JPS6419057A - Allyl(1-propenyl) disulfide and production thereof - Google Patents
Allyl(1-propenyl) disulfide and production thereofInfo
- Publication number
- JPS6419057A JPS6419057A JP62174007A JP17400787A JPS6419057A JP S6419057 A JPS6419057 A JP S6419057A JP 62174007 A JP62174007 A JP 62174007A JP 17400787 A JP17400787 A JP 17400787A JP S6419057 A JPS6419057 A JP S6419057A
- Authority
- JP
- Japan
- Prior art keywords
- formula
- halogenating agent
- allyl
- methyl
- expressed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/55—Design of synthesis routes, e.g. reducing the use of auxiliary or protecting groups
Abstract
NEW MATERIAL:A compound expressed by formula I (X and Y are H or methyl; Y is methyl when X is H and X is methyl when Y is H). EXAMPLE:Allyl(trans 1-propenyl) disulfide. USE:A garlic component useful as a spice, folk, medicine, etc. PREPARATION:A 1-propenethiol derivative expressed by formula II (A is thiol- protecting group eliminating by a halogenating agent) is reacted with an allyl mercaptan derivative expressed by formula III in the presence of a halogenating agent in a solvent, such as THF, at 0-100 deg.C for 30-180min to afford the aimed compound expressed by formula I. The halogenating agent is used in an amount of 1-3 equiv. based on the compound expressed by formula II and the excessive halogenating agent is removed by treating with a reducing agent, such as sodium sulfite, after completing the reaction.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP62174007A JPS6419057A (en) | 1987-07-14 | 1987-07-14 | Allyl(1-propenyl) disulfide and production thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP62174007A JPS6419057A (en) | 1987-07-14 | 1987-07-14 | Allyl(1-propenyl) disulfide and production thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS6419057A true JPS6419057A (en) | 1989-01-23 |
Family
ID=15971013
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP62174007A Pending JPS6419057A (en) | 1987-07-14 | 1987-07-14 | Allyl(1-propenyl) disulfide and production thereof |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6419057A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5011975A (en) * | 1988-03-04 | 1991-04-30 | Nippon Miktron Limited | Novel (trans 1-propenyl)disulfide derivative and process for preparing the same |
EP0464521A2 (en) * | 1990-06-22 | 1992-01-08 | Wakunaga Seiyaku Kabushiki Kaisha | Polysulfide compounds and lipid peroxidation inhibitor containing the polysulfide compounds as active ingredient |
US5231114A (en) * | 1990-06-22 | 1993-07-27 | Wakunaga Seiyaku Kabushiki Kaisha | Polysulfides compounds and lipid peroxidation inhibitor containing the polysulfide compounds as active ingredient |
-
1987
- 1987-07-14 JP JP62174007A patent/JPS6419057A/en active Pending
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5011975A (en) * | 1988-03-04 | 1991-04-30 | Nippon Miktron Limited | Novel (trans 1-propenyl)disulfide derivative and process for preparing the same |
EP0464521A2 (en) * | 1990-06-22 | 1992-01-08 | Wakunaga Seiyaku Kabushiki Kaisha | Polysulfide compounds and lipid peroxidation inhibitor containing the polysulfide compounds as active ingredient |
US5231114A (en) * | 1990-06-22 | 1993-07-27 | Wakunaga Seiyaku Kabushiki Kaisha | Polysulfides compounds and lipid peroxidation inhibitor containing the polysulfide compounds as active ingredient |
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