JPWO2021156628A5 - - Google Patents

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JPWO2021156628A5
JPWO2021156628A5 JP2022544060A JP2022544060A JPWO2021156628A5 JP WO2021156628 A5 JPWO2021156628 A5 JP WO2021156628A5 JP 2022544060 A JP2022544060 A JP 2022544060A JP 2022544060 A JP2022544060 A JP 2022544060A JP WO2021156628 A5 JPWO2021156628 A5 JP WO2021156628A5
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biomass
fuel
solid
biomass fuel
solid biomass
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Priority claimed from GB2001650.7A external-priority patent/GB2591789A/en
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固体バイオマス燃料を生成するための方法であって、
(i)30,000μm~60,000μmの平均粒子直径(D50)を有する、1又は2以上のバイオマスの供給源を準備するステップ、
(ii)前記1又は2以上のバイオマスの供給源を微粉化して、1000μm~10,000μmの平均粒子直径(D50)を有する微粉化バイオマス粉末を提供するステップ、
(iii)前記微粉化バイオマス粉末を乾燥させて、乾燥微粉化バイオマス粉末を提供するステップ、
(iv)前記乾燥微粉化バイオマス粉末を成形して、成形バイオマス生成物を提供するステップ、
(v)前記成形バイオマス生成物を、0.25~5時間、160℃~420℃の温度に加熱して、固体バイオマス燃料を提供するステップ、及び
(vi)前記固体バイオマス燃料から塵粒子を除去するステップ
を含み、
前記1又は2以上のバイオマスの供給源が、バガス、ヒマワリ茎、小麦茎、トウモロコシ茎、ソルガム茎、大豆茎、ピーナッツ茎、綿茎、菜種茎、ココナッツ殻、パーム殻、海藻、ピーナッツ皮、又はこれらの組合せを含む、前記方法。
A method for producing solid biomass fuel, the method comprising:
(i) providing one or more sources of biomass having an average particle diameter (D50) of 30,000 μm to 60,000 μm;
(ii) pulverizing the one or more sources of biomass to provide a pulverized biomass powder having an average particle diameter (D50) of 1000 μm to 10,000 μm;
(iii) drying the micronized biomass powder to provide a dry micronized biomass powder;
(iv) shaping the dry micronized biomass powder to provide a shaped biomass product;
(v) heating the shaped biomass product to a temperature of 160°C to 420°C for 0.25 to 5 hours to provide a solid biomass fuel; and (vi) removing dust particles from the solid biomass fuel. including the step of
The source of the one or more biomass is bagasse, sunflower stalk, wheat stalk, corn stalk, sorghum stalk, soybean stalk, peanut stalk, cotton stalk, rapeseed stalk, coconut shell, palm shell, seaweed, peanut skin, or The above methods, including combinations thereof.
