JPWO2022185838A5 - - Google Patents

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JPWO2022185838A5
JPWO2022185838A5 JP2022536568A JP2022536568A JPWO2022185838A5 JP WO2022185838 A5 JPWO2022185838 A5 JP WO2022185838A5 JP 2022536568 A JP2022536568 A JP 2022536568A JP 2022536568 A JP2022536568 A JP 2022536568A JP WO2022185838 A5 JPWO2022185838 A5 JP WO2022185838A5
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carbonaceous
mass
producing
less
graphite material
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JP2022536568A
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JP7210810B1 (en
JPWO2022185838A1 (en
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Priority claimed from PCT/JP2022/004421 external-priority patent/WO2022185838A1/en
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Claims (6)

メソフェーズ小球体焼成物を粉砕する粉砕工程と、
前記粉砕工程で得られた粉砕物を、珪素元素および鉄元素の存在下で黒鉛化する黒鉛化工程と、
前記黒鉛化工程で得られた黒鉛化物を解砕する解砕工程と、
前記解砕工程で得られた解砕物に炭素質前駆体を付着させる付着工程と、
前記炭素質前駆体が付着した前記解砕物を焼成することにより、前記炭素質前駆体を炭素質にして、前記炭素質で前記解砕物を被覆する被覆工程と、を備え
前記解砕工程がメカノケミカル処理からなる、炭素質被覆黒鉛材料の製造方法。
a pulverizing step of pulverizing the fired mesophase spherules;
A graphitization step of graphitizing the pulverized product obtained in the pulverization step in the presence of elemental silicon and elemental iron;
A crushing step of crushing the graphitized material obtained in the graphitization step;
an attaching step of attaching a carbonaceous precursor to the crushed material obtained in the crushing step;
a coating step of calcining the crushed material to which the carbonaceous precursor is attached to convert the carbonaceous precursor into a carbonaceous material and coat the crushed material with the carbonaceous material ;
A method for producing a carbonaceous-coated graphite material , wherein the crushing step comprises a mechanochemical treatment .
前記粉砕物の平均粒子径が10.0μm以上、20.0μm以下である請求項1に記載の炭素質被覆黒鉛材料の製造方法。 The method for producing a carbonaceous-coated graphite material according to claim 1, wherein the pulverized material has an average particle size of 10.0 µm or more and 20.0 µm or less. 前記珪素元素の添加量が前記粉砕物100質量部に対し1質量部以上、5質量部以下であり、
前記鉄元素の添加量が前記粉砕物100質量部に対し1質量部以上、5質量部以下である請求項1または2に記載の炭素質被覆黒鉛材料の製造方法。
The addition amount of the silicon element is 1 part by mass or more and 5 parts by mass or less with respect to 100 parts by mass of the pulverized material,
3. The method for producing a carbonaceous-coated graphite material according to claim 1, wherein the iron element is added in an amount of 1 part by mass or more and 5 parts by mass or less with respect to 100 parts by mass of the pulverized material.
前記炭素質の被覆量が0.5~15.0質量%である、請求項1~のいずれか1項に記載の炭素質被覆黒鉛材料の製造方法。 The method for producing a carbonaceous-coated graphite material according to any one of claims 1 to 3 , wherein the carbonaceous coating amount is 0.5 to 15.0% by mass. 前記黒鉛材料の平均粒子径が10.0μm以上、20.0μm以下、d002が0.3360nm以下、BET法による比表面積が2.0m2/g以上、水銀圧入法で測定される0.1μm未満の細孔容積が10.0μL/g以上である請求項1~のいずれか1項に記載の炭素質被覆黒鉛材料の製造方法。 The graphite material has an average particle size of 10.0 μm or more and 20.0 μm or less, d 002 of 0.3360 nm or less, a specific surface area of 2.0 m 2 /g or more by BET method, and 0.1 μm measured by mercury porosimetry. The method for producing a carbonaceous-coated graphite material according to any one of claims 1 to 4 , wherein the pore volume of less than 10.0 µL/g or more. 前記黒鉛材料がリチウムイオン二次電池の負極材料である請求項1~のいずれか1項に記載の炭素質被覆黒鉛材料の製造方法。 The method for producing a carbonaceous-coated graphite material according to any one of claims 1 to 5 , wherein the graphite material is a negative electrode material for a lithium ion secondary battery.
JP2022536568A 2021-03-01 2022-02-04 Method for producing carbonaceous coated graphite material Active JP7210810B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2021031718 2021-03-01
JP2021031718 2021-03-01
PCT/JP2022/004421 WO2022185838A1 (en) 2021-03-01 2022-02-04 Method for producing carbonaceous substance-coated graphite material

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JPWO2022185838A1 JPWO2022185838A1 (en) 2022-09-09
JP7210810B1 JP7210810B1 (en) 2023-01-23
JPWO2022185838A5 true JPWO2022185838A5 (en) 2023-02-01

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JP (1) JP7210810B1 (en)
KR (1) KR20220125255A (en)
CN (1) CN115279694A (en)
TW (1) TWI796149B (en)
WO (1) WO2022185838A1 (en)

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2884746B2 (en) 1990-09-03 1999-04-19 松下電器産業株式会社 Non-aqueous electrolyte secondary battery
WO1997018160A1 (en) * 1995-11-14 1997-05-22 Osaka Gas Company Limited Cathode material for lithium secondary battery, process for manufacturing the same, and secondary battery using the same
JP2000090928A (en) * 1998-09-11 2000-03-31 Nippon Steel Corp Manufacture of highly graphitized carbon powder for lithium secondary battery negative electrode
JP4672958B2 (en) * 2002-10-10 2011-04-20 Jfeケミカル株式会社 Graphite particles, lithium ion secondary battery, negative electrode material therefor and negative electrode
JP4689391B2 (en) 2005-07-28 2011-05-25 Jfeケミカル株式会社 Method for producing graphite material for negative electrode material of lithium ion secondary battery
JP4707570B2 (en) 2006-01-20 2011-06-22 Jfeケミカル株式会社 Method for producing fine graphite particles
JP6240586B2 (en) * 2014-10-28 2017-11-29 Jfeケミカル株式会社 Graphite particles for negative electrode material of lithium ion secondary battery, negative electrode of lithium ion secondary battery and lithium ion secondary battery
JP6412520B2 (en) * 2015-06-01 2018-10-24 Jfeケミカル株式会社 Carbonaceous coated graphite particles for lithium ion secondary battery anode material, lithium ion secondary battery anode and lithium ion secondary battery
CN112424118A (en) * 2019-06-13 2021-02-26 杰富意化学株式会社 Method for producing monolithic mesophase graphitized article

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