JPWO2021140492A5 - - Google Patents
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- JPWO2021140492A5 JPWO2021140492A5 JP2022541897A JP2022541897A JPWO2021140492A5 JP WO2021140492 A5 JPWO2021140492 A5 JP WO2021140492A5 JP 2022541897 A JP2022541897 A JP 2022541897A JP 2022541897 A JP2022541897 A JP 2022541897A JP WO2021140492 A5 JPWO2021140492 A5 JP WO2021140492A5
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- 238000000034 method Methods 0.000 claims 11
- 238000001723 curing Methods 0.000 claims 7
- 230000005855 radiation Effects 0.000 claims 7
- 239000011248 coating agent Substances 0.000 claims 6
- 238000000576 coating method Methods 0.000 claims 6
- 239000011162 core material Substances 0.000 claims 6
- 239000002537 cosmetic Substances 0.000 claims 4
- 238000004049 embossing Methods 0.000 claims 3
- 239000004922 lacquer Substances 0.000 claims 3
- 239000007788 liquid Substances 0.000 claims 3
- 229920001169 thermoplastic Polymers 0.000 claims 3
- 239000004416 thermosoftening plastic Substances 0.000 claims 3
- 229910000831 Steel Inorganic materials 0.000 claims 2
- 239000000463 material Substances 0.000 claims 2
- 239000002184 metal Substances 0.000 claims 2
- 239000000203 mixture Substances 0.000 claims 2
- -1 polyethylene terephthalate Polymers 0.000 claims 2
- 238000003847 radiation curing Methods 0.000 claims 2
- 239000010959 steel Substances 0.000 claims 2
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 claims 1
- 239000004925 Acrylic resin Substances 0.000 claims 1
- 229920000178 Acrylic resin Polymers 0.000 claims 1
- 238000004140 cleaning Methods 0.000 claims 1
- 238000004040 coloring Methods 0.000 claims 1
- 238000005520 cutting process Methods 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N monoethanolamine hydrochloride Natural products NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims 1
- 239000000049 pigment Substances 0.000 claims 1
- 229920000728 polyester Polymers 0.000 claims 1
- 229920000139 polyethylene terephthalate Polymers 0.000 claims 1
- 239000005020 polyethylene terephthalate Substances 0.000 claims 1
- 238000007788 roughening Methods 0.000 claims 1
- 238000007493 shaping process Methods 0.000 claims 1
- 239000013008 thixotropic agent Substances 0.000 claims 1
Claims (26)
－ 上面（１００Ａ）および下面が与えられた芯材（１００，２００，３００）と、
－ 前記芯材（１００，２００，３００）の前記上面（１００Ａ）に直接または間接的に貼り付けられた化粧上部構造物（２０１）とを備え、
前記化粧上部構造物（２０１）が、
・ 少なくとも１つの化粧像を形成する少なくとも１つの化粧印刷層（２０１，３０１，３０８）と、
・ 前記印刷層（２０１，３０１，３０８）を少なくとも部分的に覆う、実質的に透明または半透明の三次元エンボス構造物（２０２，３０５）とを含み、
前記エンボス構造物（２０２，３０５）が、
○ 複数の凹部（１０３，２０３）が設けられている、少なくとも１つの、少なくとも部分的に硬化されたベース層（１０１，２０４，３０６Ａ，３０６Ｂ）と、
○ 前記ベース層（１０１，２０４，３０６Ａ，３０６Ｂ）の上にデジタル印刷された複数の隆起部（１０５，２０５）によって形成されている、少なくとも１つの、少なくとも部分的に硬化された隆起パターン層（３０７）と、を含む多層エンボス構造物（２０２，３０５）であり、
前記エンボス構造物（２０２，３０５）の上部表面の少なくとも一部に粗面化テクスチャが形成されており、好ましくは、
－ 前記粗面化エンボス構造物（２０２，３０５）を少なくとも部分的に覆う少なくとも１つの仕上げ層（３０９）
を備える、化粧表面被覆部材。 A decorative surface covering member, in particular a decorative panel (110, 220, 330, 400A, 400B) such as a floor panel, ceiling panel or wall panel,
- a core material (100, 200, 300) provided with an upper surface (100A) and a lower surface;
- a decorative upper structure (201 ) attached directly or indirectly to the upper surface (100A) of the core material (100, 200, 300) ,
The decorative upper structure (201)
- at least one decorative print layer (201, 301, 308) forming at least one decorative image;
