JP2016108330A - Bath agent - Google Patents
Bath agent Download PDFInfo
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- JP2016108330A JP2016108330A JP2015232459A JP2015232459A JP2016108330A JP 2016108330 A JP2016108330 A JP 2016108330A JP 2015232459 A JP2015232459 A JP 2015232459A JP 2015232459 A JP2015232459 A JP 2015232459A JP 2016108330 A JP2016108330 A JP 2016108330A
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- fragrance
- bath agent
- scent
- cyclodextrin
- container
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- 239000013040 bath agent Substances 0.000 title claims abstract description 30
- 239000000203 mixture Substances 0.000 claims abstract description 21
- 229920000858 Cyclodextrin Polymers 0.000 claims abstract description 18
- 239000001116 FEMA 4028 Substances 0.000 claims abstract description 14
- WHGYBXFWUBPSRW-FOUAGVGXSA-N beta-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO WHGYBXFWUBPSRW-FOUAGVGXSA-N 0.000 claims abstract description 14
- 235000011175 beta-cyclodextrine Nutrition 0.000 claims abstract description 14
- 229960004853 betadex Drugs 0.000 claims abstract description 14
- 239000000378 calcium silicate Substances 0.000 claims abstract description 13
- 229910052918 calcium silicate Inorganic materials 0.000 claims abstract description 13
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000003205 fragrance Substances 0.000 claims description 42
- 239000000463 material Substances 0.000 claims description 17
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Natural products CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 claims description 10
- 229930003658 monoterpene Natural products 0.000 claims description 7
- 150000002773 monoterpene derivatives Chemical class 0.000 claims description 7
- 235000002577 monoterpenes Nutrition 0.000 claims description 7
- -1 silicic acid compound Chemical class 0.000 claims description 7
- 235000001510 limonene Nutrition 0.000 claims description 6
- 229940087305 limonene Drugs 0.000 claims description 6
- 239000002304 perfume Substances 0.000 claims description 4
- 235000012239 silicon dioxide Nutrition 0.000 claims description 4
- 239000004793 Polystyrene Substances 0.000 claims description 3
- 229920002223 polystyrene Polymers 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 125000000396 limonene group Chemical group 0.000 claims description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims 1
- 239000000796 flavoring agent Substances 0.000 abstract description 9
- 235000019634 flavors Nutrition 0.000 abstract description 9
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 abstract description 8
- 235000017557 sodium bicarbonate Nutrition 0.000 abstract description 4
- 229910000030 sodium bicarbonate Inorganic materials 0.000 abstract description 4
- 241000207199 Citrus Species 0.000 abstract description 3
- 235000020971 citrus fruits Nutrition 0.000 abstract description 3
- 230000000052 comparative effect Effects 0.000 description 21
- 229920006300 shrink film Polymers 0.000 description 19
- 238000003287 bathing Methods 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- 238000012790 confirmation Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 230000001953 sensory effect Effects 0.000 description 3
- 235000002639 sodium chloride Nutrition 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 229940037003 alum Drugs 0.000 description 1
- 235000001014 amino acid Nutrition 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 230000017531 blood circulation Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 235000010216 calcium carbonate Nutrition 0.000 description 1
- 235000012241 calcium silicate Nutrition 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 239000012611 container material Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 150000002337 glycosamines Chemical class 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000003230 hygroscopic agent Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229910000031 sodium sesquicarbonate Inorganic materials 0.000 description 1
- 235000018341 sodium sesquicarbonate Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- WCTAGTRAWPDFQO-UHFFFAOYSA-K trisodium;hydrogen carbonate;carbonate Chemical compound [Na+].[Na+].[Na+].OC([O-])=O.[O-]C([O-])=O WCTAGTRAWPDFQO-UHFFFAOYSA-K 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
本発明は入浴剤に関する。詳しくは、香りを充分に保持し、安定した品質を有する入浴剤に係るものである。 The present invention relates to a bath agent. Specifically, the present invention relates to a bath agent that sufficiently retains fragrance and has stable quality.
