CN107779235A - A kind of compound biomass granular fuel - Google Patents
A kind of compound biomass granular fuel Download PDFInfo
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- CN107779235A CN107779235A CN201710810646.XA CN201710810646A CN107779235A CN 107779235 A CN107779235 A CN 107779235A CN 201710810646 A CN201710810646 A CN 201710810646A CN 107779235 A CN107779235 A CN 107779235A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/40—Solid fuels essentially based on materials of non-mineral origin
- C10L5/44—Solid fuels essentially based on materials of non-mineral origin on vegetable substances
- C10L5/445—Agricultural waste, e.g. corn crops, grass clippings, nut shells or oil pressing residues
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/40—Solid fuels essentially based on materials of non-mineral origin
- C10L5/44—Solid fuels essentially based on materials of non-mineral origin on vegetable substances
- C10L5/442—Wood or forestry waste
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L9/00—Treating solid fuels to improve their combustion
- C10L9/10—Treating solid fuels to improve their combustion by using additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
- C10L2230/22—Function and purpose of a components of a fuel or the composition as a whole for improving fuel economy or fuel efficiency
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/08—Drying or removing water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/24—Mixing, stirring of fuel components
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/28—Cutting, disintegrating, shredding or grinding
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/32—Molding or moulds
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
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- Engineering & Computer Science (AREA)
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- Agronomy & Crop Science (AREA)
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- Solid Fuels And Fuel-Associated Substances (AREA)
Abstract
The present invention relates to bio-fuel technical field, more particularly to a kind of compound biomass granular fuel.Compound biomass granular fuel of the present invention is made of fuel matrix, graphene and coconut shell powder, and fuel matrix therein is prepared using wheat straw, wood chip, corncob, peanut shell, straw, rice husk, oil tea shell and cotton seed hulls as raw material.Compound biomass granular fuel of the present invention is in addition to the advantages of common biomass fuel, also with burning efficiency height, burning velocity is moderate, firing duration is long, can gently discharge the combustion heat and realizes the characteristics such as continuous heat supply, so as to be especially suitable for finishing the production requirement of enterprise.
Description
Technical field
The present invention relates to bio-fuel technical field, more particularly to a kind of compound biomass granular fuel.
Background technology
Bioenergy due to its high energy, environmental protection, it is inexpensive, easy to use, renewable the features such as turned into the popular energy and ground
Field is studied carefully, by the common concern of countries in the world government and scientist.In states such as the U.S., Sweden and Austria, bioenergy
Using accounting for 4%, 16% and the 10% of the disposable energy-output ratio of the state respectively.Also the exploitation of bioenergy is attached great importance in China
And utilization, but current research emphasis is concentrated mainly on methane engineering technology, gasifying stalk central gas supply technology and garbage loading embeading
Generation technology etc., research and development, production for biomass fuel product and the research such as utilizes just to start to walk.
Biomass fuel is typically referred to by agriculture and forestry organic waste material, such as stalk, sawdust, bagasse, rice chaff, straw, rice husk, peanut
Shell, corncob, oil tea shell, cotton seed hulls etc. and " three surplus things " strip made from processing or block environmentally friendly new energy.Relative to biography
System fuel, biomass fuel have many technical advantages as a kind of regenerative resource:Purity height, small volume, burning-point are low, heating
Measure big, high combustion efficiency, cost is cheap, be readily transported, be easy to use, sulphur phosphorus content is extremely low, does not corrode boiler, will not cause acid
Extracting rate that rain, harmful gas emission are few, environmentally friendly, production environment sanitation and hygiene, ash are cut is low, the ashes after burning can be used as organic potassium
Fertilizer recycles, suitable for coal-burning boiler etc..
The above-mentioned advantage of biomass fuel obtains being widely recognized as energy field, and part research institution and enterprise are also right
It has been carried out the research of correlation and has achieved certain progress.For example, patent application " a kind of biomass fuel and preparation method thereof "
(CN201611207595.3) one kind biomass fuel made of corn stalk, straw, soybean straw, rice bran, sawmilling face is disclosed;
In another example patent application " a kind of biomass fuel and preparation method thereof " (CN201710411862.7) discloses one kind by fruit
The biomass fuel that skin, edible fungi residue, wood chip, attapulgite clay, straw, Chinese tallow seed slag composition are formed, has burning
The characteristics of efficiency high.
