JPWO2016084615A1 - Liquid skin preparation - Google Patents

Abstract

Component A: nylon powder, component B: bentonite and / or laponite, component C: organic salt and / or inorganic salt, component D: nonionic surfactant, and component E: water, and the content of component A is 0 0.5 to 5.0% by mass, the content of Component B is 0.4% by mass or less, the content of Component C is 0.1 to 3.0% by mass, Liquid skin external preparation whose mass ratio [(content of said component A) / (content of said component B)] of content of said component A with respect to content is 100 or less. The liquid skin external preparation of this invention can be used as a lotion, for example.

Description

  The present invention relates to a liquid external preparation for skin.

  As a liquid skin external preparation used for cosmetics, a liquid skin external preparation containing powder in a liquid such as water or alcohol is known. For example, it is known that when a lotion containing nylon powder is applied to the skin, the nylon powder remains on the skin surface after moisture has volatilized, and a smooth feeling can be obtained. Such a skin lotion is used when the nylon powder settles and separates into two layers during storage, and when used, the nylon powder is shaken to disperse and then applied to the skin.

For example, Patent Document 1 contains the following components (A), (B), (C), (D) and (E), and the mass ratio of ethanol to water (D) / (E) is 20/80. A two-layer type cosmetic characterized by ˜80 / 20 is disclosed.
(A) Organic powder (B) Water-soluble inorganic salt (C) Surfactant (D) Ethanol (E) Water

  In such a liquid external preparation for skin, a component that is hardly soluble in water such as a fragrance or menthol may be added, but the component that is hardly soluble in water is adsorbed to the powder, so there is no solubilizer. Can be solubilized.

JP 2004-262887 A

  However, when the content of a component hardly soluble in water in the liquid skin external preparation is large or when the liquid skin external preparation is stored for a long period of time, the solubilizing ability of the powder is insufficient, and the liquid skin external preparation The liquid may become opaque and impair the appearance.

  Then, the present inventors examined improving solubilization ability more by mix | blending nonionic surfactant as a solubilizer in the liquid skin external preparation containing a nylon powder. As a result, although the solubilizing ability of the liquid skin external preparation is improved, if a nonionic surfactant is included as a solubilizing agent in the liquid skin external preparation containing nylon powder, nylon powder caking may occur. I understood. In addition, in order to suppress this caking, when bentonite and / or laponite, and organic salt and / or inorganic salt are further blended, depending on the content range of the components, the liquid skin external preparation may be separated into three layers to give an appearance. It turns out that there is a case to lose.

  An object of the present invention is to provide a liquid external preparation for skin that suppresses caking and three-layer separation and is easy to use.

The present invention solves the above problems,
Component A: nylon powder, component B: bentonite and / or laponite, component C: organic salt and / or inorganic salt, component D: nonionic surfactant, and component E: water,
The content of component A is 0.5 to 5.0% by mass,
The content of component B is 0.4% by mass or less
The content of component C is 0.1 to 3.0% by mass,
The liquid skin external preparation whose mass ratio [(content of the said component A) / (content of the said component B)] of content of the said component A with respect to content of the said component B is 100 or less.

  ADVANTAGE OF THE INVENTION According to this invention, the liquid skin external preparation which suppresses caking and three-layer separation and is easy to use can be provided.

  The liquid skin external preparation of the present invention is essential for component A: nylon powder, component B: bentonite and / or laponite, component C: organic salt and / or inorganic salt, component D: nonionic surfactant, and component E: water. Contains as an ingredient. The liquid skin external preparation of this invention may contain components other than the said component A, component B, component C, component D, and component E.

  In the present specification, “liquid” has a viscosity at 25 ° C. of 3000 mPa · s or less, preferably 1 to 1000 mPa · s, and more preferably 1 to 200 mPa · s. The viscosity can be measured with a tuning fork type vibration viscometer.

  In this specification, each component (for example, component AD) may use only 1 type, and may use 2 or more types. In addition, in this specification, content of each component means the total amount, when using 2 or more types of the same component.

  Component A is nylon powder (also referred to as nylon powder or nylon particles). In the liquid skin external preparation of the present invention, Component A mainly exerts an effect of imparting a smooth feel (smooth feeling) to the skin after application. In addition, for example, when applied to the face, an effect of suppressing glare can be exhibited. The smooth feeling refers to, for example, a dry feeling without stickiness.

