JPS637378B2 - - Google Patents
Info
- Publication number
- JPS637378B2 JPS637378B2 JP55005605A JP560580A JPS637378B2 JP S637378 B2 JPS637378 B2 JP S637378B2 JP 55005605 A JP55005605 A JP 55005605A JP 560580 A JP560580 A JP 560580A JP S637378 B2 JPS637378 B2 JP S637378B2
- Authority
- JP
- Japan
- Prior art keywords
- silver
- layer
- dye
- image
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000463 material Substances 0.000 claims description 94
- 229910052709 silver Inorganic materials 0.000 claims description 65
- 239000004332 silver Substances 0.000 claims description 65
- 239000000975 dye Substances 0.000 claims description 53
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 50
- -1 anionic organic compound Chemical class 0.000 claims description 43
- 238000012546 transfer Methods 0.000 claims description 34
- 238000009792 diffusion process Methods 0.000 claims description 27
- 238000011161 development Methods 0.000 claims description 24
- 238000000034 method Methods 0.000 claims description 24
- 150000001875 compounds Chemical class 0.000 claims description 19
- 239000000084 colloidal system Substances 0.000 claims description 9
- 125000000129 anionic group Chemical group 0.000 claims description 8
- 230000008569 process Effects 0.000 claims description 8
- 150000004010 onium ions Chemical class 0.000 claims description 7
- 239000004094 surface-active agent Substances 0.000 claims description 7
- 229920000151 polyglycol Polymers 0.000 claims description 6
- 239000010695 polyglycol Substances 0.000 claims description 6
- 239000000980 acid dye Substances 0.000 claims description 5
- 150000002894 organic compounds Chemical class 0.000 claims description 5
- 239000011347 resin Substances 0.000 claims description 5
- 229920005989 resin Polymers 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 125000002091 cationic group Chemical group 0.000 claims description 3
- 150000002170 ethers Chemical class 0.000 claims description 3
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 2
- 229910052946 acanthite Inorganic materials 0.000 claims description 2
- 150000008052 alkyl sulfonates Chemical class 0.000 claims description 2
- 150000001721 carbon Chemical group 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- 150000004665 fatty acids Chemical class 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 235000014593 oils and fats Nutrition 0.000 claims description 2
- XUARKZBEFFVFRG-UHFFFAOYSA-N silver sulfide Chemical compound [S-2].[Ag+].[Ag+] XUARKZBEFFVFRG-UHFFFAOYSA-N 0.000 claims description 2
- 229940056910 silver sulfide Drugs 0.000 claims description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 2
- RZXLPPRPEOUENN-UHFFFAOYSA-N Chlorfenson Chemical compound C1=CC(Cl)=CC=C1OS(=O)(=O)C1=CC=C(Cl)C=C1 RZXLPPRPEOUENN-UHFFFAOYSA-N 0.000 claims 1
- 230000002378 acidificating effect Effects 0.000 claims 1
- 125000005526 alkyl sulfate group Chemical group 0.000 claims 1
- 239000003054 catalyst Substances 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate group Chemical group S(=O)(=O)([O-])[O-] QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 claims 1
- 239000010410 layer Substances 0.000 description 41
- 108010010803 Gelatin Proteins 0.000 description 15
- 229920000159 gelatin Polymers 0.000 description 15
- 239000008273 gelatin Substances 0.000 description 15
- 235000019322 gelatine Nutrition 0.000 description 15
- 235000011852 gelatine desserts Nutrition 0.000 description 15
- 239000000839 emulsion Substances 0.000 description 11
- 238000012545 processing Methods 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 229910021607 Silver chloride Inorganic materials 0.000 description 5
- 239000011230 binding agent Substances 0.000 description 5
- 230000003287 optical effect Effects 0.000 description 5
- 230000009467 reduction Effects 0.000 description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 4
- YYJGVALNTRPFMY-UHFFFAOYSA-N 3,6-dihydroxy-2-octadecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCCCCCCCC1=C(O)C=CC(O)=C1S(O)(=O)=O YYJGVALNTRPFMY-UHFFFAOYSA-N 0.000 description 3
- ZZEYCGJAYIHIAZ-UHFFFAOYSA-N 4-methyl-1-phenylpyrazolidin-3-one Chemical compound N1C(=O)C(C)CN1C1=CC=CC=C1 ZZEYCGJAYIHIAZ-UHFFFAOYSA-N 0.000 description 3
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 3
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 3
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 3
- 239000003945 anionic surfactant Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 3
- 239000011241 protective layer Substances 0.000 description 3
- 230000004044 response Effects 0.000 description 3
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 3
- PGWMQVQLSMAHHO-UHFFFAOYSA-N sulfanylidenesilver Chemical group [Ag]=S PGWMQVQLSMAHHO-UHFFFAOYSA-N 0.000 description 3
- 150000004763 sulfides Chemical class 0.000 description 3
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 229930040373 Paraformaldehyde Natural products 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 235000019445 benzyl alcohol Nutrition 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000008139 complexing agent Substances 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- UXMZNEHSMYESLH-UHFFFAOYSA-M hexadecyl(triphenyl)phosphanium;bromide Chemical compound [Br-].C=1C=CC=CC=1[P+](C=1C=CC=CC=1)(CCCCCCCCCCCCCCCC)C1=CC=CC=C1 UXMZNEHSMYESLH-UHFFFAOYSA-M 0.000 description 2
- 230000002452 interceptive effect Effects 0.000 description 2
- 239000011133 lead Substances 0.000 description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
- AJDUTMFFZHIJEM-UHFFFAOYSA-N n-(9,10-dioxoanthracen-1-yl)-4-[4-[[4-[4-[(9,10-dioxoanthracen-1-yl)carbamoyl]phenyl]phenyl]diazenyl]phenyl]benzamide Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2NC(=O)C(C=C1)=CC=C1C(C=C1)=CC=C1N=NC(C=C1)=CC=C1C(C=C1)=CC=C1C(=O)NC1=CC=CC2=C1C(=O)C1=CC=CC=C1C2=O AJDUTMFFZHIJEM-UHFFFAOYSA-N 0.000 description 2
