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Syntheses and Structural Characterizations of Two New Cu-S Clusters of Dialkyl Dithiophosphates: A Sulfide-Centered CuI8 Cube,{Cu8 [S2P (OiPr) 2] 6 (. mu. 8-S)}, and a Distorted Octahedral {Cu6 [S2P (OEt) 2] 6. cntdot. 2H2O} Cluster
A second-order nonlinear optical material with a 5-fold interpenetrating diamondoid framework based on two achiral precursors: spontaneous resolution to absolute chiral induction
[Cr (d pa)(ox) 2]−: a new bis-oxalato building block for the design of heteropolymetallic systems. Crystal structures and magnetic properties of PPh 4 [Cr (dpa)(ox) 2], AsPh 4 [Cr (dpa)(ox) 2], Hdpa [Cr (dpa)(ox) 2]· 4H 2 O, Rad [Cr (dpa)(ox) 2]· H 2 O and Sr [Cr (dpa)(ox) 2] 2· 8H 2 O (dpa= 2, 2′-dipyridylamine)
The solvothermal synthesis and characterization of quaternary arsenic chalcogenides CsTMAsQ 3 (TM= Hg, Cd; Q= S, Se) using Cs+ as a structure directing agent: from 1D anionic chains to 2D anionic layers
Unprecedented 3D polycatenation based on ribbons of rings found in two metallosupramolecular polymers whose open frameworks show reversible collapse upon de-and rehydration
The phenomenon of conglomerate crystallization. 24. Spontaneous resolution in coordination compounds. Classical and spontaneous resolution of the amminebromobis (ethylenediamine) cobalt (2+) cation. Crystal structures and absolute configurations of resolved (+) 589-[cis-. LAMBDA.(. delta.. lambda.)-Co (en) 2 (NH3) Br] S4O6 (I) and of conglomerate crystals of [cis-. LAMBDA.(. delta.. lambda.)-Co (en) 2 (NH3) Br] S4O6 (II)