But also there are some problems during the promoting the use of of biomass fuel, due to the original of biomass fuel
Expect that burning-point is relatively low, and purity is higher, so its efficiency of combustion is universal very high, but incident problem be exactly burning velocity very
It hurry up, substantial amounts of heat can be discharged in a short time, for most of users, this feature of biomass fuel does not interfere with
Normal use, however, for being engaged in the user of finishing industry, often the thermal source lasting with greater need for stable exports, greatly
Calorimetric amount short time quick release can cause to produce the drastically rise of temperature, have a strong impact on the normal operation of its production technology, no
The quality of product can only be reduced, it is also possible to which production equipment facility is caused serious harm.It is fast to be additionally, since burning velocity, accordingly
Firing duration will shorten, when production technology is time-consuming longer, the demand of midway increase or refuelling will be faced,
So as to propose higher requirement to the working condition of reality, while add technical difficulty and running cost.Biomass fuel
Above-mentioned characteristic greatly limit its application scope, cause it is many finishing enterprises be still difficult to by the use of its as mainly
Production fuel.
For the present invention on the basis of existing biomass fuel, research and development obtain a kind of new compound biomass granular fuel,
By the adjustment and optimization to its formula components, on the premise of its total burning efficiency is not reduced, its burning velocity is slow down, greatly
Width extends its firing duration, its combustion heat is steadily discharged with more constant speed, so as to adapt to finish
Enterprise is also made that beneficial exploration for biomass fuel to the production requirement of basic fuel in promoting the use of for more areas.
The content of the invention
The present invention is intended to provide a kind of compound biomass granular fuel of suitable finishing enterprise production requirement, present invention combustion
Material can effectively slow down fuel combustion speed, significantly extend firing duration, make it on the premise of total burning efficiency is not reduced
The combustion heat can steadily be discharged with more constant speed.
Graphene is a kind of cellular flat film formed by carbon atom with sp2 hybrid forms, is a kind of only one layer
Or the quasi- two-dimensional material of multilayer atomic thickness.Graphene is due to special with very good intensity, flexible, conductive, heat conduction, optics
Property, it is widely applied in fields such as physics, material, electronic information, computer, Aero-Space.It was found that will be a small amount of
Graphene is added in biomass granule fuel according to a certain ratio can effectively slow down its burning velocity, be advantageous to it and continue surely
Fixed release heat energy, but the addition of graphene needs strictly to be controlled, addition is very few can not effectively to control burn rate,
Total burning efficiency can at most be influenceed by adding.At present, had not been reported on application of the graphene in fuel area.
It was also found that a certain amount of coconut shell powder is added in above-mentioned fuel formulation, it can further extend burning
Duration, the raising to efficiency of burning are also helpful.
First, the invention provides a kind of compound biomass granular fuel, it is characterised in that it is by following quality percentages
Made of the raw material of ratio:
Fuel matrix 95.6-96.0%, graphene 0.6-0.8%, coconut shell powder 3.2-3.8%;
Wherein described fuel matrix is made of the raw material of following weight parts:
Wheat straw 30-40, wood chip 20-30, corncob 20-30, peanut shell 20-25,
Straw 20-25, rice husk 15-20, oil tea shell 15-20, cotton seed hulls 15-20;
The compound biomass granular fuel is made by following steps:
(1) after wheat straw, wood chip, corncob, peanut shell, straw, rice husk, oil tea shell and cotton seed hulls being respectively dried, crushed
40 mesh sieves are crossed, the above-mentioned raw materials after sieving are uniform in stirrer for mixing, obtain fuel matrix;
(2) graphene, coconut shell powder are added in above-mentioned fuel matrix, being sufficiently stirred makes it well mixed, is stirring
During add a small amount of water and the moisture in the mixed-powder that controls to obtain is 10-12%;
(3) gained mixed-powder extrusion forming in press, is cooled to after room temperature and obtains this composite biomass particle
Fuel.
