JPS6471850A - Sulfoxide derivative and production thereof - Google Patents

Sulfoxide derivative and production thereof

Info

Publication number
JPS6471850A
JPS6471850A JP22872787A JP22872787A JPS6471850A JP S6471850 A JPS6471850 A JP S6471850A JP 22872787 A JP22872787 A JP 22872787A JP 22872787 A JP22872787 A JP 22872787A JP S6471850 A JPS6471850 A JP S6471850A
Authority
JP
Japan
Prior art keywords
compound
formula
react
optically active
derivative
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP22872787A
Other languages
Japanese (ja)
Other versions
JPH0558628B2 (en
Inventor
Seiichi Takano
Kuniro Ogasawara
Masafumi Yanase
Michiyasu Takahashi
Naoya Kasai
Kazuhiko Sakaguchi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Osaka Soda Co Ltd
Original Assignee
Daiso Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Daiso Co Ltd filed Critical Daiso Co Ltd
Priority to JP22872787A priority Critical patent/JPS6471850A/en
Publication of JPS6471850A publication Critical patent/JPS6471850A/en
Publication of JPH0558628B2 publication Critical patent/JPH0558628B2/ja
Granted legal-status Critical Current

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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

NEW MATERIAL:The compound of formula I (R<1> and R<2> are H, 1-22C alkyl, alkenyl or aralkyl; pH is phenyl). USE:A synthetic intermediate for pharmaceuticals, agricultural chemicals, other physiologically active substances, ferroelectric liquid crystal material, etc. Since the compound has especially high optical purity, it is excellent as a production raw material for high-purity optically active substance. PREPARATION:An optically active epichlorohydrin of formula II is made to react with a hydrogen nucleophilic compound or a carbon nucleophilic compound and the obtained compound of formula III is made to react with thiophenol to obtain a sulfide derivative of formula IV. The reaction is carried out in a solvent such as THF at -78--30 deg.C. The produced derivative is oxidized with an oxidation agent (e.g. peracid) to obtain the objective compound of formula I (R<2> is H).
JP22872787A 1987-09-11 1987-09-11 Sulfoxide derivative and production thereof Granted JPS6471850A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP22872787A JPS6471850A (en) 1987-09-11 1987-09-11 Sulfoxide derivative and production thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP22872787A JPS6471850A (en) 1987-09-11 1987-09-11 Sulfoxide derivative and production thereof

Publications (2)

Publication Number Publication Date
JPS6471850A true JPS6471850A (en) 1989-03-16
JPH0558628B2 JPH0558628B2 (en) 1993-08-27

Family

ID=16880863

Family Applications (1)

Application Number Title Priority Date Filing Date
JP22872787A Granted JPS6471850A (en) 1987-09-11 1987-09-11 Sulfoxide derivative and production thereof

Country Status (1)

Country Link
JP (1) JPS6471850A (en)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5746975A (en) * 1980-09-04 1982-03-17 Sanwa Chem:Kk Preparation of alpha- or beta-substituted -deltaalpha,beta-or deltabeta-,gamma-butenolide

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5746975A (en) * 1980-09-04 1982-03-17 Sanwa Chem:Kk Preparation of alpha- or beta-substituted -deltaalpha,beta-or deltabeta-,gamma-butenolide

Also Published As

Publication number Publication date
JPH0558628B2 (en) 1993-08-27

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Legal Events

Date Code Title Description
LAPS Cancellation because of no payment of annual fees