JPS63286482A - Aqueous polishing agent for tire - Google Patents
Aqueous polishing agent for tireInfo
- Publication number
- JPS63286482A JPS63286482A JP12058587A JP12058587A JPS63286482A JP S63286482 A JPS63286482 A JP S63286482A JP 12058587 A JP12058587 A JP 12058587A JP 12058587 A JP12058587 A JP 12058587A JP S63286482 A JPS63286482 A JP S63286482A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- water
- silicone oil
- parts
- fatty acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000005498 polishing Methods 0.000 title abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 39
- 229920002545 silicone oil Polymers 0.000 claims abstract description 36
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 17
- 229930195729 fatty acid Natural products 0.000 claims abstract description 17
- 239000000194 fatty acid Substances 0.000 claims abstract description 17
- -1 sorbitan fatty acid ester Chemical class 0.000 claims abstract description 13
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 12
- 239000004094 surface-active agent Substances 0.000 claims abstract description 9
- 125000004423 acyloxy group Chemical group 0.000 claims abstract description 3
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 19
- 239000000203 mixture Substances 0.000 claims description 17
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- 239000000839 emulsion Substances 0.000 abstract description 5
- 239000004721 Polyphenylene oxide Substances 0.000 abstract description 4
- 239000003795 chemical substances by application Substances 0.000 abstract description 4
- 229920000570 polyether Polymers 0.000 abstract description 4
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 239000002352 surface water Substances 0.000 abstract 1
- XZIIFPSPUDAGJM-UHFFFAOYSA-N 6-chloro-2-n,2-n-diethylpyrimidine-2,4-diamine Chemical compound CCN(CC)C1=NC(N)=CC(Cl)=N1 XZIIFPSPUDAGJM-UHFFFAOYSA-N 0.000 description 7
- 235000013162 Cocos nucifera Nutrition 0.000 description 7
- 244000060011 Cocos nucifera Species 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 229940035044 sorbitan monolaurate Drugs 0.000 description 7
- LWZFANDGMFTDAV-BURFUSLBSA-N [(2r)-2-[(2r,3r,4s)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O LWZFANDGMFTDAV-BURFUSLBSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 235000011067 sorbitan monolaureate Nutrition 0.000 description 5
- KLSJWNVTNUYHDU-UHFFFAOYSA-N Amitrole Chemical compound NC1=NC=NN1 KLSJWNVTNUYHDU-UHFFFAOYSA-N 0.000 description 4
- 125000006353 oxyethylene group Chemical group 0.000 description 4
- 239000002184 metal Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 241000047703 Nonion Species 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 229920005862 polyol Polymers 0.000 description 2
- 150000003077 polyols Chemical class 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- 241000282320 Panthera leo Species 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- ZFDPAZDODACYOG-UHFFFAOYSA-M sodium;[(1,5-dimethyl-3-oxo-2-phenylpyrazol-4-yl)amino]methanesulfonate Chemical compound [Na+].CN1C(C)=C(NCS([O-])(=O)=O)C(=O)N1C1=CC=CC=C1 ZFDPAZDODACYOG-UHFFFAOYSA-M 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
Abstract
Description
【発明の詳細な説明】
「産業上の利用分野」
本発明は自動車のタイヤに塗布するだけで、拭きとりの
ｂらなり乳化状態のタイヤ用艶出し剤に関する。DETAILED DESCRIPTION OF THE INVENTION "Industrial Application Field" The present invention relates to a tire polish that is in an emulsified state and can be wiped off simply by being applied to automobile tires.
「従来の技術及び発明が解決しようとする問題点」従来
から家具、プラスチック、タイヤ等の艶出し剤としてジ
メチルシリコーンオイルを含有する水性組成物が知られ
ており、その改良法も種々提案されている。例えばジメ
チルシリコーンオイルをひまし油などの天然油、或ｒＦ
！ポリエチレングリコール、グリセリンなどのポリオー
ル類と併用して界面活性剤で乳化して水性化する種々の
組成物の開発がなされている。``Prior art and problems to be solved by the invention'' Aqueous compositions containing dimethyl silicone oil have been known as polishing agents for furniture, plastics, tires, etc., and various improvements have been proposed. There is. For example, dimethyl silicone oil can be replaced with natural oil such as castor oil, or rF.