- 229920002866 paraformaldehyde Polymers 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 150000003346 selenoethers Chemical class 0.000 description 2
- ONVGIJBNBDUBCM-UHFFFAOYSA-N silver;silver Chemical compound [Ag].[Ag+] ONVGIJBNBDUBCM-UHFFFAOYSA-N 0.000 description 2
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- 150000003871 sulfonates Chemical class 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- 239000001043 yellow dye Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- LUMLZKVIXLWTCI-NSCUHMNNSA-N (e)-2,3-dichloro-4-oxobut-2-enoic acid Chemical compound OC(=O)C(\Cl)=C(/Cl)C=O LUMLZKVIXLWTCI-NSCUHMNNSA-N 0.000 description 1
- GGZHVNZHFYCSEV-UHFFFAOYSA-N 1-Phenyl-5-mercaptotetrazole Chemical compound SC1=NN=NN1C1=CC=CC=C1 GGZHVNZHFYCSEV-UHFFFAOYSA-N 0.000 description 1
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- 241001479434 Agfa Species 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 229920001612 Hydroxyethyl starch Polymers 0.000 description 1
- 229920002873 Polyethylenimine Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 241000978776 Senegalia senegal Species 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 239000000783 alginic acid Substances 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 229960001126 alginic acid Drugs 0.000 description 1
- 150000004781 alginic acids Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical group 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 229940037003 alum Drugs 0.000 description 1
- 150000001449 anionic compounds Chemical class 0.000 description 1
- 229920006318 anionic polymer Polymers 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- HGWAKQDTQVDVRP-OKULMJQMSA-N butyl (z,12r)-12-hydroxyoctadec-9-enoate Chemical class CCCCCC[C@@H](O)C\C=C/CCCCCCCC(=O)OCCCC HGWAKQDTQVDVRP-OKULMJQMSA-N 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- JIRRNZWTWJGJCT-UHFFFAOYSA-N carbamothioylthiourea Chemical compound NC(=S)NC(N)=S JIRRNZWTWJGJCT-UHFFFAOYSA-N 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000005137 deposition process Methods 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- OAEGRYMCJYIXQT-UHFFFAOYSA-N dithiooxamide Chemical compound NC(=S)C(N)=S OAEGRYMCJYIXQT-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000008098 formaldehyde solution Substances 0.000 description 1
- 229940015043 glyoxal Drugs 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229940050526 hydroxyethylstarch Drugs 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- ZAKLKBFCSHJIRI-UHFFFAOYSA-N mucochloric acid Natural products OC1OC(=O)C(Cl)=C1Cl ZAKLKBFCSHJIRI-UHFFFAOYSA-N 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical group [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920001467 poly(styrenesulfonates) Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 239000011970 polystyrene sulfonate Substances 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical group 0.000 description 1
- 150000004023 quaternary phosphonium compounds Chemical group 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 230000001568 sexual effect Effects 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- FVEFRICMTUKAML-UHFFFAOYSA-M sodium tetradecyl sulfate Chemical compound [Na+].CCCCC(CC)CCC(CC(C)C)OS([O-])(=O)=O FVEFRICMTUKAML-UHFFFAOYSA-M 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 150000004026 tertiary sulfonium compounds Chemical group 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- YUKQRDCYNOVPGJ-UHFFFAOYSA-N thioacetamide Chemical compound CC(N)=S YUKQRDCYNOVPGJ-UHFFFAOYSA-N 0.000 description 1
- DLFVBJFMPXGRIB-UHFFFAOYSA-N thioacetamide Natural products CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C8/00—Diffusion transfer processes or agents therefor; Photosensitive materials for such processes
- G03C8/42—Structural details
- G03C8/52—Bases or auxiliary layers; Substances therefor
- G03C8/56—Mordant layers
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C8/00—Diffusion transfer processes or agents therefor; Photosensitive materials for such processes
- G03C8/24—Photosensitive materials characterised by the image-receiving section
- G03C8/26—Image-receiving layers
- G03C8/28—Image-receiving layers containing development nuclei or compounds forming such nuclei
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Architecture (AREA)
- Structural Engineering (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
- Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
- Photosensitive Polymer And Photoresist Processing (AREA)
Description
æ¬çºæã¯æ¡æ£è»¢åæ³ã«ããææåããã³é»çœé
åã®è£œé ã«äœ¿çšããã®ã«å¥œé©ãªéæå æ§å容äœæ
æã«é¢ããã ç¹å¥ã«äœãããåçããã²ã³åéä¹³å€ææãçš
ããŠæ¡æ£è»¢åã«ãã€ãŠå€è²åãäœãããšã¯çŸåšå¹Ÿ
ã€ãã®æ¹æ³ã§çšããããŠãããæå æ§ç©è³ªãšããŠ
ããã²ã³åéãçšããŠäœçšãããæææ¡æ£è»¢åæ³
ã¯ãå šãŠåãåçã«åºã¥ããŠãããå³ã¡ããã²ã³
åéã®åã«å¿ããéãžã®éå ã«ãã€ãŠå¶åŸ¡ããã
ææãŸãã¯ææ圢ææ§é éšã®æå床ã®å€åã«åºã¥
ããŠããããããã®æ¹æ³ã¯ãæ¬æ¥ã®å€è²ã®æ¯è²ãŸ
ãã¯è¢«åäœã®å€è²ããªã³ãã圢æãã幟ã€ãã®é
ããããåè²ææåããåãæ§æãããããã€ã³
ã¹ã¿ã³ãã«ã©ãŒããªã³ãã®è£œé ã®ããã®åºæ¬ã§ã
ãã ã°ã©ãã€ãã¯ã¢ãŒãã®åéãäŸãã°ã«ã©ãŒãã«
ãŒãã€ã³ã°ãå°å³è£œå³ããã³æè¡çã€ã©ã¹ãã®å
éã«ãããŠãåè²ææåã«å ããŠãã«ã©ãŒæ å ±ã«
補åãã圢ã§é»è²åãå«æããŠããããªã³ããæ±
ããããŠããã ãã®ãããå容äœææäžã«éåãäœãããšã«åº
ã¥ããæ®éã®é»è²éé¯å¡©æ¡æ£è»¢åæ³ãšçµåããæ
ææ¡æ£è»¢åæ³ã䜿çšãããŠãããé»çœåããã³æ
æåã¯ãæ¡æ£ãããéé¯å¡©ãéã«éå ããããšã
æ¥è§Šäœçšãããããã®çŸåæ žãå«æããåãå容
äœææäžã«æŽåãããŠåœ¢æãããã å容äœææäžã«æ¡æ£ãããææãŸãã¯æ¡æ£ãã
ãææ圢æç©è³ªãã圢æãããææã¯ããããåª
æã«ãã€ãŠã³ãã€ãå±€äžã«æ®éå®çããããææ
æ¡æ£è»¢åæ³ã«ãããŠã¯ã芪氎æ§ã³ãã€ãåªäœäžã§
ã®ææãŸããã¯ææ圢æç©è³ªã®æå床ã¯ããã®æ§
é äžã«ã¢ããªã³æ§åºãååšããããšã«ãã€ãŠæ®é
åŸããããåŸã€ãŠåªæå€ã¯äžè¬ã«ã«ããªã³æ§æ§é
éšãæããååç©ã§ããã é žæ§ææã®ããã®ç¹ã«å¥œé©ãªææåªææ§ååç©
ã«ã¯ãäŸãã°ç±³åœç¹èš±ç¬¬3173786å·ãå第3227550
å·ãå第3271147å·ããã³å第3271148å·æ现æžã«
èšèŒãããŠããåŠãææ©ãªããŠã ååç©ãããã
ãããã«ã¯æ¡æ£é»æ¢æ§åºãäŸãã°å¥œãŸããã¯å°ãª
