JPS6353239B2 - - Google Patents
Info
- Publication number
- JPS6353239B2 JPS6353239B2 JP54041180A JP4118079A JPS6353239B2 JP S6353239 B2 JPS6353239 B2 JP S6353239B2 JP 54041180 A JP54041180 A JP 54041180A JP 4118079 A JP4118079 A JP 4118079A JP S6353239 B2 JPS6353239 B2 JP S6353239B2
- Authority
- JP
- Japan
- Prior art keywords
- rhenium
- platinum
- catalyst
- weight
- reforming
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 102
- 239000003054 catalyst Substances 0.000 claims description 86
- 229910052697 platinum Inorganic materials 0.000 claims description 51
- 229910052702 rhenium Inorganic materials 0.000 claims description 46
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims description 46
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 28
- 229910052717 sulfur Inorganic materials 0.000 claims description 28
- 239000011593 sulfur Substances 0.000 claims description 28
- 238000002407 reforming Methods 0.000 claims description 24
- 238000000034 method Methods 0.000 claims description 20
- 239000002131 composite material Substances 0.000 claims description 8
- 229910052739 hydrogen Inorganic materials 0.000 claims description 8
- 239000001257 hydrogen Substances 0.000 claims description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 5
- 238000001833 catalytic reforming Methods 0.000 claims description 5
- 150000002431 hydrogen Chemical class 0.000 claims description 3
- 229910052736 halogen Inorganic materials 0.000 claims 1
- 150000002367 halogens Chemical class 0.000 claims 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 15
- DBJYYRBULROVQT-UHFFFAOYSA-N platinum rhenium Chemical compound [Re].[Pt] DBJYYRBULROVQT-UHFFFAOYSA-N 0.000 description 13
- 238000002474 experimental method Methods 0.000 description 9
- 230000032683 aging Effects 0.000 description 7
- 230000007423 decrease Effects 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 238000011160 research Methods 0.000 description 6
- MRMOZBOQVYRSEM-UHFFFAOYSA-N tetraethyllead Chemical compound CC[Pb](CC)(CC)CC MRMOZBOQVYRSEM-UHFFFAOYSA-N 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- -1 platinum metals Chemical class 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000000571 coke Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 230000008929 regeneration Effects 0.000 description 3
- 238000011069 regeneration method Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000010779 crude oil Substances 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 2
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000008186 active pharmaceutical agent Substances 0.000 description 1
- 150000001350 alkyl halides Chemical class 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- QGJOPFRUJISHPQ-NJFSPNSNSA-N carbon disulfide-14c Chemical compound S=[14C]=S QGJOPFRUJISHPQ-NJFSPNSNSA-N 0.000 description 1
- 238000004517 catalytic hydrocracking Methods 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical class O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000000051 modifying effect Effects 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000005504 petroleum refining Methods 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 229910001404 rare earth metal oxide Inorganic materials 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000005987 sulfurization reaction Methods 0.000 description 1
- HRLYFPKUYKFYJE-UHFFFAOYSA-N tetraoxorhenate(2-) Chemical compound [O-][Re]([O-])(=O)=O HRLYFPKUYKFYJE-UHFFFAOYSA-N 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 150000003738 xylenes Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G35/00—Reforming naphtha
- C10G35/04—Catalytic reforming
- C10G35/06—Catalytic reforming characterised by the catalyst used
- C10G35/085—Catalytic reforming characterised by the catalyst used containing platinum group metals or compounds thereof
- C10G35/09—Bimetallic catalysts in which at least one of the metals is a platinum group metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/656—Manganese, technetium or rhenium
- B01J23/6567—Rhenium
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US89489078A | 1978-04-10 | 1978-04-10 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS54145707A JPS54145707A (en) | 1979-11-14 |
| JPS6353239B2 true JPS6353239B2 (fr) | 1988-10-21 |