The mass percent of above-mentioned raw materials is preferred:
Fuel matrix 95.6%, graphene 0.6%, coconut shell powder 3.8%;
Wherein described fuel matrix is made of the raw material of following weight parts:
Wheat straw 30, wood chip 20, corncob 20, peanut shell 20,
Straw 20, rice husk 15, oil tea shell 15, cotton seed hulls 15.
The mass percent of above-mentioned raw materials is further preferably:
Fuel matrix 95.8%, graphene 0.7%, coconut shell powder 3.5%;
Wherein described fuel matrix is made of the raw material of following weight parts:
Wheat straw 35, wood chip 25, corncob 25, peanut shell 20,
Straw 20, rice husk 20, oil tea shell 15, cotton seed hulls 15.
The mass percent of above-mentioned raw materials is further preferably:
Fuel matrix 96.0%, graphene 0.8%, coconut shell powder 3.2%;
Wherein described fuel matrix is made of the raw material of following weight parts:
Wheat straw 40, wood chip 30, corncob 30, peanut shell 25,
Straw 25, rice husk 20, oil tea shell 20, cotton seed hulls 20.
Further, compound biomass granular fuel of the present invention, it is characterised in that obtained composite biomass particle combustion
Expect for graininess, bar-shaped, strip or bulk.
Secondly, the invention further relates to a kind of application of compound biomass granular fuel in biofuel products are prepared.
Finally, present invention also offers a kind of preparation method of compound biomass granular fuel, comprise the steps:
(1) after wheat straw, wood chip, corncob, peanut shell, straw, rice husk, oil tea shell and cotton seed hulls being respectively dried, crushed
40 mesh sieves are crossed, the above-mentioned raw materials after sieving are uniform in stirrer for mixing, obtain fuel matrix;
(2) graphene and coconut shell powder are weighed, wherein graphene quality is total equivalent to the compound biomass granular fuel
The 0.6-0.8% of quality, coconut shell powder quality, will equivalent to the 3.2-3.8% of the compound biomass granular fuel gross mass
Graphene and coconut shell powder are added in above-mentioned fuel matrix, and being sufficiently stirred makes it well mixed, are added in whipping process few
Moisture in amount water and the mixed-powder for controlling to obtain is 10-12%;
(3) gained mixed-powder is squeezed into graininess, bar-shaped, strip or bulk in press, is cooled to after room temperature i.e.
Obtain compound biomass granular fuel.
In addition to the technical advantage with common biomass fuel, compound biomass granular fuel of the present invention also has burning
Efficiency is high, burning velocity is moderate, firing duration is long, can gently discharge the combustion heat and realizes the characteristics such as continuous heat supply, from
And it is especially suitable for finishing the production requirement of enterprise, as a kind of inexpensive, high-effect, widely applicable environment-friendly fuel, this hair
The popularization and application of bright product are expected to produce good economic and social benefit.
Embodiment
Illustrate embodiments of the present invention below by way of specific instantiation, those skilled in the art can be by this specification
Disclosed content understands other advantages and effect of the present invention easily.The present invention can also pass through specific realities different in addition
The mode of applying is embodied or practiced, the various details in this specification can also be based on different viewpoints with application, without departing from
Various modifications or alterations are carried out under the spirit of the present invention.
Before the specific embodiment of the invention is further described, it should be appreciated that protection scope of the present invention is not limited to down
State specific specific embodiment;It is also understood that the term used in the embodiment of the present invention is specific specific in order to describe
Embodiment, the protection domain being not intended to be limiting of the invention.
When embodiment provides number range, it should be appreciated that except non-invention is otherwise noted, two ends of each number range
Any one numerical value can be selected between point and two end points.Unless otherwise defined, in the present invention all technologies for using and
Scientific terminology is identical with the meaning that those skilled in the art of the present technique are generally understood that.Except used in embodiment specific method, equipment,
Outside material, according to grasp of the those skilled in the art to prior art and the record of the present invention, it can also use and this
Any method, equipment and the material of the similar or equivalent prior art of method, equipment described in inventive embodiments, material come real
The existing present invention.
Embodiment 1
A kind of compound biomass granular fuel, it is made of the raw material of following mass percents:
Fuel matrix 95.6%, graphene 0.6%, coconut shell powder 3.8%;
Wherein described fuel matrix is made of the raw material of following weight parts:
Wheat straw 30, wood chip 20, corncob 20, peanut shell 20,
Straw 20, rice husk 15, oil tea shell 15, cotton seed hulls 15.
