KR0137508B1 - Hemp hosiery and process for its manufacture - Google Patents

Hemp hosiery and process for its manufacture

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Publication number
KR0137508B1
KR0137508B1 KR1019950021412A KR19950021412A KR0137508B1 KR 0137508 B1 KR0137508 B1 KR 0137508B1 KR 1019950021412 A KR1019950021412 A KR 1019950021412A KR 19950021412 A KR19950021412 A KR 19950021412A KR 0137508 B1 KR0137508 B1 KR 0137508B1
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South Korea
Prior art keywords
weight
hemp
parts
socks
fiber
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KR1019950021412A
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Korean (ko)
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KR970006657A (en
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조현준
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조현준
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Priority to KR1019950021412A priority Critical patent/KR0137508B1/en
Publication of KR970006657A publication Critical patent/KR970006657A/en
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Publication of KR0137508B1 publication Critical patent/KR0137508B1/en

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    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41BSHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
    • A41B11/00Hosiery; Panti-hose
    • A41B11/001Decoration; Marking
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B1/00Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/22Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes specially adapted for knitting goods of particular configuration
    • D04B1/24Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes specially adapted for knitting goods of particular configuration wearing apparel
    • D04B1/26Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes specially adapted for knitting goods of particular configuration wearing apparel stockings
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06CFINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C27/00Compound processes or apparatus, for finishing or dressing textile fabrics, not otherwise provided for
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06CFINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C7/00Heating or cooling textile fabrics
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Socks And Pantyhose (AREA)

Abstract

본 발명은 대마양말의 제조방법에 관한 것으로, 좀 더 상세하게는 대마섬유를 약 38∼51mm의 크기로 절단한 다음, 상기 섬유 100중량부에 대하여 평활제 3∼8중량부, 유연제 7∼15중량부 및 대전방지제 0.5∼3중량부를 도포시켜 48시간이상 밀폐된 공간에서 보관하는 단계; 상기 대마섬유 20∼55중량% 및 면 20∼70중량%를 필수적으로 하고, 여기에 아클릴섬유 10∼30중량% 및/또는 울 10∼15중량%를 선택적으로 첨가시킨 조성물을 혼합하는 단계; 및 개섬, 연조, 조방, 정방, 권사, 표백, 및 염색단계를 거쳐 40∼60℃로 유지되는 키토콜라-α 희석수에 함침시킨 다음, 건조시킨후, 110∼160℃에서 90초∼3분간 열처리시켜 편조 및 가공하는 단계로 이루어지는 대마양말의 제조방법에 관한 것이다. 상기 방법으로 제조된 대마양말은 착용시 발에서 분비되는 땀과 피지를 빨리 흡수함과 동시에 건조가 빠른 효과가 있다.The present invention relates to a method for producing hemp socks, and more particularly, hemp fibers are cut to a size of about 38 to 51 mm, and then 3 to 8 parts by weight of a smoothing agent and 7 to 15 parts by weight of 100 parts by weight of the fiber. Applying parts by weight and 0.5 to 3 parts by weight of an antistatic agent and store in an enclosed space for at least 48 hours; Mixing 20 to 55% by weight of the hemp fibers and 20 to 70% by weight of cotton, and optionally adding 10 to 30% by weight of acryl fiber and / or 10 to 15% by weight of wool; And impregnated with dilution of chitocola-α maintained at 40-60 ° C. through open-ispension, softening, spinning, spinning, spinning, bleaching, and dyeing, followed by drying, followed by drying at 110-160 ° C. for 90 seconds to 3 minutes. It relates to a method for producing hemp socks comprising the step of heat treatment braiding and processing. Hemp socks prepared by the above method has a quick drying effect while absorbing sweat and sebum secreted from the foot when worn.

Description

대마양말 및 이의 제조방법Hemp Socks and Manufacturing Method thereof

본 발명은 대마(大麻: Hemp Fiber) 양말 및 이의 제조방법에 관한 것으로, 좀 더 상세하게는 착용시 발에서 분비되는 땀과 피지를 빨리 흡수함과 동시에 건조가 빠른 대마양말 및 이를 제조하는 방법에 관한 것이다.The present invention relates to hemp fiber socks and a method for manufacturing the same, and more particularly, to quickly absorbs sweat and sebum secreted from the foot when worn, and quickly dry hemp socks and a method of manufacturing the same. It is about.

마섬유의 종류는 식물에서 섬유를 채취하는 부위에 따라 인피섬유(bast fiber), 엽맥섬유(leaf fiber), 과실섬유(fruit fiber)등으로 구분하는데, 대마는 아마(flax 또는 linen), 저마(ramie), 황마(jute)등과 더불어 인피섬유에 해당한다.Hemp fibers are classified into bast fiber, leaf fiber and fruit fiber according to the part of the fiber harvested from the plant, and hemp is flax or linen, Along with ramie and jute, it corresponds to bast fiber.