- a substantially transparent or translucent three-dimensional embossed structure (202, 305) at least partially covering the printing layer (201, 301, 308);
The embossed structure (202, 305) is
o at least one at least partially cured base layer (101, 204, 306A, 306B) provided with a plurality of recesses (103, 203 );
o at least one at least partially cured raised pattern layer formed by a plurality of digitally printed ridges (105, 205) on said base layer (101, 204, 306A, 306B ) ; 307) , and a multilayer embossed structure (202, 305) ,
A roughened texture is formed on at least a portion of the upper surface of the embossed structure (202, 305) , preferably,
- at least one finishing layer (309 ) at least partially covering said roughened embossed structures (202, 305 );
A decorative surface covering member comprising:
前記隆起部（１０５，２０５）の少なくとも一部が、前記ベース層（１０１，２０４，３０６Ａ，３０６Ｂ）のうちの凹部がない前記部分に印刷される、請求項１から３のいずれか一項に記載の表面被覆部材。 The plurality of recesses (103, 203 ) are provided in a part of the base layer (101 , 204, 306A, 306B), and the recess is provided in another part of the base layer (101, 204, 306A, 306B). There is no
4. According to any one of claims 1 to 3 , at least part of the raised portions (105, 205) are printed on the portions of the base layer (101, 204, 306A, 306B) that are free of recesses. The surface coating member described.
前記ベース層（１０１，２０４，３０６Ａ，３０６Ｂ）に設けられた前記凹部（１０３，２０３）は、深さが２マイクロメートルから１００マイクロメートルの間、好ましくは３マイクロメートルから５０マイクロメートルの間にあり、
前記隆起パターン層（３０７）の前記隆起部（１０５，２０５）は、高さが２マイクロメートルから５００マイクロメートルの間、好ましくは３マイクロメートルから３００マイクロメートルの間にあり、
前記ベース層（１０１，２０４，３０６Ａ，３０６Ｂ）の前記凹部（１０３，２０３）の少なくとも一部が、前記化粧印刷層（２０１，３０１，３０８）によって形成された少なくとも１つの化粧像の少なくとも一部と位置合わせ調整される、請求項１から５のいずれか一項に記載の表面被覆部材。 The base layer (101, 204, 306A, 306B) is a printing base layer (101, 204, 306A, 306B) ,
The recesses (103, 203) provided in the base layer (101, 204, 306A, 306B) have a depth between 2 micrometers and 100 micrometers, preferably between 3 micrometers and 50 micrometers. can be,
the ridges (105, 205) of the raised pattern layer (307) have a height between 2 micrometers and 500 micrometers, preferably between 3 micrometers and 300 micrometers;
At least a portion of the recess (103, 203) of the base layer (101, 204, 306A, 306B) is at least a portion of at least one decorative image formed by the decorative printing layer (201, 301, 308). The surface covering member according to any one of claims 1 to 5, which is aligned and adjusted with .
少なくとも１つの追加の化粧印刷層（２０１，３０１，３０８）が、少なくとも１つのベース層（１０１，２０４，３０６Ａ，３０６Ｂ）および少なくとも１つの隆起パターン層（３０７）に位置している、請求項１から６のいずれか一項に記載の表面被覆部材。 At least a portion of the raised portions (105, 205) of the raised pattern layer (307 ) are aligned with at least a portion of the at least one decorative image formed by the decorative print layer (201, 301, 308). is,
1 . The at least one additional decorative print layer ( 201 , 301 , 308 ) is located on the at least one base layer ( 101 , 204 , 306 A, 306 B) and the at least one raised pattern layer ( 307 ). 7. The surface coating member according to any one of 6 to 6 .
前記凹部（１０３，２０３）の少なくとも一部が、化学的にエンボス加工された凹部（１０３，２０３）である、請求項１から７のいずれか一項に記載の表面被覆部材。 a colored coating is applied in the recess (103, 203) and on the base layer (101, 204, 306A, 306B) ;
Surface covering member according to any one of claims 1 to 7, wherein at least some of the recesses (103, 203) are chemically embossed recesses (103, 203) .
