JPS646235A - 3-hydroxy-2,4,5-trifluorobenzoic acid - Google Patents
3-hydroxy-2,4,5-trifluorobenzoic acidInfo
- Publication number
- JPS646235A JPS646235A JP15971287A JP15971287A JPS646235A JP S646235 A JPS646235 A JP S646235A JP 15971287 A JP15971287 A JP 15971287A JP 15971287 A JP15971287 A JP 15971287A JP S646235 A JPS646235 A JP S646235A
- Authority
- JP
- Japan
- Prior art keywords
- acid
- hydroxy
- sulfuric acid
- catalyst
- raw material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
NEW MATERIAL:3-Hydroxy-2,4,5-trifluorobenzoic acid shown by the formula. USE:Useful as a raw material for high polymer materials, drugs and agricultural chemicals. PREPARATION:4-Hydroxy-3,5,6-trifluorophthalic acid is decarboxylated in the presence of a catalyst such as an acid or alkali under heating to give a compound shown by the formula. When especially sulfuric acid is used as the catalyst, the concentration of sulfuric acid is preferably 50-80wt.% and the amount of sulfuric acid used is preferably 300-700pts.wt. aqueous solution of sulfuric acid based on 100pts.wt. 4-hydroxy-3,5,6-trifluorophthalic acid. When an alkaline substance is used as the catalyst, the amount of the alkali used is preferably 0.01-0.4mol. based on 1mol. of the raw material and the concentration of the preparation is 300-700pts.wt. water based on 100pts.wt. raw material. The reaction is carried out at normal pressure in the case of use of the sulfuric acid and under pressure in the case of use of the alkali.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP62159712A JPH0610159B2 (en) | 1987-06-29 | 1987-06-29 | Process for producing 3-hydroxy-2,4,5-trifluorobenzoic acid |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP62159712A JPH0610159B2 (en) | 1987-06-29 | 1987-06-29 | Process for producing 3-hydroxy-2,4,5-trifluorobenzoic acid |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS646235A true JPS646235A (en) | 1989-01-10 |
JPH0610159B2 JPH0610159B2 (en) | 1994-02-09 |
Family
ID=15699640
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP62159712A Expired - Lifetime JPH0610159B2 (en) | 1987-06-29 | 1987-06-29 | Process for producing 3-hydroxy-2,4,5-trifluorobenzoic acid |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH0610159B2 (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01268662A (en) * | 1988-04-21 | 1989-10-26 | Nippon Carbide Ind Co Inc | Production of 2,4,5-trifluoro-3-hydroxybenzoic acid and production of 2,4,5-trifluoro-3-alkoxybenzoic acid |
US4948249A (en) * | 1987-06-23 | 1990-08-14 | Hopkins Manufacturing Corporation | Headlight aiming and light pattern testing apparatus and method |
US5233082A (en) * | 1982-11-16 | 1993-08-03 | Occidental Chemical Corporation | Method of making 3-hydroxy-2,4,5-trifluorobenzoic acid |
US5380926A (en) * | 1994-03-28 | 1995-01-10 | Occidental Chemical Corporation | Method of making 3-methoxy-2,4,5-trifluorobenzoic acid |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63264440A (en) * | 1986-12-04 | 1988-11-01 | Ube Ind Ltd | 2,4,5-trifluoro-3-hydroxybenzoic acid and production thereof |
-
1987
- 1987-06-29 JP JP62159712A patent/JPH0610159B2/en not_active Expired - Lifetime
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63264440A (en) * | 1986-12-04 | 1988-11-01 | Ube Ind Ltd | 2,4,5-trifluoro-3-hydroxybenzoic acid and production thereof |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5233082A (en) * | 1982-11-16 | 1993-08-03 | Occidental Chemical Corporation | Method of making 3-hydroxy-2,4,5-trifluorobenzoic acid |
US4948249A (en) * | 1987-06-23 | 1990-08-14 | Hopkins Manufacturing Corporation | Headlight aiming and light pattern testing apparatus and method |
JPH01268662A (en) * | 1988-04-21 | 1989-10-26 | Nippon Carbide Ind Co Inc | Production of 2,4,5-trifluoro-3-hydroxybenzoic acid and production of 2,4,5-trifluoro-3-alkoxybenzoic acid |
US5380926A (en) * | 1994-03-28 | 1995-01-10 | Occidental Chemical Corporation | Method of making 3-methoxy-2,4,5-trifluorobenzoic acid |
Also Published As
Publication number | Publication date |
---|---|
JPH0610159B2 (en) | 1994-02-09 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EXPY | Cancellation because of completion of term | ||
FPAY | Renewal fee payment (prs date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20080209 Year of fee payment: 14 |