일반적으로, 대마섬유는 다른 마섬유들에 비하여 다음과 같은 장점들을 가지고 있으므로 이러한 장점들이 마섬유 제품에 부가될 경우 종래의 마섬유 제품에서 찾을 수 없었던 새로운 기능을 확보할 수 있다고 판단된다.In general, hemp fibers have the following advantages over other hemp fibers, so that when these advantages are added to hemp fiber products, it may be possible to secure new functions not found in conventional hemp fiber products.

(1) 대마의 흡수성은 면, 아마보다 크고 대기의 보통상태에서 8∼12%(면은 5∼8%), 포화상태에서는 30%의 수분을 흡수한다(면은 14∼20%). 대마의 공정수분율은 12%(면은 8.5%)이다. 뿐만 아니라 대마는 면에 비하여 훨씬 수분흡수속도가 빠르며, 동시에 흡수된 수분의 발산성이 우수한 특징을 가지고 있다.(1) The absorbency of hemp is greater than cotton and flax, and it absorbs 8 to 12% of water in the normal state of the atmosphere (5 to 8% of cotton) and 30% of water in saturation (14 to 20% of cotton). Hemp process moisture is 12% (8.5% for cotton). In addition, hemp has a much faster water absorption rate than cotton, and at the same time, it has excellent water dissipation properties.

(2) 대마는 강력이 매우 크며(면의 3배, 아마의 1.5배) 내구성, 내수성이 풍부하다. 건조강도는 5∼8g/d 정도이며, 습윤시에는 본래의 강도보다 증가하는 특성이 있다.(2) Hemp is very strong (3 times of cotton and 1.5 times of flax) and is rich in durability and water resistance. The dry strength is about 5 to 8 g / d, and when wet, there is a characteristic of increasing the original strength.

(3) 대마의 신도는 1.5∼2.0%로 잘 늘어나지 않는다.(3) The elongation of hemp does not increase to 1.5 ~ 2.0%.

(4) 대마섬유의 표면은 왁스(wax)성이 적어서 까실까실하고 방적사의 경우 통풍성이 좋다.(4) The surface of hemp fiber has low wax, so it's hard to see.

(5) 대마섬유 자체가 항균성을 가지고 있는 것으로 알려져 있으며, 여기에 관한 많은 연구들이 진행되고 있다.(5) Hemp fibers themselves are known to have antimicrobial properties, and many studies are being conducted on them.

한편, 종래의 양말은 면을 주제로 하여 제조되었으나, 전술한 바와 같이 대마의 흡수성 및 발산성이 면보다 매우 우수하여 대마을 주제로 하는 제품이 개발될 경우, 기존의 면양말을 대체할 수 있을거라 판단된다. 그러나, 상기 대마섬유를 포함하는 마섬유는 기존에 Y셔츠류, 양장지, 스웨터 넥-타이, 남성정장용 등에 혼방사로 사용되어 왔으나, 착용시의 구김발생, 세탁견뢰도의 부족, 장기 착용시 품위손상, 내구성 부족 등 보완되어야 할 결점이 많이 발생되어 제품개발에 문제점이 많은 것으로 평가되어 왔다.On the other hand, the conventional socks were manufactured on the theme of cotton, but as described above, the absorbency and divergence of hemp is much better than cotton, so if hemp-themed products are developed, existing socks can be replaced. Judging. However, hemp fibers containing hemp fibers have been used as blend yarns for Y-shirts, dress papers, sweater neck-ties, men's suits, etc., but wrinkles during wearing, lack of fastness to washing, damage to dignity during long-term wearing, Many defects that need to be compensated for, such as lack of durability, have been evaluated as a lot of problems in product development.

따라서, 본 발명의 목적은 상술한 문제점을 해결할 수 있는 대마양말의 제조방법을 제공하는데 있다.Accordingly, it is an object of the present invention to provide a method for producing hemp socks that can solve the above problems.

본 발명의 다른 목적은 상기 방법으로 제조된 대마양말을 제공하는데 있다.Another object of the present invention to provide a hemp socks prepared by the above method.

상기 목적을 달성하기 위한 본 발명의 방법은 대마섬유를 약 38∼51mm의 크기로 절단한 다음, 상기 섬유 100중량부에 대하여 평활제 3∼8중량부, 유연제 7∼15중량부 및 대전방지제 0.5∼3중량부를 도포시켜 48시간이상 밀폐된 공간에서 보관하는 단계; 상기 대마섬유 20∼55중량% 및 면 20∼70중량%를 필수적으로 하고, 여기에 아크릴섬유 10∼30중량% 및/또는 울(wool) 10∼15중량%를 선택적으로 첨가시켜 혼합하는 단계; 및 개섬, 연조, 조방, 정방, 권사, 표백, 및 염색단계를 거쳐 40∼60℃로 유지되는 키토콜라-α 희석수에 함침시킨 다음, 건조시킨후, 110∼160℃에서 90초∼3분간 열처리시켜 편조 및 가공하는 단계로 이루어진다.The method of the present invention for achieving the above object is to cut the hemp fibers into a size of about 38 to 51mm, and then 3 to 8 parts by weight of a smoothing agent, 7 to 15 parts by weight of softener and antistatic agent based on 100 parts by weight of the fiber. Applying to 3 parts by weight to store in a closed space for more than 48 hours; 20 to 55% by weight of the hemp fibers and 20 to 70% by weight of cotton, and optionally adding 10-30% by weight of acrylic fibers and / or 10-15% by weight of wool to mix them; And impregnated with dilution of chitocola-α maintained at 40-60 ° C. through open-ispension, softening, spinning, spinning, spinning, bleaching, and dyeing, followed by drying, followed by drying at 110-160 ° C. for 90 seconds to 3 minutes. Heat treatment consists of braiding and processing.