  Examples of the component A material include nylon 6 and nylon 12. Of these, nylon 12 is preferred.

  The average particle size of component A is not particularly limited, but is preferably 1.0 to 40.0 μm, more preferably 1.0 to 20.0 μm, and still more preferably 3.0 to 10.0 μm.

  In the present specification, the average particle diameter can be measured by a laser diffraction scattering method. Specifically, for example, it can be measured using a laser diffraction / scattering particle size distribution analyzer (LA950V2 manufactured by HORIBA).

  As Component A, a commercially available product can be used. As said commercial item, the product name "Ganz Pearl GPA-550" by Aika Kogyo Co., Ltd .; the product name "Orgasol (R) 2002 EXD NAT COS" by Arkema Co., Ltd., etc. are mentioned, for example.

  Component A may be used alone or in combination of two or more.

  The content of Component A is 0.5% by mass or more, preferably 1.0% by mass or more, and preferably 1.5% by mass or more in 100% by mass of the liquid skin external preparation of the present invention from the viewpoint of obtaining a smooth feeling. Is more preferable. Further, the content of Component A is 5.0% by mass or less, preferably 4.5% by mass or less, in 100% by mass of the liquid skin external preparation of the present invention, from the viewpoint of preventing unpleasant squeakiness. 0.0 mass% or less is more preferable. That is, the content of component A is 0.5 to 5.0% by mass in 100% by mass of the liquid external preparation for use in the present invention, preferably 1.0 to 4.5% by mass, and 1.5 to 4%. 0.0 mass% is more preferable. The content of component A is the total content of all components A in the liquid skin external preparation of the present invention. Note that the squeaky feeling means, for example, a feeling that the powder and the powder rub against each other and feel an unnatural catch.

  Component B is bentonite and / or laponite (ie, one or both of bentonite and laponite). In the liquid skin external preparation of the present invention, Component B mainly exhibits the effect of suppressing Component A caking. Component B may use only 1 type and may use 2 or more types.

  The content of Component B is 0.4% by mass or less, preferably 0.3% by mass or less, and preferably 0.2% by mass in 100% by mass of the liquid skin external preparation of the present invention from the viewpoint of suppressing three-layer separation. % Or less is more preferable. Further, the lower limit of the content of Component B is not particularly limited, but from the viewpoint of suppressing caking, in 100% by mass of the liquid skin external preparation of the present invention, 0.01% by mass or more is preferable, and 0.1% by mass or more. Is more preferable. That is, the content of Component B is 0.4% by mass or less, preferably 0.01 to 0.3% by mass, and preferably 0.1 to 0.2% by mass in 100% by mass of the liquid skin external preparation of the present invention. % Is more preferable. The content of component B is the total content of all components B in the liquid skin external preparation of the present invention.

  The mass ratio of the content of component A to the content of component B [(content of component A) / (content of component B)] is 100 or less, preferably 50 or less, from the viewpoint of suppressing caking. 20 or less is more preferable, and 15 or less is more preferable. Further, the mass ratio of the content of component A to the content of component B [(content of component A) / (content of component B)] is preferably 1.0 or more from the viewpoint of improving the feeling of use. 0.0 or more is more preferable.

  The liquid skin external preparation of the present invention may contain powders other than nylon powder (sometimes referred to as “other powders”) as long as the effects of the present invention are not impaired.

  Other powders are not particularly limited, and examples thereof include polyethylene powder, silica, polystyrene, polymethyl methacrylate (PMMA), urethane, talc, silicone powder, and hydroxyapatite.

  The average particle size of other powders is not particularly limited, but is preferably 0.1 to 40.0 μm, and more preferably 1.0 to 20.0 μm.

  Other powders may be used alone or in combination of two or more.

  When the liquid skin external preparation of the present invention contains other powders, the content of the other powders in the liquid skin external preparation of the present invention is 0.01 to 100 parts by mass of the content of nylon powder. 10.0 mass parts is preferable, More preferably, it is 0.05-1.0 mass part.

  Component C is an organic salt and / or an inorganic salt (ie, one or both of an organic salt and an inorganic salt). Component C, together with Component B, mainly exhibits the effect of suppressing caking of Component A. Component C may use only 1 type and may use 2 or more types.

