JPS63265960A - Flame-retarding resin composition - Google Patents
Flame-retarding resin compositionInfo
- Publication number
- JPS63265960A JPS63265960A JP10009487A JP10009487A JPS63265960A JP S63265960 A JPS63265960 A JP S63265960A JP 10009487 A JP10009487 A JP 10009487A JP 10009487 A JP10009487 A JP 10009487A JP S63265960 A JPS63265960 A JP S63265960A
- Authority
- JP
- Japan
- Prior art keywords
- resin
- rubber
- resin composition
- inorganic powder
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011342 resin composition Substances 0.000 title claims abstract description 10
- 229920005989 resin Polymers 0.000 claims abstract description 16
- 239000011347 resin Substances 0.000 claims abstract description 16
- 239000000843 powder Substances 0.000 claims abstract description 15
- -1 alkyl phosphate Chemical compound 0.000 claims abstract description 9
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 8
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 8
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims abstract description 8
- 239000000347 magnesium hydroxide Substances 0.000 claims abstract description 8
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims abstract description 8
- 239000010452 phosphate Substances 0.000 claims abstract description 8
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims abstract description 5
- 239000001095 magnesium carbonate Substances 0.000 claims abstract description 5
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims abstract description 5
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 4
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 claims abstract description 4
- 229960001545 hydrotalcite Drugs 0.000 claims abstract description 4
- 229910001701 hydrotalcite Inorganic materials 0.000 claims abstract description 4
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims abstract description 3
- 150000001875 compounds Chemical class 0.000 claims abstract description 3
- 125000000217 alkyl group Chemical group 0.000 claims abstract 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 4
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 4
- 239000003063 flame retardant Substances 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- 239000005060 rubber Substances 0.000 claims description 4
- 229920001971 elastomer Polymers 0.000 claims description 3
- 229920000178 Acrylic resin Polymers 0.000 claims description 2
- 239000004925 Acrylic resin Substances 0.000 claims description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 2
- 229920000181 Ethylene propylene rubber Polymers 0.000 claims description 2
- 244000043261 Hevea brasiliensis Species 0.000 claims description 2
- 229920000459 Nitrile rubber Polymers 0.000 claims description 2
- 239000004952 Polyamide Substances 0.000 claims description 2
- 239000004734 Polyphenylene sulfide Substances 0.000 claims description 2
- 239000004793 Polystyrene Substances 0.000 claims description 2
- 229920000800 acrylic rubber Polymers 0.000 claims description 2
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims description 2
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 claims description 2
- 229920005549 butyl rubber Polymers 0.000 claims description 2
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 claims description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 2
- 229920002681 hypalon Polymers 0.000 claims description 2
- 229920003052 natural elastomer Polymers 0.000 claims description 2
- 229920001194 natural rubber Polymers 0.000 claims description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 2
- 229920000058 polyacrylate Polymers 0.000 claims description 2
- 229920002647 polyamide Polymers 0.000 claims description 2
- 229920000515 polycarbonate Polymers 0.000 claims description 2
- 239000004417 polycarbonate Substances 0.000 claims description 2
- 229920000098 polyolefin Polymers 0.000 claims description 2
- 229920000069 polyphenylene sulfide Polymers 0.000 claims description 2
- 229920002223 polystyrene Polymers 0.000 claims description 2
- 229920001021 polysulfide Polymers 0.000 claims description 2
- 239000005077 polysulfide Substances 0.000 claims description 2
- 150000008117 polysulfides Polymers 0.000 claims description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 8
- 239000002253 acid Substances 0.000 abstract description 5
- 125000005907 alkyl ester group Chemical group 0.000 abstract 1
- TVACALAUIQMRDF-UHFFFAOYSA-N dodecyl dihydrogen phosphate Chemical compound CCCCCCCCCCCCOP(O)(O)=O TVACALAUIQMRDF-UHFFFAOYSA-N 0.000 abstract 1
- UHGIMQLJWRAPLT-UHFFFAOYSA-N octadecyl dihydrogen phosphate Chemical compound CCCCCCCCCCCCCCCCCCOP(O)(O)=O UHGIMQLJWRAPLT-UHFFFAOYSA-N 0.000 abstract 1
- 239000000654 additive Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 3
- 238000004898 kneading Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920005992 thermoplastic resin Polymers 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 description 1
- 239000003508 Dilauryl thiodipropionate Substances 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 235000019304 dilauryl thiodipropionate Nutrition 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000012756 surface treatment agent Substances 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 238000007779 wet slurry method Methods 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Abstract
Description
【発明の詳細な説明】 ［産業上の利用分野コ 本発明は難燃性樹脂組成物に係るものである。[Detailed description of the invention] [Industrial application fields] The present invention relates to a flame retardant resin composition.