이하, 본 발명을 좀 더 구체적으로 살펴보면 다음과 같다.Hereinafter, the present invention will be described in more detail.

먼저, 대마섬유에 효소처리하여 팩틴질을 제거하는 정련공정을 거쳐서 장섬유를 가지런한 형태로 유지시켜서 방적공정 진행에 적합하도록하여 섬유원료로서의 구비조건을 갖춘다. 그후, 면방적 공정에 알맞는 길이(38∼51mm)로 절단하여 타섬유와의 혼합이 잘 이루어지도록 하고, 연신(Drafting) 공정에 문제점이 없도록 한다. 대마섬유의 손상을 방지하고 마찰계수를 적절히 하기 위하여, 상기 대마섬유 100중량부에 대하여 평활제 3∼8중량부, 유연제 7∼15중량부 및 대전방지제 0.5∼3중량부를 예를 들어, 스프레이(Spray) 방식으로 도포시켜 오일링(Oiling)시킨다. 상기 평활제는 집속성 향상, 모우발생 및 롤러 감김방지, 절사방지, 수율향상 및 양말 편조시 절사방지를 목적으로 사용되며, 3중량부 미만이면 집속성 부족으로 감김현상 및 절사가 발생하여 방적성이 불량하며, 8중량부를 초과하면 기계 오물부착, 넵(Nep) 발생 및 균일도가 저하된다. 상기 유연제는 개섬시 분쇄방지, 손실감소 및 유연성 향상 등의 목적으로 사용되며, 7중량부 미만이면 손상이 많고, 섬유장이 짧아지며 방적성이 나쁘고, 손실이 많이 발생된다. 15중량부를 초과하면 상기 조건은 충족되나 방적시 집속성이 떨어져서 감김현상이나 절사 현상이 발생하여 방적성 나쁘다. 상기 대전방지제는 집속성 향상, 화기예방 및 실의 균정도 향상 등의 목적으로 사용되며, 0.5중량부 미만이면 정전기 발생으로 생산 및 품질이 저하되며, 3중량부를 초과하면 윤활성 및 집속성이 저하되는 단점이 잇다.First, through the refining process of enzymatic treatment of hemp fibers to remove the pectin, the long fibers are maintained in a neat form so that they are suitable for the spinning process, and thus, the fiber raw materials are provided. After that, it is cut to a length (38 to 51 mm) suitable for the surface spinning process so as to be mixed with other fibers well, and there is no problem in the stretching process. In order to prevent damage to the hemp fibers and appropriate friction coefficient, 3 to 8 parts by weight of the smoothing agent, 7 to 15 parts by weight of the softener and 0.5 to 3 parts by weight of the antistatic agent, for example, spray ( Apply oil by spray). The smoothing agent is used for the purpose of improving the focusing ability, preventing the occurrence of raising and rolling, preventing the cutting off, improving the yield, and preventing the cutting off when weaving socks, and if less than 3 parts by weight, the winding phenomenon and cutting occurs due to lack of focusing. This defect is poor, and if it exceeds 8 parts by weight, the adhesion of mechanical dirt, the generation of Neps, and the uniformity are reduced. The softening agent is used for the purpose of preventing grinding, reducing loss and improving flexibility during opening, and when less than 7 parts by weight, there are many damages, shorter fiber lengths, poor spinning properties, and a lot of losses. If the amount exceeds 15 parts by weight, the above conditions are satisfied, but the spinning property is poor, and the spinning phenomenon and the cutting phenomenon occur, resulting in poor spinning properties. The antistatic agent is used for the purpose of improving focusability, preventing fire, and improving the uniformity of the yarn. If the amount of the antistatic agent is less than 0.5 parts by weight, the production and quality are lowered. There are disadvantages.

상기 오일링시킨 대마원료에 상기 첨가제들이 골고루 침투, 분산되도록 샌드위치(Sandwich)식으로 적층시킨 상태에서 48시간 이상 밀폐된 공간에 보관한다.The additives are uniformly infiltrated and dispersed in the oiled hemp raw material and stored in a sealed space for at least 48 hours in a sandwiched manner.

