여 본 발명자들은 광범위한 연구를 수행한 결과, 원적외선 방출, 탈취작용, 흡착작용, 항균작용, 또는 일정한 열전도도를 갖는 맥반석을 함유하는 건축물 미장용 모르타르 조성물을 개발하였고, 본 발명은 이에 기초하여 완성되었다.In order to solve this problem, the present inventors have conducted extensive research, and have developed a mortar composition for plastering a building containing elvan with far-infrared emission, deodorization, adsorption, antibacterial action, or constant thermal conductivity. Completed on this basis.

따라서, 본 발명의 목적은 고급주택, 사무실, 병원의 바닥 및 벽면, 특히 온돌방바닥, 지하실벽면 등의 미장제로 사용되어 접착력, 내충격성, 내마모성, 방염성 등이 우수한 맥반석을 함유하는 건축물 미장용 모르타르 조성물을 제공하는데 있다.Therefore, an object of the present invention is used as a plastering agent for floors and walls of luxury houses, offices, hospitals, especially ondol floors, basement wall surfaces, etc., and contains mortar compositions for building plasters having excellent adhesion, impact resistance, abrasion resistance, and flame resistance. To provide.

상기 목적을 달성하기 위한 본 발명의 조성물은 100메쉬(mesh0 이상으로 분쇄된 맥반석 10∼20중량%, 아크릴수지 15∼30중량%, 실리카 50∼70중량%, 틱소트로피(thixotropic) 에전트 0.1∼0.8중량%, 물 3∼10중량% 및 기타첨가제로 이루어진다.The composition of the present invention for achieving the above object is 100 mesh (10-20% by weight of ganbanite, 15-30% by weight of acrylic resin, 50-70% by weight of silica, thixotropic agent 0.1-) 0.8% by weight, 3-10% by weight of water and other additives.

이하 본 발명을 좀 더 구체적으로 살펴보면 다음과 같다.Looking at the present invention in more detail as follows.

본 발명에 사용되는 맥반석은 석영반암의 풍화로 그 중에 함유된 장석이 분해되어 일부 고령토화 과정에 있는 암석으로서, 다공질의 구조이고 색은 항백색이며 모양은 맥반모양이다. 또한, 백색의 반점이 박혀있는 것이 특징이며, 약 20% 수용성으로 알려져 있다.Elvan rock used in the present invention is a rock in which the feldspar contained therein is decomposed due to the weathering of quartz rock rock, and it is in the process of kaolinization. It is also characterized by the presence of white spots and is known to be about 20% water soluble.

일반적인 맥반석은 중량% 기준으로 SiO260∼70, Al2O317∼23, Fe2O32∼5, FeO 0.5∼2, CaO 3∼7, MgO 1∼4, H2O+ 0.5∼2, TiO20.2∼1, P2O50.1∼1, K2O 1∼4, Na2O 4∼7, 및 MnO 0.05∼1로 이루어져 있지만, 본 발명에서는 상기 범위에 제한받지 않고, 상용되는 맥반석을 모두 포함할 수 있다.The general elvan is based on the weight percent SiO 2 60-70, Al 2 O 3 17-23, Fe 2 O 3 2-5, FeO 0.5-2, CaO 3-7, MgO 1-4, H 2 O + 0.5-2 , TiO 2 0.2-1, P 2 O 5 0.1-1, K 2 O 1-4, Na 2 O 4-7, and MnO 0.05-1, but is not limited to the above range in the present invention, It can contain all the Elvan rocks.

이와같이, 맥반석은 Si, Na, K, Mg, Ca등의 풍부한 필수성분의 공급원이 되며 또한 Mo, Zn, Cu등의 미량 요소성분을 공급하는 것으로 고대로부터 한약재로서 일절의 피부질환에 사용되었고 최근에는 식물 성장을 촉진한다는 실험보고가 있다.Like this, elvan is a source of abundant essential ingredients such as Si, Na, K, Mg, Ca, and also supplies trace elements such as Mo, Zn, Cu. There is an experimental report that promotes plant growth.

