JPS5481253A - 2-methyl-2-hydroxyperhydrotriquinacene - Google Patents
2-methyl-2-hydroxyperhydrotriquinaceneInfo
- Publication number
- JPS5481253A JPS5481253A JP14962177A JP14962177A JPS5481253A JP S5481253 A JPS5481253 A JP S5481253A JP 14962177 A JP14962177 A JP 14962177A JP 14962177 A JP14962177 A JP 14962177A JP S5481253 A JPS5481253 A JP S5481253A
- Authority
- JP
- Japan
- Prior art keywords
- formula
- compound
- hydroxyperhydrotriquinacene
- methyl
- methyladamantane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
NEW MATERIAL:2-Methyl-2-hydroxyperhydrotriquinacene of formula I.
USE: An intermediate for synthesis of 1-methyladamantane.
PROCESS: Perhydrotriquinacene-2-one of formula II is reacted with a methylmagnesium halide or methyllithium in an ether solvent, and hydrolyzed to give the compound of formula I, which is reacted with sulfuric acid to form a compound of formula III. The compound of formula III is rearranged with a Lewis acid to form 1-methyladamantane of formula IV.
COPYRIGHT: (C)1979,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP14962177A JPS5481253A (en) | 1977-12-12 | 1977-12-12 | 2-methyl-2-hydroxyperhydrotriquinacene |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP14962177A JPS5481253A (en) | 1977-12-12 | 1977-12-12 | 2-methyl-2-hydroxyperhydrotriquinacene |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS5481253A true JPS5481253A (en) | 1979-06-28 |
Family
ID=15479211
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP14962177A Pending JPS5481253A (en) | 1977-12-12 | 1977-12-12 | 2-methyl-2-hydroxyperhydrotriquinacene |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5481253A (en) |
-
1977
- 1977-12-12 JP JP14962177A patent/JPS5481253A/en active Pending
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