1又は2以上のバイオマスの供給源が、バガス、ヒマワリ茎、小麦茎、トウモロコシ茎、ソルガム茎、大豆茎、ピーナッツ茎、綿茎、菜種茎、ココナッツ殻、パーム殻、海藻、ピーナッツ皮、若しくはこれらの組合せから本質的になる、又はこれらからなる、請求項1に記載の方法。The source of one or more biomass is bagasse, sunflower stalk, wheat stalk, corn stalk, sorghum stalk, soybean stalk, peanut stalk, cotton stalk, rapeseed stalk, coconut shell, palm shell, seaweed, peanut skin, or these. 2. The method of claim 1, consisting essentially of or consisting of a combination of. 30,000μm~60,000μmの平均粒子直径(D50)を有する1又は2以上のバイオマスの供給源を準備するステップ(i)が、30,000μm~60,000μmの平均粒子直径(D50)を有するように、前記1又は2以上のバイオマスの供給源をチョッピングすることを含む、請求項1に記載の方法。step (i) of providing one or more sources of biomass having an average particle diameter (D50) of 30,000 μm to 60,000 μm, 2. The method of claim 1, comprising chopping the one or more sources of biomass so that the source of biomass is chopped. 微粉化バイオマス粉末を乾燥させて、乾燥微粉化バイオマス粉末を提供するステップ(iii)が、乾燥シリンダー内で微粉化バイオマスを乾燥させることを含む、請求項1に記載の方法であって、
(i)前記微粉化バイオマス粉末の水分率が20重量%以下であり、かつ、前記方法が、単一の乾燥シリンダー内で前記微粉化バイオマスを乾燥させることを含むか;あるいは
(ii)前記微粉化バイオマス粉末の水分率が20重量%以上であり、かつ、前記方法が、複数の乾燥シリンダー内で前記微粉化バイオマスを乾燥させることを含む;
前記方法
2. The method of claim 1, wherein step (iii) of drying the micronized biomass powder to provide a dry micronized biomass powder comprises drying the micronized biomass in a drying cylinder,
(i) the moisture content of the micronized biomass powder is 20% by weight or less, and the method comprises drying the micronized biomass in a single drying cylinder; or
(ii) the moisture content of the micronized biomass powder is 20% by weight or more, and the method includes drying the micronized biomass in a plurality of drying cylinders;
Said method .
成形バイオマス生成物を加熱するステップ(v)が、0.4~2.5時間行われ、かつ、成形バイオマス生成物を加熱するステップが、前記成形バイオマス生成物を、180℃~350℃の温度に加熱することを含む、請求項1に記載の方法。step (v) of heating the shaped biomass product is carried out for 0.4 to 2.5 hours, and heating the shaped biomass product is heated to a temperature of 180°C to 350°C. 2. The method of claim 1, comprising heating to. 成形バイオマス生成物を加熱するステップ(v)を、固体バイオマス燃料の一様性が制御されるように適応させ、ステップ(v)を、前記固体バイオマス燃料の一様性が制御されるように適応させることが、前記成形バイオマス生成物を加熱しながら回転させる装置において、ステップ(v)を実施することを含む、請求項1に記載の方法。the step (v) of heating the shaped biomass product is adapted such that the uniformity of the solid biomass fuel is controlled; and the step (v) is adapted such that the uniformity of the solid biomass fuel is controlled. 2. The method of claim 1, wherein causing comprises performing step (v) in an apparatus that rotates the shaped biomass product while heating. ステップ(v)を、固体バイオマス燃料の一様性が制御されるように適応させることが、成形バイオマス生成物の回転の速さ又は方向を制御することを含む、請求項6に記載の方法。7. The method of claim 6, wherein adapting step (v) so that uniformity of the solid biomass fuel is controlled comprises controlling the speed or direction of rotation of the shaped biomass product. 固体バイオマス燃料から塵粒子を除去するステップ(vi)が、2mm~8mmのポアサイズを有するスクリーンを用いて、前記固体バイオマス燃料から塵粒子を除去することを含む、請求項1に記載の方法。