그후, 상기 대마섬유 20∼55중량%에 면 20∼70중량%를 필수적으로 혼합시키고, 여기에 아크릴섬유 10∼30중량% 및/또는 울 10∼15중량%를 선택적으로 첨가시킨 조성물을 균일하게 혼합시켜 후속 공정에서 안정된 혼방효과가 나타나도록 한다. 이때, 상기 대마섬유가 20중량% 미만이면 흡습성과 발산성이 저하되어 대마특성이 희석되며, 55중량%를 초과하면 대마특성은 향상되나 내구성이 저하된다.Thereafter, 20 to 70% by weight of cotton is essentially mixed with 20 to 55% by weight of the hemp fiber, and a composition in which 10 to 30% by weight of acrylic fiber and / or 10 to 15% by weight of wool is selectively added thereto is uniformly added. Mixing results in a stable blending effect in subsequent processes. At this time, if the hemp fiber is less than 20% by weight, the hygroscopicity and divergence are lowered, and the hemp properties are diluted.

한편, 상기 조성물은 계절에 따라 그 조성이 변화될 수 있다. 예를 들어, 하절기에는 대마 30∼50중량% 및 면 50∼70중량%로 이루어진 조성물 또는 대마 20∼55중량%, 면 20∼50중량% 및 아크릴섬유 25∼30중량%로 이루어진 조성물이 바람직하며, 동절기에는 대마 20∼50중량%, 면 30∼70중량% 및 아크릴섬유 10∼20중량%로 이루어진 조성물 또는 대마 20∼30중량%, 면 35∼40중량%, 아크릴섬유 20∼30중량% 및 울 10∼15중량%로 이루어진 조성물이 바람직하다.On the other hand, the composition of the composition may be changed according to the season. For example, in summer, a composition consisting of 30-50% by weight of hemp and 50-70% by weight of cotton or 20-55% by weight of hemp, 20-50% by weight of cotton and 25-30% by weight of acrylic fiber is preferable. In winter, the composition consists of 20-50% by weight of hemp, 30-70% by weight and 10-20% by weight of acrylic fiber or 20-30% by weight of hemp, 35-40% by weight, 20-30% by weight of acrylic fiber, and Preference is given to a composition consisting of 10 to 15% by weight of wool.

본 발명에 따른 대마섬유와 타섬유를 혼합시킨 혼타면은 기존의 일반적인 공정인 개섬, 연조, 조방, 정방, 권사, 표백, 및 염색단계를 거친다. 이를 개략적으로 설명하면 다음과 같다.Honta cotton mixed with hemp fibers and other fibers according to the present invention is subjected to the existing general processes such as open island, softening, spinning, square, winding, bleaching, and dyeing. If this is outlined as follows.

개섬(Carding)Carding

상기 혼합된 섬유는 헝크러진 상태로 섬유의 배열이 불량하므로 배열을 좋게 하기 위하여 거치는 공정이며, 협잡물이나 단섬유도 제거하여 가지런한 상태로 만든다.Since the mixed fibers are poorly arranged in a hunked state, the fibers are processed to improve the alignment, and also remove impurities and short fibers to make them neat.

연조(Drawing)Drawing

상기 개섬공정에서 방출된 소면(Sliver)은 부풀은 상태로 균정도와 안정감이 없으므로 여러 가닥을 함께 공급하여 더블링(Doubling) 효과를 부여함으로서 배열성이 더욱 좋아지고 균정도가 향상되어 다음 공정에서 우수한 품질을 방출할 수 있다.Since the Sliver released from the opening process has no uniformity and stability in the swollen state, by supplying several strands together to give a doubling effect, the arrangement is better and the uniformity is improved, which is excellent in the next process. It can emit quality.

조방(Rovlng)Rovlng

상기 연조공정에서 방출된 소면을 좀 더 섬세하고 가늘게 만들어서 강력을 주고 적당한 꼬임을 주어 방적할 수 있도록 한다.The noodle released in the softening process is made more delicate and thin so as to give strength and moderate twist to spin.

정방(Spinnlng)Spinnlng

상기 조방에서 나온 조사를 원하는 굵기로 만들기 위하여 연신을 주고 가연(Twisting)을 하여 실을 만드는 공정이다.In order to make the irradiation from the scavenger to the desired thickness, it is a process of making yarn by stretching and twisting.

권사(Winding)Winding

상기 정방에서 나온 실은 결점부분(Thin, Thick, Slub 등)을 제거하여 후속 공정에서 편리하게 사용할 수 있도록 지관에 감아주는 공정이다.The yarn from the square is a process of winding the branch pipe to remove the defects (Thin, Thick, Slub, etc.) to be used conveniently in the subsequent process.

표백(Bleaching)Bleaching

과산화수소(H2O2)와 형광증백제를 잘 혼합하여 약 80℃에서 약 30분간 처리하여 증백효과가 뚜렷하도록 한다.Hydrogen peroxide (H 2 O 2 ) and the fluorescent brightener is mixed well and treated for about 30 minutes at about 80 ℃ to make the brightening effect clear.

염색(染色 : Dyeing)Dyeing

색상에 따라 반응성 염료 0.5∼2.0% 이상을 60∼80℃에서 1시간 30분∼2시간 동안 천연섬유 측면만 염색하여 은은하고 고유한 색상으로 만든다.Depending on the color, at least 0.5-2.0% of the reactive dyes are dyed only at the natural fiber side at 60-80 ° C. for 1 hour 30 minutes to 2 hours to produce a subtle and unique color.