또한, 맥반석은 향에 대한 흡착 때문에 화장품 산업에 사용되고 있을 뿐만 담배의 니코틴 제거에도 사용되고 있으며, 맥반석중에 함유된 미네랄(mineral)이 용출되기 때문에 인체에 유용한 물질로서 사용되고 있고, 미네랄이 물에 용출되어 수질의 조정 즉 pH가 조절되므로 물의 산도를 조절할 수 있으며, 각각의 미네랄 상호간의 종류나 농도의 균형을 맞추어 준다. 아울러, 물속에 공기중의 산소를 많이 끌어들여서 용존산소량을 증가시킴으로 물의 신선도를 유지해 주며, 체내에 유해한 카드늄이나 농약성분인 유기염소류를 흡착한 이온조절 작용으로 흡착, 제거하기 때문에 해독의 효과가 있다.In addition, elvan is used in the cosmetics industry because of its adsorption to fragrances, and it is also used to remove nicotine in tobacco. It is used as a useful substance for humans because the minerals contained in elvan are eluted. The pH of the water is adjusted, so that the acidity of the water can be adjusted, and the balance between each mineral type and concentration. In addition, it keeps the freshness of water by increasing the amount of dissolved oxygen by drawing a lot of oxygen in the air into the water and detoxifying effect because it adsorbs and removes harmful cadmium or organic chlorine which is a pesticide ingredient. have.

본 발명에서는 상기 맥반석을 약 100메쉬 이상으로 분쇄하여 10∼20중량%로 사용한다. 이때, 맥반석을 100메쉬 이하로 분쇄할 경우에는 맥반석의 입도가 크게 되어 본 발명의 다른 성분들과 잘 혼합되지 않을 뿐만 아니라 최종제품의 외관이 저하되며 맥반석 분말이 탈리될 수도 있다. 또한, 맥반석을 10중량% 미만으로 혼합하였을 경우에는 맥반석 첨가효과가 나타나지 않으며, 20중량%을 초과하면 건축물 미장용 모르타르와의 혼합이 불균일하게 이루어지게 되고 최종제품의 외관이 저하되며, 결착력이 부족하여 모르타르로 부터 맥반석 분말이 쉽게 탈리되어 맥반석 첨가의 효과가 상실된다.In the present invention, the ganbanite is ground to about 100 mesh or more and used at 10 to 20% by weight. In this case, when the ganguerite is pulverized to 100 mesh or less, the granules have a large particle size, which may not be well mixed with other components of the present invention, and the appearance of the final product may be deteriorated and the gannetrite powder may be detached. In addition, when the elvan is mixed at less than 10% by weight, the elvan does not have an effect of adding the elvan. If it exceeds 20% by weight, the mixing with the mortar for plastering of the building is made uneven and the appearance of the final product is deteriorated. Therefore, the elvan powder is easily detached from the mortar, and the effect of the addition of elvan is lost.

한편, 상기 성분 중 무수규산과 산화알미늄은 강한 흡착력으로 악취를 제거하는 능력이 있어 건물에 거주하는 사람 또는 동물, 및 음식물에 의한 악취를 반감시킬 수 있다. 아울러, 상기 맥반석은 다공성이므로 우기시 상승되는 습도를 기존의 시멘트 모르타르보다 더욱 많이 흡수할 수 있다. 좀 더 바람직하게는 상기 맥반석을 고온에서 가열시켜 불순물 및 수분을 제거하여 좀더 다공성으로 유도함으로써 상기 효과를 상승시킬 수 있다.On the other hand, silicic anhydride and aluminum oxide in the components have the ability to remove the odor with a strong adsorption power can halve the odor by people or animals living in buildings, and food. In addition, since the elvan is porous, the humidity rising during the rainy season can absorb more than the conventional cement mortar. More preferably, the effect can be enhanced by heating the elvan rock at a high temperature to remove impurities and moisture to lead to more porosity.

본 발명에서 바인더로 사용되는 아크릴수지는 메틸 메타크릴레이트 또는 아크릴릭 모노머의 중합체 또는 공중합체로서, 최종 조성물에 대하여 15∼30중량% 사용된다. 이때, 15중량% 미만이면 최종 모르타르의 결착력이 부족하며, 30중량%를 초과하면 결착력은 우수하나 경제적으로 불리한 단점이 있다.The acrylic resin used as the binder in the present invention is a polymer or copolymer of methyl methacrylate or acrylic monomer, and is used in an amount of 15 to 30% by weight based on the final composition. At this time, less than 15% by weight of the final mortar lacks the binding force, more than 30% by weight is excellent in binding strength, but there are disadvantages economically disadvantageous.

