JPS638309A - Bathing agent or cosmetic, dissolved in use and containing clathrate of aromatic essential oil component - Google Patents

Bathing agent or cosmetic, dissolved in use and containing clathrate of aromatic essential oil component

Info

Publication number
JPS638309A
JPS638309A JP15106886A JP15106886A JPS638309A JP S638309 A JPS638309 A JP S638309A JP 15106886 A JP15106886 A JP 15106886A JP 15106886 A JP15106886 A JP 15106886A JP S638309 A JPS638309 A JP S638309A
Authority
JP
Japan
Prior art keywords
cosmetic
essential oil
clathrate
aromatic
dissolved
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP15106886A
Other languages
Japanese (ja)
Inventor
Kohei Hasebe
浩平 長谷部
Yutaka Ando
裕 安藤
Yoshihiro Chikamatsu
義博 近松
Kyoko Hayashi
林 恭子
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ichimaru Pharcos Co Ltd
Original Assignee
Ichimaru Pharcos Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ichimaru Pharcos Co Ltd filed Critical Ichimaru Pharcos Co Ltd
Priority to JP15106886A priority Critical patent/JPS638309A/en
Publication of JPS638309A publication Critical patent/JPS638309A/en
Pending legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73Polysaccharides
    • A61K8/738Cyclodextrins
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/10Washing or bathing preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/56Compounds, absorbed onto or entrapped into a solid carrier, e.g. encapsulated perfumes, inclusion compounds, sustained release forms

Abstract

PURPOSE:The titled bathing agent or cosmetic, obtained by including an aromatic essential oil ingredient having particularly high volatility, e.g. HINOKI essential oil, etc., using a cyclic dextrin and containing the resultant clathrate, having improved stability as well as preservation quality and obtainable as powder without scattering property. CONSTITUTION:A bathing agent or cosmetic obtained by forming a clathrate from a volatile liquid oil prepared by steam distillation of trees, leaves, branches and roots HINOKI (Chamaecyparis obtusa Endl.), Crysptomaeria japonica D. Don, Thujopsis dolabrata Sieb. et Zucc., leaves of HINOKI, etc., or various essential oils and aromatic ingredients isolated from the essential oils as well as other animal or plant-derived natural perfume obtained by steam distillation or volatile synthetic perfume using cyclic dextrin and used for bathing or cosmetic dissolved in use. The above-mentioned clathrate becomes odorless powder and the aromatic ingredients are not volatilized unless dissolved by adding water. Direct tableting thereof can be carried out. USE:Usable also as medicines for internal use.

Description

【発明の詳細な説明】 〔イ〕 発明の目的 本発明は、芳香精油成分を環状デキストリンを用いて包
接し、その包接物を含有してなる、新規な浴用剤又は、
使用時溶解化粧料に関する。
[Detailed Description of the Invention] [A] Object of the Invention The present invention provides a novel bath agent containing an aromatic essential oil component using a cyclic dextrin, or a novel bath agent containing the clathrate;
Concerning cosmetics that dissolve during use.

本発明による芳香精油成分には、例えば、テレピン油を
はじめ、ヒノキ、スギ、アスナロ、ヒバなどの樹木、葉
、枝、根から水蒸気蒸留法によって得られた、揮発性の
液状油をはじめ、その他、次表(第1表)に示すごとく
の各稚の精油及び、それらの精油からsriされた芳香
成分、さらに、他の動・植物由来の、水蒸気蒸留によっ
て得られた、天然香料又は、揮発性のある合成香料が用
いられる。
The aromatic essential oil components according to the present invention include, for example, turpentine oil, volatile liquid oils obtained by steam distillation from trees, leaves, branches, and roots such as cypress, cedar, asunaro, and hiba, and others. , as shown in the following table (Table 1), as well as the aromatic components extracted from these essential oils, as well as natural fragrances obtained by steam distillation or volatile substances derived from other animals and plants. A synthetic fragrance is used.

又、包接に当って用いる環状デキストリンは、α、β、
7型の環状デキストリン、又は、それらの複合物が用い
られる。
In addition, the cyclic dextrin used for inclusion is α, β,
Type 7 cyclic dextrins or complexes thereof are used.