The method of claim 1, wherein step (vi) of removing dust particles from the solid biomass fuel comprises removing dust particles from the solid biomass fuel using a screen having a pore size of 2 mm to 8 mm. 固体バイオマス燃料から塵粒子を除去するステップ(vi)が、前記固体バイオマス燃料を、振動、回転、ローリング、又はこれらの任意の組合せに供することを含む、請求項8に記載の方法。9. The method of claim 8, wherein step (vi) of removing dust particles from solid biomass fuel comprises subjecting the solid biomass fuel to vibration, rotation, rolling, or any combination thereof. DIN EN 15103によって決定される固体バイオマス燃料のバルク密度が、0.55kg/l~0.8kg/lである、及び/又はDIN EN 15210-1によって決定される固体バイオマス燃料の機械的耐久性が、90%以上である、請求項1に記載の方法。the bulk density of the solid biomass fuel as determined by DIN EN 15103 is between 0.55 kg/l and 0.8 kg/l and/or the mechanical durability of the solid biomass fuel as determined by DIN EN 15210-1 is , 90% or more. (i)1若しくは2以上のバイオマスの供給源が、バガスを含み、若しくはバガスから本質的になり、固体バイオマス燃料が、0.60kg/L~0.65kg/Lのバルク密度を有し、前記固体バイオマス燃料の機械的耐久性が95%以上であるか、(i) the one or more sources of biomass comprises or consists essentially of bagasse, and the solid biomass fuel has a bulk density of 0.60 kg/L to 0.65 kg/L; The mechanical durability of the solid biomass fuel is 95% or more,
(ii)1若しくは2以上のバイオマスの供給源が、ヒマワリ茎を含み、若しくはヒマワリ茎から本質的になり、前記固体バイオマス燃料が、0.60kg/L~0.65kg/Lのバルク密度を有し、前記固体バイオマス燃料の機械的耐久性が95%以上であるか、(ii) the one or more sources of biomass comprises or consists essentially of sunflower stems, and the solid biomass fuel has a bulk density of 0.60 kg/L to 0.65 kg/L; and the mechanical durability of the solid biomass fuel is 95% or more,
(iii)1若しくは2以上のバイオマスの供給源が、小麦茎を含み、若しくは小麦茎から本質的になり、前記固体バイオマス燃料が、0.58kg/L~0.65kg/Lのバルク密度を有し、前記固体バイオマス燃料の機械的耐久性が95%以上であるか、(iii) the one or more sources of biomass comprises or consists essentially of wheat stalks, and the solid biomass fuel has a bulk density of 0.58 kg/L to 0.65 kg/L. and the mechanical durability of the solid biomass fuel is 95% or more,
(iv)1若しくは2以上のバイオマスの供給源が、トウモロコシ茎を含み、若しくはトウモロコシ茎から本質的になり、前記固体バイオマス燃料が、0.61kg/L~0.66kg/Lのバルク密度を有し、前記固体バイオマス燃料の機械的耐久性が96%以上であるか、(iv) the one or more sources of biomass comprise or consist essentially of cornstalk, and the solid biomass fuel has a bulk density of 0.61 kg/L to 0.66 kg/L; and the mechanical durability of the solid biomass fuel is 96% or more,
(v)1若しくは2以上のバイオマスの供給源が、ソルガム茎を含み、若しくはソルガム茎から本質的になり、前記固体バイオマス燃料が、0.62kg/L~0.66kg/Lのバルク密度を有し、前記固体バイオマス燃料の機械的耐久性が97%以上であるか、(v) the one or more sources of biomass comprise or consist essentially of sorghum stalks, and the solid biomass fuel has a bulk density of 0.62 kg/L to 0.66 kg/L. and the mechanical durability of the solid biomass fuel is 97% or more,
(vi)1若しくは2以上のバイオマスの供給源が、大豆茎を含み、若しくは大豆茎から本質的になり、前記固体バイオマス燃料が、0.61kg/L~0.66kg/Lのバルク密度を有し、前記固体バイオマス燃料の機械的耐久性が96%以上であるか、(vi) the one or more sources of biomass comprise or consist essentially of soybean stalks, and the solid biomass fuel has a bulk density of 0.61 kg/L to 0.66 kg/L; and the mechanical durability of the solid biomass fuel is 96% or more,