ããšã12åã®ççŽ ååãæããççŽ éãå«æãã
ã®ã奜ãŸããåçŽã¢ã³ã¢ããŠã ååç©ãäžçŽã¹ã«
ãããŠã ååç©ããã³åçŽãã¹ãããŠã ååç©ã
å«æããã æ¬çºæã®åºç€ãšãªã€ãç 究ããã³å®éšäžã«ãæ
æåã«å ããŠéåã圢æããæ¡æ£è»¢åæ³ã«ãã
ãŠãé žæ§ææã®ããã®åªæå€ãšããŠäœçšãããªã
ãŠã ååç©ããéåã®åœ¢æã«åŠšå®³å¹æãæããã
ãšãåŸã€ãŠçŸåæ žã®ååšäžã«éé¯å¡©ãéå ããã
ãšã«ãã€ãŠåŸãããå åŠå¯åºŠã«åŠšå®³å¹æãæãã
ããšãèŠåºããã ãã®åŠšå®³å¹æã®æ©æ§ã¯è¯ãå€ããªãã®ã§ãã
ããããã¯ãªããŠã ååç©ãé¯å¡©ã®è² ã«åž¯é»ãã
éå«æã€ãªã³ãçŸåæ žã«å°éããã®ãé»æ¢ããã
ããšã®è§Šåªçæ¥è§Šãå°éãããã®ãšæšå®ãããã æ¬çºæã«ããã°ãå åŠå¯åºŠæžå°ã®äžèšåé¡ã¯ã
ææ転åããã³éé¯å¡©æ¡æ£è»¢åæ³ã«äœ¿çšããã®ã«
å¹é©ãªéæå æ§å容äœææãæäŸããããšã«ãã€
ãŠè§£æ±ºãããäžèšææã¯ã (i) æ¯æäœã (ii) é žæ§ææãåªæã§ããææ©ãªããŠã ååç©ã
å«æãã第ïŒææ©èŠªæ°Žæ§ã³ãã€ãå±€ãããã³ (iii) éé¯å¡©ã®éãžã®éå ãæ¥è§Šäœçšãããããã®
çŸåæ žãå«æããéæ第ïŒææ©èŠªæ°Žæ§ã³ãã€ã
å±€ ãå«æããäžèšææã¯ãŸãäžèšå±€(iii)äžã«ããã³ïŒ
ãŸãã¯å±€(ii)ãš(iii)ã®éã®èŠªæ°Žæ§ã³ãã€ãäžéå±€äž
ã«ãææ©ååç©ã®ççŽ ååã«çµåããã¢ããªã³æ§
åºãæããææ©ååç©ïŒä»¥åŸã¢ããªã³æ§ææ©åå
ç©ãšç§°ããïŒã®å°ãªããšãïŒçš®ãå«æããã ã¢ããªã³æ§ææ©ååç©ããªããŠã ååç©ãšåå¿
ããããããŠãªããŠã ååç©ã¯éé¯å¡©ã¢ããªã³ãš
åå¿ããããšããé»æ¢ããããã®ãšä¿¡ããããã ç¹ã«æå¹ãªã¢ããªã³æ§ææ©ååç©ã¯ãã¹ã«ãã
ãŒãåºãŸãã¯ãµã³ããšãŒãåºãå«æããã¢ããªã³
ææ©çé¢æŽ»æ§å€ã§ããã ã¹ã«ãããŒãã®äŸã«ã¯ã¢ã«ãã«ã¹ã«ãããŒãã
ã¢ã«ã«ãªãŒã«ã¹ã«ãããŒããã¢ã«ãã«ããšããŒã«
ããªã°ãªã³ãŒã«ãšãŒãã«ã¹ã«ãããŒãããããã
ã·ã¢ã«ã«ã³ã¹ã«ãããŒããèèªé žã¿ãŠã©ã€ãåå
ç©ããã³ã¹ã«ãã³ãã¯é žãšã¹ãã«ãããã ãµã«ããšãŒãã®äŸã«ã¯äžçŽããã³äºçŽã¢ã«ãã«
ãµã«ããšãŒãããµã«ããšãŒãåããªã°ãªã³ãŒã«ãš
ãŒãã«ããµã«ããšãŒãåã¢ã«ãã«ããšããŒã«ããª
ã°ãªã³ãŒã«ãšãŒãã«ããã³æ²¹ããã³èèªã®ç¡«é žãš
ã¹ãã«ãããã ã¢ããªã³çé¢æŽ»æ§å€ããã³ãã®è£œé ã®ååŠã¯ã¯
ãŒããŒã»ãšã ã»ãªã³ãã€ãŒã«ãè1976幎ããŒã»
ã«ã»ããã«ãŒã»ã€ã³ã³ãŒãã¬ã€ã·ãšã³ïŒããŠãŒãš
ãŒã¯ã»ã¢ã³ãã»ããŒãŒã«ïŒçºè¡ããã¢ããªãã
ã¯ã»ãµãŒãã¢ã¯ã¿ã³ãã第éšã«èšèŒãããŠã
ããç³æ²¹ã¹ã«ãããŒãã«ã€ããŠã¯ç¹ã«ç¬¬330é ã
第335é ãåç §ã®ããšã 奜ãŸããã®ã¯ãã®ååæ§é äžã«ãå°ãªããšã12
åã®ççŽ ååã®éäžæççŽ éãäŸãã°C12ãC18ã®
ïœâã¢ã«ãã«éãæããã¢ããªã³æ§ææ©ååç©ã§
ããããããååç©ã¯çé¢æŽ»æ§å€ãŸãã¯æ¹¿æœ€å€ãš
ããŠæåããã ç¹ã«è¯å¥œãªçµæã¯ã (1) ã¢ãšããŸã«OTïŒAEROSOL OTïŒïŒäžèšæ§é
åŒ ãæããçé¢æŽ»æ§å€ã«å¯Ÿããç±³åœããŠãŒãšãŒã¯
åžã®ã¢ã¡ãªã«ã³ã»ãµã€ã¢ãããã»ã³ã ãããŒã®
åååïŒã (2) ãã¹ã¿ãã³ïŒŽïŒHOSTAPON ïŒïŒäžèšæ§é
åŒ ãæããçé¢æŽ»æ§å€ã«å¯Ÿãã西ãã€ãåœãã©ã³
ã¯ãã«ãåžã®ããã¹ãã»ã¢ãŒã»ã²ãŒã®åååïŒã (3) ã¿ãŒãžããŒã«ïŒïŒTERGITOL4ïŒïŒäžèšæ§é
åŒ ãæããçé¢æŽ»æ§å€ã«å¯Ÿããç±³åœããŠãŒãšãŒã¯
åžã®ãŠããªã³ã»ã«ãŒãã€ãã»ã¢ã³ãã»ã«ãŒãã³
ã®åååïŒã (4) ã¡ã«ãŸã©ãïŒMERSOLAT ïŒãäžèšæ§é
åŒ ïŒ²âCH2âSO3Na ïŒåŒäžïŒ²ã¯C14ãC18ã®ç·ç¶ã¢ã«ãã«åºã§ã
ãïŒãæããçé¢æŽ»æ§å€ã«å¯Ÿãã西ãã€ãåœã¬
ãã¢ãŒã¯ãŒã³ã®ãã€ãšã«ã»ã¢ãŒã»ã²ãŒã®åå
åãã (5) ãµã³ããŸã«NEïŒSANDOZOL NEïŒïŒã¹ã«ã
ã³åããã«ãªã·ãã¬ãšãŒãã«å¯Ÿããã¹ã€ã¹åœã
ãŒãŒã«ã®ãµã³ãã»ã¢ãŒã»ã²ãŒã®åååïŒã (6) ãŠã«ãã©ãã³ïŒ·ïŒULTRAVON ïŒïŒäžèšæ§
é åŒ ãæããçé¢æŽ»æ§å€ã«å¯Ÿããã¹ã€ã¹åœããŒãŒã«
ã®ããã»ã¬ã€ã®ãŒã»ã¢ãŒã»ã²ãŒã®åååïŒ ã®åŠãåžè²©ã®ã¢ããªã³ææ©çé¢æŽ»æ§å€ãçšããŠåŸ
ãããã æ¬çºæã«ãã䜿çšããã®ã«å¥œé©ãªã¢ããªã³çé¢
掻æ§å€ã®ä»ã®äŸã¯ãç±³åœç¹èš±ç¬¬2527260å·ãå第
2600831å·ãå第2719087å·ãå第3003877å·ãå
第3026202å·ãå第3415649å·ãå第3788850å·ã
å第3788851å·ãå第3788852å·ãå第3793032å·
ããã³å第3963499å·æ现æžãè±åœç¹èš±ç¬¬808228
å·ãå第1024808å·ãããã³å第1216389å·æ现æž
ã«èŠåºãããšãã§ããã æ¬çºæã«ããå容äœææã§äœ¿çšããã®ã«å¥œé©ãª
ã¢ããªã³æ§ææ©ååç©ã¯ãŸãã¢ããªã³æ§éåäœã
äŸãã°ããªã¹ãã¬ã³ã¹ã«ãããŒãããã³ãžãŒã»ãš
ãã»ããã€ã³èãã¶ã»ããªã«ã«ã»ãã¬ã¹ïŒãã³ã
ã³ã»ããŠãŒãšãŒã¯ïŒ1966幎çºè¡ããããªãã°ã©ã
ã€ãã¯ã»ãšãã«ãžãšã³ã»ã±ãã¹ããªãŒã第167é
ã«èšèŒãããŠããåŠã玫å€ç·åžåå€ãšããŠäœçšã
ãã¢ããªã³æ§ååç©ãå«ãã æ¬çºæã¯ãæ¡æ£è»¢åéåããã³å°ãªããšãïŒçš®
ã®ææ転ååãéæå æ§å容äœææäžã«åœ¢æãã
ãæ¹æ³ãå«ã¿ã䜿çšããå容äœææãäžè¿°ããåŠ
ãæ¬çºæã«ããå容äœææã§ããããšãç¹åŸŽãšã
ãã éå補é ã®ããã®æ¡æ£è»¢åæ³ã¯åçæè¡åéã§
éåžžã«è¯ãç¥ãããŠãããããã¯åçããã²ã³å
éææã®åã«å¿ããé²å ããã³çŸåãããã³ãã
ãææãããã²ã³åéé¯åå€ã®ååšäžã«å容äœæ
æãšæ¥è§Šãããããšãå«ããé¯åãããããã²ã³
åéã¯æ¡æ£ã«ãã€ãŠå容äœææã«è»¢åããããã
ææäžã§éåã«å€ããããããã«ãªããé²å ãã
ãããã²ã³åéææäžã§ã®æœåã®çŸåã¯ãããã
ææã®å容äœææãšã®æ¥è§Šã«å ç«ã€ãŠãŸãã¯äžéš
å ç«ã€ãŠè¡ãªã€ãŠãããããããã¯ãããææå
å¿ã®æ¥è§Šäžã«çããããŠãããã æ¬çºæã«ããäžèšæ¹æ³ã«ãããŠãæ¡æ£è»¢åéå
ã®åœ¢æã¯ãå容äœææäžã§ã®è»¢åææåã®åœ¢æã®
åã«ãŸãã¯ããã«ç¶ããŠè¡ãªã€ãŠãããã転åæ
æåã¯äŸãã°ããèªäœç¥ãããŠããããã«ãå容
äœææäžã«ææã®åã«å¿ãã転åãŸãã¯ææçæ
ååç©ã®åã«å¿ãã転åã«ãã€ãŠäœãããšãã§ã
ãã äžæ¹ã§ã¯éå圢ææ§é¯ååç©ããã³ä»æ¹ã§ã¯æ
æå圢ææ§ååç©ããç°ãªãå¥ã ã®åçææïŒã
ããã¯é£ç¶çã«å容äœææãšæ¥è§Šãããããã«ã
ãïŒããå容äœææã«è»¢åãããã éæå æ§å容äœææäžã«ææåãäœããããã
ãã²ã³åéä¹³å€å±€ãšçµåããŠåææäŸäžæ§ç©è³ªã
æããåçææã䜿çšãããåææäŸäžæ§ç©è³ªã¯
ãã®ææäžã§ãå§ãæåæ§ãŸãã¯å§ãéæåæ§ã§
ãããåã«å¿ããŠçŸåãããããã²ã³åéã®åã«
å¿ããéå ã«å¿çããŠæåæ§ã«åã«å¿ããå€åã
åãããåŸã€ãŠåææäŸäžæ§ç©è³ªã¯ããããç©è³ª
ãå«æããåçææã«ãããŠãäžèšææãæææ¡
æ£è»¢åæ³ãå®æœãããã䜿çšããåŠç液ã§ééã
ããæå§ãã¯æ¡æ£æ§ã§ããããšãéæ¡æ£æ§ã§ãã
ããšãã§ãããéæ¡æ£æ§ç©è³ªã¯ãåçææãåŠç
液ãåžåãããšãåçææäžã§ããããæ¡æ£ãå
ããã®ãé»æ¢ãŸãã¯å®è³ªçã«é»æ¢ããã®ã«å åãª
åçææäžã§ã®éæåæ§ãäžããããäžè¬ã«åµ©é«
ã«ãããç©è³ªã§ããã ååææå³ã¡å容äœææäžã«æ®éã®ãã¬ããã²
ã³åéä¹³å€ã®çŸåã«å¿çããŠããžè»¢åææåãäž
ããåææäŸäžæ§ç³»ã¯ããžäœçšæ§ãšç§°ããããå
åææäžã«æ®éã®ãã¬ããã²ã³åéä¹³å€ã®çŸåã«
å¿çããŠãã¬è»¢ååãäžããåææäŸäžæ§ç³»ã¯ã
ã¬äœçšæ§ãšç§°ãããã è±åœç¹èš±ç¬¬804972å·æ现æžïŒããã¯ç±³åœç¹èš±ç¬¬
2983606å·æ现æžã«çžåœããïŒã«èšèŒãããŠãã
åŠãããã¬äœçšæ§ããã²ã³åéä¹³å€å±€ãçšããŠã
ãžã«ã©ãŒè»¢ååã圢æããããããææçŸåå€
ïŒå³ã¡åãååäžã«ããã²ã³åéçŸåæ©èœãšææ
ã®çºè²ç³»ãå«æããææïŒã䜿çšã§ãããçŸåå¯
èœããã²ã³åéãšåå¿ããããšã«ãã€ãŠãææçŸ
åå€ã¯ãã®ã¢ã«ã«ãªæ§åªäœäžã§ã®æ¡æ£å¯èœæ§ã倱
ããæªåå¿ææçŸåå€ã¯å容äœææã«è»¢åããã
ãã®äžã«åªæå€ã«ãã€ãŠå®çãããã å容äœææäžã«ããžã«ã©ãŒåã圢æããããã®
å¥ã®æ¹æ³ã«ããã°ãäŸãã°å ¬åããããã€ãç¹èš±
åºé¡ïŒDtâOSïŒç¬¬2402900å·ãç±³åœç¹èš±ç¬¬
3980479å·æ现æžããã³1976幎ïŒæã«åºé¡ããã
ãªãµãŒãã»ãã€ã¹ã¯ããžã€ãŒ14432å·ã«èšèŒãã
ãŠããåŠããæ¡æ£æ§åäŸäžæ§ææãæŸåºããå§ã
éæåæ§ã®ååç©ãéåçŸåã«éæ¯äŸããŠæŸåºã
ããã æŽã«å¥ã®æ¹æ³ãäŸãã°ããªãã°ã©ãã€ãã¯ã»ãµ
ã€ãšã³ã¹ã»ãšã³ãã»ãšã³ãžãã¢ãªã³ã°ç¬¬20巻第ïŒ
å·ïŒæïŒïŒæå䜵å·ïŒ1976幎ïŒç¬¬155é ã第158
é ãç±³åœç¹èš±ç¬¬3980479å·ãå ¬åããããã€ãç¹
èš±åºé¡ç¬¬2645656å·ãå第2242762å·ãå第
2505248å·ããã³1968幎ïŒæ24æ¥åºé¡ç¬¬1772929å·
æ现æžã«èšèŒãããŠããåŠãæ¹æ³ã§ã¯ãææåã¯
ããã²ã³åéçŸåã«æ¯äŸããæ¿åºŠã§äœããããåŸ
ã€ãŠããžææåã®å容äœææäžã§ã®çæã«ã¯ãã
ãžäœçšæ§ä¹³å€ã®äœ¿çšå³ã¡çŸåãããšãéé²å éšå
ã§éåãåãå ¥ããä¹³å€ã®äœ¿çšããŸãã¯åŸæ¥ã®ã
ã¬ä¹³å€ã䜿çšãããšãã«ã¯äŸãã°è±åœç¹èš±ç¬¬
904364å·æ现æžç¬¬19é 第ïŒè¡ã第41è¡ã«èšèŒãã
ãŠããåŠãéé¯å¡©æ¡æ£è»¢åæ³ã«åºã¥ããé©åœãªå