［従来の技術］
各種樹脂に難燃性を付与する手段として、水酸化マグネ
シウム、塩基性炭酸マグネシウム、炭酸カルシウム、ハ
イドロタルサイト等の全屈の醇化物や炭酸化物を樹脂中
に添加することが行なわれている。この場合、これらの
添加量は効果の点から一般にかなり多情に用いられるの
が普通である。[Prior Art] As a means of imparting flame retardancy to various resins, it is possible to add to the resins full-strength liquefied compounds and carbonates such as magnesium hydroxide, basic magnesium carbonate, calcium carbonate, and hydrotalcite. It is being done. In this case, the amounts of these additives are generally used fairly liberally from the viewpoint of effectiveness.
［発明の解決しようとする問題点］
しかしながら、これら添加物は一般に親木性である為、
樹脂中での分散が悪く、樹脂本来の物性が著しく損われ
る欠点がある。[Problems to be solved by the invention] However, since these additives are generally wood-philic,
Dispersion in the resin is poor and the inherent physical properties of the resin are significantly impaired.
又、水酸化マグネシウムや塩基性炭酸マグネシウムにあ
っては、」−記欠点に加え、耐酸性が悪くなる欠点を有
している。Moreover, magnesium hydroxide and basic magnesium carbonate have a drawback of poor acid resistance in addition to the drawbacks mentioned above.
これら欠点に対し、樹脂への分散性の改良、物性維持、
耐酸性の向上を目的としてアニオン系界面活性剤による
表面処理が提案されている。（特公昭５７−２８４２１
号公報参照）しかしながら、かかる処理を行なっても尚
、十分満足し得るものでなく、特に耐酸性については未
だかなり不満足である。To address these drawbacks, improve dispersibility in resin, maintain physical properties,
Surface treatment with anionic surfactants has been proposed for the purpose of improving acid resistance. (Tokuko Sho 57-28421
However, even after such treatment, the results are still not fully satisfactory, and in particular, the acid resistance is still quite unsatisfactory.
［問題点を解決する為の手段］
本発明者は従来技術が有する上記欠点を排除し、耐水性
、耐ｍ性をヒ分なものにし、高温、高湿下においても１
分使用に耐え得る難燃性樹脂組成物を得ることを［１的
として種々研究、検討した結果、水酸化マグネシウム等
の無機質粉体をリン酸アルキルエステルにより処理した
ものを樹脂中に添加することにより、前記目的を達成し
得ることを見出した。かくして本発明は、リン酸アルキ
ルエステルによって処理した無機粉体を、樹脂１００部
に対し３０〜２００部添加してなる難燃性樹脂組成物を
提供するにある。[Means for Solving the Problems] The present inventor has eliminated the above-mentioned drawbacks of the prior art, has excellent water resistance and m-resistance, and has achieved 100% resistance even under high temperature and high humidity.
In order to obtain a flame-retardant resin composition that can withstand long-term use, we have conducted various research and examinations and found that an inorganic powder such as magnesium hydroxide treated with an alkyl phosphate ester is added to the resin. It has been found that the above object can be achieved by the following method. Thus, the present invention provides a flame-retardant resin composition in which 30 to 200 parts of inorganic powder treated with a phosphoric acid alkyl ester is added to 100 parts of resin.
本発明において用いられるリン酸アルキルエステルとし
ては例えばモノステアリルリン醇エステル酸、モノラウ
リルリン酸エステル、千ノオレイルリン酸エステル等の
０８〜Ｃ２２の艮釦アルキルエステルが好ましい。更に
リン酸アルキルエステルの誘導体も用い得る。As the phosphoric acid alkyl ester used in the present invention, 08 to C22 alkyl esters such as monostearyl phosphoric ester acid, monolauryl phosphoric ester, and 1,000 oleyl phosphoric ester are preferable. Furthermore, derivatives of phosphoric acid alkyl esters may also be used.