! Various compositions have been developed that are emulsified and made aqueous by using surfactants in combination with polyols such as polyethylene glycol and glycerin.
しかしながら、従来の水性艶出し剤においてはジメチル
シリコーンオイルと前記他成分とが相容性に欠けること
から、タイヤに塗布したまま放置した場合、深み、透明
感に欠け、仕上がりが不均一になガ、モツプやウェスを
用−て拭きとり作業を行なわなければならないなどの問
題があった。However, in conventional water-based polishes, dimethyl silicone oil lacks compatibility with the other ingredients mentioned above, so if left after being applied to tires, the finish may lack depth, lack transparency, and become uneven. However, there were problems such as having to use a mop or rag to wipe it off.
又従来のジメチルシリコーンオイルを含有する水性艶出
し剤は乳化剤としてポリオキシエチレンアルキルエーテ
ル、ポリオキシエチレンアルキルフェニルエーテル、ポ
リオキシアルキルエステル、ポリオキシソルビタンエス
テルなどのノニオン界面活性剤、アルキルエーテルサル
フェート、アルキルサルフェート、アルキルスルホネー
トなどのアニオン界面活性剤が主として使用され°てお
り、これらの乳化剤は、自動車塗膜に軟化やふくれなど
の悪影響を与え、金属やメッキ部分を腐蝕するなどの問
題があった。In addition, conventional aqueous polishing agents containing dimethyl silicone oil contain nonionic surfactants such as polyoxyethylene alkyl ether, polyoxyethylene alkyl phenyl ether, polyoxyalkyl ester, polyoxysorbitan ester, alkyl ether sulfates, alkyl esters, etc. as emulsifiers. Anionic surfactants such as sulfates and alkyl sulfonates are mainly used, and these emulsifiers have problems such as softening and blistering of automobile paint films and corroding metals and plated parts.
又、従来の水性艶出し剤はジメチルシリコーンオイルと
水溶性の界面活性剤或いはポリオール類が配合されてお
り、タイヤゴムに対する付着性が弱いために水洗いや洗
剤液で洗浄した場合に容易に流れ落ちてしまい、耐水性
、持続性に欠ける問題があった。In addition, conventional water-based polishes contain dimethyl silicone oil and water-soluble surfactants or polyols, and because they have weak adhesion to tire rubber, they easily wash off when washed with water or detergent. However, there were problems with lack of water resistance and durability.
「問題点を解決するための手段及び作用」本発明は上記
問題点を解決したもので、下記（Ａ）〜（Ｄ）を含有す
ることを特徴とする水性タイヤ用艶出し剤組成物である
。"Means and effects for solving the problems" The present invention solves the above problems, and is a water-based tire polish composition characterized by containing the following (A) to (D). .