Family
ID=25403638
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4118079A Granted JPS54145707A (en) | 1978-04-10 | 1979-04-06 | Catalytic reforming with rheniummplatinum catalyst containing more rhenium than platinum |
Country Status (16)
| Country | Link |
|---|---|
| JP (1) | JPS54145707A (fr) |
| AU (2) | AU537495B2 (fr) |
| BE (1) | BE875386A (fr) |
| BR (1) | BR7902106A (fr) |
| CA (1) | CA1127583A (fr) |
| DE (1) | DE2913183A1 (fr) |
| DK (1) | DK149692C (fr) |
| EG (1) | EG13933A (fr) |
| FI (1) | FI65798C (fr) |
| FR (1) | FR2422711B1 (fr) |
| GB (1) | GB2018278B (fr) |
| IT (1) | IT1116165B (fr) |
| MX (1) | MX151766A (fr) |
| NL (1) | NL7902617A (fr) |
| NO (1) | NO791160L (fr) |
| SE (1) | SE432604B (fr) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1223836A (fr) * | 1981-12-31 | 1987-07-07 | William E. Winter | Reformage catalytique |
| RU2206599C1 (ru) * | 2002-04-25 | 2003-06-20 | Макаров Павел Алексеевич | Способ получения ароматических углеводородов |
| FR2840548B1 (fr) | 2002-06-07 | 2005-03-18 | Inst Francais Du Petrole | Lit homogene de catalyseur et procede de transformation d'hydrocarbures en composes aromatiques avec ledit lit |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3415737A (en) * | 1966-06-24 | 1968-12-10 | Chevron Res | Reforming a sulfur-free naphtha with a platinum-rhenium catalyst |
| GB1256000A (en) * | 1968-04-24 | 1971-12-08 | Universal Oil Prod Co | Hydrocarbon conversion catalyst and processes for the manufacture and use thereof |
| CA949544A (en) * | 1970-02-13 | 1974-06-18 | Henry Erickson | Rhenium and platinum series metal-containing catalysts |
| FR2125126A1 (en) * | 1971-02-12 | 1972-09-29 | Universal Oil Prod Co | Hydrocarbon conversion - with a catalyst contg a platinum group metal,rhenium,tin and halogen |
| GB1374863A (en) * | 1972-03-13 | 1974-11-20 | Universal Oil Prod Co | Catalyst and process for the isomerization of hydrocarbons |
| CA1050917A (fr) * | 1973-05-07 | 1979-03-20 | Atlantic Richfield Company | Procede de reforming |
| FR2286187A1 (fr) * | 1974-09-25 | 1976-04-23 | Catalyse Soc Prod Francais | Catalyseurs d'hydroconversion des hydrocarbures |
-
1979
- 1979-03-26 AU AU45470/79A patent/AU537495B2/en not_active Ceased
- 1979-04-02 DE DE19792913183 patent/DE2913183A1/de not_active Ceased
- 1979-04-03 GB GB7911596A patent/GB2018278B/en not_active Expired
- 1979-04-03 NL NL7902617A patent/NL7902617A/xx not_active Application Discontinuation
- 1979-04-04 FR FR7908480A patent/FR2422711B1/fr not_active Expired
- 1979-04-05 BR BR7902106A patent/BR7902106A/pt unknown
- 1979-04-05 DK DK140379A patent/DK149692C/da not_active IP Right Cessation
- 1979-04-05 FI FI791128A patent/FI65798C/fi not_active IP Right Cessation
- 1979-04-06 BE BE0/194457A patent/BE875386A/fr not_active IP Right Cessation
- 1979-04-06 NO NO791160A patent/NO791160L/no unknown
- 1979-04-06 IT IT48661/79A patent/IT1116165B/it active
- 1979-04-06 JP JP4118079A patent/JPS54145707A/ja active Granted
- 1979-04-09 CA CA325,146A patent/CA1127583A/fr not_active Expired
- 1979-04-09 EG EG212/79A patent/EG13933A/xx active
- 1979-04-09 SE SE7903154A patent/SE432604B/sv not_active IP Right Cessation
- 1979-04-10 MX MX177265A patent/MX151766A/es unknown
-
1984
- 1984-04-18 AU AU27076/84A patent/AU2707684A/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| NO791160L (no) | 1979-10-11 |
| FI65798C (fi) | 1984-07-10 |
| IT1116165B (it) | 1986-02-10 |
| FR2422711A1 (fr) | 1979-11-09 |
| DK149692C (da) | 1987-03-30 |
| MX151766A (es) | 1985-03-07 |
| AU4547079A (en) | 1979-10-18 |
| BR7902106A (pt) | 1979-11-27 |
| JPS54145707A (en) | 1979-11-14 |
| GB2018278B (en) | 1982-08-11 |
| NL7902617A (nl) | 1979-10-12 |
| FI791128A (fi) | 1979-10-11 |
| FI65798B (fi) | 1984-03-30 |
| DK140379A (da) | 1979-10-11 |
| BE875386A (fr) | 1979-10-08 |
| SE432604B (sv) | 1984-04-09 |
| FR2422711B1 (fr) | 1985-11-29 |
| SE7903154L (sv) | 1979-10-11 |
| DK149692B (da) | 1986-09-08 |
| GB2018278A (en) | 1979-10-17 |
| CA1127583A (fr) | 1982-07-13 |
| DE2913183A1 (de) | 1979-10-18 |
| EG13933A (en) | 1983-03-31 |
| IT7948661A0 (it) | 1979-04-06 |
| AU537495B2 (en) | 1984-06-28 |
| AU2707684A (en) | 1984-08-02 |
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