′産業上の利用分野」 本発明によって得られた、芳香精油成分の包接物は、そ
のまま浴用剤として、又、浴用剤の他の処方中に添加し
て、浴用芳香料となして用いることが出来ると共に、使
用時溶解して用いる粉末状又は、顆粒状の化粧料として
、用いることが出来る。
``Industrial Application Fields'' The clathrate of aromatic essential oil components obtained by the present invention can be used as a bath agent as it is, or as a bath fragrance by being added to other formulations of bath agents. In addition, it can be used as a powder or granule cosmetic that is dissolved before use.

1従来の技術。1 Conventional technology.

環状(サイクロ)デキストリンを用いて、各種薬物の包
接物(化合物)となすことは、公知である。又、第1表
中で示きれる、各種の芳香精油成分などを、浴用として
用いることも、すでに公知である。
It is known that cyclic (cyclo)dextrins are used to form clathrates (compounds) of various drugs. It is also already known that the various aromatic essential oil components shown in Table 1 can be used for bathing purposes.

しかし、本発明のごとく、芳香精油成分を環状デキスト
リンを用い包接し、これを浴用剤としであるいは、使用
時に溶解して用いる、化粧料に応用した例は、他に見当
らない。
However, as in the present invention, there has been no other example in which an aromatic essential oil component is clathrated with a cyclic dextrin and applied to a cosmetic product, which is used as a bath additive or dissolved at the time of use.

1発明が解決しようとする問題点」 本発明者らは、浴用剤の開発をテーマとなし。1. The problem that the invention seeks to solve.” The present inventors' theme was the development of bath additives.

湯浴中で、さっと溶解され、気分を爽快にしてくれる、
芳香精油成分の、粉体又は顆粒、あるいは、12m(発
泡錠)への配合について、研究を続けてきた。そして、
例えば、第1表中に示すごとくの精油成分は、製剤化上
、次のごとくの難点があった。すなわち、処方中の賦形
剤(結合剤)に、直接的に配合すれば、その結果は、ど
んどん揮発きれ、芳香成分が製剤化後、発散してしまう
欠点があった。又、揮発成分が賦形剤に滲透し、じみを
形成することなどの欠点があった。
It dissolves quickly in a hot water bath, making you feel refreshed.
We have been conducting research on incorporating aromatic essential oil components into powder, granules, or 12m (effervescent tablets). and,
For example, the essential oil components shown in Table 1 have the following difficulties in formulation. That is, if it is directly added to the excipient (binder) in the formulation, the result is that it volatilizes rapidly, resulting in the fragrance component being released after the formulation. In addition, there were drawbacks such as the volatile components seeping into the excipient and forming a bleed.

したがって、従来は、これらの芳香精油を添加した浴用
剤は、芳香が発散しにくいように、包装を密閉し、外気
との接触を避けることの出来る、包装及び容器に充填す
る方法、あるいは、芳香精油を、一度、他の賦形剤に吸
着させ、これを顆粒化し、又は、錠剤となし、その上に
、芳香成分が発散しないように、被膜剤を用いて、コー
ティングするなどの方法が採用きれていた。
Therefore, conventionally, bath additives containing these aromatic essential oils have been packaged tightly to prevent the fragrance from escaping, and filled into containers that can avoid contact with the outside air. Methods such as adsorbing essential oils onto other excipients, granulating them or forming them into tablets, and then coating them with a coating agent to prevent aromatic components from escaping are adopted. I was exhausted.

又、被膜剤をもとに、芳香精油成分をマイクロカプセル
化する試みもなされてきたが、芳香精油成分は、加温下
で、どんどん揮発する性質があり、各種の有機溶媒にI
i(溶なために、芳香性の精油成分、例えば、第1表中
に示ずごとくの、芳香精油は、それが出来ないでいた。
In addition, attempts have been made to microcapsule aromatic essential oil components using coating agents, but aromatic essential oil components have the property of rapidly evaporating under heating, and are difficult to immerse in various organic solvents.
i (Due to their soluble nature, aromatic essential oil components, such as the aromatic essential oils listed in Table 1, have not been able to do so.

本発明者は、この現状をふまえ、ヒノキ精油など、とく
に揮発性の高い芳香精油を、顆粒や錠剤、粉体の剤形の
浴用剤に、安定に用いることが出来、しかも、浴湯中に
入れた際には、その温水中に、さっと溶解し、それぞれ
の芳香精油本来の芳香が、発散きれるための手段を求め
、その研究開発を続けた結果、本発明の成功に至った。
In view of this current situation, the present inventors have discovered that it is possible to stably use highly volatile aromatic essential oils, such as cypress essential oil, in bath preparations in the form of granules, tablets, and powders, and that they can be added to bath water. We searched for a means to quickly dissolve in the hot water and release the original aroma of each aromatic essential oil, and continued research and development led to the success of the present invention.