転æ³ã®é©çšãå¿ èŠãšããã å容äœææã®çŸåæ žå«æå±€ã§äœ¿çšããã¢ããªã³
æ§ææ©ååç©ã®éã¯ãéåã®å åŠå¯åºŠã«ã€ããŠã®
ææå容äœå±€ã®ã«ããªã³åªæå€ã®äžå©ãªåœ±é¿ãå°
éããå¿ èŠåºŠã«å¿ããŠæ±ºããç°¡åãªè©Šéšã§æ±ºå®ã§
ãããéåžžãªããŠã åªæå€ã«å¯ŸããŠã¢ããªã³æ§æ
æ©ååç©ïŒã100ééïŒ ã®ç¯å²ã®éãæºè¶³ã§ãã
çµæãäžãããäŸãã°ïŒm2ã«ã€ããŠçŽ10ïœã®ãªã
ãŠã åªæå€ã«å¯ŸããŠã¢ããªã³æ§ææ©ååç©0.33ã
6.66ïœïŒm2ã䜿çšããããªããŠã åªæå€ã®éã¯åŸ
æ¥ã®æææ¡æ£è»¢åæ³ã«ãããéãšåãã§ãããäŸ
ãã°çŽ15ãçŽïŒïœïŒm2ã§ããã éåå容局ã®ãã€ã³ããŒããã³ææå容局ã®ã
ã€ã³ããŒã¯ææ©èŠªæ°Žæ§ãã€ã³ããŒäŸãã°ãŒã©ã
ã³ãã«ã«ããã·ã¡ãã«ã»ã«ããŒã¹ãã¢ã©ãã€ãŽ
ã ãã¢ã«ã®ã³é žãœãŒããã¢ã«ã®ã³é žã®ãããã¬ã³
ã°ãªã³ãŒã«ãšã¹ãã«ãããããã·ãšãã«æŸ±ç²ãã
ãã¹ããªã³ãããããã·ãšãã«ã»ã«ããŒã¹ãããª
ããã«ãããªãã³ããã³ããªããã«ã¢ã«ã³ãŒã«ã
ããã çŸåæ žãšããŠããã±ã«ãŸãã¯éã®ç¡«åç©ãŸãã¯
ãããã®æ··åç¡«ååç©ã䜿çšããã®ã奜ãŸããã
ãããä»ã®çŸåæ žäŸãã°ééå±ã®ç¡«åç©äŸãã°ã¢
ã³ãã¢ã³ããã¹ãã¹ãã«ãããŠã ãã³ãã«ããé
ããã³äºéã®ç¡«åç©ãåæ§ã«äœ¿çšã§ãããä»ã®å¥œ
é©ãªæ žã¯ã»ã¬ã³åç©ãä»ã»ã¬ã³åç©ãå€ç¡«åç©ã
ããã³ããã²ã³åé«ïŒïŒã®çŸ€ã«å±ãããéãã
ã³äºéã®æ··åç¡«åç©å¡©ã¯ãããã ãã§ããã³ããª
ã¢ã»ã¿ããããžããªããŠãŒã¬ããããã³ãžããªãª
ããµãããšæ··åãããšã掻æ§ãªæ žã§ããããã¶ã
ããããã²ã³åéã䜿çšã§ããããã®ã¿ãªããã³
ãã€ãç¶ã®ééå±èªäœã奜ãŸããã¯éãéãçœ
éããã©ãžãŠã ããã³æ°Žéã䜿çšã§ãããäž¡è ã®
åå容局ã¯ããããã®æ©æ¢°ç匷床ãæ¹è¯ããã
ããéåžžã®ç¡¬åå€ã§ç¡¬åããŠããããèçœè³ªç³»ã³
ãã€ãå±€ã«å¥œé©ãªç¡¬åå€ã«ã¯äŸãã°ãã«ã ã¢ã«ã
ãããã°ãªãªãã¶ãŒã«ãã ã³ã¯ãã«é žãã¯ãã æ
ã°ããå«ãã æ¬çºææ¹æ³ãå®æœããã«åœã€ãŠãå¿ èŠãªçŸåæ ž
ã¯ãããã²ã³åéé¯åå€ã®ååšäžåã«å¿ããŠé²å
ããææãå容äœææãšæ¥è§Šãããåã«ããã®å Ž
ã§åœ¢æãããããšãã§ãããããã¯ãã®å Žã§ä»äž
ããããšãã§ãããäŸãã°ç±³åœç¹èš±ç¬¬3617276å·
æ现æžã«èšèŒãããŠããåŠããçŸåæ žã¯ãæ žãå
æ£ãã圢ã§ä¿ã€ã«å åãªã ãã®éã®èŠªæ°Žæ§ã³ãã€
ããå«æãããã€ãªã€ãŒæ¶²äœããåæ£ç¶æ ã§ä»äž
ããããšãã§ããã éæã§ããéåå容局ã«ã€ããŠãããšããäžèš
åã¯äžéæåå€ãå®è³ªçã«å«æããªãããšãæå³
ãããããããªããããã¯ãææå容局ã®äžãå³
ã¡æ¯æäœãšææå容局ã®éããŸãã¯çŸåæ žãå«æ
ããéåå容局ã®äžã«ãã€ã³ããŒäžã«åæ£ããã
äŸãã°äºé žåãã¿ã³ãå«æããå åå°å±€ãä»äžã
ãå¯èœæ§ãæé€ãããã®ã§ã¯ãªãããã ãåŸè ã®
å Žåæ¯æäœã¯éæã«ããå åå°å±€ã¯åŠç液ã«å¯Ÿã
ééæ§ã§ãããã¢ããªã³ç³»å¯æº¶æ§ååºãå«æãã
ããã«éåäœãã€ã³ããŒäžã«äžéæåå€äŸãã°äº
é žåãã¿ã³ãå«æãã奜é©ãªå åå°å±€ã¯ç±³åœç¹èš±
第3721555å·æ现æžã«èšèŒãããŠãããäºé žåã
ã¿ã³ãå«æããäžéæå åå°å±€ã¯éåããã³ææ
åãèŠãããšã®ã§ããçœè²ã®å°ã圢æããããã
ã¯æ¬æ¥äžéæåå°æ§é ãæããªããã€ã«ã æš¹èæ¯
æäœã䜿çšãããšãèå³ãããã æ®éã®ããã²ã³åéåçã«äœ¿çšãããããªæš¹è
æ¯æäœã¯ãçŽæ¯æäœãããéåžžã«å¯žæ³å®å®æ§ã§ã
ããåŸã€ãŠæš¹èåºæãæããå容äœææãšæŽåã
ããå転åã«åé¡ãæèµ·ãããããªããšã¯ãªãã
çŽæ¯æäœã䜿çšãããšãã¯æš¹è被èŠãäŸãã°ããª
ãšãã¬ã³è¢«èŠãäžããã®ã奜ãŸãããããã¯ãã
ãããšæ°Žåæææ§ãéåžžã«å°ãªããªãã湿最æ¡æ£
転ååŠçã«æŽã«æ¥éãªæ¥è§Šä¹Ÿç¥æ§ãšãªãããã§ã
ãã éé¯å¡©æ¡æ£è»¢åæ³ããã³ãã®ããã®åå容局ã«
ã€ããŠã®è©³çŽ°ã¯ãšãŒã»ãããããã³ã€ãŒã»ãŠãšã€
ãèãããªãŒã«ã«ã»ãã¬ã¹ïŒãã³ãã³ïŒããŠãŒãš
ãŒã¯ïŒ1972幎çºè¡ãã·ã«ããŒã»ãã©ã€ãã»ãã€ã
ãŠãŒãžãšã³ã»ããã»ã·ãºãã«èŠåºãããšãã§ãã
ãŸãåœæ¥è ã«ã¯è¯ãç¥ãããŠããã 以äžã«å®æœäŸãæããŠæ¬çºæã説æããããæ¬
çºæã¯ãããã«éå®ããããã®ã§ã¯ãªããå šãŠã®
å²åïŒæ¯ïŒããã³çŸåçã¯ä»ã«ç¹èšãã¬éãéé
ã«ããã å®æœäŸ ïŒ (1) æ¯èŒå容äœææã®è£œé ã æ¯èŒå容äœææã®è£œé ã«åœã€ãŠã¯ãåªæå€ãš
ããŠãã¹ãããŠã ååç©ãå«æããææåå容局
ã¯ãïŒm2ã«ã€ããŠ65ïœã®æ¹¿æœ€è¢«èŠçã§äžèšçµæç©
ããéæãªäžå¡ãããããªãšãã¬ã³ãã¬ãã¿ã¬ãŒ
ãäžã«è¢«èŠããã èžæºæ°Ž 656ml ãŒã©ãã³ 72ïœ æ¹¿æœ€å€ãšããŠCF3ïŒCF2ïŒ8COONH4ã®ïŒïŒ 氎溶
液 10ml ãããµãã·ã«ããªããšãã«ãã¹ãããŠã ããã
ã€ãã®8.8ïŒ æº¶æ¶² 250ml ãã«ã ã¢ã«ãããïŒïŒ 氎溶液 10ml ãããµãã·ã«ããªããšãã«ãã¹ãããŠã ããã
ã€ã溶液ã¯ã22ïœã®äžèšååç©ã100mlã®ãšã¿ã
ãŒã«ã«æº¶è§£ãã次ãã§æ°Žã250mlã«ãªããŸã§å ã
ãŠäœã€ãã 也ç¥ããææåå容局äžã«äžèšçµæç©ãã40
ïœïŒm2ã®æ¹¿æœ€è¢«èŠçã§è¢«èŠããã
åã®è£œé ã«äœ¿çšããã®ã«å¥œé©ãªéæå æ§å容äœæ
æã«é¢ããã ç¹å¥ã«äœãããåçããã²ã³åéä¹³å€ææãçš
ããŠæ¡æ£è»¢åã«ãã€ãŠå€è²åãäœãããšã¯çŸåšå¹Ÿ
ã€ãã®æ¹æ³ã§çšããããŠãããæå æ§ç©è³ªãšããŠ
ããã²ã³åéãçšããŠäœçšãããæææ¡æ£è»¢åæ³
ã¯ãå šãŠåãåçã«åºã¥ããŠãããå³ã¡ããã²ã³
åéã®åã«å¿ããéãžã®éå ã«ãã€ãŠå¶åŸ¡ããã
ææãŸãã¯ææ圢ææ§é éšã®æå床ã®å€åã«åºã¥
ããŠããããããã®æ¹æ³ã¯ãæ¬æ¥ã®å€è²ã®æ¯è²ãŸ
ãã¯è¢«åäœã®å€è²ããªã³ãã圢æãã幟ã€ãã®é
ããããåè²ææåããåãæ§æãããããã€ã³
ã¹ã¿ã³ãã«ã©ãŒããªã³ãã®è£œé ã®ããã®åºæ¬ã§ã
ãã ã°ã©ãã€ãã¯ã¢ãŒãã®åéãäŸãã°ã«ã©ãŒãã«
ãŒãã€ã³ã°ãå°å³è£œå³ããã³æè¡çã€ã©ã¹ãã®å
éã«ãããŠãåè²ææåã«å ããŠãã«ã©ãŒæ å ±ã«
補åãã圢ã§é»è²åãå«æããŠããããªã³ããæ±
ããããŠããã ãã®ãããå容äœææäžã«éåãäœãããšã«åº
ã¥ããæ®éã®é»è²éé¯å¡©æ¡æ£è»¢åæ³ãšçµåããæ
ææ¡æ£è»¢åæ³ã䜿çšãããŠãããé»çœåããã³æ
æåã¯ãæ¡æ£ãããéé¯å¡©ãéã«éå ããããšã
æ¥è§Šäœçšãããããã®çŸåæ žãå«æããåãå容
äœææäžã«æŽåãããŠåœ¢æãããã å容äœææäžã«æ¡æ£ãããææãŸãã¯æ¡æ£ãã
ãææ圢æç©è³ªãã圢æãããææã¯ããããåª
æã«ãã€ãŠã³ãã€ãå±€äžã«æ®éå®çããããææ
æ¡æ£è»¢åæ³ã«ãããŠã¯ã芪氎æ§ã³ãã€ãåªäœäžã§
ã®ææãŸããã¯ææ圢æç©è³ªã®æå床ã¯ããã®æ§
é äžã«ã¢ããªã³æ§åºãååšããããšã«ãã€ãŠæ®é
åŸããããåŸã€ãŠåªæå€ã¯äžè¬ã«ã«ããªã³æ§æ§é
éšãæããååç©ã§ããã é žæ§ææã®ããã®ç¹ã«å¥œé©ãªææåªææ§ååç©
ã«ã¯ãäŸãã°ç±³åœç¹èš±ç¬¬3173786å·ãå第3227550
å·ãå第3271147å·ããã³å第3271148å·æ现æžã«
èšèŒãããŠããåŠãææ©ãªããŠã ååç©ãããã
ãããã«ã¯æ¡æ£é»æ¢æ§åºãäŸãã°å¥œãŸããã¯å°ãª
ããšã12åã®ççŽ ååãæããççŽ éãå«æãã
ã®ã奜ãŸããåçŽã¢ã³ã¢ããŠã ååç©ãäžçŽã¹ã«
ãããŠã ååç©ããã³åçŽãã¹ãããŠã ååç©ã
å«æããã æ¬çºæã®åºç€ãšãªã€ãç 究ããã³å®éšäžã«ãæ
æåã«å ããŠéåã圢æããæ¡æ£è»¢åæ³ã«ãã
ãŠãé žæ§ææã®ããã®åªæå€ãšããŠäœçšãããªã
ãŠã ååç©ããéåã®åœ¢æã«åŠšå®³å¹æãæããã
ãšãåŸã€ãŠçŸåæ žã®ååšäžã«éé¯å¡©ãéå ããã
ãšã«ãã€ãŠåŸãããå åŠå¯åºŠã«åŠšå®³å¹æãæãã
ããšãèŠåºããã ãã®åŠšå®³å¹æã®æ©æ§ã¯è¯ãå€ããªãã®ã§ãã
ããããã¯ãªããŠã ååç©ãé¯å¡©ã®è² ã«åž¯é»ãã
éå«æã€ãªã³ãçŸåæ žã«å°éããã®ãé»æ¢ããã
ããšã®è§Šåªçæ¥è§Šãå°éãããã®ãšæšå®ãããã æ¬çºæã«ããã°ãå åŠå¯åºŠæžå°ã®äžèšåé¡ã¯ã
ææ転åããã³éé¯å¡©æ¡æ£è»¢åæ³ã«äœ¿çšããã®ã«
å¹é©ãªéæå æ§å容äœææãæäŸããããšã«ãã€
ãŠè§£æ±ºãããäžèšææã¯ã (i) æ¯æäœã (ii) é žæ§ææãåªæã§ããææ©ãªããŠã ååç©ã
å«æãã第ïŒææ©èŠªæ°Žæ§ã³ãã€ãå±€ãããã³ (iii) éé¯å¡©ã®éãžã®éå ãæ¥è§Šäœçšãããããã®
çŸåæ žãå«æããéæ第ïŒææ©èŠªæ°Žæ§ã³ãã€ã
å±€ ãå«æããäžèšææã¯ãŸãäžèšå±€(iii)äžã«ããã³ïŒ
ãŸãã¯å±€(ii)ãš(iii)ã®éã®èŠªæ°Žæ§ã³ãã€ãäžéå±€äž
ã«ãææ©ååç©ã®ççŽ ååã«çµåããã¢ããªã³æ§
åºãæããææ©ååç©ïŒä»¥åŸã¢ããªã³æ§ææ©åå
ç©ãšç§°ããïŒã®å°ãªããšãïŒçš®ãå«æããã ã¢ããªã³æ§ææ©ååç©ããªããŠã ååç©ãšåå¿
ããããããŠãªããŠã ååç©ã¯éé¯å¡©ã¢ããªã³ãš
åå¿ããããšããé»æ¢ããããã®ãšä¿¡ããããã ç¹ã«æå¹ãªã¢ããªã³æ§ææ©ååç©ã¯ãã¹ã«ãã
ãŒãåºãŸãã¯ãµã³ããšãŒãåºãå«æããã¢ããªã³
ææ©çé¢æŽ»æ§å€ã§ããã ã¹ã«ãããŒãã®äŸã«ã¯ã¢ã«ãã«ã¹ã«ãããŒãã
ã¢ã«ã«ãªãŒã«ã¹ã«ãããŒããã¢ã«ãã«ããšããŒã«
ããªã°ãªã³ãŒã«ãšãŒãã«ã¹ã«ãããŒãããããã
ã·ã¢ã«ã«ã³ã¹ã«ãããŒããèèªé žã¿ãŠã©ã€ãåå
ç©ããã³ã¹ã«ãã³ãã¯é žãšã¹ãã«ãããã ãµã«ããšãŒãã®äŸã«ã¯äžçŽããã³äºçŽã¢ã«ãã«
ãµã«ããšãŒãããµã«ããšãŒãåããªã°ãªã³ãŒã«ãš
