JPS6324485B2 - - Google Patents
Info
- Publication number
- JPS6324485B2 JPS6324485B2 JP56005063A JP506381A JPS6324485B2 JP S6324485 B2 JPS6324485 B2 JP S6324485B2 JP 56005063 A JP56005063 A JP 56005063A JP 506381 A JP506381 A JP 506381A JP S6324485 B2 JPS6324485 B2 JP S6324485B2
- Authority
- JP
- Japan
- Prior art keywords
- bromide
- chlorine
- iodide
- oxidizing agent
- glycine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 claims description 42
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 33
- 239000000460 chlorine Substances 0.000 claims description 33
- 229910052801 chlorine Inorganic materials 0.000 claims description 33
- 239000007800 oxidant agent Substances 0.000 claims description 33
- 239000004471 Glycine Substances 0.000 claims description 21
- 239000007864 aqueous solution Substances 0.000 claims description 18
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 claims description 16
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 14
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 12
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 claims description 12
- FVAUCKIRQBBSSJ-UHFFFAOYSA-M sodium iodide Chemical compound [Na+].[I-] FVAUCKIRQBBSSJ-UHFFFAOYSA-M 0.000 claims description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 claims description 4
- 230000000087 stabilizing effect Effects 0.000 claims description 4
- CEJLBZWIKQJOAT-UHFFFAOYSA-N dichloroisocyanuric acid Chemical compound ClN1C(=O)NC(=O)N(Cl)C1=O CEJLBZWIKQJOAT-UHFFFAOYSA-N 0.000 claims description 3
- YRIZYWQGELRKNT-UHFFFAOYSA-N 1,3,5-trichloro-1,3,5-triazinane-2,4,6-trione Chemical compound ClN1C(=O)N(Cl)C(=O)N(Cl)C1=O YRIZYWQGELRKNT-UHFFFAOYSA-N 0.000 claims description 2
- KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- SWLVFNYSXGMGBS-UHFFFAOYSA-N ammonium bromide Chemical compound [NH4+].[Br-] SWLVFNYSXGMGBS-UHFFFAOYSA-N 0.000 claims description 2
- 229910001622 calcium bromide Inorganic materials 0.000 claims description 2
- WGEFECGEFUFIQW-UHFFFAOYSA-L calcium dibromide Chemical compound [Ca+2].[Br-].[Br-] WGEFECGEFUFIQW-UHFFFAOYSA-L 0.000 claims description 2
- 159000000007 calcium salts Chemical class 0.000 claims description 2
- OTCKOJUMXQWKQG-UHFFFAOYSA-L magnesium bromide Chemical compound [Mg+2].[Br-].[Br-] OTCKOJUMXQWKQG-UHFFFAOYSA-L 0.000 claims description 2
- 229910001623 magnesium bromide Inorganic materials 0.000 claims description 2
- 239000011591 potassium Substances 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- 159000000001 potassium salts Chemical class 0.000 claims description 2
- 235000009518 sodium iodide Nutrition 0.000 claims description 2
- 229950009390 symclosene Drugs 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 20
- 238000005260 corrosion Methods 0.000 description 17
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 16
- 230000007797 corrosion Effects 0.000 description 16
- 230000001590 oxidative effect Effects 0.000 description 10
- 239000005708 Sodium hypochlorite Substances 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 8
- 229910052742 iron Inorganic materials 0.000 description 8
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 8
- 238000004659 sterilization and disinfection Methods 0.000 description 7
- 230000007423 decrease Effects 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 239000012085 test solution Substances 0.000 description 5
- 229910000831 Steel Inorganic materials 0.000 description 4
- 238000007792 addition Methods 0.000 description 4
- 239000003619 algicide Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- 239000000654 additive Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 239000000498 cooling water Substances 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 230000001954 sterilising effect Effects 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- 150000007973 cyanuric acids Chemical class 0.000 description 2