〔口〕 発明の構成 本発明は、芳香精油成分を、環状デキストリンを用いて
、その包接物となし、これを浴用となすこと、又は使用
時溶解化粧料となすことにある。
[Mouth] Structure of the Invention The present invention is to prepare an aromatic essential oil component into a clathrate using a cyclic dextrin, and use this as a bath product or as a cosmetic that dissolves when used.

本発明による芳香精油成分は、水蒸気蒸留法によって得
られる、あらゆる動・植物由来の揮発性の天然香料、あ
るいは、揮発性の合成香油(香料)に適用出来る。
The aromatic essential oil component according to the present invention can be applied to any volatile natural fragrance derived from animals or plants or volatile synthetic fragrance oil (fragrance) obtained by steam distillation.

1実施例1」 精油成分として、ヒノキ精油(和歌山両度)をもとに、
その1〜10gを、環状デキストリン(α又はβ、又は
、α、β、7の複合物)50gと混和し、水を少低加え
、乳鉢上で、1〜3時間、圧力を加えながら、よく練り
上げた後、減圧下で乾燥して、その包接物を得た。
1 Example 1 Based on cypress essential oil (Wakayama Ryodo) as an essential oil component,
Mix 1 to 10 g of it with 50 g of cyclic dextrin (α or β, or a composite of α, β, and 7), add a little water, and place it in a mortar for 1 to 3 hours while applying pressure. After kneading, the mixture was dried under reduced pressure to obtain the clathrate.

「実施例2」 前表第1表に示す、それぞれの、水蒸気蒸留して得られ
た精油、及び、水蒸気蒸留して得られた、スギの精油を
、各々1〜10gに対して、β−環状デキストリン、又
は、α、β、7の複合状態にある環状デキストリン50
gと混和し、2゜5j!の水を加え、よく攪拌を行ない
、静置し、析出した沈澱物を濾取し、減圧下で乾燥して
、それぞれの包接物を得た。
"Example 2" β- Cyclic dextrin or cyclic dextrin in a complex state of α, β, 7 50
Mix with g, 2゜5j! of water was added thereto, stirred well, allowed to stand, and the precipitate precipitated was collected by filtration and dried under reduced pressure to obtain each clathrate.

上記、1〜2の実施例で得られた包接物は、まったく芳
香を有せず、無臭となる。
The clathrates obtained in Examples 1 and 2 above have no fragrance and are odorless.

又、40°Cの恒温槽下に保存し、それぞれの包接物の
芳香発散性についてみたが、いずれも、はとんど芳香は
発散されず、長期間にわたり安定な状態が保持されてい
る。
In addition, we stored them in a constant temperature bath at 40°C and examined the aroma release properties of each clathrate, but in all cases, the fragrance was hardly released and the state remained stable for a long period of time. .

−H%水中では、い41れも可溶であるが、とくに浴湯
中では、即、溶解4゛ると共に、それぞれ特有の芳香が
発散橿゛るようになる。
-H% All of them are soluble in water, but especially in bath water, they immediately dissolve and emit their respective unique aromas.

水中では、ffi l’l’すること番こより溶解性が
早まる。又、市販の化粧水や乳液中に添加すると、溶解
し、特有の芳香が発散されるようになる。
In water, solubility is faster than ffill'l'. When added to commercially available lotions and emulsions, it dissolves and emits a unique fragrance.

したがって、浴用剤として、そのまま用いても良く、あ
るいは、使用時溶解して用いる化粧料として、粉末状や
顆粒状の形態となしたものに、添加して用いることが出
来るが、例えば、その製剖化例を示すと、次のごとくで
ある。
Therefore, it can be used as it is as a bath agent, or it can be added to a powder or granule form as a cosmetic that is dissolved before use. An example of autopsy is as follows.

r参考処方例−1」 実施例1又は2で得られた精油のいずれかの包接物適量
を、既存の顆粒となした浴用剤の処方中に添加し、浴用
剤となし用いる。
rReference Formulation Example-1 An appropriate amount of the clathrate of either the essential oil obtained in Example 1 or 2 is added to the existing granulated bath preparation formulation and used as a bath preparation.