Preparation method is as follows:
(1) after wheat straw, wood chip, corncob, peanut shell, straw, rice husk, oil tea shell and cotton seed hulls being respectively dried, crushed
40 mesh sieves are crossed, the above-mentioned raw materials after sieving are uniform in stirrer for mixing, obtain fuel matrix;
(2) graphene, coconut shell powder are added in above-mentioned fuel matrix, being sufficiently stirred makes it well mixed, is stirring
During add a small amount of water and the moisture in the mixed-powder that controls to obtain is 10-12%;
(3) gained mixed-powder is squeezed into graininess in press, and this composite biomass is obtained after being cooled to room temperature
Granular fuel.
Embodiment 2
A kind of compound biomass granular fuel, it is made of the raw material of following mass percents:
Fuel matrix 95.8%, graphene 0.7%, coconut shell powder 3.5%;
Wherein described fuel matrix is made of the raw material of following weight parts:
Wheat straw 35, wood chip 25, corncob 25, peanut shell 20,
Straw 20, rice husk 20, oil tea shell 15, cotton seed hulls 15.
Preparation method is the same as embodiment 1.
Embodiment 3
A kind of compound biomass granular fuel, it is made of the raw material of following mass percents:
Fuel matrix 96.0%, graphene 0.8%, coconut shell powder 3.2%;
Wherein described fuel matrix is made of the raw material of following weight parts:
Wheat straw 40, wood chip 30, corncob 30, peanut shell 25,
Straw 25, rice husk 20, oil tea shell 20, cotton seed hulls 20.
Preparation method is the same as embodiment 1.
Comparative example 1
A kind of compound biomass granular fuel, it is made of the raw material of following weight parts:
Wheat straw 30, wood chip 20, corncob 20, peanut shell 20,
Straw 20, rice husk 15, oil tea shell 15, cotton seed hulls 15.
Preparation method is as follows:
(1) after wheat straw, wood chip, corncob, peanut shell, straw, rice husk, oil tea shell and cotton seed hulls being respectively dried, crushed
40 mesh sieves are crossed, the above-mentioned raw materials after sieving are uniform in stirrer for mixing, a small amount of water is added in whipping process and is controlled
To mixed-powder in moisture be 10-12%;
(2) gained mixed-powder is squeezed into graininess in press, and composite biomass is obtained after being cooled to room temperature
Grain fuel.
Comparative example 2
A kind of compound biomass granular fuel, it is made of the raw material of following mass percents:
Fuel matrix 96.2%, coconut shell powder 3.8%;
Wherein described fuel matrix is made of the raw material of following weight parts:
Wheat straw 30, wood chip 20, corncob 20, peanut shell 20,
Straw 20, rice husk 15, oil tea shell 15, cotton seed hulls 15.
Preparation method is as follows:
(1) after wheat straw, wood chip, corncob, peanut shell, straw, rice husk, oil tea shell and cotton seed hulls being respectively dried, crushed
40 mesh sieves are crossed, the above-mentioned raw materials after sieving are uniform in stirrer for mixing, obtain fuel matrix;
(2) coconut shell powder is added in above-mentioned fuel matrix, being sufficiently stirred makes it well mixed, adds in whipping process
Moisture in the mixed-powder for entering a small amount of water and controlling to obtain is 10-12%;
(3) gained mixed-powder is squeezed into graininess in press, and composite biomass is obtained after being cooled to room temperature
Grain fuel.
Comparative example 3
A kind of compound biomass granular fuel, it is made of the raw material of following mass percents:
Fuel matrix 99.4%, graphene 0.6%;
Wherein described fuel matrix is made of the raw material of following weight parts:
Wheat straw 30, wood chip 20, corncob 20, peanut shell 20,
Straw 20, rice husk 15, oil tea shell 15, cotton seed hulls 15.
Preparation method is as follows:
(1) after wheat straw, wood chip, corncob, peanut shell, straw, rice husk, oil tea shell and cotton seed hulls being respectively dried, crushed
40 mesh sieves are crossed, the above-mentioned raw materials after sieving are uniform in stirrer for mixing, obtain fuel matrix;
(2) graphene is added in above-mentioned fuel matrix, being sufficiently stirred makes it well mixed, is added in whipping process
Moisture in a small amount of water and the mixed-powder for controlling to obtain is 10-12%;
(3) gained mixed-powder is squeezed into graininess in press, and composite biomass is obtained after being cooled to room temperature
Grain fuel.