상기 과정을 마친 섬유는 40∼60℃로 유지되는 키토콜라-α(Chitocolla-α) 희석수에 함침시켜 항균방취가공을 수행한다. 상기 키토콜라-α는 키토산과 콜라겐을 주제로 하여 분자내에 아미노기 등의 복합적인 반응성 관능기를 가지도록 중합한 키토-콜라 유도체로서, 실리콘 또는 우레탄수지를 바인더로 사용할 수 있는 특수 에멀존으로써, 다음과 같은 특성을 갖는다.After the above process, the fiber is impregnated with chitocolla-α (Chitocolla-α) diluted water maintained at 40 to 60 ° C. to perform antibacterial and deodorizing processing. The chitocola-α is a chito-colla derivative polymerized to have a complex reactive functional group such as an amino group in a molecule based on chitosan and collagen, and is a special emulsion that can use a silicone or urethane resin as a binder. Have the same characteristics.

① 항균방취성을 부여하여 섬유내에서 세균증식을 억제하고 방취효과가 지속되도록 한다.① It gives antibacterial deodorization to suppress bacterial growth in fiber and to keep deodorizing effect.

② 흡습 및 보습성이 뛰어나며 감촉을 부드럽게 한다.② It is excellent in moisture absorption and moisturizing and softens the texture.

③ 흡수성과 발산성이 우수하여 땀을 빠르게 흡수하고 발산시켜 주므로 항상 쾌적한 착용을 할 수 있게 한다.③ Absorption and divergence is excellent, so it absorbs and diverts sweat quickly so you can always wear comfortable.

④ 대전방지성이 탁월하여 신고 벗을 때 방전이 되며 먼지부착과 달라붙기가 없도록 한다.④ It has excellent antistatic property and discharges when it is removed and prevented from sticking to dust.

⑤ 세탁견뢰도가 우수하여 반복세탁시에도 질감이 변하지 안고 기능이 지속된다.⑤ It has excellent washing fastness and its function does not change even after repeated washing.

본 발명에서는 상기 키토콜라-α가 적어도 5중량% 이상 함유된 키토콜라-α 희석수에 상기 섬유를 함침시킨 다음, 상기 섬유를 짜고, 건조시킨후, 110∼160℃에서 90초∼3분간 열처리시킨 다음, 양말기(Hosiery Machine)를 일반용 양말, 사업용 양말, 산업용 양말, 및 각종 스포츠용 양말에 적합하도록 서로 다른 조직과 패턴으로 차별화시켜 제조하는 편조(Knitting)단계, 및 착용중에 수축으로 인한 변화를 없애기 위하여 생산된 양말제품을 가공하여 완성제품의 품위가 유지되도록 하는 가공(Steam setting)단계를 수행한다.In the present invention, the fiber is impregnated with dilution water of chitocola-α containing at least 5% by weight or more of the chitocola-α, and then the fibers are squeezed and dried, followed by heat treatment at 110 to 160 ° C. for 90 seconds to 3 minutes. Knitting step of differentiating and fabricating Hosiery Machine into different tissues and patterns to be suitable for general socks, business socks, industrial socks, and various sports socks, and changes due to shrinkage during wearing In order to eliminate the process of the sock products produced by the processing (Steam setting) step to maintain the finished product quality.

이하 실시예를 통하여 본 발명을 좀 더 구체적으로 살펴보지만, 하기 예에 본 발명의 범주가 한정되는 것은 아니다.Hereinafter, the present invention will be described in more detail with reference to the following examples, but the scope of the present invention is not limited to the following examples.

제조예(대마섬유의 제조)Production example (production of hemp fiber)

대마섬유에 효소처리하여 펙틴질을 제거하고 섬유길이를 38∼51mm로 절단하였다. 상기 섬유에 평활제 5중량%(중일화성 제품명 Neo Ramilon), 유연제 10중량%(중일화성 제품명 Neo Amine-901) 및 대전방지제 1중량%(중일화성 제품명 Anti Spin-700)을 스프레이 방식으로 도포하여 샌드위치식으로 적층시킨 상태에서 약 55시간 밀폐된 공간에 보관하여 전처리된 대마섬유를 제조하였다.The hemp fibers were enzymatically treated to remove pectin and the fiber length was cut to 38-51 mm. 5% by weight of the smoothing agent (neoplasticized product name Neo Ramilon), 10% by weight softener (neoplasticized product name Neo Amine-901) and 1% by weight of antistatic agent (anti-neutralized product name Anti Spin-700) was applied to the fiber by spraying Pre-treated hemp fibers were prepared by storing them in a closed space for about 55 hours in a sandwiched state.