(配合に当っての目安:浴用顆粒) 硫酸ナトリウム45〜48%、炭酸水素ナトリウム39
〜42%、ホウ砂2%、色素(黄色4号)少量、実施例
1又は2で得られた包接物の1種、又は1種以上を1〜
8%。
(Guideline for formulation: Bath granules) Sodium sulfate 45-48%, Sodium hydrogen carbonate 39%
~42%, 2% borax, a small amount of pigment (yellow No. 4), one or more clathrates obtained in Example 1 or 2.
8%.

「参考処方例−2」 実施例1又は2で得られた精油のいずれかの包接物適量
を、他の浴用側成分と混和し、粉末とするか、あるいは
、他の浴用剤の成分と混和し、顆粒となし、打錠機にか
けて、浴用剤(錠)となして用いる。
"Reference Formulation Example-2" An appropriate amount of the clathrate of either the essential oil obtained in Example 1 or 2 is mixed with other bath ingredients to form a powder, or mixed with other bath ingredients. Mix, make granules, press into a tablet machine, and use as bath preparations (tablets).

(配合に当っての目安:発泡性浴用錠)硫酸ナトリウム
29%、炭酸水素ナトリウム20%、フハク酸33%、
炭酸ナトリウム13%、色素(黄色4号)又は、ガデニ
ールイエロ−(−丸ファルコス(株)製:クチナシエキ
ス)適量、実施例1又は2に準拠して得られた芳香精油
成分を含むエキスの包接物1〜5%。
(Guideline for formulation: effervescent bath tablets) 29% sodium sulfate, 20% sodium bicarbonate, 33% succinic acid,
13% sodium carbonate, a suitable amount of pigment (yellow No. 4) or gardenia yellow (manufactured by Maru Falcos Co., Ltd.: gardenia extract), an extract containing aromatic essential oil components obtained according to Example 1 or 2. Inclusions 1-5%.

「参考処方例−3」 オリザノール50%含有脱脂米糠中に、実施例1又は2
で得られた包接物の1種を適量添加し、浴用糠袋として
用いる。
"Reference Formulation Example-3" Example 1 or 2 was added to defatted rice bran containing 50% oryzanol.
An appropriate amount of one of the clathrates obtained in step 1 is added and used as a bran bag for bathing.

「参考処方例−4」 ビタミンC又は、その誘導体あるいは、その他、水中で
不安定な化粧品配合成分を含有する、使用時溶解して用
いる粉末タイプの化粧料の処Jj中に、実施例1又は2
にNA拠して得られた、ヒノキ又はスギの精油の包接物
を適量加えて混合し、PPT包装あるいは、ヒートシー
ルなどの分包機にかけて分包し、使用時溶解化粧料とな
して用いる。
"Reference Formulation Example-4" Example 1 or 2
An appropriate amount of clathrates of cypress or cedar essential oil obtained based on NA is added and mixed, and the mixture is packaged using PPT packaging or a packaging machine such as a heat seal, and used as a dissolving cosmetic at the time of use.

「参考処方例−5゜ ヒノキ又はスギの精油、その他、第1表中で示す精油を
、環状デキストリンで包接された粉末について、粉末、
顆粒、錠剤、カプセルの形態で用いられる、口臭防止剤
の処方中、あるいは、口中清涼剤の処方中に、適量を添
加して、口臭又は口中用剤を製して用いる。
"Reference Prescription Example - 5゜Hinoki or Japanese cedar essential oil and other essential oils shown in Table 1 are included in powder with cyclic dextrin.
An appropriate amount is added to the formulation of a halitosis prevention agent or a mouth freshener used in the form of granules, tablets, or capsules to prepare a halitosis or mouth freshener.

〔ハ〕 発明の効果 本発明による、芳香精油成分を、環状デキストリンによ
って製した、包接物は、無臭な粉体となり、水を加えて
、溶解しない限り、芳香成分は発散されないことが特徴
である。
[C] Effects of the Invention The clathrate of the present invention, in which the aromatic essential oil component is made from cyclic dextrin, is characterized in that it becomes an odorless powder and the aromatic component is not released unless water is added to dissolve it. be.