本発明に用いられる無機粉体としては、例えば水酸化マ
グネシウム、水酸化アルミニウム、Ｊ１！基性炭酸マグ
ネシウム、炭酸カルシウム、ハイドロタルサイトが挙げ
られ、とりわけ水酸化マグネシウムは好適である。これ
ら無機粉体に対するリン酸アルキルエステルの処理量は
、無機粉体１００部に対し０．０５〜１０部、好ましく
は０．１〜５部か適当である。Examples of the inorganic powder used in the present invention include magnesium hydroxide, aluminum hydroxide, J1! Examples include basic magnesium carbonate, calcium carbonate, and hydrotalcite, with magnesium hydroxide being particularly preferred. The amount of alkyl phosphate treated with these inorganic powders is 0.05 to 10 parts, preferably 0.1 to 5 parts, based on 100 parts of the inorganic powder.
その処理手段としては特に制限はなく、例えば乾式法と
してヘンシェル中に無機粉体を入れ、処理剤を直接或は
適当な溶媒で希釈して添加し、十分攪拌する手段や湿式
スラリー法等を適宜採用し得る。その他、無機粉体と樹
脂とを混練する時に同時に処理剤を投入するインテグラ
ルブレンド法等も採用し得る。There is no particular restriction on the treatment method, for example, a dry method in which inorganic powder is placed in a Henschel, a treatment agent is added directly or diluted with an appropriate solvent, and thoroughly stirred, or a wet slurry method is used as appropriate. Can be adopted. In addition, an integral blending method, in which a processing agent is added at the same time as the inorganic powder and resin are kneaded, may also be adopted.
次に、本発明に用いられる樹脂としては、種々の熱可塑
性樹脂やゴム類が挙げられる。Next, examples of the resin used in the present invention include various thermoplastic resins and rubbers.
熱可塑性樹脂としては、例えばポリオレフィン、ポリア
ミド、ポリカーボネート、ポリスチレン、アクリル樹脂
、ＡＢＳ樹脂、ポリフェニレンサルファイド、ウレタン
、エチレンビニルアセテート等が、又ゴム類としては例
えば、天然ゴム、イソプレン、ブタジェン、スチレンブ
タジェン、クロロプレン、ニトリルゴム、ブチルゴム、
クロロスルホン化ポリエチレン、多硫化ゴム、アクリル
ゴム、エチレンプロピレンゴム等が夫々挙げられる。そ
してこれら樹脂は夫々単独或は数種を併用することや所
望により共重合して用いることも可能である。Examples of thermoplastic resins include polyolefin, polyamide, polycarbonate, polystyrene, acrylic resin, ABS resin, polyphenylene sulfide, urethane, ethylene vinyl acetate, etc., and examples of rubbers include natural rubber, isoprene, butadiene, styrene butadiene, Chloroprene, nitrile rubber, butyl rubber,
Examples include chlorosulfonated polyethylene, polysulfide rubber, acrylic rubber, and ethylene propylene rubber. These resins may be used alone or in combination, or may be copolymerized if desired.
かくしてこれら樹脂と処理された無機粉体との混合手段
としては特に制限はなく、これらを均一に混合し得る手
段であるなら適宜な手段を採用し得る。例えば、押出混
練、ロール混練、バンバリーミキサ−による混練等が挙
げられる。又成形体を得ることもでき、この場合には射
出成形、押出し成形、プレス成形等を採用し得る。There is no particular restriction on the means for mixing these resins and the treated inorganic powder, and any suitable means may be employed as long as it is capable of uniformly mixing them. Examples include extrusion kneading, roll kneading, and kneading using a Banbury mixer. It is also possible to obtain a molded article, in which case injection molding, extrusion molding, press molding, etc. can be employed.
更に本発明においては、これら樹脂組成物に対し、本発
明の目的を逸脱しない限り他の適宜な添加剤を併用する
こともできる。かかる添加剤としては例えば、ガラスフ
ァイ／へ一等の充埴材、カーボンブラックや酸化チタン
等の顔料や着色剤、ジラウリルチオジプロピオネートＷ
の酸化防止剤、ステアリン酸亜鉛等の滑剤、２−ヒドロ
キシ−４−オクトキシベンンフェノン等の紫外線吸収剤
類等が羊げられる。Furthermore, in the present invention, other appropriate additives may be used in combination with these resin compositions as long as they do not depart from the purpose of the present invention. Such additives include, for example, fillers such as glass fibre/hexafluoride, pigments and coloring agents such as carbon black and titanium oxide, and dilauryl thiodipropionate W.
Examples include antioxidants, lubricants such as zinc stearate, and ultraviolet absorbers such as 2-hydroxy-4-octoxybennephenone.
［実施例］
以下実施例等において用いた試験方法は次の如くである
。[Examples] The test methods used in the following Examples are as follows.
