JPS6367474B2 - - Google Patents
Info
- Publication number
- JPS6367474B2 JPS6367474B2 JP57039058A JP3905882A JPS6367474B2 JP S6367474 B2 JPS6367474 B2 JP S6367474B2 JP 57039058 A JP57039058 A JP 57039058A JP 3905882 A JP3905882 A JP 3905882A JP S6367474 B2 JPS6367474 B2 JP S6367474B2
- Authority
- JP
- Japan
- Prior art keywords
- vinyl chloride
- pigment
- parts
- resin
- chloride resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000011347 resin Substances 0.000 claims description 20
- 229920005989 resin Polymers 0.000 claims description 20
- 239000000049 pigment Substances 0.000 claims description 18
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 16
- 239000000463 material Substances 0.000 claims description 10
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 6
- 229910052709 silver Inorganic materials 0.000 claims description 6
- 239000004332 silver Substances 0.000 claims description 6
- 239000011248 coating agent Substances 0.000 claims description 5
- 238000000576 coating method Methods 0.000 claims description 5
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052737 gold Inorganic materials 0.000 claims description 3
- 239000010931 gold Substances 0.000 claims description 3
- 239000002932 luster Substances 0.000 description 9
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000004088 foaming agent Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- -1 Usually Substances 0.000 description 1
- 239000004156 Azodicarbonamide Substances 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical compound NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 description 1
- 235000019399 azodicarbonamide Nutrition 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000009408 flooring Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000003760 hair shine Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
Description
【発明の詳細な説明】
本発明は壁紙もしくは床材等の化粧材に関し、
更に詳しくは金色光沢、銀色光沢あるいはパール
光沢を有する化粧材に関する。[Detailed description of the invention] The present invention relates to decorative materials such as wallpaper or flooring materials,
More specifically, the present invention relates to a decorative material having golden luster, silver luster, or pearl luster.
従来、金色光沢、銀色光沢、あるいはパール光
沢等の光沢を有する化粧材を製造するには基材に
コーテイングし、ゲル化させた塩化ビニル樹脂上
に対応するそれぞれの顔料、すなわち金色顔料、
銀色顔料あるいはパール顔料をインキに混合して
印刷するか、もしくは塩化ビニル樹脂に混合して
コーテイングするのが通常であつた。ところが、
このような光沢を有する顔料は他の顔料と比べて
高価な上、インキの場合の中の樹脂100重量部当
たり30〜50重量部という高濃度に混合した上多量
に（Wetで30ｇ／m2程度）塗布する必要があり、
これより少ないと十分な光沢が得られなかつた。
又コーテイングの場合は樹脂中に30部前後の量を
混合しなければ目的を達しない。 Conventionally, in order to produce cosmetic materials with luster such as golden luster, silver luster, or pearl luster, a base material is coated and a corresponding pigment is coated on a gelled vinyl chloride resin, that is, a golden pigment,
Usually, silver pigments or pearl pigments were mixed with ink for printing, or mixed with vinyl chloride resin for coating. However,
Pigments with such luster are expensive compared to other pigments, and are mixed at a high concentration of 30 to 50 parts by weight per 100 parts by weight of resin in the case of ink . degree) need to be applied,
If the amount is less than this, sufficient gloss cannot be obtained.
In addition, in the case of coating, the purpose cannot be achieved unless approximately 30 parts of the resin is mixed into the resin.
ところで、本発明者は、紙等の基材に塩化ビニ
ル樹脂(A)をコーテイングし、ゲル化させた後、こ
の上に、クリアーな塩化ビニル樹脂(B)に金色顔
料、銀色顔料又はパール顔料を混入したペースト
をコーテイングして成る化粧材は、その顔料の混
合量が、樹脂100重量部当たり２〜３重量部、多
くとも10重量部以下で、前記樹脂100重量部当た
り30〜50重量部混合したインキで印刷したもの及
び樹脂中に30部前後混合してコーテイングしたも
のと同等程度の光沢を有することを発見して本発
明を完成した。この良好な光沢は、塩化ビニル樹
脂(B)がクリアーであるため、顔料による乱反射が
有効に利用できることと、塩化ビニル樹脂(B)自体
の良好な光択に基いていると思われる。この樹脂
(B)には着色したプラスチツク等のくず等を混合す
ることができる。 By the way, the present inventor coated a base material such as paper with vinyl chloride resin (A) and gelled it, and then added gold pigment, silver pigment, or pearl pigment to clear vinyl chloride resin (B). The amount of the pigment mixed is 2 to 3 parts by weight per 100 parts by weight of the resin, and at most 10 parts by weight or less, and 30 to 50 parts by weight per 100 parts by weight of the resin. The present invention was completed by discovering that it has the same level of gloss as those printed with mixed ink and those coated with around 30 parts mixed in resin. This good gloss is thought to be based on the fact that since the vinyl chloride resin (B) is clear, the diffused reflection caused by the pigment can be effectively utilized, and on the good optical selection of the vinyl chloride resin (B) itself. This resin
(B) may be mixed with colored plastic scraps, etc.