（Ａ） ジメチルシリコーンオイル２〜６０ｉｉ％（
Ｂ） 下記一般式（Ｉ）で表わされる基を少なくとも
１個有する、水に不溶性又は自己乳化性のポリエーテル
変性シリコーンオイル】〜１５重１％
（式中ＲＶｉ水素原子、炭素数］〜２０の一価炭化水素
基又はアシロキシ基、ａは０〜４の整数、ｎけ２又Ｆｉ
３、ｍ ｈ ２〜３ Ｑの整数。〕（Ｃ） Ｊｆｆｉ
肪酸アルキロールアミドとソルビタン脂肪酸エステルと
の比が］ ： ０．１〜】〜３である混合界面活性剤０
．５〜５．０重量％（Ｄ） 水９６．５〜２０．０重
ｆ１％即ちジメチルシリコーンオイルと特定のポリエー
テル変性シリコーンオイルを併用し特定比率の混合界面
活性剤で水に乳化きせることにより、使用性、安全性、
耐水性、持続性にすぐれた水性艶出し剤組成物が得らｎ
たのである。(A) Dimethyl silicone oil 2-60ii% (
B) Water-insoluble or self-emulsifying polyether-modified silicone oil having at least one group represented by the following general formula (I)] ~15% by weight (in the formula RVi hydrogen atom, carbon number] ~20 Monovalent hydrocarbon group or acyloxy group, a is an integer of 0 to 4, n digits Fi
3, m h 2-3 Q integer. ] (C) Jffi
Mixed surfactant 0 in which the ratio of fatty acid alkylolamide to sorbitan fatty acid ester is ]: 0.1 to] to 3
．． 5 to 5.0% by weight (D) Water 96.5 to 20.0% by weight f1%, that is, by using a combination of dimethyl silicone oil and a specific polyether-modified silicone oil and emulsifying it in water with a specific ratio of mixed surfactant. , usability, safety,
An aqueous polish composition with excellent water resistance and durability can be obtained.
It was.
本発明に用いる（Ａ）成分のジメチルシリコーンオイル
は２５℃における粘度が１００００ ａｓ以下好捷しく
け１０〜１０００ｃｓＯものであり、例えば信越化学工
業吹製ＫＦ ９６−３５０ Ｃｓ、同ＫＦ９６−１００
（ｌｃｓ等があげられる。ジメチルシリコーンオイルの
配合量は組成物全量中２〜６０重量％好ましくけ５〜３
０重（１％である。２重量％未満では艶出し効果が充分
に得られなく、６０重量％を超えるとべたつきが感じら
れ仕上りが悪くなる。The dimethyl silicone oil as component (A) used in the present invention has a viscosity of 10,000 as or less at 25° C., and preferably 10 to 1,000 csO.
(LCS, etc.) The amount of dimethyl silicone oil blended is preferably 2 to 60% by weight based on the total amount of the composition, and 5 to 3% by weight.
0 weight (1%) If it is less than 2% by weight, a sufficient polishing effect cannot be obtained, and if it exceeds 60% by weight, it will feel sticky and the finish will be poor.
（Ｂ）成分のポリエーテル変性シリコーンオイルにお−
て、親水性又は水溶性効果を与えるオキシエチレン基の
含有量が多すぎると、ポリエーテル変性シリコーンオイ
ルと（Ａ）成分であるジメチルシリコーンオイルとの相
溶性が悪くなり、更に水溶性の増大のため、塗布後の皮
膜の耐水性が劣ったり、皮膜の光分な持続性が得られな
い等の不利益が生じる。又オキシエチレン基の含有量が
少なすぎると、ジメチルシリコーンオイルの乳化安定性
に劣ったものとなり、平滑で均一な深みのある艶が得ら
れない。本発明者の試験では、ジメチルシリコーンオイ
ルの乳化安定性に優れ、十分な耐水性と持続性を有する
皮膜を与えるためのポリエーテル変性シリコーンオイル
のジメチルシロキシ単位トオキシエチレン単位との比は
、］０：］から】０：１５の範囲が必要であり望ましく
け１０：３から１０：１０の範囲である。(B) component polyether-modified silicone oil.
However, if the content of oxyethylene groups that provide hydrophilic or water-soluble effects is too large, the compatibility between polyether-modified silicone oil and dimethyl silicone oil, which is component (A), will deteriorate, and the water solubility will increase. Therefore, there are disadvantages such as poor water resistance of the film after application and failure to obtain long-term durability of the film. If the content of oxyethylene groups is too low, the emulsion stability of the dimethyl silicone oil will be poor, making it impossible to obtain a smooth, uniform, deep gloss. In tests conducted by the present inventor, the ratio of dimethylsiloxy units to toxyethylene units of polyether-modified silicone oil in order to provide a film with excellent emulsion stability, sufficient water resistance, and durability of dimethyl silicone oil is as follows: A range of from 0:] to 0:15 is necessary, and preferably from 10:3 to 10:10.