  Component C includes metal salts (for example, monovalent metal salts, divalent or higher polyvalent metal salts, etc.) and the like. Examples of the metal salt include sodium salt, potassium salt, calcium salt, magnesium salt, zinc salt, ammonium salt, aluminum salt and the like. Specifically, zinc paraphenol sulfonate, sodium chloride, potassium chloride, calcium chloride, magnesium chloride, magnesium sulfate, alum, sodium carbonate, sodium bicarbonate, potassium bicarbonate, ammonium chloride, sodium phosphate, dihydrogen phosphate Examples include sodium, sodium dihydrogen phosphate, sodium citrate (trisodium citrate), disodium edetate, potassium aluminum sulfate, tetrasodium edetate, and zinc pyrrolidonecarboxylate. Among these, zinc salts are preferable, and zinc pyrrolidone carboxylate (PCA zinc) and zinc paraphenol sulfonate are preferable from the viewpoint of obtaining the effect of suppressing sebum due to the liquid external preparation for skin.

  Component C may use only 1 type and may use 2 or more types.

  Content of component C is 0.1 mass% or more in 100 mass% of liquid external preparations of this invention from a viewpoint of caking suppression, 0.4 mass% or more is preferable, and 0.8 mass% or more is preferable. More preferred. Moreover, content of the component C is 3.0 mass% or less in 100 mass% of liquid external preparations of this invention from a viewpoint of suppressing three-layer separation, and 2.0 mass% or less is preferable. 6 mass% or less is more preferable, and 1.2 mass% or less is further more preferable. That is, the content of Component C is 0.1 to 3.0% by mass, preferably 0.1 to 2.0% by mass, in 100% by mass of the liquid skin external preparation of the present invention, and 0.4 to 1 .6% by mass is more preferable, and 0.8 to 1.2% by mass is more preferable. The content of component C is the total content of all components C in the liquid skin external preparation of the present invention.

  Component D is a nonionic surfactant. Component D mainly exhibits the effect of solubilizing poorly water-soluble substances such as fragrances and refreshing ingredients in the water-based composition. Component D may use only 1 type and may use 2 or more types.

  As component D, for example, polyoxyethylene fatty acid, glycerin fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyglycerin fatty acid ester, sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester, sucrose fatty acid ester, polyoxyethylene alkyl ether, Examples include polyoxyethylene polyoxypropylene alkyl ether, polyoxyethylene alkyl phenyl ether, polyoxyethylene (cured) castor oil, fatty acid alkylolamide, and the like. Among these, polyoxyethylene polyoxypropylene alkyl ether and polyoxyethylene (cured) castor oil are preferable. Examples of the polyoxyethylene polyoxypropylene alkyl ether include polyoxyethylene polyoxypropylene decyl tetradecyl ether.

  The content of Component D is not particularly limited, but is preferably 0.01% by mass or more, more preferably 0.1% by mass or more, in 100% by mass of the liquid skin external preparation of the present invention, from the viewpoint of improving the solubilization ability. . In addition, the content of Component D is preferably 5.0% by mass or less, more preferably 1.0% by mass or less, in 100% by mass of the liquid skin external preparation of the present invention, from the viewpoints of caking suppression and usability. That is, the content of Component D is preferably 0.01 to 5.0% by mass and more preferably 0.1 to 1.0% by mass in 100% by mass of the liquid skin external preparation of the present invention. The content of component D is the total content of all components D in the liquid skin external preparation of the present invention.

  Component E is water and is not particularly limited, but purified water is preferred. The content of component E is not particularly limited, but is preferably 50.0% by mass or more, and 60.0% by mass in 100% by mass of the liquid skin external preparation of the present invention from the viewpoint of imparting a refreshing feel like water. The above is more preferable. In addition, the content of component E is preferably 94.0% by mass or less, and 90.0% by mass or less, in 100% by mass of the liquid skin external preparation of the present invention, from the viewpoint of adding ethanol to impart antiseptic power. More preferably, it is more preferably 85.0% by mass or less. That is, the content of Component E is preferably 50.0 to 94.0% by mass, more preferably 60.0 to 90.0% by mass, and more preferably 60.0 to 100% by mass of the liquid skin external preparation of the present invention. 85.0 mass% is more preferable.