耐水性：位相水蒸気気相にサンプルを吊し、ＣＯ２ガス
を１００°Ｃ１圧力３ｋｇ／ｃｍ２ Ｇ下に４０時間接
触せしめてＣＯ２に対する反応性を外観変化及び重量変
化で評
価した。Water resistance: A sample was suspended in a phase steam vapor phase and brought into contact with CO2 gas at 100°C and a pressure of 3kg/cm2G for 40 hours, and the reactivity to CO2 was evaluated by changes in appearance and weight.
引張りテスト： ＪＩＳ−に−７１１３による。Tensile test: According to JIS-7113.
トルクの測定ニラポプラストミル（東洋精機■製）を用
い、樹脂と粉体とを１５０
°Ｃで混練したときのトルクを測定
し、加工性の目安とした。Measurement of Torque Using a Nilapoplast Mill (manufactured by Toyo Seiki ■), the torque when the resin and powder were kneaded at 150°C was measured and used as a measure of workability.
実施例１〜３
粉状の水酸化マグネシウム（以下水マグという）１ｋｇ
に、ジ自トリデシルリン酸エステルをそれぞれ２０ｇ、
５０ｇ、１００ｇ投入しヘンシェルミキサーを用いて常
温で３０分間高速攪拌処理した。この表面処理した水マ
グを低密度ポリエチレン１００部に対し、１７０部、他
にカーボンブラック２部をロール混合しプレス成形して
３０ｍｍ Ｘｌ、５部ｍｔのシートを得た。試験結果
を表１に示す。Examples 1 to 3 1 kg of powdered magnesium hydroxide (hereinafter referred to as water mug)
, 20 g of diautotridecyl phosphate,
50g and 100g were added and stirred at high speed for 30 minutes at room temperature using a Henschel mixer. This surface-treated water mug was roll-mixed with 170 parts of low-density polyethylene, 2 parts of carbon black, and press-molded to obtain a sheet of 30 mm Xl and 5 parts mt. The test results are shown in Table 1.
実施例４〜７
水マグ１ｋｇに対し、表２の各種アルキルリン酸エステ
ルをそれぞれ２０ｇ、ヘンシェルミキサーを用い常温で
３０分間高速で攪拌処理した。この処理水マグを実施例
１〜３と同様の方法で混練、プレス成形し試料とした。Examples 4 to 7 20 g of each of the various alkyl phosphate esters shown in Table 2 were stirred at high speed for 30 minutes at room temperature using a Henschel mixer per 1 kg of water mug. This treated water mug was kneaded and press-molded in the same manner as in Examples 1 to 3 to prepare a sample.
試験結果を表３に示す。The test results are shown in Table 3.
比較例１〜２
表面処理剤としてオレイン酸およびステアリン酸をそれ
ぞれ水マグ１ｋｇに対し２０ｇ処理する他は、実施例１
〜７と同様の処理を行なって試験した。結果を表３に示
す。Comparative Examples 1 to 2 Example 1 except that 20 g of oleic acid and stearic acid were each used as a surface treatment agent per 1 kg of water mug.
Tests were carried out in the same manner as in 7. The results are shown in Table 3.
表 １ 表 ２ 表 ３Table 1 Table 2 Table 3
Claims (1)
を、樹脂１００部に対し３０〜２００部添加してなる難
燃性樹脂組成物。 ２、リン酸アルキルエステルが ▲数式、化学式、表等があります▼ 又は（ＲＯ）＿ｎＰ（ＯＨ）＿３＿−＿ｎ、但しＲ：ア
ルキル基、ｎ＝０、１、２、３で表わされる化合物で特
許請求の範囲１の樹脂組成物。 ３、無機粉体が水酸化マグネシウム、水酸化アルミニウ
ム、塩基性炭酸マグネシウム、炭酸カルシウム、ハイド
ロタルサイトである請求の範囲１の樹脂組成物。 ４、樹脂がポリオレフィン、ポリアミド、ポリカーボネ
ート、ポリスチレン、アクリル樹 脂、ＡＢＳ樹脂、ポリフェニレンサルファイド、ウレタ
ン、エチレンビニルアセテート、天然ゴム、イソプレン
、ブタジエン、スチレンプタジエンゴム、クロロプレン
、ニトリルゴム、ブチルゴム、クロロスルホン化ポリエ
チレン、多硫化ゴム、アクリルゴム、エチレンプロピレ
ンゴムである請求の範囲１の樹脂組成物。 ５、リン酸アルキルエステルの処理量は、無機粉体１０
０部に対し０．０５〜１０部で特許請求の範囲１の樹脂
組成物。[Scope of Claims] 1. A flame-retardant resin composition prepared by adding 30 to 200 parts of inorganic powder treated with a phosphoric acid alkyl ester to 100 parts of resin. 2. Phosphoric acid alkyl ester is a patented compound represented by ▲ mathematical formula, chemical formula, table, etc. ▼ or (RO)_nP(OH)_3_-_n, where R: alkyl group, n = 0, 1, 2, 3 A resin composition according to claim 1. 3. The resin composition according to claim 1, wherein the inorganic powder is magnesium hydroxide, aluminum hydroxide, basic magnesium carbonate, calcium carbonate, or hydrotalcite. 4. Resin is polyolefin, polyamide, polycarbonate, polystyrene, acrylic resin, ABS resin, polyphenylene sulfide, urethane, ethylene vinyl acetate, natural rubber, isoprene, butadiene, styrene-butadiene rubber, chloroprene, nitrile rubber, butyl rubber, chlorosulfonated polyethylene , polysulfide rubber, acrylic rubber, or ethylene propylene rubber. 5. The amount of alkyl phosphate treated is 10% of the inorganic powder.
