JPH0517937B2 - - Google Patents
Info
- Publication number
- JPH0517937B2 JPH0517937B2 JP12978484A JP12978484A JPH0517937B2 JP H0517937 B2 JPH0517937 B2 JP H0517937B2 JP 12978484 A JP12978484 A JP 12978484A JP 12978484 A JP12978484 A JP 12978484A JP H0517937 B2 JPH0517937 B2 JP H0517937B2
- Authority
- JP
- Japan
- Prior art keywords
- ethanolamine
- present
- chlorine
- perchlorate
- added
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920005989 resin Polymers 0.000 claims description 21
- 239000011347 resin Substances 0.000 claims description 21
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 claims description 19
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 18
- 239000000460 chlorine Substances 0.000 claims description 16
- 229910052801 chlorine Inorganic materials 0.000 claims description 16
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 15
- 239000011342 resin composition Substances 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 description 9
- 238000004040 coloring Methods 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 9
- 230000002265 prevention Effects 0.000 description 9
- 239000000203 mixture Substances 0.000 description 8
- 150000003839 salts Chemical class 0.000 description 8
- RRMWARHVTVWNOC-UHFFFAOYSA-N 2-aminoethyl perchlorate Chemical compound Cl(=O)(=O)(=O)OCCN RRMWARHVTVWNOC-UHFFFAOYSA-N 0.000 description 7
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 7
- 239000003381 stabilizer Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 229960004418 trolamine Drugs 0.000 description 6
- 238000009472 formulation Methods 0.000 description 5
- -1 polyethylene Polymers 0.000 description 4
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000004709 Chlorinated polyethylene Substances 0.000 description 2
- 239000004593 Epoxy Chemical class 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 150000008043 acidic salts Chemical class 0.000 description 2
- 150000001447 alkali salts Chemical class 0.000 description 2
- 229910052788 barium Inorganic materials 0.000 description 2
- 229910052793 cadmium Inorganic materials 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229910052745 lead Inorganic materials 0.000 description 2
- 231100000053 low toxicity Toxicity 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- SBMJKCDBJMFHGS-UHFFFAOYSA-L barium(2+);2-nonylphenolate Chemical compound [Ba+2].CCCCCCCCCC1=CC=CC=C1[O-].CCCCCCCCCC1=CC=CC=C1[O-] SBMJKCDBJMFHGS-UHFFFAOYSA-L 0.000 description 1