  The liquid skin external preparation of the present invention preferably further contains ethanol. The content of ethanol is not particularly limited, but from the viewpoint of improving the feeling of use of the liquid skin external preparation and suppressing irritation to the skin, 40.0 mass% or less is preferable in 100 mass% of the liquid skin external preparation of the present invention, 35.0 mass% or less is more preferable, and 25.0 mass% or less is further more preferable. Further, the content of ethanol is not particularly limited, but from the viewpoint of improving the antiseptic power of the liquid skin external preparation and improving the solubility of the poorly water-soluble component in the liquid skin external preparation, in 100% by mass of the liquid skin external preparation of the present invention. 5.0 mass% or more is preferable, and 15.0 mass% or more is more preferable.

  The liquid skin external preparation of this invention may contain the fragrance | flavor. As the above-mentioned fragrance, known and commonly used fragrances can be used, and in particular, known fragrances used for external preparations for skin and cosmetics are preferable. A fragrance | flavor may use only 1 type and may use 2 or more types.

  Although content of a fragrance | flavor is not specifically limited, From a viewpoint of obtaining sufficient fragrance and fragrance persistence, 0.1 mass% or more is preferable in 100 mass% of liquid skin external preparations of this invention, 0.15 mass% The above is more preferable. Moreover, 1.0 mass% or less is preferable in 100 mass% of liquid external preparations of this invention from a viewpoint of suppressing excessive aromaticity, and, as for content of a fragrance | flavor, 0.5 mass% or less is more preferable. That is, the content of the fragrance is preferably 0.1 to 1.0% by mass and more preferably 0.15 to 0.5% by mass in 100% by mass of the liquid skin external preparation of the present invention.

  The liquid skin external preparation of the present invention may contain a refreshing agent. As the above-mentioned refreshing agent, a known and commonly used refreshing agent can be used, and in particular, a known refreshing agent used for an external preparation for skin and cosmetics is preferable. Although it does not specifically limit as said refreshing agent, For example, a menthol, a menthol derivative (For example, a menthyl glyceryl ether, a menthyl lactate, a menthol glycoside etc.), camphor, mint oil, peppermint oil, eucalyptus oil, etc. are mentioned. From the viewpoint of versatility and cooling effect, menthol (l-menthol) is preferred. Only 1 type may be used for a refreshing agent, and 2 or more types may be used for it.

  Although content of a refreshing agent is not specifically limited, From a viewpoint of obtaining sufficient refreshing feeling, 0.01 mass% or more is preferable in 100 mass% of liquid external preparations of this invention, and 0.02 mass% or more is more. preferable. The content of the refreshing agent is preferably 7.0% by mass or less, more preferably 1.0% by mass or less, in 100% by mass of the liquid external preparation for skin of the present invention, from the viewpoint of suppressing an excessive refreshing feeling. 0.5 mass% or less is more preferable. That is, the content of the refreshing agent is preferably 0.01 to 7.0% by mass, more preferably 0.01 to 1.0% by mass in 100% by mass of the liquid skin external preparation of the present invention, and 0.02 to 0.02%. 0.05 mass% is more preferable.

  The liquid skin external preparation of the present invention is not particularly limited, but moisturizers, bactericides, higher alcohols, lower alcohols other than ethanol, surfactants other than component D (amphoteric surfactants, etc.), fats and oils, hydrocarbon oils, Waxes, higher fatty acids, fatty acid ester oils, sterols, viscosity modifiers, pH adjusters, inorganic pigments, dyes, antioxidants, UV absorbers, vitamins, astringents, whitening agents, animal and plant extracts, sequestering metal ions An agent or the like may be included as an optional component.

  The liquid skin external preparation of this invention can be manufactured by a conventional method. For example, the product of the present invention can be produced by adding a powder component to a container charged with a liquid component and stirring at room temperature.

  Although pH of the liquid skin external preparation of this invention is not specifically limited, From a viewpoint of the influence on a human body, 3.0-8.0 are preferable at 25 degreeC, for example, More preferably, it is 4.0-7.0. Adjustment of pH of the liquid skin external preparation of this invention can be implemented by adding an acid or an alkali suitably.

  Although it does not specifically limit as liquid skin external preparation of this invention, For example, skin external preparations which give a refreshing feeling to the applied skin, such as refreshing cosmetics; External preparations; antiperspirant skin external preparations; fragrance skin external preparations; bactericidal skin external preparations; washing skin external preparations; sunscreen skin external preparations and the like. Especially, the skin external preparation which gives a refreshing feeling is preferable. In addition, the liquid skin external preparation of this invention may be any of cosmetics, quasi drugs, pharmaceuticals, and miscellaneous goods, for example.