前記隆起パターン層（３０７）が、バイアクリレート、好ましくはトリプロピレン・グリコール・バイアクリレートを含む、請求項１から９のいずれか一項に記載の表面被覆部材。 the raised pattern layer (307) contains acrylic resin;
Surface covering member according to any one of the preceding claims, wherein the raised pattern layer (307) comprises a biacrylate, preferably tripropylene glycol biacrylate .
少なくとも１つの仕上げ層（３０９）が付着され、少なくとも１つの仕上げ層（３０９）にはいかなる粗面化テクスチャもない、請求項１から１０のいずれか一項に記載の表面被覆部材。 at least one finishing layer (309) is applied, said upper surface of said embossed structure (202, 305) being completely covered by a finishing layer (309) , in particular a lacquer layer ;
Surface covering element according to any one of the preceding claims, on which at least one finishing layer (309) is applied, the at least one finishing layer (309) being free of any roughening texture .
前記芯材（１００，２００，３００）の前記上面（１００Ａ）に、好ましくはプライマー（２０６Ａ，２０６Ｂ）またはフィルムによって形成された支持体層（２０６，３０２）が設けられ、前記化粧層の少なくとも一部が前記支持体層（２０６，３０２）に直接印刷される、請求項１から１１のいずれか一項に記載の表面被覆部材。 At least a part of the decorative layer is printed directly on the upper surface (100A) of the core material (100, 200, 300) ,
A support layer (206, 302) preferably formed of a primer (206A, 206B) or a film is provided on the upper surface (100A) of the core material (100, 200, 300), and at least one of the decorative layers Surface covering element according to any one of claims 1 to 11, wherein the parts are printed directly on the support layer (206, 302) .
少なくとも１つの中間層（３０３）が、透明または半透明で光反射性の熱可塑性層（３０３）によって、好ましくはポリエステル層によって、より好ましくはポリエチレン・テレフタレート層によって形成され、
前記光反射性の熱可塑性層（３０３）が前記印刷化粧層（３０１，３０８）に接着され、
前記ベース層（１０１，２０４，３０６Ａ，３０６Ｂ）が、前記光反射性の熱可塑性層（３０３）の上部に直接付着され、より好ましくは、前記粗面化テクスチャが少なくとも前記中間層（３０３）の一部に設けられている、請求項１から１２のいずれか一項に記載の表面被覆部材。 at least one intermediate layer (303 ) is located between the printed decorative layer (301, 308) and the embossed structure (202, 305) ;
at least one intermediate layer (303) is formed by a transparent or translucent light-reflective thermoplastic layer (303), preferably by a polyester layer, more preferably by a polyethylene terephthalate layer;
the light-reflective thermoplastic layer (303) is adhered to the printed decorative layer (301, 308);
Said base layer (101, 204, 306A, 306B) is deposited directly on top of said light-reflective thermoplastic layer (303), more preferably said roughened texture forms at least one of said intermediate layers (303). The surface covering member according to any one of claims 1 to 12, which is partially provided .
前記芯材（１００，２００，３００）の前記上面（１００Ａ）が実質的に平坦である、請求項１から１３のいずれか一項に記載の表面被覆部材。 the embossed structure (202, 305) comprises a plurality of base layers (101, 204, 306A, 306B) and/or a plurality of raised pattern layers (307) ;
Surface covering member according to any one of claims 1 to 13, wherein the upper surface (100A) of the core (100, 200, 300) is substantially flat .
前記エンボス構造物（２０２，３０５）の前記上部表面の前記粗面化テクスチャが、隣り合う実質的に平坦な、ある角度を相互に囲む複数の表面小平面を含む、請求項１から１４のいずれか一項に記載の表面被覆部材。 the roughened texture is a brush roughened texture;
15. Any of claims 1 to 14, wherein the roughened texture of the upper surface of the embossed structure (202, 305) comprises a plurality of adjacent substantially flat surface facets mutually surrounding an angle. The surface coating member according to item (1).
