JPWO2021209268A5

JPWO2021209268A5 -

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Publication number: JPWO2021209268A5
Authority: JP; Japan
Prior art keywords: alkyl; hydrogen; alkoxy; cyano; group
Prior art date: 2024-04-11
Legal status : Pending

Application number

JP2022562283A

Other languages

English (en)

Japanese (ja)

Other versions

JP2023521819A (ja

Publication date

2024-04-11

2021-04-01 Application filed filed Critical

2021-04-01 Priority claimed from PCT/EP2021/058569 external-priority patent/WO2021209268A1/en

2023-05-25 Publication of JP2023521819A publication Critical patent/JP2023521819A/ja

2024-04-11 Publication of JPWO2021209268A5 publication Critical patent/JPWO2021209268A5/ja

Status Pending legal-status Critical Current

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150000001875 compounds Chemical class 0.000 claims description 415
239000001257 hydrogen Substances 0.000 claims description 323
229910052739 hydrogen Inorganic materials 0.000 claims description 323
239000011737 fluorine Substances 0.000 claims description 198
229910052731 fluorine Inorganic materials 0.000 claims description 198
-1 nitro, hydroxyl Chemical group 0.000 claims description 187
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 175
239000000460 chlorine Chemical group 0.000 claims description 168
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical group [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 167
229910052801 chlorine Inorganic materials 0.000 claims description 167
125000004093 cyano group Chemical group *C#N 0.000 claims description 160
125000006273 (C1-C3) alkyl group Chemical group 0.000 claims description 154
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 145
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 145
229910052794 bromium Inorganic materials 0.000 claims description 145
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 132
229910052736 halogen Inorganic materials 0.000 claims description 128
150000002367 halogens Chemical group 0.000 claims description 128
PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 112
125000006583 (C1-C3) haloalkyl group Chemical group 0.000 claims description 107
125000004169 (C1-C6) alkyl group Chemical group 0.000 claims description 101
230000002363 herbicidal effect Effects 0.000 claims description 99
125000001153 fluoro group Chemical group F* 0.000 claims description 86
239000000203 mixture Substances 0.000 claims description 86
125000006677 (C1-C3) haloalkoxy group Chemical group 0.000 claims description 82
125000006274 (C1-C3)alkoxy group Chemical group 0.000 claims description 80
125000005913 (C3-C6) cycloalkyl group Chemical group 0.000 claims description 77
125000006536 (C1-C2)alkoxy group Chemical group 0.000 claims description 72
125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 61
125000004432 carbon atom Chemical group C* 0.000 claims description 57
239000004009 herbicide Substances 0.000 claims description 57
125000004191 (C1-C6) alkoxy group Chemical group 0.000 claims description 52
238000009472 formulation Methods 0.000 claims description 47
125000001424 substituent group Chemical group 0.000 claims description 45
150000002148 esters Chemical class 0.000 claims description 40
229920006395 saturated elastomer Polymers 0.000 claims description 38
150000003839 salts Chemical class 0.000 claims description 37
125000006592 (C2-C3) alkenyl group Chemical group 0.000 claims description 36
125000004399 C1-C4 alkenyl group Chemical group 0.000 claims description 34
125000006650 (C2-C4) alkynyl group Chemical group 0.000 claims description 33
238000000034 method Methods 0.000 claims description 32
229910052702 rhenium Inorganic materials 0.000 claims description 30
125000004430 oxygen atom Chemical group O* 0.000 claims description 29
125000006645 (C3-C4) cycloalkyl group Chemical group 0.000 claims description 28
125000006593 (C2-C3) alkynyl group Chemical group 0.000 claims description 27
125000006552 (C3-C8) cycloalkyl group Chemical group 0.000 claims description 22
125000004455 (C1-C3) alkylthio group Chemical group 0.000 claims description 19
125000003601 C2-C6 alkynyl group Chemical group 0.000 claims description 19
125000000217 alkyl group Chemical group 0.000 claims description 19
125000006595 (C1-C3) alkylsulfinyl group Chemical group 0.000 claims description 16
125000006555 (C3-C5) cycloalkyl group Chemical group 0.000 claims description 15
241000347391 Umbrina cirrosa Species 0.000 claims description 15
125000003118 aryl group Chemical group 0.000 claims description 15
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 15
125000004400 (C1-C12) alkyl group Chemical group 0.000 claims description 13