  The liquid skin external preparation of the present invention is used by applying to the skin. Although it does not specifically limit as an application site | part of the liquid skin external preparation of this invention, For example, a face, a body, a head (scalp) etc. are mentioned. Of these, the face is preferable. That is, the liquid skin external preparation of the present invention is preferably a facial skin external preparation.

  The liquid skin external preparation of the present invention is preferably a lotion, for example. Moreover, it can also be used as a sheet cosmetic by impregnating the liquid skin external preparation of this invention which is a skin lotion into sheet base materials, such as a nonwoven fabric. Furthermore, the liquid skin external preparation of the present invention, which is a skin lotion, can also be used as a mist cosmetic used by filling a spray container (aerosol type or non-aerosol type) and spraying it in a mist form. That is, the liquid skin external preparation of the present invention is not particularly limited, but can be used in a dosage form such as lotion, mist, sheet (paper), and the like.

  When the liquid skin external preparation of the present invention is used as a product, the container for filling the liquid skin external preparation of the present invention is not particularly limited. For example, a hinge bottle, a screw bottle, (aerosol type or non-aerosol type) A spray container, a pump container, etc. are mentioned.

  The present invention is a liquid skin external preparation containing nylon powder (component A) in a medium of water (component E). Since the liquid skin external preparation of this invention is liquid, there is little stickiness and a refreshing feeling of use is obtained. In addition, Component A can give a smooth feel to the skin after application. Furthermore, when applying to a face etc., the effect which suppresses the glare by sebum with the component A can be exhibited.

  The liquid skin external preparation of this invention contains a nonionic surfactant (component D) further. This improves the ability of the liquid skin external preparation of the present invention to solubilize components that are hardly soluble in water such as fragrances and refreshing agents, so that various components are incorporated into the liquid skin external preparation of the present invention. The degree of freedom increases. Furthermore, even when the liquid skin external preparation of the present invention is stored for a long time, the solubilized component does not precipitate, which is preferable.

  On the other hand, in the composition comprising Component A, Component D, and Component E, the inventor has improved the dispersibility of Component A by Component D. It was presumed that this was due to the fact that the sedimentation layer of component A was caking strongly. In the present invention, component B and component C are added to eliminate the caking problem. By blending these, it is presumed that the aggregate of component A and component B is formed, but caking of the sedimented layer is effectively suppressed. In addition, it is presumed that the formation of the aggregates is insufficient only with Component A and Component B without adding Component C, but the caking inhibiting effect cannot be obtained.

  Here, in the composition containing the above components A to E, the present inventors, after shaking the composition, in addition to the powder sedimentation layer and the water layer, the powder suspended above the water layer It was found that the phenomenon of separation into three layers occurs. Although the details are unknown, it is presumed that the foam generated when shaking is stabilized by the component D, and the component A and the component B adhere to the foam and float. When the powder floats in a layered manner in this way, the appearance as a liquid external preparation for skin is poor and the commercial value is lowered, which is a problem.

  Therefore, as a result of further intensive studies, the present inventor has solved the above three-layer separation problem when the component A and the component B are limited to a specific blending ratio, and the settled layer and the water layer even after shaking. The present invention was completed by finding that a liquid external preparation for skin having a good appearance can be obtained.

  Thereby, the liquid skin external preparation of this invention exhibits a favorable external appearance at the time of use, while having the outstanding usability | use_condition and the outstanding solubilization ability.

  Hereinafter, the present invention will be described in more detail based on examples and the like, but the present invention is not limited only to such examples.

Examples 1 to 9 and Comparative Examples 1 to 8 [Preparation of liquid skin external preparation]
A liquid external preparation for skin having the composition described in Table 1 was prepared by stirring and mixing with a disper mixer and subjected to the following evaluation. The viscosities at 25 ° C. of the liquid external preparations of the examples were all in the range of 1 to 200 mPa · s. Moreover, pH of the liquid skin external preparation of an Example was all within the range of 4.0-7.0.

Evaluation of liquid skin external preparations The liquid skin external preparations prepared in each Example and each Comparative Example were evaluated as follows.

