JPS6327694B2 - - Google Patents

Info

Publication number

JPS6327694B2

JPS6327694B2 JP53078723A JP7872378A JPS6327694B2 JP S6327694 B2 JPS6327694 B2 JP S6327694B2 JP 53078723 A JP53078723 A JP 53078723A JP 7872378 A JP7872378 A JP 7872378A JP S6327694 B2 JPS6327694 B2 JP S6327694B2

Authority

JP

Japan

Prior art keywords

thin film

crystalline

electrons

electrochromic

optical properties

Prior art date

1978-06-30

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Links

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• 239000010409 thin film Substances 0.000 claims description 34
• 239000010408 film Substances 0.000 claims description 29
• QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 claims description 14
• 229910001930 tungsten oxide Inorganic materials 0.000 claims description 14
• 150000001768 cations Chemical class 0.000 claims description 12
• 230000005540 biological transmission Effects 0.000 claims description 10
• 150000002500 ions Chemical class 0.000 claims description 10
• 230000003287 optical effect Effects 0.000 claims description 9
• 239000000758 substrate Substances 0.000 claims description 8
• 230000002441 reversible effect Effects 0.000 claims description 6
• 238000006243 chemical reaction Methods 0.000 description 5
• 230000003595 spectral effect Effects 0.000 description 4
• 238000002834 transmittance Methods 0.000 description 4
• QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 3
• 239000007787 solid Substances 0.000 description 3
• VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
• 229910052804 chromium Inorganic materials 0.000 description 2
• 239000011651 chromium Substances 0.000 description 2
• 238000010586 diagram Methods 0.000 description 2
• 239000003792 electrolyte Substances 0.000 description 2
• 239000011521 glass Substances 0.000 description 2
• 229910001416 lithium ion Inorganic materials 0.000 description 2
• WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
• 238000000034 method Methods 0.000 description 2
• 229910052758 niobium Inorganic materials 0.000 description 2
• 239000010955 niobium Substances 0.000 description 2
• GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 2
• 229910052715 tantalum Inorganic materials 0.000 description 2
• GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 2
• WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
• 229910052721 tungsten Inorganic materials 0.000 description 2
• 239000010937 tungsten Substances 0.000 description 2
• 229910052720 vanadium Inorganic materials 0.000 description 2
• LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 2
• 229910000873 Beta-alumina solid electrolyte Inorganic materials 0.000 description 1
• 229910004261 CaF 2 Inorganic materials 0.000 description 1
• ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
• VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
• FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 1
• UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
• RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
• 238000010521 absorption reaction Methods 0.000 description 1
• 229910001413 alkali metal ion Inorganic materials 0.000 description 1
• 230000015572 biosynthetic process Effects 0.000 description 1
• WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 1
• 229910001634 calcium fluoride Inorganic materials 0.000 description 1
• 239000002800 charge carrier Substances 0.000 description 1
• 239000004020 conductor Substances 0.000 description 1
• 238000004042 decolorization Methods 0.000 description 1
• 230000006866 deterioration Effects 0.000 description 1
• 238000010438 heat treatment Methods 0.000 description 1
• 238000005286 illumination Methods 0.000 description 1
• 229910003437 indium oxide Inorganic materials 0.000 description 1
• PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 description 1
• 230000003993 interaction Effects 0.000 description 1
• YAFKGUAJYKXPDI-UHFFFAOYSA-J lead tetrafluoride Chemical compound F[Pb](F)(F)F YAFKGUAJYKXPDI-UHFFFAOYSA-J 0.000 description 1
• 239000007788 liquid Substances 0.000 description 1
• 239000011244 liquid electrolyte Substances 0.000 description 1
• YQNQTEBHHUSESQ-UHFFFAOYSA-N lithium aluminate Chemical compound [Li+].[O-][Al]=O YQNQTEBHHUSESQ-UHFFFAOYSA-N 0.000 description 1
• GCICAPWZNUIIDV-UHFFFAOYSA-N lithium magnesium Chemical compound [Li].[Mg] GCICAPWZNUIIDV-UHFFFAOYSA-N 0.000 description 1
• PAZHGORSDKKUPI-UHFFFAOYSA-N lithium metasilicate Chemical compound [Li+].[Li+].[O-][Si]([O-])=O PAZHGORSDKKUPI-UHFFFAOYSA-N 0.000 description 1
• IDBFBDSKYCUNPW-UHFFFAOYSA-N lithium nitride Chemical compound [Li]N([Li])[Li] IDBFBDSKYCUNPW-UHFFFAOYSA-N 0.000 description 1
• 229910052912 lithium silicate Inorganic materials 0.000 description 1
• KUJOABUXCGVGIY-UHFFFAOYSA-N lithium zinc Chemical compound [Li].[Zn] KUJOABUXCGVGIY-UHFFFAOYSA-N 0.000 description 1
• 238000004519 manufacturing process Methods 0.000 description 1
• 239000000463 material Substances 0.000 description 1
• 229910052750 molybdenum Inorganic materials 0.000 description 1
• 239000011733 molybdenum Substances 0.000 description 1
• 239000002244 precipitate Substances 0.000 description 1
• 229910052702 rhenium Inorganic materials 0.000 description 1
• WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
• 229910052814 silicon oxide Inorganic materials 0.000 description 1
• 150000004763 sulfides Chemical class 0.000 description 1
• XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
• 229910001887 tin oxide Inorganic materials 0.000 description 1
• 229910052719 titanium Inorganic materials 0.000 description 1
• 239000010936 titanium Substances 0.000 description 1
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1