- AGXUVMPSUKZYDT-UHFFFAOYSA-L barium(2+);octadecanoate Chemical compound [Ba+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AGXUVMPSUKZYDT-UHFFFAOYSA-L 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 238000009775 high-speed stirring Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 150000002903 organophosphorus compounds Chemical class 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical class OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920013716 polyethylene resin Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000012756 surface treatment agent Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- CHJMFFKHPHCQIJ-UHFFFAOYSA-L zinc;octanoate Chemical compound [Zn+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O CHJMFFKHPHCQIJ-UHFFFAOYSA-L 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Description
産業上の利用分野
本発明は着色防止性に優れた含塩素樹脂組成物
に関する。
従来の技術及び問題点
一般に含塩素樹脂、例えばポリ塩化ビニル樹
脂、ポリ塩化ビニリデン樹脂、塩素化ポリエチレ
ン樹脂、塩化ビニル−塩化ビニリデン共重合体等
は、加工時の熱により著しい着色や分解が起る。
これらを防止するために、安定剤が添加されてい
る。安定剤としてCd，Pbの化合物を使用したも
のはその着色防止性の点で満足するものが得られ
ていたが、Cd，Pbの毒性のため近年その使用は
制限されつつある。
このため毒性の低い金属であるCa，Ba，Mg，
Znの化合物を使用した安定剤の開発が進められ
ている。しかしこれらCa，Ba，Mg，Zn化合物
は毒性が低い点は長所であるが、着色防止性の面
で充分でないので、有機リン化合物やエポキシ化
合物、また、特開昭53−18655、特開昭55−9625、
特開昭55−71744号公報に見られるようなその他
の種々の着色防止剤を組み合せて着色防止性の向
上を計らねばならない。それでも加工条件が苛酷
な場合など着色防止性は完全ではない。
問題点の解決の手段
本発明者等は研究を重ねた結果、エタノールア
ミンの過塩素酸塩を、従来より安定剤として使用
されている化合物と共に含塩素樹脂に添加するこ
とにより、著しく着色防止性が向上することを見
出し本発明を完成するに至つた。すなわち、本発
明は、含塩素樹脂100重量部に対し、エタノール
アミンの過塩素酸塩を0.001〜５重量部好ましく
は0.01〜５重量部更に好ましくは0.1〜５重量部
添加することを特徴とする含塩素樹脂組成物であ
る。
過塩素酸塩の調製
本発明に使用するエタノールアミンの過塩素酸
塩は、エタノールアミンを過塩素酸の水溶液で中
和することで得ることが出来る。使用するエタノ
ールアミンはモノ、ジ、トリ、いずれのエタノー
ルアミンでも良いが、特にトリエタノールアミン
の過塩素酸塩が、すぐれた着色防止性を示す。
また本発明のエタノールアミンの過塩素酸塩
は、塩基性塩、および酸性塩も包含するものであ
る。例えばトリエタノールアミンに１モルに対
し、過塩素酸１モルで中和した場合、中性塩が得
られる。トリエタノールアミンの１モルに対し過
塩素酸0.6モルの場合塩基性塩が、さらにトリエ
タノールアミンの１モルに対し過塩素酸1.2モル
の場合酸性塩がそれぞれ得られるが、いずれも含
塩素樹脂に添加した場合すぐれた着色防止性を示
す。
本発明のエタノールアミンの過塩素酸塩は水溶
液の状態で含塩素樹脂へ添加するものである。こ
れはエタノールアミンは水溶性であり又過塩素酸
は60％、40％等の水溶液としてしか供給されない
ためである。エタノールアミンの過塩素酸塩の水
溶液中の含有量が既知であれば、含塩素樹脂への
エタノールアミンの過酸素酸塩の添加量は100％
換算で算出可能である。また、水溶液の状態で含
塩素樹脂へ添加しても、分散、混合を充分に行な
えば、充分に改善効果を示すものである。
応用できる含塩素樹脂の範囲
本発明にいう含塩素樹脂とは、例えば塩化ビニ
ル、塩化ビニリデン等の重合により得られる単独
および共重合体並びにこれらの共重合可能な化合
物との共重合体、例えば塩化ビニール−エチレン
共重合体、更にはポリエチレン、ポリプロピレン
等のポリオレフイン樹脂を塩素化して得られた樹
脂、例えば塩素化ポリエチレン、塩素化ポリプロ
ピレン等が挙げられる。更に、含塩素樹脂と塩素
を含まない樹脂例えばABS、MBS、EVA、ブタ
ジエン樹脂等とのポリマーブレンドの際にも本発
明は用いることができる。
これ等含塩素樹脂100重量部に対する本発明の
エタノールアミンの過塩素酸塩の添加量は0.001
〜５重量部である。
本発明の応用範囲
本発明組成物と通常安定剤成分として使用され
ている公知の物質とを併用することは、なんら本
発明の効果を減ずるものではない。これら通常使
用される安定剤とは、金属有機酸塩類、有機フオ
スフアイト化合物、有機錫化合物、酸化防止剤、
紫外線吸収剤、金属酸化物、金属水酸化物、ポリ
オール類、含窒素系非金属化合物、エポキシ化合
物等が挙げられる。この他に必要に応じて可塑
剤、顔料、充填剤、発泡剤、帯電防止剤、防曇
剤、プレートアウト防止剤、表面処理剤、滑剤、
難燃剤等を配合に加えることは何等差し支えな
い。
実施例
以下実施例により具体的に説明する。実施例に
於けるテスト方法は次の通りである。各実施例の
配合にもとずき、各配合組成を計量し、スチーム
ジヤケツト付きのヘンシエルミキサーに投入し、
スチームで加熱しながら、高速回転（3000R.P.