125000006660 (C3-C4) halocycloalkyl group Chemical group 0.000 claims description 13
125000004043 oxo group Chemical group O=* 0.000 claims description 13
125000004433 nitrogen atom Chemical group N* 0.000 claims description 12
229910052717 sulfur Inorganic materials 0.000 claims description 12
125000004434 sulfur atom Chemical group 0.000 claims description 12
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 11
150000001408 amides Chemical class 0.000 claims description 11
125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 claims description 11
239000011593 sulfur Substances 0.000 claims description 11
125000006710 (C2-C12) alkenyl group Chemical group 0.000 claims description 10
125000006711 (C2-C12) alkynyl group Chemical group 0.000 claims description 10
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 10
229910052799 carbon Inorganic materials 0.000 claims description 10
125000006526 (C1-C2) alkyl group Chemical group 0.000 claims description 9
125000004209 (C1-C8) alkyl group Chemical group 0.000 claims description 9
125000000882 C2-C6 alkenyl group Chemical group 0.000 claims description 8
125000004648 C2-C8 alkenyl group Chemical group 0.000 claims description 8
125000004649 C2-C8 alkynyl group Chemical group 0.000 claims description 8
239000002671 adjuvant Substances 0.000 claims description 8
125000003545 alkoxy group Chemical group 0.000 claims description 8
150000007970 thio esters Chemical class 0.000 claims description 8
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 7
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 4
239000011630 iodine Chemical group 0.000 claims description 4
229910052740 iodine Inorganic materials 0.000 claims description 4
125000003170 phenylsulfonyl group Chemical group C1(=CC=CC=C1)S(=O)(=O)* 0.000 claims description 4
150000002431 hydrogen Chemical group 0.000 claims 22
150000003254 radicals Chemical class 0.000 description 74
241000196324 Embryophyta Species 0.000 description 49
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 36
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 30
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 28
ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 27
239000003112 inhibitor Substances 0.000 description 21
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 21
108090000623 proteins and genes Proteins 0.000 description 21
WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 18
239000013543 active substance Substances 0.000 description 18
244000038559 crop plants Species 0.000 description 18
235000014113 dietary fatty acids Nutrition 0.000 description 16
239000000194 fatty acid Substances 0.000 description 16
229930195729 fatty acid Natural products 0.000 description 16
239000000243 solution Substances 0.000 description 16
150000001412 amines Chemical class 0.000 description 15
239000003960 organic solvent Substances 0.000 description 15
108700019146 Transgenes Proteins 0.000 description 14
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 14
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 13
235000010469 Glycine max Nutrition 0.000 description 13
244000068988 Glycine max Species 0.000 description 13
238000006243 chemical reaction Methods 0.000 description 12
241000219146 Gossypium Species 0.000 description 11
239000000463 material Substances 0.000 description 11
239000004094 surface-active agent Substances 0.000 description 11
238000012360 testing method Methods 0.000 description 11
238000011282 treatment Methods 0.000 description 11
229920000742 Cotton Polymers 0.000 description 10
240000008042 Zea mays Species 0.000 description 10
230000015572 biosynthetic process Effects 0.000 description 10
239000000839 emulsion Substances 0.000 description 10
150000004665 fatty acids Chemical class 0.000 description 10
239000011541 reaction mixture Substances 0.000 description 10
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 9
235000002595 Solanum tuberosum Nutrition 0.000 description 9
244000061456 Solanum tuberosum Species 0.000 description 9
ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical group CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 9
238000010790 dilution Methods 0.000 description 9
239000012895 dilution Substances 0.000 description 9
230000000694 effects Effects 0.000 description 9
235000019198 oils Nutrition 0.000 description 9
239000000843 powder Substances 0.000 description 9
239000000047 product Substances 0.000 description 9
230000009261 transgenic effect Effects 0.000 description 9
JGFZNNIVVJXRND-UHFFFAOYSA-N N,N-Diisopropylethylamine (DIPEA) Chemical compound CCN(C(C)C)C(C)C JGFZNNIVVJXRND-UHFFFAOYSA-N 0.000 description 8
