JPS5481253A - 2-methyl-2-hydroxyperhydrotriquinacene - Google Patents

2-methyl-2-hydroxyperhydrotriquinacene

Info

Publication number
JPS5481253A
JPS5481253A JP14962177A JP14962177A JPS5481253A JP S5481253 A JPS5481253 A JP S5481253A JP 14962177 A JP14962177 A JP 14962177A JP 14962177 A JP14962177 A JP 14962177A JP S5481253 A JPS5481253 A JP S5481253A
Authority
JP
Japan
Prior art keywords
formula
compound
hydroxyperhydrotriquinacene
methyl
methyladamantane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP14962177A
Other languages
Japanese (ja)
Inventor
Yoshiaki Inamoto
Yoshiaki Fujikura
Naotake Takaishi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kao Corp
Original Assignee
Kao Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kao Corp filed Critical Kao Corp
Priority to JP14962177A priority Critical patent/JPS5481253A/en
Publication of JPS5481253A publication Critical patent/JPS5481253A/en
Pending legal-status Critical Current

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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

NEW MATERIAL:2-Methyl-2-hydroxyperhydrotriquinacene of formula I.
USE: An intermediate for synthesis of 1-methyladamantane.
PROCESS: Perhydrotriquinacene-2-one of formula II is reacted with a methylmagnesium halide or methyllithium in an ether solvent, and hydrolyzed to give the compound of formula I, which is reacted with sulfuric acid to form a compound of formula III. The compound of formula III is rearranged with a Lewis acid to form 1-methyladamantane of formula IV.
COPYRIGHT: (C)1979,JPO&Japio
JP14962177A 1977-12-12 1977-12-12 2-methyl-2-hydroxyperhydrotriquinacene Pending JPS5481253A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP14962177A JPS5481253A (en) 1977-12-12 1977-12-12 2-methyl-2-hydroxyperhydrotriquinacene

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP14962177A JPS5481253A (en) 1977-12-12 1977-12-12 2-methyl-2-hydroxyperhydrotriquinacene

Publications (1)

Publication Number Publication Date
JPS5481253A true JPS5481253A (en) 1979-06-28

Family

ID=15479211

Family Applications (1)

Application Number Title Priority Date Filing Date
JP14962177A Pending JPS5481253A (en) 1977-12-12 1977-12-12 2-methyl-2-hydroxyperhydrotriquinacene

Country Status (1)

Country Link
JP (1) JPS5481253A (en)

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