前記ベース層（１０１，２０４，３０６Ａ，３０６Ｂ）および／または前記パターン層（３０７）が水性インク組成物から成り、
前記ベース層（１０１，２０４，３０６Ａ，３０６Ｂ）および／または前記パターン層（３０７）が、ａ）少なくとも１つの有機および／または水性のインク媒体と、（ｂ）少なくとも１つのエタノールアミン化合物と、（ｃ）顔料などの少なくとも１つの着色材料とを含むインク組成物から成る、請求項１から１５のいずれか一項に記載の表面被覆部材。 the embossed structure (202, 305) comprises at least one thixotropic agent;
The base layer (101, 204, 306A, 306B) and/or the pattern layer (307) are made of an aqueous ink composition,
Said base layer (101, 204, 306A, 306B) and/or said patterned layer (307) comprises: a) at least one organic and/or aqueous ink medium; (b) at least one ethanolamine compound; c) at least one coloring material such as a pigment, and comprising an ink composition according to any one of claims 1 to 15 .
前記粗面化テクスチャが前記ベース層（１０１，２０４，３０６Ａ，３０６Ｂ）の少なくとも一部と、前記パターン層（３０７）の少なくとも一部との両方に形成される、請求項１から１６のいずれか一項に記載に記載の表面被覆部材。 A roughened texture is formed on the entire upper surface of the embossed structure (202, 305) ,
17. Any one of claims 1 to 16, wherein the roughened texture is formed on both at least part of the base layer (101, 204, 306A, 306B) and at least part of the patterned layer (307). The surface coating member according to item 1.
前記エンボス構造物（２０２，３０５）が印刷エンボス構造物（２０２，３０５）であり、前記印刷エンボス構造物（２０２，３０５）の上部表面の少なくとも一部に機械粗面化テクスチャが形成されている、前記請求項１から１７のいずれか一項に記載の表面被覆部材。 the roughened texture includes a plurality of scratches and/or sharp edges;
The embossed structure (202, 305) is a printed embossed structure (202, 305), and a mechanically roughened texture is formed on at least a part of the upper surface of the printed embossed structure (202, 305). , the surface covering member according to any one of claims 1 to 17 .
Ａ）少なくとも１つの化粧像を前記芯材（１００，２００，３００）の前記上面（１００Ａ）に印刷によって、好ましくはデジタル印刷によって形成するステップと、
Ｂ）液体ベース層（１０１）を、ステップＡ）の間に形成された少なくとも１つの化粧像の少なくとも一部に付着させるステップと、
Ｃ）エンボス液滴（１０２）が噴霧されている位置で前記ベース層（１０１，２０４，３０６Ａ，３０６Ｂ）の厚さが変化するようにして、これらの位置で凹部（１０３，２０３）が前記液体ベース層（１０１）に形成されるように、複数のエンボス液滴（１０２）を液体のベース層（１０１）の上に、位置選択的に印刷するステップと、
Ｄ）前記凹部（１０３，２０３）が設けられた前記ベース層（１０１，２０４，３０６Ａ，３０６Ｂ）を少なくとも部分的に硬化させるステップと、
Ｅ）複数の隆起部（１０５，２０５）によって形成される隆起パターン層（３０７）を前記ベース層（１０１，２０４，３０６Ａ，３０６Ｂ）に、好ましくは、ステップＤ）の間に少なくとも部分的に硬化されている前記ベース層（１０１，２０４，３０６Ａ，３０６Ｂ）に、位置選択的に印刷するステップと、
Ｆ）前記パターン層（３０７）を部分的に硬化させるステップであって、前記ベース層（１０１，２０４，３０６Ａ，３０６Ｂ）と前記パターン層（３０７）が一緒にエンボス構造物（２０２，３０５）を形成するステップと、
Ｇ）前記エンボス構造物（２０２，３０５）の前記上部表面の少なくとも一部を機械的に処理して前記エンボス構造物（２０２，３０５）に粗面化テクスチャを形成するステップと、
Ｋ）前記エンボス構造物（２０２，３０５）の前記粗面化上部表面に、好ましくは少なくとも１つのラッカー層を含む、少なくとも１つの仕上げ層（３０９）を付着させるステップと
を含む方法。 A method for manufacturing a decorative surface covering member according to any one of claims 1 to 18, comprising:
A) forming at least one cosmetic image on the upper surface (100A) of the core (100, 200, 300 ) by printing, preferably by digital printing;
B) applying a liquid base layer (101) to at least a portion of the at least one cosmetic image formed during step A);
C ) The thickness of the base layer (101, 204, 306A, 306B) changes at the positions where the embossed droplets (102) are sprayed, so that the recesses (103, 203) are formed at these positions. positionally selectively printing a plurality of embossed droplets (102) onto the liquid base layer (101) so as to be formed in the liquid base layer (101);
D) at least partially curing the base layer (101, 204, 306A , 306B) provided with the recess (103, 203);
E) applying a raised pattern layer (307) formed by a plurality of ridges (105, 205) to said base layer (101, 204, 306A, 306B) , preferably at least partially curing during step D); positionally selectively printing on the base layer (101, 204, 306A, 306B) that is
F) partially curing the patterned layer (307) , wherein the base layer (101, 204, 306A, 306B) and the patterned layer (307) together form an embossed structure (202, 305); a step of forming;
G) mechanically treating at least a portion of the upper surface of the embossed structure (202, 305) to form a roughened texture in the embossed structure (202, 305) ;
K) applying on said roughened upper surface of said embossed structure (202, 305) at least one finishing layer (309) , preferably comprising at least one lacquer layer.