<Caking deterrence>
The liquid skin external preparation (about 100 ml) prepared in each example and each comparative example was placed in a cylinder container [Nessler tube, Sansho Co., Ltd., Nessler colorimetric tube (100 ml), outer diameter × length: φ30 × 250 (Unit: mm)]. The cylinder container was left to stand for 1 week, and then shaken at a shaking width of 100 mm and a shaking speed of 100 mm / second, and the dispersion of the powder (dispersion of the powder forming the sedimented layer) was visually confirmed. The caking inhibitory property was evaluated according to the following criteria.
A (very good): The sedimentation layer is completely dispersed by shaking 10 times or less.
○ (Good): The sedimentation layer is completely dispersed by the soaking 11 to 20 times.
X (defect): The sedimentation layer is not completely dispersed even after 20 reciprocations.

<Appearance (with or without three-layer separation)>
The liquid external preparation for skin (about 100 ml) prepared in each example and each comparative example was filled into a transparent cylindrical container (capacity 120 ml). The container was sufficiently shaken and then left standing. The appearance of the contents of the container 30 minutes after the start of standing was visually confirmed. The appearance (existence of three-layer separation) was evaluated according to the following criteria.
A (very good): No floating powder layer is observed, and no three-layer separation is observed.
○ (Good): A slight powder layer is observed.
X (defect): A layer of floating powder is clearly seen, and three-layer separation is clearly seen.

<Usage>
The liquid skin external preparation (about 1 ml) prepared in each Example and each Comparative Example was applied to the face of a specialized panelist, and the smooth feeling after application was evaluated according to the following criteria. The evaluation test was carried out by five professional panelists in a room at a temperature of 23 ° C. and a relative humidity of 60%.
A (very good): An excellent smooth feeling can be obtained by touching with a hand after drying.
○ (Good): A dry feeling can be obtained by touching with a hand after drying.
X (defect): Touching with a hand after drying, a feeling of smoothness is not obtained, or an unpleasant squeaky feeling is felt.

  The results are shown in Table 1 below.

  Details of each raw material of each example, each comparative example, and the following prescription examples are as follows. In addition, the amount described in the table is not the amount of merchandise but the amount of each component (amount of active ingredient).

Nylon powder (product name: Ganzpearl GPA-550, nylon 12, average particle size: 4.0-6.0 μm, manufactured by Aika Kogyo Co., Ltd.)
Bentonite (manufactured by Nippon Organoclay Co., Ltd., trade name: Bengel)
Laponite (manufactured by Rockwood Additives, trade name: Laponite XL21)
PCA zinc (Ajinomoto Co., Inc., trade name: AJIDEW ZN-100)
Polyoxyethylene polyoxypropylene decyl tetradecyl ether (manufactured by Nippon Surfactant Kogyo Co., Ltd., trade name: PEN-4630)
Menthol (Takasago International Corporation, trade name: Mentor JP COS)

  From the comparison of each Example and Comparative Example 1, it can be seen that the usability is good when the content of Component A is 0.5% by mass or more in the liquid skin external preparation of the present invention. In addition, the feeling of use of Comparative Example 1 was such that a smooth feeling was not obtained.

  From the comparison of each Example and Comparative Example 2, it can be seen that the usability is good when the content of Component A is 5.0% by mass or less in the liquid skin external preparation of the present invention. In addition, the usability of Comparative Example 2 was unpleasant squeaky.

  From the comparison of each Example and Comparative Examples 2, 3, 7, and 8, it can be seen that when both the component B and the component C are included in the liquid skin external preparation of the present invention, caking is suppressed.

  From the comparison of each Example and Comparative Example 4, it can be seen that when component A / component B is 100 or less, caking is suppressed.

  From the comparison of each Example and Comparative Examples 5 and 6, it can be seen that the three-layer separation can be suppressed when the content of Component B is 0.4% by mass or less in the liquid skin external preparation of the present invention.

  Furthermore, the formulation example of the liquid skin external preparation of this invention is shown below.