ポリエーテル変性シリコーンオイルのジメチルシロキシ
単位とオキシエチレン単位との比が上記の範囲にあれば
、一般式ＣＩ）で示される基の中にはオキシエチレン単
位の他てオキシプロピレン単位が含まれても同様な効果
がある事が確認された。If the ratio of dimethylsiloxy units to oxyethylene units in the polyether-modified silicone oil is within the above range, the group represented by general formula CI) may contain oxypropylene units in addition to oxyethylene units. It was confirmed that it had a similar effect.
かかるポリエーテル変性シリコーンオイルとしては例え
ば信越化学工業（輿製ＫＦ９４５があげらｎる。ＫＦ９
４５は下記一般式（ＩＩ）で水式れるものでポリエーテ
ル変性シリコーンオイルの配合量ハ組酸物全量中１〜１
５重Ｊ＃チ好捷しくは２”Ｙ１０重量％である。１重量
％未満では耐水性が悪く、１５５重量％を超えると乳化
安定性が悪く皮膜にべたつきが感じられるようになる。Examples of such polyether-modified silicone oil include KF945 manufactured by Shin-Etsu Chemical Co., Ltd. (Koshi).
45 is a water-based product with the following general formula (II), and the amount of polyether-modified silicone oil is 1 to 1 in the total amount of acids.
Preferably, the amount is 10% by weight of 2" Y. If it is less than 1% by weight, the water resistance will be poor, and if it exceeds 155% by weight, the emulsion stability will be poor and the film will feel sticky.
（Ｃ）成分の混合界面活性剤はゴム、塗膜、プラスチッ
ク、金属、メッキ等に対して安全であり、シリコーンオ
イルを乳化さすのに優れて論る脂肪酸アルキロール了ミ
ドとソルビタン脂肪酸エステル型の非イオン界面活性剤
の特定比率の混合物であり、この特定の比率によって前
記（Ａ）成分及び（Ｂ）成分を安定に乳化さすものであ
る。脂肪酸アルキロールアミドとしては例えばヤシ脂肪
酸ジェタノールアミド（アミゾールＣＤ、用研ファイン
ケミカル■製）があげられ、ソルビタン脂肪酸エステル
としてはソルビタンモノラウレート（スパン２０、花王
（ハ）製）があげられる。混合界゛面活性剤の配合量は
組成物全量中０．５〜５．０重量％好ましくは１〜３重
ｔ％である。０．５重量％未満では乳化安定性が悪く、
５．０重量％を超えると耐水性が悪くなる。The mixed surfactant of component (C) is safe for rubber, paint films, plastics, metals, plating, etc., and contains fatty acid alkylol ryomide and sorbitan fatty acid ester type, which are excellent for emulsifying silicone oil. It is a mixture of nonionic surfactants in a specific ratio, and this specific ratio stably emulsifies the components (A) and (B). Examples of the fatty acid alkylolamide include coconut fatty acid jetanolamide (Amizol CD, manufactured by Yoken Fine Chemicals), and examples of the sorbitan fatty acid ester include sorbitan monolaurate (Span 20, manufactured by Kao Corporation). The blending amount of the mixed surfactant is 0.5 to 5.0% by weight, preferably 1 to 3% by weight, based on the total amount of the composition. If it is less than 0.5% by weight, emulsion stability is poor;
If it exceeds 5.0% by weight, water resistance will deteriorate.
ＣＤ）成分の水は組成物全量中９６．５〜２０．０重量
％好オしくは９２〜５７重ｉ′チであり、２０．０重量
−以下では乳化が困難であり、９６．５重量％以上では
（Ａ）成分、（Ｂ）成分の含有量が少なくなりすぎ充分
な艶出し効果が得らｎ、ない。CD) Component water is 96.5 to 20.0% by weight of the total composition, preferably 92 to 57% by weight, and if it is less than 20.0% by weight, it is difficult to emulsify; % or more, the contents of component (A) and component (B) become too small and a sufficient polishing effect cannot be obtained.