235000002017 Zea mays subsp mays Nutrition 0.000 description 8
239000003086 colorant Substances 0.000 description 8
238000002703 mutagenesis Methods 0.000 description 8
231100000350 mutagenesis Toxicity 0.000 description 8
239000007787 solid Substances 0.000 description 8
239000007921 spray Substances 0.000 description 8
150000003871 sulfonates Chemical class 0.000 description 8
REGOCDRDNZNRMC-UHFFFAOYSA-N 3-ethoxy-2-methyl-3-oxopropanoic acid Chemical compound CCOC(=O)C(C)C(O)=O REGOCDRDNZNRMC-UHFFFAOYSA-N 0.000 description 7
241000238631 Hexapoda Species 0.000 description 7
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 7
240000006394 Sorghum bicolor Species 0.000 description 7
235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 7
239000002253 acid Chemical class 0.000 description 7
239000004480 active ingredient Substances 0.000 description 7
150000001721 carbon Chemical group 0.000 description 7
235000005822 corn Nutrition 0.000 description 7
239000002270 dispersing agent Substances 0.000 description 7
229910052757 nitrogen Inorganic materials 0.000 description 7
IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 7
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 7
239000003921 oil Substances 0.000 description 7
239000002904 solvent Substances 0.000 description 7
150000003467 sulfuric acid derivatives Chemical class 0.000 description 7
239000000725 suspension Substances 0.000 description 7
239000000080 wetting agent Substances 0.000 description 7
238000005160 1H NMR spectroscopy Methods 0.000 description 6
235000006008 Brassica napus var napus Nutrition 0.000 description 6
244000020551 Helianthus annuus Species 0.000 description 6
235000003222 Helianthus annuus Nutrition 0.000 description 6
WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 6
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
240000007594 Oryza sativa Species 0.000 description 6
235000007164 Oryza sativa Nutrition 0.000 description 6
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 6
125000003342 alkenyl group Chemical group 0.000 description 6
150000004945 aromatic hydrocarbons Chemical class 0.000 description 6
150000001735 carboxylic acids Chemical class 0.000 description 6
JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 6
239000004495 emulsifiable concentrate Substances 0.000 description 6
239000003995 emulsifying agent Substances 0.000 description 6
USFNHCHDFXTCST-UHFFFAOYSA-N ethyl 3-(3,5-difluoroanilino)-2-methyl-3-oxopropanoate Chemical compound CCOC(=O)C(C)C(=O)NC1=CC(F)=CC(F)=C1 USFNHCHDFXTCST-UHFFFAOYSA-N 0.000 description 6
229910052938 sodium sulfate Inorganic materials 0.000 description 6
235000011152 sodium sulphate Nutrition 0.000 description 6
238000003786 synthesis reaction Methods 0.000 description 6
QWWHRELOCZEQNZ-UHFFFAOYSA-N 2,2-dichloro-1-(1-oxa-4-azaspiro[4.5]decan-4-yl)ethanone Chemical compound ClC(Cl)C(=O)N1CCOC11CCCCC1 QWWHRELOCZEQNZ-UHFFFAOYSA-N 0.000 description 5
108010000700 Acetolactate synthase Proteins 0.000 description 5
244000105624 Arachis hypogaea Species 0.000 description 5
235000010777 Arachis hypogaea Nutrition 0.000 description 5
240000002791 Brassica napus Species 0.000 description 5
HZLLQZQWRKZOQV-UHFFFAOYSA-N ClC=1C=C(C=C(C=1)Cl)N1C(C(C1)(C(=O)OCC)C)=O Chemical compound ClC=1C=C(C=C(C=1)Cl)N1C(C(C1)(C(=O)OCC)C)=O HZLLQZQWRKZOQV-UHFFFAOYSA-N 0.000 description 5
VIPSUSCESBPEQM-UHFFFAOYSA-N FC=1C=C(C=C(C=1)F)N1C(C(C1)(C(=O)OCC)C)=O Chemical compound FC=1C=C(C=C(C=1)F)N1C(C(C1)(C(=O)OCC)C)=O VIPSUSCESBPEQM-UHFFFAOYSA-N 0.000 description 5
239000005562 Glyphosate Substances 0.000 description 5
YNQSILKYZQZHFJ-UHFFFAOYSA-N R-29148 Chemical compound CC1CN(C(=O)C(Cl)Cl)C(C)(C)O1 YNQSILKYZQZHFJ-UHFFFAOYSA-N 0.000 description 5
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 5
235000010749 Vicia faba Nutrition 0.000 description 5
240000006677 Vicia faba Species 0.000 description 5
230000009471 action Effects 0.000 description 5
150000001298 alcohols Chemical class 0.000 description 5
239000007864 aqueous solution Substances 0.000 description 5
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235000013339 cereals Nutrition 0.000 description 5
239000011248 coating agent Substances 0.000 description 5
238000000576 coating method Methods 0.000 description 5
239000002131 composite material Substances 0.000 description 5
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UPQZOUHVTJNGFK-UHFFFAOYSA-N diethyl 2-methylpropanedioate Chemical compound CCOC(=O)C(C)C(=O)OCC UPQZOUHVTJNGFK-UHFFFAOYSA-N 0.000 description 5
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 5
239000008187 granular material Substances 0.000 description 5
125000005843 halogen group Chemical group 0.000 description 5