Comparative example 4
A kind of compound biomass granular fuel, it is made of the raw material of following mass percents:
Fuel matrix 95.8%, graphene 0.4%, coconut shell powder 3.8%;
Wherein described fuel matrix is made of the raw material of following weight parts:
Wheat straw 30, wood chip 20, corncob 20, peanut shell 20,
Straw 20, rice husk 15, oil tea shell 15, cotton seed hulls 15.
Preparation method is as follows:
(1) after wheat straw, wood chip, corncob, peanut shell, straw, rice husk, oil tea shell and cotton seed hulls being respectively dried, crushed
40 mesh sieves are crossed, the above-mentioned raw materials after sieving are uniform in stirrer for mixing, obtain fuel matrix;
(2) graphene, coconut shell powder are added in above-mentioned fuel matrix, being sufficiently stirred makes it well mixed, is stirring
During add a small amount of water and the moisture in the mixed-powder that controls to obtain is 10-12%;
(3) gained mixed-powder is squeezed into graininess in press, and composite biomass is obtained after being cooled to room temperature
Grain fuel.
Comparative example 5
A kind of compound biomass granular fuel, it is made of the raw material of following mass percents:
Fuel matrix 95.2%, graphene 1.0%, coconut shell powder 3.8%;
Wherein described fuel matrix is made of the raw material of following weight parts:
Wheat straw 30, wood chip 20, corncob 20, peanut shell 20,
Straw 20, rice husk 15, oil tea shell 15, cotton seed hulls 15.
Preparation method is as follows:
(1) after wheat straw, wood chip, corncob, peanut shell, straw, rice husk, oil tea shell and cotton seed hulls being respectively dried, crushed
40 mesh sieves are crossed, the above-mentioned raw materials after sieving are uniform in stirrer for mixing, obtain fuel matrix;
(2) graphene, coconut shell powder are added in above-mentioned fuel matrix, being sufficiently stirred makes it well mixed, is stirring
During add a small amount of water and the moisture in the mixed-powder that controls to obtain is 10-12%;
(3) gained mixed-powder is squeezed into graininess in press, and composite biomass is obtained after being cooled to room temperature
Grain fuel.
Combustibility is tested
Combustibility test is carried out to obtained compound biomass granular fuel in above-described embodiment 1-3, comparative example 1-5.
Test event:
Total heating effect:The total amount of heat (kCal/kg) that the fuel of Unit Weight is sent;
It is segmented heating effect:The heat that the fuel of analytical unit weight is sent in the preceding second half section of total burning time respectively
(kCal/kg);
Firing duration:Under identical burning condition, the fuel combustion of Unit Weight finishes required time (second/kg);
Slag yield:Weight of slagging tap after the fuel combustion of Unit Weight accounts for the percentage (%) of weight of fuel.
The combustibility test result of each compound biomass granular fuel sample is as shown in table 1 below.
The combustibility test result of the compound biomass granular fuel of table 1
It can be seen from Table 1 that compared with each comparative example group, compound biomass granular fuel (embodiment 1-3 of the present invention
Group) it can slow down burning velocity on the premise of its total burning efficiency is ensured, significantly extend firing duration, according to segmentation
Heating effect result understands that the burning velocity of fuel of the present invention is moderate, and its combustion heat can steadily be released with more constant speed
Put, so as to avoid, production temperature drastically raises caused by rapid, high volume heat release in the short time, is advantageous to finish enterprise's production
The normal operation of technique, it is especially suitable for the production requirement of such enterprise.
The preferred embodiments of the disclosure and embodiment are explained in detail above, but the present invention is not limited to
The above-described embodiment and examples, in those skilled in the art's possessed knowledge, the present invention can also not departed from
Various changes can be made on the premise of design.