血行促進や温浴効果を得る、または、家庭でも手軽に温泉気分を味わう目的などから、浴槽中の湯に投入して用いられる種々の入浴剤が存在する。また、入浴剤に配合された香料によって、リラックス効果や使用感が高められたものとなっている。 There are various bathing agents that are used by putting them in hot water in a bathtub for the purpose of promoting blood circulation and warm bathing, or for enjoying a hot spring feeling easily at home. Moreover, the fragrance | flavor mix | blended with the bath agent has become the relaxation effect and the usability | use_condition increased.
使用者が浴湯中でも香りが感じられるように、化粧品等の製品と比べ、入浴剤に配合される香料は配合割合が多いことが特徴である。一般的な香料の配合割合は、例えば化粧水では重量比率で０〜０．１％程度であるのに対し、入浴剤では０〜３％の範囲で配合される。 The fragrance | flavor mix | blended with a bath agent is the characteristics that there are many compounding ratios compared with products, such as cosmetics, so that a user may sense fragrance also in bath water. The blending ratio of a general fragrance is, for example, about 0 to 0.1% by weight in the case of lotion, but in the range of 0 to 3% in the case of a bath agent.
また、浴湯中に香料を速やかに拡散させて、香り立ちを良好にすることを試みた入浴剤が存在し、例えば、特許文献１に記載の入浴剤が提案されている。 Further, there are bathing agents that attempt to quickly diffuse the fragrance into the bath water to improve the fragrance, and for example, the bathing agent described in Patent Document 1 has been proposed.
しかしながら、入浴剤において、厳密に密封された容器を使用した場合を除き、経時的に香りが漏れ出していく現象が発生する。この結果、充填当初に比べ、使用時の香調が著しく低下し、製品の品質を損なうおそれがあるものとなっている。 However, except for the case where a strictly sealed container is used in a bath agent, a phenomenon in which a fragrance leaks over time occurs. As a result, compared to the beginning of filling, the fragrance tone during use is remarkably lowered, and the quality of the product may be impaired.
また、香料成分は一般的に分子量が小さく、容器の材質によっては包材を透過して香り漏れが生じることもある。入浴剤から漏れた香りが、隣接する他の製剤に移ってしまう香り移りが発生する問題もあった。更に、香料成分が容器の成分を溶解し、変形させてしまう不具合も存在している。 Moreover, the fragrance | flavor component generally has a small molecular weight, and depending on the material of the container, the fragrance leakage may occur through the packaging material. There was also a problem that the scent that leaked from the bathing agent was transferred to another adjacent preparation. Further, there is a problem that the fragrance component dissolves and deforms the components of the container.
一方、厳密に密封された容器を使用した際には、内部が陰圧となり、気圧変化によって容器が変形してしまう問題があった。 On the other hand, when a strictly sealed container is used, there is a problem that the inside becomes a negative pressure and the container is deformed by a change in atmospheric pressure.
本発明は、以上の点に鑑みて創案されたものであり、香りを充分に保持し、安定した品質を有する入浴剤を提供することを目的とする。 The present invention has been made in view of the above points, and an object of the present invention is to provide a bath agent that sufficiently retains fragrance and has stable quality.
上記の目的を達成するために、本発明の入浴剤は、少なくともモノテルペンを含む香料と、β−シクロデキストリンと、ケイ酸化合物とを含有する混合組成物から構成されている。 In order to achieve the above object, the bath agent of the present invention is composed of a mixed composition containing a fragrance containing at least a monoterpene, β-cyclodextrin, and a silicic acid compound.
ここで、β−シクロデキストリン及びケイ酸化合物によって、香料を吸着して保持しやすいものとなる。 Here, it becomes easy to adsorb | suck and hold | maintain a fragrance | flavor by (beta) -cyclodextrin and a silicic acid compound.