ãŒãã«ããµã«ããšãŒãåã¢ã«ãã«ããšããŒã«ããª
ã°ãªã³ãŒã«ãšãŒãã«ããã³æ²¹ããã³èèªã®ç¡«é žãš
ã¹ãã«ãããã ã¢ããªã³çé¢æŽ»æ§å€ããã³ãã®è£œé ã®ååŠã¯ã¯
ãŒããŒã»ãšã ã»ãªã³ãã€ãŒã«ãè1976幎ããŒã»
ã«ã»ããã«ãŒã»ã€ã³ã³ãŒãã¬ã€ã·ãšã³ïŒããŠãŒãš
ãŒã¯ã»ã¢ã³ãã»ããŒãŒã«ïŒçºè¡ããã¢ããªãã
ã¯ã»ãµãŒãã¢ã¯ã¿ã³ãã第éšã«èšèŒãããŠã
ããç³æ²¹ã¹ã«ãããŒãã«ã€ããŠã¯ç¹ã«ç¬¬330é ã
第335é ãåç §ã®ããšã 奜ãŸããã®ã¯ãã®ååæ§é äžã«ãå°ãªããšã12
åã®ççŽ ååã®éäžæççŽ éãäŸãã°C12ãC18ã®
ïœâã¢ã«ãã«éãæããã¢ããªã³æ§ææ©ååç©ã§
ããããããååç©ã¯çé¢æŽ»æ§å€ãŸãã¯æ¹¿æœ€å€ãš
ããŠæåããã ç¹ã«è¯å¥œãªçµæã¯ã (1) ã¢ãšããŸã«OTïŒAEROSOL OTïŒïŒäžèšæ§é
åŒ ãæããçé¢æŽ»æ§å€ã«å¯Ÿããç±³åœããŠãŒãšãŒã¯
åžã®ã¢ã¡ãªã«ã³ã»ãµã€ã¢ãããã»ã³ã ãããŒã®
åååïŒã (2) ãã¹ã¿ãã³ïŒŽïŒHOSTAPON ïŒïŒäžèšæ§é
åŒ ãæããçé¢æŽ»æ§å€ã«å¯Ÿãã西ãã€ãåœãã©ã³
ã¯ãã«ãåžã®ããã¹ãã»ã¢ãŒã»ã²ãŒã®åååïŒã (3) ã¿ãŒãžããŒã«ïŒïŒTERGITOL4ïŒïŒäžèšæ§é
åŒ ãæããçé¢æŽ»æ§å€ã«å¯Ÿããç±³åœããŠãŒãšãŒã¯
åžã®ãŠããªã³ã»ã«ãŒãã€ãã»ã¢ã³ãã»ã«ãŒãã³
ã®åååïŒã (4) ã¡ã«ãŸã©ãïŒMERSOLAT ïŒãäžèšæ§é
åŒ ïŒ²âCH2âSO3Na ïŒåŒäžïŒ²ã¯C14ãC18ã®ç·ç¶ã¢ã«ãã«åºã§ã
ãïŒãæããçé¢æŽ»æ§å€ã«å¯Ÿãã西ãã€ãåœã¬
ãã¢ãŒã¯ãŒã³ã®ãã€ãšã«ã»ã¢ãŒã»ã²ãŒã®åå
åãã (5) ãµã³ããŸã«NEïŒSANDOZOL NEïŒïŒã¹ã«ã
ã³åããã«ãªã·ãã¬ãšãŒãã«å¯Ÿããã¹ã€ã¹åœã
ãŒãŒã«ã®ãµã³ãã»ã¢ãŒã»ã²ãŒã®åååïŒã (6) ãŠã«ãã©ãã³ïŒ·ïŒULTRAVON ïŒïŒäžèšæ§
é åŒ ãæããçé¢æŽ»æ§å€ã«å¯Ÿããã¹ã€ã¹åœããŒãŒã«
ã®ããã»ã¬ã€ã®ãŒã»ã¢ãŒã»ã²ãŒã®åååïŒ ã®åŠãåžè²©ã®ã¢ããªã³ææ©çé¢æŽ»æ§å€ãçšããŠåŸ
ãããã æ¬çºæã«ãã䜿çšããã®ã«å¥œé©ãªã¢ããªã³çé¢
掻æ§å€ã®ä»ã®äŸã¯ãç±³åœç¹èš±ç¬¬2527260å·ãå第
2600831å·ãå第2719087å·ãå第3003877å·ãå
第3026202å·ãå第3415649å·ãå第3788850å·ã
å第3788851å·ãå第3788852å·ãå第3793032å·
ããã³å第3963499å·æ现æžãè±åœç¹èš±ç¬¬808228
å·ãå第1024808å·ãããã³å第1216389å·æ现æž
ã«èŠåºãããšãã§ããã æ¬çºæã«ããå容äœææã§äœ¿çšããã®ã«å¥œé©ãª
ã¢ããªã³æ§ææ©ååç©ã¯ãŸãã¢ããªã³æ§éåäœã
äŸãã°ããªã¹ãã¬ã³ã¹ã«ãããŒãããã³ãžãŒã»ãš
ãã»ããã€ã³èãã¶ã»ããªã«ã«ã»ãã¬ã¹ïŒãã³ã
ã³ã»ããŠãŒãšãŒã¯ïŒ1966幎çºè¡ããããªãã°ã©ã
ã€ãã¯ã»ãšãã«ãžãšã³ã»ã±ãã¹ããªãŒã第167é
ã«èšèŒãããŠããåŠã玫å€ç·åžåå€ãšããŠäœçšã
ãã¢ããªã³æ§ååç©ãå«ãã æ¬çºæã¯ãæ¡æ£è»¢åéåããã³å°ãªããšãïŒçš®
ã®ææ転ååãéæå æ§å容äœææäžã«åœ¢æãã
ãæ¹æ³ãå«ã¿ã䜿çšããå容äœææãäžè¿°ããåŠ
ãæ¬çºæã«ããå容äœææã§ããããšãç¹åŸŽãšã
ãã éå補é ã®ããã®æ¡æ£è»¢åæ³ã¯åçæè¡åéã§
éåžžã«è¯ãç¥ãããŠãããããã¯åçããã²ã³å
éææã®åã«å¿ããé²å ããã³çŸåãããã³ãã
ãææãããã²ã³åéé¯åå€ã®ååšäžã«å容äœæ
æãšæ¥è§Šãããããšãå«ããé¯åãããããã²ã³
åéã¯æ¡æ£ã«ãã€ãŠå容äœææã«è»¢åããããã
ææäžã§éåã«å€ããããããã«ãªããé²å ãã
ãããã²ã³åéææäžã§ã®æœåã®çŸåã¯ãããã
ææã®å容äœææãšã®æ¥è§Šã«å ç«ã€ãŠãŸãã¯äžéš
å ç«ã€ãŠè¡ãªã€ãŠãããããããã¯ãããææå
å¿ã®æ¥è§Šäžã«çããããŠãããã æ¬çºæã«ããäžèšæ¹æ³ã«ãããŠãæ¡æ£è»¢åéå
ã®åœ¢æã¯ãå容äœææäžã§ã®è»¢åææåã®åœ¢æã®
åã«ãŸãã¯ããã«ç¶ããŠè¡ãªã€ãŠãããã転åæ
æåã¯äŸãã°ããèªäœç¥ãããŠããããã«ãå容
äœææäžã«ææã®åã«å¿ãã転åãŸãã¯ææçæ
ååç©ã®åã«å¿ãã転åã«ãã€ãŠäœãããšãã§ã
ãã äžæ¹ã§ã¯éå圢ææ§é¯ååç©ããã³ä»æ¹ã§ã¯æ
æå圢ææ§ååç©ããç°ãªãå¥ã ã®åçææïŒã
ããã¯é£ç¶çã«å容äœææãšæ¥è§Šãããããã«ã
ãïŒããå容äœææã«è»¢åãããã éæå æ§å容äœææäžã«ææåãäœããããã
ãã²ã³åéä¹³å€å±€ãšçµåããŠåææäŸäžæ§ç©è³ªã
æããåçææã䜿çšãããåææäŸäžæ§ç©è³ªã¯
ãã®ææäžã§ãå§ãæåæ§ãŸãã¯å§ãéæåæ§ã§
ãããåã«å¿ããŠçŸåãããããã²ã³åéã®åã«
å¿ããéå ã«å¿çããŠæåæ§ã«åã«å¿ããå€åã
åãããåŸã€ãŠåææäŸäžæ§ç©è³ªã¯ããããç©è³ª
ãå«æããåçææã«ãããŠãäžèšææãæææ¡
æ£è»¢åæ³ãå®æœãããã䜿çšããåŠç液ã§ééã
ããæå§ãã¯æ¡æ£æ§ã§ããããšãéæ¡æ£æ§ã§ãã
ããšãã§ãããéæ¡æ£æ§ç©è³ªã¯ãåçææãåŠç
液ãåžåãããšãåçææäžã§ããããæ¡æ£ãå
ããã®ãé»æ¢ãŸãã¯å®è³ªçã«é»æ¢ããã®ã«å åãª
åçææäžã§ã®éæåæ§ãäžããããäžè¬ã«åµ©é«
ã«ãããç©è³ªã§ããã ååææå³ã¡å容äœææäžã«æ®éã®ãã¬ããã²
ã³åéä¹³å€ã®çŸåã«å¿çããŠããžè»¢åææåãäž
ããåææäŸäžæ§ç³»ã¯ããžäœçšæ§ãšç§°ããããå
åææäžã«æ®éã®ãã¬ããã²ã³åéä¹³å€ã®çŸåã«
å¿çããŠãã¬è»¢ååãäžããåææäŸäžæ§ç³»ã¯ã
ã¬äœçšæ§ãšç§°ãããã è±åœç¹èš±ç¬¬804972å·æ现æžïŒããã¯ç±³åœç¹èš±ç¬¬
2983606å·æ现æžã«çžåœããïŒã«èšèŒãããŠãã
åŠãããã¬äœçšæ§ããã²ã³åéä¹³å€å±€ãçšããŠã
ãžã«ã©ãŒè»¢ååã圢æããããããææçŸåå€
ïŒå³ã¡åãååäžã«ããã²ã³åéçŸåæ©èœãšææ
ã®çºè²ç³»ãå«æããææïŒã䜿çšã§ãããçŸåå¯
èœããã²ã³åéãšåå¿ããããšã«ãã€ãŠãææçŸ
åå€ã¯ãã®ã¢ã«ã«ãªæ§åªäœäžã§ã®æ¡æ£å¯èœæ§ã倱
ããæªåå¿ææçŸåå€ã¯å容äœææã«è»¢åããã
ãã®äžã«åªæå€ã«ãã€ãŠå®çãããã å容äœææäžã«ããžã«ã©ãŒåã圢æããããã®
å¥ã®æ¹æ³ã«ããã°ãäŸãã°å ¬åããããã€ãç¹èš±
åºé¡ïŒDtâOSïŒç¬¬2402900å·ãç±³åœç¹èš±ç¬¬
3980479å·æ现æžããã³1976幎ïŒæã«åºé¡ããã
ãªãµãŒãã»ãã€ã¹ã¯ããžã€ãŒ14432å·ã«èšèŒãã
ãŠããåŠããæ¡æ£æ§åäŸäžæ§ææãæŸåºããå§ã
éæåæ§ã®ååç©ãéåçŸåã«éæ¯äŸããŠæŸåºã
ããã æŽã«å¥ã®æ¹æ³ãäŸãã°ããªãã°ã©ãã€ãã¯ã»ãµ
ã€ãšã³ã¹ã»ãšã³ãã»ãšã³ãžãã¢ãªã³ã°ç¬¬20巻第ïŒ
å·ïŒæïŒïŒæå䜵å·ïŒ1976幎ïŒç¬¬155é ã第158
é ãç±³åœç¹èš±ç¬¬3980479å·ãå ¬åããããã€ãç¹
èš±åºé¡ç¬¬2645656å·ãå第2242762å·ãå第
2505248å·ããã³1968幎ïŒæ24æ¥åºé¡ç¬¬1772929å·
æ现æžã«èšèŒãããŠããåŠãæ¹æ³ã§ã¯ãææåã¯
ããã²ã³åéçŸåã«æ¯äŸããæ¿åºŠã§äœããããåŸ
ã€ãŠããžææåã®å容äœææäžã§ã®çæã«ã¯ãã
ãžäœçšæ§ä¹³å€ã®äœ¿çšå³ã¡çŸåãããšãéé²å éšå
ã§éåãåãå ¥ããä¹³å€ã®äœ¿çšããŸãã¯åŸæ¥ã®ã
ã¬ä¹³å€ã䜿çšãããšãã«ã¯äŸãã°è±åœç¹èš±ç¬¬
904364å·æ现æžç¬¬19é 第ïŒè¡ã第41è¡ã«èšèŒãã
ãŠããåŠãéé¯å¡©æ¡æ£è»¢åæ³ã«åºã¥ããé©åœãªå
転æ³ã®é©çšãå¿ èŠãšããã å容äœææã®çŸåæ žå«æå±€ã§äœ¿çšããã¢ããªã³
æ§ææ©ååç©ã®éã¯ãéåã®å åŠå¯åºŠã«ã€ããŠã®
ææå容äœå±€ã®ã«ããªã³åªæå€ã®äžå©ãªåœ±é¿ãå°
éããå¿ èŠåºŠã«å¿ããŠæ±ºããç°¡åãªè©Šéšã§æ±ºå®ã§
ãããéåžžãªããŠã åªæå€ã«å¯ŸããŠã¢ããªã³æ§æ
æ©ååç©ïŒã100ééïŒ ã®ç¯å²ã®éãæºè¶³ã§ãã
çµæãäžãããäŸãã°ïŒm2ã«ã€ããŠçŽ10ïœã®ãªã
ãŠã åªæå€ã«å¯ŸããŠã¢ããªã³æ§ææ©ååç©0.33ã
6.66ïœïŒm2ã䜿çšããããªããŠã åªæå€ã®éã¯åŸ
æ¥ã®æææ¡æ£è»¢åæ³ã«ãããéãšåãã§ãããäŸ
ãã°çŽ15ãçŽïŒïœïŒm2ã§ããã éåå容局ã®ãã€ã³ããŒããã³ææå容局ã®ã
ã€ã³ããŒã¯ææ©èŠªæ°Žæ§ãã€ã³ããŒäŸãã°ãŒã©ã
ã³ãã«ã«ããã·ã¡ãã«ã»ã«ããŒã¹ãã¢ã©ãã€ãŽ
ã ãã¢ã«ã®ã³é žãœãŒããã¢ã«ã®ã³é žã®ãããã¬ã³
ã°ãªã³ãŒã«ãšã¹ãã«ãããããã·ãšãã«æŸ±ç²ãã
ãã¹ããªã³ãããããã·ãšãã«ã»ã«ããŒã¹ãããª
ããã«ãããªãã³ããã³ããªããã«ã¢ã«ã³ãŒã«ã
ããã çŸåæ žãšããŠããã±ã«ãŸãã¯éã®ç¡«åç©ãŸãã¯
ãããã®æ··åç¡«ååç©ã䜿çšããã®ã奜ãŸããã
ãããä»ã®çŸåæ žäŸãã°ééå±ã®ç¡«åç©äŸãã°ã¢
ã³ãã¢ã³ããã¹ãã¹ãã«ãããŠã ãã³ãã«ããé
ããã³äºéã®ç¡«åç©ãåæ§ã«äœ¿çšã§ãããä»ã®å¥œ
é©ãªæ žã¯ã»ã¬ã³åç©ãä»ã»ã¬ã³åç©ãå€ç¡«åç©ã
ããã³ããã²ã³åé«ïŒïŒã®çŸ€ã«å±ãããéãã
ã³äºéã®æ··åç¡«åç©å¡©ã¯ãããã ãã§ããã³ããª
ã¢ã»ã¿ããããžããªããŠãŒã¬ããããã³ãžããªãª
ããµãããšæ··åãããšã掻æ§ãªæ žã§ããããã¶ã
ããããã²ã³åéã䜿çšã§ããããã®ã¿ãªããã³
ãã€ãç¶ã®ééå±èªäœã奜ãŸããã¯éãéãçœ
éããã©ãžãŠã ããã³æ°Žéã䜿çšã§ãããäž¡è ã®
åå容局ã¯ããããã®æ©æ¢°ç匷床ãæ¹è¯ããã
ããéåžžã®ç¡¬åå€ã§ç¡¬åããŠããããèçœè³ªç³»ã³
ãã€ãå±€ã«å¥œé©ãªç¡¬åå€ã«ã¯äŸãã°ãã«ã ã¢ã«ã
ãããã°ãªãªãã¶ãŒã«ãã ã³ã¯ãã«é žãã¯ãã æ
ã°ããå«ãã æ¬çºææ¹æ³ãå®æœããã«åœã€ãŠãå¿ èŠãªçŸåæ ž
ã¯ãããã²ã³åéé¯åå€ã®ååšäžåã«å¿ããŠé²å
ããææãå容äœææãšæ¥è§Šãããåã«ããã®å Ž
ã§åœ¢æãããããšãã§ãããããã¯ãã®å Žã§ä»äž