0 parts to 0.05 to 10 parts of the resin composition according to claim 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10009487A JPS63265960A (en) | 1987-04-24 | 1987-04-24 | Flame-retarding resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10009487A JPS63265960A (en) | 1987-04-24 | 1987-04-24 | Flame-retarding resin composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63265960A true JPS63265960A (en) | 1988-11-02 |
| JPH042617B2 JPH042617B2 (en) | 1992-01-20 |
Family
ID=14264820
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10009487A Granted JPS63265960A (en) | 1987-04-24 | 1987-04-24 | Flame-retarding resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63265960A (en) |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0341132A (en) * | 1989-07-10 | 1991-02-21 | Kyowa Chem Ind Co Ltd | Flame retardant and flame-retarding resin composition |
| JPH0391563A (en) * | 1989-09-05 | 1991-04-17 | Nippon G Ii Plast Kk | Polyphenylene sulfide resin composition |
| WO1992006135A1 (en) * | 1990-10-08 | 1992-04-16 | Henkel Kommanditgesellschaft Auf Aktien | Cationic laminar compounds |
| WO1993006173A1 (en) * | 1991-09-24 | 1993-04-01 | Asahi Kasei Kogyo Kabushiki Kaisha | Polyurethane composition |
| JPH08113769A (en) * | 1994-10-19 | 1996-05-07 | Tosoh Corp | Bonding composition and laminate using bonding composition |
| FR2734835A1 (en) * | 1995-09-22 | 1996-12-06 | Zschimmer Schwarz France | Mineral or organic particle suspension surface property modification |
| US5990206A (en) * | 1996-02-28 | 1999-11-23 | Kao Corporation | Asphalt modifier composition and asphalt composition |
| WO2000026289A1 (en) * | 1998-10-30 | 2000-05-11 | Kyowa Chemical Industry Co., Ltd. | Inhibitors against deterioration by chlorine and polyurethane compositions |
| WO2001010958A1 (en) * | 1999-08-06 | 2001-02-15 | Kyowa Chemical Industry Co., Ltd. | Highly acid-resistant, hydration-resistant magnesium oxide particles and resin compositions |
| CN1098897C (en) * | 1999-06-03 | 2003-01-15 | 南京大学 | Process for preparing S and N contg. paraffin reinforced and toughened aluminium powder-polyurethane composite material |
| JP2010047703A (en) * | 2008-08-22 | 2010-03-04 | Kyowa Chem Ind Co Ltd | Flame-retardant resin composition |
| JP2014001406A (en) * | 2000-11-27 | 2014-01-09 | Cristal Usa Inc | Pigments treated with organo-phosphoric acids and their salts |
| JP2014047234A (en) * | 2012-08-29 | 2014-03-17 | Kao Corp | Polylactic acid resin composition |
| JP2015511646A (en) * | 2012-03-13 | 2015-04-20 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | Thermoplastic polyurethane, method for producing thermoplastic polyurethane, method for using thermoplastic polyurethane, method for using flame retardant |
| JP2015521666A (en) * | 2012-06-22 | 2015-07-30 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | Flame retardant thermoplastic polyurethane based on polycarbonate diol |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5173040A (en) * | 1974-12-20 | 1976-06-24 | Nippon Zeon Co | Taihenshokusei nannenseikatsushaonseini suguretaseikeihin |
| JPS5330648A (en) * | 1976-09-02 | 1978-03-23 | Kyowa Kagaku Kougiyou Kk | Incombustible resin compositions |
| JPS5569644A (en) * | 1978-11-15 | 1980-05-26 | Ciba Geigy Ag | Fireeretarded plastic polyvinyl chloride composition |
| JPS5592771A (en) * | 1978-09-20 | 1980-07-14 | Aluminum Co Of America | Coated inorganic filler |