また、モノテルペンがリモネンである場合には、リモネンによる容器成分の溶解や変形を生じにくくさせることができる。例えば、容器がポリスチレンで形成された際には、リモネンで溶解されることがあるが、これを混合組成物に保持させることで、溶解が生じないものとなる。 Further, when the monoterpene is limonene, it is possible to make it difficult for the limonene to dissolve or deform the container components. For example, when the container is formed of polystyrene, it may be dissolved with limonene, but by holding this in the mixed composition, dissolution does not occur.
また、ケイ酸化合物が、ケイ酸カルシウムである場合には、より一層、香料を吸着して保持しやすいものとなる。 Further, when the silicate compound is calcium silicate, the fragrance is more easily adsorbed and held.
また、β−シクロデキストリンが、含有量が入浴剤の全量基準で重量比率が１〜５％である場合には、より一層充分に香料を吸着して保持しやすいものとなる。 In addition, when the content of β-cyclodextrin is 1 to 5% based on the total amount of the bath agent, the perfume is more easily adsorbed and retained.
一方、β−シクロデキストリンの含有量が全量基準の重量比率で１％未満である場合には、香料の吸着が不充分となり、香り漏れが生じるものとなる。また、β−シクロデキストリンの含有量が全量基準の重量比率で５％を超える場合には、製剤の粉体流動性が高くなり、充填時に粉舞いが生じて、取扱いに不便なものとなる。 On the other hand, when the content of β-cyclodextrin is less than 1% in terms of the weight ratio based on the total amount, adsorption of the fragrance becomes insufficient, and fragrance leakage occurs. On the other hand, when the content of β-cyclodextrin exceeds 5% in terms of the weight ratio based on the total amount, the powder fluidity of the preparation becomes high and powdering occurs at the time of filling, which is inconvenient to handle.
また、混合組成物がポリスチレンを含む素材で形成された容器に収容される場合には、モノテルペンによる容器の溶解や変形が生じにくいものとなる。 Further, when the mixed composition is contained in a container formed of a material containing polystyrene, the container is hardly dissolved or deformed by monoterpene.
また、上記の目的を達成するために、本発明の入浴剤は、無機塩類と、少なくともモノテルペンを含む香料と、β−シクロデキストリンと、ケイ酸カルシウムとを含有する混合組成物から構成されている。 In order to achieve the above object, the bath agent of the present invention is composed of a mixed composition containing inorganic salts, a fragrance containing at least a monoterpene, β-cyclodextrin, and calcium silicate. Yes.
ここで、β−シクロデキストリン及びケイ酸カルシウムによって、香料を吸着して保持しやすいものとなる。 Here, it becomes easy to adsorb | suck and hold | maintain a fragrance | flavor with (beta) -cyclodextrin and calcium silicate.
また、上記の目的を達成するために、本発明の入浴剤は、香料と、β−シクロデキストリンと、ケイ酸カルシウムとを含有する混合組成物から構成されている。 Moreover, in order to achieve said objective, the bath agent of this invention is comprised from the mixed composition containing a fragrance | flavor, (beta) -cyclodextrin, and a calcium silicate.
ここで、β−シクロデキストリン及びケイ酸カルシウムによって、香料を吸着して保持しやすいものとなる。 Here, it becomes easy to adsorb | suck and hold | maintain a fragrance | flavor with (beta) -cyclodextrin and calcium silicate.
本発明に係る入浴剤は、香りを充分に保持し、安定した品質を有するものとなっている。 The bath agent according to the present invention sufficiently retains the fragrance and has a stable quality.
以下、本発明を適用した入浴剤の一例の組成について説明する。 Hereinafter, the composition of an example of a bath agent to which the present invention is applied will be described.
ここで示す入浴剤は、全量基準で重量比率が、炭酸水素ナトリウム：９３．５％、β−シクロデキストリン：５．０％、香料（柑橘系）：１．０％、ケイ酸カルシウム：０．５％を含む組成を有している。 The bathing agent shown here has weight ratios based on the total amount of sodium bicarbonate: 93.5%, β-cyclodextrin: 5.0%, fragrance (citrus): 1.0%, calcium silicate: 0.00. It has a composition containing 5%.
