JPS643960A - Molten carbonate fuel cell - Google Patents

Molten carbonate fuel cell

Info

Publication number
JPS643960A
JPS643960A JP62157749A JP15774987A JPS643960A JP S643960 A JPS643960 A JP S643960A JP 62157749 A JP62157749 A JP 62157749A JP 15774987 A JP15774987 A JP 15774987A JP S643960 A JPS643960 A JP S643960A
Authority
JP
Japan
Prior art keywords
iron
electrode
deterioration
less
chromium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP62157749A
Other languages
Japanese (ja)
Other versions
JPH0550103B2 (en
Inventor
Takatoshi Yoshioka
Hiroshi Fukui
Kiyoshi Hiyama
Takehiko Yoshida
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hitachi Ltd
Original Assignee
Hitachi Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Ltd filed Critical Hitachi Ltd
Priority to JP62157749A priority Critical patent/JPS643960A/en
Publication of JPS643960A publication Critical patent/JPS643960A/en
Publication of JPH0550103B2 publication Critical patent/JPH0550103B2/ja
Granted legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90Selection of catalytic material
    • H01M4/9016Oxides, hydroxides or oxygenated metallic salts
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8605Porous electrodes
    • H01M4/8621Porous electrodes containing only metallic or ceramic material, e.g. made by sintering or sputtering
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/02Details
    • H01M8/0202Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0204Non-porous and characterised by the material
    • H01M8/0206Metals or alloys
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M2004/8678Inert electrodes with catalytic activity, e.g. for fuel cells characterised by the polarity
    • H01M2004/8689Positive electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/14Fuel cells with fused electrolytes
    • H01M2008/147Fuel cells with molten carbonates
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0017Non-aqueous electrolytes
    • H01M2300/0048Molten electrolytes used at high temperature
    • H01M2300/0051Carbonates
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/02Details
    • H01M8/0202Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0204Non-porous and characterised by the material
    • H01M8/0206Metals or alloys
    • H01M8/0208Alloys
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Inert Electrodes (AREA)

Abstract

PURPOSE:To prevent deterioration in catalytic activity of a cathode and deterioration in cell performance by specifying the composition of a nickel-chromium alloy comprising chromium, iron, silicon, manganese, and carbon. CONSTITUTION:An electrode reinforcement is made of a nickel-chromium alloy comprising 15-25wt.% chromium, 0.5wt.% or less iron, 3.0wt.% or less silicon, 2.5wt.% or less manganese, 0.15wt.% or less carbon, and the balance nickel. Even if the electrode reinforcement is brought into contact with molten carbonate at 550-850 deg.C and exposed to an oxidizing gas atmosphere, iron is little eluded from the electrode reinforcement because it contains only 0.5wt.% of iron. Iron oxide does not clog the pores of a cathode made of porous ceramic and does not cover the surface of the electrode. Deterioration in catalytic activity of the electrode and deterioration in cell performance can be prevented.
JP62157749A 1987-06-26 1987-06-26 Molten carbonate fuel cell Granted JPS643960A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP62157749A JPS643960A (en) 1987-06-26 1987-06-26 Molten carbonate fuel cell

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP62157749A JPS643960A (en) 1987-06-26 1987-06-26 Molten carbonate fuel cell

Publications (2)

Publication Number Publication Date
JPS643960A true JPS643960A (en) 1989-01-09
JPH0550103B2 JPH0550103B2 (en) 1993-07-28

Family

ID=15656507

Family Applications (1)

Application Number Title Priority Date Filing Date
JP62157749A Granted JPS643960A (en) 1987-06-26 1987-06-26 Molten carbonate fuel cell

Country Status (1)

Country Link
JP (1) JPS643960A (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4945260Y1 (en) * 1970-02-02 1974-12-11
JPS60190654U (en) * 1984-05-29 1985-12-17 株式会社 共和 wrapping string

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4945260Y1 (en) * 1970-02-02 1974-12-11
JPS60190654U (en) * 1984-05-29 1985-12-17 株式会社 共和 wrapping string

Also Published As

Publication number Publication date
JPH0550103B2 (en) 1993-07-28

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Legal Events

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