(vii)1若しくは2以上のバイオマスの供給源が、ピーナッツ茎を含み、若しくはピーナッツ茎から本質的になり、前記固体バイオマス燃料が、0.62kg/L~0.68kg/Lのバルク密度を有し、前記固体バイオマス燃料の機械的耐久性が97%以上であるか、(vii) the one or more sources of biomass comprise or consist essentially of peanut stalks, and the solid biomass fuel has a bulk density of 0.62 kg/L to 0.68 kg/L; and the mechanical durability of the solid biomass fuel is 97% or more,
(viii)1若しくは2以上のバイオマスの供給源が、綿茎を含み、若しくは綿茎から本質的になり、前記固体バイオマス燃料が、0.62kg/L~0.68kg/Lのバルク密度を有し、前記固体バイオマス燃料の機械的耐久性が98%以上であるか、(viii) the one or more sources of biomass comprises or consists essentially of cotton stalks, and the solid biomass fuel has a bulk density of 0.62 kg/L to 0.68 kg/L. and the mechanical durability of the solid biomass fuel is 98% or more,
(ix)1若しくは2以上のバイオマスの供給源が、菜種茎を含み、若しくは菜種茎から本質的になり、前記固体バイオマス燃料が、0.58kg/L~0.65kg/Lのバルク密度を有し、前記固体バイオマス燃料の機械的耐久性が98%以上であるか、(ix) the one or more sources of biomass comprise or consist essentially of rapeseed stalks, and the solid biomass fuel has a bulk density of 0.58 kg/L to 0.65 kg/L; and the mechanical durability of the solid biomass fuel is 98% or more,
(x)1若しくは2以上のバイオマスの供給源が、ココナッツ外殻を含み、若しくはココナッツ外殻から本質的になり、前記固体バイオマス燃料が、0.62kg/L~0.72kg/Lのバルク密度を有し、前記固体バイオマス燃料の機械的耐久性が98%以上であるか、(x) the one or more sources of biomass comprises or consists essentially of coconut shells, and the solid biomass fuel has a bulk density of 0.62 kg/L to 0.72 kg/L; and the mechanical durability of the solid biomass fuel is 98% or more,
(xi)1若しくは2以上のバイオマスの供給源が、パーム殻を含み、若しくはパーム殻から本質的になり、前記固体バイオマス燃料が、0.62kg/L~0.70kg/Lのバルク密度を有し、前記固体バイオマス燃料の機械的耐久性が98%以上であるか、(xi) the one or more sources of biomass comprises or consists essentially of palm shells, and the solid biomass fuel has a bulk density of 0.62 kg/L to 0.70 kg/L; and the mechanical durability of the solid biomass fuel is 98% or more,
(xii)1若しくは2以上のバイオマスの供給源が、海藻を含み、若しくは海藻から本質的になり、前記固体バイオマス燃料が、0.61kg/L~0.66kg/Lのバルク密度を有し、前記固体バイオマス燃料の機械的耐久性が96%以上であるか、又は(xii) the one or more sources of biomass comprises or consists essentially of seaweed, and the solid biomass fuel has a bulk density of 0.61 kg/L to 0.66 kg/L; The mechanical durability of the solid biomass fuel is 96% or more, or
(xiii)1若しくは2以上のバイオマスの供給源が、ピーナッツ皮を含み、若しくはピーナッツ皮から本質的になり、前記固体バイオマス燃料が、0.61kg/L~0.66kg/Lのバルク密度を有し、前記固体バイオマス燃料の機械的耐久性が97%以上であり、(xiii) the one or more sources of biomass comprises or consists essentially of peanut skin, and the solid biomass fuel has a bulk density of 0.61 kg/L to 0.66 kg/L. and the mechanical durability of the solid biomass fuel is 97% or more,
前記バルク密度がDIN EN 15103によって決定され、前記機械的耐久性がDIN EN 15210-1によって決定される、請求項1に記載の方法。2. The method according to claim 1, wherein the bulk density is determined according to DIN EN 15103 and the mechanical durability is determined according to DIN EN 15210-1.