炭酸水素ナトリウムは、入浴剤の主成分であり、皮膚の汚れを乳化し、清浄効果を有するものである。上記の組成では９３．５％配合されている。 Sodium hydrogen carbonate is a main component of the bath agent and emulsifies skin dirt and has a cleaning effect. In the above composition, 93.5% is blended.
β−シクロデキストリンは、香料を保持する基剤であり、上記の組成では５．０％配合されている。 β-cyclodextrin is a base that holds a fragrance, and is 5.0% in the above composition.
香料（柑橘系）は入浴剤を賦香するものであり、リモネンを含むものとなっている。上記の組成では１．０％配合されている。 The fragrance (citrus) perfumes the bath agent and contains limonene. In the above composition, 1.0% is blended.
ケイ酸カルシウムは、入浴剤の粉体流動性を調整し、かつ、水分を吸収する吸湿剤としても作用する。上記の組成では０．５％配合されている。 Calcium silicate adjusts the powder fluidity of the bath agent and also acts as a hygroscopic agent that absorbs moisture. In the above composition, 0.5% is blended.
ここで、入浴剤の主成分は炭酸水素ナトリウムに限定されるものではない。例えば、無機塩類である硫酸ナトリウム、硫酸マグネシウム、炭酸ナトリウム、セスキ炭酸ナトリウム、炭酸カルシウム、塩化ナトリウム、塩化カリウム、アミノ酸と糖、ミョウバン等を主成分とするものであってもよい。また、その剤型も限定されず粉末や顆粒、結晶状であってもよい。 Here, the main component of the bath agent is not limited to sodium bicarbonate. For example, inorganic salts such as sodium sulfate, magnesium sulfate, sodium carbonate, sodium sesquicarbonate, calcium carbonate, sodium chloride, potassium chloride, amino acids and sugar, alum and the like may be used as main components. Moreover, the dosage form is not limited and may be powder, granule, or crystal.
また、β−シクロデキストリンの全量基準の重量比率が５．０％に限定される必要はない。但し、香料を充分に吸着させ、香りを保持可能にする点から、β−シクロデキストリンは、全量基準の重量比率で１．０〜５．０％の範囲で配合されることが好ましい。 Further, the weight ratio based on the total amount of β-cyclodextrin is not necessarily limited to 5.0%. However, it is preferable that β-cyclodextrin is blended in the range of 1.0 to 5.0% in terms of the weight ratio based on the total amount from the viewpoint that the fragrance can be sufficiently adsorbed and the fragrance can be maintained.
また、必ずしも、ケイ酸カルシウムの全量基準の重量比率が０．５％に限定される必要はない。 Further, the weight ratio based on the total amount of calcium silicate is not necessarily limited to 0.5%.
上記で説明した本発明を適用した入浴剤の一例は、香りを充分に保持し、香り漏れや香り移りが生じにくい組成となっている。また、充填した容器の変形が生じにくいものとなっている。 An example of the bathing agent to which the present invention described above is applied has a composition that sufficiently retains fragrance and does not easily cause fragrance leakage or fragrance transfer. Further, deformation of the filled container is difficult to occur.
以上のとおり、本発明を適用した入浴剤は、香りを充分に保持し、安定した品質を有するものとなっている。 As described above, the bath agent to which the present invention is applied has a sufficient scent and a stable quality.
以下、本発明の実施例を説明する。 Examples of the present invention will be described below.
本発明を適用した入浴剤の実施例及び比較例の試料を作製し、以下の評価を行った。
（１）試料の化学成分
まず、表１〜表１０に示す組成となるように原料成分を添加して、実施例１〜４０及び比較例１〜１２の各試料を作製した。香料はリモネンが含有されたものである。なお、以下表１〜表１０に示す数値は、原料の全量を基準にした重量比率（％）を示したものである。
The sample of the example and comparative example of the bath agent to which this invention was applied was produced, and the following evaluation was performed.