したがって、このものは、乾燥状態で、開封しておいて
も、従来の芳香精油のごとく、空気中に、芳香を発散し
、蒸発してしまうことがないこと、つまり、安定性、保
存性が良いこと、さらに、粉体としてえられ、しかも飛
散性がなく、直接、打錠することも可能であるなどの利
点がある。よって、粉末、顆粒、錠剤などの形態の浴用
剤中には、大変、優れたメリットがある。
Therefore, even if the package is opened in a dry state, this product does not emit fragrance into the air and evaporate like traditional aromatic essential oils, which means that it has good stability and shelf life. Another advantage is that it can be obtained as a powder, has no scattering properties, and can be directly compressed into tablets. Therefore, bath preparations in the form of powders, granules, tablets, etc. have very good advantages.

一方、本発明によれば、例えば参考処方例−5のごとく
、内服用医薬品などにおいて、これらの芳香精油が、処
方中に用いられることが多いので、その安定化にも役立
ち、しかも内服後、日中で、良好な芳香を発散させるこ
とが出来るなど、その用途は大きなものがある。
On the other hand, according to the present invention, as shown in Reference Prescription Example 5, these aromatic essential oils are often used in the prescription of internal medicines, so they are useful for stabilizing them, and furthermore, after internal administration, It has many uses, including being able to emit a pleasant fragrance during the day.

次表(第2表)は、その効果について示したものである
The following table (Table 2) shows the effects.

Claims (1)

【特許請求の範囲】[Claims] (1) 芳香精油成分を、環状デキストリンを用いて包接して、
その包接物を含有することを特徴とする浴用剤又は、使
用時溶解化粧料。
(1) Including aromatic essential oil components using cyclic dextrin,
A bath agent or a cosmetic that dissolves during use, characterized by containing the clathrate.
JP15106886A 1986-06-26 1986-06-26 Bathing agent or cosmetic, dissolved in use and containing clathrate of aromatic essential oil component Pending JPS638309A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP15106886A JPS638309A (en) 1986-06-26 1986-06-26 Bathing agent or cosmetic, dissolved in use and containing clathrate of aromatic essential oil component

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP15106886A JPS638309A (en) 1986-06-26 1986-06-26 Bathing agent or cosmetic, dissolved in use and containing clathrate of aromatic essential oil component

Publications (1)

Publication Number Publication Date
JPS638309A true JPS638309A (en) 1988-01-14

Family

ID=15510603

Family Applications (1)

Application Number Title Priority Date Filing Date
JP15106886A Pending JPS638309A (en) 1986-06-26 1986-06-26 Bathing agent or cosmetic, dissolved in use and containing clathrate of aromatic essential oil component

Country Status (1)

Country Link
JP (1) JPS638309A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03172397A (en) * 1989-11-30 1991-07-25 Sunstar Inc Cleanser composition
JPH0474107A (en) * 1990-05-15 1992-03-09 Sunstar Inc Cosmetic composition
KR19990083666A (en) * 1999-02-24 1999-12-06 오윤명 Extract method of essential oil having the effect of antimicrobial, antifungal extracted from chamaecyparis obtusa.
US7879824B2 (en) 2001-07-31 2011-02-01 Dermal Research Laboratories, Inc. Methods of preventing or treating diseases and conditions using complex carbohydrates
US8003782B1 (en) * 1999-02-01 2011-08-23 Dermal Research Laboratories, Inc. Pharmaceutical composition of complex carbohydrates and essential oils and methods of using the same
JP2016108330A (en) * 2014-12-01 2016-06-20 関西酵素株式会社 Bath agent

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03172397A (en) * 1989-11-30 1991-07-25 Sunstar Inc Cleanser composition
JPH0474107A (en) * 1990-05-15 1992-03-09 Sunstar Inc Cosmetic composition
US8003782B1 (en) * 1999-02-01 2011-08-23 Dermal Research Laboratories, Inc. Pharmaceutical composition of complex carbohydrates and essential oils and methods of using the same
US9220290B2 (en) 1999-02-01 2015-12-29 Dermal Research Laboratories, Inc. Pharmaceutical composition of complex carbohydrates and essential oils and methods of using the same
KR19990083666A (en) * 1999-02-24 1999-12-06 오윤명 Extract method of essential oil having the effect of antimicrobial, antifungal extracted from chamaecyparis obtusa.
US8367642B2 (en) 2000-07-31 2013-02-05 Dermal Research Laboratories, Inc. Methods of preventing or treating diseases and conditions using complex carbohydrates
US7879824B2 (en) 2001-07-31 2011-02-01 Dermal Research Laboratories, Inc. Methods of preventing or treating diseases and conditions using complex carbohydrates
JP2016108330A (en) * 2014-12-01 2016-06-20 関西酵素株式会社 Bath agent

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