また、基材上にコーテイングする塩化ビニル樹
脂(A)は任意の色に着色したもので良いが、金色顔
料を用いる場合には黄色、銀又はパール顔料を用
いる場合にはグレーに着色したものを用いると、
この上にコーテイングしたペーストの光沢が映え
る。 In addition, the vinyl chloride resin (A) coated on the base material may be colored in any color, but if a gold pigment is used, it should be yellow, and if a silver or pearl pigment is used, it should be colored gray. When used,
The gloss of the paste coated on top of this shines.
また、塩化ビニル樹脂(A)には発泡剤を混合して
おくことができ、ペーストをコーテイングすると
共に発泡させ、加圧してエンボス加工することが
でき、このようにエンボスしても、化粧材の光沢
は良好である。 In addition, a foaming agent can be mixed with the vinyl chloride resin (A), and the paste can be coated and foamed, and embossed by applying pressure. The gloss is good.
以下実施例により本発明を説明する。 The present invention will be explained below with reference to Examples.
実施例
壁紙用裏打ち紙に、グレーに着色した下記配合
の塩化ビニルゾル(A)を0.1〜0.15の厚みでコーテ
イングした。Example A wallpaper lining paper was coated with a gray-colored vinyl chloride sol (A) having the following formulation to a thickness of 0.1 to 0.15.
＜塩化ビニルゾル＞
塩化ビニル樹脂 100重量部
可塑剤（ジオクチルフタレート） 60 〃
発泡剤（アゾジカーボンアミド系） ４ 〃
充填剤（炭酸カルシウム） 50 〃
安定剤 ３ 〃
チタン 10 〃
黒色着色剤 微量
上記ゾルをゲル化させた後、下記配合のペース
トを約0.1mmの厚みでコーテイングしながら、塩
化ビニルゾル(A)を発泡させ、同時にエンボスをか
けた。<Vinyl chloride sol> Vinyl chloride resin 100 parts by weight Plasticizer (dioctyl phthalate) 60 〃 Foaming agent (azodicarbonamide type) 4 〃 Filler (calcium carbonate) 50 〃 Stabilizer 3 〃 Titanium 10 〃 Black colorant Trace amount Above sol After gelling, the vinyl chloride sol (A) was foamed while coating with a paste of the following composition to a thickness of about 0.1 mm, and embossing was performed at the same time.
＜ペースト＞
塩化ビニル樹脂 100重量部
可塑剤 50 〃
安定剤 ３ 〃
パール顔料 10 〃
パール顔料は、塩化ビニルゾルの樹脂分とペー
ストの樹脂分の合計量100部当たり４〜５部であ
る。<Paste> Vinyl chloride resin 100 parts by weight Plasticizer 50 Stabilizer 3 Pearl pigment 10 The pearl pigment is used in an amount of 4 to 5 parts per 100 parts of the total resin content of the vinyl chloride sol and the paste.
得られた化粧材は良好なパール光沢と凹凸を有
するものであつた。 The obtained decorative material had good pearlescent luster and unevenness.
Claims (1)
グし、ゲル化させた後、この上に、クリアーな塩
化ビニル樹脂(B)のゾル中に金色顔料、銀色顔料又
はパール顔料を混入したペーストをコーテイング
して成る化粧材。1 After coating a base material such as paper with vinyl chloride resin (A) and gelling it, gold pigment, silver pigment, or pearl pigment is mixed into the clear vinyl chloride resin (B) sol. A decorative material made by coating paste.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3905882A JPS58155951A (en) | 1982-03-12 | 1982-03-12 | Decorative material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3905882A JPS58155951A (en) | 1982-03-12 | 1982-03-12 | Decorative material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58155951A JPS58155951A (en) | 1983-09-16 |
| JPS6367474B2 true JPS6367474B2 (en) | 1988-12-26 |
Family
ID=12542529
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3905882A Granted JPS58155951A (en) | 1982-03-12 | 1982-03-12 | Decorative material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS58155951A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS536385A (en) * | 1976-07-07 | 1978-01-20 | Sanrotsuku Kougiyou Kk | Decorative sheet containing flake |
| JPS536835A (en) * | 1976-07-07 | 1978-01-21 | Matsushita Electric Ind Co Ltd | Flat battery |
| JPS547485A (en) * | 1977-06-20 | 1979-01-20 | Toppan Printing Co Ltd | Vessel |
| JPS5541243A (en) * | 1978-09-18 | 1980-03-24 | Toppan Printing Co Ltd | Multilayer vessel |
| JPS55125167A (en) * | 1979-03-22 | 1980-09-26 | Umehiko:Kk | Production of wall covering material having metallic luster |
-
1982
- 1982-03-12 JP JP3905882A patent/JPS58155951A/en active Granted
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS536385A (en) * | 1976-07-07 | 1978-01-20 | Sanrotsuku Kougiyou Kk | Decorative sheet containing flake |
| JPS536835A (en) * | 1976-07-07 | 1978-01-21 | Matsushita Electric Ind Co Ltd | Flat battery |
| JPS547485A (en) * | 1977-06-20 | 1979-01-20 | Toppan Printing Co Ltd | Vessel |
| JPS5541243A (en) * | 1978-09-18 | 1980-03-24 | Toppan Printing Co Ltd | Multilayer vessel |
| JPS55125167A (en) * | 1979-03-22 | 1980-09-26 | Umehiko:Kk | Production of wall covering material having metallic luster |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS58155951A (en) | 1983-09-16 |
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