실시예 1(하절기용 대마양말의 제조)Example 1 (production of hemp socks for summer)

상기 제조예의 대마섬유 40중량%, 면 35중량% 및 아크릴섬유 25중량%로 이루어진 조성물을 균일하게 혼합한 다음, 통상의 개섬, 연조, 조방, 정방 및 권사공정을 순차적으로 거쳐, 과산화수소(H2O2) 5%와 형광증백제 0.5%를 잘 혼합하여 약 80℃에서 약 30분간 표백시키고, 청색 반응성 염료(영국 ICI사 제품, Blue HEXL, Red HEGXL) 1중량%로 약 70℃에서 110분동안 천연섬유 측면만 염색하였다.The composition consisting of 40% by weight of hemp fiber, 35% by weight of cotton and 25% by weight of acrylic fiber of the manufacturing example was uniformly mixed, and then sequentially subjected to the normal opening, softening, spinning, spinning and winding processes, and hydrogen peroxide (H 2 O 2 ) 5% and 0.5% fluorescent whitening agent are mixed well and bleached at about 80 ° C. for about 30 minutes, and 1% by weight of a blue reactive dye (BCI, UK, Blue HEXL, Red HEGXL) is 110 minutes at about 70 ° C. Only the natural fiber side was dyed.

상기 염색된 섬유를 약 50℃로 유지되는 대양이화주식회사의 키토콜라-α 희석수에 함침시켜 항균방취가공을 수행하였다. 상기 키토콜라-α는 키토콜라-α-A 5중량%, 키토콜라-α-B 5중량% 및 물 90중량%로 이루어졌다. 그후, 상기 섬유를 짜고, 건조시킨후, 약 140℃에서 2분간 열처리시킨 다음, 양말기를 이용하여 일반용 양말을 제조하였다.The dyed fiber was impregnated with dilution water of Chitocola-α of Dion Co., Ltd., which is maintained at about 50 ° C., to carry out antibacterial and deodorization processing. The chitocola-α consisted of 5% by weight of chitocola-α-A, 5% by weight of chitocola-α-B and 90% by weight of water. Thereafter, the fibers were squeezed, dried, and then heat treated at about 140 ° C. for 2 minutes, and then general socks were manufactured using a hosiery machine.

실시예 2(하절기용 대마양말의 제조)Example 2 (Production of Summer Hemp Socks)

상기 실시예 1에서 섬유조성울을 대마 40중량% 및 면 60중량%로한 것을 제외하고는 동일하게 수행하였다.Except that the fiber composition wool in Example 1 40% by weight and 60% by weight cotton was performed in the same manner.

실시예 3(동절기용 대마양말의 제조)Example 3 (Manufacture of Hemp Socks for Winter)

상기 실시예 1에서 섬유조성을 대마 25중량%, 면 37중량%, 아크릴 섬유 25중량% 및 울 13중량%로 한 것을 제외하고는 동일하게 수행하였다.The fiber composition was performed in the same manner as in Example 1 except that hemp 25%, cotton 37%, acrylic fiber 25%, and wool 13% by weight.

실시예 4(동절기용 대마양말의 제조)Example 4 (Manufacture of Hemp Socks for Winter)

상기 실시예 1에서 섬유조성을 대마 40중량%, 면 45중량% 및 아크릴섬유 15중량%로한 것을 제외하고는 동일하게 수행하였다.Except that the fiber composition in Example 1 40% by weight, 45% by weight cotton and 15% by weight acrylic fiber was performed in the same manner.

한편, 상기 실시예 1 내지 4의 대마양말과 시판되는 면양말의 항균방취성, 흡습 및 보습성, 흡수성과 발산성, 대전방지제 및 세탁견뢰도를 측정하여 그 결과를 하기 표1에 기재하였다.On the other hand, the antibacterial deodorization, hygroscopicity and moisture retention, absorbency and divergence, antistatic agent and wash fastness of the hemp socks and commercially available cotton socks of Examples 1 to 4 are described in Table 1 below.

상기 측정항목의 측정방법은 다음과 같다.The measuring method of the said measurement item is as follows.

1) 항균방취성: 상기 실시예 1 내지 4의 시편(이하 “시험편”이라함)과 시판 면양말의 시편(이하 “대조편”이라함)에 공시균을 각각 접종, 배양시킨후, 각각의 액체배치에서 진탕 배양한 다음, 각 액체배지내의 세균수를 측정하였고, 항균성 있는 시험편에서 세균감소율을 계산하였다.1) Antibacterial deodorization: After inoculating and incubating each of the specimens of Examples 1 to 4 (hereinafter referred to as "test specimen") and commercially available cotton socks (hereinafter referred to as "control"), respectively, After shaking culture in the liquid batch, the number of bacteria in each liquid medium was measured, and the rate of bacterial reduction in the antimicrobial test piece was calculated.

·방취도: 시험편과 대조편을 5컬레씩 10시간 이상 착용한후, 숙련된 검사요원에 의해 동일한 조건하에서 취기를 확인하였다.Deodorization: The test piece and the control piece were worn at five colors for 10 hours or more, and odor was confirmed under the same conditions by a skilled inspector.