ããããšãã§ãããäŸãã°ç±³åœç¹èš±ç¬¬3617276å·
æ现æžã«èšèŒãããŠããåŠããçŸåæ žã¯ãæ žãå
æ£ãã圢ã§ä¿ã€ã«å åãªã ãã®éã®èŠªæ°Žæ§ã³ãã€
ããå«æãããã€ãªã€ãŒæ¶²äœããåæ£ç¶æ ã§ä»äž
ããããšãã§ããã éæã§ããéåå容局ã«ã€ããŠãããšããäžèš
åã¯äžéæåå€ãå®è³ªçã«å«æããªãããšãæå³
ãããããããªããããã¯ãææå容局ã®äžãå³
ã¡æ¯æäœãšææå容局ã®éããŸãã¯çŸåæ žãå«æ
ããéåå容局ã®äžã«ãã€ã³ããŒäžã«åæ£ããã
äŸãã°äºé žåãã¿ã³ãå«æããå åå°å±€ãä»äžã
ãå¯èœæ§ãæé€ãããã®ã§ã¯ãªãããã ãåŸè ã®
å Žåæ¯æäœã¯éæã«ããå åå°å±€ã¯åŠç液ã«å¯Ÿã
ééæ§ã§ãããã¢ããªã³ç³»å¯æº¶æ§ååºãå«æãã
ããã«éåäœãã€ã³ããŒäžã«äžéæåå€äŸãã°äº
é žåãã¿ã³ãå«æãã奜é©ãªå åå°å±€ã¯ç±³åœç¹èš±
第3721555å·æ现æžã«èšèŒãããŠãããäºé žåã
ã¿ã³ãå«æããäžéæå åå°å±€ã¯éåããã³ææ
åãèŠãããšã®ã§ããçœè²ã®å°ã圢æããããã
ã¯æ¬æ¥äžéæåå°æ§é ãæããªããã€ã«ã æš¹èæ¯
æäœã䜿çšãããšãèå³ãããã æ®éã®ããã²ã³åéåçã«äœ¿çšãããããªæš¹è
æ¯æäœã¯ãçŽæ¯æäœãããéåžžã«å¯žæ³å®å®æ§ã§ã
ããåŸã€ãŠæš¹èåºæãæããå容äœææãšæŽåã
ããå転åã«åé¡ãæèµ·ãããããªããšã¯ãªãã
çŽæ¯æäœã䜿çšãããšãã¯æš¹è被èŠãäŸãã°ããª
ãšãã¬ã³è¢«èŠãäžããã®ã奜ãŸãããããã¯ãã
ãããšæ°Žåæææ§ãéåžžã«å°ãªããªãã湿最æ¡æ£
転ååŠçã«æŽã«æ¥éãªæ¥è§Šä¹Ÿç¥æ§ãšãªãããã§ã
ãã éé¯å¡©æ¡æ£è»¢åæ³ããã³ãã®ããã®åå容局ã«
ã€ããŠã®è©³çŽ°ã¯ãšãŒã»ãããããã³ã€ãŒã»ãŠãšã€
ãèãããªãŒã«ã«ã»ãã¬ã¹ïŒãã³ãã³ïŒããŠãŒãš
ãŒã¯ïŒ1972幎çºè¡ãã·ã«ããŒã»ãã©ã€ãã»ãã€ã
ãŠãŒãžãšã³ã»ããã»ã·ãºãã«èŠåºãããšãã§ãã
ãŸãåœæ¥è ã«ã¯è¯ãç¥ãããŠããã 以äžã«å®æœäŸãæããŠæ¬çºæã説æããããæ¬
çºæã¯ãããã«éå®ããããã®ã§ã¯ãªããå šãŠã®
å²åïŒæ¯ïŒããã³çŸåçã¯ä»ã«ç¹èšãã¬éãéé
ã«ããã å®æœäŸ ïŒ (1) æ¯èŒå容äœææã®è£œé ã æ¯èŒå容äœææã®è£œé ã«åœã€ãŠã¯ãåªæå€ãš
ããŠãã¹ãããŠã ååç©ãå«æããææåå容局
ã¯ãïŒm2ã«ã€ããŠ65ïœã®æ¹¿æœ€è¢«èŠçã§äžèšçµæç©
ããéæãªäžå¡ãããããªãšãã¬ã³ãã¬ãã¿ã¬ãŒ
ãäžã«è¢«èŠããã èžæºæ°Ž 656ml ãŒã©ãã³ 72ïœ æ¹¿æœ€å€ãšããŠCF3ïŒCF2ïŒ8COONH4ã®ïŒïŒ 氎溶
液 10ml ãããµãã·ã«ããªããšãã«ãã¹ãããŠã ããã
ã€ãã®8.8ïŒ æº¶æ¶² 250ml ãã«ã ã¢ã«ãããïŒïŒ 氎溶液 10ml ãããµãã·ã«ããªããšãã«ãã¹ãããŠã ããã
ã€ã溶液ã¯ã22ïœã®äžèšååç©ã100mlã®ãšã¿ã
ãŒã«ã«æº¶è§£ãã次ãã§æ°Žã250mlã«ãªããŸã§å ã
ãŠäœã€ãã 也ç¥ããææåå容局äžã«äžèšçµæç©ãã40
ïœïŒm2ã®æ¹¿æœ€è¢«èŠçã§è¢«èŠããã
ãè¡šã
(2) æ¬çºæã«ããå容äœææã®è£œé ã
çŸåæ žå«æå±€ãäžèšçµæç©ãã48ïœïŒm2ã®æ¹¿æœ€
被èŠçã§è¢«èŠãã以å€ã¯æ¯èŒææãšåããå容
äœææãäœã€ãã
被èŠçã§è¢«èŠãã以å€ã¯æ¯èŒææãšåããå容
äœææãäœã€ãã
ãè¡šã
(3) åŠçã
éé²å
æå
æ§ãã¬åããã²ã³åéä¹³å€ææã³ã
ã©ããïŒCOPYRAPIDïŒãã«ã®ãŒåœã¢ãŒããŒãŒ
ã«ã®ã¢ã°ãã¢ã»ã²ãŽãšã«ãã»ãšãã»ãŽã€ã®åæš
åïŒãçšãåãæ¡ä»¶ã§æ¯èŒå容äœææãšæ¬çºæ
ã«ããå容äœææãæ¡æ£è»¢ååŠçããã åŠçã¯ãã¢ã³ãã¬ã»ãããããã³ãšãã€ã¹ã»ãŠ
ãšã€ãèããªãŒã«ã«ã»ãã¬ã¹ïŒãã³ãã³âããŠãŒ
ãšãŒã¯ïŒ1972幎çºè¡ãããªãã°ã©ãã€ãã¯ã»ã·ã«
ããŒã»ãã©ã€ãã»ãã€ããŠãŒãžãšã³ã»ããã»ã·
ãºãã®ç¬¬255é ã®ç¬¬ïŒã»ïŒïŒå³ã«ç€ºãããŠããå
ã®åžè²©ã®æ¡æ£è»¢ååŠçè£ çœ®ã§è¡ãªã€ãã åŠç溶液ã¯äžèšçµæãæããŠããã èžæºæ°Ž 800ml ããããã·ãšãã«ã»ã«ããŒã¹ ïŒïœ æ°Žé žåãããªãŠã 15ïœ ãã³ãžã«ã¢ã«ã³ãŒã« 10ml ãã©ãã«ã ã¢ã«ããã ïŒïœ ããªç¡«é žãããªãŠã ïŒç¡æ°ŽïŒ 10ïœ èåãããªãŠã ïŒïœ ïŒâããšãã«âïŒâããã©ãŸãªã³âïŒâããªã³
ã®ïŒïŒ ãšã¿ããŒã«æº¶æ¶² ïŒml çŸåæ žå«æå±€äžã«ææ©ã¢ããªã³æ§ååç©ãå«æ
ããªãå容äœææã«ãããŠåŸãããçŸåã¯è€è²
ãæãããã¹ãã¹ïŒMACBETHãåååïŒã¢ã
ã«TDâ102埮枬å å 床èšã§çœè²å ã§æž¬å®ããå
åŠå¯åºŠã¯0.14ã«ãããªãã€ãã æ¬çºæã«ããå容äœææã«åŸãããéåã¯é»
è²ã§ãããæ¯èŒææã«ã€ããŠã®ãšåãæ¡ä»¶äžã§
2.95ã®å åŠå¯åºŠãæããŠããã æ¯èŒææã§æž¬å®ããéã®éã¯0.120ïœïŒm2ã§
ãã€ãããäžæ¹æ¬çºæã«ããå容äœææã§ã¯
0.917ïœïŒm2ã®éãå«æããŠããã é²å ãçŸåããããã²ã³åéä¹³å€ææããåé¢
ããåŸãå容äœææã¯ã転åããçŸåå€ã«ããæ±
æïŒçŒãïŒãé²ãããå®å®å溶液ã§åŠçããŠãã
ãããã®ããã«å¥œé©ãªå®å®å溶液ã¯ãšã¿ããŒã«ãš
æ°Žã®æ··åç©ã«æº¶è§£ããç¡Œé žãšããªãšãã¬ã³ã€ãã³
ãå«æããã å®æœäŸ ïŒ å®æœäŸïŒã®å容äœææã®è£œé ãç¹°è¿ãããã
ãããªãããçŸåæ žå«æå±€ã¯48ïœïŒm2ã®æ¹¿æœ€è¢«èŠ
çã§äžèšçµæç©ãã被èŠããã
ã©ããïŒCOPYRAPIDïŒãã«ã®ãŒåœã¢ãŒããŒãŒ
ã«ã®ã¢ã°ãã¢ã»ã²ãŽãšã«ãã»ãšãã»ãŽã€ã®åæš
åïŒãçšãåãæ¡ä»¶ã§æ¯èŒå容äœææãšæ¬çºæ
ã«ããå容äœææãæ¡æ£è»¢ååŠçããã åŠçã¯ãã¢ã³ãã¬ã»ãããããã³ãšãã€ã¹ã»ãŠ
ãšã€ãèããªãŒã«ã«ã»ãã¬ã¹ïŒãã³ãã³âããŠãŒ
ãšãŒã¯ïŒ1972幎çºè¡ãããªãã°ã©ãã€ãã¯ã»ã·ã«
ããŒã»ãã©ã€ãã»ãã€ããŠãŒãžãšã³ã»ããã»ã·
ãºãã®ç¬¬255é ã®ç¬¬ïŒã»ïŒïŒå³ã«ç€ºãããŠããå
ã®åžè²©ã®æ¡æ£è»¢ååŠçè£ çœ®ã§è¡ãªã€ãã åŠç溶液ã¯äžèšçµæãæããŠããã èžæºæ°Ž 800ml ããããã·ãšãã«ã»ã«ããŒã¹ ïŒïœ æ°Žé žåãããªãŠã 15ïœ ãã³ãžã«ã¢ã«ã³ãŒã« 10ml ãã©ãã«ã ã¢ã«ããã ïŒïœ ããªç¡«é žãããªãŠã ïŒç¡æ°ŽïŒ 10ïœ èåãããªãŠã ïŒïœ ïŒâããšãã«âïŒâããã©ãŸãªã³âïŒâããªã³
ã®ïŒïŒ ãšã¿ããŒã«æº¶æ¶² ïŒml çŸåæ žå«æå±€äžã«ææ©ã¢ããªã³æ§ååç©ãå«æ
ããªãå容äœææã«ãããŠåŸãããçŸåã¯è€è²
ãæãããã¹ãã¹ïŒMACBETHãåååïŒã¢ã
ã«TDâ102埮枬å å 床èšã§çœè²å ã§æž¬å®ããå
åŠå¯åºŠã¯0.14ã«ãããªãã€ãã æ¬çºæã«ããå容äœææã«åŸãããéåã¯é»
è²ã§ãããæ¯èŒææã«ã€ããŠã®ãšåãæ¡ä»¶äžã§
2.95ã®å åŠå¯åºŠãæããŠããã æ¯èŒææã§æž¬å®ããéã®éã¯0.120ïœïŒm2ã§
ãã€ãããäžæ¹æ¬çºæã«ããå容äœææã§ã¯
0.917ïœïŒm2ã®éãå«æããŠããã é²å ãçŸåããããã²ã³åéä¹³å€ææããåé¢
ããåŸãå容äœææã¯ã転åããçŸåå€ã«ããæ±
æïŒçŒãïŒãé²ãããå®å®å溶液ã§åŠçããŠãã
ãããã®ããã«å¥œé©ãªå®å®å溶液ã¯ãšã¿ããŒã«ãš
æ°Žã®æ··åç©ã«æº¶è§£ããç¡Œé žãšããªãšãã¬ã³ã€ãã³
ãå«æããã å®æœäŸ ïŒ å®æœäŸïŒã®å容äœææã®è£œé ãç¹°è¿ãããã
ãããªãããçŸåæ žå«æå±€ã¯48ïœïŒm2ã®æ¹¿æœ€è¢«èŠ
çã§äžèšçµæç©ãã被èŠããã
ãè¡šã
ãè¡šã
å®æœäŸïŒã®å容äœææãšæ¯èŒããŠããã®å容
äœææãçšããŠãå®æœäŸïŒã«èšèŒãããã®ãšåæ§
ã®æ¹è¯ãããçµæãåŸãããã å®æœäŸ ïŒ å®æœäŸïŒã«ãã€ãŠé»çœéåã圢æããå容äœæ
æãã次ã®åŠãæ§æããåã«å¿ããŠé²å ããæ
å æ§æææ¡æ£è»¢åææïŒãšçµåããŠå容äœææãš
ããŠäœ¿çšããã äž¡åŽã15ïœïŒm2ã®ããªãšãã¬ã³å±€ã§è¢«èŠãã
110ïœïŒm2ã®çŽã·ãŒããããªãäžå¡ãããèæ°Žæ§
çŽæ¯æäœããã³ããæŸé»åŠçãããã®äžã«äžèšã®
åå±€ãäžèšé åºã§ãææïŒm2ã«ã€ããŠäžèšã®éã§
被èŠããã (1) ç¡«åéæ ž 20mg ïŒâããšãã«âïŒâã¡ãã«âïŒâãã©ãŸãªãž
ãã³ 150mg ããŒã³ã¿æææŸåºæ§ååç©M3ïŒæ§é åŒåŸè¿°
ãïŒ 800mg ãŒã©ãã³ ïŒmg ã也ç¥åŸå«æããéæ²æŸ±æ§å±€ïŒ (2) 2.5ïœã®ãŒã©ãã³ã2.6ïœã®ãªã¯ã¿ãã·ã«ãã€
ããããã³ã¹ã«ãã³é žããã³é1.1ïœã«çžåœã
ãéã®å¡©åéãå«æããç·è²æå æ§ãã¬äœçšæ§
ãŒã©ãã³å¡©åéä¹³å€ïŒ (3) ïŒïœã®ãŒã©ãã³ãå«æããä¿è·å±€ã ææïŒã¯ç·è²ãã€ã«ã¿ãŒãçµåããå€è²éæç»
ãä»ããŠåãé²å ããã é²å åŸåŠçããææããã³ïŒããäžèšã®åŠç
液ãå«æããã³ããã«ãŒãCP38
ïŒCOPYPROOFCP38ãåååïŒæ¡æ£è»¢ååŠçè£
眮äžã§æ¥è§ŠãããŠæææ¡æ£è»¢åãããã æ°Žé žåãããªãŠã 15ïœ ããããã·ãšãã«ã»ã«ããŒã¹ ïŒïœ ãã³ãžã«ã¢ã«ã³ãŒã« 10ïœ ãã©ãã«ã ã¢ã«ããã ïŒïœ ç¡æ°Žããªç¡«é žãããªãŠã 10ïœ èåãããªãŠã ïŒïœ 氎㧠ïŒãšããã ïŒåéæ¥è§ŠãããåŸãå容ææãåçææïŒ
ããå¥é¢ããæŽæµãã也ç¥ãããæ¢ã«çŸåæ žå±€äž
ã«é»çœéåãå«æããŠããå容äœææã®åªæå±€
äžã«ããŒã³ã¿ææåãåŸãããã æå æ§æææ¡æ£è»¢åææãæ¢ã«éåããã³äž
è¿°ããããŒã³ã¿ææåãå«æããå容äœææãš
çµåããŠé²å ã䜿çšããã ææã¯æ¬¡ã®ãšããã«æ§æããïŒéã¯ïŒm2ã«ã€
ããŠè¡šãããŠããïŒã (1) ç¡«åéæ ž 0.02ïœ ïŒâããšãã«âïŒâã¡ãã«âïŒâãã©ãŸãªãž
ãã³ 0.15ïœ ã·ã¢ã³æææŸåºæ§ååç©C3ïŒæ§é åŒåŸè¿°ãïŒ
ïŒïœ ãŒã©ãã³ ïŒïœ ã也ç¥åŸå«æããéæ²æŸ±æ§å±€ïŒ (2) 2.5ïœã®ãŒã©ãã³ã3.1ïœã®ãªã¯ã¿ãã·ã«ãã€