以上のように本発明組成物は前記（Ａ）〜■斤成分とし
て含有するものであるが、用途に応じて一価アルコール
、多価アルコール、ケトン類、エーテル類を適宜添加し
てもよい。As described above, the composition of the present invention contains the components (A) to (2) above, but monohydric alcohols, polyhydric alcohols, ketones, and ethers may be added as appropriate depending on the purpose.
又本発明組成物はハンドスプレーによって直接タイヤに
塗布してもよく、ある込は噴射剤を用いてエアゾール製
品として使用して嘱よい。The composition of the present invention may also be applied directly to tires by hand spraying, or may be used as an aerosol product using a propellant.
「実施例、比較例」
実施例１
水１５重量部にヤシ脂肪酸ジェタノールアミド（アミゾ
ールＣＤ ） ］、ｉｓ重量部、ソルビタンモノラウレ
ート（スパン２０）】重量部、ポリエーテル変性シリコ
ーンオイル（ＫＦ９４５）４重ＩＮＩＩＬジメチルシリ
コーンオイル（ＫＦ ９６−３５０ｃｓ）１５］［ｆｉ
部を加えホモミキサーで乳化し、残りの水６３．５重量
部を加えて調整した。"Examples and Comparative Examples" Example 1 15 parts by weight of water, coconut fatty acid jetanolamide (Amizol CD)], is parts by weight, sorbitan monolaurate (span 20)] parts by weight, polyether-modified silicone oil (KF945) Quadruple INIIL dimethyl silicone oil (KF 96-350cs) 15] [fi
1 part and emulsified with a homomixer, and the remaining 63.5 parts by weight of water was added to adjust.
実施例２
水１０重量部にヤシ脂肪酸ジェタノールアミド（７ミソ
ールＣＤ ） １．２重量部、ソルビタンモノラウレー
ト（スパン２０ ） ０．８重量部、ポリエーテル変性
シリコーンオイル（ＫＦ９４５）３重Ｊｉ＆ジメチルシ
リコーンオイル１５Ｍｋｍ（ＫＦ ９６−３５０ｃｓｌ
Ｏ重量部及びＫＦ ９６−１０００ Ｃ１１５重量部）
を加え、ホモばキサ−で乳化し残シの水７０査貴部を加
えて調整した〇
実施例３
水１５ｉ徂部にヤシ脂肪酸ジ′エタノール了ミド（７ミ
ソールＣＤ ） １．５重量部、ソルビタンモノラウレ
ート（スパン２（１）］’ｉｉ部、ポリエーテル変性シ
リコーンオイル（ＫＦ ９４５ ） 二（、Ｓｆｉ量部
置部メチルシリコーンオイル（ＫＦ ’１６−１０００
ａｓ）１５重量部をクロえ、ホモミキサーで乳化し残り
の水６４４重量を加えて調整した。Example 2 10 parts by weight of water, 1.2 parts by weight of coconut fatty acid jetanolamide (7 Misole CD), 0.8 parts by weight of sorbitan monolaurate (Span 20), polyether modified silicone oil (KF945) triple Ji & dimethyl Silicone oil 15Mkm (KF 96-350csl
O parts by weight and KF 96-1000 C115 parts by weight)
Example 3 1.5 parts by weight of coconut fatty acid di-ethanolic acid (7 misole CD) was added to 15 parts of water and emulsified with a homovaxer, and the remaining 70 parts of water were added. Sorbitan monolaurate (Span 2 (1))'ii parts, polyether modified silicone oil (KF 945), parts Sfi, parts methyl silicone oil (KF '16-1000)
as) 15 parts by weight was mixed, emulsified with a homomixer, and the remaining 644 parts by weight of water was added to adjust.