본 발명에서 충진제로 사용되는 실리카는 50∼70중량%로 사용되며, 이 또한 100메쉬 이상으로 분쇄하여 사용한다. 50중량% 미만으로 혼합하였을 경우에는 충진효과가 미비하며, 70%중량%을 초과하면 건축물 미장용 모르타르의 혼합이 불균일하게 이루어지게 되고 최종제품의 외관이 불량하게 된다.Silica used as a filler in the present invention is used in 50 to 70% by weight, which is also used by grinding to more than 100 mesh. When the mixture is less than 50% by weight, the filling effect is insignificant, and when it exceeds 70% by weight, the mixing of building mortar is uneven and the appearance of the final product is poor.

또한, 증점제로 사용되는 틱소트로피 에전트는 단순한 휘저어 주기만 하여도 겔이 유동성인 졸로 변하고, 이것을 방치하면다시 겔로 되돌아가는 특성이 갖는 시약으로서 최종 조성물에 대하여 0.1∼0.8중량% 사용된다. 아울러, 본 발명에 따른 조성물은 상술한 성분에 3∼10중량%의 물과 분쇄시킨 골재와 같은 기타첨가물를 더욱 포함한다.In addition, the thixotropic agent used as a thickener is used as a reagent having the property of turning the gel into a fluid sol by simple stirring and returning it to the gel when left alone. In addition, the composition according to the present invention further comprises 3 to 10% by weight of water and other additives such as pulverized aggregates in the above-described components.

이러한 성분을 갖는 본 발명의 조성물은 먼지, 유분 등과 같은 이 물질을 완전히 제거시킨 소지면에 도포한 다음, 흙 손으로 미장 마감하고, 표면을 매끄럽게 하기 위하여 약간의 물기를 분사시킨 후 표면을 정리하여 미장을 마감한다.The composition of the present invention having such a component is applied to a surface of which the substance such as dust, oil, etc. is completely removed, and then plastered with trowel, sprayed with a little water to smooth the surface, and then the surface is cleaned To close.

본 발명에 따른 조성물은 맥반석을 함유함으로써 원적외선을 방출하여 신진대사가 촉진되며 혈액순환을 원활하게 하여 피로회복 및 인체에 유익한 작용으로 쾌적한 생활환경을 조성해 주며, 전통 온돌방 및 돌 침대 등 찜질효과를 동시에 얻을 수 있고 , 스트레스 해소 및 쾌적 수면에 큰 효과가 있다. 또한 강력한 탈취작용으로 건물내의 여러 냄새를 제거해 주고, 강한 흡착작용으로 건물내의 습기를 흡수 또는 방출하므로 습기조절 기능이 있다. 아울러, 상술한 탈취 및 습기의 흡착작용으로 곰팡이 및 유해 균류의 서식을 방지할 수 있고, 일정한 열전도도를 유지할 수 있어 온돌 바닥 전체가 골고루 따뜻하며 축열작용이 매우 높아 난방비가 절감되는 효과가 있다.The composition according to the present invention releases far infrared rays by containing elvan, promotes metabolism, facilitates blood circulation, creates a pleasant living environment with a beneficial effect on the recovery of fatigue and the human body, and at the same time to the traditional ondol room and stone bed It has a great effect on stress relief and comfortable sleep. In addition, the strong deodorizing action to remove various odors in the building, and the strong adsorption action to absorb or release the moisture in the building has a moisture control function. In addition, the deodorization and adsorption of moisture can prevent the mold and harmful fungi incubation, and can maintain a constant thermal conductivity, the entire floor is evenly warm, and the heat storage action is very high, the heating cost is reduced.

이하 실시예를 통하여 본 발명을 좀 더 구체적으로 설명하지만, 하기예에 본 발명의 범주가 한정되는 것은 아니다.Hereinafter, the present invention will be described in more detail with reference to Examples, but the scope of the present invention is not limited to the following Examples.