(i)バイオマス固体燃料の総乾燥硫黄含有量が、0.5重量%以下であり、前記総乾燥硫黄含有量がDIN EN 15289によって決定される;(ii)バイオマス固体燃料の総乾燥水素含有量が、3重量%以上であり、前記総乾燥水素含有量がDIN EN 15104によって決定される;(iii)バイオマス固体燃料の総乾燥酸素含有量が、20重量%以上であり、前記総乾燥酸素含有量がDIN EN 15296によって決定される;(iv)バイオマス固体燃料の総乾燥炭素含有量が、40重量%以上であり、総乾燥炭素含有量がDIN EN 15104によって決定される;(v)バイオマス固体燃料の総乾燥窒素含有量が、5.0重量%未満であり、前記総乾燥窒素含有量がDIN EN 15104によって決定される;(vi)固体バイオマス燃料の化学的酸素要求量(COD)が、水中に浸漬させる場合、5000ppm以下であり、前記化学的酸素要求量がGB/11914-89によって決定される;(vii)固体バイオマス燃料の固定炭素含有量が、20重量%以上であり、前記固定炭素含有量がDIN EN 51734によって決定される;(viii)固体バイオマス燃料の灰分が、20重量%未満であり、前記灰分が550℃において、EN 14775によって決定される;(ix)固体バイオマス燃料の揮発性物質含有量が、35重量%~80重量%であり、前記揮発性物質含有量がDIN EN 15148によって決定される;(x)固体バイオマス燃料の内部水分率が、8重量%未満であり、前記内部水分率が、DIN EN 14774によって決定される;(xi)バイオマス固体燃料が、4300kcal/kg~6500kcal/kgの発熱量を有し、前記発熱量がDIN EN 14918に従って決定される;(xii)バイオマス固体燃料が、10重量%未満のベース水分率を有し、前記ベース水分率がGB/T211-2017によって決定される;(xiii)固体バイオマス燃料のpHが4~10である;及び/又は、(xiv)固体バイオマス燃料が、最大20日間耐水性である;請求項1に記載の方法。(i) the total dry sulfur content of the biomass solid fuel is not more than 0.5% by weight, said total dry sulfur content being determined according to DIN EN 15289; (ii) the total dry hydrogen content of the biomass solid fuel is at least 3% by weight and said total dry hydrogen content is determined according to DIN EN 15104; (iii) the total dry oxygen content of the biomass solid fuel is at least 20% by weight and said total dry oxygen content is determined according to DIN EN 15104; (iv) the total dry carbon content of the biomass solid fuel is at least 40% by weight and the total dry carbon content is determined according to DIN EN 15104; (v) the biomass solid fuel the total dry nitrogen content of the fuel is less than 5.0% by weight, said total dry nitrogen content being determined according to DIN EN 15104; (vi) the chemical oxygen demand (COD) of the solid biomass fuel is (vii) the fixed carbon content of the solid biomass fuel is 20% by weight or more and the fixed carbon the carbon content is determined according to DIN EN 51734; (viii) the ash content of the solid biomass fuel is less than 20% by weight, said ash content being determined according to EN 14775 at 550°C; (ix) the carbon content of the solid biomass fuel is determined according to DIN EN 51734; (x) the internal moisture content of the solid biomass fuel is less than 8% by weight; , said internal moisture content is determined according to DIN EN 14774; (xi) the biomass solid fuel has a calorific value of 4300 kcal/kg to 6500 kcal/kg, said calorific value is determined according to DIN EN 14918; xii) the biomass solid fuel has a base moisture content of less than 10% by weight, said base moisture content being determined by GB/T211-2017; (xiii) the pH of the solid biomass fuel is between 4 and 10; and 2. The method of claim 1, wherein:/or (xiv) the solid biomass fuel is water resistant for up to 20 days. バイオマスに由来する材料が、固体バイオマス燃料中に、前記固体バイオマス燃料の総燃料含有量の少なくとも95重量%の量で存在する、請求項1に記載の方法。2. The method of claim 1, wherein the biomass-derived material is present in the solid biomass fuel in an amount of at least 95% by weight of the total fuel content of the solid biomass fuel. 請求項1~13のいずれかに記載の方法によって得ることができる又は得られた固体バイオマス燃料。Solid biomass fuel obtainable or obtained by the method according to any of claims 1 to 13. 1又は2以上のバイオマスの供給源に由来する固体バイオマス燃料であって、前記1又は2以上のバイオマスの供給源が、A solid biomass fuel derived from one or more biomass sources, the one or more biomass sources comprising:
(i)バガスを含む、バガスからなる、若しくはバガスから本質的になる;(i) comprises, consists of, or consists essentially of bagasse;
(ii)ヒマワリ茎を含む、ヒマワリ茎からなる、若しくはヒマワリ茎から本質的になる;(ii) comprises, consists of, or consists essentially of sunflower stems;
(iii)小麦茎を含む、小麦茎からなる、若しくは小麦茎から本質的になる;(iii) comprises, consists of, or consists essentially of wheat stalk;
(iv)トウモロコシ茎を含む、トウモロコシ茎からなる、若しくはトウモロコシ茎から本質的になる;(iv) comprises, consists of, or consists essentially of corn stalk;
(v)大豆茎を含む、大豆茎からなる、若しくは大豆茎から本質的になる;(v) comprises, consists of, or consists essentially of soybean stalks;
(vi)ソルガム茎を含む、ソルガム茎からなる、若しくはソルガム茎から本質的になる;(vi) comprises, consists of, or consists essentially of sorghum stalk;
(vii)ピーナッツ皮を含む、ピーナッツ皮からなる、若しくはピーナッツ殻から本質的になる;(vii) comprising, consisting of, or consisting essentially of peanut shell;
(viii)綿茎を含む、綿茎からなる、若しくは綿茎から本質的になる;(viii) comprising, consisting of, or consisting essentially of cotton stalk;
(ix)菜種茎を含む、菜種茎からなる、若しくは菜種茎から本質的になる;(ix) comprising, consisting of, or consisting essentially of rapeseed stems;
(x)ココナッツ殻を含む、ココナッツ殻からなる、若しくはココナッツ殻から本質的になる;(x) comprises, consists of, or consists essentially of coconut shell;
(xi)パーム殻を含む、パーム殻からなる、若しくはパーム殻から本質的になる;(xi) comprising, consisting of, or consisting essentially of palm shell;
(xii)海藻を含む、海藻からなる、若しくは海藻から本質的になる;又は(xii) comprises, consists of, or consists essentially of seaweed; or
(xiii)ピーナッツ皮を含む、ピーナッツ皮からなる、若しくはピーナッツ皮から本質的になり;(xiii) comprising, consisting of, or consisting essentially of peanut skin;
DIN EN 15103によって決定される前記固体バイオマス燃料のバルク密度が、0.55kg/l~0.8kg/lであり、DIN EN 15210-1によって決定される前記固体バイオマス燃料の機械的耐久性が、95%以上であり、前記固体バイオマス燃料の化学的酸素要求量(COD)が、水中に浸漬させる場合、5000ppm以下であり、かつ、バイオマスに由来する材料が、前記固体バイオマス燃料中に、前記固体バイオマス燃料の総燃料含有量の少なくとも95重量%の量で存在する、前記固体バイオマス燃料。The bulk density of the solid biomass fuel as determined according to DIN EN 15103 is between 0.55 kg/l and 0.8 kg/l and the mechanical durability of the solid biomass fuel as determined according to DIN EN 15210-1 is 95% or more, the chemical oxygen demand (COD) of the solid biomass fuel is 5000 ppm or less when immersed in water, and the material derived from biomass is contained in the solid biomass fuel. The solid biomass fuel is present in an amount of at least 95% by weight of the total fuel content of the biomass fuel.
請求項14又は15に記載の固体バイオマス燃料を、エネルギーを生じるように燃焼させるステップを含む、燃焼方法。A combustion method comprising the step of combusting the solid biomass fuel according to claim 14 or 15 to produce energy. 石炭などの化石燃料と一緒に固体バイオマス燃料を同時焼成し、燃焼させ、及び/又は、方法のPM1.0排出が、175mg/kg未満である、請求項16に記載の方法。17. The method of claim 16, wherein the solid biomass fuel is co-fired and combusted with a fossil fuel such as coal, and/or the PM 1.0 emissions of the method are less than 175 mg/kg.
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