(1) Chemical component of sample First, the raw material component was added so that it might become a composition shown in Table 1-Table 10, and each sample of Examples 1-40 and Comparative Examples 1-12 was produced. The fragrance contains limonene. In addition, the numerical value shown below in Table 1-Table 10 shows the weight ratio (%) on the basis of the whole quantity of a raw material.
（２）香り漏れ及び香り移りの確認
各試料８３５ｇを８８０ｇ容量の円筒形のポリエチレン製ボトル（φ８．５ｃｍ×２１．５ｃｍ、ポリエステル製シュリンクフィルム巻き付け済）に充填し、容器及びろ紙を同じアルミ袋（約４０ｃｍ×２０ｃｍ）に密封し、５０℃で７２時間保管した。保管後、アルミ袋を開封し、各試料を密封したアルミ袋の袋内の香りの強さを官能試験にて評価し、香り漏れの確認を行った。また、アルミ袋に同封したろ紙を取りだし、開放状態で１０分間静置した後、香りの強さを官能試験にて評価し、香り移りの確認を行った。官能試験は以下に示す評価基準で点数を付け、１０名の平均値から算出した。
１）非常に強い香りを感じる（５点）
２）香りを感じる（４点）。
３）弱い香りを感じる（３点）。
４）僅かに香りを感じる（２点）。
５）ほとんど香りを感じない（１点）。
６）香りを感じない（０点）。
(2) Confirmation of fragrance leakage and fragrance transfer 835 g of each sample is filled into a cylindrical polyethylene bottle (φ8.5 cm × 21.5 cm, polyester shrink film already wrapped) having a capacity of 880 g, and the container and filter paper are packed in the same aluminum bag. Sealed (about 40 cm × 20 cm) and stored at 50 ° C. for 72 hours. After storage, the aluminum bag was opened, the strength of the scent in the bag of the aluminum bag sealed with each sample was evaluated by a sensory test, and scent leakage was confirmed. Moreover, the filter paper enclosed in the aluminum bag was taken out and left still for 10 minutes in an open state, and then the strength of the scent was evaluated by a sensory test, and the scent transfer was confirmed. The sensory test was scored according to the evaluation criteria shown below and calculated from the average value of 10 people.
1) Feel a very strong scent (5 points)
2) Feel the scent (4 points).
3) I feel a weak scent (3 points).
4) Slight scent (2 points).
5) Almost no scent (1 point).
6) No scent (0 points).
（３）資材の変形の確認
前述した香り漏れ及び香り移りの確認の保管後の容器について、容器資材への影響を観察した。シュリンクフィルムの破損がほとんど見られないもの（表１〜１０では○で記載）、シュリンクフィルムの破損が生じたもの（表１〜１０では△で記載）、シュリンクフィルムの破損が顕著なもの（表１〜１０では×で記載）と判断した。
なお、図１は資材の変形の確認に用いた容器及びシュリンクフィルムの前後を示す写真である。また、図２は比較例１、図３は比較例２、図４は比較例４、図５は実施例４、図６は実施例８、図７は実施例１２、図８は比較例５、図９は実施例１６、図１０は比較例６に該当し、その容器及びシュリンクフィルムの前後を示す写真である。なお、参考までに、図１に相当するカラー写真を参考図１及び参考図２に、図２に相当するカラー写真を参考図３及び参考図４に、図３に相当するカラー写真を参考図５及び参考図６に、図４に相当するカラー写真を参考図７及び参考図８に、図５に相当するカラー写真を参考図９及び参考図１０に、図６に相当するカラー写真を参考図１１及び参考図１２に図７に相当するカラー写真を参考図１３及び参考図１４に、図８に相当するカラー写真を参考図１５及び参考図１６に、図９に相当するカラー写真を参考図１７及び参考図１８に、図１０に相当するカラー写真を参考図１９及び参考図２０に掲載する。
(3) Confirmation of material deformation The container after storage of the above-described confirmation of scent leakage and scent transfer was observed for the effect on the container material. Those in which the shrinkage of the shrink film is hardly seen (indicated by a circle in Tables 1 to 10), those in which the shrinkage of the shrink film occurred (indicated by a triangle in Tables 1 to 10), and those in which the shrinkage of the shrink film is remarkable (table 1 to 10).