実施例４
水１５重世部にヤシ脂肪酸ジェタノールアミド（アミゾ
ールＣＤ）１．５重量 ｇｆｌ、ソルビタンモノラウレ
ート（スパン２０ ）］、５ｉｌｉｉ、ポリエーテル変
性シリコーンオイル（ＫＦ ９４５ ） ５．Ｏｆｔ量
部５ジメチルシリコーンオイル２０重量部（ＫＰＯ３−
３５０ｃｓ １０重量部、ＫＦ ９８−１０００ｃａ
］０重量ｍ）を加え、ホモミキサーで乳化し残りの水５
７重量部をクロえて調整した。Example 4 1.5 parts by weight of coconut fatty acid jetanolamide (Amizol CD) gfl, sorbitan monolaurate (span 20), 5ilii, polyether-modified silicone oil (KF 945) in 15 parts of water. Of amount parts 5 dimethyl silicone oil 20 parts by weight (KPO3-
350cs 10 parts by weight, KF 98-1000ca
]0 weight m), emulsify with a homomixer, and add remaining water 5
Adjustments were made by adding 7 parts by weight.
比較例】
水】５重量部にヤシ脂肪酸ジェタノールアミド（アミゾ
ールＣＤ）２！ｆｉ：部、ソルビタンモノラウレート（
スパン２０）１重量部、ジメチルシリコーンオイル（Ｋ
Ｆ ９６−３５０ ｃｓ ）１５ｉｉ部を加え、ホモミ
キサーで乳化し残りの水６７重量部をクロえて調整した
。Comparative Example] Water: 5 parts by weight and 2 parts of coconut fatty acid jetanolamide (Amizole CD)! fi: part, sorbitan monolaurate (
Span 20) 1 part by weight, dimethyl silicone oil (K
F96-350 cs) 15ii parts were added, emulsified with a homomixer, and the remaining 67 parts by weight of water was added to prepare the mixture.
比較例２
水１５重を部にヤシ脂肪酸ジェタノールアミド（アミゾ
ールＣＤ）３重量部、ソルビタンモノラウレート（スパ
ン２０）１重量部、ポリエーテル変性シリコーンオイル
（ＫＦ９４５）５〜重量部を加え、ホモばキサ−で乳化
し残りの水７６重量部′Ｉｋ７１１］えて調整した。Comparative Example 2 To 15 parts by weight of water, 3 parts by weight of coconut fatty acid jetanolamide (Amizol CD), 1 part by weight of sorbitan monolaurate (Span 20), and 5 to 5 parts by weight of polyether-modified silicone oil (KF945) were added. The resulting mixture was emulsified with a vacuum cleaner and 76 parts by weight of remaining water (Ik711) was added to prepare the mixture.
比較例３
水】０重量部にオレイン酸モルポリン石ケン０．３、Ｈ
２部、ポリオキシエチレ７ノニルフェニルエーテル（ノ
ニオンＮ５２０６． 日本油脂＠）裂）２重量部、ジ
メチルシリコーンオイル（ＫＦ ９６−３５９６−３５
Ｏ重食ｍｔ−加え、ホモミキサーで乳化し残りの水７２
．７重量部ｔ−加えて調整した。Comparative Example 3 Water: 0 parts by weight of oleic acid molpoline soap 0.3, H
2 parts, polyoxyethylene 7 nonyl phenyl ether (Nonion N5206. NOF@) 2 parts by weight, dimethyl silicone oil (KF 96-3596-35)
Add O heavy food mt-, emulsify with homomixer and add remaining water 72
．． Adjustments were made by adding 7 parts by weight.