[실시예1]Example 1

100메쉬 이상으로 분쇄된 맥반석 10중량%, ICI사의 아크릴수지(상품명; EVACITE) 20중량%, 100메쉬 이상으로 분쇄된 실리카 60중량%, Degussa사의 틱소트로피 에전트(상품명; AEROSIL R 972) 0.4중량%, 물 6.6중량% 및 100메쉬 이상으로 분쇄된 골재 3중량%를 교반기가 부착된 용기에 넣고 1500rpm으로 2시간동안 충분히 혼합하여 본 발명의 맥반석을 함유 건축물 미장용 모르타르를 제조하였다.10% by weight of ganbanite crushed to 100 mesh or more, 20% by weight of acrylic resin (trade name; EVACITE) of ICI, 60% by weight of silica crushed to 100 mesh or more, 0.4 weight of thixotropic agent of Degussa (brand name; AEROSIL R 972) %, 6.6% by weight of water and 3% by weight of aggregates pulverized to 100 mesh or more were put in a container with a stirrer and sufficiently mixed for 2 hours at 1500rpm to prepare a mortar for building plaster containing ganban stone of the present invention.

[실시예2]Example 2

100메쉬 이상으로 분쇄된 맥반석 20중량%, ICI사의 아크릴수지(상품명; EVACITE) 15중량%, 100메쉬 이상으로 분쇄된 실리카 55중량%, Defussa사의 틱소트로피 에전트(상품명; AEROSIL R 972) 0.4중량%, 물 6.6중량% 및 100메쉬 이상으로 분쇄된 골재 3중량%를 교반기가 부착된 용기에 넣고 1500rpm으로 2시간 동안 충분히 혼합하여 본 발명의 맥반석을 함유 건축물 미장용 모르타르를 제조하였다.20% by weight of ganbanite crushed to 100 mesh or more, 15% by weight of acrylic resin (trade name; EVACITE) from ICI, 55% by weight of silica crushed to 100 mesh or more, 0.4% by weight of thixotropic agent from Defussa (brand name; AEROSIL R 972) %, 6.6% by weight of water and 3% by weight of aggregates pulverized to 100 mesh or more were put in a container equipped with a stirrer and sufficiently mixed for 2 hours at 1500 rpm to prepare a mortar for building plaster containing ganban stone of the present invention.

상기 실시예 1 및 2의 방법으로 제조된 모르타르의 시편(1×1×1cm)을 제조하여 탈취시험 및 용출시험하여, 그 결과를 하기 표 1에 기재하였다.Mortar specimens (1 × 1 × 1 cm) prepared by the methods of Examples 1 and 2 were prepared, deodorization test and dissolution test, and the results are shown in Table 1 below.

1)용출조건 : 2㎖/㎠×60℃×30분(보사부 고시 94-28)1) Elution condition: 2ml / ㎠ × 60 ℃ × 30min (Notice 94-28

Claims (1)

100메쉬 이상으로 분쇄된 맥반석 10∼20중량%, 아크릴수지 15∼30중량%, 실리카 50∼70중량%, 틱소트로피 에전트 0.1∼0.8중량%, 물 3∼10중량% 및 나머지는 분쇄시킨 골재로 이루어진 것을 특징으로 하는 맥반석을 함유하는 건축물 미장용 모르타르 조성물.10 to 20% by weight of ganbanite, 15 to 30% by weight of acrylic resin, 50 to 70% by weight of silica, 0.1 to 0.8% by weight of thixotropic agent, 3 to 10% by weight of water, and the remainder of the aggregate Mortar composition for building plaster containing elvan rock, characterized in that consisting of.
KR1019960004564A 1996-02-23 1996-02-23 Mortar compositin for finishing construction KR0144012B1 (en)

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KR970069274A (en) * 1996-04-18 1997-11-07 황선두 Far-infrared radiation resin mortar composition

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KR100475425B1 (en) * 2001-10-08 2005-03-10 김낙주 Mortar
KR100403488B1 (en) * 2002-05-29 2003-11-01 Alphbio Co Ltd Method for preparing liquid ceramic constructional finishing material excellent in emitting far infrared ray and anion, and liquid ceramic constructional finishing material obtained therefrom
KR100403487B1 (en) * 2002-05-29 2003-11-01 Alphbio Co Ltd Method for making separated liquid-powder type ceramic constructional finishing material, and ceramic constructional finishing material obtained therefrom
KR20040033387A (en) * 2002-10-14 2004-04-28 (주)제니아크 Composite and manufacture method for an escarp finish for health

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR970069274A (en) * 1996-04-18 1997-11-07 황선두 Far-infrared radiation resin mortar composition

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