FIG. 1 is a photograph showing the front and back of the container and the shrink film used for confirming the deformation of the material. 2 is Comparative Example 1, FIG. 3 is Comparative Example 2, FIG. 4 is Comparative Example 4, FIG. 5 is Example 4, FIG. 6 is Example 8, FIG. 7 is Example 12, and FIG. FIG. 9 corresponds to Example 16 and FIG. 10 corresponds to Comparative Example 6, and is a photograph showing the container and the shrink film before and after. For reference, the color photograph corresponding to FIG. 1 is shown in Reference FIGS. 1 and 2, the color photograph corresponding to FIG. 2 is shown in Reference FIGS. 3 and 4, and the color photograph corresponding to FIG. 5 and Reference FIG. 6, the color photograph corresponding to FIG. 4 is referred to in Reference FIGS. 7 and 8, the color photograph corresponding to FIG. 5 is referred to in Reference Figures 9 and 10, and the color photograph corresponding to FIG. 11 and FIG. 12 refer to the color photograph corresponding to FIG. 7 in the reference FIG. 13 and reference FIG. 14, refer to the color photograph corresponding to FIG. 8 in the reference FIG. 15 and reference FIG. In FIG. 17 and Reference FIG. 18, color photographs corresponding to FIG. 10 are shown in Reference FIG. 19 and Reference FIG.
表１は、実施例１〜４及び比較例１〜４の試料における香り漏れ、香り移り及び資材の変形を示した結果である。表２は、実施例５〜８の試料における香り漏れ、香り移り及び資材の変形を示した結果である。表３は、実施例９〜１２及び比較例５の試料における香り漏れ、香り移り及び資材の変形を示した結果である。表４は、実施例１３〜１６及び比較例６の試料における香り漏れ、香り移り及び資材の変形を示した結果である。表５は、実施例１７〜２０及び比較例７の試料における香り漏れ、香り移り及び資材の変形を示した結果である。表６は、実施例２１〜２４及び比較例８の試料における香り漏れ、香り移り及び資材の変形を示した結果である。表７は、実施例２５〜２８及び比較例９の試料における香り漏れ、香り移り及び資材の変形を示した結果である。表８は、実施例２９〜３２及び比較例１０の試料における香り漏れ、香り移り及び資材の変形を示した結果である。表９は、実施例３３〜３６及び比較例１１の試料における香り漏れ、香り移り及び資材の変形を示した結果である。表１０は、実施例３７〜４０及び比較例１２の試料における香り漏れ、香り移り及び資材の変形を示した結果である。 Table 1 shows the results of scent leakage, scent transfer, and material deformation in the samples of Examples 1 to 4 and Comparative Examples 1 to 4. Table 2 shows the results of scent leakage, scent transfer, and material deformation in the samples of Examples 5 to 8. Table 3 shows the results of scent leakage, scent transfer, and material deformation in the samples of Examples 9 to 12 and Comparative Example 5. Table 4 shows the results of scent leakage, scent transfer, and material deformation in the samples of Examples 13 to 16 and Comparative Example 6. Table 5 shows the results of scent leakage, scent transfer, and material deformation in the samples of Examples 17 to 20 and Comparative Example 7. Table 6 shows the results of scent leakage, scent transfer, and material deformation in the samples of Examples 21 to 24 and Comparative Example 8. Table 7 shows the results of scent leakage, scent transfer, and material deformation in the samples of Examples 25 to 28 and Comparative Example 9. Table 8 shows the results of fragrance leakage, fragrance transfer, and material deformation in the samples of Examples 29 to 32 and Comparative Example 10. Table 9 shows the results of scent leakage, scent transfer, and material deformation in the samples of Examples 33 to 36 and Comparative Example 11. Table 10 shows the results of scent leakage, scent transfer, and material deformation in the samples of Examples 37 to 40 and Comparative Example 12.