- 230000000249 desinfective effect Effects 0.000 description 2
- 150000001469 hydantoins Chemical class 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- 229910001209 Low-carbon steel Inorganic materials 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- -1 cyclic amide compound Chemical class 0.000 description 1
- 239000002778 food additive Substances 0.000 description 1
- 235000013373 food additive Nutrition 0.000 description 1
- 239000010842 industrial wastewater Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000003641 microbiacidal effect Effects 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- UKLNMMHNWFDKNT-UHFFFAOYSA-M sodium chlorite Chemical compound [Na+].[O-]Cl=O UKLNMMHNWFDKNT-UHFFFAOYSA-M 0.000 description 1
- 229960002218 sodium chlorite Drugs 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000009182 swimming Effects 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/76—Treatment of water, waste water, or sewage by oxidation with halogens or compounds of halogens
- C02F1/766—Treatment of water, waste water, or sewage by oxidation with halogens or compounds of halogens by means of halogens other than chlorine or of halogenated compounds containing halogen other than chlorine
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B11/00—Oxides or oxyacids of halogens; Salts thereof
- C01B11/04—Hypochlorous acid
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B7/00—Halogens; Halogen acids
- C01B7/01—Chlorine; Hydrogen chloride
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Plant Pathology (AREA)
- Dentistry (AREA)
- Water Supply & Treatment (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Hydrology & Water Resources (AREA)
- Health & Medical Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56005063A JPS57119981A (en) | 1981-01-19 | 1981-01-19 | Method for stabilizing aqueous solution containing chlorine-containing oxidizing agent |
| GB8201256A GB2095111B (en) | 1981-01-19 | 1982-01-18 | Method for stabilizing an aqueous solution containing a chlorine-based oxidant |
| FR8200753A FR2498172B1 (fr) | 1981-01-19 | 1982-01-19 | Procede pour stabiliser une solution aqueuse contenant un oxydant a base de chlore et solution aqueuse ainsi stabilisee |
| DE19823201460 DE3201460A1 (de) | 1981-01-19 | 1982-01-19 | Verfahren zur stabilisierung einer waessrigen loesung, welche ein oxidationsmittel auf chlorbasis enthaelt, sowie eine stabilisierte waessrige loesung desselben |
| US06/340,595 US4411799A (en) | 1981-01-19 | 1982-01-19 | Method for stabilizing an aqueous solution containing a chlorine-based oxidant |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56005063A JPS57119981A (en) | 1981-01-19 | 1981-01-19 | Method for stabilizing aqueous solution containing chlorine-containing oxidizing agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS57119981A JPS57119981A (en) | 1982-07-26 |
| JPS6324485B2 true JPS6324485B2 (US07534539-20090519-C00280.png) | 1988-05-20 |
Family
ID=11600930
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP56005063A Granted JPS57119981A (en) | 1981-01-19 | 1981-01-19 | Method for stabilizing aqueous solution containing chlorine-containing oxidizing agent |
Country Status (5)
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4643835A (en) * | 1985-08-28 | 1987-02-17 | Nalco Chemical Company | Asiatic clam control chemical |
| US4872999A (en) * | 1987-07-17 | 1989-10-10 | Nalco Chemical Company | Mixture of halides such as NaOCl and a bromide salt for removal of mussels and barnacles from salt or brackish water |
| US4975109A (en) * | 1988-05-02 | 1990-12-04 | Lester Technologies Corp. | Microbiocidal combinations of materials and their use |
| GB8814222D0 (en) * | 1988-06-15 | 1988-07-20 | Total Pool Chemicals Ltd | Improvement in/relating to sanitation of swimming pool water |
| CA2056379C (en) * | 1989-06-16 | 2001-01-09 | Thomas C. Kuechler | Biocidal methods and compositions for recirculating water systems |