比較例４
水１０重量部にポリオキシエチレンノニルフェニルエー
テルａｆｆｉｎ部（リポノックスＮＣＪ、ライオン（虹
１重量部及びノニオンＮ５２０６、日本油脂（力製２Ｎ
証部）及びジメチルシリコーンオイル１５重量部（ＫＦ
９６−３５０ ａｓ ５重ｉｉ部及びＫＦ ９６−）
０００ｃｓ ） ０重ｆ部）を刀ａえ、ホモミキサーで
乳化し残りの水７２重量部を加えて調整した。Comparative Example 4 10 parts by weight of water was mixed with 1 part by weight of polyoxyethylene nonyl phenyl ether affin (Liponox NCJ, 1 part by weight of Lion (Niji) and 1 part by weight of Nonion N5206, NOF (2N
) and 15 parts by weight of dimethyl silicone oil (KF
96-350 as quintuple II part and KF 96-)
000cs) 0 parts by weight) was aerated, emulsified with a homomixer, and the remaining 72 parts by weight of water was added to adjust.
実施例１〜４及び比較例１〜４の各々について行なった
試験方法は下記の方法で調べた０（艶の定着性〕
水性艶出し剤組成物をノ・ンドスプレーで自動車タイヤ
ゴム表面に塗布した時の艶の定着性を調べる。The test method conducted for each of Examples 1 to 4 and Comparative Examples 1 to 4 was as follows. Examining the fixation of time gloss.
○ 均一に付着している
Δ 不均一に付着している
× はじきがあり付着が愚論
（耐水性）
水性艶出し剤組成物をノ・ンドスプレーで自動車タイヤ
ゴム表面に塗布して、３０分間放置後、水で洗す流した
あとの艶の有無によって調べる。○ Adhered evenly Δ Adhered unevenly × Repellent and adhesion is poor (water resistant) After applying the water-based polish composition to the rubber surface of an automobile tire with a no-do spray and leaving it for 30 minutes. Check whether there is any shine after rinsing with water.
○ 艶がある
Δ わずかに艶がある
× 艶がな−
（耐塗膜性）
ＪＩＳＫ−２２３６の自動車用艶出しワックスの塗装面
への影響試験の塗装試験板に水性艶出し剤組成物を塗布
して（５０℃ｘ４ｈｒ）放置し、室温に戻してから塗布
面と無塗布面と比較して調べる。○ Glossy Δ Slightly glossy × Glossy - (Paint film resistance) A water-based polish composition was applied to a painted test panel for testing the effect of JISK-2236 automotive polish wax on painted surfaces. (50°C x 4 hours), and after returning to room temperature, compare and examine the coated and uncoated surfaces.
○ 全く変化なし
Δ わずかに変色、ふくれがある
Ｘ 変色、ふくれ、軟化がある
（金属腐食性）
ＪＩＳＫ−２２３４不凍液の金属腐食性試験の鋳鉄の金
属試験板に水性艶出し剤組成物を塗布して、常温で１日
間放置した後のスチール表面の状態について塗布面と無
塗布面と比較して調べる。○ No change at all Δ Slight discoloration and blistering The condition of the steel surface after being left at room temperature for one day was compared between the coated surface and the uncoated surface.
○ 全く変化なし
Δ わずかに変色がある
Ｘ サビ、変色がある
本発明の艶出し剤組成物は、自動車タイヤやゴム製品の
表面に塗布、成力はスプレーするだけで、均一な艶出し
効果が得られ、しかも耐水性に優れているので、雨や洗
車に強く、長く持続することが期待できる。又、塗装面
や金属面に付着した場合でも悪影響のない無害な組成物
になっているから使用面に於すても安全である。○ No change Δ Slight discoloration Moreover, it has excellent water resistance, so it can be expected to be resistant to rain and car washes and last for a long time. Furthermore, it is a harmless composition that does not cause any adverse effects even if it adheres to painted or metal surfaces, so it is safe to use.