M）にて、約５分間混合を行い、混合物の品温が
110℃まで上昇したところで内容物を取出し、常
温まで放冷した。なお本発明の塩の濃度はエタノ
ールアミン１モルに対して調整する過塩素酸水溶
液のモル数によつて異るが本実施例では、約70％
〜50％の範囲内にある。本発明の塩に伴なう水分
は上述の如く加熱しながら高速撹拌を行うこと
で、含塩素樹脂へ均一分散、除去をすることがで
きる。
次に、均一に分散された配合物100ｇをミキシ
ングロールを用い、175℃で５分間混練し厚さ0.3
mmの試験用シートを作成した。このシートを５cm
×５cmの大きさに切り、重ね合わせて熱プレス機
を用い、180℃にて５分間、10分間、15分間熱プ
レスを行ない、着色防止性を比較した。
評価数値は次の通り
１〜２ 黒色〜褐色
３〜４ 赤褐色
５〜６ 黄 色
７〜８ 微黄色
９〜10 無 色
実施例 １
配合 塩化ビニル樹脂 100重量部
DOP 40
ステアリン酸バリウム １
本発明の塩（第１表） 0.1 （水溶液
で使用する
が、水の部分
を除いた100
％換算での添
加量）
結果を第１表に示した。
INDUSTRIAL APPLICATION FIELD The present invention relates to a chlorine-containing resin composition with excellent coloration prevention properties. Conventional techniques and problems In general, chlorine-containing resins such as polyvinyl chloride resin, polyvinylidene chloride resin, chlorinated polyethylene resin, vinyl chloride-vinylidene chloride copolymer, etc. undergo significant discoloration and decomposition due to heat during processing. .
To prevent these, stabilizers are added. The use of Cd and Pb compounds as stabilizers has been satisfactory in terms of anti-coloration properties, but their use has been restricted in recent years due to the toxicity of Cd and Pb. Therefore, Ca, Ba, Mg, which are metals with low toxicity,
Stabilizers using Zn compounds are being developed. However, although these Ca, Ba, Mg, and Zn compounds have the advantage of low toxicity, they do not have sufficient anti-coloring properties, so organic phosphorus compounds, epoxy compounds, and 55−9625,
In order to improve the coloring prevention properties, it is necessary to combine various other coloring inhibitors such as those found in JP-A-55-71744. Even so, the coloring prevention property is not perfect when the processing conditions are severe. Means for Solving the Problems As a result of repeated research, the present inventors have found that by adding ethanolamine perchlorate to chlorine-containing resins together with a compound conventionally used as a stabilizer, the present inventors have achieved remarkable coloration prevention properties. The present invention was completed based on the discovery that this improves the performance of the present invention. That is, the present invention is characterized in that 0.001 to 5 parts by weight, preferably 0.01 to 5 parts by weight, and more preferably 0.1 to 5 parts by weight of ethanolamine perchlorate is added to 100 parts by weight of the chlorine-containing resin. It is a chlorine-containing resin composition. Preparation of perchlorate The perchlorate of ethanolamine used in the present invention can be obtained by neutralizing ethanolamine with an aqueous solution of perchloric acid. The ethanolamine used may be mono-, di-, or tri-ethanolamine, but perchlorate of triethanolamine exhibits particularly excellent coloring prevention properties. The ethanolamine perchlorate of the present invention also includes basic salts and acidic salts. For example, when 1 mole of triethanolamine is neutralized with 1 mole of perchloric acid, a neutral salt is obtained. A basic salt is obtained when 1 mole of triethanolamine is used with 0.6 mole of perchloric acid, and an acidic salt is obtained when 1 mole of triethanolamine is used with 1.2 moles of perchloric acid. When added, it exhibits excellent coloration prevention properties. The ethanolamine perchlorate of the present invention is added to the chlorinated resin in the form of an aqueous solution. This is because ethanolamine is water-soluble and perchloric acid is supplied only as a 60%, 40%, etc. aqueous solution. If the content of ethanolamine perchlorate in the aqueous solution is known, the amount of ethanolamine peroxylate added to the chlorine-containing resin is 100%.