| JPS62280255A (en) * | 1986-05-29 | 1987-12-05 | Asahi Chem Ind Co Ltd | Flame-retardant resin composition |
-
1987
- 1987-04-24 JP JP10009487A patent/JPS63265960A/en active Granted
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5173040A (en) * | 1974-12-20 | 1976-06-24 | Nippon Zeon Co | Taihenshokusei nannenseikatsushaonseini suguretaseikeihin |
| JPS5330648A (en) * | 1976-09-02 | 1978-03-23 | Kyowa Kagaku Kougiyou Kk | Incombustible resin compositions |
| JPS5592771A (en) * | 1978-09-20 | 1980-07-14 | Aluminum Co Of America | Coated inorganic filler |
| JPS5569644A (en) * | 1978-11-15 | 1980-05-26 | Ciba Geigy Ag | Fireeretarded plastic polyvinyl chloride composition |
| JPS62280255A (en) * | 1986-05-29 | 1987-12-05 | Asahi Chem Ind Co Ltd | Flame-retardant resin composition |
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5447969A (en) * | 1901-09-24 | 1995-09-05 | Asahi Kasei Kogyo Kabushiki Kaisha | Polyurethane composition |
| JPH0341132A (en) * | 1989-07-10 | 1991-02-21 | Kyowa Chem Ind Co Ltd | Flame retardant and flame-retarding resin composition |
| US5151455A (en) * | 1989-07-10 | 1992-09-29 | Kyowa Chemical Industry | Flame retardant and flame retardant resin composition |
| JPH0563499B2 (en) * | 1989-07-10 | 1993-09-10 | Kyowa Kagaku Kogyo Kk | |
| JPH0391563A (en) * | 1989-09-05 | 1991-04-17 | Nippon G Ii Plast Kk | Polyphenylene sulfide resin composition |
| WO1992006135A1 (en) * | 1990-10-08 | 1992-04-16 | Henkel Kommanditgesellschaft Auf Aktien | Cationic laminar compounds |
| WO1993006173A1 (en) * | 1991-09-24 | 1993-04-01 | Asahi Kasei Kogyo Kabushiki Kaisha | Polyurethane composition |
| JPH08113769A (en) * | 1994-10-19 | 1996-05-07 | Tosoh Corp | Bonding composition and laminate using bonding composition |
| FR2734835A1 (en) * | 1995-09-22 | 1996-12-06 | Zschimmer Schwarz France | Mineral or organic particle suspension surface property modification |
| US5990206A (en) * | 1996-02-28 | 1999-11-23 | Kao Corporation | Asphalt modifier composition and asphalt composition |
| WO2000026289A1 (en) * | 1998-10-30 | 2000-05-11 | Kyowa Chemical Industry Co., Ltd. | Inhibitors against deterioration by chlorine and polyurethane compositions |
| CN1098897C (en) * | 1999-06-03 | 2003-01-15 | 南京大学 | Process for preparing S and N contg. paraffin reinforced and toughened aluminium powder-polyurethane composite material |
| WO2001010958A1 (en) * | 1999-08-06 | 2001-02-15 | Kyowa Chemical Industry Co., Ltd. | Highly acid-resistant, hydration-resistant magnesium oxide particles and resin compositions |
| JP2014001406A (en) * | 2000-11-27 | 2014-01-09 | Cristal Usa Inc | Pigments treated with organo-phosphoric acids and their salts |
| JP2010047703A (en) * | 2008-08-22 | 2010-03-04 | Kyowa Chem Ind Co Ltd | Flame-retardant resin composition |
| JP2015511646A (en) * | 2012-03-13 | 2015-04-20 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | Thermoplastic polyurethane, method for producing thermoplastic polyurethane, method for using thermoplastic polyurethane, method for using flame retardant |
| JP2015521666A (en) * | 2012-06-22 | 2015-07-30 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | Flame retardant thermoplastic polyurethane based on polycarbonate diol |
| JP2014047234A (en) * | 2012-08-29 | 2014-03-17 | Kao Corp | Polylactic acid resin composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH042617B2 (en) | 1992-01-20 |
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