ステップＤ）の間に前記ベース層（１０１，２０４，３０６Ａ，３０６Ｂ）の６０％から９０％が硬化され、
ステップＦ）の間に前記パターン層（３０７）の６０％から９０％が硬化される、請求項２０に記載の方法。 during step G) material is removed from said embossed structure (202, 305) ;
During step D) 60% to 90% of said base layer (101, 204, 306A, 306B) is cured;
21. A method according to claim 20, wherein between 60% and 90% of the patterned layer (307) is cured during step F) .
ステップＧ）の間に前記エンボス構造物（２０２，３０５）の前記上部表面の少なくとも一部が、軸方向に回転する少なくとも２つの連続するブラシ・ローラ（１２０ａ，１２０ｂ，１２０ｃ，１３０）、好ましくは金属ブラシ・ローラ、特に鋼ブラシ・ローラを使用して少なくとも２回処理され、
ステップＧ）の間に少なくとも２つのブラシ・ローラ（１２０ａ，１２０ｂ，１２０ｃ，１３０）が互いに反対方向に回転する、請求項２０または２１に記載の方法。 During step G), at least a portion of the upper surface of the embossing structure (202, 305) comprises at least one axially rotating brush roller (120a, 120b, 120c, 130) , preferably a metal brush. Processed using rollers, especially steel brush rollers,
During step G) at least a portion of the upper surface of the embossing structure (202, 305) is rotated by at least two successive axially rotating brush rollers (120a, 120b, 120c, 130), preferably processed at least twice using metal brush rollers, especially steel brush rollers;
22. A method according to claim 20 or 21, wherein during step G) at least two brush rollers (120a, 120b, 120c, 130) rotate in opposite directions .
ステップＫ）が適用され、ステップＨ）がステップＧ）の後に、かつステップＫ）の前に実行される、請求項２０から２２のいずれか一項に記載の方法。 the method comprises a step H), subsequent to performing step G), comprising the step of mechanically cleaning the surface covering member, in particular the embossed structure (202, 305) ;
23. A method according to any one of claims 20 to 22, wherein step K) is applied and step H) is performed after step G) and before step K) .
前記方法が、少なくとも１つの表面被覆部材の少なくとも１つの縁部を賦形することを含むステップＪ）を含む、請求項２０から２３のいずれか一項に記載の方法。 the method comprises step I) comprising the step of cutting the surface covering member into a plurality of smaller surface covering members ;
24. A method according to any one of claims 20 to 23, wherein the method comprises step J) comprising shaping at least one edge of at least one surface covering member .