2) 흡습 및 보습성: 시험편과 대조편을 한 시험병에 동시에 넣고 약 3시간동안 교반한 후, 상기 시험편과 대조편을 길이방향으로 링거를 통과시킨 다음, 2장의 흡수지 사이에 넣고, 이것을 링거의 롤러 사이로 통과시킨후, 무게를 아는 용기에 넣고 0.1g까지 정확히 무게를 측정하였다.2) Hygroscopicity and Moisturizing: The test piece and the control piece were simultaneously placed in one test bottle and stirred for about 3 hours. The test piece and the control piece were passed through the ringer in the longitudinal direction, and then placed between two absorbent papers. After passing through the rollers, the weight was placed in a container with a known weight to accurately weigh 0.1g.

3) 흡수성과 발산성: 시험편과 대조편을 초하중(최소 규정 절단 하중의 1%)하에서 38.1cm되게 표시하고 시료에 가한 초하중을 풀고 표시한 부분을 정확히 절단한다. 또한 시험편의 양끝에서 각각 7.6cm되게 불용성 잉크로 정확히 표시한다. 시험편은 0.1g까지 무게를 측정하고, 상기 시험편을 루프형태로 하여 상기 루프를 실온에서 증류수가 담긴 용기속에 첨지시키되, 표시한 부분이 수면과 일치할때 까지 물에 잠기게 하고 절단 부분이 수면 밖으로 나오게 한다. 시험편은 24시간 침지시킨다. 시험편을 꺼내어 표시한 부분을 잘라서 물에 침지하지 않은 부분을 제거한다. 시험편은 통풍이 원활한 표준상태의 방에서 여분의 물을 제거하기 위하여 철망에 얹어 놓는다. 물기를 제거하는 동안 시험편을 수평으로 뉘어 놓고, 시료를 1.5시간 방치한다. 1.5시간 후 시험편의 중량을 측정하여 수분 흡수량을 기록하였다.3) Absorption and divergence: Mark the specimen and the control piece at 38.1 cm under the super load (at least 1% of the specified cutting load), untie the super load applied to the sample and cut the marked part correctly. In addition, it is precisely marked with insoluble ink so that each end of the specimen is 7.6 cm. The specimen is weighed up to 0.1 g, and the specimen is in the form of a loop, and the loop is placed in a container of distilled water at room temperature, submerged in water until the marked portion coincides with the water surface, and the cut portion is out of the water surface. To come out. The specimen is immersed for 24 hours. Take out the specimen and cut the marked part to remove the part not immersed in water. The specimens are placed on a wire mesh to remove excess water in a standard room with good ventilation. Lay the specimen horizontally while removing water and leave the sample for 1.5 hours. After 1.5 hours, the weight of the test piece was measured and the moisture absorption amount was recorded.

4) 대전방지성: 시험편과 대조편을 마찰포로 마찰 대전시켜 금속판에 달라붙게 한다음 떨어 뜨림과 달라붙임을 반복해서 더이상 달라붙지 않을때 까지의 시간을 측정하였다.4) Antistatic property: The test pieces and the control pieces were frictionally charged with a friction cloth to stick to the metal plate, and then the time until the bonds were no longer stuck was repeated.

5) 세탁견뢰도: 시험편과 대조편을 세탁액에 넣어 10회 세탁하고, 건조시킨 다음, 시험편의 변퇴색과 오염정도를 각각 변퇴색용 표준 회색 색표 또는 오염용 표준 회색 색표와 비교하여 그 견뢰도를 판정하였다.5) Wash fastness: Wash the test piece and the control piece in the washing solution for 10 times, dry them, and compare the color fading and contamination of the test piece with the standard gray color table for the color fading or the standard gray color table for the contamination. Determined.

상기 표1로부터 알 수 있는 바와 같이, 본 발명에 따른 대마양말은 흡수성과 발산성을 동시에 가지고 있으므로 착용시 발에서 분비되는 땀과 피지를 빨리 흡수함과 동시에 건조가 빠르도록 해준다. 또한, 높은 열전도성을 가지는 대마섬유는 여름철에 독특한 냉감효과를 가지며, 동절기용으로 제조한 것은 울을 혼합하여 보온성을 증대시켜 준다. 대마 특유의 항균성과 더불어 항균방취가공제로 사용한 키토콜라-α의 성능에 의하여 무좀, 습진, 진균성 질환 등을 예방할 수 있고, 대마섬유의 표면재질에 의하여 장시간 착용하더라도 발바닥이 포송포송하고 악취가 발생하지 않는 장점을 가지고 있는 위생적이며 새로운 차원의 양말이다.As can be seen from Table 1, the hemp socks according to the present invention has both absorbency and divergence at the same time, so that the sweat and sebum secreted from the foot when worn quickly and at the same time dry quickly. In addition, hemp fiber having high thermal conductivity has a unique cooling effect in summer, and manufactured for the winter season increases the heat retention by mixing wool. The ability of chitocola-α used as an antibacterial and deodorizing agent in addition to the hemp's unique antibacterial properties prevents athlete's foot, eczema and fungal diseases. It is a hygienic new level of socks with advantages that do not occur.