It can be calculated by conversion. Furthermore, even if it is added to the chlorine-containing resin in the form of an aqueous solution, it will exhibit sufficient improvement effects as long as it is sufficiently dispersed and mixed. Range of applicable chlorine-containing resins The chlorine-containing resins referred to in the present invention include, for example, homopolymers and copolymers obtained by polymerization of vinyl chloride, vinylidene chloride, etc., and copolymers with compounds that can be copolymerized with these, such as chlorinated resins. Examples include resins obtained by chlorinating vinyl-ethylene copolymers and polyolefin resins such as polyethylene and polypropylene, such as chlorinated polyethylene and chlorinated polypropylene. Furthermore, the present invention can also be used in polymer blends of chlorine-containing resins and chlorine-free resins such as ABS, MBS, EVA, butadiene resins, etc. The amount of the ethanolamine perchlorate of the present invention added to 100 parts by weight of these chlorine-containing resins is 0.001.
~5 parts by weight. Scope of Application of the Present Invention The combined use of the composition of the present invention and a known substance commonly used as a stabilizer component does not diminish the effects of the present invention. These commonly used stabilizers include metal organic acid salts, organic phosphite compounds, organic tin compounds, antioxidants,
Examples include ultraviolet absorbers, metal oxides, metal hydroxides, polyols, nitrogen-containing nonmetallic compounds, and epoxy compounds. In addition, plasticizers, pigments, fillers, foaming agents, antistatic agents, antifogging agents, plate-out prevention agents, surface treatment agents, lubricants,
There is no problem in adding flame retardants etc. to the formulation. Examples The following examples will specifically explain the invention. The test method in the example is as follows. Based on the formulation of each example, each formulation was weighed and put into a Henschel mixer equipped with a steam jacket,
Rotates at high speed (3000R.P.) while heating with steam.
M), mix for about 5 minutes until the temperature of the mixture reaches
When the temperature rose to 110°C, the contents were taken out and allowed to cool to room temperature. Note that the concentration of the salt of the present invention varies depending on the number of moles of the perchloric acid aqueous solution adjusted to 1 mole of ethanolamine, but in this example, it is approximately 70%.
Within the range of ~50%. The water accompanying the salt of the present invention can be uniformly dispersed and removed in the chlorine-containing resin by performing high-speed stirring while heating as described above. Next, 100g of the uniformly dispersed compound was kneaded for 5 minutes at 175°C using a mixing roll until the thickness was 0.3cm.
A test sheet of mm was created. This sheet is 5cm
The pieces were cut into 5 cm pieces, stacked one on top of the other, and heat pressed at 180°C for 5 minutes, 10 minutes, and 15 minutes using a heat press machine to compare the coloring prevention properties. The evaluation values are as follows: 1-2 Black to brown 3-4 Reddish brown 5-6 Yellow 7-8 Slight yellow 9-10 Colorless Example 1 Formulation Vinyl chloride resin 100 parts by weight DOP 40 Barium stearate 1 According to the present invention Salt (Table 1) 0.1 (Used in aqueous solution, but excluding the water part 100
(Amount added in terms of %) The results are shown in Table 1.
【表】
実施例 ２
塩化ビニル樹脂 100重量部
ABS 30
DOP 40
炭酸カルシウム 10
バリウムノニルフエネート 1.0
亜鉛オクトエート 0.05
ペンタエリスリトール 0.3
本発明の塩（第２表） 0.2 （水溶液で使用
するが水の部分を除い
た100％換算での添加
量）
また、比較のため本発明の塩の代りに、公知の
着色防止剤を0.2重量部添加し、対照とした。
結果を第２表に示した。[Table] Example 2 Vinyl chloride resin 100 parts by weight ABS 30 DOP 40 Calcium carbonate 10 Barium nonyl phenate 1.0 Zinc octoate 0.05 Pentaerythritol 0.3 Salt of the present invention (Table 2) 0.2 (Used in aqueous solution, but the water part For comparison, instead of the salt of the present invention, 0.2 parts by weight of a known coloring inhibitor was added as a control. The results are shown in Table 2.
【表】
実施例 ３
実施例１と同一の配合で、エタノールアミンと
過塩素酸との割合及びエタノールアミン過塩素酸
塩の添加量を第３表に示すように種々に変更して
試験した。
結果を第３表に示した。[Table] Example 3 Tests were conducted using the same formulation as in Example 1, but with various changes in the ratio of ethanolamine to perchloric acid and the amount of ethanolamine perchlorate added as shown in Table 3. The results are shown in Table 3.