実施例２〜４、６〜８、１０〜１２、１４〜１６、１８〜２０、２２〜２４、２６〜２８、３０〜３２、３４〜３６、３８〜４０では、ほとんど香りを感じない、または香りを感じない程度の香り漏れ及び香り移りであることが確認された。また、シュリンクフィルムの破損がほとんど見られない程度の資材の変形であった。 In Examples 2-4, 6-8, 10-12, 14-16, 18-20, 22-24, 26-28, 30-32, 34-36, 38-40, almost no scent, or It was confirmed that the fragrance leaked and the fragrance transferred to such an extent that the fragrance was not felt. Further, the deformation of the material was such that the shrinkage of the shrink film was hardly observed.
実施例１、５、９、１３、１７、２１、２５、２９、３３及び３７では、僅かな香りを感じる程度の香り漏れであり、ほとんど香りを感じない程度または僅かな香りを感じる程度の香り移りであった。また、シュリンクフィルムの破損が生じていた。 In Examples 1, 5, 9, 13, 17, 21, 25, 29, 33, and 37, the fragrance leaks to the extent that it feels a slight scent, and the scent that feels little or no fragrance. It was a transition. Further, the shrink film was damaged.
比較例１〜１２では、各実施例よりも強い香り漏れ及び香り移りが確認され、シュリンクフィルムの破損が顕著な程の資材の変形が生じていた。 In Comparative Examples 1 to 12, a stronger scent leakage and scent transfer were confirmed than in each of the examples, and the material was deformed so that the shrinkage of the shrink film was remarkable.
Claims (8)
β−シクロデキストリンと、
ケイ酸化合物とを含有する混合組成物から構成された入浴剤。 A perfume containing at least a monoterpene,
β-cyclodextrin;
The bath agent comprised from the mixed composition containing a silicic acid compound.
請求項１に記載の入浴剤。 The bath agent according to claim 1, wherein the monoterpene is limonene.
請求項１または請求項２に記載の入浴剤。 The bath agent according to claim 1 or 2, wherein the silicate compound is calcium silicate or anhydrous silicic acid.
請求項１または請求項２に記載の入浴剤。 The bath agent according to claim 1 or 2, wherein the silicate compound is calcium silicate.
請求項１、請求項２、請求項３または請求項４に記載の入浴剤。 The bath agent according to claim 1, 2, 3, or 4, wherein the β-cyclodextrin has a weight ratio of 1 to 5% based on the total amount of the bath agent.
請求項１、請求項２、請求項３、請求項４または請求項５に記載の入浴剤。 The bath composition according to claim 1, claim 2, claim 3, claim 4, or claim 5, wherein the mixed composition is contained in a container formed of a material containing polystyrene.
少なくともモノテルペンを含む香料と、
β−シクロデキストリンと、
ケイ酸カルシウムとを含有する混合組成物から構成された入浴剤。 Inorganic salts,
A perfume containing at least a monoterpene,
β-cyclodextrin;
The bath agent comprised from the mixed composition containing a calcium silicate.
β−シクロデキストリンと、
ケイ酸カルシウムとを含有する混合組成物から構成された入浴剤。 Fragrance,
β-cyclodextrin;
The bath agent comprised from the mixed composition containing a calcium silicate.
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| US20200170901A1 (en) * | 2018-12-04 | 2020-06-04 | Henkel Ag & Co. Kgaa | Deodorant cosmetic compositions comprising calcium silicate and sodium bicarbonate |
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