ããããã³ã¹ã«ãã³é žããã³é1.3ïœã«çžåœã
ãéã®å¡©åéãå«æããèµ€è²æå æ§ãã¬äœçšæ§
ãŒã©ãã³âå¡©åéä¹³å€ïŒ (3) ïŒïœã®ãŒã©ãã³ãå«æããä¿è·å±€ã äžè¿°ããé åºã§äžè¿°ããçŽæ¯æäœã«è¢«èŠããã ææã®é²å ã¯ææïŒã«ã€ããŠè¡ãªã€ãã®ãšå
æ§ã«ããŠè¡ãªã€ãããã ãèµ€è²ãã€ã«ã¿ãŒãä»ã
ãŠè¡ãªã€ããææ転åã®æ¹æ³ã¯ææïŒã«å¯Ÿããã®
ãšåãã§ãã€ããçŸåæ žå«æå±€äžã«é»çœéåãã
ã³åªæå±€äžã«ããŒã³ã¿ææåãæ¢ã«å«æããŠãã
å容äœææã®åªæå±€äžã«ã·ã¢ã³ææåãåŸãã
ãã æå æ§æææ¡æ£è»¢åææããæ¢ã«éåããã³
äžèšåãã€ãŠåœ¢æããããŒã³ã¿ããã³ã·ã¢ã³ææ
åãå«æããå容äœææãšçµåããŠé²å ãã䜿
çšããã ææã¯æ¬¡ã®åŠãæ§æããïŒéã¯ïŒm2ã«ã€ããŠ
è¡šãããŠããïŒã (1) ç¡«åéæ ž 0.02ïœ ïŒâããšãã«âïŒâã¡ãã«âïŒâãã©ãŸãªãž
ãã³ 0.15ïœ é»è²æææŸåºæ§ååç©Y3ïŒæ§é åŒåŸè¿°ãïŒ
ïŒïœ ãŒã©ãã³ ïŒïœ ã也ç¥åŸå«æããéæ²æŸ±æ§å±€ïŒ (2) 2.5ïœã®ãŒã©ãã³ã3.6ïœã®ãªã¯ã¿ãã·ã«ãã€
ããããã³ã¹ã«ãã³é žããã³é1.6ïœã«çžåœã
ãéã®å¡©åéãå«æããéè²æå æ§ãã¬äœçšæ§
ãŒã©ãã³å¡©åéä¹³å€ïŒ (3) ãŒã©ãã³ïŒïœãå«æããä¿è·å±€ã äžè¿°ããé åºã§åè¿°ããçŽæ¯æäœã«è¢«èŠããã ææã®åã«å¿ããé²å ã¯ææïŒã«å¯Ÿããã®ãš
åãã«è¡ãªã€ãããã ãéè²ãã€ã«ã¿ãŒãä»ããŠ
è¡ãªã€ããææ転åã®æ¹æ³ã¯ææïŒããã³ïŒ£ãšå
ãã§ãã€ããåªæå±€äžã«ã·ã¢ã³ææåããã³ããŒ
ã³ã¿ææåãããããŠçŸåæ žå«æå±€äžã«é»çœéå
ãæ¢ã«å«æããŠããå容äœææã®åªæå±€äžã«é»
è²ææåãåŸãããã åãå容äœææäžã«å ãææåã圢æããæ
åŸã®åãšããŠé»çœåã圢æããããšã«ãã€ãŠåã
çµæãåŸãããã ãŠã«ãã©ãã³ïŒ·ïŒULTRAVON ïŒåååïŒ
ã®ä»£ãã«åãã¢ã«éã§åè¿°ããä»ã®åžè²©ã®ã¢ããª
ã³æ§ææ©çé¢æŽ»æ§å€ãçšããŠå®è³ªçã«åãçµæã
åŸãããã ååç© M3 ïŒå ¬åããããã€ãç¹èš±åºé¡ç¬¬75ïŒ01348å·ã«
èšèŒãããŠããåŠãããŠäœã€ãïŒã ååç© C3 ïŒç±³åœç¹èš±ç¬¬3929760å·ã«èšèŒãããŠããåŠã
ããŠäœã€ãïŒã ååç© Y3 ïŒç±³åœç¹èš±ç¬¬3929760å·ã«èšèŒãããŠããåŠã
ããŠäœã€ãïŒã
äœææãçšããŠãå®æœäŸïŒã«èšèŒãããã®ãšåæ§
ã®æ¹è¯ãããçµæãåŸãããã å®æœäŸ ïŒ å®æœäŸïŒã«ãã€ãŠé»çœéåã圢æããå容äœæ
æãã次ã®åŠãæ§æããåã«å¿ããŠé²å ããæ
å æ§æææ¡æ£è»¢åææïŒãšçµåããŠå容äœææãš
ããŠäœ¿çšããã äž¡åŽã15ïœïŒm2ã®ããªãšãã¬ã³å±€ã§è¢«èŠãã
110ïœïŒm2ã®çŽã·ãŒããããªãäžå¡ãããèæ°Žæ§
çŽæ¯æäœããã³ããæŸé»åŠçãããã®äžã«äžèšã®
åå±€ãäžèšé åºã§ãææïŒm2ã«ã€ããŠäžèšã®éã§
被èŠããã (1) ç¡«åéæ ž 20mg ïŒâããšãã«âïŒâã¡ãã«âïŒâãã©ãŸãªãž
ãã³ 150mg ããŒã³ã¿æææŸåºæ§ååç©M3ïŒæ§é åŒåŸè¿°
ãïŒ 800mg ãŒã©ãã³ ïŒmg ã也ç¥åŸå«æããéæ²æŸ±æ§å±€ïŒ (2) 2.5ïœã®ãŒã©ãã³ã2.6ïœã®ãªã¯ã¿ãã·ã«ãã€
ããããã³ã¹ã«ãã³é žããã³é1.1ïœã«çžåœã
ãéã®å¡©åéãå«æããç·è²æå æ§ãã¬äœçšæ§
ãŒã©ãã³å¡©åéä¹³å€ïŒ (3) ïŒïœã®ãŒã©ãã³ãå«æããä¿è·å±€ã ææïŒã¯ç·è²ãã€ã«ã¿ãŒãçµåããå€è²éæç»
ãä»ããŠåãé²å ããã é²å åŸåŠçããææããã³ïŒããäžèšã®åŠç
液ãå«æããã³ããã«ãŒãCP38
ïŒCOPYPROOFCP38ãåååïŒæ¡æ£è»¢ååŠçè£
眮äžã§æ¥è§ŠãããŠæææ¡æ£è»¢åãããã æ°Žé žåãããªãŠã 15ïœ ããããã·ãšãã«ã»ã«ããŒã¹ ïŒïœ ãã³ãžã«ã¢ã«ã³ãŒã« 10ïœ ãã©ãã«ã ã¢ã«ããã ïŒïœ ç¡æ°Žããªç¡«é žãããªãŠã 10ïœ èåãããªãŠã ïŒïœ 氎㧠ïŒãšããã ïŒåéæ¥è§ŠãããåŸãå容ææãåçææïŒ
ããå¥é¢ããæŽæµãã也ç¥ãããæ¢ã«çŸåæ žå±€äž
ã«é»çœéåãå«æããŠããå容äœææã®åªæå±€
äžã«ããŒã³ã¿ææåãåŸãããã æå æ§æææ¡æ£è»¢åææãæ¢ã«éåããã³äž
è¿°ããããŒã³ã¿ææåãå«æããå容äœææãš
çµåããŠé²å ã䜿çšããã ææã¯æ¬¡ã®ãšããã«æ§æããïŒéã¯ïŒm2ã«ã€
ããŠè¡šãããŠããïŒã (1) ç¡«åéæ ž 0.02ïœ ïŒâããšãã«âïŒâã¡ãã«âïŒâãã©ãŸãªãž
ãã³ 0.15ïœ ã·ã¢ã³æææŸåºæ§ååç©C3ïŒæ§é åŒåŸè¿°ãïŒ
ïŒïœ ãŒã©ãã³ ïŒïœ ã也ç¥åŸå«æããéæ²æŸ±æ§å±€ïŒ (2) 2.5ïœã®ãŒã©ãã³ã3.1ïœã®ãªã¯ã¿ãã·ã«ãã€
ããããã³ã¹ã«ãã³é žããã³é1.3ïœã«çžåœã
ãéã®å¡©åéãå«æããèµ€è²æå æ§ãã¬äœçšæ§
ãŒã©ãã³âå¡©åéä¹³å€ïŒ (3) ïŒïœã®ãŒã©ãã³ãå«æããä¿è·å±€ã äžè¿°ããé åºã§äžè¿°ããçŽæ¯æäœã«è¢«èŠããã ææã®é²å ã¯ææïŒã«ã€ããŠè¡ãªã€ãã®ãšå
æ§ã«ããŠè¡ãªã€ãããã ãèµ€è²ãã€ã«ã¿ãŒãä»ã
ãŠè¡ãªã€ããææ転åã®æ¹æ³ã¯ææïŒã«å¯Ÿããã®
ãšåãã§ãã€ããçŸåæ žå«æå±€äžã«é»çœéåãã
ã³åªæå±€äžã«ããŒã³ã¿ææåãæ¢ã«å«æããŠãã
å容äœææã®åªæå±€äžã«ã·ã¢ã³ææåãåŸãã
ãã æå æ§æææ¡æ£è»¢åææããæ¢ã«éåããã³
äžèšåãã€ãŠåœ¢æããããŒã³ã¿ããã³ã·ã¢ã³ææ
åãå«æããå容äœææãšçµåããŠé²å ãã䜿
çšããã ææã¯æ¬¡ã®åŠãæ§æããïŒéã¯ïŒm2ã«ã€ããŠ
è¡šãããŠããïŒã (1) ç¡«åéæ ž 0.02ïœ ïŒâããšãã«âïŒâã¡ãã«âïŒâãã©ãŸãªãž
ãã³ 0.15ïœ é»è²æææŸåºæ§ååç©Y3ïŒæ§é åŒåŸè¿°ãïŒ
ïŒïœ ãŒã©ãã³ ïŒïœ ã也ç¥åŸå«æããéæ²æŸ±æ§å±€ïŒ (2) 2.5ïœã®ãŒã©ãã³ã3.6ïœã®ãªã¯ã¿ãã·ã«ãã€
ããããã³ã¹ã«ãã³é žããã³é1.6ïœã«çžåœã
ãéã®å¡©åéãå«æããéè²æå æ§ãã¬äœçšæ§
ãŒã©ãã³å¡©åéä¹³å€ïŒ (3) ãŒã©ãã³ïŒïœãå«æããä¿è·å±€ã äžè¿°ããé åºã§åè¿°ããçŽæ¯æäœã«è¢«èŠããã ææã®åã«å¿ããé²å ã¯ææïŒã«å¯Ÿããã®ãš
åãã«è¡ãªã€ãããã ãéè²ãã€ã«ã¿ãŒãä»ããŠ
è¡ãªã€ããææ転åã®æ¹æ³ã¯ææïŒããã³ïŒ£ãšå
ãã§ãã€ããåªæå±€äžã«ã·ã¢ã³ææåããã³ããŒ
ã³ã¿ææåãããããŠçŸåæ žå«æå±€äžã«é»çœéå
ãæ¢ã«å«æããŠããå容äœææã®åªæå±€äžã«é»
è²ææåãåŸãããã åãå容äœææäžã«å ãææåã圢æããæ
åŸã®åãšããŠé»çœåã圢æããããšã«ãã€ãŠåã
çµæãåŸãããã ãŠã«ãã©ãã³ïŒ·ïŒULTRAVON ïŒåååïŒ
ã®ä»£ãã«åãã¢ã«éã§åè¿°ããä»ã®åžè²©ã®ã¢ããª
ã³æ§ææ©çé¢æŽ»æ§å€ãçšããŠå®è³ªçã«åãçµæã
åŸãããã ååç© M3 ïŒå ¬åããããã€ãç¹èš±åºé¡ç¬¬75ïŒ01348å·ã«
èšèŒãããŠããåŠãããŠäœã€ãïŒã ååç© C3 ïŒç±³åœç¹èš±ç¬¬3929760å·ã«èšèŒãããŠããåŠã
ããŠäœã€ãïŒã ååç© Y3 ïŒç±³åœç¹èš±ç¬¬3929760å·ã«èšèŒãããŠããåŠã
ããŠäœã€ãïŒã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ (i) æ¯æäœ (ii) é žæ§ææãåªæããããšã®ã§ããææ©ãªããŠ
ã ååç©ãå«æãã第äžææ©èŠªæ°Žæ§ã³ãã€ã
å±€ãããã³ (iii) éé¯å¡©ã®éãžã®éå ãæ¥è§Šäœçšããããã®çŸ
åæ žãå«æããéæ第äºææ©èŠªæ°Žæ§ã³ãã€ãå±€ ãå«æããææ転åããã³éé¯å¡©æ¡æ£è»¢åæ³ã«äœ¿
çšããã®ã«å¥œé©ãªéæå æ§å容äœææã«ãããŠã
äžèšææããŸãäžèšå±€(iii)äžããã³ïŒãŸãã¯å±€(ii)ãš
(iii)ã®éã®èŠªæ°Žæ§ã³ãã€ãäžéå±€äžã«ãççŽ ååã«
çµåããã¢ããªã³æ§åºãæããææ©ååç©ã®å°ãª
ããšãïŒçš®ãå«æããããšãç¹åŸŽãšããéæå æ§
å容äœææã ïŒ äžèšææ©ååç©ãã¹ã«ãããŒãåºãŸãã¯ãµã«
ããšãŒãåºãå«æããã¢ããªã³æ§ææ©çé¢æŽ»æ§å€
ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®å容äœææã ïŒ ã¢ããªã³æ§ææ©ååç©ããã®æ§é äžã«å°ãªã
ãšã12åã®é£ç¶ççŽ ååã®éäžæççŽ éãæãã
ç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®å容äœææã ïŒ ã¢ããªã³æ§ææ©ååç©ããã¢ã«ãã«ã¹ã«ãã
ãŒããã¢ã«ã«ãªãŒã«ã¹ã«ãããŒããã¢ã«ãã«ããš
ããŒã«ããªã°ãªã³ãŒã«ãšãŒãã«ã¹ã«ãããŒããã
ãããã·ã¢ã«ã«ã³ã¹ã«ãããŒããèèªé žã¿ãŠã©ã€
ãååç©ãã¹ã«ããã¯ãé žãšã¹ãã«ãäžçŽããã³
äºçŽã¢ã«ãã«ãµã«ããšãŒãããµã«ããšãŒãåããª
ã°ãªã³ãŒã«ãšãŒãã«ããµã«ããšãŒãåã¢ã«ãã«ã
ãšããŒã«ããªã°ãªã³ãŒã«ãšãŒãã«ããã³æ²¹ããã³
èèªã®ç¡«é žãšã¹ãã«ãããªã矀ããéžæããäžå¡
ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã第ïŒé ã®äœããäž
ã€ã«èšèŒã®å容äœææã ïŒ äžèšææ©ååç©ããå±€(ii)äžã«ååšããé žæ§æ
æåªææ§ååç©ã«å¯ŸããŠïŒã100ééïŒ ã«çžåœã
ãéã§å±€(iii)äžã«ååšããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã
第ïŒé ã®äœããäžã€ã«èšèŒã®å容äœææã ïŒ ã«ããªã³æ§é žæ§ææåªææ§ååç©ã0.5ãïŒ
ïœïŒm2ã®éã§å±€(ii)äžã«ååšããç¹èš±è«æ±ã®ç¯å²ç¬¬
ïŒé ã第ïŒé ã®äœããäžã€ã«èšèŒã®å容äœææã ïŒ çŸåæ žãããã±ã«ãŸãã¯éã®ç¡«åç©ãŸãã¯ã
ããã®æ··åç¡«åç©ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã
第ïŒé ã®äœããäžã€ã«èšèŒã®å容äœææã ïŒ æ¯æäœãå åå°å±€ãæ æããæš¹èæ¯æäœã§ã
ãç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã第ïŒé ã®äœããäžã€ã«
èšèŒã®å容äœææã
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB7902551 | 1979-01-24 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS55133043A JPS55133043A (en) | 1980-10-16 |
| JPS637378B2 true JPS637378B2 (ja) | 1988-02-16 |
Family
ID=10502710
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP560580A Granted JPS55133043A (en) | 1979-01-24 | 1980-01-21 | Nonnphotosensitive acceptor material suitable for producing black*white*silver image and dye image* and produsing images using same |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US4288522A (ja) |
| EP (1) | EP0014008B1 (ja) |
| JP (1) | JPS55133043A (ja) |
| CA (1) | CA1132826A (ja) |
| DE (1) | DE3061117D1 (ja) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5948369B2 (ja) * | 1980-06-11 | 1984-11-26 | ã³ãã«æ ªåŒäŒç€Ÿ | åçç»å圢ææ¹æ³ |
| JPS61167949A (ja) * | 1985-01-22 | 1986-07-29 | Fuji Photo Film Co Ltd | éå¡©æ¡æ£è»¢åæ³åçèŠçŽ |
| JPS61281237A (ja) * | 1985-06-07 | 1986-12-11 | Fuji Photo Film Co Ltd | éå¡©æ¡æ£è»¢åæ³åçèŠçŽ |
| EP0261280B1 (en) * | 1986-09-23 | 1990-06-06 | Agfa-Gevaert N.V. | Diffusion transfer imaging method and receptor sheet for making personal identification documents |
| JPS63271257A (ja) * | 1987-04-30 | 1988-11-09 | Fuji Photo Film Co Ltd | éå¡©æ¡æ£è»¢åã«ããç»å圢ææ¹æ³ |
| EP0290077B1 (en) * | 1987-05-06 | 1995-07-05 | Agfa-Gevaert N.V. | A method for processing a photographic material |
| EP0380814B1 (en) * | 1989-01-31 | 1994-08-03 | Agfa-Gevaert N.V. | Process for the production of a laminar article |
| JP2896449B2 (ja) * | 1992-01-30 | 1999-05-31 | å¯å£«åçãã€ã«ã æ ªåŒäŒç€Ÿ | è²çŽ åºå®èŠçŽ |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3034890A (en) * | 1955-05-31 | 1962-05-15 | Polaroid Corp | Color formation |
| BE561463A (ja) * | 1956-10-09 | |||
| DE1070029B (ja) * | 1958-03-31 | 1959-11-26 | ||
| US2983606A (en) * | 1958-07-14 | 1961-05-09 | Polaroid Corp | Processes and products for forming photographic images in color |
| US3203796A (en) * | 1962-04-27 | 1965-08-31 | Gevaert Photo Prod Nv | Use of starch ether layers in diffusion transfer processes |
| US3435761A (en) * | 1966-05-10 | 1969-04-01 | Eastman Kodak Co | Premordanted imbibition dye printing blank |
| DE1931122C3 (de) * | 1968-06-20 | 1974-04-25 | Fuji Photo Film Co. Ltd., Ashigara, Kanagawa (Japan) | Photographischer Farbentwickler |
| UST878006I4 (en) * | 1970-01-14 | 1970-09-08 | Defensive publication | |
| US3635707A (en) * | 1970-07-24 | 1972-01-18 | Harold E Cole | Diffusion transfer products adapted for multiple application of processing composition and/or opacifier and processes for their use |
| US3787209A (en) * | 1972-04-24 | 1974-01-22 | Polaroid Corp | Color diffusion transfer color process and film with silver precipitating layer |
| FR2309901A1 (fr) * | 1975-05-02 | 1976-11-26 | Kodak Pathe | Procede et produit pour l'obtention d'images photographiques par diffusion-transfert |
-
1980
- 1980-01-02 CA CA342,915A patent/CA1132826A/en not_active Expired
- 1980-01-11 DE DE8080200024T patent/DE3061117D1/de not_active Expired
- 1980-01-11 EP EP80200024A patent/EP0014008B1/en not_active Expired
- 1980-01-21 JP JP560580A patent/JPS55133043A/ja active Granted
- 1980-01-22 US US06/114,082 patent/US4288522A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP0014008B1 (en) | 1982-11-24 |
| US4288522A (en) | 1981-09-08 |
| DE3061117D1 (en) | 1982-12-30 |
| CA1132826A (en) | 1982-10-05 |
| JPS55133043A (en) | 1980-10-16 |
| EP0014008A1 (en) | 1980-08-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPS60122940A (ja) | åçèŠçŽ | |
| US4144064A (en) | Photographic material for use in the silver complex diffusion transfer process | |
| US3384483A (en) | Multicolor dye developer image transfer systems | |
| US2698244A (en) | Photographic transfer process utilizing a primary color developer for producing a colored photographic transfer image | |
| JPS637378B2 (ja) | ||
| US3625685A (en) | Photographic color diffusion-transfer element comprising aqueous film-forming synthetic polymer suspension layers intermediate its sensitive layers and processes for their use | |
| US3607269A (en) | Image-receiving elements and photographic processes employing same | |
| US3985561A (en) | Diffusion transfer process using silver halide emulsions with 90% chloride and high binder to silver halide ratios | |
| US4009031A (en) | Diffusion transfer image-receiving element having polyvinylpyridine layer treated with hydrophilic colloid/ammonia solution | |
| US3345168A (en) | Diffusion transfer receiving sheet containing china clay and an aliphatic amine | |
| JPS6332375B2 (ja) | ||
| EP0290077B1 (en) | A method for processing a photographic material | |
| US3418117A (en) | Multicolor dye developer image transfer systems | |
| US3335005A (en) | Silver complex diffusion transfer process | |
| US3765889A (en) | Silver transfer diffusion process | |
| US3620728A (en) | Receiving sheet for diffusion transfer processes | |
| US3709687A (en) | Diffusion transfer receiving element with varing concentration of precipitating nuclei | |
| US4224402A (en) | Photographic material for use in the silver complex diffusion transfer process | |
| US3849131A (en) | Color photographic diffusion transfer process | |
| US3313624A (en) | Photographic products and processes utilizing inorganic chlorates as antifoggants | |
| US5030545A (en) | Method of forming images by silver salt diffusion transfer | |
| US3404002A (en) | Interimage characteristics of silver halide dye developer image transfer systems | |
| US3535114A (en) | Azoniaanthracene dye developing agents in diffusion transfer | |
| JPS5933891B2 (ja) | éé¯å¡©æ¡æ£è»¢åçšææ | |
| JP2539959B2 (ja) | éé¯å¡©æ¡æ£è»¢åååææ |