Claims (7)

대마섬유를 38∼51mm의 크기로 절단한 다음, 상기 섬유 100중량부에 대하여 평활제 3∼8중량부, 유연제 7∼15중량부 및 대전방지제 0.5∼3중량부를 도포시켜 48시간이상 밀폐된 공간에서 보관하는 단계;Hemp fibers are cut to a size of 38 to 51 mm, and then 3 to 8 parts by weight of smoothing agent, 7 to 15 parts by weight of softener and 0.5 to 3 parts by weight of antistatic agent are applied to 100 parts by weight of the fiber, and the space is enclosed for more than 48 hours. Storing in; 상기 대마섬유 20∼55중량% 및 면 20∼70중량%를 필수적으로 하고, 여기에 아크릴섬유 10∼30중량% 및 10∼15중량%를 선택적으로 혼합하는 단계; 및20 to 55% by weight of the hemp fibers and 20 to 70% by weight of cotton, optionally mixing 10 to 30% by weight and 10 to 15% by weight acrylic fibers; And 개섬, 연조, 조방, 정방, 권사, 표백 및 염색단계를 거쳐 40∼60℃로 유지되는 키토콜라-α 희석수에 함침시킨 다음, 건조시킨후, 110∼160℃에서 90초∼3분간 열처리시켜 편조 및 가공하는 단계로 이루어지는 것을 특징으로 하는 대마양말의 제조방법.Impregnated with dilution water of chitocola-α maintained at 40-60 ° C. through opening, softening, spinning, spinning, spinning, bleaching, and dyeing steps, and then drying and heat-processing at 110-160 ° C. for 90 seconds to 3 minutes. Hemp socks manufacturing method comprising the steps of braiding and processing. 제1항에 있어서, 상기 혼합단계에서 대마 30∼50중량% 및 면 50∼70중량%로 이루어져 하절기용으로 사용됨을 특징으로 하는 대마양말의 제조방법.The method of claim 1, wherein the mixing step consists of hemp 30 to 50% by weight and cotton 50 to 70% by weight used for the summer season. 제1항에 있어서, 상기 혼합단계에서 대마 20∼55중량%, 면 20∼50중량% 및 아크릴섬유 25∼30중량%로 이루어져 하절기용으로 사용됨을 특징으로 하는 대마양말의 제조방법.The method of claim 1, wherein the mixing step is made of hemp 20 to 55% by weight, cotton 20 to 50% by weight and acrylic fiber 25 to 30% by weight used for the summer season. 제1항에 있어서, 상기 혼합단계에서 대마 20∼50중량%, 면 30∼70중량% 및 아크릴섬유 10∼20중량%로 이루어져 동절기용으로 사용됨을 특징으로 하는 대마양말의 제조방법.The method of claim 1, wherein the mixing step comprises hemp 20 to 50% by weight, cotton 30 to 70% by weight and acrylic fiber 10 to 20% by weight used for the winter season. 제1항에 있어서, 상기 혼합단계에서 대마 20∼30중량%, 면 35∼40중량%, 아크릴섬유 20∼30중량% 및 울 10∼15중량%로 이루어져 하절기용으로 사용됨을 특징으로 하는 대마양말의 제조방법.The hemp socks according to claim 1, wherein the hemp socks are used for the summer season in the mixing step, comprising 20 to 30 wt% of hemp, 35 to 40 wt% of cotton, 20 to 30 wt% of acrylic fiber, and 10 to 15 wt% of wool. Manufacturing method. 제1항에 있어서, 상기 키토콜라-α 희석수가 키토콜라-α를 5중량% 함유하는 것을 특징으로 하는 대마양말의 제조방법.The method of claim 1, wherein the dilution of chitocola-α contains 5% by weight of chitocola-α. 제1항 내지 제6항중 어느 한 항의 방법으로 제조된 것을 특징으로 하는 대마양말.A hemp sock prepared by the method of any one of claims 1 to 6.
KR1019950021412A 1995-07-20 1995-07-20 Hemp hosiery and process for its manufacture KR0137508B1 (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100746168B1 (en) * 2005-12-13 2007-08-03 김동욱 a socks
KR100806033B1 (en) * 2007-04-18 2008-02-26 김주환 Sanitary cloth made of hemp
KR101031718B1 (en) * 2008-06-30 2011-05-04 한국실크연구원 Mixed yarn of silk and ramie, method for producing mixed yarn of silk and ramie
KR101459235B1 (en) * 2013-06-19 2014-11-12 삼일방직주식회사 Hemp-blended air-jet spun yarn and process of producing thereof

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114732174A (en) * 2022-03-22 2022-07-12 浙江凯诗利科技有限公司 Preparation method of sweat-absorbing and breathable socks

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100746168B1 (en) * 2005-12-13 2007-08-03 김동욱 a socks
KR100806033B1 (en) * 2007-04-18 2008-02-26 김주환 Sanitary cloth made of hemp
WO2008130099A1 (en) * 2007-04-18 2008-10-30 Ju-Hwan Kim Sanitary cloth made of hemp
KR101031718B1 (en) * 2008-06-30 2011-05-04 한국실크연구원 Mixed yarn of silk and ramie, method for producing mixed yarn of silk and ramie
KR101459235B1 (en) * 2013-06-19 2014-11-12 삼일방직주식회사 Hemp-blended air-jet spun yarn and process of producing thereof

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