JPS634053A - 銅製品等の表面に緑青被膜を形成する方法 - Google Patents
銅製品等の表面に緑青被膜を形成する方法Info
- Publication number
- JPS634053A JPS634053A JP14729186A JP14729186A JPS634053A JP S634053 A JPS634053 A JP S634053A JP 14729186 A JP14729186 A JP 14729186A JP 14729186 A JP14729186 A JP 14729186A JP S634053 A JPS634053 A JP S634053A
- Authority
- JP
- Japan
- Prior art keywords
- copper
- patina
- film
- product
- concn
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000010949 copper Substances 0.000 title claims abstract description 35
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 29
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 27
- 241001311547 Patina Species 0.000 title claims abstract description 23
- 238000000034 method Methods 0.000 title claims description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000010408 film Substances 0.000 claims abstract description 11
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 10
- 229910000881 Cu alloy Inorganic materials 0.000 claims abstract description 7
- 239000010409 thin film Substances 0.000 claims abstract description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 20
- 239000001569 carbon dioxide Substances 0.000 claims description 10
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 10
- 229940116318 copper carbonate Drugs 0.000 abstract description 3
- GEZOTWYUIKXWOA-UHFFFAOYSA-L copper;carbonate Chemical compound [Cu+2].[O-]C([O-])=O GEZOTWYUIKXWOA-UHFFFAOYSA-L 0.000 abstract description 3
- 229910000069 nitrogen hydride Inorganic materials 0.000 abstract 2
- 239000008246 gaseous mixture Substances 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 description 9
- 238000000576 coating method Methods 0.000 description 9
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 3
- PRYBYZBYRVRKQY-UHFFFAOYSA-L C([O-])([O-])=O.[Cu+2].[Cu]=O Chemical compound C([O-])([O-])=O.[Cu+2].[Cu]=O PRYBYZBYRVRKQY-UHFFFAOYSA-L 0.000 description 3
- 239000001099 ammonium carbonate Substances 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 235000012501 ammonium carbonate Nutrition 0.000 description 2
- 239000000908 ammonium hydroxide Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 description 1
- 239000005749 Copper compound Substances 0.000 description 1
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 235000014676 Phragmites communis Nutrition 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 235000012538 ammonium bicarbonate Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- OVFCVRIJCCDFNQ-UHFFFAOYSA-N carbonic acid;copper Chemical compound [Cu].OC(O)=O OVFCVRIJCCDFNQ-UHFFFAOYSA-N 0.000 description 1
- 150000001879 copper Chemical class 0.000 description 1
- 150000001880 copper compounds Chemical class 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- 229910000009 copper(II) carbonate Inorganic materials 0.000 description 1
- NWFNSTOSIVLCJA-UHFFFAOYSA-L copper;diacetate;hydrate Chemical compound O.[Cu+2].CC([O-])=O.CC([O-])=O NWFNSTOSIVLCJA-UHFFFAOYSA-L 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000011646 cupric carbonate Substances 0.000 description 1
- 235000019854 cupric carbonate Nutrition 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Landscapes
- Chemical Treatment Of Metals (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14729186A JPS634053A (ja) | 1986-06-24 | 1986-06-24 | 銅製品等の表面に緑青被膜を形成する方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14729186A JPS634053A (ja) | 1986-06-24 | 1986-06-24 | 銅製品等の表面に緑青被膜を形成する方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS634053A true JPS634053A (ja) | 1988-01-09 |
| JPS6357500B2 JPS6357500B2 (es) | 1988-11-11 |
Family
ID=15426885
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP14729186A Granted JPS634053A (ja) | 1986-06-24 | 1986-06-24 | 銅製品等の表面に緑青被膜を形成する方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS634053A (es) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0483568A1 (de) * | 1990-10-27 | 1992-05-06 | KM Europa Metal Aktiengesellschaft | Verfahren zur Herstellung von braunen Deckschichten auf Kupfer |
| US5838099A (en) * | 1996-02-26 | 1998-11-17 | Victor Company Of Japan, Ltd. | Deflection yoke having first coil parts for correction of cross-misconverge and red/blue vertical misconverge |
-
1986
- 1986-06-24 JP JP14729186A patent/JPS634053A/ja active Granted
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0483568A1 (de) * | 1990-10-27 | 1992-05-06 | KM Europa Metal Aktiengesellschaft | Verfahren zur Herstellung von braunen Deckschichten auf Kupfer |
| US5838099A (en) * | 1996-02-26 | 1998-11-17 | Victor Company Of Japan, Ltd. | Deflection yoke having first coil parts for correction of cross-misconverge and red/blue vertical misconverge |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6357500B2 (es) | 1988-11-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US2499261A (en) | Compositions and methods for depositing amorphous metal-phosphate coatings on metal surfaces | |
| ES8704141A1 (es) | Un metodo mejorado de deposicion quimica en fase vapor para producir un revestimiento de oxido de estano adulterado con fluor | |
| US3497401A (en) | Patination of copper | |
| CN110408917A (zh) | 一种低成本耐候钢锈板生产方法 | |
| US4427499A (en) | Process for surface treatment of stainless steel sheet | |
| JPS634053A (ja) | 銅製品等の表面に緑青被膜を形成する方法 | |
| JP4415449B2 (ja) | 耐候性に優れた表面処理鋼材の製造方法 | |
| US1951304A (en) | Method of coloring copper and copper alloys | |
| CA2188661A1 (en) | Artificial patina | |
| US3752707A (en) | Corrosion resistant composition and method | |
| US1974140A (en) | Production of an adherent patina upon copper or its alloys | |
| Bastidas et al. | Corrosion of bronze by acetic and formic acid vapours, sulphur dioxide and sodium chloride particles | |
| US5714052A (en) | Method for producing brochantite patina on copper | |
| US3669766A (en) | Formation of coating on copper containing materials | |
| US3284249A (en) | Decorative finish for copper | |
| SU1659827A1 (ru) | Способ изготовлени хлорсеребр ного электрода | |
| JPS6115154B2 (es) | ||
| PT1685273E (pt) | Método para a patinação de cobre | |
| JP3696139B2 (ja) | 緑青発色組成液及び緑青形成方法 | |
| JPH0348274B2 (es) | ||
| JPH02236286A (ja) | 早期に緑青を形成する銅製品とその製造方法 | |
| SU1135804A1 (ru) | Кислый водный раствор химического никелировани | |
| US3522109A (en) | Processes for producing decorative and protective coatings on copper metal | |
| JPH03236481A (ja) | 緑青の形成方法 | |
| JPH03236479A (ja) | 緑青の形成方法 |