Formulation Example 1: Cool cosmetic (lotion)
Ethanol 25.0% by mass
Glycerin 4.0% by mass
1,3-butylene glycol 3.0% by mass
Polyoxyethylene polyoxypropylene decyl tetradecyl ether
0.3% by mass
Xanthan gum 0.05% by mass
PCA zinc 1.0% by mass
Nylon powder 2.0% by mass
Bentonite 0.2% by mass
Fragrance 0.2% by mass
Menthol 0.2% by mass
Hamamelis extract 0.1% by mass
Aloe extract (2) 0.1% by mass
Citric acid 0.02% by mass
Sodium citrate 0.1% by mass
Metal sequestering agent Appropriate amount Preservative Appropriate amount Purified water balance Total 100.0% by mass

Formulation Example 2: Acne (for sterilization) cosmetic (skin lotion)
Ethanol 15.0% by mass
Glycerin 4.0% by mass
1,3-butylene glycol 3.0% by mass
Polyoxyethylene polyoxypropylene decyl tetradecyl ether
0.3% by mass
PCA zinc 1.0% by mass
Nylon powder 2.0% by mass
Bentonite 0.2% by mass
Fragrance 0.2% by mass
Menthol 0.05% by mass
Isopropyl methylphenol 0.1% by mass
Salicylic acid 0.1% by mass
Dipotassium glycyrrhizinate 0.1% by mass
Citric acid 0.02% by mass
Sodium citrate 0.1% by mass
Metal sequestering agent Appropriate amount Preservative Appropriate amount Purified water balance Total 100.0% by mass

Formulation Example 3: Whitening Cosmetic (Lotion)
Ethanol 10.0% by mass
Glycerin 4.0% by mass
1,3-butylene glycol 3.0% by mass
Polyoxyethylene polyoxypropylene decyl tetradecyl ether
0.5% by mass
Xanthan gum 0.05% by mass
Sodium chloride 0.2% by mass
Nylon powder 2.0% by mass
Bentonite 0.2% by mass
Silica anhydride 0.8% by mass
Fragrance 0.2% by mass
L-ascorbic acid 2-glucoside 2.0 mass%
Dipotassium glycyrrhizinate 0.1% by mass
Citric acid 0.02% by mass
Sodium citrate 0.1% by mass
Metal sequestering agent Appropriate amount Preservative Appropriate amount Purified water balance Total 100.0% by mass

Formulation Example 4: Whitening Cosmetic (Lotion)
Ethanol 10.0% by mass
Glycerin 4.0% by mass
1,3-butylene glycol 3.0% by mass
Polyoxyethylene polyoxypropylene decyl tetradecyl ether
0.5% by mass
Xanthan gum 0.05% by mass
Sodium chloride 0.2% by mass
Nylon powder 2.0% by mass
Bentonite 0.2% by mass
Silica anhydride 0.8% by mass
Fragrance 0.2% by mass
Tranexamic acid 2.0% by mass
Dipotassium glycyrrhizinate 0.1% by mass
Citric acid 0.02% by mass
Sodium citrate 0.1% by mass
Metal sequestering agent Appropriate amount Preservative Appropriate amount Purified water balance Total 100.0% by mass

Formulation Example 5: Body Cool Cosmetic (Mist)
Ethanol 40.0% by mass
1,3-butylene glycol 3.0% by mass
Polyoxyethylene polyoxypropylene decyl tetradecyl ether
0.2% by mass
Zinc paraphenolsulfonate 0.3% by mass
Nylon powder 2.0% by mass
Bentonite 0.2% by mass
Silica anhydride 2.0% by mass
Cross-linked polystyrene 1.0% by mass
Fragrance 0.2% by mass
Isopropyl methylphenol 0.1% by mass
Menthol 2.0% by mass
Menthyl glyceryl ether 0.3% by mass
Kanfa 0.1% by mass
1,8-cineole 0.1% by mass
Borneol 0.1% by mass
Carboxyvinyl polymer 0.01% by mass
Potassium hydroxide appropriate amount Metal sequestering agent appropriate amount Purified water balance 100.0% by mass
The composition is filled in a non-aerosol type spray container to obtain a mist cosmetic.

  The liquid skin external preparation of this invention can be used as a lotion, for example.

Claims (3)

Component A: nylon powder, component B: bentonite and / or laponite, component C: organic salt and / or inorganic salt, component D: nonionic surfactant, and component E: water,
The content of component A is 0.5 to 5.0% by mass,
The content of component B is 0.4% by mass or less,
The content of component C is 0.1 to 3.0% by mass,
Liquid skin external preparation whose mass ratio [(content of said component A) / (content of said component B)] of content of said component A with respect to content of said component B is 100 or less.   The liquid skin external preparation of Claim 1 whose content of the said component D is 0.01-5.0 mass%. The liquid skin external preparation of Claim 1 or 2 which is a skin lotion.