150000002430 hydrocarbons Chemical group 0.000 description 5
230000001965 increasing effect Effects 0.000 description 5
150000007530 organic bases Chemical class 0.000 description 5
229920000642 polymer Polymers 0.000 description 5
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239000000126 substance Substances 0.000 description 5
125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 5
IAJOBQBIJHVGMQ-UHFFFAOYSA-N 2-amino-4-[hydroxy(methyl)phosphoryl]butanoic acid Chemical compound CP(O)(=O)CCC(N)C(O)=O IAJOBQBIJHVGMQ-UHFFFAOYSA-N 0.000 description 4
108010068327 4-hydroxyphenylpyruvate dioxygenase Proteins 0.000 description 4
102100028626 4-hydroxyphenylpyruvate dioxygenase Human genes 0.000 description 4
HBAQYPYDRFILMT-UHFFFAOYSA-N 8-[3-(1-cyclopropylpyrazol-4-yl)-1H-pyrazolo[4,3-d]pyrimidin-5-yl]-3-methyl-3,8-diazabicyclo[3.2.1]octan-2-one Chemical class C1(CC1)N1N=CC(=C1)C1=NNC2=C1N=C(N=C2)N1C2C(N(CC1CC2)C)=O HBAQYPYDRFILMT-UHFFFAOYSA-N 0.000 description 4
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235000007238 Secale cereale Nutrition 0.000 description 4
244000082988 Secale cereale Species 0.000 description 4
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
235000011684 Sorghum saccharatum Nutrition 0.000 description 4
HEDRZPFGACZZDS-MICDWDOJSA-N Trichloro(2H)methane Chemical compound [2H]C(Cl)(Cl)Cl HEDRZPFGACZZDS-MICDWDOJSA-N 0.000 description 4
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235000007264 Triticum durum Nutrition 0.000 description 4
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PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 4
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CGNBQYFXGQHUQP-UHFFFAOYSA-N 2,3-dinitroaniline Chemical class NC1=CC=CC([N+]([O-])=O)=C1[N+]([O-])=O CGNBQYFXGQHUQP-UHFFFAOYSA-N 0.000 description 3
PAQZWJGSJMLPMG-UHFFFAOYSA-N 2,4,6-tripropyl-1,3,5,2$l^{5},4$l^{5},6$l^{5}-trioxatriphosphinane 2,4,6-trioxide Chemical compound CCCP1(=O)OP(=O)(CCC)OP(=O)(CCC)O1 PAQZWJGSJMLPMG-UHFFFAOYSA-N 0.000 description 3
239000005631 2,4-Dichlorophenoxyacetic acid Substances 0.000 description 3
CAAMSDWKXXPUJR-UHFFFAOYSA-N 3,5-dihydro-4H-imidazol-4-one Chemical class O=C1CNC=N1 CAAMSDWKXXPUJR-UHFFFAOYSA-N 0.000 description 3
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239000005504 Dicamba Substances 0.000 description 3
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239000005561 Glufosinate Substances 0.000 description 3
235000004341 Gossypium herbaceum Nutrition 0.000 description 3
240000002024 Gossypium herbaceum Species 0.000 description 3
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BZLVMXJERCGZMT-UHFFFAOYSA-N Methyl tert-butyl ether Chemical compound COC(C)(C)C BZLVMXJERCGZMT-UHFFFAOYSA-N 0.000 description 3
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
235000021536 Sugar beet Nutrition 0.000 description 3
229940100389 Sulfonylurea Drugs 0.000 description 3
244000299461 Theobroma cacao Species 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
241000209140 Triticum Species 0.000 description 3
235000021307 Triticum Nutrition 0.000 description 3
235000002098 Vicia faba var. major Nutrition 0.000 description 3
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125000000304 alkynyl group Chemical group 0.000 description 3
150000008064 anhydrides Chemical class 0.000 description 3
150000001450 anions Chemical class 0.000 description 3
230000000844 anti-bacterial effect Effects 0.000 description 3
239000002518 antifoaming agent Substances 0.000 description 3
239000007798 antifreeze agent Substances 0.000 description 3
239000003899 bactericide agent Substances 0.000 description 3
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 3
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 3
239000011230 binding agent Substances 0.000 description 3
238000009395 breeding Methods 0.000 description 3
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125000002837 carbocyclic group Chemical group 0.000 description 3
239000003795 chemical substances by application Substances 0.000 description 3
VXIVSQZSERGHQP-UHFFFAOYSA-N chloroacetamide Chemical class NC(=O)CCl VXIVSQZSERGHQP-UHFFFAOYSA-N 0.000 description 3
125000004218 chloromethyl group Chemical group [H]C([H])(Cl)* 0.000 description 3
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JTHMVYBOQLDDIY-UHFFFAOYSA-N methyl 2-[(4-methyl-5-oxo-3-propoxy-1,2,4-triazole-1-carbonyl)sulfamoyl]benzoate Chemical compound O=C1N(C)C(OCCC)=NN1C(=O)NS(=O)(=O)C1=CC=CC=C1C(=O)OC JTHMVYBOQLDDIY-UHFFFAOYSA-N 0.000 description 1
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JP2022562283A 2020-04-14 2021-04-01 ベータ－ラクタム及びその除草剤としての使用 Pending JP2023521819A (ja)