【表】
発明の効果
実施例１の結果から明らかな如く、本発明の塩
は、水溶液の状態であつても、含塩素樹脂へ配合
する際加熱しながら、高速撹拌を行なうことで、
通常の添加物と同様に使用でき、その添加効果を
発揮することが分かる。また、エタノールアミン
塩は対照と比較しモノ、ジ、トリいずれもその着
色防止性にすぐれ、特にエタノールアミンがトリ
エタノールアミンの場合改善効果が著しいことが
分かる。
実施例２に於ては、本発明の塩は対照の公知着
色防止剤に比較して着色防止性が優れていること
がわかる。したがつて、商品価値が著しく高い塩
素含有樹脂が提供でき、また、他の高価な公知安
定剤の配合量の減少による配合価格の低減など、
顕著な効果を有するものである。[Table] Effects of the Invention As is clear from the results of Example 1, even when the salt of the present invention is in the form of an aqueous solution, it can be mixed with a chlorine-containing resin by heating and stirring at high speed.
It can be seen that it can be used in the same way as ordinary additives and exhibits its effects. In addition, it can be seen that the mono-, di-, and tri-ethanolamine salts have excellent anti-coloration properties compared to the control, and the improvement effect is particularly remarkable when the ethanolamine is triethanolamine. In Example 2, it can be seen that the salt of the present invention has superior coloring prevention properties compared to the known coloring inhibitor as a control. Therefore, we can provide a chlorine-containing resin with extremely high commercial value, and also reduce the compounding price by reducing the amount of other expensive known stabilizers.
It has a remarkable effect.
Claims (1)
ミンの過塩素塩酸を0.001〜５重量部添加するこ
とを特徴とする含塩素樹脂組成物。1. A chlorine-containing resin composition characterized in that 0.001 to 5 parts by weight of perchloric acid of ethanolamine is added to 100 parts by weight of the chlorine-containing resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12978484A JPS619451A (en) | 1984-06-23 | 1984-06-23 | Chlorine-containing resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12978484A JPS619451A (en) | 1984-06-23 | 1984-06-23 | Chlorine-containing resin composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS619451A JPS619451A (en) | 1986-01-17 |
| JPH0517937B2 true JPH0517937B2 (en) | 1993-03-10 |
Family
ID=15018136
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12978484A Granted JPS619451A (en) | 1984-06-23 | 1984-06-23 | Chlorine-containing resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS619451A (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1343838B1 (en) * | 2000-12-13 | 2005-04-06 | Crompton Vinyl Additives GmbH | Stabilizer system for stabilizing polymers that contain halogen |
| DE10124734A1 (en) | 2001-05-21 | 2002-12-05 | Baerlocher Gmbh | Finely divided stabilizer composition for halogen-containing polymers |
| DE10160662A1 (en) * | 2001-12-11 | 2003-06-18 | Baerlocher Gmbh | Stabilizer composition, useful for foamed material and polymer composition useful for production of hard or (especially) soft PVC, contains an organic onium perchlorate |
| US20030153661A1 (en) * | 2002-01-04 | 2003-08-14 | Crompton Corporation | Stability improvement of aluminum hydroxide in PVC compound |
| JP2004315787A (en) * | 2003-04-11 | 2004-11-11 | Rohm & Haas Co | Heat stabilizer composition for halogen-containing vinyl polymer |
| CN1757665A (en) * | 2004-10-07 | 2006-04-12 | 罗门哈斯公司 | Thermal stabilizer compositions for halogen-containing vinyl polymers |
| AU2005333454B2 (en) † | 2005-06-23 | 2011-09-22 | Catena Additives Gmbh & Co. Kg | Coordination-polymeric triethanolamineperchlorato(triflato)metal inner complexes as additives for synthetic polymers |
| FR2986003B1 (en) * | 2012-01-24 | 2015-01-16 | Arkema France | PROCESS FOR THE PREPARATION OF HALOGEN POLYMERS |
| TWI689538B (en) | 2018-11-12 | 2020-04-01 | 南亞塑膠工業股份有限公司 | Stabilizer for use in halogen-containing polymer and its use thereof |
-
1984
- 1984-06-23 JP JP12978484A patent/JPS619451A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS619451A (en) | 1986-01-17 |
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| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |