JPS6366115A - Composition for oral cavity for deodorizing nicotine - Google Patents
Composition for oral cavity for deodorizing nicotineInfo
- Publication number
- JPS6366115A JPS6366115A JP61210582A JP21058286A JPS6366115A JP S6366115 A JPS6366115 A JP S6366115A JP 61210582 A JP61210582 A JP 61210582A JP 21058286 A JP21058286 A JP 21058286A JP S6366115 A JPS6366115 A JP S6366115A
- Authority
- JP
- Japan
- Prior art keywords
- oil
- tobacco tar
- deodorizing
- group
- zinc
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 45
- 230000001877 deodorizing effect Effects 0.000 title claims abstract description 36
- 210000000214 mouth Anatomy 0.000 title claims abstract 4
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 title abstract 3
- 229960002715 nicotine Drugs 0.000 title abstract 3
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 title abstract 3
- 239000003921 oil Substances 0.000 claims abstract description 48
- 235000019198 oils Nutrition 0.000 claims abstract description 48
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims abstract description 18
- WTWBUQJHJGUZCY-UHFFFAOYSA-N cuminaldehyde Chemical compound CC(C)C1=CC=C(C=O)C=C1 WTWBUQJHJGUZCY-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000001887 acacia decurrens willd. var. dealbata absolute Substances 0.000 claims abstract description 11
- 239000010630 cinnamon oil Substances 0.000 claims abstract description 11
- 239000010648 geranium oil Substances 0.000 claims abstract description 11
- 235000019717 geranium oil Nutrition 0.000 claims abstract description 11
- NVIPUOMWGQAOIT-UHFFFAOYSA-N (E)-7-Hexadecen-16-olide Natural products O=C1CCCCCC=CCCCCCCCCO1 NVIPUOMWGQAOIT-UHFFFAOYSA-N 0.000 claims abstract description 9
- NVIPUOMWGQAOIT-DUXPYHPUSA-N 7-hexadecen-1,16-olide Chemical compound O=C1CCCCC\C=C\CCCCCCCCO1 NVIPUOMWGQAOIT-DUXPYHPUSA-N 0.000 claims abstract description 9
- 239000011592 zinc chloride Substances 0.000 claims abstract description 9
- 235000005074 zinc chloride Nutrition 0.000 claims abstract description 9
- 240000002943 Elettaria cardamomum Species 0.000 claims abstract description 8
- 235000005300 cardamomo Nutrition 0.000 claims abstract description 8
- 150000003751 zinc Chemical class 0.000 claims abstract description 8
- 241000212322 Levisticum officinale Species 0.000 claims abstract description 6
- 239000001645 levisticum officinale Substances 0.000 claims abstract description 6
- WGIWBXUNRXCYRA-UHFFFAOYSA-H trizinc;2-hydroxypropane-1,2,3-tricarboxylate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O WGIWBXUNRXCYRA-UHFFFAOYSA-H 0.000 claims abstract description 6
- 239000011746 zinc citrate Substances 0.000 claims abstract description 6
- 235000006076 zinc citrate Nutrition 0.000 claims abstract description 6
- 229940068475 zinc citrate Drugs 0.000 claims abstract description 6
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000004246 zinc acetate Substances 0.000 claims abstract description 4
- 235000013904 zinc acetate Nutrition 0.000 claims abstract description 4
- 239000003205 fragrance Substances 0.000 claims description 86
- 235000002637 Nicotiana tabacum Nutrition 0.000 claims description 53
- 241000208125 Nicotiana Species 0.000 claims description 51
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 claims description 23
- 239000000341 volatile oil Substances 0.000 claims description 22
- OSWPMRLSEDHDFF-UHFFFAOYSA-N methyl salicylate Chemical compound COC(=O)C1=CC=CC=C1O OSWPMRLSEDHDFF-UHFFFAOYSA-N 0.000 claims description 21
- 239000004615 ingredient Substances 0.000 claims description 20
- 239000000796 flavoring agent Substances 0.000 claims description 13
- 229960005233 cineole Drugs 0.000 claims description 12
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 claims description 12
- WEEGYLXZBRQIMU-UHFFFAOYSA-N Eucalyptol Chemical compound C1CC2CCC1(C)OC2(C)C WEEGYLXZBRQIMU-UHFFFAOYSA-N 0.000 claims description 11
- 235000019634 flavors Nutrition 0.000 claims description 10
- 229960001047 methyl salicylate Drugs 0.000 claims description 10
- 244000042664 Matricaria chamomilla Species 0.000 claims description 8
- 235000007232 Matricaria chamomilla Nutrition 0.000 claims description 8
- 235000002020 sage Nutrition 0.000 claims description 8
- 235000013709 carrot oil Nutrition 0.000 claims description 7
- 239000010636 coriander oil Substances 0.000 claims description 7
- 239000001538 helichrysum angustifolium dc. absolute Substances 0.000 claims description 7
- 235000019719 rose oil Nutrition 0.000 claims description 7
- 239000010666 rose oil Substances 0.000 claims description 7
- 235000007866 Chamaemelum nobile Nutrition 0.000 claims description 6
- 239000001276 artemisia dracunculus l. absolute Substances 0.000 claims description 6
- 235000010650 Hyssopus officinalis Nutrition 0.000 claims description 5
- 235000014749 Mentha crispa Nutrition 0.000 claims description 5
- 235000010676 Ocimum basilicum Nutrition 0.000 claims description 5
- 240000007926 Ocimum gratissimum Species 0.000 claims description 5
- 235000008694 Humulus lupulus Nutrition 0.000 claims description 4
- 244000025221 Humulus lupulus Species 0.000 claims description 4
- 244000179970 Monarda didyma Species 0.000 claims description 4
- 235000010672 Monarda didyma Nutrition 0.000 claims description 4
- 240000006054 Agastache cana Species 0.000 claims description 3
- 241000196324 Embryophyta Species 0.000 claims description 3
- 235000002911 Salvia sclarea Nutrition 0.000 claims description 3
- 244000182022 Salvia sclarea Species 0.000 claims description 3
- CANRESZKMUPMAE-UHFFFAOYSA-L Zinc lactate Chemical compound [Zn+2].CC(O)C([O-])=O.CC(O)C([O-])=O CANRESZKMUPMAE-UHFFFAOYSA-L 0.000 claims description 3
- 235000013624 davana Nutrition 0.000 claims description 3
- 244000170514 davana Species 0.000 claims description 3
- MFGZXPGKKJMZIY-UHFFFAOYSA-N ethyl 5-amino-1-(4-sulfamoylphenyl)pyrazole-4-carboxylate Chemical compound NC1=C(C(=O)OCC)C=NN1C1=CC=C(S(N)(=O)=O)C=C1 MFGZXPGKKJMZIY-UHFFFAOYSA-N 0.000 claims description 3
- 239000011576 zinc lactate Substances 0.000 claims description 3
- 235000000193 zinc lactate Nutrition 0.000 claims description 3
- 229940050168 zinc lactate Drugs 0.000 claims description 3
- 244000024873 Mentha crispa Species 0.000 claims description 2
- 229930007050 cineol Natural products 0.000 claims description 2
- 229960000314 zinc acetate Drugs 0.000 claims description 2
- 229960001939 zinc chloride Drugs 0.000 claims description 2
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 2
- 229960001763 zinc sulfate Drugs 0.000 claims description 2
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 2
- 239000001683 mentha spicata herb oil Substances 0.000 abstract description 8
- 235000019721 spearmint oil Nutrition 0.000 abstract description 8
- 238000002156 mixing Methods 0.000 abstract description 7
- 235000015112 vegetable and seed oil Nutrition 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 6
- 239000001926 citrus aurantium l. subsp. bergamia wright et arn. oil Substances 0.000 abstract description 5
- 239000002304 perfume Substances 0.000 abstract description 5
- 239000000306 component Substances 0.000 abstract 1
- 230000003287 optical effect Effects 0.000 abstract 1
- 239000010669 rosewood oil Substances 0.000 abstract 1
- 239000008158 vegetable oil Substances 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 30
- RUVINXPYWBROJD-ONEGZZNKSA-N trans-anethole Chemical compound COC1=CC=C(\C=C\C)C=C1 RUVINXPYWBROJD-ONEGZZNKSA-N 0.000 description 24
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 18
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 16
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 16
- 229940041616 menthol Drugs 0.000 description 15
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 13
- 235000019441 ethanol Nutrition 0.000 description 13
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 13
- 239000000606 toothpaste Substances 0.000 description 13
- 229940034610 toothpaste Drugs 0.000 description 13
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 12
- 229940011037 anethole Drugs 0.000 description 12
- 235000013399 edible fruits Nutrition 0.000 description 12
- 239000001525 mentha piperita l. herb oil Substances 0.000 description 12
- RUVINXPYWBROJD-UHFFFAOYSA-N para-methoxyphenyl Natural products COC1=CC=C(C=CC)C=C1 RUVINXPYWBROJD-UHFFFAOYSA-N 0.000 description 12
- 235000019477 peppermint oil Nutrition 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 235000007129 Cuminum cyminum Nutrition 0.000 description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 10
- RFFOTVCVTJUTAD-UHFFFAOYSA-N cineole Natural products C1CC2(C)CCC1(C(C)C)O2 RFFOTVCVTJUTAD-UHFFFAOYSA-N 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 10
- 239000011734 sodium Substances 0.000 description 10
- 229910052708 sodium Inorganic materials 0.000 description 10
- 239000004359 castor oil Substances 0.000 description 9
- 235000019438 castor oil Nutrition 0.000 description 9
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 9
- 235000011187 glycerol Nutrition 0.000 description 8
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 8
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 8
- 229960002216 methylparaben Drugs 0.000 description 8
- 239000008213 purified water Substances 0.000 description 8
- 239000012086 standard solution Substances 0.000 description 8
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 7
- 235000010234 sodium benzoate Nutrition 0.000 description 7
- 239000004299 sodium benzoate Substances 0.000 description 7
- 235000016639 Syzygium aromaticum Nutrition 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 239000000523 sample Substances 0.000 description 6
- 239000001509 sodium citrate Substances 0.000 description 6
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 6
- SGHZXLIDFTYFHQ-UHFFFAOYSA-L Brilliant Blue Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SGHZXLIDFTYFHQ-UHFFFAOYSA-L 0.000 description 5
- 239000005973 Carvone Substances 0.000 description 5
- 241000510672 Cuminum Species 0.000 description 5
- 244000304337 Cuminum cyminum Species 0.000 description 5
- 239000002202 Polyethylene glycol Substances 0.000 description 5
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 5
- -1 amine compounds Chemical class 0.000 description 5
- 239000002324 mouth wash Substances 0.000 description 5
- 229920001223 polyethylene glycol Polymers 0.000 description 5
- 206010006326 Breath odour Diseases 0.000 description 4
- QFOHBWFCKVYLES-UHFFFAOYSA-N Butylparaben Chemical compound CCCCOC(=O)C1=CC=C(O)C=C1 QFOHBWFCKVYLES-UHFFFAOYSA-N 0.000 description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 244000166124 Eucalyptus globulus Species 0.000 description 4
- 241000218228 Humulus Species 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 229940051866 mouthwash Drugs 0.000 description 4
- 229940085605 saccharin sodium Drugs 0.000 description 4
- FTLYMKDSHNWQKD-UHFFFAOYSA-N (2,4,5-trichlorophenyl)boronic acid Chemical compound OB(O)C1=CC(Cl)=C(Cl)C=C1Cl FTLYMKDSHNWQKD-UHFFFAOYSA-N 0.000 description 3
- 244000061408 Eugenia caryophyllata Species 0.000 description 3
- 244000078639 Mentha spicata Species 0.000 description 3
- AOMUHOFOVNGZAN-UHFFFAOYSA-N N,N-bis(2-hydroxyethyl)dodecanamide Chemical compound CCCCCCCCCCCC(=O)N(CCO)CCO AOMUHOFOVNGZAN-UHFFFAOYSA-N 0.000 description 3
- 244000223014 Syzygium aromaticum Species 0.000 description 3
- 239000010619 basil oil Substances 0.000 description 3
- 229940018006 basil oil Drugs 0.000 description 3
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- 229920003123 carboxymethyl cellulose sodium Polymers 0.000 description 3
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- 235000013355 food flavoring agent Nutrition 0.000 description 3
- 239000001735 hyssopus officinalis l. herb oil Substances 0.000 description 3
- 229940031957 lauric acid diethanolamide Drugs 0.000 description 3
- 239000012488 sample solution Substances 0.000 description 3
- 230000001953 sensory effect Effects 0.000 description 3
- 241000220479 Acacia Species 0.000 description 2
- 235000011468 Albizia julibrissin Nutrition 0.000 description 2
- 241000207199 Citrus Species 0.000 description 2
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 2
- 244000000626 Daucus carota Species 0.000 description 2
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- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 244000000182 Helichrysum angustifolium Species 0.000 description 2
- 235000018625 Helichrysum angustifolium Nutrition 0.000 description 2
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- 240000005852 Mimosa quadrivalvis Species 0.000 description 2
- PVNIIMVLHYAWGP-UHFFFAOYSA-N Niacin Chemical compound OC(=O)C1=CC=CN=C1 PVNIIMVLHYAWGP-UHFFFAOYSA-N 0.000 description 2
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- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000001889 artemisia pallens wall. flower oil Substances 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- FUFJGUQYACFECW-UHFFFAOYSA-L calcium hydrogenphosphate Chemical compound [Ca+2].OP([O-])([O-])=O FUFJGUQYACFECW-UHFFFAOYSA-L 0.000 description 2
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- 238000011156 evaluation Methods 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- OVBPIULPVIDEAO-LBPRGKRZSA-N folic acid Chemical compound C=1N=C2NC(N)=NC(=O)C2=NC=1CNC1=CC=C(C(=O)N[C@@H](CCC(O)=O)C(O)=O)C=C1 OVBPIULPVIDEAO-LBPRGKRZSA-N 0.000 description 2
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- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
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- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
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- WJLVQTJZDCGNJN-UHFFFAOYSA-N Chlorhexidine hydrochloride Chemical compound Cl.Cl.C=1C=C(Cl)C=CC=1NC(N)=NC(N)=NCCCCCCN=C(N)N=C(N)NC1=CC=C(Cl)C=C1 WJLVQTJZDCGNJN-UHFFFAOYSA-N 0.000 description 1
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- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 1
- 108010001682 Dextranase Proteins 0.000 description 1
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 235000003550 Dracunculus Nutrition 0.000 description 1
- 241000316827 Dracunculus <angiosperm> Species 0.000 description 1
- 235000004692 Eucalyptus globulus Nutrition 0.000 description 1
- 240000004476 Eucalyptus polybractea Species 0.000 description 1
- 235000009683 Eucalyptus polybractea Nutrition 0.000 description 1
- 239000001653 FEMA 3120 Substances 0.000 description 1
- 235000007297 Gaultheria procumbens Nutrition 0.000 description 1
- 240000001238 Gaultheria procumbens Species 0.000 description 1
- 208000032139 Halitosis Diseases 0.000 description 1
- 235000008418 Hedeoma Nutrition 0.000 description 1
- 241001267646 Hedeoma Species 0.000 description 1
- 241000038859 Horia Species 0.000 description 1
- 244000165082 Lavanda vera Species 0.000 description 1
- 235000002997 Lavandula Nutrition 0.000 description 1
- 241000212321 Levisticum Species 0.000 description 1
- VTAJIXDZFCRWBR-UHFFFAOYSA-N Licoricesaponin B2 Natural products C1C(C2C(C3(CCC4(C)CCC(C)(CC4C3=CC2)C(O)=O)C)(C)CC2)(C)C2C(C)(C)CC1OC1OC(C(O)=O)C(O)C(O)C1OC1OC(C(O)=O)C(O)C(O)C1O VTAJIXDZFCRWBR-UHFFFAOYSA-N 0.000 description 1
- 235000006685 Mentha cardiaca Nutrition 0.000 description 1
- 235000004357 Mentha x piperita Nutrition 0.000 description 1
- OVBPIULPVIDEAO-UHFFFAOYSA-N N-Pteroyl-L-glutaminsaeure Natural products C=1N=C2NC(N)=NC(=O)C2=NC=1CNC1=CC=C(C(=O)NC(CCC(O)=O)C(O)=O)C=C1 OVBPIULPVIDEAO-UHFFFAOYSA-N 0.000 description 1
- 241001529734 Ocimum Species 0.000 description 1
- 235000011205 Ocimum Nutrition 0.000 description 1
- 235000019502 Orange oil Nutrition 0.000 description 1
- 240000007495 Oswego tea Species 0.000 description 1
- 235000017927 Pelargonium graveolens Nutrition 0.000 description 1
- 244000270673 Pelargonium graveolens Species 0.000 description 1
- 235000004347 Perilla Nutrition 0.000 description 1
- 244000124853 Perilla frutescens Species 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 241001072909 Salvia Species 0.000 description 1
- 235000017276 Salvia Nutrition 0.000 description 1
- 235000001500 Salvia lavandulifolia Nutrition 0.000 description 1
- 244000258095 Salvia lavandulifolia Species 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 235000004552 Yucca aloifolia Nutrition 0.000 description 1
- 235000012044 Yucca brevifolia Nutrition 0.000 description 1
- 235000017049 Yucca glauca Nutrition 0.000 description 1
- 240000005780 Yucca gloriosa Species 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 244000030166 artemisia Species 0.000 description 1
- 235000009052 artemisia Nutrition 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 239000002199 base oil Substances 0.000 description 1
- HUMNYLRZRPPJDN-KWCOIAHCSA-N benzaldehyde Chemical group O=[11CH]C1=CC=CC=C1 HUMNYLRZRPPJDN-KWCOIAHCSA-N 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 229960004365 benzoic acid Drugs 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- OBNCKNCVKJNDBV-UHFFFAOYSA-N butanoic acid ethyl ester Natural products CCCC(=O)OCC OBNCKNCVKJNDBV-UHFFFAOYSA-N 0.000 description 1
- 235000010418 carrageenan Nutrition 0.000 description 1
- 239000000679 carrageenan Substances 0.000 description 1
- 229920001525 carrageenan Polymers 0.000 description 1
- 229940113118 carrageenan Drugs 0.000 description 1
- ULDHMXUKGWMISQ-UHFFFAOYSA-N carvone Natural products CC(=C)C1CC=C(C)C(=O)C1 ULDHMXUKGWMISQ-UHFFFAOYSA-N 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 229960001927 cetylpyridinium chloride Drugs 0.000 description 1
- YMKDRGPMQRFJGP-UHFFFAOYSA-M cetylpyridinium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+]1=CC=CC=C1 YMKDRGPMQRFJGP-UHFFFAOYSA-M 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229960003260 chlorhexidine Drugs 0.000 description 1
- 229960004504 chlorhexidine hydrochloride Drugs 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 125000003555 cineol group Chemical group 0.000 description 1
- 229940043350 citral Drugs 0.000 description 1
- 239000001279 citrus aurantifolia swingle expressed oil Substances 0.000 description 1
- XJCRCPKBJWRZAX-UHFFFAOYSA-L disodium;dibenzoate Chemical compound [Na+].[Na+].[O-]C(=O)C1=CC=CC=C1.[O-]C(=O)C1=CC=CC=C1 XJCRCPKBJWRZAX-UHFFFAOYSA-L 0.000 description 1
- 239000010642 eucalyptus oil Substances 0.000 description 1
- 229940044949 eucalyptus oil Drugs 0.000 description 1
- 235000019152 folic acid Nutrition 0.000 description 1
- 239000011724 folic acid Substances 0.000 description 1
- 229960000304 folic acid Drugs 0.000 description 1
- 235000004611 garlic Nutrition 0.000 description 1
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 description 1
- 239000010649 ginger oil Substances 0.000 description 1
- 235000012208 gluconic acid Nutrition 0.000 description 1
- 239000000174 gluconic acid Substances 0.000 description 1
- 229950006191 gluconic acid Drugs 0.000 description 1
- LPLVUJXQOOQHMX-UHFFFAOYSA-N glycyrrhetinic acid glycoside Natural products C1CC(C2C(C3(CCC4(C)CCC(C)(CC4C3=CC2=O)C(O)=O)C)(C)CC2)(C)C2C(C)(C)C1OC1OC(C(O)=O)C(O)C(O)C1OC1OC(C(O)=O)C(O)C(O)C1O LPLVUJXQOOQHMX-UHFFFAOYSA-N 0.000 description 1
- 239000001685 glycyrrhizic acid Substances 0.000 description 1
- 229960004949 glycyrrhizic acid Drugs 0.000 description 1
- UYRUBYNTXSDKQT-UHFFFAOYSA-N glycyrrhizic acid Natural products CC1(C)C(CCC2(C)C1CCC3(C)C2C(=O)C=C4C5CC(C)(CCC5(C)CCC34C)C(=O)O)OC6OC(C(O)C(O)C6OC7OC(O)C(O)C(O)C7C(=O)O)C(=O)O UYRUBYNTXSDKQT-UHFFFAOYSA-N 0.000 description 1
- 235000019410 glycyrrhizin Nutrition 0.000 description 1
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 1
- 235000001050 hortel pimenta Nutrition 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 239000000457 mentha pulegium l. herb oil Substances 0.000 description 1
- 239000001220 mentha spicata Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 235000001968 nicotinic acid Nutrition 0.000 description 1
- 239000011664 nicotinic acid Substances 0.000 description 1
- 229960003512 nicotinic acid Drugs 0.000 description 1
- 239000010502 orange oil Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920001983 poloxamer Polymers 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000010668 rosemary oil Substances 0.000 description 1
- 229940058206 rosemary oil Drugs 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229960004711 sodium monofluorophosphate Drugs 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
- 229940098465 tincture Drugs 0.000 description 1
- 229940042585 tocopherol acetate Drugs 0.000 description 1
- 239000010913 used oil Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000009637 wintergreen oil Substances 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
- CRUISIDZTHMGJT-UHFFFAOYSA-L zinc;dichloride;hydrochloride Chemical compound Cl.[Cl-].[Cl-].[Zn+2] CRUISIDZTHMGJT-UHFFFAOYSA-L 0.000 description 1
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は、日中のタバコヤニ臭の消臭に優れた効果をも
つ口腔用組成物に関する。DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to an oral composition that is highly effective in deodorizing tobacco tar odor during the day.
従来の技術 び 明が解決しようとする一間4〔朝従来
より、口臭の予防、除去に関して多くの研究が行なわれ
ている。例えば、植物抽出物として、ユッカ(特開昭5
3−133645号)、ハツカ及びシソ(特開昭54−
84070号、59−163307号)、ニラケイ及び
サクシ(特開昭54−84070号)、レモン油(特開
昭53−133645号、56−158708号)、ジ
ンジャ−油(特開昭56−158708号、58−88
308号)、柑橘類の果皮(特開昭59−163307
号)、茶(特開昭53−133645号、54−840
00号、56−158708号)、用菌、当帰、萬本、
セロリ、クミン(特開昭59−13712号)、ハイビ
スカス(特開昭59−227814号)、キキョウ(特
開昭60−7.848号)、ツバキ科植物(特開昭60
−153778号)等を用いて口臭を除去する方法が提
案されている。また、亜鉛塩が口臭阻止の効果があるこ
とも知られている(特開昭60−233008号)。Conventional Techniques A great deal of research has been conducted on the prevention and removal of bad breath. For example, as a plant extract, yucca
No. 3-133645), peppermint and perilla (Japanese Patent Application Laid-open No. 1983-
84070, 59-163307), Nirakei and Sakshi (JP 54-84070), lemon oil (JP 53-133645, JP 56-158708), ginger oil (JP 56-158708) , 58-88
308), Citrus Peel (Japanese Patent Publication No. 59-163307)
No.), tea (JP-A No. 53-133645, 54-840
No. 00, No. 56-158708), Bacteria, Toki, Manmoto,
Celery, cumin (Japanese Patent Publication No. 59-13712), hibiscus (Japanese Patent Application Publication No. 59-227814), bellflower (Japanese Patent Application Publication No. 60-7.848), Camelliaaceae plants (Japanese Patent Application Publication No. 60-7.848)
-153778) and the like have been proposed to remove bad breath. It is also known that zinc salts have the effect of preventing bad breath (Japanese Patent Application Laid-Open No. 60-233008).
しかしながら、これらの提案は口臭のうち一般口臭やニ
ンニク臭、即ち硫化水素、チオール、ジサルファイド等
の硫黄化合物に対する消臭効果を目的としているものが
主で、アミン系化合物を主成分とするタバコヤニ臭の消
臭とは異なる。However, these proposals are mainly aimed at deodorizing effects on general halitosis and garlic odor, that is, sulfur compounds such as hydrogen sulfide, thiol, and disulfide, and are aimed at eliminating tobacco tar odor, which is mainly composed of amine compounds. This is different from deodorizing.
タバコヤニの消臭に関しては、従来、単品香料(アルデ
ヒドC6〜C□2、ベンズアルデヒド、シトラール、ジ
メトール、エチルブチレート、エチルカプロエート、フ
ェンシルアルコール等)や天然香料(バジルオイル、ベ
ルガモツトオイル、ユーカリプタスオイル、ラベンダー
オイル、ラベンダーオイル、レモンオイル、ライムオイ
ル、オレンジオイル、ペパーミントオイル、ローズマリ
ーオイル、スペアミントオイル等)を用いてタバコ臭を
マスキングする方法(フレグランスジャーナルNo、7
2.p 56.1985)が検討されているが、口腔用
組成物に用いた場合効果が必ずしも十分でない。また、
Q−アスコルビン酸、安息香酸、グルコン酸、葉酸、ニ
コチン酸による消臭方法(特開昭60−136506号
)も提案されているが、配合安定性や使用時の官能特性
の点で問題がある。Conventionally, single fragrances (aldehydes C6 to C□2, benzaldehyde, citral, dimetol, ethyl butyrate, ethyl caproate, fencyl alcohol, etc.) and natural fragrances (basil oil, bergamot oil, etc.) have been used to deodorize tobacco tar. How to mask cigarette odor using eucalyptus oil, lavender oil, lavender oil, lemon oil, lime oil, orange oil, peppermint oil, rosemary oil, spearmint oil, etc. (Fragrance Journal No. 7)
2. p 56.1985), but the effects are not necessarily sufficient when used in oral compositions. Also,
A deodorizing method using Q-ascorbic acid, benzoic acid, gluconic acid, folic acid, and nicotinic acid (Japanese Patent Application Laid-open No. 136506/1983) has also been proposed, but there are problems in terms of formulation stability and sensory characteristics during use. .
本発明は上記事情に鑑みなされたもので、口中のタバコ
ヤニ臭の消臭効果に優れ、配合性の良い口腔用組成物を
提供することを目的とする。The present invention was made in view of the above circumstances, and it is an object of the present invention to provide an oral composition that has an excellent deodorizing effect on tobacco tar odor in the mouth and has good blendability.
叫題痺を解決するための手段及び 肛
本発明者らは、上記目的を達成するため、タバコヤニ臭
の消臭物質として各種天然香料について鋭意検討を行な
った結果、下記(1)よりなる群(第1香料群)、即ち
(1)アンブレットリド及びアンブレットリドを主香成
分とする精油、クミンアルデヒド及びクミンアルデヒド
を主香成分とする精油、並びにシナモン油、ゼラニウム
油、ロベージ油、イモーテルアブソリュート及びミモザ
アブソリュート
の香料成分が優れたタバコヤニの消臭力を示し、これら
香料を配合した口腔用組成物がタバコヤニ消臭用として
有効であることを知見した。更に、下記(2)よりなる
群(第2香料群)、即ち(2)ベルガモツト、カルダモ
ン、スペアミント、セージスパニッシュ、バジル、ホッ
プ、クラリセージ、ダバナ及びヒソップ
の植物の精油がそれ自体では十分なタバコヤニ消臭効果
がないにもかかわらず、上述した第1香料群の1種又は
2種以上の香料と併用した場合には、これらが相乗的に
作用し、消臭効果が著しく高まること、更に下記(3)
よりなる群(第3香料群)、即ち
(3)ボアドローズ油、カモミルブルー油、キャロット
油、コリアンダー油、エストラゴン油、ペニロイヤル油
、サリチル酸メチル及びこれを主香成分とする精油、シ
ネオール及びこれを主香成分とする精油、並びにベンズ
アルデヒド
の香料成分もそれ自体タバコヤニを消臭する効果が十分
ないにもかかわらず、第1香料群の1種又は2種以上の
香料と併用する場合は、その相乗的作用により、タバコ
ヤニ消臭効果がより高まると共に、この第3香料群の1
種又は2種以上の香料を口腔用組成物に配合すると口腔
用組成物の使用感が高まること、また第1香料群の香料
に加えて亜鉛塩を配合することにより、タバコヤニ消臭
効果が更に優れた口腔用組成物を得ることができること
を知見し、本発明をなすに至ったものである。In order to achieve the above object, the inventors of the present invention conducted intensive studies on various natural fragrances as deodorizing substances for tobacco tar odor, and found that the group consisting of the following (1) ( (1) ambrettolide and essential oils whose main fragrance component is ambrettolide, cuminaldehyde and essential oils whose main fragrance component is cuminaldehyde, cinnamon oil, geranium oil, lovage oil, and immortelle absolute. It has been found that the fragrance components of Mimosa Absolute and Mimosa Absolute exhibit excellent tobacco tar deodorizing power, and that oral compositions containing these fragrances are effective as tobacco tar deodorizers. Furthermore, the essential oils of the group consisting of the following (2) (second fragrance group), namely (2) bergamot, cardamom, spearmint, sage Spanish, basil, hops, clary sage, davana, and hyssop, are sufficient to eliminate tobacco tar by themselves. Even though there is no odor effect, when used in combination with one or more fragrances from the first fragrance group mentioned above, they act synergistically and the deodorizing effect is significantly enhanced. 3)
(3rd fragrance group), namely (3) boad rose oil, chamomile blue oil, carrot oil, coriander oil, estragon oil, penyroyal oil, methyl salicylate and essential oils containing this as the main fragrance ingredient, cineol and this Even though essential oils whose main fragrance component is benzaldehyde and the fragrance component of benzaldehyde do not have a sufficient effect of deodorizing tobacco tar by themselves, when used in combination with one or more fragrances from the first fragrance group, Due to the synergistic effect, the tobacco tar deodorizing effect is further enhanced, and one of the third fragrance group
The feeling of use of the oral composition is enhanced by blending one or more flavoring agents into the oral composition, and the tobacco tar deodorizing effect is further enhanced by incorporating a zinc salt in addition to the flavoring agent of the first fragrance group. The inventors discovered that it is possible to obtain an excellent oral composition, and have thus come up with the present invention.
以下、本発明につき更に詳述する。The present invention will be explained in more detail below.
本発明のタバコヤニ消臭用口腔用組成物は、マウスウォ
ッシュ、練歯磨、潤製歯磨、液状歯磨、スプレータイプ
口中清涼剤、口腔用パスタ等として調製、適用され得る
もので、タバコヤニ消臭用成分として第1香料群、即ち
アンブレットリド及びアンブレットリドを主香成分とす
る精油、クミンアルデヒド及びクミンアルデヒドを主香
成分とする精油、並びにシナモン油、ゼラニウム油、ロ
ベージ油、イモーテルアブソリュート、及びミモザアブ
ソリュートから選ばれる1種又は2種以上の香料成分を
配合してなるものである。The tobacco tar deodorizing oral composition of the present invention can be prepared and applied as a mouthwash, toothpaste, moist toothpaste, liquid toothpaste, spray type mouth freshener, oral pasta, etc., and is a tobacco tar deodorizing ingredient. The first fragrance group includes ambrettolide and essential oils containing ambrettolide as the main fragrance ingredient, cuminaldehyde and essential oils containing cuminaldehyde as the main fragrance ingredient, as well as cinnamon oil, geranium oil, lovage oil, immortelle absolute, and mimosa. It is made by blending one or more types of fragrance ingredients selected from absolutes.
ここで、アンブレットリドを香成分とする精油としては
、例えばハイビスカス・アベルモスカス(Hibisc
us abelmoschus L、)の種子を水蒸気
蒸留して得ることができるアンプレッドシード油が好適
であり、また、クミンアルデヒドを主香成分とする精油
としては、クミニウム・シミナム(Cuminum c
yminum L、)の種子を水蒸気蒸留して得ること
ができるクミン油が好適に用いられる。Here, as an essential oil containing ambrettolide as a fragrance component, for example, Hibiscus abelmoscus (Hibisc.
Amplified seed oil, which can be obtained by steam distilling the seeds of Cuminium c.
Cumin oil, which can be obtained by steam distilling the seeds of C. yminum L.), is preferably used.
また、シナモン油は、シナモマム・ジラニカム(Cin
namomum zeylanicum)の樹皮、ゼラ
ニウム油はベラルゴニウム・グラベオレンス(P el
argoniumgraveolens L ’ He
r)の葉部と小枝部、ロベージ油はレビスチカム・オフ
ィシナル・コック(Levistj、cumoffic
inale Koch)の根茎を各々水蒸気蒸留して得
られたものが好適に用いられ、イモテールアブソリュー
トはへりクリサム・アングスチホリウム(Helich
rysum angustifolium D、C)の
花部、ミモザアブソリュートはアカシア・デクレンス・
ウィルド・パル・ディールバータ(Acacia de
currcnsWild、var、dealbata)
の花部を各々石油エーテルで抽出した後、エタノールで
抽出して得られたものなどが好適に用いられる。Cinnamon oil is also available from Cinnamomum jiranicum (Cinnamonum).
The bark and geranium oil of Belargonium graveolens (Pel
argoniumgraveolens L'He
r) leaves and twigs, lovage oil is Levisticum officinal cock (Levistj, cumoffic).
Those obtained by steam distilling the rhizomes of Helichrysum angustifolium (Helichrysum angustifolium) are preferably used.
The flower part of rysum angustifolium D, C), mimosa absolute is Acacia declens.
Wild Pal Diverta (Acacia de
currcnsWild, var, dealbata)
Preferably used are those obtained by extracting each flower part with petroleum ether and then extracting with ethanol.
なお、第1香料群の配合量は特に制限されないが、口腔
用組成物の全成分量に対し0.001〜0.5重量%が
好ましく、このように第1香料群をこの範囲内で口腔用
組成物に配合することにより、タバコヤニ消臭効果に優
れた口腔用組成物を得ることができるが、第1香料群の
配合量が0.001重量%より少ないとタバコヤニ消臭
効果が十分発揮されない場合がある。なお、第1香料群
を0.5重量%を超えて配合してもタバコヤニ消臭効果
がそれ以上高まらないので、あまり多く配合することは
経済的に不利である。The amount of the first fragrance group to be blended is not particularly limited, but is preferably 0.001 to 0.5% by weight based on the total amount of ingredients in the oral composition. By incorporating the first fragrance group into a composition for oral use, it is possible to obtain an oral composition with excellent tobacco tar deodorizing effect, but when the amount of the first fragrance group is less than 0.001% by weight, the tobacco tar deodorizing effect is sufficiently exhibited. It may not be possible. It should be noted that even if the first fragrance group is blended in an amount exceeding 0.5% by weight, the tobacco tar deodorizing effect will not further increase, so it is economically disadvantageous to blend in too much.
本発明の口腔用組成物には、前記第1香料群の香料に加
えて、下記の第2香料群、即ちベルガモツト、カルダモ
ン、スペアミント、セージスパニッシュ、バジル、ホッ
プ、クラリセージ、ダバナ及びヒソップから選ばれる植
物性精油の1種又は2種以上を香料成分として配合する
ことが好ましい。このように第1香料群の香料と第2香
料群の香料とを併用することにより、第2香料群の香料
それ自体は十分なタバコヤニ消臭力がないにもかかわら
ず、これらが優れた相乗効果を発揮し、タバコヤニ消臭
効果を著しく増強する。In addition to the fragrance of the first fragrance group, the oral composition of the present invention includes a fragrance selected from the following second fragrance group, namely bergamot, cardamom, spearmint, sage Spanish, basil, hops, clary sage, davana, and hyssop. It is preferable to incorporate one or more kinds of vegetable essential oils as a fragrance ingredient. In this way, by using the fragrance of the first fragrance group and the fragrance of the second fragrance group together, even though the fragrance of the second fragrance group itself does not have sufficient tobacco tar deodorizing power, they have an excellent synergistic effect. It is effective and significantly enhances the tobacco tar deodorizing effect.
ここで、この第2香料群において、ベルガモツトはシト
ラス・オランチウム・ベルガミア(Citrus au
rantium bergamja)の果皮を圧搾して
得られる油、また、カルダモンはエレタリア0カルダモ
ナム(E 1ettaria cardamomum)
の実部、スペアミントはメンタ・スピカータ(Ment
ha 5picata)或いはメンタ・カルブイア−力
(Mentha cardiaca L、)の全草、セ
ージスノ(ニッシュはサルビア・ラバンデュラホリア(
Salvialavandulaefolia)の葉部
、バジルはオシナム・バシリカム(Ocimum ba
silicum)の花部、ホップはヒュムラス・ルプラ
ス(Humulus 1upulus L、)の花部、
ヒソップはヒソラプス・オフィシナリス(Hyssop
us officinalis L、)の葉部を各々水
蒸気蒸留して得られたものなどが好適に用いられる。Here, in this second fragrance group, bergamot is similar to Citrus aurantium bergamia (Citrus au
rantium bergamja), and cardamom is obtained by pressing the peel of E. 1ettaria cardamomum.
The fruit of spearmint is Mentha spicata (Menta spicata).
ha 5 picata) or Mentha cardiaca L., sage snow (nish is Salvia lavandula horia (L.)
Salvialavandulaefolia) leaves, basil is Ocimum basilicum (Ocimum ba.
silicum), hops are the flowers of Humulus 1upulus L,
Hyssop is Hyssop officinalis.
Those obtained by steam distilling the leaves of P. us officinalis L.) are preferably used.
なお、第2香料群の香料の配合量に制限はないが、前記
第1香料群と第2香料群との給配合量が口腔用組成物の
全成分量に対し0.001〜0.5重量%となるように
第2香料群を配合することが好ましい。この場合、第1
香料群と第2香料群との併用割合は、重量比で1:0.
1〜1:150、特に1:0.5〜1:50とすること
が好ましい。There is no limit to the blending amount of the fragrance of the second fragrance group, but the blending amount of the first fragrance group and the second fragrance group is 0.001 to 0.5 with respect to the total component amount of the oral composition. It is preferable that the second fragrance group is blended in such a manner that the proportion of the second fragrance group is % by weight. In this case, the first
The combined use ratio of the fragrance group and the second fragrance group is 1:0 by weight.
The ratio is preferably 1 to 1:150, particularly 1:0.5 to 1:50.
本発明の口腔用組成物には、更に第1香料群の香料或い
は第1及び第2香料群の香料に加えて第3香料群、即ち
ボアドローズ油、カモミルブルー油、キャロット油、コ
リアンダー油、エストラゴン油、ペニロイヤル油、サリ
チル酸メチル及びこれを主香成分とする精油、シネオー
ル及びこれを主香成分とする精油、並びにベンズアルデ
ヒドから選ばれる1種又は2種以上の香料成分を配合す
ることが好ましい。In addition to the fragrance of the first fragrance group or the fragrance of the first and second fragrance groups, the oral composition of the present invention further contains a third fragrance group, namely boad rose oil, chamomile blue oil, carrot oil, coriander oil, It is preferable to blend one or more fragrance ingredients selected from estragon oil, penyroyal oil, methyl salicylate and essential oils containing this as the main fragrance ingredient, cineole and essential oils containing this as the main fragrance ingredient, and benzaldehyde. .
これらの第3香料群の香料は、それ単独で口腔用組成物
に配合してもタバコヤニ消臭効果はほとんどないにもか
かわらず、この第3香料群の香料を第1香料群の香料ま
たは第1及び第2香料群の香料を配合した口腔用組成物
中に配合すると、第3香料群の香料成分のもつ香味が第
1香料群、更には第2香料群の香料のもつ特徴的な強い
香味と調和し、タバコヤニ消臭用口腔用組成物の使用感
が良くなると共に1口腔用組成物のタバコヤニ消臭効果
が増強するものである。Although these third fragrance group fragrances have almost no tobacco tar deodorizing effect even if they are incorporated alone into oral compositions, they are combined with the third fragrance group fragrances or the first fragrance group fragrances. When blended into an oral composition containing the fragrances of the first and second fragrance groups, the flavor of the fragrance ingredients of the third fragrance group becomes stronger, which is characteristic of the fragrances of the first fragrance group and even the second fragrance group. It harmonizes with the flavor, improves the feeling of use of the tobacco tar deodorizing oral composition, and enhances the tobacco tar deodorizing effect of the oral composition.
ここで、第3香料群において、ボアドローズ油はアニバ
―ロゼオドラ・デュク(Aniba rosaeodo
raDucke、)の木部、カモミルブルー油はマトリ
カリア・シャモミラ(Matricaria cham
omilla L、)の花部、キャロット油はダウカス
・キャロタ(Daucus carota L、’)の
種子、コリアンダー油はコリアンドラム・サチバム(C
oriandorum Sativum L、)の果実
、エストラゴン油はアルテミシア・ドラカンカラス(A
rtemisia dracunculus L 、)
の葉部、ペニロイヤル油はヘデオマ・プレギオイデス(
HedeoIIla pulegioides(L 、
) P ers、)或いはメンタ・プレジウム(Men
tha pulegium L 、)の葉部を各々水蒸
気蒸留して得られたものが好適に用いられ、サリチル酸
メチルを主香成分とする精油としては、グルテリア・プ
ロカンベンズ(Gaultheria procumb
ens)の葉部を水蒸気蒸留することにより得られるウ
ィンターグリーン油、シネオールを主香成分とする精油
としては、ユー力リプラス・グログラス(E ucal
yptus globulus)、ユーカリプタス・ポ
リブラクタ(Eucalyptus polybrac
tea)、ユーカリプタス・デイブス(Eucalyp
tus’dives Var、C,)或いはユーカリプ
タス・スミシイ(Eucalyptus 5m1thi
i)の葉を水蒸気蒸留することにより得られる精油が好
適に用いられる。Here, in the third fragrance group, bore rose oil is Aniba rosaeodora duc.
raDucke, ), chamomile blue oil is derived from Matricaria chamomilla (Matricaria chamomilla).
omilla L,); carrot oil is derived from the seeds of Daucus carota (Daucus carota L,'); coriander oil is derived from Coriandrum sativum (C).
oriandorum Sativum L,), estragon oil is extracted from the fruit of Artemisia dracancarus (A
rtemisia dracunculus L,)
The leaves of Hedeoma plegioides (Pleniroyal oil)
HedeoIIla pulegioides (L,
) Pers, ) or Menta Presium (Men
tha pulegium L.) is preferably used, and essential oils containing methyl salicylate as the main aromatic component include Gulteria procumbens (Gaultheria procumbens).
Wintergreen oil, which is obtained by steam distilling the leaves of E. ens, and essential oils whose main scent is cineole, include Eucalliplus grosgrain (Eucal
yptus globulus), Eucalyptus polybrac
tea), Eucalyptus daves (Eucalyp)
tus'dives Var, C,) or Eucalyptus smithi (Eucalyptus 5m1thi)
The essential oil obtained by steam distilling the leaves of i) is preferably used.
前記第3香料群の香料の配合量は別に限定されないが、
組成物全体の0.01〜5重量%とすることが好ましい
。The amount of the fragrance of the third fragrance group is not particularly limited, but
It is preferably 0.01 to 5% by weight of the entire composition.
更に、本発明の口腔用組成物には、亜鉛塩を配合するこ
とが好ましく、亜鉛塩を第1香料群の香料と併用するこ
とにより、タバコヤニ消臭効果に更に優れ、使用感の良
いタバコヤニ消臭用組成物を得ることができる。Furthermore, it is preferable to incorporate a zinc salt into the oral composition of the present invention, and by using the zinc salt in combination with the fragrance of the first fragrance group, a tobacco tar deodorizer with even better tobacco tar deodorizing effect and a pleasant feeling of use can be obtained. An odor composition can be obtained.
ここで、亜鉛塩は、無機酸の塩でも有機酸の塩でもよく
、具体的には塩化亜鉛、クエン酸亜鉛、酢酸亜鉛、乳酸
亜鉛、サリチル酸亜鉛、硫酸亜鉛等が例示され、これら
の1種又は2種以上を併用して配合することが好ましい
。Here, the zinc salt may be an inorganic acid salt or an organic acid salt, and specific examples thereof include zinc chloride, zinc citrate, zinc acetate, zinc lactate, zinc salicylate, zinc sulfate, etc. Alternatively, it is preferable to use two or more kinds in combination.
また、配合量に特に制限はないが、口腔用組成物の全成
分量に対し0.01〜1重量%とすることが好ましい。Further, although there is no particular restriction on the amount to be added, it is preferably 0.01 to 1% by weight based on the total amount of components of the oral composition.
なお、本発明には、前記第1.第2.第3香料群の香料
に加えて更に他の香料、例えばエッチ・ビー・ハース(
H、B 、 Heath)の「ソース・ブック・オブ1
フレーバー(S ouce B ook of F 1
avor)。Note that the present invention includes the above-mentioned No. 1. Second. In addition to the fragrances of the third fragrance group, there are also other fragrances, such as H.B. Hearth (
Source Book of 1 by H.B. Heath)
Flavor (Souse Book of F 1
avor).
AVI、No、6〜9,1981Jに記載されている香
料を配合することができる。Perfumes described in AVI, No. 6-9, 1981J can be blended.
また、本発明の口腔用組成物のその他の成分としては、
その種類、使用目的等に応じた適宜な成分が選択、配合
され得る。例えば、マウスウォッシュを調製する場合に
は、エタノール、多価アルコール、界面活性剤、甘味剤
、防腐剤、色素などが配合され、また歯磨の調製には、
研磨剤、粘結剤、粘稠剤、界面活性剤、甘味剤、防腐剤
、色素などが配合され得る。In addition, other components of the oral composition of the present invention include:
Appropriate components can be selected and blended depending on the type, purpose of use, etc. For example, when preparing mouthwash, ethanol, polyhydric alcohol, surfactants, sweeteners, preservatives, pigments, etc. are mixed, and when preparing toothpaste,
Abrasives, binders, thickeners, surfactants, sweeteners, preservatives, pigments, etc. may be added.
見所五羞米
本発明のタバコヤニ消臭用口腔用組成物は、特定の香料
の配合により、喫煙者の日中より発するタバコヤニの不
快臭を効果的に消臭して臭いを低減させるものである。Highlights: The tobacco tar deodorizing oral composition of the present invention effectively eliminates and reduces the unpleasant tobacco tar odor emitted by smokers during the day by incorporating a specific flavoring agent. .
次に実験例により本発明の効果を具体的に示す。Next, the effects of the present invention will be specifically illustrated by experimental examples.
〔実験例1〕
グラスウールを詰めたトラップにタバコの煙を通じた後
、グラスウールに付着したタバコヤニをエタノールに溶
解し、このエタノールをエバポレーターにて留去してタ
バコヤニ抽出物を得た。この抽出物を純水に溶かして不
溶物を炉別した後、50ppmの水溶液とし、これをタ
バコヤニ標準液とした。[Experimental Example 1] After passing tobacco smoke through a trap filled with glass wool, tobacco tar adhering to the glass wool was dissolved in ethanol, and the ethanol was distilled off using an evaporator to obtain a tobacco tar extract. This extract was dissolved in pure water and insoluble matter was removed by a furnace, and then a 50 ppm aqueous solution was prepared, which was used as a tobacco tar standard solution.
次いで、タバコヤニ標準液と第1表に示す各種天然香料
(精油、アブソリュート、コンクリート、チンキ、レジ
ノイド)とを用い、下記処方にてサンプル液を調製し、
タバコヤニ標準液に対する各種天然香料配合サンプル液
のタバコヤニ臭の強さを官能評価した。Next, a sample solution was prepared using the tobacco tar standard solution and various natural fragrances (essential oil, absolute, concrete, tincture, resinoid) shown in Table 1 according to the following formulation.
The intensity of the tobacco tar odor of various natural flavored sample solutions was sensory evaluated against the tobacco tar standard solution.
天然香料 合サンプル 方
タバコヤニ標準液 90重量%
天然香料 0.001//ポリ
オキシエチレン硬化ヒマシ油(60モル)0.05
〃エタノール 1.
94.9/1純 水
8計 100
.0重量%なお、サンプル液のタバコヤニ臭の強さの官
能評価は、10名のパネラ−がサンプル液調製直後と1
時間後において1度に5種類のサンプル液を下記基準に
従い評価することにより行なった。Natural flavor mixture sample Tobacco tar standard solution 90% by weight
Natural fragrance 0.001 // Polyoxyethylene hydrogenated castor oil (60 mol) 0.05
〃Ethanol 1.
94.9/1 pure water
8 total 100
.. 0% by weight In addition, the sensory evaluation of the strength of the tobacco tar odor of the sample liquid was conducted by 10 panelists: immediately after preparing the sample liquid, and 1% after the preparation of the sample liquid.
After a period of time, five types of sample liquids were evaluated at once according to the following criteria.
ゞ及び基′
タバコヤニ標準液と天然香料配合サンプル液とを各々ビ
ーカーに取り入れ、そのタバコヤニ臭を下記基準にて評
価した。A tobacco tar standard solution and a natural flavoring sample solution were each placed in a beaker, and the tobacco tar odor thereof was evaluated according to the following criteria.
4:タバコヤニ臭をほとんど感じない。4: Almost no tobacco tar odor.
3: をわずかに感じる。3: Slightly felt.
2: を感じるが、タバコヤニ標準液より弱
い。2: I can feel it, but it is weaker than the tobacco tar standard solution.
1:タバコヤニ標準液に比ベタバコヤニ臭の強さはほと
んど変わらないか、或いはむしろ強くなっている。1: Compared to the tobacco tar standard solution, the intensity of the tobacco tar odor is almost the same, or even stronger.
結果を第1表に示す。なお、結果は10名のパネラ−の
評点の平均値で示す。The results are shown in Table 1. Note that the results are shown as the average value of the scores of 10 panelists.
第1−1表
7N開口HG3−66115(6)
第1−2表
第]−−3表
第1表の結果より、精油としてアンプレッドシード油、
シナモン油、クミン油、ゼラニウム油、ロベージ油、ア
ブソリュートとしてイモ−チル、ミモザリーフが優れた
タバコヤニ消臭力を示すことが知見された。Table 1-1 7N opening HG3-66115 (6) Table 1-2 ]--Table 3 From the results in Table 1, amplified seed oil as essential oil,
It has been found that cinnamon oil, cumin oil, geranium oil, lovage oil, absolute immotyl, and mimosa leaf exhibit excellent tobacco tar deodorizing power.
〔実験例2〕
実験例1と同様にして調製したタバコヤニ標準液50
mQに第2〜4表に示す成分組成で調製したマウスウォ
ッシュサンプル2.0gを添加し、均一に混合した後、
30分後に実験例1と同様の方法でタバコヤニ臭の強さ
と香味特性を評価した。[Experimental Example 2] Tobacco resin standard solution 50 prepared in the same manner as Experimental Example 1
After adding 2.0 g of mouthwash sample prepared with the ingredient composition shown in Tables 2 to 4 to mQ and mixing uniformly,
After 30 minutes, the intensity of tobacco tar odor and flavor characteristics were evaluated in the same manner as in Experimental Example 1.
なお、香味特性は10名のパネラ−を用い、下記基準に
従って評価した。The flavor characteristics were evaluated by 10 panelists according to the following criteria.
香味特性評価基準
A、香りの良さ B、味の良さ
5、良い 5.良い
4、やや良い 4.やや良い
3、ふつう 3.ふつう
2、やや悪い 2.やや悪い
1、悪い 1+悪い
結果を第2表に示す。なお、結果は10名のパネラ−の
評点の平均値で示す。Flavor characteristic evaluation criteria A, good aroma B, good taste 5, good 5. Good 4, Fairly good 4. Fairly good 3, Fair 3. Fair 2, Fair 2. Table 2 shows the results of "slightly poor 1" and "poor 1" + "poor." Note that the results are shown as the average value of the scores of 10 panelists.
第 4 表
以下、実施例を挙げて本発明を更に具体的に説明するが
、本発明は下記の実施例に制限されるものではない。Table 4 Hereinafter, the present invention will be explained in more detail with reference to examples, but the present invention is not limited to the following examples.
〔実施例1〜16〕
下記に示す成分組成のマウスウォッシュ(実施例1〜6
)、練歯磨(実施例7〜12)、潤製歯磨(実施例13
)、液状歯磨(実施例14)、口腔用パスタ(実施例1
5)、スプレータイプ日中清涼剤(実施例16)を各々
常法により調製した。[Examples 1 to 16] Mouthwashes with the ingredient compositions shown below (Examples 1 to 6)
), toothpaste (Examples 7 to 12), Junsei toothpaste (Example 13)
), liquid toothpaste (Example 14), oral pasta (Example 1)
5) and a spray type daytime refreshing agent (Example 16) were each prepared by conventional methods.
この口腔用組成物のタバコヤニ臭の消臭効果と使用感を
評価したところ、いずれの口腔用組成物も消臭効果に優
れ、使用感も良好であった。When the tobacco tar odor deodorizing effect and feeling of use of these oral compositions were evaluated, all oral compositions had excellent deodorizing effect and good feeling of use.
〔実施例1〕 7′″″′ウオン′°(単位8重量%
)エチルアルコール 10
.0グリセリン 10.
0クエン酸
0.1クエン酸ナトリウム
0.4安息香酸ナトリウム
0.3ラウリル硫酸ナトリウム
0.5サツカリンナトリウム
0.05緑色3号
0.001黄色203号
0.00LP、○、E、(40
)硬化ヒマシ油 2・0塩化亜鉛
0.IQ−メント
ール 0.2ア
ンプレットシード油 0.0
05クミン油
0.005シナモン油
0.001ペパーミント油
0.1フルーツコンパウンド
0.05アネトール
0.05精製水
残
計 100.0
〔実施例2〕 マウスウォッシー (単位2重
量%)エチルアルコール
15.0ソルビツト
10.0クエン酸
0.05クエン酸ナトリウム
0.2安息香酸ナトリウム
0.2ラウリル硫酸ナトリウム
0.3サツカリンナトリウム
0.05青色1号
0.001黄色4号
0.001P、O
,E、(40)硬化ヒマシ油 3,5
セチルピリジニウムクロライド 0.
05臭化ドミフエン
0.005a−メントール
0.1ゼラニウム油
0.005ミモザアブソリユート
0.005ベルガモツト油
0.005スペアミント油
0.01セージスパニツ
シユ油 0.005ヒソップ
油 0.003
クローブパツド油 0.
005アネトール
0.01精製水 残
計 100.0
〔実施例3〕 ″′悼ウつツ”’ C単位:
iff、量%)エチルアルコール
20.0グリセリン
5.0ソルビツト
5.0クエン酸
0.1クエン酸ナトリウム
0.4安息香酸ナトリウム
0.1ラウリル硫酸ナトリウム
0.1サッカリンナトリウム
0.05緑色1号
0.001黄色4号
0.001P、
O,E、(40)硬化ヒマシ油 2.
0クエン酸亜鉛 0
.2Q−メントール
0・I5クミン油
0.001シナモン油
0.001イモーテルアブソリュート
0.007ホツプ油
0.001サリチル酸
メチル 0.4シネオー
ル 0.014
ベンズアルデヒド 0.
01ペパーミント油
0.003クローブパツド油
0.007フルーツコンパウンド
0.05アネトール
0.05計
100.0〔実施例4〕 7′″′
−′−ウオツシ“ (単位8重量%)エチルアル
コール 5.0グリセリ
ン 15.0クエン酸
0.05クエ
ン酸ナトリウム 0.2
メチルパラベン 0.
1サツカリンナトリウム
0.05青色1号
0.001黄色203号
0.001プルロニックF−1273,0
酢酸亜鉛 0.
2Q−メントール
0.3アンプレツトシード油
0.001ゼラニウム油
0.0010ページ油
0.003イモーテルアブソリュ
ート 0.002ミモザアブソリ
ユート 0.005カルダモ
ン油 0.005
バジル油 0
.001ダバナ油
0.001ボアドローズ油
0.01カモミルブルー油
0.001コリアンダー油
0.005シネオール
0.01ペパーミント油
0.2フルーツコン
パウンド 0.001アネト
ール 0.02
精製水 残
計 100.0
〔実施例5〕7′″)″−ウオ・′°(単位2重量%)
エチルアルコール 10.
0グリセリン 10.
Oクエン酸
0.1クエン酸ナトリウム
0.4メチルパラベン
0.05ラウリル硫酸ナトリウム
0.5サツカリンナトリウム
0.05緑色3号
0.001黄色203号
0.001P、○、E、
(40)硬化ヒマシ油 2.0乳酸亜
鉛 0.5Q−
メントール 0.2ク
ミン油 0.
001ミモザアブソリユート
0.002スペアミント油
0.2クラリセージ油
0.001キヤロツト油
0.01エストラゴン油
0.01ペニロイヤル油
0.01Q−カルボン
0.05ペパーミ
ント油 0.05アネ
トール o、0
3精製水 残
計 100.0
〔実施例6〕 ″″″″7′° (単位・重量
%)エチルアルコール 1
5.0グリセリン 1
0.0クエン酸
0.05クエン酸ナトリウム
0.2ラウリル硫酸ナトリウム
0.3サッカリンナトリウム
0.05青色1号
0.001黄色4号
0.001P、O,E、
(40)硬化ヒマシ油 1.0サリ
チル酸亜鉛 0.50
−メントール 0.0
7シナモン油
0.005イモーテルアブソリュート
0.002ミモザアブソリユート
0.002セージスパニツシユ油
0.001ホツプ油
0.001ヒソップ油
0.001キヤロ
ツト油 0.00
5コリアンダー油 0.
01シネオール
0.01ペパーミント油
o、02フルーツコンパウンド
0.01アネトール
0.01計
ioo、。[Example 1] 7''''''won'° (unit: 8% by weight)
) Ethyl alcohol 10
.. 0 Glycerin 10.
0 citric acid
0.1 Sodium citrate
0.4 Sodium benzoate
0.3 Sodium lauryl sulfate
0.5 Satucalin Sodium
0.05 Green No. 3
0.001 Yellow No. 203
0.00LP, ○, E, (40
) Hydrogenated castor oil 2.0 zinc chloride
0. IQ-Menthol 0.2 Amplet Seed Oil 0.0
05 Cumin oil
0.005 cinnamon oil
0.001 peppermint oil
0.1 fruit compound
0.05 Anethole
0.05 purified water
Remaining total 100.0
[Example 2] Mouthwash (unit: 2% by weight) Ethyl alcohol
15.0 sorbit
10.0 citric acid
0.05 Sodium citrate
0.2 Sodium benzoate
0.2 Sodium lauryl sulfate
0.3 Satucalin Sodium
0.05 Blue No. 1
0.001 Yellow No. 4
0.001P, O
,E, (40) Hydrogenated castor oil 3,5
Cetylpyridinium chloride 0.
05 Domifuene bromide
0.005a-menthol
0.1 geranium oil
0.005 Mimosa Absolute
0.005 bergamot oil
0.005 spearmint oil
0.01 Sage spanish oil 0.005 Hyssop oil 0.003
Clove pad oil 0.
005 Anethole
0.01 Purified water Remaining total 100.0
[Example 3] ``Mourning Utsutsu''' C unit:
if, amount%) ethyl alcohol
20.0 Glycerin
5.0 sorbit
5.0 citric acid
0.1 Sodium citrate
0.4 Sodium benzoate
0.1 Sodium lauryl sulfate
0.1 saccharin sodium
0.05 Green No. 1
0.001 Yellow No. 4
0.001P,
O, E, (40) Hydrogenated castor oil 2.
0 Zinc citrate 0
.. 2Q-Menthol
0.I5 cumin oil
0.001 cinnamon oil
0.001 Immortelle Absolute 0.007 Hop Oil
0.001 Methyl salicylate 0.4 Cineole 0.014
Benzaldehyde 0.
01 peppermint oil
0.003 clove pad oil
0.007 fruit compound
0.05 Anethole
0.05 total
100.0 [Example 4] 7′″′
-'-Watertail (Unit: 8% by weight) Ethyl alcohol 5.0 Glycerin 15.0 Citric acid
0.05 Sodium citrate 0.2
Methylparaben 0.
1Sactucalin sodium
0.05 Blue No. 1
0.001 Yellow No. 203
0.001 Pluronic F-1273.0 Zinc acetate 0.
2Q-Menthol
0.3 amplified seed oil
0.001 geranium oil
0.0010 pages oil
0.003 Immortelle Absolute 0.002 Mimosa Absolute 0.005 Cardamom Oil 0.005
Basil oil 0
.. 001 Davana oil
0.001 bore rose oil
0.01 chamomile blue oil
0.001 coriander oil
0.005 cineole
0.01 Peppermint oil 0.2 Fruit compound 0.001 Anethole 0.02
Purified water balance 100.0
[Example 5] 7′″)″-Uo・′° (unit: 2% by weight)
Ethyl alcohol 10.
0 Glycerin 10.
O citric acid
0.1 Sodium citrate
0.4 methylparaben
0.05 Sodium lauryl sulfate
0.5 Satucalin Sodium
0.05 Green No. 3
0.001 Yellow No. 203
0.001P, ○, E,
(40) Hydrogenated castor oil 2.0 Zinc lactate 0.5Q-
Menthol 0.2 Cumin oil 0.
001 Mimosa Absolute
0.002 spearmint oil
0.2 clary sage oil
0.001 carrot oil
0.01 Estragon oil
0.01 pennyroyal oil
0.01Q-carvone
0.05 Peppermint oil 0.05 Anethole o, 0
3 Purified water remaining total 100.0
[Example 6] ″″″″7′° (Unit/weight %) Ethyl alcohol 1
5.0 Glycerin 1
0.0 citric acid
0.05 Sodium citrate
0.2 Sodium lauryl sulfate
0.3 saccharin sodium
0.05 Blue No. 1
0.001 Yellow No. 4
0.001P, O, E,
(40) Hydrogenated castor oil 1.0 Zinc salicylate 0.50
-Menthol 0.0
7 cinnamon oil
0.005 Immortal Absolute
0.002 Mimosa Absolute
0.002 Sage spanish oil
0.001 hop oil
0.001 hyssop oil
0.001 Carrot oil 0.00
5 Coriander oil 0.
01 Cineole
0.01 peppermint oil
o, 02 fruit compound
0.01 Anethole
0.01 total
ioo,.
〔実施例7〕 練 歯 磨 (単位2重量
%)第2リン酸カルシウム
50カルボキシメチルセルロースナトリウム
0.5カラギーナン
0.5グリセリン
1゜ソルビット 1
0プロピレングリコール 2
.0ラウリル硫酸ナトリウム
1.5安息香酸ナトリウム
0.1メチルパラベン
0.1サツカリンナトリウム
0.1塩化亜鉛
0.2Q−メントール
0.1クミン油
0.001イモーテルアブソリュ
ート 0.002スペアミント油
0.4サルチル酸メ
チル 0. IQ−
カルボン 0.0
5ペパーミント油 0
.3クローブパツド油
0.0iフルーツコンパウンド
0.001アネトール
0.08精製水 残
計 100.
0〔実施例8〕 練 歯 磨 (単位2重
量%)水酸化アルミニウム
4゜カラギーナン
0.5アルギン酸ナトリウム
0.5ソルビツト
30プロピレングリコール
2.0ラウリル硫酸ナトリウム
1.5ラウリン酸ジエタノールアミド
0.3安息香酸ナトリウム
0.1メチルパラベン
0.1サツカリンナトリウム
0.1モノフルオロリン酸ナトリ
ウム 0.76デキストラナーゼ(
100万u/g) 0.2クエン酸亜鉛
0.2P、○、E
、(4−0)硬化ヒマシ油 0.5Q
−メントール 0.
10ベージ油
0.002イモーテルアブソリュート
00OO3キヤロツト油
0.01サリチル酸メチル
0.5シネオール
0.01ベンズアルデヒド
0.01ペパーミント油
0・1クローブパツド油
0.01フルーツコ
ンパウンド 0.001アネ
トール 0.0
1計 100.
0〔実施例9〕 練 歯 磨 (11’−
位: f(量%)炭酸カルシウム
40カルボキシメチルセルロースナトリウム
1.0ソルビツト
20プロピレングリコール
2.0エチルアルコール
0.5ラウリル硫酸ナトリウム
1.5安息香酸ナトリウム
0.5−詞一
サッカリンナトリウム 0
,1トラネキサム酸
0・1塩化ナトリウム
10Ω−メントール
0.1アンプレツトシード油
0.001シナモン油
0.001ゼラニウム油
0.001ミモザアブソリユー
ト 0.001カルダモン
油 0.001ス
ペアミント油 0.4
セージスパニツシユ油 0.
001ホツプ油
0.001ボアドローズ油
0.01カモミルブルー油
0.001シネオール
0.2Q−カルボン
0.1ペパーミント油
0.25クローブバツド油
0.005フルーツコ
ンパウンド 0.002アネ
トール 0・0
5=35−
計 100.0
〔実施例10〕 練 歯 磨 (単イ立8重
量%)ジルコノシリケート
30無水ケイ酸 2
カルボキシメチルセルロースナトリウム 1.
0ソルビツト 30
ポリエチレングリコール1400 5.
0ラウリル硫酸ナトリウム 1
.5ラウリン酸ジエタノールアミド
0.3メチルパラベン
0.1ブチルパラベン
0・1サツカリンナトリウム
0.14青色1号
0.001塩酸クロルヘキシジン
0.01塩化亜鉛
0.10−メントール
0.25クミン油
0.002ベルガモ
ツト油 0.001
バジル油 0
.001クラリセージ油
0.001ダバナ油
0.001ヒソップ油
0.001コリアンダー油
0.’01サリチル酸メチ
ル 0.25ベンズアル
デヒド 0.15精製水
残
計 100.0
〔実施例11〕 練 歯 磨 (単位3重
量%)無水ケイ酸
25カルボキシメチルセルロースナトリウム
1.0ソルビツト
30ポリエチレングリコール#400
5.0ラウリル硫酸ナトリウム
1.5ラウロイルサルコシン酸ナトリウム
0.3ラウリン酸ジエタノールアミド
0.3メチルパラベン
0・1ブチルパラベン
0・1サツカリンナトリウム
0.12青色1号
0.001塩化亜鉛
0.IQ−メントール
0.1ゼラニウム油
0.001ミモザ
アブソリユート 0.001
スペアミント油 0.
3エストラゴン油 0
.01ペニロイヤル油
0.01サリチル酸メチル
0.1シネオール
0.01ベンズアルデヒド
O,01Q−カルボン
0.1ペパーミント油
0.2アネトール
0.01計
100.0第2リン酸カルシウ
ム 40無水ケイ酸
2カルボキシメチルセル
ロースナトリウム 1.0グリセリン
15ポリエチレングリコール#
400 3.0ラウリル硫酸ナトリウム
1.0ラウロイルサルコシン
酸ナトリウム 0.3メチルパラベン
0・2ブチルパラベン
0・1サツカリンナ
トリウム 0.1トラネキ
サム酸 0.1酢酸ト
コフエロール 0.1β−
グリチルリチン酸 0.0
5塩酸クロルヘキシジン 0
.02クエン酸亜鉛
0.IQ−メントール
0.1アンプリツトシード油
0.0010ページ油
0.001ベルガモツト油
0.001カルダモン油
0.001ボアドローズ
油 0.01サリチ
ル酸メチル 0.05シ
ネオール 0.0
3ベンズアルデヒド 0
.02フルーツコンパウンド
0.4精製水 残
計 100.
0〔実施例13〕 潤製歯磨 (単位2重
量%)炭酸カルシウム
80無水ケイ酸
2.0ポリエチレングリコール#4000
1.0ポリエチレングリコール#400
10ラウリル硫酸ナトリウム
1.5サツカリンナトリウム
0.1塩化亜鉛
0.IQ−メントール
0.2ペパーミント油
0.1アネトール
0.05シネオール
0.1ベンズアルデヒド
0.01イモーテルアブソ
リュート 0.002フルーツコ
ンパウンド 0.005計
100.0グリ
セリン 35プロピレン
グリコール 5.0ポリアク
リル酸ナトリウム 2.0ラウリ
ル硫酸ナトリウム 1.0ラウ
リン酸ジエタノールアミド 1.5サ
ツカリンナトリウム 0.
2安息香酸ナトリウム 0
.3塩化亜鉛
0.IP、O,E、(60)硬化ヒマシ油
2.OQ−メントール
0.1℃−カルボン
0.1ペパーミント油
0.1スペアミント油
0.2アネトール
0.05サリチル酸メチル
0.2ベンズアルデヒ
ド 0.1クミン油
0.005クロ
ーブパツド油 0.0
05精製水 残
計 100.0
〔実施例15〕 1腔用A 、7.9 (単
位二重量%)流動パラフィン
25ソルビツト
15セタノール
5.0パラフインろう
5.0マイクロクリスタリンろう
10メチルパラベン
0.2安息香酸ナトリウム
0.1塩化亜鉛
0.IP、O,E、(40)硬化ヒ
マシ油 4.OQ−メントール
0・5サリチル酸メチル
0.8クミン油
0.005フルー
ツコンパウンド 0.05精
製氷 残[Example 7] Toothpaste (unit: 2% by weight) dibasic calcium phosphate
50 carboxymethyl cellulose sodium
0.5 carrageenan
0.5 glycerin
1゜Sorvit 1
0 propylene glycol 2
.. 0 Sodium lauryl sulfate
1.5 Sodium benzoate
0.1 methylparaben
0.1 Satucalin Sodium
0.1 zinc chloride
0.2Q-menthol
0.1 cumin oil
0.001 Immortelle Absolute 0.002 Spearmint Oil 0.4 Methyl Salicylate 0. IQ-
Carvone 0.0
5 peppermint oil 0
.. 3 clove pad oil
0.0i fruit compound
0.001 Anethole
0.08 Purified water balance 100.
0 [Example 8] Toothpaste (unit: 2% by weight) Aluminum hydroxide
4゜Carrageenan
0.5 Sodium alginate
0.5 sorbit
30 propylene glycol
2.0 Sodium lauryl sulfate
1.5 Lauric acid diethanolamide
0.3 Sodium benzoate
0.1 methylparaben
0.1 Satucalin Sodium
0.1 Sodium monofluorophosphate 0.76 Dextranase (
1 million u/g) 0.2 Zinc citrate 0.2P, ○, E
, (4-0) Hydrogenated castor oil 0.5Q
-Menthol 0.
10 base oil
0.002 Immortal Absolute
00OO3 Carrot oil
0.01 Methyl salicylate
0.5 cineole
0.01 benzaldehyde
0.01 peppermint oil
0.1 clove pad oil 0.01 fruit compound 0.001 anethole 0.0
1 total 100.
0 [Example 9] Toothpaste (11'-
Place: f (amount %) calcium carbonate
40 Sodium carboxymethylcellulose 1.0 Sorbit
20 propylene glycol
2.0 ethyl alcohol
0.5 Sodium lauryl sulfate
1.5 Sodium benzoate
0.5-Saccharin Sodium 0
,1 tranexamic acid
0.1 sodium chloride
10Ω-menthol
0.1 amplified seed oil
0.001 cinnamon oil
0.001 geranium oil
0.001 Mimosa absolute 0.001 Cardamom oil 0.001 Spearmint oil 0.4
Sage spanish oil 0.
001 hop oil
0.001 bore rose oil
0.01 chamomile blue oil
0.001 cineole
0.2Q-carvone
0.1 peppermint oil
0.25 Clove Butt Oil 0.005 Fruit Compound 0.002 Anethole 0.0
5=35- total 100.0
[Example 10] Toothpaste (single powder 8% by weight) Zirconosilicate
30 Silicic anhydride 2
Carboxymethyl cellulose sodium 1.
0 sorbit 30
Polyethylene glycol 1400 5.
0 Sodium lauryl sulfate 1
.. 5 Lauric acid diethanolamide
0.3 methylparaben
0.1 Butylparaben
0.1 satsucalin sodium
0.14 Blue No. 1
0.001 Chlorhexidine hydrochloride
0.01 zinc chloride
0.10-menthol
0.25 cumin oil
0.002 Bergamot oil 0.001
Basil oil 0
.. 001 clary sage oil
0.001 Davana oil
0.001 hyssop oil
0.001 coriander oil
0. '01 Methyl salicylate 0.25 Benzaldehyde 0.15 Purified water Remaining total 100.0
[Example 11] Toothpaste (unit: 3% by weight) Silicic anhydride
25 carboxymethylcellulose sodium
1.0 sorbit
30 polyethylene glycol #400
5.0 Sodium lauryl sulfate
1.5 Sodium lauroyl sarcosinate
0.3 Lauric acid diethanolamide
0.3 methylparaben
0.1 butylparaben
0.1 satsucalin sodium
0.12 Blue No. 1
0.001 zinc chloride
0. IQ-menthol
0.1 geranium oil
0.001 Mimosa Absolute 0.001
Spearmint oil 0.
3 Estragon oil 0
.. 01 Peniroyal oil
0.01 Methyl salicylate
0.1 cineole
0.01 benzaldehyde
O,01Q-carvone
0.1 peppermint oil
0.2 Anethole
0.01 total
100.0 Dibasic calcium phosphate 40 Silicic anhydride
2 Sodium carboxymethyl cellulose 1.0 Glycerin
15 polyethylene glycol #
400 3.0 Sodium lauryl sulfate 1.0 Sodium lauroyl sarcosinate 0.3 Methylparaben
0.2-butylparaben
0.1 Sacchulin sodium 0.1 Tranexamic acid 0.1 Tocopherol acetate 0.1β-
Glycyrrhizic acid 0.0
Chlorhexidine 5-hydrochloride 0
.. 02 Zinc citrate
0. IQ-menthol
0.1 Amplified Seed Oil
0.0010 pages oil
0.001 bergamot oil
0.001 cardamom oil
0.001 Bored rose oil 0.01 Methyl salicylate 0.05 Cineole 0.0
3 Benzaldehyde 0
.. 02 fruit compound
0.4 Purified water balance 100.
0 [Example 13] Junsei toothpaste (unit: 2% by weight) calcium carbonate
80 silicic anhydride
2.0 polyethylene glycol #4000
1.0 polyethylene glycol #400
10 Sodium lauryl sulfate
1.5 Satucalin Sodium
0.1 zinc chloride
0. IQ-menthol
0.2 peppermint oil
0.1 anethole
0.05 cineole
0.1 benzaldehyde
0.01 Immortelle Absolute 0.002 Fruit Compound 0.005 Total
100.0 Glycerin 35 Propylene Glycol 5.0 Sodium Polyacrylate 2.0 Sodium Lauryl Sulfate 1.0 Lauric Diethanolamide 1.5 Saccharin Sodium 0.