Claims (1)
イヤ用艶出し剤組成物。 （Ａ）ジメチルシリコーンオイル２〜６０重量％ （Ｂ）下記一般式（ I ）で表わされる基を少なくとも
１個有する、水に不溶性又は自己乳化性のポリエーテル
変性シリコーンオイル１〜１５重量％ 一般式（ I ）▲数式、化学式、表等があります▼ （式中Ｒは水素原子、炭素数１〜２０の一価炭化水素基
又はアシロキシ基、ａは０〜４の整数、ｎは２又は３、
ｍは２〜３０の整数。） （Ｃ）脂肪酸アルキロールアミドとソルビタン脂肪酸エ
ステルとの比が１：０．１〜１：３である混合界面活性
剤０．５〜５．０重量％ （Ｄ）水９６．５〜２０．０重量％[Scope of Claims] A water-based tire polish composition characterized by containing the following (A) to (D). (A) 2 to 60% by weight of dimethyl silicone oil (B) 1 to 15% by weight of water-insoluble or self-emulsifying polyether-modified silicone oil having at least one group represented by the following general formula (I) (I) ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ (In the formula, R is a hydrogen atom, a monovalent hydrocarbon group with 1 to 20 carbon atoms or an acyloxy group, a is an integer from 0 to 4, n is 2 or 3,
m is an integer from 2 to 30. ) (C) 0.5 to 5.0% by weight of a mixed surfactant in which the ratio of fatty acid alkylolamide and sorbitan fatty acid ester is 1:0.1 to 1:3 (D) Water 96.5 to 20% by weight. 0% by weight
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62120585A JPH066692B2 (en) | 1987-05-19 | 1987-05-19 | Glazing agent for water-based tire |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62120585A JPH066692B2 (en) | 1987-05-19 | 1987-05-19 | Glazing agent for water-based tire |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63286482A true JPS63286482A (en) | 1988-11-24 |
| JPH066692B2 JPH066692B2 (en) | 1994-01-26 |
Family
ID=14789918
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62120585A Expired - Lifetime JPH066692B2 (en) | 1987-05-19 | 1987-05-19 | Glazing agent for water-based tire |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH066692B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5085694A (en) * | 1991-03-04 | 1992-02-04 | Dow Corning Corporation | Polish compositions |
| JP2005154535A (en) * | 2003-11-25 | 2005-06-16 | Soft99 Corporation | Lustering composition for tire |
| CN103666281A (en) * | 2013-11-22 | 2014-03-26 | 南通信一服饰有限公司 | Stain removal and leather softening shoe polish |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111303767B (en) * | 2020-03-26 | 2021-11-16 | 北京京蝠环保科技有限公司 | Tire glazing glaze |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5121589A (en) * | 1974-08-19 | 1976-02-20 | Fuji Polymer Ind | SHIRIKOON RIKEIZAISOSEIBUTSU |
| JPS59193176A (en) * | 1984-03-29 | 1984-11-01 | アーマー オール プロダクツ コーポレーション | Surface protecting method |
| JPS60170679A (en) * | 1984-02-15 | 1985-09-04 | Hitachi Elevator Eng & Serv Co Ltd | Cleaning and polishing agent |
-
1987
- 1987-05-19 JP JP62120585A patent/JPH066692B2/en not_active Expired - Lifetime
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5121589A (en) * | 1974-08-19 | 1976-02-20 | Fuji Polymer Ind | SHIRIKOON RIKEIZAISOSEIBUTSU |
| JPS60170679A (en) * | 1984-02-15 | 1985-09-04 | Hitachi Elevator Eng & Serv Co Ltd | Cleaning and polishing agent |
| JPS59193176A (en) * | 1984-03-29 | 1984-11-01 | アーマー オール プロダクツ コーポレーション | Surface protecting method |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5085694A (en) * | 1991-03-04 | 1992-02-04 | Dow Corning Corporation | Polish compositions |
| JP2005154535A (en) * | 2003-11-25 | 2005-06-16 | Soft99 Corporation | Lustering composition for tire |
| CN103666281A (en) * | 2013-11-22 | 2014-03-26 | 南通信一服饰有限公司 | Stain removal and leather softening shoe polish |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH066692B2 (en) | 1994-01-26 |
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