ステップＥ）の間に、前記隆起パターン（３０７）が、ステップＡ）の間に形成された少なくとも１つの化粧像の少なくとも一部と位置合わせ調整されている第２のデジタルテンプレートに従って、前記ベース層（１０１，２０４，３０６Ａ，３０６Ｂ）に印刷され、
前記第１のデジタルテンプレートが前記第２のデジタルテンプレートとは異なり、
ステップＤ）による前記ベース層（１０１，２０４，３０６Ａ，３０６Ｂ）の硬化、および／またはステップＦ）による前記パターン層（３０７）の硬化が、好ましくはＵＶ放射および／または電子放射および／またはＩＲ放射および／またはエキシマ放射による放射線硬化で行われ、
好ましくは、ステップＫ）が適用され、前記方法が、ステップＫ）の間に付着される前記少なくとも１つの仕上げ層（３０９）、特に前記少なくとも１つのラッカー層を放射線硬化によって、好ましくはＵＶ放射および／またはＩＲ放射および／またはエキシマ放射によって硬化する前記ステップを含むステップＬ）を含む、請求項２０から２４のいずれか一項に記載の方法。 During step C), the embossed droplets (102) are aligned with at least a portion of the at least one cosmetic image formed during step A) according to a first digital template. printed on the base layer (101) ,
During step E), the base layer is arranged in accordance with a second digital template in which the raised pattern (307) is aligned with at least a portion of the at least one cosmetic image formed during step A). (101, 204, 306A, 306B),
the first digital template is different from the second digital template,
The curing of said base layer (101, 204, 306A, 306B) according to step D) and/or the curing of said patterned layer (307) according to step F) is preferably carried out by UV radiation and/or electron radiation and/or IR radiation. and/or radiation curing with excimer radiation,
Preferably, step K) is applied and said method comprises curing said at least one finishing layer (309), in particular said at least one lacquer layer, applied during step K) by radiation curing, preferably by UV radiation and 25. A method according to any one of claims 20 to 24, comprising a step L) comprising said step of curing by IR radiation and/or excimer radiation .
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|---|---|---|---|
| NL2024631 | 2020-01-09 | ||
| NL2024631A NL2024631B1 (en) | 2020-01-09 | 2020-01-09 | Decorative surface covering element, surface covering element covering, and method of producing such a decorative surface covering element |
| PCT/IB2021/050164 WO2021140492A1 (en) | 2020-01-09 | 2021-01-11 | Decorative surface covering element, surface covering element covering, and method of producing such a decorative surface covering element |
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| JP2023510763A JP2023510763A (en) | 2023-03-15 |
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| EP (1) | EP4087989B1 (en) |
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| CA (1) | CA3161092A1 (en) |
| DK (1) | DK4087989T3 (en) |
| MX (1) | MX2022008033A (en) |
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| NL2027548B1 (en) * | 2021-02-12 | 2022-09-12 | I4F Licensing Nv | Decorative panel, and decorative panel covering |
| NL2030319B1 (en) * | 2021-12-28 | 2023-07-03 | I4F Licensing Nv | Method for manufacturing personalized decorative laminated panels, and personalized decorative laminated panels |
| WO2024013561A1 (en) * | 2022-07-11 | 2024-01-18 | Decora S.A. | Decorative plate with a synchronous structure and the method of its production |
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| JPH0780995A (en) * | 1993-09-14 | 1995-03-28 | Dantani Plywood Co Ltd | Manufacture of decorative plate |
| US6908663B1 (en) * | 2000-11-15 | 2005-06-21 | Awi Licensing Company | Pigmented radiation cured wear layer |
| US7081291B2 (en) * | 2002-01-11 | 2006-07-25 | Domco Tarkett Inc. | Selectively embossed surface coverings and processes of manufacture |
| US7597777B2 (en) * | 2005-09-09 | 2009-10-06 | The Procter & Gamble Company | Process for high engagement embossing on substrate having non-uniform stretch characteristics |
| BE1016875A5 (en) * | 2005-12-23 | 2007-08-07 | Flooring Ind Ltd | FLOOR PANEL AND METHOD FOR MANUFACTURING SUCH FLOOR PANEL. |
| PL2839957T3 (en) * | 2010-04-13 | 2019-08-30 | Välinge Innovation AB | Embossed and digital printed building panel and method for its fabrication |
| HUE062323T2 (en) * | 2013-06-20 | 2023-10-28 | Xylo Tech Ag | Directly printed panel having a two-layer design |
| BE1021743B1 (en) * | 2013-12-10 | 2016-01-14 | Unilin Bvba | FLOORING AND MANUFACTURING METHOD |
| US11230631B2 (en) * | 2015-08-24 | 2022-01-25 | Toppan Printing Co., Ltd. | Decorative sheet, and transparent resin sheet |
| US10718118B2 (en) * | 2015-11-09 | 2020-07-21 | Dale Thomas | Simulated rock panels |
| US10618335B2 (en) * | 2015-12-15 | 2020-04-14 | Hewlett-Packard Development Company, L.P. | Embossed print media |
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