Sodium dibenzoate 0
.. Zinc trichloride
0. IP, O, E, (60) Hydrogenated castor oil
2. OQ-Menthol
0.1℃-carvone
0.1 peppermint oil
0.1 spearmint oil
0.2 Anethole
0.05 Methyl salicylate 0.2 Benzaldehyde 0.1 Cumin oil
0.005 Clove pad oil 0.0
05 Purified water balance 100.0
[Example 15] Single cavity A, 7.9 (unit duplex weight %) liquid paraffin
25 sorbit
15 cetanol
5.0 paraffin wax
5.0 microcrystalline wax
10 methylparaben
0.2 Sodium benzoate
0.1 zinc chloride
0. IP, O, E, (40) Hydrogenated castor oil 4. OQ-Menthol
0.5 Methyl salicylate 0.8 Cumin oil
0.005 fruit compound 0.05 purified ice remainder
Claims (1)
上の香料成分を配合してなることを特徴とするタバコヤ
ニ消臭用口腔用組成物。 (1)アンブレットリド及びアンブレットリドを主香成
分とする精油、クミンアルデヒド及びクミンアルデヒド
を主香成分とする精油、並びにシナモン油、ゼラニウム
油、ロベージ油、イモーテルアブソリュート及びミモザ
アブソリュート。 2、上記(1)よりなる群から選ばれる1種又は2種以
上の香料成分の配合量が0.001〜0.5重量%であ
る特許請求の範囲第1項記載のタバコヤニ消臭用口腔用
組成物。 3、上記(1)よりなる群から選ばれる1種又は2種以
上の香料成分に下記(2)よりなる群から選ばれる1種
又は2種以上の植物の精油を併用してなることを特徴と
する特許請求の範囲第1項記載のタバコヤニ消臭用口腔
用組成物。 (2)ベルガモット、カルダモン、スペアミント、セー
ジスパニッシュ、バジル、ホップ、クラリセージ、ダバ
ナ及びヒソップ。 4、上記(1)よりなる群から選ばれる1種又は2種以
上の香料成分と、上記(2)よりなる群から選ばれる1
種又は2種以上の植物の精油との総配合量が0.001
〜0.5重量%である特許請求の範囲第3項記載のタバ
コヤニ消臭用口腔用組成物。 5、下記(3)よりなる群から選ばれる1種又は2種以
上の香料成分を配合してなることを特徴とする特許請求
の範囲第1項乃至第4項のいずれか1項に記載のタバコ
ヤニ消臭用口腔用組成物。 (3)ボアドローズ油、カモミルブルー油、キャロット
油、コリアンダー油、エストラゴン油、ペニロイヤル油
、サリチル酸メチル及びこれを主香成分とする精油、シ
ネオール及びこれを主香成分とする精油、並びにベンズ
アルデヒド。 6、上記(3)よりなる群から選ばれる1種又は2種以
上の香料成分の配合量が組成物全体の0.01〜5重量
%である特許請求の範囲第5項記載のタバコヤニ消臭用
口腔用組成物。 7、亜鉛塩を0.01〜1重量%配合してなることを特
徴とする特許請求の範囲第1項乃至第6項のいずれか1
項に記載のタバコヤニ消臭用口腔用組成物。 8、亜鉛塩が塩化亜鉛、クエン酸亜鉛、酢酸亜鉛、乳酸
亜鉛、サリチル酸亜鉛及び硫酸亜鉛よりなる群から選ば
れた1種又は2種以上である特許請求の範囲第7項記載
のタバコヤニ消臭用口腔用組成物。[Scope of Claims] 1. An oral composition for deodorizing tobacco tar, which contains one or more flavor components selected from the group consisting of (1) below. (1) Ambrettolide and essential oils containing ambrettolide as the main fragrance ingredient, cumin aldehyde and essential oils containing cumin aldehyde as the main fragrance ingredient, cinnamon oil, geranium oil, lovage oil, immortelle absolute and mimosa absolute. 2. The tobacco tar deodorizing oral cavity according to claim 1, wherein the amount of one or more flavor components selected from the group consisting of (1) is 0.001 to 0.5% by weight. Composition for use. 3. It is characterized by the combination of one or more fragrance ingredients selected from the group consisting of (1) above and one or more essential oils of plants selected from the group consisting of (2) below. A tobacco tar deodorizing oral composition according to claim 1. (2) Bergamot, cardamom, spearmint, sage Spanish, basil, hops, clary sage, davana and hyssop. 4. One or more fragrance ingredients selected from the group consisting of (1) above, and 1 selected from the group consisting of (2) above.
The total amount of essential oils from seeds or two or more plants is 0.001
The tobacco tar deodorizing oral composition according to claim 3, wherein the tobacco tar deodorizing composition is 0.5% by weight. 5. The composition according to any one of claims 1 to 4, characterized in that it contains one or more fragrance ingredients selected from the group consisting of the following (3): Oral composition for deodorizing tobacco tar. (3) Bored rose oil, chamomile blue oil, carrot oil, coriander oil, estragon oil, penyroyal oil, methyl salicylate and essential oils containing this as the main fragrance ingredient, cineol and essential oils containing this as the main fragrance ingredient, and benzaldehyde. 6. The tobacco tar deodorizer according to claim 5, wherein the amount of one or more flavor components selected from the group consisting of (3) above is 0.01 to 5% by weight of the entire composition. Oral composition for use. 7. Any one of claims 1 to 6, characterized in that it contains 0.01 to 1% by weight of zinc salt.
2. The tobacco tar deodorizing oral composition described in 1. 8. The tobacco tar deodorizer according to claim 7, wherein the zinc salt is one or more selected from the group consisting of zinc chloride, zinc citrate, zinc acetate, zinc lactate, zinc salicylate, and zinc sulfate. Oral composition for use.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP61210582A JPH0816049B2 (en) | 1986-09-09 | 1986-09-09 | Oral composition for deodorizing tobacco tar |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP61210582A JPH0816049B2 (en) | 1986-09-09 | 1986-09-09 | Oral composition for deodorizing tobacco tar |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS6366115A true JPS6366115A (en) | 1988-03-24 |
JPH0816049B2 JPH0816049B2 (en) | 1996-02-21 |
Family
ID=16591700
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP61210582A Expired - Fee Related JPH0816049B2 (en) | 1986-09-09 | 1986-09-09 | Oral composition for deodorizing tobacco tar |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH0816049B2 (en) |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1995015186A1 (en) * | 1993-11-30 | 1995-06-08 | Quest International B.V. | Anti-smoke perfumes and compositions |
JPH11246376A (en) * | 1998-02-27 | 1999-09-14 | Sunstar Inc | Composition for oral cavity |
WO2000028952A1 (en) * | 1998-11-12 | 2000-05-25 | Block Drug Company, Inc. | Flavour blend for masking unpleasant taste of zinc compounds |
GB2357967A (en) * | 2000-01-06 | 2001-07-11 | Mars Uk Ltd | Antibacterial agents |
JP2002104947A (en) * | 2000-09-29 | 2002-04-10 | Kobayashi Pharmaceut Co Ltd | Deodorant |
JP2002275495A (en) * | 2001-03-16 | 2002-09-25 | Takasago Internatl Corp | Perfumery composition for eliminating tobacco smell |
WO2006093311A1 (en) * | 2005-03-01 | 2006-09-08 | Ajinomoto Co., Inc. | Detergent composition |
JP2007153841A (en) * | 2005-12-07 | 2007-06-21 | Wakoudou Kk | Oral composition |
US8741275B2 (en) | 2010-06-04 | 2014-06-03 | Robetet, Inc. | Malodor neutralizing compositions comprising undecylenic acid or citric acid |
JP2015081237A (en) * | 2013-10-22 | 2015-04-27 | 花王株式会社 | Agent of inhibiting odors caused by sotolon |
US9114180B2 (en) | 2012-03-30 | 2015-08-25 | Robertet, Inc. | Malodor neutralizing compositions containing acids and alicyclic ketones |
US9200241B2 (en) | 2011-01-27 | 2015-12-01 | Robertet, Inc. | Malodor neutralizing compositions comprising bornyl acetate or isobornyl acetate |
CN111603416A (en) * | 2019-02-22 | 2020-09-01 | 好维股份有限公司 | Oral care compositions comprising hops extract |
JP2021104976A (en) * | 2019-12-26 | 2021-07-26 | サンスター株式会社 | Oral composition |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5341289B2 (en) * | 2001-09-14 | 2013-11-13 | 株式会社コーセー | Masking agent and cosmetic containing the same |
Citations (4)
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---|---|---|---|---|
JPS49132250A (en) * | 1972-10-04 | 1974-12-18 | ||
JPS5049439A (en) * | 1973-08-23 | 1975-05-02 | ||
JPS59175410A (en) * | 1983-03-26 | 1984-10-04 | Kanebo Shokuhin Kk | Cariostatic agent |
JPS59175422A (en) * | 1983-03-26 | 1984-10-04 | Kanebo Shokuhin Kk | Cariostatic agent |
-
1986
- 1986-09-09 JP JP61210582A patent/JPH0816049B2/en not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS49132250A (en) * | 1972-10-04 | 1974-12-18 | ||
JPS5049439A (en) * | 1973-08-23 | 1975-05-02 | ||
JPS59175410A (en) * | 1983-03-26 | 1984-10-04 | Kanebo Shokuhin Kk | Cariostatic agent |
JPS59175422A (en) * | 1983-03-26 | 1984-10-04 | Kanebo Shokuhin Kk | Cariostatic agent |
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1995015186A1 (en) * | 1993-11-30 | 1995-06-08 | Quest International B.V. | Anti-smoke perfumes and compositions |
US5676163A (en) * | 1993-11-30 | 1997-10-14 | Quest International Bv | Anti-smoke perfumes and compositions |
JPH11246376A (en) * | 1998-02-27 | 1999-09-14 | Sunstar Inc | Composition for oral cavity |
WO2000028952A1 (en) * | 1998-11-12 | 2000-05-25 | Block Drug Company, Inc. | Flavour blend for masking unpleasant taste of zinc compounds |
US6169118B1 (en) | 1998-11-12 | 2001-01-02 | Block Drug Company, Inc. | Flavor blend for masking unpleasant taste of zinc compounds |
GB2357967A (en) * | 2000-01-06 | 2001-07-11 | Mars Uk Ltd | Antibacterial agents |
JP2002104947A (en) * | 2000-09-29 | 2002-04-10 | Kobayashi Pharmaceut Co Ltd | Deodorant |
JP2002275495A (en) * | 2001-03-16 | 2002-09-25 | Takasago Internatl Corp | Perfumery composition for eliminating tobacco smell |
WO2006093311A1 (en) * | 2005-03-01 | 2006-09-08 | Ajinomoto Co., Inc. | Detergent composition |
JP2007153841A (en) * | 2005-12-07 | 2007-06-21 | Wakoudou Kk | Oral composition |
US8741275B2 (en) | 2010-06-04 | 2014-06-03 | Robetet, Inc. | Malodor neutralizing compositions comprising undecylenic acid or citric acid |
US9200241B2 (en) | 2011-01-27 | 2015-12-01 | Robertet, Inc. | Malodor neutralizing compositions comprising bornyl acetate or isobornyl acetate |
US9114180B2 (en) | 2012-03-30 | 2015-08-25 | Robertet, Inc. | Malodor neutralizing compositions containing acids and alicyclic ketones |
JP2015081237A (en) * | 2013-10-22 | 2015-04-27 | 花王株式会社 | Agent of inhibiting odors caused by sotolon |
CN111603416A (en) * | 2019-02-22 | 2020-09-01 | 好维股份有限公司 | Oral care compositions comprising hops extract |
CN111603416B (en) * | 2019-02-22 | 2023-09-01 | 好维股份有限公司 | Oral care compositions comprising hops extract |
JP2021104976A (en) * | 2019-12-26 | 2021-07-26 | サンスター株式会社 | Oral composition |
Also Published As
Publication number | Publication date |
---|---|
JPH0816049B2 (en) | 1996-02-21 |
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