| US5688515A (en) * | 1989-06-16 | 1997-11-18 | Occidental Chemical Corporation | Hypochlorite donor/bromide ion donor tablets which are stable in water |
| US5254526A (en) * | 1989-08-24 | 1993-10-19 | Jock Hamilton | Method to prevent algae growth in pools and spas |
| US5141652A (en) * | 1990-04-18 | 1992-08-25 | Ethyl Corporation | Water treatment process |
| US5194162A (en) * | 1991-07-05 | 1993-03-16 | Hodak Frank J | Method for treating swimming pool water |
| KR100339129B1 (ko) * | 1999-12-13 | 2002-05-31 | 심상희 | 알칼리 금속 또는 알칼리 토금속의 차아브롬산염을 이용한미생물 오염제어방법 및 이에 사용되는 오염제어시스템 |
| KR100486381B1 (ko) * | 2002-03-05 | 2005-04-29 | 애큐랩주식회사 | 차아염소산염과 브로마이드이온 공급원으로 구성되어 있는미생물 살균제의 제조방법 및 이를 이용한 미생물 제어방법 |
| US9371556B2 (en) | 2004-03-05 | 2016-06-21 | Gen-Probe Incorporated | Solutions, methods and kits for deactivating nucleic acids |
| US20060099274A1 (en) * | 2004-11-10 | 2006-05-11 | Hoshizaki Denki Kabushiki Kaisha | Expulsive liquid for exterminating disease injury of plants |
| DE102005058339A1 (de) * | 2005-12-06 | 2007-06-28 | Henkel Kgaa | Stabilitätsverbesserung flüssiger hypochlorithaltiger Wasch- und Reinigungsmittel |
| DE102005058642B3 (de) * | 2005-12-07 | 2007-07-26 | Henkel Kgaa | Erhöhung der Stabilität flüssiger hypochlorithaltiger Wasch- und Reinigungsmittel |
| DE102005062008B3 (de) | 2005-12-22 | 2007-08-30 | Henkel Kgaa | Geruchsreduktion hypochlorithaltiger Mittel |
| DE102005063181A1 (de) * | 2005-12-30 | 2007-07-05 | Henkel Kgaa | Erhöhung der Stabilität hypochlorithaltiger Waschmittel |
| DE102005063177A1 (de) | 2005-12-30 | 2007-07-05 | Henkel Kgaa | Erhöhung der Stabilität hypochlorihaltiger Waschmittel |
| RU2617724C1 (ru) * | 2015-12-09 | 2017-04-26 | Михаил Алексеевич Баранов | Акустическая система с набором сменных акустических линз |
| EP4054338A4 (en) * | 2019-11-06 | 2023-12-06 | De Nora Holdings US, Inc. | CONTROLLED PRODUCTION OF AQUEOUS HALOGEN SOLUTIONS WITH DIFFERENT COMPOSITIONS |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2464198A (en) * | 1945-08-24 | 1949-03-15 | Jr Goldsmith Hall Conant | Process for preparing a chemical composition for water purification |
| US2583558A (en) * | 1949-09-10 | 1952-01-29 | Morgan Sabalol Products Inc | Octaglycine dihydroheptiodide and methods of making the same |
| US2583559A (en) * | 1949-09-10 | 1952-01-29 | Morgan Sabalol Products Inc | Tetraglycine dihydroheptiodide and methods of making the same |
| US3147219A (en) * | 1961-06-14 | 1964-09-01 | Laurence O Paterson | Process of disinfecting water |
| US3928575A (en) * | 1971-02-24 | 1975-12-23 | Dow Chemical Co | Method and composition for rapid disinfection |
| US3799758A (en) * | 1971-08-09 | 1974-03-26 | Monsanto Co | N-phosphonomethyl-glycine phytotoxicant compositions |
| JPS5647163B2 (US07534539-20090519-C00280.png) * | 1974-06-29 | 1981-11-07 | ||
| US3930015A (en) * | 1975-01-30 | 1975-12-30 | Betz Laboratories | Slimicidal compositions containing 2,2-dibromo-3-nitrilopropionamide and their use |
| US4297224A (en) * | 1980-06-04 | 1981-10-27 | Great Lakes Chemical Corporation | Method for the control of biofouling in recirculating water systems |
-
1981
- 1981-01-19 JP JP56005063A patent/JPS57119981A/ja active Granted
-
1982
- 1982-01-18 GB GB8201256A patent/GB2095111B/en not_active Expired
- 1982-01-19 FR FR8200753A patent/FR2498172B1/fr not_active Expired
- 1982-01-19 US US06/340,595 patent/US4411799A/en not_active Expired - Fee Related
- 1982-01-19 DE DE19823201460 patent/DE3201460A1/de active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| DE3201460A1 (de) | 1982-08-26 |
| FR2498172B1 (fr) | 1988-07-08 |
| DE3201460C2 (US07534539-20090519-C00280.png) | 1987-04-30 |
| US4411799A (en) | 1983-10-25 |
| GB2095111B (en) | 1984-04-18 |
| FR2498172A1 (fr) | 1982-07-23 |
| GB2095111A (en) | 1982-09-29 |
| JPS57119981A (en) | 1982-07-26 |
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