JPS6471849A - Sulfide derivative and production thereof - Google Patents

Sulfide derivative and production thereof

Info

Publication number
JPS6471849A
JPS6471849A JP62228726A JP22872687A JPS6471849A JP S6471849 A JPS6471849 A JP S6471849A JP 62228726 A JP62228726 A JP 62228726A JP 22872687 A JP22872687 A JP 22872687A JP S6471849 A JPS6471849 A JP S6471849A
Authority
JP
Japan
Prior art keywords
compound
formula
thiophenol
reacting
nucleophilic compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP62228726A
Other languages
Japanese (ja)
Other versions
JPH0548222B2 (en
Inventor
Seiichi Takano
Kuniro Ogasawara
Masafumi Yanase
Michiyasu Takahashi
Naoya Kasai
Kazuhiko Sakaguchi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Osaka Soda Co Ltd
Original Assignee
Daiso Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Daiso Co Ltd filed Critical Daiso Co Ltd
Priority to JP62228726A priority Critical patent/JPS6471849A/en
Publication of JPS6471849A publication Critical patent/JPS6471849A/en
Publication of JPH0548222B2 publication Critical patent/JPH0548222B2/ja
Granted legal-status Critical Current

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

NEW MATERIAL:The compound of formula I (R<1> is H, 1-22C alkyl, alkenyl or aralkyl; pH is phenyl). EXAMPLE:(R)-(-)-6-methyl-2-hydroxy-5-heptylphenyl sulfide. USE:A synthetic intermediate for pharmaceuticals, agricultural chemicals, other physiologically active substances, ferroelectric liquid crystal material, etc. Since the compound has especially high optical purity, it is excellent as a production raw material for high-purity optically active substance. PREPARATION:The objective compound of formula I can be produced by reacting an optically active epichlorohydrin of formula II with a hydrogen nucleophilic compound or a carbon nucleophilic compound (e.g. metal hydride) and reacting the obtained compound of formula III with thiophenol. The amount of the hydrogen nucleophilic compound or the carbon nucleophilic compound is 1.5-10 equivalent and that of thiophenol is 1-2 equivalent based on the compound of formula II. The reaction is carried out at -78--30 deg.C.
JP62228726A 1987-09-11 1987-09-11 Sulfide derivative and production thereof Granted JPS6471849A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP62228726A JPS6471849A (en) 1987-09-11 1987-09-11 Sulfide derivative and production thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP62228726A JPS6471849A (en) 1987-09-11 1987-09-11 Sulfide derivative and production thereof

Publications (2)

Publication Number Publication Date
JPS6471849A true JPS6471849A (en) 1989-03-16
JPH0548222B2 JPH0548222B2 (en) 1993-07-20

Family

ID=16880849

Family Applications (1)

Application Number Title Priority Date Filing Date
JP62228726A Granted JPS6471849A (en) 1987-09-11 1987-09-11 Sulfide derivative and production thereof

Country Status (1)

Country Link
JP (1) JPS6471849A (en)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5746975A (en) * 1980-09-04 1982-03-17 Sanwa Chem:Kk Preparation of alpha- or beta-substituted -deltaalpha,beta-or deltabeta-,gamma-butenolide

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5746975A (en) * 1980-09-04 1982-03-17 Sanwa Chem:Kk Preparation of alpha- or beta-substituted -deltaalpha,beta-or deltabeta-,gamma-butenolide

Also Published As

Publication number Publication date
JPH0548222B2 (en) 1993-07-20

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Legal Events

Date Code Title Description
LAPS Cancellation because of no payment of annual fees