Claims (7)
1. a kind of compound biomass granular fuel, it is characterised in that it is made of the raw material of following mass percents:
Fuel matrix 95.6-96.0%, graphene 0.6-0.8%, coconut shell powder 3.2-3.8%;
Wherein described fuel matrix is made of the raw material of following weight parts:
Wheat straw 30-40, wood chip 20-30, corncob 20-30, peanut shell 20-25,
Straw 20-25, rice husk 15-20, oil tea shell 15-20, cotton seed hulls 15-20;
The compound biomass granular fuel is made by following steps:
(1) 40 are crossed after wheat straw, wood chip, corncob, peanut shell, straw, rice husk, oil tea shell and cotton seed hulls being respectively dried, crushed
Mesh sieve, the above-mentioned raw materials after sieving are uniform in stirrer for mixing, obtain fuel matrix;
(2) graphene, coconut shell powder are added in above-mentioned fuel matrix, being sufficiently stirred makes it well mixed, in whipping process
Moisture in the middle mixed-powder for adding a small amount of water and controlling to obtain is 10-12%;
(3) gained mixed-powder extrusion forming in press, this compound biomass granular fuel is obtained after being cooled to room temperature.
2. compound biomass granular fuel as claimed in claim 1, wherein the mass percent of each raw material is:
Fuel matrix 95.6%, graphene 0.6%, coconut shell powder 3.8%;
Wherein described fuel matrix is made of the raw material of following weight parts:
Wheat straw 30, wood chip 20, corncob 20, peanut shell 20,
Straw 20, rice husk 15, oil tea shell 15, cotton seed hulls 15.
3. compound biomass granular fuel as claimed in claim 1, wherein the mass percent of each raw material is:
Fuel matrix 95.8%, graphene 0.7%, coconut shell powder 3.5%;
Wherein described fuel matrix is made of the raw material of following weight parts:
Wheat straw 35, wood chip 25, corncob 25, peanut shell 20,
Straw 20, rice husk 20, oil tea shell 15, cotton seed hulls 15.
4. compound biomass granular fuel as claimed in claim 1, wherein the mass percent of each raw material is:
Fuel matrix 96.0%, graphene 0.8%, coconut shell powder 3.2%;
Wherein described fuel matrix is made of the raw material of following weight parts:
Wheat straw 40, wood chip 30, corncob 30, peanut shell 25,
Straw 25, rice husk 20, oil tea shell 20, cotton seed hulls 20.
5. compound biomass granular fuel as claimed in claim 1, it is characterised in that obtained composite biomass particle combustion
Expect for graininess, bar-shaped, strip or bulk.
6. application of the compound biomass granular fuel as described in claim any one of 1-5 in biofuel products are prepared.
7. a kind of preparation method of compound biomass granular fuel, comprises the steps:
(1) 40 are crossed after wheat straw, wood chip, corncob, peanut shell, straw, rice husk, oil tea shell and cotton seed hulls being respectively dried, crushed
Mesh sieve, the above-mentioned raw materials after sieving are uniform in stirrer for mixing, obtain fuel matrix;
(2) graphene and coconut shell powder are weighed, wherein graphene quality is equivalent to the compound biomass granular fuel gross mass
0.6-0.8%, coconut shell powder quality equivalent to the compound biomass granular fuel gross mass 3.2-3.8%, by graphite
Alkene and coconut shell powder are added in above-mentioned fuel matrix, and being sufficiently stirred makes it well mixed, and a small amount of water is added in whipping process
And the moisture in the mixed-powder for controlling to obtain is 10-12%;
(3) gained mixed-powder is squeezed into graininess, bar-shaped, strip or bulk in press, is obtained after being cooled to room temperature
Compound biomass granular fuel.
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CN109022083A (en) * | 2018-07-29 | 2018-12-18 | 深圳市心版图科技有限公司 | A kind of biomass new energy fuel and preparation method thereof |
CN110747031A (en) * | 2019-11-26 | 2020-02-04 | 金玖洲新能源有限公司 | Biological new energy fuel and preparation method thereof |
CN111019730A (en) * | 2019-12-10 | 2020-04-17 | 固始龙海新能源科技有限公司 | Multilayer-structure composite biomass granular fuel with stable heat release and preparation method thereof |
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EP4100496A1 (en) * | 2020-02-06 | 2022-12-14 | Bai, Hong Mei | Process for producing solid biomass fuel |
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